CN104860645A - Glazed tile prepared from yellow soil - Google Patents

Glazed tile prepared from yellow soil Download PDF

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Publication number
CN104860645A
CN104860645A CN201510289561.2A CN201510289561A CN104860645A CN 104860645 A CN104860645 A CN 104860645A CN 201510289561 A CN201510289561 A CN 201510289561A CN 104860645 A CN104860645 A CN 104860645A
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Prior art keywords
parts
cotta
terra
loess
glaze
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CN201510289561.2A
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CN104860645B (en
Inventor
马生芳
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SINO RISING-SUN CONSTRUCTION GROUP CO., LTD.
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Suzhou Tuo Ke Instrument And Equipment Co Ltd
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Abstract

The invention relates to glazed tile prepared from yellow soil. The green body of the glazed tile comprises yellow soil, high alumina bauxite, albite, quartz, fused magnesite, carbon fiber, phenol formaldehyde resin, starch and rice hull; glaze of the glazed tile comprises iron oxide yellow, titanium dioxide, feldspar powder, nano-zinc oxide, silicon nitride, carbon fiber, stannic oxide, TEOS and polytetrafluoroethylene. The glazed tile is smooth and clean in surface and bright in color, has good properties of crush resistance, fire resistance and acid and alkali resistance, and is light in mass, low in water absorption, good in breathability and low in cost.

Description

A kind of terra-cotta utilizing loess to prepare
Technical field
The invention belongs to terra-cotta field, particularly a kind of terra-cotta utilizing loess to prepare.
Background technology
Terra-cotta are ancient, the traditional stupaliths of one, China.Along with the development of tourism, people are also more and more for the demand of terra-cotta, are also more and more higher to its requirement.
Terra-cotta, material is firm, bright in luster, glaze colours is smooth, and always as the building object of Chinese tradition, it developed through the successive dynasties, the improvement of quality, owing to having multiple excellent function, and is widely used in modern architecture.
Existing terra-cotta are all adopt multiple pug mixed sintering to form usually, and its glaze layer is general thicker and produce stress, quality weight, easily cause product glaze paint to occur be full of cracks, collapse the defect of stripping.Smooth not, and pug easily produces pollution in process of production, cost and energy consumption high, the quality of product is stable not, and its glaze paint glossiness is inadequate, and colour generation is abundant not, stable, easily fades under solar radiation in climate variability area or for a long time.
The technical problem that the present invention mainly solves is: for the deficiencies in the prior art, a kind of terra-cotta utilizing loess to prepare are provided, this terra-cotta smooth surface is clean and tidy, bright in colour beautiful, there is the performance of excellent resistance to compression, fire-resistant and acid and alkali-resistance, and quality is light, water-intake rate is low, good permeability, and cost is low.
Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of terra-cotta utilizing loess to prepare, by optimizing the composition of terra-cotta base substrate and glaze, improve the colouring effect of terra-cotta, resistance to compression, the performance of fire-resistant and acid and alkali-resistance and the physical and chemical performance such as water-intake rate and ventilation property.
Utilize terra-cotta prepared by loess, this terra-cotta base substrate weight part is composed as follows:
Loess 100-120 part; Alumine 20-30 part; Albite 8-10 part; Quartz 2-6 part; Electrosmelted magnesite clinker 2-6 part; Carbon fiber 2-6 part; Resol 2-6 part; Starch 2-6 part; Rice husk 2-6 part;
This terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 40-50 part; Titanium dioxide 1-5 part; Feldspar Powder 1-5 part; Nano zine oxide 1-5 part; Silicon carbide 1-5 part; Carbon fiber 1-5 part; Tindioxide 1-5 part; TEOS 1-5 part; Tetrafluoroethylene 1-5 part;
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
As preferably, the chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
As preferably, the particle diameter of alumine is less than 1 μm.
As preferably, this terra-cotta base substrate weight part is composed as follows:
Loess 110 parts; Alumine 25 parts; Albite 9 parts; 2 parts, quartz; Electrosmelted magnesite clinker 2 parts; 2 parts, carbon fiber; 2 parts, resol; Starch 2 parts; 2 parts, rice husk.
As preferably, this terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 45 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts.
Beneficial effect of the present invention:
(1) generally speaking, by optimizing the composition of terra-cotta base substrate and glaze, the colouring effect of terra-cotta, resistance to compression, the performance of fire-resistant and acid and alkali-resistance and the physical and chemical performance such as water-intake rate and ventilation property is improved; This terra-cotta smooth surface is clean and tidy, bright in colour beautiful, and have the performance of excellent resistance to compression, fire-resistant and acid and alkali-resistance, and quality is light, water-intake rate is low, good permeability, and cost is low.The water-intake rate of these terra-cotta is less than 5.5%, and ultimate compression strength is greater than 56Mpa.
(2) in base substrate batching, be the first main raw material with loess, alumine is the second main raw material, and auxiliary albite, quartz, electrosmelted magnesite clinker, carbon fiber, resol, starch and rice husk, and the weight part composition by optimizing each component, the resistance to compression of customer service loess is strong, the imperfect deficiency of stability, and optimizes water suction and the permeability of base substrate.And there is good viscosity due to loess, better with the keying action of glaze layer, therefore, glaze layer can be very thin, thus can prevent glaze paint from occurring be full of cracks, collapse the defect of stripping.Meanwhile, loess carries color, also can produce material impact to the colour brightness of terra-cotta entirety.
(3) by with the addition of titanium dioxide and silicon carbide in glaze, the toughness of upper layer can be improved, and nano zine oxide, the automatically cleaning effect of terra-cotta can be played; And Feldspar Powder can play the effect of sintering aid; And the interpolation of TEOS and tetrafluoroethylene, effective surface protection can be carried out for terra-cotta, improve the smooth degree on surface.Terra-cotta smooth surface out prepared by the application is clean and tidy, bright in colour beautiful, and has good stability.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
Utilize terra-cotta prepared by loess,
This terra-cotta base substrate weight part is composed as follows:
Loess 110 parts; Alumine 25 parts; Albite 9 parts; 2 parts, quartz; Electrosmelted magnesite clinker 2 parts; 2 parts, carbon fiber; 2 parts, resol; Starch 2 parts; 2 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 45 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts;
The chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
The particle diameter of alumine is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
Embodiment 2:
Utilize terra-cotta prepared by loess,
This terra-cotta base substrate weight part is composed as follows:
Loess 112 parts; Alumine 26 parts; Albite 8 parts; 2 parts, quartz; Electrosmelted magnesite clinker 4 parts; 2 parts, carbon fiber; 4 parts, resol; Starch 2 parts; 2 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 46 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts;
The chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
The particle diameter of alumine is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
Embodiment 3:
Utilize terra-cotta prepared by loess,
This terra-cotta base substrate weight part is composed as follows:
Loess 109 parts; Alumine 22 parts; Albite 9 parts; 5 parts, quartz; Electrosmelted magnesite clinker 5 parts; 5 parts, carbon fiber; 5 parts, resol; Starch 5 parts; 5 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 42 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts;
The chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
The particle diameter of alumine is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
Embodiment 4:
Utilize terra-cotta prepared by loess,
This terra-cotta base substrate weight part is composed as follows:
Loess 119 parts; Alumine 27 parts; Albite 9 parts; 2 parts, quartz; Electrosmelted magnesite clinker 5 parts; 2 parts, carbon fiber; 2 parts, resol; Starch 2 parts; 5 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 47 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts;
The chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
The particle diameter of alumine is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
Embodiment 5:
Utilize terra-cotta prepared by loess,
This terra-cotta base substrate weight part is composed as follows:
Loess 100 parts; Alumine 20 parts; Albite 9 parts; 4 parts, quartz; Electrosmelted magnesite clinker 5 parts; 4 parts, carbon fiber; 5 parts, resol; Starch 4 parts; 5 parts, rice husk;
This terra-cotta glaze weight part is composed as follows,
Iron oxide yellow 50 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts;
The chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
The particle diameter of alumine is less than 1 μm.
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.

Claims (5)

1. the terra-cotta utilizing loess to prepare, is characterized in that:
This terra-cotta base substrate weight part is composed as follows:
Loess 100-120 part; Alumine 20-30 part; Albite 8-10 part; Quartz 2-6 part; Electrosmelted magnesite clinker 2-6 part; Carbon fiber 2-6 part; Resol 2-6 part; Starch 2-6 part; Rice husk 2-6 part;
This terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 40-50 part; Titanium dioxide 1-5 part; Feldspar Powder 1-5 part; Nano zine oxide 1-5 part; Silicon carbide 1-5 part; Carbon fiber 1-5 part; Tindioxide 1-5 part; TEOS 1-5 part; Tetrafluoroethylene 1-5 part;
Its preparation method is as follows:
(1) batch mixing: terra-cotta blank raw material is weighed, pulverizes, sieved, add water batch mixing, and old mud 3 days;
(2) pressed compact is shaping, makes type at 55Mpa pressure, is incubated 2 hours, the demoulding;
(3) base substrate is dried: dry 1 hour at 150 DEG C in drying kiln, during kiln discharge, base substrate water-content is less than 1.2wt%;
(4) glazing: glaze raw material is added water and prepares glaze, and glazing, glaze thickness is 0.2mm; Dry 24 hours after glazing and at 150 DEG C;
(5) burn till: in calcining kiln, temperature rise rate 80 DEG C/h, after being warming up to 1500 DEG C, be incubated 2 hours, utilize loess to prepare terra-cotta.
2. the terra-cotta utilizing loess to prepare as claimed in claim 1, is characterized in that, the chemical constitution of loess is: SiO2 55wt%, Al2O3 25wt%, Fe2O3 8%, CaO 7wt%, other compositions 5wt%.
3. the terra-cotta utilizing loess to prepare as claimed in claim 1 or 2, is characterized in that, the particle diameter of alumine is less than 1 μm.
4. the terra-cotta utilizing loess to prepare as claimed in claim 1, is characterized in that, this terra-cotta base substrate weight part is composed as follows:
Loess 110 parts; Alumine 25 parts; Albite 9 parts; 2 parts, quartz; Electrosmelted magnesite clinker 2 parts; 2 parts, carbon fiber; 2 parts, resol; Starch 2 parts; 2 parts, rice husk.
5. the terra-cotta utilizing loess to prepare as described in claim 1 or 5, is characterized in that, this terra-cotta glaze weight part is composed as follows:
Iron oxide yellow 45 parts; Titanium dioxide 2 parts; Feldspar Powder 2 parts; Nano zine oxide 2 parts; 2 parts, silicon carbide; 2 parts, carbon fiber; Tindioxide 2 parts; TEOS 2 parts; Tetrafluoroethylene 2 parts.
CN201510289561.2A 2015-06-01 2015-06-01 A kind of glazed tiles utilizing loess to prepare Expired - Fee Related CN104860645B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107352809A (en) * 2017-07-24 2017-11-17 太仓市科教新城琉璃艺术策划中心 A kind of coloured glaze containing loess composition
CN107365076A (en) * 2017-07-24 2017-11-21 太仓市科教新城琉璃艺术策划中心 A kind of coloured glaze containing alumine composition
CN107555926A (en) * 2017-08-18 2018-01-09 寿县维东建材商贸有限公司 A kind of azulejo watt of service life length and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103538141A (en) * 2013-10-15 2014-01-29 常熟大象建陶有限公司 Colored glaze ceramic tile, production method of colored glaze ceramic tile, and forming device using production method
CN103693993A (en) * 2013-12-23 2014-04-02 宾阳县明翔新材料科技有限公司 Ceramic tile with heat-preservation and heat-insulation functions and production method of same
CN103833325A (en) * 2014-01-04 2014-06-04 安徽省含山瓷业股份有限公司 Low-cost domestic ceramic containing laterite
CN104311152A (en) * 2014-09-30 2015-01-28 句容金猴机械研究所有限公司 Glazed tile glaze and preparation method and application thereof
CN104860644A (en) * 2015-05-29 2015-08-26 苏州拓科仪器设备有限公司 Underglaze blue and underglaze red glaze ceramic

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103538141A (en) * 2013-10-15 2014-01-29 常熟大象建陶有限公司 Colored glaze ceramic tile, production method of colored glaze ceramic tile, and forming device using production method
CN103693993A (en) * 2013-12-23 2014-04-02 宾阳县明翔新材料科技有限公司 Ceramic tile with heat-preservation and heat-insulation functions and production method of same
CN103833325A (en) * 2014-01-04 2014-06-04 安徽省含山瓷业股份有限公司 Low-cost domestic ceramic containing laterite
CN104311152A (en) * 2014-09-30 2015-01-28 句容金猴机械研究所有限公司 Glazed tile glaze and preparation method and application thereof
CN104860644A (en) * 2015-05-29 2015-08-26 苏州拓科仪器设备有限公司 Underglaze blue and underglaze red glaze ceramic

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107352809A (en) * 2017-07-24 2017-11-17 太仓市科教新城琉璃艺术策划中心 A kind of coloured glaze containing loess composition
CN107365076A (en) * 2017-07-24 2017-11-21 太仓市科教新城琉璃艺术策划中心 A kind of coloured glaze containing alumine composition
CN107555926A (en) * 2017-08-18 2018-01-09 寿县维东建材商贸有限公司 A kind of azulejo watt of service life length and preparation method thereof

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