CN107500540B - Wear-resistant ceramic tile decal glaze, preparation method thereof and glazed tile - Google Patents
Wear-resistant ceramic tile decal glaze, preparation method thereof and glazed tile Download PDFInfo
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- CN107500540B CN107500540B CN201710638449.4A CN201710638449A CN107500540B CN 107500540 B CN107500540 B CN 107500540B CN 201710638449 A CN201710638449 A CN 201710638449A CN 107500540 B CN107500540 B CN 107500540B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead
- C03C8/12—Frit compositions, i.e. in a powdered or comminuted form containing lead containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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Abstract
The invention discloses a wear-resistant porcelainThe brick decal glaze comprises prefabricated components, printing paste and printing oil, wherein the prefabricated components comprise the following raw materials in parts by weight: 65-75 parts of frit; 10-20 parts of feldspar; 10-15 parts of kaolinite; the frit comprises the following components in percentage by weight: 0.05-0.08% Fe2O3；0.52‑1.84%MgO；6.31‑10.56%CaO；0.22‑1.5%TiO2；10.48‑18.98%Al2O3；58.56‑65.94%SiO2；0.01‑0.02%ZrO2；0.72‑1.83%PbO；3.14‑5.85%ZnO；0.01‑0.02%B2O3(ii) a 1.83-5.35% BaO. The invention also discloses a preparation method of the wear-resistant ceramic tile decal and a wear-resistant glazed tile. The invention can improve the wear resistance and transparency of the glazed surface of the ceramic tile.
Description
Technical Field
The invention relates to the field of ceramics, in particular to a wear-resistant ceramic tile decal and a preparation method of the wear-resistant ceramic tile decal.
Background
With the continuous improvement of the quality and taste of life of people, the requirements of people on houses are not only on the layer of keeping out wind and rain and keeping warm, but also on the quality of family life. Therefore, the ceramic tiles play a very important role in home decoration. With the development of the economy, the ceramic tile is developed and improved in all aspects along with the development and improvement of science and technology, and the ceramic tile is developed from the initial external wall tile and the internal wall tile to the full-glazed ceramic tile and the imitation stone at present. Although the prior full-glazed and stone-like ceramic tile has the advantages of rich colors and high glossiness, the abrasion resistance of the glaze layer on the surface of the existing ceramic tile product is about 2000 turns, and after the full-glazed ceramic tile is used for a period of time, the scratch marks on the glaze surface are very obvious, so that the beautiful effect is greatly reduced. In addition, insufficient hardness of the glazed layer of the tile results in easy damage to the tile surface. The transparency of the glaze layer is not high, so that the color is not bright and bright enough, and the improvement of the product quality is influenced.
Disclosure of Invention
The invention aims to solve the technical problem of providing a wear-resistant ceramic tile decal glaze which can improve the wear resistance and transparency of a ceramic tile glaze.
The technical problem to be solved by the invention is to provide a preparation method of the wear-resistant ceramic tile decal glaze, which can improve the wear resistance and transparency of the ceramic tile glaze.
The technical problem to be solved by the invention is to provide a wear-resistant glazed tile, which can improve the wear resistance and transparency of the glazed tile.
In order to solve the technical problem, the invention provides a wear-resistant tile decal glaze which comprises a prefabricated component, a printing paste and printing oil, wherein the prefabricated component comprises the following raw materials in parts by weight:
65-75 parts of frit;
10-20 parts of feldspar;
10-15 parts of kaolinite;
the frit comprises the following components in percentage by weight:
Fe2O30.05-0.08%；
MgO 0.52-1.84%；
CaO 6.31-10.56%；
TiO20.22-1.5%；
Al2O310.48-18.98%；
SiO258.56-65.94%；
ZrO20.01-0.02%；
PbO 0.72-1.83%；
ZnO 3.14-5.85%；
B2O30.01-0.02%；
BaO 1.83-5.35%。
as the preferable technical scheme of the wear-resistant ceramic tile decal glaze, the prefabricated components, the printing paste and the printing oil are mixed according to the following weight parts:
95-110 parts of prefabricated components;
50-60 parts of printing paste;
20-30 parts of stamp-pad ink.
As the preferable technical scheme of the wear-resistant ceramic tile decal, the stamp-pad ink is prepared from the following raw materials: ethylene glycol, glycerol, diethylene glycol, carboxymethyl cellulose and water.
As a preferable technical scheme of the wear-resistant tile decal, the frit comprises the following components in percentage by weight:
Fe2O30.05-0.08%；
MgO 0.72-1.35%；
CaO 6.31-9.56%；
TiO20.32-0.97%；
Al2O311.35-15.98%；
SiO260.56-63.94%；
ZrO20.01-0.02%；
PbO 0.72-1.83%；
ZnO 3.14-4.85%；
B2O30.01-0.02%；
BaO 1.83-3.35%。
correspondingly, the invention also provides a preparation method of the wear-resistant ceramic tile decal, which comprises the following steps:
A. preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
sending the frits, the feldspar and the kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry;
sending the screened slurry into a roller way type dryer for drying, powdering, grinding and refining to prepare a prefabricated component;
B. preparing a decal:
weighing 95-110 parts of prefabricated components, 50-60 parts of stamp-pad ink and 20-30 parts of stamp-pad ink;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
As a preferred technical scheme of the preparation method of the wear-resistant ceramic tile decal glaze, in the step of preparing the prefabricated components, slurry after ball milling is sieved by a 325-mesh sieve, and the sieve allowance is less than or equal to 0.05 g.
As the preferable technical scheme of the preparation method of the wear-resistant ceramic tile decal glaze, in the step of preparing the prefabricated components, slurry after screening is sent into a roller way type dryer and dried at the temperature of 180-220 ℃.
Correspondingly, the invention also provides a glazed tile printed with the wear-resistant ceramic tile decal, wherein the glazed tile is a ceramic tile applied with the wear-resistant ceramic tile decal.
As the preferable technical scheme of the glazed tile printed with the wear-resistant tile decal glaze, the wear resistance of the glaze layer of the glazed tile is 10000-12000 turns.
The implementation of the invention has the following beneficial effects:
by adjusting the formula and process of the decal glaze, the initial melting temperature and the melting temperature of the decal glaze are improved, and the way of high-temperature slow burning is combined, so that the problem of glaze layer bubbles caused by decomposition and volatilization of organic matters, carbonate and the like in a blank during one-time burning is solved, and finally, the glaze layer is compact, and has no crystallization and micro-bubbles. Compared with the existing print glaze, the print glaze provided by the invention is printed by a flat-bed printing machine, and various performances such as wear resistance, breaking strength and stain resistance of the glazed tile obtained after high-temperature sintering are obviously improved, so that the technical problems that the traditional glazed tile is not wear-resistant, the surface is easy to wear out and the surface is easy to scratch are solved. Meanwhile, the formula of the printed glaze adopts high-transparency raw materials, and the prepared glaze layer is full and rich in color, natural in texture and high in simulation degree.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail below.
In the existing glazed tile, a plurality of micro bubbles are generated in a glaze layer due to the decomposition and volatilization of organic matters, carbonate and the like in a blank body, and the micro bubbles are difficult to be discharged into air and retained in the glaze layer, so that the compactness, the wear resistance and the transparency of the glaze layer are difficult to be improved.
Therefore, the invention improves the initial melting temperature and the melting temperature of the glaze by adjusting the formula of the glaze, overcomes the defects of glaze layer bubbles caused by decomposition and volatilization of organic matters, carbonate and the like in a blank during one-time firing by adopting a high-temperature slow firing mode, finally ensures that the glaze layer is compact, does not have crystallization and microbubbles, and meets the requirements of the glaze layer on luster, transparency and high hardness.
The invention provides a wear-resistant tile decal glaze which comprises a prefabricated component, a printing paste and printing oil, wherein the prefabricated component comprises the following raw materials in parts by weight:
65-75 parts of frit;
10-20 parts of feldspar;
10-15 parts of kaolinite;
the frit comprises the following components in percentage by weight:
Fe2O30.05-0.08%；
MgO 0.52-1.84%；
CaO 6.31-10.56%；
TiO20.22-1.5%；
Al2O310.48-18.98%；
SiO258.56-65.94%；
ZrO20.01-0.02%；
PbO 0.72-1.83%；
ZnO 3.14-5.85%；
B2O30.01-0.02%；
BaO 1.83-5.35%。
the frit in the formula of the decal glaze is an important raw material influencing the wear resistance and transparency of the glaze layer, so that the inventor conducts comparison experiments on different frit components through long-term repeated research to find a formula capable of improving the wear resistance and transparency of the glaze layer.
The following is a formulation table for three frit formulations # 1, # 2 and # 3:
| serial number | Fe2O3（%） | MgO（%） | CaO（%） | TiO2（%） | Al2O3（%） | SiO2（%） | ZrO2（%） | PbO（%） | ZnO（%） | B2O3（%） | BaO（%） |
| 1# | 0.07 | 1.54 | 8.96 | 1.07 | 13.8 | 62.79 | 0.02 | 1.2 | 5.39 | 0.01 | 5.15 |
| 2# | 0.08 | 1.42 | 8.93 | 0.78 | 14.8 | 63.98 | 0.01 | 1.0 | 4.53 | 0.01 | 4.46 |
| 3# | 0.06 | 1.76 | 9.28 | 0.87 | 15.6 | 63.8 | 0.01 | 1.0 | 4.72 | 0.01 | 2.89 |
The method comprises the steps of mixing the three frits 1#, 2# and 3# with feldspar and kaolinite with the same weight to prepare prefabricated components, preparing A, B and C three decal glaze samples according to the proportion of 100 parts of the prefabricated components, 55 parts of printing paste and 25 parts of printing oil, and inspecting various performance indexes of glazed tiles applying the A, B and C three decal glaze samples and existing glazed tiles according to national standards GB/T4100-2015 & lt 0.5% Bla type-ceramic tiles & gt ceramic tile annex G dry-pressing ceramic tiles E & lt 0.5% and national standards GB 6566-2010 & lt & gt building material radionuclide limits & gt, wherein A, B and C products meet the related requirements of the national standards and meet the requirements of class A decorative materials in the national standards. The test results are as follows:
| item | A | B | C | Existing glazed tile |
| Average Water absorption (%) | 0.01% | 0.01% | 0.02% | 0.05% |
| Breaking Strength (N) | 3120 | 3450 | 3200 | 2800 |
| Modulus of rupture (Mpa) | 38 | 42 | 40 | 40 |
| Abrasion resistance (turn) | 12000 to 4 stages | 12000 to 4 stages | 12000 to 4 stages | 6000-4 grade |
| Stain resistance (grade) | Grade GL A | Grade GL A | Grade GL A | Grade GL B |
| Transparency | 84% | 85% | 85% | 60% |
The detection results show that the glazed tile prepared by the formula 2# frit formula has the best performances such as wear resistance, modulus of rupture, water absorption and the like. Compared with the existing print glaze, the print glaze provided by the invention is printed by a flat-bed printing machine, and the wear resistance, the breaking strength and the pollution resistance of the glazed tile obtained after high-temperature sintering are obviously improved, so that the technical problems that the traditional glazed tile is not wear-resistant, the surface is easy to wear, and the surface is easy to scratch are solved. Meanwhile, the formula of the printed glaze adopts high-transparency raw materials, and the prepared glaze layer is full and rich in color, natural in texture and high in simulation degree.
Correspondingly, the invention also provides a preparation method of the wear-resistant ceramic tile decal, which comprises the following steps:
A. preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
sending the frits, the feldspar and the kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry;
sending the screened slurry into a roller way type dryer for drying, powdering, grinding and refining to prepare a prefabricated component;
B. preparing a decal:
weighing 95-110 parts of prefabricated components, 50-60 parts of stamp-pad ink and 20-30 parts of stamp-pad ink;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
Preferably, the stamp-pad ink is prepared from the following raw materials: ethylene glycol, glycerol, diethylene glycol, carboxymethyl cellulose and water.
In order to better mix the frit, feldspar and kaolinite with the paste and the stamp-pad ink uniformly, the preparation method comprises the steps of firstly carrying out wet ball milling on the frit, the feldspar and the kaolinite for 24 hours by using a high-alumina lining ball mill, and sieving slurry after ball milling by using a 325-mesh sieve, wherein the sieve residue is less than or equal to 0.05 g. And then sending the screened slurry into a roller way type dryer, drying at the temperature of 200 ℃, powdering, grinding and refining to obtain the prefabricated components.
And (3) feeding the components into a high-alumina lining ball mill according to the proportion of 100 parts of the prefabricated components, 55 parts of the printing paste and 25 parts of the printing oil, and carrying out ball milling for 2.5 hours, wherein the purpose of ball milling again is to uniformly mix the three materials without making requirements on fineness because the fineness of the prefabricated components meets the requirement. And then placing the ball-milled printed glaze for 48h to age the ball-milled printed glaze, and aiming at further uniformly dispersing the stamp-pad ink and the stamp-pad ink, fully discharging bubbles generated in the glaze making process and avoiding the influence on the properties of compactness, hardness, transparency and the like of a glaze layer caused by the bubbles remained in the glaze layer prepared by using the printed glaze.
Correspondingly, the invention also provides a glazed tile printed with the wear-resistant ceramic tile decal, wherein the glazed tile is a ceramic tile applied with the wear-resistant ceramic tile decal.
It is noted that the wear resistance of the glaze layer of the glazed tile reaches 10000-12000 turns.
The glazed tile can be an antiskid tile, an antique tile or a wall tile, but is not limited to the above list.
By adjusting the formula and process of the decal glaze, the initial melting temperature and the melting temperature of the decal glaze are improved, and a high-temperature slow-burning mode is combined, so that the problem that glaze layer bubbles are caused by decomposition and volatilization of organic matters, carbonate and the like in a blank body during one-time burning is solved, the glaze layer is compact, free of crystallization and micro-bubble, and the requirements of the glaze layer on luster, transparency and high hardness are met.
The following is further illustrated by the specific examples:
example 1
A. Preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
the prefabricated components are prepared from the following raw materials in parts by weight:
65 parts of frit;
20 parts of feldspar;
15 parts of kaolinite;
the frit comprises the following components in percentage by weight:
Fe2O30.07%；
MgO 1.54%；
CaO 8.96%；
TiO21.07%；
Al2O313.8%；
SiO262.79%；
ZrO20.02%；
PbO 1.2%；
ZnO 5.39%；
B2O30.01%；
BaO 5.15%。
sending the frits, feldspar and kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry by a 325-mesh sieve with the sieve allowance less than or equal to 0.05 g;
feeding the sieved slurry into a roller way type dryer, drying at the temperature of 200 ℃, pulverizing, grinding and refining to obtain a prefabricated component;
B. preparing a decal:
weighing 95 parts of prefabricated components, 60 parts of stamp-pad ink and 20 parts of stamp-pad ink;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
C. Preparing glazed tiles:
and (3) applying the printing glaze on the surface of the ceramic tile blank by a lithography process, firing at the high temperature of 1100-1250 ℃ for 120 minutes, preserving the heat for 15 minutes, cooling, taking out, and polishing to finally obtain the glazed tile.
Example 2
A. Preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
the prefabricated components are prepared from the following raw materials in parts by weight:
60 parts of frit;
15 parts of feldspar;
15 parts of kaolinite;
the frit comprises the following components in percentage by weight:
Fe2O30.08%；
MgO 1.42%；
CaO 8.93%；
TiO20.78%；
Al2O314.8%；
SiO263.98%；
ZrO20.01%；
PbO 1.0%；
ZnO 4.53%；
B2O30.01%；
BaO 4.46%。
sending the frits, feldspar and kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry by a 325-mesh sieve with the sieve allowance less than or equal to 0.05 g;
feeding the sieved slurry into a roller way type dryer, drying at the temperature of 200 ℃, pulverizing, grinding and refining to obtain a prefabricated component;
B. preparing a decal:
weighing 100 parts of the prefabricated components, 55 parts of the stamp-pad ink and 25 parts of the stamp-pad ink;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
C. Preparing glazed tiles:
and (3) applying the printing glaze on the surface of the ceramic tile blank by a lithography process, firing at the high temperature of 1100-1250 ℃ for 120 minutes, preserving the heat for 15 minutes, cooling, taking out, and polishing to finally obtain the glazed tile.
Example 3
A. Preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
the prefabricated components are prepared from the following raw materials in parts by weight:
72 parts of frit;
18 parts of feldspar;
13 parts of kaolinite;
the frit comprises the following components in percentage by weight:
Fe2O30.08%；
MgO 1.35%；
CaO 6.31%；
TiO21.5%；
Al2O316.23%；
SiO265.34%；
ZrO20.02%；
PbO 1.5%；
ZnO 3.47%；
B2O30.02%；
BaO 4.18%。
sending the frits, feldspar and kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry by a 325-mesh sieve with the sieve allowance less than or equal to 0.05 g;
feeding the sieved slurry into a roller way type dryer, drying at the temperature of 200 ℃, pulverizing, grinding and refining to obtain a prefabricated component;
B. preparing a decal:
weighing 102 parts of the prefabricated components, 58 parts of the stamp-pad ink and 24 parts of stamp-pad ink;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
C. Preparing glazed tiles:
and (3) applying the printing glaze on the surface of the ceramic tile blank by a lithography process, firing at the high temperature of 1100-1250 ℃ for 120 minutes, preserving the heat for 15 minutes, cooling, taking out, and polishing to finally obtain the glazed tile.
Example 4
A. Preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
the prefabricated components are prepared from the following raw materials in parts by weight:
65 parts of frit;
12 parts of feldspar;
15 parts of kaolinite;
the frit comprises the following components in percentage by weight:
Fe2O30.05%；
MgO 1.64%；
CaO 10.2%；
TiO20.95%；
Al2O312.35%；
SiO262.29%；
ZrO20.01%；
PbO 1.80%；
ZnO 5.49%；
B2O30.01%；
BaO 5.21%。
sending the frits, feldspar and kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry by a 325-mesh sieve with the sieve allowance less than or equal to 0.05 g;
feeding the sieved slurry into a roller way type dryer, drying at the temperature of 200 ℃, pulverizing, grinding and refining to obtain a prefabricated component;
B. preparing a decal:
weighing 100 parts of prefabricated components, 60 parts of printing paste and 28 parts of printing oil;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
C. Preparing glazed tiles:
and (3) applying the printing glaze on the surface of the ceramic tile blank by a lithography process, firing at the high temperature of 1100-1250 ℃ for 120 minutes, preserving the heat for 15 minutes, cooling, taking out, and polishing to finally obtain the glazed tile.
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (8)
1. The wear-resistant tile decal glaze is characterized by comprising a prefabricated component, a printing paste and printing oil, wherein the prefabricated component comprises the following raw materials in parts by weight:
65-75 parts of frit;
10-20 parts of feldspar;
10-15 parts of kaolinite;
the frit comprises the following components in percentage by weight:
the prefabricated components, the printing paste and the printing oil are mixed according to the following weight parts:
95-110 parts of prefabricated components;
50-60 parts of printing paste;
20-30 parts of stamp-pad ink.
2. The wear-resistant tile decal according to claim 1, wherein said stamp-pad ink is prepared from the following raw materials: ethylene glycol, glycerol, diethylene glycol, carboxymethyl cellulose and water.
3. The wear-resistant tile decal according to claim 1, wherein said frit comprises, in weight percent:
4. a method of preparing a wear resistant tile decal according to claim 1, comprising the steps of:
A. preparation of the preformed components:
weighing frit, feldspar and kaolinite according to the weight parts for later use;
sending the frits, the feldspar and the kaolinite into a high-alumina lining ball mill for ball milling for 24 hours to form slurry, and sieving the slurry;
sending the screened slurry into a roller way type dryer for drying, powdering, grinding and refining to prepare a prefabricated component;
B. preparing a decal:
weighing 95-110 parts of prefabricated components, 50-60 parts of stamp-pad ink and 20-30 parts of stamp-pad ink;
and (3) feeding the prefabricated components, the printing paste and the printing oil into a high-alumina lining ball mill for ball milling for 2.5 hours, and ageing for 48 hours to obtain the wear-resistant ceramic tile printing glaze.
5. The method for preparing a wear-resistant tile decal according to claim 4, wherein said step of preparing a pre-formed component comprises the step of passing the ball-milled slurry through a 325 mesh sieve with a screen residue of 0.05g or less.
6. The method for preparing the abrasion-resistant tile decal according to claim 4, wherein in the step of preparing the prefabricated components, the screened slurry is sent to a roller-type dryer and dried at the temperature of 180-220 ℃.
7. A glazed tile printed with a wear resistant tile decal according to any one of claims 1-3, wherein said glazed tile is a tile to which said wear resistant tile decal is applied.
8. The glazed tile printed with the wear-resistant tile decal according to claim 7, wherein said glazed tile has a wear resistance of 10000-.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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| CN106587621A (en) * | 2016-11-11 | 2017-04-26 | 广东道氏技术股份有限公司 | Diamond glaze with super abrasion resistance and three-dimensional decorative effect |
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