CN111362577A - Bright glaze for ceramic archaized bricks and preparation method thereof - Google Patents
Bright glaze for ceramic archaized bricks and preparation method thereof Download PDFInfo
- Publication number
- CN111362577A CN111362577A CN202010158003.3A CN202010158003A CN111362577A CN 111362577 A CN111362577 A CN 111362577A CN 202010158003 A CN202010158003 A CN 202010158003A CN 111362577 A CN111362577 A CN 111362577A
- Authority
- CN
- China
- Prior art keywords
- glaze
- weight
- frit
- additives
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/22—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The glaze is prepared by ball milling of glaze and additives, and comprises the following raw materials in percentage by weight: 37-84% of zirconium white frit, 9-56% of transparent frit and 5-7% of clay, wherein the additives are sodium tripolyphosphate and sodium polymethyl cellulose, and the addition amounts of the additives are 0.2-0.4% and 0.3-0.6% of the weight of the glaze respectively; the raw materials are mixed, dried, ball-milled and glazed, and then bright glaze can be formed on the surface of the antique brick blank. The invention develops the bright glaze which can be applied to the green body of the antique brick, has the advantages of smooth, smooth and exquisite glaze surface, high microhardness, higher glossiness, environmental protection and no pollution, and has good wear resistance and decorative performance and obvious bright effect of the antique brick.
Description
Technical Field
The invention relates to the technical field of ceramic preparation, in particular to a bright glaze for ceramic archaized bricks and a preparation method thereof.
Background
As an architectural ceramic product, in order to show the historical heavy feeling and the vicious feeling of the years, a layer of low-glossiness matt glaze is usually applied to the surface of the ceramic archaized brick. In recent years, with the change of the aesthetic sense of people, visual impact is pursued, and the glaze decoration of the antique tile is gradually developed from matt glaze to bright glaze.
The Chinese invention patent "a ceramic bright glaze ink and a preparation method thereof" (CN105131716A) discloses a preparation method of a bright glaze ink for ink-jet printing, wherein the bright glaze comprises the following components in parts by weight: SiO 22：Al2O3：CaO：MgO：KNaO：Li2O：BaO：ZnO：B2O3：P2O555-65: 7-13: 4-10: 2.1-4.5: 4-10: 0.8-2: 4-6: 2.1-5.5: 6-10: 0 to 3 percent of P, 0 to 3 percent of P is present in the glaze material although the glaze obtained after sintering has the excellent performances of smooth glaze surface, brightness, no pinhole, glossiness of more than 91 and the like2O5Its potential toxicity limits its application, and in addition, its wear resistance is not reported. The Chinese invention patent (CN107417117A) discloses a bright glaze with smooth surface and good glossiness without pinholes or bubbles and a preparation method thereof, wherein each component of the bright glaze is SiO255～80wt％，Al2O38～15wt％，B2O30～5wt％，CaO 5～ 13wt％，MgO 2～6wt％，BaO1～8wt％，ZnO 0～5wt％，K2O 1～4wt％，Na2O1-4 wt%, but the wear resistance and the gloss performance are not reported.
Disclosure of Invention
In order to solve the problems, the invention provides a bright glaze for ceramic archaized bricks and a preparation method thereof, and the specific technical scheme is as follows:
the glaze for the ceramic archaized brick is prepared by ball milling of glaze and additives, and comprises the following raw materials in percentage by weight: 37-84% of zirconium white frit, 9-56% of transparent frit and 5-7% of clay, wherein the additives are sodium tripolyphosphate and sodium polymethyl cellulose, and the addition amounts of the additives are 0.2-0.4% and 0.3-0.6% of the weight of the glaze respectively.
Preferably, the glaze comprises the following components in percentage by weight: 60% of zirconium white frit, 34% of transparent frit and 6% of clay, wherein the addition amounts of the sodium tripolyphosphate and the sodium polymethylcellulose are respectively 0.3% and 0.5% of the weight of the glaze.
A preparation method of a bright glaze for ceramic archaized bricks comprises the following steps:
(1) ball-milling the zirconium white frit, the transparent frit and the clay to a certain particle size;
(2) putting the ball-milled raw materials into a ball mill in proportion, and carrying out ball milling and mixing for 60-120 min by a wet method to obtain a mixture;
(3) drying the mixture for 24-48 h at 90 ℃ by using a drying oven to prepare dry glaze powder;
(4) the glaze dry powder, the additive, the ball mill and water are ball milled for 20-24 hours in a ball milling tank according to a certain proportion to prepare slurry;
(5) applying the slurry on the surface of an antique brick blank, and naturally drying for 12-24 hours at room temperature to obtain a sample;
(6) and (3) firing the sample at 1050-1150 ℃ to form the bright glaze on the surface of the archaized green brick body.
Further, the zirconium white frit comprises the following chemical components in percentage by weight: SiO 2251～58％、Al2O36～7％、Fe2O30.01～1％、TiO20.01～1％、CaO 6～9％、MgO 2～4％、K2O 3～5％、 Na2O0.01～1％、ZrO23～5％、ZnO 12～14％、BaO 0.01～1％。
Further, the transparent frit comprises the following chemical components in percentage by weight: SiO 2262～65％、Al2O38～12％、Fe2O30.01～1％、CaO 12～14％、MgO 1～2％、K2O 2～3％、Na2O 0.01～1％、 ZrO20.01～1％、ZnO 6～7％、BaO 0.01～1％。
Further, theThe clay comprises the following chemical components in percentage by weight: SiO 2260～66％、Al2O332～36％、Fe2O30.01～1％、TiO20.01～1％、CaO 0.01～1％、K2O 0.01～1％。
Further, the average particle sizes of the zirconium white clinker, the transparent clinker and the clay are 375 meshes, 325 meshes and 250 meshes respectively.
Further, the additives are sodium tripolyphosphate and sodium polymethylcellulose, and the addition amounts of the additives are 0.2-0.4% and 0.3-0.6% of the weight of the glaze respectively.
Further, the proportion of the step (4) is as follows: (dry powder and additives): ball grinding: the mass ratio of the water is 1:2: 0.6-0.7.
Further, the temperature system of the sintering is as follows: when the temperature is less than 1000 ℃, the heating rate is 5 ℃/min, the heat is preserved for 30min every 100 ℃, when the temperature is more than or equal to 1000 ℃, the heating rate is 3 ℃/min, the heat is preserved for 60min every 100 ℃, and the heat is preserved for 15-30 min at the highest temperature.
Has the advantages that:
the invention develops the bright glaze which can be applied to the green body of the antique brick, fills the blank of the domestic bright glaze for the antique brick, does not contain harmful heavy metal elements such as lead, cadmium and the like in the chemical composition of the raw materials, and has the advantages of flat, smooth and fine glaze surface, high microhardness, higher glossiness, environmental protection, no pollution, good wear resistance and decorative performance and obvious bright effect of the antique brick.
Detailed Description
The invention is further described below with reference to specific examples:
the glaze for the ceramic archaized brick is prepared by ball milling of glaze and additives, and comprises the following raw materials in percentage by weight: 37-84% of zirconium white frit, 9-56% of transparent frit and 5-7% of clay, wherein the additives are sodium tripolyphosphate and sodium polymethyl cellulose, and the addition amounts of the additives are 0.2-0.4% and 0.3-0.6% of the weight of the glaze respectively.
Preferably, the glaze comprises the following components in percentage by weight: 60% of zirconium white frit, 34% of transparent frit and 6% of clay, wherein the addition amounts of the sodium tripolyphosphate and the sodium polymethylcellulose are respectively 0.3% and 0.5% of the weight of the glaze.
Example 1:
a preparation method of a bright glaze for ceramic archaized bricks is characterized in that the bright glaze is prepared by ball milling of glaze and additives, 37% of zirconium white frit, 56% of transparent frit and 7% of clay are weighed according to weight percentage, wherein the zirconium white frit comprises the following chemical components in percentage by weight: SiO 2258％，Al2O36％，Fe2O30.01％， TiO20.01％，CaO 6％，MgO4％，K2O 5％，Na2O 1％，ZrO25%, ZnO 14%, BaO 0.98%; the transparent frit comprises the following chemical components in percentage by weight: SiO 2265％，Al2O310％， Fe2O31％，CaO 14％，MgO 1％，K2O 2％，Na2O0.01％，ZrO20.01 percent, ZnO6 percent and BaO 0.98 percent; the clay comprises the following chemical components in percentage by weight: SiO 2260％，Al2O336％，Fe2O31％，TiO21％，CaO 1％，K2O 1％。
The preparation method comprises the following steps:
(1) preparing raw materials: respectively ball-milling the zirconium white frit, the transparent frit and the clay into powder for later use; the average grain sizes of the zirconium white frits, the transparent frits and the clay after ball milling are 375 meshes, 325 meshes and 250 meshes respectively.
(2) Mixing materials: weighing the zirconium white frit, the transparent frit and the clay according to the weight percentage, and putting the mixture into a ball mill for wet ball milling and mixing for 120min to prepare a mixture.
(3) And (3) drying: and drying the mixed slurry for 48 hours at 90 ℃ by using a drying oven to obtain the dry glaze powder.
(4) Grinding and pulping: the glaze dry powder, the additive, the ball mill and water are ball-milled in a ball milling tank for 24 hours according to a certain proportion to prepare slurry; wherein, the proportion of the materials is (dry powder and additive): ball grinding: the mass ratio of water is 1:2: 0.6; the additives are sodium tripolyphosphate (STTP) and sodium polymethylcellulose (CMC), and the addition amounts of the additives are 0.2 percent and 0.3 percent of the weight of the glaze respectively.
(5) Glazing: applying the slurry on the surface of an antique brick blank, and naturally drying for 12 hours at room temperature to obtain a sample;
(6) and (3) firing: and (3) firing the sample at 1050 ℃ to form a bright glaze on the surface of the archaized brick green body, thus obtaining the bright glaze decorated archaized brick product.
The firing temperature system is that when the temperature is less than 1000 ℃, the heating rate is 5 ℃/min, the heat is preserved for 30min every 100 ℃, when the temperature is more than or equal to 1000 ℃, the heating rate is 3 ℃/min, the heat is preserved for 60min every 100 ℃, and the heat is preserved for 30min at the highest temperature, so that the archaized brick with the bright glaze is obtained.
Tests prove that the glaze for the antique brick prepared by the embodiment is flat, smooth and fine, has high microhardness of 673.03HV and high glossiness of 80 degrees, and has good glaze decoration effect.
Example 2:
a preparation method of a bright glaze for ceramic archaized bricks is characterized in that the bright glaze is prepared by ball milling of glaze and additives, 84% of zirconium white frit, 9% of transparent frit and 7% of clay are weighed according to weight percentage, wherein the zirconium white frit comprises the following chemical components in percentage by weight: SiO 2252％，Al2O37％，Fe2O31％，TiO21％，CaO 9％，MgO 4％，K2O5％，Na2O 1％，ZrO25%, ZnO 14%, BaO 1%; the transparent frit comprises the following chemical components in percentage by weight: SiO 2262％，Al2O312％，Fe2O31％， CaO 12％，MgO 2％，K2O 2％，Na2O 1％，ZrO21%, ZnO 6% and BaO 1%; the clay comprises the following chemical components in percentage by weight: SiO 2266％，Al2O332％，Fe2O30.01％，TiO20.01％，CaO 0.99％，K2O 0.99％。
The preparation method comprises the following steps:
(1) preparing raw materials: respectively ball-milling the zirconium white frit, the transparent frit and the clay into powder for later use; the average grain sizes of the zirconium white frits, the transparent frits and the clay after ball milling are 375 meshes, 325 meshes and 250 meshes respectively.
(2) Mixing materials: weighing the zirconium white frit, the transparent frit and the clay according to the weight percentage, and putting the mixture into a ball mill for wet ball milling and mixing for 60min to prepare a mixture.
(3) And (3) drying: and drying the mixed slurry for 24 hours at 90 ℃ by using a drying oven to obtain the dry glaze powder.
(4) Grinding and pulping: the glaze dry powder, the additive, the ball mill and water are ball milled for 20 hours in a ball milling tank according to a certain proportion to prepare slurry; wherein, the proportion of the materials is (dry powder and additive): ball grinding: the mass ratio of water is 1:2: 0.7; the additives are sodium tripolyphosphate (STTP) and sodium polymethylcellulose (CMC), and the addition amounts of the additives are 0.4 percent and 0.6 percent of the weight of the glaze respectively.
(5) Glazing: applying the slurry on the surface of an antique brick blank, and naturally drying for 24 hours at room temperature to obtain a sample;
(6) and (3) firing: and (3) firing the sample at 1150 ℃ to form the bright glaze on the surface of the archaized brick green body, thus obtaining the bright glaze decorated archaized brick product.
The firing temperature system is that when the temperature is less than 1000 ℃, the heating rate is 5 ℃/min, the heat is preserved for 30min every 100 ℃, when the temperature is more than or equal to 1000 ℃, the heating rate is 3 ℃/min, the heat is preserved for 60min every 100 ℃, and the highest temperature is preserved for 15min, so that the archaized brick with the bright glaze is obtained.
Tests prove that the glaze for the antique brick prepared by the embodiment is flat, smooth and fine, has high microhardness of 741.90HV and high glossiness of 90 degrees, and has good glaze decoration effect.
Example 3:
a preparation method of a bright glaze for ceramic archaized bricks is characterized in that the bright glaze is prepared by ball milling of glaze and additives, 60% of zirconium white frit, 34% of transparent frit and 6% of clay are weighed according to weight percentage, wherein the zirconium white frit is prepared by mixing zirconium white frit, transparent frit and clayThe frit comprises the following chemical components in percentage by weight: SiO 2254.5％，Al2O36.5％，Fe2O30.5％， TiO20.5％，CaO 7％，MgO 5％，K2O 6％，Na2O 0.5％，ZrO25%, ZnO 14%, BaO 0.5%; the transparent frit comprises the following chemical components in percentage by weight: SiO 2263.5％，Al2O310％， Fe2O30.5％，CaO 14％，MgO 1.5％，K2O2.5％，Na2O 0.5％，ZrO20.5 percent, ZnO 6.5 percent and BaO 0.5 percent; the clay comprises the following chemical components in percentage by weight: SiO 2263％，Al2O335％，Fe2O30.5％，TiO20.5％，CaO 0.5％，K2O 0.5％。
The preparation method comprises the following steps:
(1) preparing raw materials: respectively ball-milling the zirconium white frit, the transparent frit and the clay into powder for later use; the average grain sizes of the zirconium white frits, the transparent frits and the clay after ball milling are 375 meshes, 325 meshes and 250 meshes respectively.
(2) Mixing materials: weighing the zirconium white frit, the transparent frit and the clay according to the weight percentage, and putting the mixture into a ball mill for ball milling and mixing for 90min by a wet method to prepare a mixture.
(3) And (3) drying: and drying the mixed slurry for 36 hours at 90 ℃ by using a drying oven to obtain the dry glaze powder.
(4) Grinding and pulping: the glaze dry powder, the additive, the ball mill and water are ball-milled in a ball milling tank for 24 hours according to a certain proportion to prepare slurry; wherein, the proportion of the materials is (dry powder and additive): ball grinding: the mass ratio of water is 1:2: 0.6; the additives are sodium tripolyphosphate (STTP) and sodium polymethylcellulose (CMC), and the addition amounts of the additives are 0.3 percent and 0.5 percent of the weight of the glaze respectively.
(5) Glazing: applying the slurry on the surface of an antique brick blank, and naturally drying for 18 hours at room temperature to obtain a sample;
(6) and (3) firing: and (3) firing the sample at 1100 ℃ to form the bright glaze on the surface of the archaized brick green body, thus obtaining the bright glaze decorated archaized brick product.
The firing temperature system is that when the temperature is less than 1000 ℃, the heating rate is 5 ℃/min, the heat is preserved for 30min every 100 ℃, when the temperature is more than or equal to 1000 ℃, the heating rate is 3 ℃/min, the heat is preserved for 60min every 100 ℃, and the highest temperature is preserved for 20min, so that the archaized brick with the bright glaze is obtained.
Tests prove that the glaze for the antique brick prepared by the embodiment is flat, smooth and fine, has high microhardness of 713.60HV and high glossiness of 86 degrees, and has good glaze decoration effect.
In conclusion, after various different proportions are repeatedly implemented, the microhardness of the prepared bright glaze for the antique brick is 673.03-741.90 HV, the glossiness is 80-90 degrees, and the glaze decoration effect is good.
Claims (10)
1. The glaze for the ceramic archaized brick is prepared by ball milling of glaze and additives, and is characterized by comprising the following raw materials in percentage by weight: 37-84% of zirconium white frit, 9-56% of transparent frit and 5-7% of clay, wherein the additives are sodium tripolyphosphate and sodium polymethyl cellulose, and the addition amounts of the additives are 0.2-0.4% and 0.3-0.6% of the weight of the glaze respectively.
2. The glaze for the ceramic archaized brick according to claim 1, wherein the glaze comprises the following components in percentage by weight: 60% of zirconium white frit, 34% of transparent frit and 6% of clay, wherein the addition amounts of the sodium tripolyphosphate and the sodium polymethylcellulose are respectively 0.3% and 0.5% of the weight of the glaze.
3. A preparation method of a bright glaze for ceramic archaized bricks is characterized by comprising the following steps:
(1) ball milling the zirconium white frit, the transparent frit, and the clay of claim 1 to a predetermined particle size;
(2) putting the ball-milled raw materials into a ball mill according to the proportion of claim 1 or 2, and carrying out ball milling and mixing for 60-120 min by a wet method to obtain a mixture;
(3) drying the mixture for 24-48 h at 90 ℃ by using a drying oven to prepare dry glaze powder;
(4) performing ball milling on the glaze dry powder, the additive, the ball mill and water in a ball milling tank according to a certain proportion for 20-24 hours to prepare slurry;
(5) applying the slurry on the surface of an antique brick blank, and naturally drying for 12-24 hours at room temperature to obtain a sample;
(6) and (3) firing the sample at 1050-1150 ℃ to form the bright glaze on the surface of the archaized green brick body.
4. The method for preparing a glaze for ceramic archaized bricks according to claim 3, wherein the zirconium white frit comprises the following chemical components in percentage by weight: SiO 2251～58％、Al2O36～7％、Fe2O30.01～1％、TiO20.01～1％、CaO 6～9％、MgO 2～4％、K2O 3～5％、Na2O 0.01～1％、ZrO23～5％、ZnO 12～14％、BaO 0.01～1％。
5. The method for preparing a glaze for ceramic archaized bricks according to claim 3, wherein the transparent frit comprises the following chemical components in percentage by weight: SiO 2262～65％、Al2O38～12％、Fe2O30.01～1％、CaO 12～14％、MgO 1～2％、K2O 2～3％、Na2O 0.01～1％、ZrO20.01～1％、ZnO 6～7％、BaO 0.01～1％。
6. The method for preparing the glaze for the ceramic archaized brick according to claim 3, wherein the clay comprises the following chemical components in percentage by weight: SiO 2260～66％、Al2O332～36％、Fe2O30.01～1％、TiO20.01～1％、CaO 0.01～1％、K2O 0.01～1％。
7. The method for preparing a glaze according to claim 3, wherein the zirconia white frit, the transparent frit and the clay in step (1) have average particle sizes of 375 meshes, 325 meshes and 250 meshes after ball milling.
8. The method for preparing the glaze of claim 3, wherein the additives are sodium tripolyphosphate and sodium methylcellulose, and the addition amounts of the additives are 0.2-0.4% and 0.3-0.6% of the weight of the glaze respectively.
9. The method for preparing the glaze for the ceramic archaized brick according to claim 8, wherein the ratio of the step (4) is as follows: (dry powder and additives): ball grinding: the mass ratio of the water is 1:2: 0.6-0.7.
10. The method for preparing the glaze for the ceramic archaized brick according to claim 6, wherein the firing temperature system is as follows: when the temperature is less than 1000 ℃, the heating rate is 5 ℃/min, the heat is preserved for 30min every 100 ℃, when the temperature is more than or equal to 1000 ℃, the heating rate is 3 ℃/min, the heat is preserved for 60min every 100 ℃, and the heat is preserved for 15-30 min at the highest temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010158003.3A CN111362577A (en) | 2020-03-09 | 2020-03-09 | Bright glaze for ceramic archaized bricks and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010158003.3A CN111362577A (en) | 2020-03-09 | 2020-03-09 | Bright glaze for ceramic archaized bricks and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111362577A true CN111362577A (en) | 2020-07-03 |
Family
ID=71202361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010158003.3A Pending CN111362577A (en) | 2020-03-09 | 2020-03-09 | Bright glaze for ceramic archaized bricks and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111362577A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112142327A (en) * | 2020-09-30 | 2020-12-29 | 景德镇欧神诺陶瓷有限公司 | Glaze composition, glaze and preparation method thereof, and ceramic tile and preparation method thereof |
| CN113264680A (en) * | 2021-07-20 | 2021-08-17 | 佛山市东鹏陶瓷有限公司 | Dry particle suspension glaze, preparation method and application in preparation of high-transparency ceramic tile |
| CN113979722A (en) * | 2021-11-25 | 2022-01-28 | 东莞市唯美陶瓷工业园有限公司 | Ceramic blank and ceramic curved rock plate |
| CN115259666A (en) * | 2022-07-29 | 2022-11-01 | 新明珠集团股份有限公司 | Dry granular glaze, ceramic tile with starlight effect and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731169A (en) * | 2012-07-13 | 2012-10-17 | 佛山市科捷制釉有限公司 | Fully glazed ceramic chip and preparation method thereof |
| CN102863259A (en) * | 2012-10-11 | 2013-01-09 | 江苏省宜兴彩陶工艺厂 | Low-temperature-glaze ceramic manufacturing method |
| CN104446344A (en) * | 2014-11-01 | 2015-03-25 | 景德镇景浮宫陶瓷文化有限公司 | Preparation method of slim mirror-plane artistic porcelain painting and product prepared by preparation method |
| CN106365452A (en) * | 2016-08-31 | 2017-02-01 | 醴陵市恒辉瓷厂 | Light gulch-gold glaze and preparing method thereof |
| CN106966598A (en) * | 2017-04-15 | 2017-07-21 | 景德镇陶瓷大学 | A kind of low temperature high-hardness, wearable throws glaze and preparation method thereof entirely |
| CN109761583A (en) * | 2019-03-29 | 2019-05-17 | 重庆唯美陶瓷有限公司 | Black ink-jet throws glaze Ceramic Tiles and preparation method thereof entirely |
| CN110372415A (en) * | 2019-08-09 | 2019-10-25 | 东莞市唯美陶瓷工业园有限公司 | A kind of light glaze Ceramic Tiles and preparation method thereof |
-
2020
- 2020-03-09 CN CN202010158003.3A patent/CN111362577A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731169A (en) * | 2012-07-13 | 2012-10-17 | 佛山市科捷制釉有限公司 | Fully glazed ceramic chip and preparation method thereof |
| CN102863259A (en) * | 2012-10-11 | 2013-01-09 | 江苏省宜兴彩陶工艺厂 | Low-temperature-glaze ceramic manufacturing method |
| CN104446344A (en) * | 2014-11-01 | 2015-03-25 | 景德镇景浮宫陶瓷文化有限公司 | Preparation method of slim mirror-plane artistic porcelain painting and product prepared by preparation method |
| CN106365452A (en) * | 2016-08-31 | 2017-02-01 | 醴陵市恒辉瓷厂 | Light gulch-gold glaze and preparing method thereof |
| CN106966598A (en) * | 2017-04-15 | 2017-07-21 | 景德镇陶瓷大学 | A kind of low temperature high-hardness, wearable throws glaze and preparation method thereof entirely |
| CN109761583A (en) * | 2019-03-29 | 2019-05-17 | 重庆唯美陶瓷有限公司 | Black ink-jet throws glaze Ceramic Tiles and preparation method thereof entirely |
| CN110372415A (en) * | 2019-08-09 | 2019-10-25 | 东莞市唯美陶瓷工业园有限公司 | A kind of light glaze Ceramic Tiles and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 中国硅酸盐学会陶瓷分会建筑卫生陶瓷专业委员会: "《现代建筑卫生陶瓷工程师手册》", 31 August 1998, 中国建材工业出版社 * |
| 池至铣: "《陶瓷釉色料及装饰》", 30 November 2015, 中国建材工业出版社 * |
| 章秦娟: "《陶瓷工艺学》", 31 January 2005, 武汉理工大学出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112142327A (en) * | 2020-09-30 | 2020-12-29 | 景德镇欧神诺陶瓷有限公司 | Glaze composition, glaze and preparation method thereof, and ceramic tile and preparation method thereof |
| CN112142327B (en) * | 2020-09-30 | 2022-05-27 | 景德镇欧神诺陶瓷有限公司 | Glaze composition, glaze and preparation method thereof, and ceramic tile and preparation method thereof |
| CN113264680A (en) * | 2021-07-20 | 2021-08-17 | 佛山市东鹏陶瓷有限公司 | Dry particle suspension glaze, preparation method and application in preparation of high-transparency ceramic tile |
| CN113979722A (en) * | 2021-11-25 | 2022-01-28 | 东莞市唯美陶瓷工业园有限公司 | Ceramic blank and ceramic curved rock plate |
| CN115259666A (en) * | 2022-07-29 | 2022-11-01 | 新明珠集团股份有限公司 | Dry granular glaze, ceramic tile with starlight effect and preparation method thereof |
| CN115259666B (en) * | 2022-07-29 | 2024-03-29 | 新明珠集团股份有限公司 | Dry grain glaze, ceramic tile with starlight effect and preparation method of ceramic tile |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN115010465B (en) | Low-temperature quick-firing ceramic rock plate and preparation method thereof | |
| CN111362577A (en) | Bright glaze for ceramic archaized bricks and preparation method thereof | |
| CN112209618B (en) | Velvet ceramic rock plate and preparation method thereof | |
| CN111233520B (en) | Starry sky blue transmutation glaze, preparation method thereof and sanitary ceramic using glaze | |
| CN105330158A (en) | Glaze of brunet ceramic and preparation method of glaze | |
| CN108484114B (en) | Glazed ceramic tile with high-content polishing waste and preparation method thereof | |
| CN103693994A (en) | Color-changing glaze tile and production method thereof | |
| CN103693992A (en) | Color-changing glaze ceramic and production method thereof | |
| CN112142328B (en) | Manufacturing method of ceramic chip with fine die texture | |
| CN106977097B (en) | Raw glaze for transparent high-gloss medium-temperature hard porcelain and preparation method thereof | |
| CN106278387B (en) | There is the glazed tile and preparation method thereof of gold decorative effect on surface | |
| CN111377611A (en) | Ru porcelain agate glaze material, manufacturing method and application in Ru porcelain | |
| CN109384389A (en) | A kind of manufacturing method of Antique Imitation Tiles clear frit | |
| CN106430977A (en) | Light greenish blue matte glaze for pottery product and preparation method of light greenish blue matte glaze | |
| CN113860742B (en) | Simulated marble glaze, simulated marble slab and preparation method | |
| CN110183251A (en) | A kind of mat glaze Ceramic Tiles and preparation method thereof | |
| CN104891808A (en) | Brown crystal glaze composition | |
| CN109231837A (en) | A kind of surface enameling method of Ceramic Tiles and its Ceramic Tiles of preparation | |
| CN101050059B (en) | Covering layer without lead, cadmium of pigment without lead on ceramic glaze, and preparation method | |
| CN106219976A (en) | A kind of combined decoration metallic Ceramic Tiles and manufacture method thereof | |
| CN103693991A (en) | Color-changing glaze and preparation method thereof | |
| CN114853346A (en) | Wear-resistant antifouling protective glaze, matt ceramic tile and preparation method thereof | |
| CN106747296A (en) | A kind of utilization rare earth tailings prepares the super flat method for throwing glaze Ceramic Tiles | |
| CN105541112A (en) | A super-flat glaze frit and a method of manufacturing super spar from the same | |
| CN106746671A (en) | A kind of preparation method of bright glaze sanitary ceramics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200703 |