CN104891808A - Brown crystal glaze composition - Google Patents
Brown crystal glaze composition Download PDFInfo
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- CN104891808A CN104891808A CN201510240583.XA CN201510240583A CN104891808A CN 104891808 A CN104891808 A CN 104891808A CN 201510240583 A CN201510240583 A CN 201510240583A CN 104891808 A CN104891808 A CN 104891808A
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Abstract
The invention relates to a brown crystal glaze composition. The brown crystal glaze composition comprises, by mass, 5 to 15% of cryolite, 15 to 25% of aluminium phosphate, 5 to 15% of calcined kaolin, 10 to 30% of quartz, 4 to 15% of ferrous tungstate, 1 to 15% of sodium tungstate, 5 to 25% of tungsten trioxide, 2 to 15% of manganese oxide, and 5 to 10% of copper oxide. Crystal pattern of the brown crystal glaze composition shapes like ice crystal; distribution is uniform; stereoscopic impression is strong; decorative effect is excellent; and firing period is short.
Description
Technical field
The present invention relates to a kind of coffee-like crystalline glaze composition, belong to construction sanitary ceramic decoration technique field.
Background technology
Crystalline glaze refers in glaze and occurs obvious thick macrocrystalline glaze.It is a kind of ornamental very strong artistic glaze, comes from the coloured glaze of Ancient Times in China.The basic feature that crystalline glaze is different from common glaze is visible xln containing some amount in glaze (crystalline substance namely in our glaze paint that can see or in glaze is colored).
The crystalline substance of crystalline glaze is spent changeable, the amount doesn't matter, and large is visible to the naked eye, and little need differentiate with microscope.Crystalline glaze porcelain, also by artificial method, carrys out the distribution of conservative control crystalline substance flower.Shape has star, needle-like or floral leaf shape etc.As a kind of advanced ceramic artistic glaze, the naturally brilliant flower that crystalline glaze is beautiful, novel, and varied, the color of outward appearance is in riotous profusion, gives strong artistic effect, is deeply subject to the welcome of users at home and abroad.
Crystalline glaze due to its tone pure, very popular.The crystallization soaking time of tradition crystalline glaze needs 4 ~ 6 hours usually, and high cost limits its application in building ceramics.Current ceramic tile industry generally adopts low temperature fast firing technique, but because the firing period of low temperature fast firing technique is short, the crystalline glaze forming well-crystallized in glaze paint is difficult to when being thus applied to the preparation of crystalline glaze, even if crystalline glaze is made frit, be placed on brick face burnt in a heap, its firing period is also more than three hours.
Because most of crystalline glaze all needs higher firing temperature and longer soaking time, and require harsher to firing process, be suitable for the also relatively little of the ceramic wall and floor bricks crystalline glaze exploitation of low temperature fast firing.
Summary of the invention
The present invention is intended to the defect overcoming existing crystalline glaze preparation technology, the invention provides a kind of coffee-like crystalline glaze composition and application thereof.
The invention provides a kind of coffee-like crystalline glaze composition, by percentage to the quality, described coffee-like crystalline glaze composition comprises 5-15% sodium aluminum fluoride, 15-25% aluminum phosphate, 5-15% calcined kaolin, 10-30% quartz, 4-15% ferrous tungstate (preferred 5-15%), 1-15% sodium wolframate, 5-25% tungstic oxide, 2-15% manganese oxide, 5-10% cupric oxide.
Preferably, described coffee-like crystalline glaze composition comprises, and calculates by percentage to the quality, 15-30%SiO
2, 10-20%Al
2o
3, 4-8%F (in XRF total analysis report shown chemical substance fluorine), 0.1-0.5%K
2o (K a small amount of here
2o comes from the raw mineral materials such as sodium aluminum fluoride, calcined kaolin), 3-5%Na
2o, 20-35%WO
3, 6-10%P
2o
5, 8-15%MnO, 6-10%CuO, 0.5-2%Fe
2o
3.
Again, present invention also offers the pottery that a kind of surface has coffee-like crystalline glaze layer, the composition of the coffee-like crystalline glaze layer of described ceramic surface comprises: calculate by percentage to the quality, 15-30%SiO
2, 10-20%Al
2o
3, 4-8%F, 0.1-0.5%K
2o, 3-5%Na
2o, 20-35%WO
3, 6-10%P
2o
5, 8-15%MnO, 6-10%CuO, 0.5-2%Fe
2o
3.
Preferably, the thickness of described coffee-like crystalline glaze layer is 0.08 ~ 0.25mm, preferred 0.1-0.25mm.
Preferably, have in described crystalline glaze diameter be 1-1.5 centimetre crystalline substance flower.
Preferably, described crystalline substance flower is ice crystal shape.
Preferably, the base substrate chemical constitution of described pottery is SiO
265 ~ 72%, Al
2o
315 ~ 23%, Fe
2o
30.1-0.8%, TiO
20.1-0.3%, CaO 0.2-1%, MgO 0.1-0.3%, K
2o 2.0-3.0%, Na
2o 2.5-3.5%.
Preferably, described pottery also comprises ground glaze layer on base substrate of spray printing successively and/or spray ink Printing patterned layer, and coffee-like crystalline glaze layer spray is on spray ink Printing patterned layer and/or ground glaze layer, and the composition of ground glaze layer comprises: calculate according to mass percent, SiO
2content 45%-65%, Al
2o
3content 20%-35%, CaO content 0%-10%, content of MgO 0-3%, K
2o content 3%-8%, Na
2o content 2%-5%, Fe
2o
3content 0%-1%, TiO
2content 0%-0.5%, ZrO
2content 4%-12%.
Can also spray ink Printing patterned layer between the ground-coat enamel and crystalline glaze of ceramic body.Crystalline glaze layer has certain transparency, thus can see pattern in spray ink Printing patterned layer through crystalline glaze layer, thus makes the pattern of described spray ink Printing patterned layer phase brightness can be handed over to print with the pattern of Blue crystalline glaze layer, improves the aesthetic feeling of pottery.
Preferably, the thickness of ground glaze layer is 0.1 ~ 0.25mm, preferred 0.15-0.25mm.
In addition, present invention also offers the preparation method of above-mentioned pottery, comprising:
1) raw material is taken, wherein, by percentage to the quality, raw material comprises 5-15% sodium aluminum fluoride, 15-25% aluminum phosphate, 5-15% calcined kaolin, 10-30% quartz, 4-15% ferrous tungstate (preferred 5-15%), 1-15% sodium wolframate, 5-25% tungstic oxide, 2-15% manganese oxide, 5-10% cupric oxide;
2), after being mixed by raw material, solvent is added and ball milling formation glaze slip;
3) glaze slip is sprayed on ceramic body, burns till at 1000-1180 DEG C after drying.
Preferably, add water in the feed, ball milling becomes glaze slip, glaze slip fineness requirement 325 mesh screen residue 0.5%.
Preferably, the form of glaze spraying is adopted evenly to be imposed on by glaze slip on the ceramic body of ground-coat enamel and/print pattern, glaze slip proportion 1.4-1.5g/cm
3, glaze slip flow velocity 7-20s.
Preferably, ground-coat enamel pulp bales contains ground glaze layer component and water, wherein ground glaze layer component preparation slurry before, need with ball mill ball milling, sieve (as 325 mesh screen residues 0.5%), proportion is 1.4-1.5g/cm
3, flow velocity 7-20s in glaze spraying process, preferably adopts glaze spraying cabinet glaze spraying mode to execute ground-coat enamel.
Preferably, heat-up rate 10-50 DEG C/min in sintering process, is incubated 2-10 minute at 1000-1180 DEG C, preferably burns till at 1130-1150 DEG C.
Beneficial effect of the present invention:
Coffee-like crystalline glaze of the present invention, adopts glaze spraying mode, and technique is simple, and crystalline substance spends into ice crystal shape, is evenly distributed, and stereoscopic sensation is strong, and have good decorative effect, firing period is short.
Accompanying drawing explanation
Fig. 1 shows the coffee-like crystalline glaze prepared in one embodiment of the invention.
Embodiment
Further illustrate the present invention below in conjunction with accompanying drawing and following embodiment, should be understood that accompanying drawing and following embodiment are only for illustration of the present invention, and unrestricted the present invention.
The present invention relates to a kind of coffee-like crystalline glaze composition and application thereof, belong to construction sanitary ceramic decoration technique field.This crystalline glaze presents a kind of coffee-like color, and formation special ice is crystalline or the crystalline glaze of particular pattern, has good decorative effect.
The present invention is by the special solubility promoter of employing and crystallizing agent, and the raw material sodium aluminum fluoride that the present invention introduces and aluminum phosphate have fluxing action, WO
3crystal can be impelled to generate fast, thus realize low temperature fast firing, provide a kind of coffee-like crystalline glaze and preparation technology thereof, this crystalline glaze is applicable to low temperature fast firing technique, firing temperature 1130 ~ 1150 DEG C, and whole firing period is 60min.
Described coffee-like crystalline glaze composition adopts following Material Percentage to prepare: sodium aluminum fluoride 5-15%, aluminum phosphate 15 ~ 25%, calcined kaolin 5-15%, quartz 10 ~ 30%, ferrous tungstate 5 ~ 15%, sodium wolframate 1 ~ 15%, tungstic oxide 5 ~ 25%, manganese oxide 2-15%, cupric oxide 5 ~ 10%.
Calculate according to mass percent, comprise SiO
2content 15 ~ 30%, Al
2o
3content 10 ~ 20%, F content 4 ~ 8%, K
2o content 0.1 ~ 0.5%, Na
2o content 3 ~ 5%, WO
3content 20 ~ 35%, P
2o
5content 6 ~ 10%, MnO content 8 ~ 15%, CuO content 6 ~ 10%, Fe
2o
3content 0.5 ~ 2%.
Adopt described coffee-like crystalline glaze composition can form coffee-like crystalline glaze layer at ceramic surface.
The thickness of described coffee-like crystalline glaze layer can be 0.08 ~ 0.25mm, preferably 0.08 ~ 0.20mm.
Have in described crystalline glaze diameter be 1-1.5 centimetre crystalline substance flower.
Described crystalline substance flower is ice crystal shape.
The base substrate chemical constitution of described pottery is SiO
265 ~ 72%, Al
2o
315 ~ 23%, Fe
2o
30.1-0.8%, TiO
20.1-0.3%, CaO 0.2-1%, MgO 0.1-0.3%, K
2o 2.0-3.0%, Na
2o 2.5-3.5%.
Described pottery also comprises ground glaze layer on base substrate of spray printing successively and/or spray ink Printing patterned layer, and coffee-like crystalline glaze layer spray printing is on spray ink Printing patterned layer and/or ground glaze layer, and the composition of ground glaze layer comprises: calculate according to mass percent, SiO
2content 45%-65%, Al
2o
3content 20%-35%, CaO content 0%-10%, content of MgO 0-3%, K
2o content 3%-8%, Na
2o content 2%-5%, Fe
2o
3content 0%-1%, TiO
2content 0%-0.5%, ZrO
2content 4%-12%.
Can also spray ink Printing patterned layer between the ground-coat enamel and crystalline glaze of ceramic body.Crystalline glaze layer has certain transparency, thus can see pattern in spray ink Printing patterned layer through crystalline glaze layer, thus makes the pattern of described spray ink Printing patterned layer phase brightness can be handed over to print with the pattern of Blue crystalline glaze layer, improves the aesthetic feeling of pottery.
The thickness of ground glaze layer is 0.1 ~ 0.25mm.
Present invention also offers the preparation technology that a kind of surface has the pottery of coffee-like crystalline glaze layer, comprise the following steps:
Step one: crystalline glaze raw material is mixed in proportion;
Step 2: add water in compound, ball milling becomes glaze slip, glaze slip fineness requirement 325 mesh screen residue 0.5%;
Step 3: adopt the form of glaze spraying evenly to be granted on the ceramic body of ground-coat enamel by crystalline glaze, glaze slip proportion 1.4 ~ 1.5g/cm
3, glaze slip flow velocity 7 ~ 20s;
Step 4: glaze firing.Heat-up rate 10 ~ 50 DEG C/min in sintering process, is incubated 2 ~ 10min at 1000-1180 DEG C.
Ground-coat enamel pulp bales contains ground glaze layer component and stamp-pad ink, wherein ground glaze layer component preparation slurry before, need with ball mill ball milling, sieve (as 325 mesh screen residues 0.5%), proportion is 1.4-1.5g/cm
3, flow velocity 7-20s in spray process, preferably adopts glaze spraying cabinet glaze spraying mode to execute ground-coat enamel.
Beneficial effect of the present invention:
Coffee-like crystalline glaze of the present invention, adopts glaze spraying mode, and technique is simple, and crystalline substance spends into ice crystal shape, is evenly distributed, and stereoscopic sensation is strong, and have good decorative effect, firing period is short.
Exemplify embodiment below further to describe the present invention in detail.Should understand equally; following examples are only used to further illustrate the present invention; can not be interpreted as limiting the scope of the invention, some nonessential improvement that those skilled in the art's foregoing according to the present invention is made and adjustment all belong to protection scope of the present invention.The processing parameter etc. that following example is concrete is also only an example in OK range, and namely those skilled in the art can be done in suitable scope by explanation herein and select, and do not really want the concrete numerical value being defined in Examples below.
Embodiment 1
Step one: crystalline glaze raw material is mixed in proportion, wherein, crystalline glaze raw material is by following mass percent preparation: sodium aluminum fluoride 11 parts, aluminum phosphate 15 parts, calcined kaolin 10 parts, quartz sand 16 parts, manganese oxide 10 parts, cupric oxide 8.5 parts, tungstic oxide 20 parts, sodium wolframate 5 parts, ferrous tungstate 4.5 parts;
Step 2: add water in compound, ball milling becomes glaze slip, glaze slip fineness requirement 325 mesh screen residue 0.5%;
Step 3: adopt the form of glaze spraying evenly to be granted on the ceramic body of ground-coat enamel by crystalline glaze, glaze slip proportion 1.4 ~ 1.5g/cm
3, glaze slip flow velocity 7 ~ 20s;
Step 4: glaze firing.After body drying, adopt roller kiln to burn till fast, in sintering process, heat-up rate 40 DEG C/min, is incubated 6min at 1150 DEG C, firing period 60 minutes;
Prepared crystalline glaze chemical constitution per-cent is: SiO
2content 21.14%, Al
2o
3content 12.09%, F content 5.83%, K
2o content 0.42%, Na
2o content 4.20%, WO
3content 26.86%, P
2o
5content 8.73%, MnO content 9.90%, CuO content 8.42%, Fe
2o
3content 1.07%;
Fig. 1 shows the pottery with coffee-like crystalline glaze prepared by the embodiment of the present invention.This pottery crystalline substance flower is evenly distributed, suitable size, about 1.2 centimetres of brilliant flower diameter, glazed thickness 0.08 ~ 0.2mm.
Claims (2)
1. a coffee-like crystalline glaze composition, it is characterized in that, by percentage to the quality, described coffee-like crystalline glaze composition comprises 5-15% sodium aluminum fluoride, 15-25% aluminum phosphate, 5-15% calcined kaolin, 10-30% quartz, 4-15% ferrous tungstate, 1-15% sodium wolframate, 5-25% tungstic oxide, 2-15% manganese oxide, 5-10% cupric oxide, preferably, ferrous tungstate 5-15%.
2. coffee-like crystalline glaze composition according to claim 1, is characterized in that, described coffee-like crystalline glaze composition comprises, and calculates by percentage to the quality, 15-30%SiO
2, 10-20% Al
2o
3, 4-8% F, 0.1-0.5% K
2o, 3-5% Na
2o, 20-35% WO
3, 6-10% P
2o
5, 8-15% MnO, 6-10% CuO, 0.5-2% Fe
2o
3.
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|---|---|---|---|
| CN201510240583.XA CN104891808B (en) | 2015-05-12 | 2015-05-12 | A kind of coffee-like crystallization enamel composition |
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|---|---|---|---|
| CN201510240583.XA CN104891808B (en) | 2015-05-12 | 2015-05-12 | A kind of coffee-like crystallization enamel composition |
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| CN104891808A true CN104891808A (en) | 2015-09-09 |
| CN104891808B CN104891808B (en) | 2017-10-27 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105712630A (en) * | 2016-03-28 | 2016-06-29 | 福建省佳美集团公司 | Furnace-transmutation crystallite rainbow color glaze and preparing method thereof |
| CN106007381A (en) * | 2016-05-24 | 2016-10-12 | 福建省佳美集团公司 | Single-layer fambe pigmented glaze and preparation method thereof |
| CN109333784A (en) * | 2018-12-11 | 2019-02-15 | 广东皓明陶瓷科技有限公司 | A kind of silking glaze and silking glaze household porcelain production technique |
| CN110835234A (en) * | 2019-11-27 | 2020-02-25 | 蒙娜丽莎集团股份有限公司 | Colored chrysanthemum-shaped crystal flower glaze, chrysanthemum-shaped crystal flower light-transmitting ceramic tile and preparation method thereof |
| CN114773089A (en) * | 2022-04-18 | 2022-07-22 | 蒙娜丽莎集团股份有限公司 | Nitrogen-doped tungsten-based ferrous crystal glaze ceramic product capable of promoting photocatalytic activity and preparation method thereof |
| CN114772932A (en) * | 2022-04-18 | 2022-07-22 | 蒙娜丽莎集团股份有限公司 | Sulfur-doped tungsten-based ferrous iron crystal glaze ceramic product with long-acting stable photocatalytic activity and preparation method thereof |
| CN114772931A (en) * | 2022-04-18 | 2022-07-22 | 蒙娜丽莎集团股份有限公司 | Tungsten-based ferrous ceramic crystal glaze with optical functional activity and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130463A (en) * | 2007-07-13 | 2008-02-27 | 邱林铿 | Production method of ceramic for generating gold crystallization dapple on glaze of ceramic and ceramic glaze used thereof |
| EP2014629A2 (en) * | 2007-06-22 | 2009-01-14 | Colorobbia Italia S.p.a. | Materials for coating ceramic bodies, preparation and use thereof and ceramic bodies including the same |
| CN102432342A (en) * | 2011-09-20 | 2012-05-02 | 江苏高淳陶瓷股份有限公司 | Preparation method of vanadium-titanium-iron system golden crystal glaze |
| CN102746029A (en) * | 2012-06-25 | 2012-10-24 | 江苏高淳陶瓷股份有限公司 | Preparation method of two-time phase-separation bright red fambe fancy glaze |
-
2015
- 2015-05-12 CN CN201510240583.XA patent/CN104891808B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2014629A2 (en) * | 2007-06-22 | 2009-01-14 | Colorobbia Italia S.p.a. | Materials for coating ceramic bodies, preparation and use thereof and ceramic bodies including the same |
| CN101130463A (en) * | 2007-07-13 | 2008-02-27 | 邱林铿 | Production method of ceramic for generating gold crystallization dapple on glaze of ceramic and ceramic glaze used thereof |
| CN102432342A (en) * | 2011-09-20 | 2012-05-02 | 江苏高淳陶瓷股份有限公司 | Preparation method of vanadium-titanium-iron system golden crystal glaze |
| CN102746029A (en) * | 2012-06-25 | 2012-10-24 | 江苏高淳陶瓷股份有限公司 | Preparation method of two-time phase-separation bright red fambe fancy glaze |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105712630A (en) * | 2016-03-28 | 2016-06-29 | 福建省佳美集团公司 | Furnace-transmutation crystallite rainbow color glaze and preparing method thereof |
| CN106007381A (en) * | 2016-05-24 | 2016-10-12 | 福建省佳美集团公司 | Single-layer fambe pigmented glaze and preparation method thereof |
| CN106007381B (en) * | 2016-05-24 | 2018-12-11 | 福建省佳美集团公司 | A kind of single layer transmutation color glaze and preparation method thereof |
| CN109333784A (en) * | 2018-12-11 | 2019-02-15 | 广东皓明陶瓷科技有限公司 | A kind of silking glaze and silking glaze household porcelain production technique |
| CN110835234A (en) * | 2019-11-27 | 2020-02-25 | 蒙娜丽莎集团股份有限公司 | Colored chrysanthemum-shaped crystal flower glaze, chrysanthemum-shaped crystal flower light-transmitting ceramic tile and preparation method thereof |
| CN110835234B (en) * | 2019-11-27 | 2022-03-25 | 蒙娜丽莎集团股份有限公司 | Colored chrysanthemum-shaped crystal flower glaze, chrysanthemum-shaped crystal flower light-transmitting ceramic tile and preparation method thereof |
| CN114773089A (en) * | 2022-04-18 | 2022-07-22 | 蒙娜丽莎集团股份有限公司 | Nitrogen-doped tungsten-based ferrous crystal glaze ceramic product capable of promoting photocatalytic activity and preparation method thereof |
| CN114772932A (en) * | 2022-04-18 | 2022-07-22 | 蒙娜丽莎集团股份有限公司 | Sulfur-doped tungsten-based ferrous iron crystal glaze ceramic product with long-acting stable photocatalytic activity and preparation method thereof |
| CN114772931A (en) * | 2022-04-18 | 2022-07-22 | 蒙娜丽莎集团股份有限公司 | Tungsten-based ferrous ceramic crystal glaze with optical functional activity and preparation method and application thereof |
| CN114772931B (en) * | 2022-04-18 | 2023-10-20 | 蒙娜丽莎集团股份有限公司 | Tungsten-based ferrous ceramic crystal glaze with optical functional activity and preparation method and application thereof |
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