CN107311457A - Anti-skid wearable Ceramic Tiles - Google Patents
Anti-skid wearable Ceramic Tiles Download PDFInfo
- Publication number
- CN107311457A CN107311457A CN201710605622.0A CN201710605622A CN107311457A CN 107311457 A CN107311457 A CN 107311457A CN 201710605622 A CN201710605622 A CN 201710605622A CN 107311457 A CN107311457 A CN 107311457A
- Authority
- CN
- China
- Prior art keywords
- parts
- skid wearable
- ceramic tiles
- glaze
- skid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 65
- 239000002245 particle Substances 0.000 claims abstract description 80
- 239000002994 raw material Substances 0.000 claims abstract description 51
- 239000006071 cream Substances 0.000 claims abstract description 48
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 39
- 239000011734 sodium Substances 0.000 claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000758 substrate Substances 0.000 claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 23
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 23
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 23
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 23
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 23
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 23
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 26
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 24
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 23
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 23
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 23
- 210000003298 dental enamel Anatomy 0.000 claims description 19
- 239000005995 Aluminium silicate Substances 0.000 claims description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 18
- 235000012211 aluminium silicate Nutrition 0.000 claims description 18
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 12
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 239000010453 quartz Substances 0.000 claims description 11
- 229910052664 nepheline Inorganic materials 0.000 claims description 9
- 239000010434 nepheline Substances 0.000 claims description 9
- 239000010456 wollastonite Substances 0.000 claims description 9
- 229910052882 wollastonite Inorganic materials 0.000 claims description 9
- 239000011787 zinc oxide Substances 0.000 claims description 9
- 238000005034 decoration Methods 0.000 claims description 6
- 238000007639 printing Methods 0.000 claims description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 4
- 238000010020 roller printing Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 14
- 238000005299 abrasion Methods 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 17
- 235000012239 silicon dioxide Nutrition 0.000 description 11
- 239000011449 brick Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 238000011056 performance test Methods 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910021532 Calcite Inorganic materials 0.000 description 3
- 238000007641 inkjet printing Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to Ceramic Tiles field, specifically there is provided a kind of anti-skid wearable Ceramic Tiles.The anti-skid wearable Ceramic Tiles include green body layer and the main anti-skid wearable layer formed using the charity of anti-skid wearable glaze after base substrate layer surface, and the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：0.2 0.4 parts of 90 110 parts of anti-skid wearable particle, 90 110 parts of cream of print and sodium tripolyphosphate；The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260 70 parts, Al2O320 30 parts, Fe2O30.01 1 parts, TiO20.1 2 parts, Na215 parts of O, K20.1 2 parts of 1 10 parts of O, 0.01 1 parts of MgO, 0.1 5 parts of CaO and loss on ignition.The anti-skid wearable Ceramic Tiles have excellent skidproof effect and abrasion resistant effect, and product quality is high, durable in use, safe and reliable.
Description
Technical field
The present invention relates to Ceramic Tiles field, in particular to a kind of anti-skid wearable Ceramic Tiles.
Background technology
With developing rapidly for science and technology, the life of people is maked rapid progress, and is followed the fashion, is shown while having cast one
In the epoch of individual character, architectural decoration material field is no exception.Ceramic Tiles are with its superior performance and decorative effect, by increasingly
The favor of many consumers, and be widely used in daily life.And ceramic antique bricks are in recent years popular rise
A kind of building and ornament materials come, pattern that it has had the splendid and ceramics of polished bricks concurrently is rich and varied, with the modern times or
Pseudo-classic charm, and it is personalized many advantages, such as, be received by the market and consumer like.
With the continuous improvement of people's living standards, client also can be more and more to the demand in terms of product function, have
The demand of personalized, long-lived, safe and reliable high-end ceramic brick product also can be more and more.Current ceramic product
There is case hardness and not enough scratched without wear-resisting, easy in (such as Ceramic Tiles), so as to influence the attractive in appearance of product；Surface of ceramic products
Coefficient of friction is relatively low, not anti-skidding, easily fall down, so as to influence the safe handling of product.Accordingly, it would be desirable to enter traveling one to prior art
There is provided a kind of anti-wear performance and the good Ceramic Tiles of non-skid property for the improvement of step.
In view of this, it is special to propose the present invention.
The content of the invention
It is an object of the invention to provide a kind of anti-skid wearable Ceramic Tiles, the anti-skid wearable Ceramic Tiles have excellent anti-skidding
Effect and abrasion resistant effect, product quality are high, durable in use, safe and reliable.
In order to realize the above-mentioned purpose of the present invention, spy uses following technical scheme：
Anti-skid wearable glaze charity is used in base with main the invention provides a kind of anti-skid wearable Ceramic Tiles, including green body layer
The anti-skid wearable layer formed after body layer surface, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：It is anti-skidding
0.2-0.4 parts of 90-110 parts of abrasion resistant particles, 90-110 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260-70 parts, Al2O320-30 parts,
Fe2O30.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and burning
0.1-2 parts of vector.
As further preferably technical scheme, the main raw material by following mass parts of the anti-skid wearable glaze prepare and
Into：0.22-0.38 parts of 92-108 parts of anti-skid wearable particle, 92-108 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO261-69 parts, Al2O321-29 parts,
Fe2O30.02-0.09 parts, TiO20.2-1.9 parts, Na21.5-4.5 parts of O, K22-9 parts of O, 0.1-0.9 parts of MgO, CaO 1-4
0.2-1.9 parts of part and loss on ignition.
As further preferably technical scheme, the main raw material by following mass parts of the anti-skid wearable glaze prepare and
Into：0.24-0.36 parts of 94-106 parts of anti-skid wearable particle, 94-106 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO262-68 parts, Al2O322-28 parts,
Fe2O30.04-0.08 parts, TiO20.4-1.8 parts, Na22-4 parts of O, K23-8 parts of O, 0.2-0.8 parts of MgO, 2-3 parts of CaO and
0.3-1.8 parts of loss on ignition.
As further preferably technical scheme, the print cream is mainly made up of the component of following mass parts：Carboxymethyl is fine
40-60 parts of plain 2-3 parts of the sodium of dimension, 40-60 parts of ethylene glycol and water.
As further preferably technical scheme, the grain composition of the anti-skid wearable particle is：80-120 mesh 20%-
30%, 120-180 mesh 50%-60%, remaining is below 200 mesh.
As further preferably technical scheme, the proportion of the anti-skid wearable glaze is 1.2-1.8g/cm3。
As further preferably technical scheme, the flow velocity of the anti-skid wearable glaze is 80-100 seconds.
As further preferably technical scheme, cover coat is additionally provided between the green body layer and anti-skid wearable layer
And decorative layer, the decorative layer be arranged at the cover coat and the anti-skid wearable layer between.
As further preferably technical scheme, the cover coat is mainly prepared from by cover-coat enamel, the cover-coat enamel it is main by
The raw material of following mass parts is prepared from：20-30 parts of potassium feldspar, 15-30 parts of quartz, 15-25 parts of nepheline, calcined kaolin 5-10
Part, 5-15 parts of aluminum oxide, 1-8 parts of wollastonite, 0.1-2 parts of zinc oxide, 10-30 parts of zirconium silicate, 10-20 parts of column kaolin, corruption
Grow sour sodium 0.1-0.3 parts, 0.1-0.3 parts of 0.1-0.3 parts of sodium carboxymethylcellulose and sodium tripolyphosphate.
As further preferably technical scheme, the decorative layer includes one or multi-channel lamina printing decoration, one or multi-channel
Roller printing and it is one or both of ink-jet printed more than combination.
Compared with prior art, beneficial effects of the present invention are：
The anti-skid wearable Ceramic Tiles that the present invention is provided include green body layer and mainly using anti-skid wearable glaze charity in green body layer
The anti-skid wearable layer formed behind surface, anti-skid wearable glaze is main by anti-skid wearable particle, print three kinds of raw materials of cream and sodium tripolyphosphate
Composition, by the reasonable cooperation of each raw material and anti-skid wearable particle each component, with good anti-skid wearable effect, while product
Surface also has higher transparency and relatively low glossiness.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the present invention.It is unreceipted specific in embodiment
Condition person, the condition advised according to normal condition or manufacturer is carried out.
Anti-skid wearable glaze charity is used in base with main the invention provides a kind of anti-skid wearable Ceramic Tiles, including green body layer
The anti-skid wearable layer formed after body layer surface, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：It is anti-skidding
0.2-0.4 parts of 90-110 parts of abrasion resistant particles, 90-110 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260-70 parts, Al2O320-30 parts,
Fe2O30.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and burning
0.1-2 parts of vector.
Unless otherwise indicated, the present invention in each product quality criteria all same；For example, anti-skid wearable glaze and anti-skid wearable
The quality criteria of particle is identical, is all such as 1 gram.
It should be noted that loss on ignition is the technical terms commonly used in ceramic field, it is according to the conventional understanding of this area
Can, the mass ratio before referring to the quality after raw material calcination and burning till.
In the anti-skid wearable glaze of the present invention, according to the mass fraction, the typical but non-limiting content of anti-skid wearable particle is：
90 parts, 91 parts, 92 parts, 93 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 99 parts, 100 parts, 101 parts, 102 parts, 103 parts, 104
Part, 105 parts, 106 parts, 107 parts, 108 parts, 109 parts or 110 parts；Printing the typical but non-limiting content of cream is：90 parts, 91 parts,
92 parts, 93 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 99 parts, 100 parts, 101 parts, 102 parts, 103 parts, 104 parts, 105 parts,
106 parts, 107 parts, 108 parts, 109 parts or 110 parts；The typical but non-limiting content of sodium tripolyphosphate is：0.2 part, 0.21 part,
0.22 part, 0.23 part, 0.24 part, 0.25 part, 0.26 part, 0.27 part, 0.28 part, 0.29 part, 0.3 part, 0.31 part, 0.32 part,
0.33 part, 0.34 part, 0.35 part, 0.36 part, 0.37 part, 0.38 part, 0.39 part or 0.4 part.Above-mentioned anti-skid wearable particle is main
Anti-skidding and wear-resisting effect is played, print cream primarily serves the effect of the viscosity of regulation anti-skid wearable glaze, and sodium tripolyphosphate mainly rises
To the effect of the suspended dispersed of regulation anti-skid wearable particle.
In the anti-skid wearable particle of the present invention, according to the mass fraction, SiO2Typical but non-limiting content is：60 parts,
61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 65.87 parts, 66 parts, 67 parts, 68 parts, 69 parts or 70 parts；Al2O3It is typical but non-limiting
Content be：20 parts, 21 parts, 22 parts, 22.86 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or 30 parts；Fe2O3
Typical but non-limiting content is：0.01 part, 0.08 part, 0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7
Part, 0.8 part, 0.9 part or 1 part；TiO2Typical but non-limiting content is：0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part,
0.6 part, 0.7 part, 0.8 part, 0.9 part, 0.99 part, 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts,
1.8 parts, 1.9 parts or 2 parts；Na2The typical but non-limiting contents of O are：1 part, 1.5 parts, 2 parts, 2.22 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts or 5 parts；K2The typical but non-limiting contents of O are：1 part, 2 parts, 3 parts, 4 parts, 4.11 parts, 5 parts, 6
Part, 7 parts, 8 parts, 9 parts or 10 parts；The typical but non-limiting contents of MgO are：0.01 part, 0.1 part, 0.2 part, 0.3 part, 0.4
Part, 0.43 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part or 1 part；The typical but non-limiting contents of CaO are：0.1 part,
0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 2.69 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts；Loss on ignition is typical but unrestricted
The content of property is：0.1 part, 0.2 part, 0.4 part, 0.6 part, 0.75 part, 0.8 part, 1 part, 1.2 parts, 1.4 parts, 1.6 parts, 1.8 parts or
2 parts.
Above-mentioned anti-skid wearable Ceramic Tiles include green body layer and main using anti-skid wearable glaze charity shape after base substrate layer surface
Into anti-skid wearable layer, anti-skid wearable glaze is main to be made up of anti-skid wearable particle, print three kinds of raw materials of cream and sodium tripolyphosphate, is passed through
The reasonable cooperation of each raw material and anti-skid wearable particle each component, with good anti-skid wearable effect, while product surface also has
There are higher transparency and relatively low glossiness.
Preferably, the anti-skid wearable particle in the present invention is mainly prepared from by the raw material of following mass parts：Aluminum oxide 10-
1-8 parts of 20 parts, 35-45 parts of potassium feldspar, 1-10 parts of soda ash, 35-45 parts of quartz and calcite.It is further preferred that in the present invention
Anti-skid wearable particle be mainly prepared from by the raw material of following mass parts：15 parts of aluminum oxide, 40 parts of potassium feldspar, 2 parts of soda ash, stone
5 parts of 38 parts of English and calcite.
Have that softening temperature is moderate using the anti-skid wearable particle of above-mentioned formula, being easy to sintering, transparency, high, glossiness is high
With the advantage of good antiskid effect.
In the present invention, according to the mass fraction, the typical but non-limiting content of aluminum oxide is：10 parts, 11 parts, 12 parts, 13
Part, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts；The typical but non-limiting content of potassium feldspar typical case is：35 parts,
36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts；Soda ash is typical but non-limiting to be：1
Part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts；Quartz is typical but non-limiting to be：35 parts, 36 parts, 37
Part, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts；The typical but non-limiting content of calcite be 1 part, 2
Part, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts or 8 parts.
It is preferably carried out in one kind in mode, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：
0.22-0.38 parts of 92-108 parts of anti-skid wearable particle, 92-108 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO261-69 parts, Al2O321-29 parts,
Fe2O30.02-0.09 parts, TiO20.2-1.9 parts, Na21.5-4.5 parts of O, K22-9 parts of O, 0.1-0.9 parts of MgO, CaO 1-4
0.2-1.9 parts of part and loss on ignition.
It is preferably carried out in one kind in mode, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：
0.24-0.36 parts of 94-106 parts of anti-skid wearable particle, 94-106 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO262-68 parts, Al2O322-28 parts,
Fe2O30.04-0.08 parts, TiO20.4-1.8 parts, Na22-4 parts of O, K23-8 parts of O, 0.2-0.8 parts of MgO, 2-3 parts of CaO and
0.3-1.8 parts of loss on ignition.
It is preferably carried out in one kind in mode, the print cream is mainly made up of the component of following mass parts：Carboxymethyl cellulose
40-60 parts of plain sodium 2-3 parts, 40-60 parts of ethylene glycol and water.Using the print cream of above-mentioned specific components and content be prepared from it is anti-skidding
The non-skid property and anti-wear performance of wear-resisting glaze are more preferable.
In the present invention preferably print cream, according to the mass fraction, the typical but non-limiting content of sodium carboxymethylcellulose is：
2 parts, 2.1 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts；Ethylene glycol is typical but non-
Restricted content is：40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52
Part, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts or 60 parts；The typical but non-limiting content of water is：40 parts, 41
Part, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56
Part, 57 parts, 58 parts, 59 parts or 60 parts.
It is preferably carried out in one kind in mode, the grain composition of the anti-skid wearable particle is：80-120 mesh 20%-
30%, 120-180 mesh 50%-60%, remaining is below 200 mesh.
In above-mentioned anti-skid wearable particle, the typical but non-limiting content of 80-120 purposes is：20%th, 21%, 22%,
23%th, 24%, 25%, 26%, 27%, 28%, 29% or 30%.The typical but non-limiting content of 120-180 purposes is：
50%th, 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58%, 59% or 60%.Anti-skid wearable particle is from above-mentioned
Level is less with the space that can make between particle, and charity is even closer uniform after product surface.
It is preferably carried out in one kind in mode, the proportion of the anti-skid wearable glaze is 1.2-1.8g/cm3.In the present invention, on
The proportion for stating anti-skid wearable glaze typical but non-limiting is：1.2g/cm3、1.3g/cm3、1.4g/cm3、1.5g/cm3、1.6g/
cm3、1.7g/cm3Or 1.8g/cm3.The good fluidity of the anti-skid wearable glaze of above-mentioned proportion, can pass through silk screen, and do not glue
Net, and then improve printing efficiency and anti-skid wearable performance.
It is preferably carried out in one kind in mode, the flow velocity of the anti-skid wearable glaze is 80-100 seconds.Flow velocity is typical but non-limit
Property processed is：80 seconds, 81 seconds, 82 seconds, 83 seconds, 84 seconds, 85 seconds, 86 seconds, 87 seconds, 88 seconds, 89 seconds, 90 seconds, 91 seconds, 92 seconds, 93
Second, 94 seconds, 95 seconds, 96 seconds, 97 seconds, 98 seconds, 99 seconds or 100 seconds.The good fluidity of the anti-skid wearable glaze of above-mentioned flow velocity, Neng Goushun
Profit is by silk screen, and not sticky net, and then improves printing efficiency and anti-skid wearable performance.
Be preferably carried out in one kind in mode, the green body layer and the anti-skid wearable layer between be additionally provided with cover coat and
Decorative layer, the decorative layer is arranged between the cover coat and anti-skid wearable layer.Cover coat can improve easy ceramic
The mechanical strength of brick, the water absorption rate for reducing base substrate；Decorative layer can enrich the diversity of ceramic brick surface pattern, make Ceramic Tiles more
Plus it is attractive in appearance, decorative layer and anti-skid wearable layer the two pattern texture it is interlaced, by increasing capacitance it is possible to increase changeable level and stereoeffect,
Produce some parts of pattern texture to may be seen indistinctly, seem the effect come out from brick borough chief.
Be preferably carried out in one kind in mode, the cover coat is mainly prepared from by cover-coat enamel, the cover-coat enamel it is main by with
The raw material of lower mass parts is prepared from：20-30 parts of potassium feldspar, 15-30 parts of quartz, 15-25 parts of nepheline, calcined kaolin 5-10
Part, 5-15 parts of aluminum oxide, 1-8 parts of wollastonite, 0.1-2 parts of zinc oxide, 10-30 parts of zirconium silicate, 10-20 parts of column kaolin, corruption
Grow sour sodium 0.1-0.3 parts, 0.1-0.3 parts of 0.1-0.3 parts of sodium carboxymethylcellulose and sodium tripolyphosphate.Using green body layer and above-mentioned
Cover coat enables to the whiteness of product suitable, not only ensure that inherence and the external quality of product, lifts the comprehensive of product
Can, and production cost is reduced, with good economic benefit.
In the present invention preferably cover-coat enamel, according to the mass fraction, the typical but non-limiting content of potassium feldspar is：20 parts, 21
Part, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or 30 parts；The typical but non-limiting content of quartz is：
15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or
30 parts；The typical but non-limiting content of nepheline is：15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts,
24 parts or 25 parts；The typical but non-limiting content of calcined kaolin is：5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8
Part, 8.5 parts, 9 parts, 9.5 parts or 10 parts；The typical but non-limiting content of aluminum oxide is：5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10
Part, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts；The typical but non-limiting content of wollastonite is：1 part, 2 parts, 3 parts, 4 parts, 5
Part, 6 parts, 7 parts or 8 parts；The typical but non-limiting content of zinc oxide be 0.1 part, 0.2 part, 0.4 part, 0.6 part, 0.8 part, 1
Part, 1.2 parts, 1.4 parts, 1.6 parts, 1.8 parts or 2 parts；The typical but non-limiting content of zirconium silicate is：10 parts, 11 parts, 12 parts,
13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28
Part, 29 parts or 30 parts；The typical but non-limiting content of column kaolin is：10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts,
16 parts, 17 parts, 18 parts, 19 parts or 20 parts；The typical but non-limiting content of sodium humate is：0.1 part, 0.12 part, 0.14 part,
0.18 part, 0.2 part, 0.22 part, 0.24 part, 0.26 part, 0.28 part or 0.3 part；Sodium carboxymethylcellulose is typical but non-limiting
Content be：0.1 part, 0.12 part, 0.14 part, 0.18 part, 0.2 part, 0.22 part, 0.24 part, 0.26 part, 0.28 part or 0.3 part；
The typical but non-limiting content of sodium tripolyphosphate is：0.1 part, 0.12 part, 0.14 part, 0.18 part, 0.2 part, 0.22 part, 0.24
Part, 0.26 part, 0.28 part or 0.3 part.
Preferably, the cover-coat enamel is mainly prepared from by the raw material of following mass parts：22-28 parts of potassium feldspar, quartz 18-25
Part, 18-22 parts of nepheline, 6-8 parts of calcined kaolin, 6-12 parts of aluminum oxide, 3-6 parts of wollastonite, 0.5-1.5 parts of zinc oxide, silicic acid
15-25 parts of zirconium, 12-18 parts of column kaolin, 0.15-0.25 parts of sodium humate, 0.15-0.25 parts of sodium carboxymethylcellulose and three
0.15-0.2 parts of polyphosphate sodium.
Alternatively, blank formulation uses the body recipe of common glazed ceramic brick, and present embodiment offer one is exemplary
Formula.To ensure flatness and the ripple glaze deformation of product, base substrate aluminum content is 21% or so, and whiteness is at 35 degree or so.Institute
Stating blank includes the raw material of following mass parts：Sand 10-30 parts of Yichuan, 10-20 parts of Ganzhou low temperature potassium sodium sand, Qianshan washing mud 16-
20 parts, 6-10 parts of Guangxi White mud, white mud 1-5 parts of Ji'an, 25-35 parts of Guangchang potassium sand, bentonite 0.5-1.5 parts of Fuzhou City and black talc
2-3 parts.
Alternatively, the moisture content of blank is 6%-6.5%；The grain composition of the blank is：20 mesh above 0-1.5%,
0-6% below 20-40 mesh 30%-60%, 20-60 mesh 72%-88%, 100 mesh, remainder is 60-100 mesh.
It is preferably carried out in one kind in mode, the decorative layer includes one or multi-channel lamina printing decoration, one or multi-channel roller
Cylinder stamp and it is one or both of ink-jet printed more than combination.
The decorative layer of present embodiment, carries out decoration stamp preferably by ink-jet printing apparatus and obtains.On the one hand, use
The mode of inkjet printing carries out pattern decorative to Ceramic Tiles so that decorative layer texture variations are abundant lively, and color is naturally true to nature, to the greatest extent
Aobvious individual character makes widely known glamour.On the other hand, the pattern texture of decorative layer and anti-skid wearable layer is interlaced, by increasing capacitance it is possible to increase changeable layer
Secondary and stereoeffect, produces some parts of pattern texture and mays be seen indistinctly, seem the effect come out from brick borough chief, enrich product
Level, product specification is improved, with good decorative effect.
It should be noted that the preparation method of the anti-skid wearable Ceramic Tiles in the present invention does not have special limitation, using this
It is prepared by technical scheme known to art personnel.
With reference to embodiment and comparative example, the present invention will be further described in detail.
Embodiment 1
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：90 parts of anti-skid wearable particle,
Print 0.2 part of 90 parts of cream and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260 parts, Al2O320 parts, Fe2O3
0.01 part, TiO20.1 part, Na21 part of O, K20.1 part of 1 part of O, 0.01 part of MgO, 0.1 part of CaO and loss on ignition；Print cream main
It is made up of the component of following mass parts：40 parts of 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Embodiment 2
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 110
0.4 part of part, 110 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO270 parts, Al2O330 parts, Fe2O3
1 part, TiO22 parts, Na25 parts of O, K22 parts of 10 parts of O, 1 part of MgO, 5 parts of CaO and loss on ignition；Print cream main by following mass parts
Component composition：60 parts of 8 parts of sodium carboxymethylcellulose, 60 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
The content of each raw material of anti-skid wearable glaze of the present embodiment and the constituent content of each raw material are different from embodiment 1.
Embodiment 3
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 100
0.3 part of part, 100 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO265 parts, Al2O325 parts, Fe2O3
0.5 part, TiO21 part, Na22.5 parts of O, K21.5 parts of 5 parts of O, 0.5 part of MgO, 2.5 parts of CaO and loss on ignition；Print cream it is main by
The component composition of following mass parts：50 parts of 10 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
The content of each raw material of the anti-skid wearable glaze of the present embodiment and the constituent content of each raw material are different from embodiment 1.
Embodiment 4
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 100
0.3 part of part, 100 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO268 parts, Al2O322 parts, Fe2O3
0.25 part, TiO20.8 part, Na22.4 parts of O, K20.9 part of 3 parts of O, 0.8 part of MgO, 1.8 parts of CaO and loss on ignition；Print cream main
It is made up of the component of following mass parts：45 parts of 1 part of sodium carboxymethylcellulose, 55 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
The constituent content of each raw material of the anti-skid wearable glaze of the present embodiment is different from embodiment 3.
Embodiment 5
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 100
0.3 part of part, 100 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO265.87 part, Al2O3 22.86
Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost
0.75 part of amount；Print cream is mainly made up of the component of following mass parts：2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50
Part；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Embodiment 6
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 100
0.3 part of part, 100 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO265.87 part, Al2O3 22.86
Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost
0.75 part of amount；Print cream is mainly made up of the component of following mass parts：2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50
Part；
The grain composition of anti-skid wearable particle is：80-120 mesh 25%, 120-180 mesh 55%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
In the present embodiment, the grain composition of anti-skid wearable particle and the difference of embodiment 5.
Embodiment 7
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 100
0.3 part of part, 100 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO265.87 part, Al2O3 22.86
Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost
0.75 part of amount；Print cream is mainly made up of the component of following mass parts：2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50
Part；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.2g/cm3, flow velocity is 90 seconds.
In the present embodiment, the proportion and flow velocity of anti-skid wearable glaze and the difference of embodiment 5.
Embodiment 8
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Anti-skid wearable particle 100
0.3 part of part, 100 parts of cream of print and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO265.87 part, Al2O3 22.86
Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost
0.75 part of amount；Print cream is mainly made up of the component of following mass parts：2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50
Part；
The grain composition of anti-skid wearable particle is：80-120 mesh 25%, 120-180 mesh 55%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.2g/cm3, flow velocity is 90 seconds.
In the present embodiment, grain composition, the proportion of anti-skid wearable glaze and the flow velocity of anti-skid wearable particle with embodiment 5
It is different.
Embodiment 9
A kind of anti-skid wearable Ceramic Tiles, include green body layer, cover coat, decorative layer and mainly use anti-skidding successively from down to up
The anti-skid wearable layer that wear-resisting glaze charity is formed after base substrate layer surface,
The cover coat is mainly prepared from by cover-coat enamel, and the cover-coat enamel is mainly prepared from by the raw material of following mass parts：
20 parts of potassium feldspar, 15 parts of quartz, 15 parts of nepheline, 5 parts of calcined kaolin, 5 parts of aluminum oxide, 1 part of wollastonite, 0.1 part of zinc oxide, silicon
0.1 part of sour 10 parts of zirconium, 10 parts of column kaolin, 0.1 part of sodium humate, 0.1 part of sodium carboxymethylcellulose and sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, cover coat and decorative layer are also included in the present embodiment.
Embodiment 10
A kind of anti-skid wearable Ceramic Tiles, include green body layer, cover coat, decorative layer and mainly use anti-skidding successively from down to up
The anti-skid wearable layer that wear-resisting glaze charity is formed after base substrate layer surface,
The cover coat is mainly prepared from by cover-coat enamel, and the cover-coat enamel is mainly prepared from by the raw material of following mass parts：
30 parts of potassium feldspar, 30 parts of quartz, 25 parts of nepheline, 10 parts of calcined kaolin, 15 parts of aluminum oxide, 8 parts of wollastonite, 2 parts of zinc oxide, silicon
0.3 part of sour 30 parts of zirconium, 20 parts of column kaolin, 0.3 part of sodium humate, 0.3 part of sodium carboxymethylcellulose and sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, cover coat and decorative layer are also included in the present embodiment.
Embodiment 11
A kind of anti-skid wearable Ceramic Tiles, include green body layer, cover coat, decorative layer and mainly use anti-skidding successively from down to up
The anti-skid wearable layer that wear-resisting glaze charity is formed after base substrate layer surface,
The cover coat is mainly prepared from by cover-coat enamel, and the cover-coat enamel is mainly prepared from by the raw material of following mass parts：
25 parts of potassium feldspar, 23 parts of quartz, 23 parts of nepheline, 8 parts of calcined kaolin, 10 parts of aluminum oxide, 5 parts of wollastonite, 1 part of zinc oxide, silicon
0.2 part of sour 20 parts of zirconium, 15 parts of column kaolin, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, cover coat and decorative layer are also included in the present embodiment.
Embodiment 12
A kind of anti-skid wearable Ceramic Tiles, include green body layer, cover coat, decorative layer and mainly use anti-skidding successively from down to up
The anti-skid wearable layer that wear-resisting glaze charity is formed after base substrate layer surface,
The cover coat is mainly prepared from by cover-coat enamel, and the cover-coat enamel is mainly prepared from by the raw material of following mass parts：
25 parts of potassium feldspar, 23 parts of quartz, 23 parts of nepheline, 8 parts of calcined kaolin, 10 parts of aluminum oxide, 5 parts of wollastonite, 1 part of zinc oxide, silicon
0.2 part of sour 20 parts of zirconium, 15 parts of column kaolin, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, cover coat and decorative layer are also included in the present embodiment；It is described
Cover coat by ink-jet printing apparatus carry out decoration stamp obtain.
Embodiment 13
A kind of anti-skid wearable Ceramic Tiles, as different from Example 12, green body layer includes the raw material of following mass parts：Yichuan
20 parts of sand, 15 parts of Ganzhou low temperature potassium sodium sand, 18 parts of mud of Qianshan washing, 8 parts of Guangxi White mud, 3 parts of the white mud in Ji'an, Guangchang potassium sand 30
2.5 parts of part, 1 part of Fuzhou City's bentonite and black talc；The moisture content of blank is 6%；The grain composition of the blank is：It is more than 20 mesh
3% below 1%, 20-40 mesh 55%, 20-60 mesh 80%, 100 mesh, remainder is 60-100 mesh；Remaining and all same of embodiment 12.
Comparative example 1
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：80 parts of anti-skid wearable particle,
Print 0.1 part of 120 parts of cream and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260 parts, Al2O320 parts, Fe2O3
0.01 part, TiO20.1 part, Na21 part of O, K20.1 part of 1 part of O, 0.01 part of MgO, 0.1 part of CaO and loss on ignition；Print cream main
It is made up of the component of following mass parts：40 parts of 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
As different from Example 1, the content of anti-skid wearable particle, print cream and sodium tripolyphosphate does not exist in this comparative example
In scope provided by the present invention.
Comparative example 2
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：80 parts of anti-skid wearable particle,
Print 0.1 part of 80 parts of cream and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO255 parts, Al2O332 parts, Fe2O3
2 parts, TiO23 parts, Na26 parts of O, K23 parts of 0.1 part of O, 1.1 parts of MgO, 0.01 part of CaO and loss on ignition；Print cream main by following
The component composition of mass parts：40 parts of 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
As different from Example 1, the content of anti-skid wearable particle in this comparative example, print cream and sodium tripolyphosphate, and
The constituent content of anti-skid wearable particle is not in scope provided by the present invention.
Comparative example 3
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：90 parts of anti-skid wearable particle
With 90 parts of cream of print；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260 parts, Al2O320 parts, Fe2O3
0.01 part, TiO20.1 part, Na21 part of O, K20.1 part of 1 part of O, 0.01 part of MgO, 0.1 part of CaO and loss on ignition；Print cream main
It is made up of the component of following mass parts：40 parts of 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
As different from Example 1, sodium tripolyphosphate is free of in the raw material of this comparative example.
Comparative example 4
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：90 parts of anti-skid wearable particle,
Print 0.2 part of 90 parts of cream and sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260 parts, Al2O320 parts, Fe2O3
0.01 part, Na21 part of O, K20.1 part of 1 part of O, 0.01 part of MgO, 0.1 part of CaO and loss on ignition；Print cream main by following mass parts
Component composition：40 parts of 2 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and water；
The grain composition of anti-skid wearable particle is：80-120 mesh 35%, 120-180 mesh 45%, remaining be 200 mesh below；
The proportion of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
As different from Example 1, TiO is free of in the component of the anti-skid wearable particle of this comparative example2。
Comparative example 5
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Common high temperature light is transparent
0.2 part of 90 parts of glaze block, 90 parts of cream of print and sodium tripolyphosphate.
As different from Example 1, in this comparative example, common high temperature light clear frit block is selected from：Clear frit, model
TC1168, Zibo day is produced into enamel frit makeing Co., Ltd.
Comparative example 6
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：Common high temperature matt is transparent
0.2 part of 90 parts of glaze block, 90 parts of cream of print and sodium tripolyphosphate.
As different from Example 1, in this comparative example, common high temperature matt clear frit block is selected from：Matt fused block, model
TC9071, Zibo day is produced into enamel frit makeing Co., Ltd.
Comparative example 7
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after base substrate layer surface with main
Into anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：90 parts of normal transparent dry granular,
Print 0.2 part of 90 parts of cream and sodium tripolyphosphate.
As different from Example 1, in this comparative example, common dry granular is selected from：Three degree dryout grain, model TC2600, Zibo
It is produced into enamel frit makeing Co., Ltd.
Table 1 be embodiment 1-13 and comparative example 1-7 in anti-skid wearable Ceramic Tiles the performance test results.
The performance test results of table 1
Explain：The regulation for being first according to GB/T3810.7 carries out abrasion test, is gone round and round a millstone through 12000 after damage：(1) if product table
Then face is tested, if pollution can not be wiped, wear-resisting grade is set to 4 grades without appreciable wear according to GB/T3810.14 regulation, if
Pollution can be wiped, and wear-resisting grade is set to 5 grades；(2) if product surface has appreciable wear, wear-resisting grade is set to 3 grades.
From the performance test results of table 1, embodiment 1-13 anti-skid factor is above 0.5, and wear-resisting grade is at 4 grades
And more than, and comparative example 1-7 anti-skid factor is not higher than 0.5, wear-resisting grade is 3 grades, is thus illustrated, provided by the present invention
Anti-skid wearable Ceramic Tiles there is good non-skid property and anti-wear performance, the raw material composition or raw material for changing anti-skid wearable glaze contain
Amount can make its anti-skid wearable degradation using existing glaze.
In addition, it was found from embodiment 5-8 the performance test results, using the present invention be preferably carried out that mode obtains it is anti-skidding
The non-skid property and anti-wear performance of wear-resistant ceramic brick more preferably, illustrate the above-mentioned thing for being preferably carried out each raw material of mode comprehensive consideration
Physicochemical property, it is scientific and reasonable, and then can further improve the non-skid property and anti-wear performance of Ceramic Tiles.
In addition, it was found from embodiment 9-13 the performance test results, add after cover coat and decorative layer, Ceramic Tiles it is anti-
Sliding coefficient and wear-resisting grade are showed no obvious reduction, illustrate that above-mentioned cover coat and decorative layer can be formed well with anti-skid wearable layer
With reference to, and the non-skid property and anti-wear performance of product will not be damaged；Through observation shows that, add cover coat and decorative layer
Afterwards, the case shell of Ceramic Tiles more enriches, and picture on surface is more diversified, and aesthetic property is more preferable, with good economic benefit.
Although illustrate and describing the present invention with specific embodiment, but it will be appreciated that without departing substantially from the present invention's
Many other changes and modification can be made in the case of spirit and scope.It is, therefore, intended that in the following claims
Including belonging to all such changes and modifications in the scope of the invention.
Claims (10)
1. a kind of anti-skid wearable Ceramic Tiles, it is characterised in that including green body layer and mainly using anti-skid wearable glaze charity in base substrate
The anti-skid wearable layer formed after layer surface, the anti-skid wearable glaze is mainly prepared from by the raw material of following mass parts：It is anti-skidding resistance to
0.2-0.4 parts of 90-110 parts of abrasive particle, 90-110 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO260-70 parts, Al2O320-30 parts, Fe2O3
0.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and loss on ignition
0.1-2 parts.
2. anti-skid wearable Ceramic Tiles according to claim 1, it is characterised in that the anti-skid wearable glaze is main by following matter
The raw material of amount part is prepared from：0.22-0.38 parts of 92-108 parts of anti-skid wearable particle, 92-108 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO261-69 parts, Al2O321-29 parts, Fe2O3
0.02-0.09 parts, TiO20.2-1.9 parts, Na21.5-4.5 parts of O, K22-9 parts of O, 0.1-0.9 parts of MgO, 1-4 parts of CaO and
0.2-1.9 parts of loss on ignition.
3. anti-skid wearable Ceramic Tiles according to claim 1, it is characterised in that the anti-skid wearable glaze is main by following matter
The raw material of amount part is prepared from：0.24-0.36 parts of 94-106 parts of anti-skid wearable particle, 94-106 parts of cream of print and sodium tripolyphosphate；
The anti-skid wearable particle is mainly made up of the component of following mass parts：SiO262-68 parts, Al2O322-28 parts, Fe2O3
0.04-0.08 parts, TiO20.4-1.8 parts, Na22-4 parts of O, K23-8 parts of O, 0.2-0.8 parts of MgO, 2-3 parts of CaO and burning are lost
0.3-1.8 parts of amount.
4. the anti-skid wearable Ceramic Tiles according to claim any one of 1-3, it is characterised in that the print cream is main by following
The component composition of mass parts：40-60 parts of 2-3 parts of sodium carboxymethylcellulose, 40-60 parts of ethylene glycol and water.
5. the anti-skid wearable Ceramic Tiles according to claim any one of 1-3, it is characterised in that the anti-skid wearable particle
Grain composition is：80-120 mesh 20%-30%, 120-180 mesh 50%-60%, remaining is below 200 mesh.
6. the anti-skid wearable Ceramic Tiles according to claim any one of 1-3, it is characterised in that the ratio of the anti-skid wearable glaze
Weight is 1.2-1.8g/cm3。
7. the anti-skid wearable Ceramic Tiles according to claim any one of 1-3, it is characterised in that the stream of the anti-skid wearable glaze
Speed is 80-100 seconds.
8. anti-skid wearable Ceramic Tiles according to claim 1, it is characterised in that the green body layer and anti-skid wearable layer
Between be additionally provided with cover coat and decorative layer, the decorative layer is arranged between the cover coat and anti-skid wearable layer.
9. anti-skid wearable Ceramic Tiles according to claim 8, it is characterised in that main prepared by cover-coat enamel of the cover coat and
Into the cover-coat enamel is mainly prepared from by the raw material of following mass parts：20-30 parts of potassium feldspar, 15-30 parts of quartz, nepheline 15-25
Part, 5-10 parts of calcined kaolin, 5-15 parts of aluminum oxide, 1-8 parts of wollastonite, 0.1-2 parts of zinc oxide, 10-30 parts of zirconium silicate, column
0.1-0.3 parts of 10-20 parts of kaolin, 0.1-0.3 parts of sodium humate, 0.1-0.3 parts of sodium carboxymethylcellulose and sodium tripolyphosphate.
10. anti-skid wearable Ceramic Tiles according to claim 8 or claim 9, it is characterised in that the decorative layer includes together or many
Road lamina printing decoration, one or multi-channel roller printing and it is one or both of ink-jet printed more than combination.
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| CN107963814A (en) * | 2017-11-16 | 2018-04-27 | 蒙娜丽莎集团股份有限公司 | Compound glaze, the wear-resisting porcelain Antique Imitation Tiles of compound glaze slip and the soft face of 4-8 degree |
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