CN107285737B - The easy clean Ceramic Tiles of anti-skid wearable - Google Patents
The easy clean Ceramic Tiles of anti-skid wearable Download PDFInfo
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- CN107285737B CN107285737B CN201710600631.0A CN201710600631A CN107285737B CN 107285737 B CN107285737 B CN 107285737B CN 201710600631 A CN201710600631 A CN 201710600631A CN 107285737 B CN107285737 B CN 107285737B
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- skid wearable
- easy clean
- mass fraction
- easy
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- 239000000919 ceramic Substances 0.000 title claims abstract description 82
- 239000002245 particle Substances 0.000 claims abstract description 87
- 239000010410 layer Substances 0.000 claims abstract description 64
- 239000011241 protective layer Substances 0.000 claims abstract description 22
- 238000002360 preparation method Methods 0.000 claims abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 77
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 64
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 49
- 239000011734 sodium Substances 0.000 claims description 45
- 229910052593 corundum Inorganic materials 0.000 claims description 41
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 41
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 40
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 35
- 229910052681 coesite Inorganic materials 0.000 claims description 34
- 229910052906 cristobalite Inorganic materials 0.000 claims description 34
- 239000000377 silicon dioxide Substances 0.000 claims description 34
- 229910052682 stishovite Inorganic materials 0.000 claims description 34
- 229910052905 tridymite Inorganic materials 0.000 claims description 34
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 27
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical group [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 16
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 16
- 239000006071 cream Substances 0.000 claims description 16
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 16
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 16
- 239000005995 Aluminium silicate Substances 0.000 claims description 14
- 235000012211 aluminium silicate Nutrition 0.000 claims description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011787 zinc oxide Substances 0.000 claims description 14
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 13
- 239000004576 sand Substances 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 10
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000454 talc Substances 0.000 claims description 10
- 235000012222 talc Nutrition 0.000 claims description 10
- 229910052623 talc Inorganic materials 0.000 claims description 10
- 230000005484 gravity Effects 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000010453 quartz Substances 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 235000019738 Limestone Nutrition 0.000 claims description 6
- 239000006004 Quartz sand Substances 0.000 claims description 6
- 229910052656 albite Inorganic materials 0.000 claims description 6
- 239000006028 limestone Substances 0.000 claims description 6
- 239000010434 nepheline Substances 0.000 claims description 6
- 229910052664 nepheline Inorganic materials 0.000 claims description 6
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 5
- 239000011449 brick Substances 0.000 abstract description 14
- 238000004140 cleaning Methods 0.000 abstract description 12
- 230000003670 easy-to-clean Effects 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005299 abrasion Methods 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 34
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 33
- 230000000052 comparative effect Effects 0.000 description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- 238000010304 firing Methods 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 229910021532 Calcite Inorganic materials 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005829 trimerization reaction Methods 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/16—Lean materials, e.g. grog, quartz
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Architecture (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Glass Compositions (AREA)
Abstract
The present invention provides a kind of easy clean Ceramic Tiles of anti-skid wearable, it is related to architectural pottery technical field, including the green body layer set gradually from bottom to up, cover coat, decorative layer, anti-skid wearable layer and easy clean protective layer, wherein, anti-skid wearable layer is mainly formed by anti-skid wearable particle preparation, easy clean protective layer is mainly formed by easy clean protection particle preparation, the generally existing surface abrasion resistance intensity of ceramic antique bricks alleviated currently on the market is inadequate, it is easy to wear, anti-skid factor is low, it is difficult that there is also cleanings simultaneously, the technical issues of the defects of hiding is dirty, making the easy clean Ceramic Tiles of obtained anti-skid wearable, not only wear-resistant strength is high, it is not easy to wear, and the anti-skid factor of product is high, effectively people can be avoided to fall down, improve the safety of product, also there is excellent stain resistance simultaneously, it is dirty to be not easy hiding, it is easy to clean, daily arrange is provided convenience Technical effect.
Description
Technical field
The present invention relates to architectural pottery technical field, more particularly, to a kind of easy clean Ceramic Tiles of anti-skid wearable.
Background technique
Ceramic antique bricks are a kind of building decoration materials to come into vogue in recent years, it has had both the splendid of polished bricks
It is rich and varied with the pattern of tile, there is many advantages, such as modern or pseudo-classic charm and personalization, be received by the market and consume
Person's likes.
With the continuous improvement of people's living standards, consumer to the demand in terms of ceramic antique bricks function also increasingly
It is more, but the generally existing surface abrasion resistance intensity of ceramic antique bricks currently on the market is inadequate, be easy to appear scratch, it is easy to wear to
The beauty and class of product are affected, and the anti-skid factor of product is low, is especially easy in the case where product surface has water
It makes one to fall down, while there is also clear up the defects of difficult, hiding is dirty, product blackening over time.
In view of this, the present invention is specifically proposed.
Summary of the invention
One of the objects of the present invention is to provide a kind of easy clean Ceramic Tiles of anti-skid wearable, to alleviate ceramics currently on the market
The generally existing surface abrasion resistance intensity of Antique Imitation Tiles is inadequate, is easy to appear scratch, easy to wear, and the anti-skid factor of product is low, simultaneously
The technical issues of the defects of there is also cleaning difficulties, hiding dirt, product blackening over time.
The easy clean Ceramic Tiles of anti-skid wearable provided by the invention, including set gradually from bottom to up green body layer, cover coat, dress
Decorations layer, anti-skid wearable layer and easy clean protective layer, the anti-skid wearable layer are prepared by anti-skid wearable glaze, the anti-skid wearable glaze
It is mainly formed by anti-skid wearable particle preparation, the anti-skid wearable particle is mainly grouped as by the group of following mass fraction meter:
SiO260~70 parts, Al2O320~30 parts, Fe2O30.01~1 part, TiO20.1~2 part, Na21~5 part of O, K2O 1~10
Part, 0.01~1 part of MgO, 0.1~5 part of CaO and 0.1~2 part of loss on ignition, the sum of above-mentioned each component are 100 parts；It is described easy clean
Protective layer is prepared by easy clean protection glaze, and the easy clean protection glaze is mainly formed by easy clean protection particle preparation, described easy clean
Protection particle is mainly grouped as by the group of following mass fraction meter: SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~
0.3 part, TiO20.01~0.1 part, Na24~8 parts of O, K22~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and burning
0.05~0.3 part of vector, the sum of above-mentioned each component is 100 parts.
Further, the anti-skid wearable particle is mainly grouped as by the group of following mass fraction meter: SiO262~68
Part, Al2O320~25 parts, Fe2O30.05~1 part, TiO20.5~1.5 part, Na22~3 parts of O, K22~6 parts of O, MgO
0.02~0.08 part, 2~4 parts of CaO and 0.1~1.5 part of loss on ignition, the sum of above-mentioned each component are 100 parts；The easy clean protection
Particle is mainly grouped as by the group of following mass fraction meter: SiO262~68 parts, Al2O318~23 parts, Fe2O30.1~0.2
Part, TiO20.02~0.08 part, Na25~7 parts of O, K23~6 parts of O, 0.1~0.2 part of MgO, 1-3 parts of CaO and loss on ignition
0.1~0.3 part, the sum of above-mentioned each component is 100 parts.
Further, the anti-skid wearable particle is mainly grouped as by the group of following mass fraction meter: SiO265~66
Part, Al2O322~23 parts, Fe2O30.07~0.09 part, TiO20.9~1.1 part, Na22~2.5 parts of O, K24~5 parts of O,
0.03~0.05 part of MgO, 2~3 parts of CaO and 0.7~0.8 part of loss on ignition, the sum of above-mentioned each component are 100 parts；It is described easy clean
Protection particle is mainly grouped as by the group of following mass fraction meter: SiO266~67 parts, Al2O320~22 parts, Fe2O3 0.15
~0.2 part, TiO20.05~0.07 part, Na25~7 parts of O, K24~5 parts of O, 0.1~0.15 part of MgO, 1.5~2 parts of CaO
With 0.1~0.2 part of loss on ignition, the sum of above-mentioned each component be 100 parts.
Further, the primary raw material of the anti-skid wearable glaze further include 90~110 parts of print cream according to the mass fraction and
0.2~0.4 part of sodium tripolyphosphate；Wherein, print cream is mainly grouped as by the group of following mass fraction meter: sodium carboxymethylcellulose 2
~3 parts, 40~60 parts of ethylene glycol and 40~60 parts of water.
Further, the primary raw material of the easy clean protection glaze further include 230~270 parts of stamp-pad ink according to the mass fraction,
20~40 parts of clear frit；The stamp-pad ink is mainly grouped as by the group of following mass fraction meter: 1~2 part of sodium carboxymethylcellulose, second
20~40 parts of glycol, 1~5 part of bentonite and 60~80 parts of water.
Further, the clear frit is mainly grouped as by the group of following mass fraction meter: 12~16 parts of albite, potassium are long
20~24 parts of stone, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and 1~5 part of zinc oxide.
Further, the grain composition of the anti-skid wearable particle are as follows: 80~120 mesh 20%~30%, 120~180 mesh
50%~60%, remaining is below 200 mesh；Preferably, the specific gravity of the anti-skid wearable particle is 1.2~1.8g/cm3, flow velocity
It is 80~100 seconds.
Further, the grain composition of the easy clean protection particle are as follows: 80~120 mesh 50%~60%, 120~200 mesh
20%~30%, remaining is below 200 mesh；Preferably, the specific gravity of the easy clean protection particle is 1.2~1.4g/cm3。
Further, the cover coat is prepared by overglaze, and the overglaze is mainly prepared by the raw material of following mass parts
It forms: 20~30 parts of potassium feldspar, quartzy 15~30 parts, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, aluminium oxide 5~15
Part, 1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate 0.1
~0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and 0.1~0.3 part of sodium tripolyphosphate.
Further, the green body layer is prepared by blank, and the blank is mainly by following original according to the mass fraction
Material is prepared: 18~22 parts of quartz sand, 12~18 parts of potassium sodium sand, 16~20 parts of mud of washing, 9~13 parts of white mud, potassium sand 28~
33 parts, 0.5~1.5 part of bentonite and 2~3 parts of black talc.
Abrasionproof wear-resistant ceramic brick provided by the invention passes through the anti-skid wearable layer and easy clean of being cascading in decorative layer
Protective layer, so that not only wear-resistant strength is high for abrasionproof wear-resistant ceramic brick, it is not easy to wear, and the anti-skid factor of product is high, Neng Gouyou
Effect avoids people from falling down, and improves the safety of product, while also having excellent stain resistance, is not easy hiding dirt, easy to clean,
It provides convenience for daily arrange, meets people for ceramic antique bricks anti-skid wearable and easy clean functional requirement.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
The present invention provides a kind of easy clean Ceramic Tiles of anti-skid wearable, including set gradually from bottom to up green body layer, overglaze
Layer, decorative layer, anti-skid wearable layer and easy clean protective layer, anti-skid wearable layer are prepared by anti-skid wearable glaze, anti-skid wearable glaze master
It to be formed by anti-skid wearable particle preparation, anti-skid wearable particle is mainly grouped as by the group of following mass fraction meter: SiO260~
70 parts, Al2O320~30 parts, Fe2O30.01~1 part, TiO20.1~2 part, Na21~5 part of O, K21~10 part of O, MgO
0.01~1 part, 0.1~5 part of CaO and 0.1~2 part of loss on ignition, the sum of said components are 100 parts；The easy clean protective layer is by easy
Clean protection glaze is prepared, and the easy clean protection glaze is mainly formed by easy clean protection particle preparation, the easy clean protection particle master
It to be grouped as by the group of following mass fraction meter: SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO2
0.01~0.1 part, Na24~8 parts of O, K22~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and loss on ignition 0.05~
0.3 part, the sum of said components are 100 parts.
Abrasionproof wear-resistant ceramic brick provided by the invention passes through the anti-skid wearable layer and easy clean of being cascading in decorative layer
Protective layer, so that not only wear-resistant strength is high for abrasionproof wear-resistant ceramic brick, it is not easy to wear, and the anti-skid factor of product is high, Neng Gouyou
Effect avoids people from falling down, and improves the safety of product, while also having excellent stain resistance, is not easy hiding dirt, easy to clean,
It provides convenience for daily arrange, meets people for ceramic antique bricks anti-skid wearable and easy clean functional requirement.
In the present invention, cover coat can be improved the mechanical strength of the easy clean Ceramic Tiles of anti-skid wearable, reduce the water suction of green body
Rate.Decorative layer can enrich the diversity of ceramic brick surface pattern, keep Ceramic Tiles more beautiful, decorative layer and anti-skid wearable layer two
The pattern texture of person is interlaced, can increase changeable level and stereoscopic effect, and it is indistinct to produce some parts of pattern texture
As it can be seen that seeming the effect come out from brick borough chief；Anti-skid wearable layer can make the Ceramic Tiles have good anti-skidding and abrasion resistant effect,
And the anti-skid wearable layer and easy clean protective layer cooperate, and shadow comparison can be formed in product surface, thus abundant gas producing formation
It is secondary, promote product specification.
In the present invention, anti-skid wearable layer is prepared by anti-skid wearable glaze, and anti-skid wearable glaze is mainly by anti-skid wearable
Grain is prepared, and anti-skid wearable particle passes through the SiO of extra fine quality number2、Al2O3、Fe2O3、TiO2、Na2O、K2O, MgO and CaO
Coordinated, so that there is good wear-resisting property and non-skid property by the anti-skid wearable layer that anti-skid wearable glaze is prepared, no
It is only not easy to wear and scratch occur, so that the easy clean Ceramic Tiles of anti-skid wearable are more attractive, and effectively people can be avoided because of surface
There is water and fall down, improves the security performance of product.
In the present invention, easy clean protective layer is mainly prepared by easy clean protection glaze, and easy clean protection glaze is mainly by easy clean guarantor
Shield particle preparation forms, and easy clean protection particle passes through the SiO of extra fine quality number2、Al2O3、Fe2O3、Ti2O、Na2O、K2O、MgO
With CaO coordinated so that not only there is good anti-fouling performance by the easy clean easy clean protective layer that is prepared of protection glaze, and
And it is not easy hiding dirt, and it is easy to clean, so that it be made to be easier to arrange.
In anti-skid wearable particle provided by the invention, SiO2Typical but non-limiting mass fraction for example 60,
60.5、61、61.5、62、62.5、63、63.5、64、64.5、65、65.5、66、66.5、67、67.5、68、68.5、69、69.5
Or 70 parts；Al2O3Typical but non-limiting mass fraction for example 20.5,21,21.5,22,22.5,23,23.5,24,
24.5,25,25.5,26,26.5,27,27.5,28,28.5,29,29.5 or 30 parts；Fe2O3Typical but non-limiting quality
Number for example 0.01,0.015,0.02,0.025,0.03,0.035,0.04,0.045,0.05,0.055,0.06,0.065,
0.07,0.075,0.08,0.085,0.09,0.095 or 0.1；TiO2Typical but non-limiting mass fraction for example 0.1,
0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,1.1,1.2,1.3,1.4,1.5,1.6,1.7,1.8,1.9 or 2 part；
Na2The typical but non-limiting mass fraction for example 1 of O, 1.2,1.4,1.6,1.8,2,2.2,2.4,2.6,2.8,3,3.2,
3.4,3.6,3.8,4,4.2,4.4,4.6,4.8 or 5 parts；K2The typical but non-limiting mass fraction for example 1 of O, 1.5,2,
2.5,3,3.5,4,4.5,5,5.5,6,6.5,7,7.5,8,8.5,9,9.5 or 10 parts；The typical but unrestricted mass parts of MgO
Number for example 0.1,0.15,0.2,0.25,0.3,0.35,0.4,0.45,0.5,0.55,0.6,0.65,0.7,0.75,0..8,
0.85,0.9,0.95 or 1 part；The typical but non-limiting mass fraction for example 0.1 of CaO, 0.2,0.3,0.4,0.5,0.6,
0.7、0.8、0.9、1、1.1、1.2、1.3、1.4、1.5、1.6、1.7、1.8、1.9、2、2.1、2.2、2.3、2.4、2.5、2.6、
2.7、2.8、2.9、3、3.1、3.2、3.3、3.4、3.53.6、3.7、3.8、3.9、4、4.1、4.2、4.3、4.4、4.5、4.6、
4.7,4.8,4.9 or 5 parts；The typical but non-limiting mass fraction for example 0.1 of loss on ignition, 0.2,0.3,0.4,0.5,0.6,
0.7,0.8,0.9,1,1.1,1.2,1.3,1.4,1.5,1.6,1.7,1.8,1.9 or 2.
Anti-skid wearable particle passes through the SiO of extra fine quality number2、Al2O3、Fe2O3、TiO2、Na2O、K2O, MgO and CaO association
With cooperation, so that anti-skid wearable particle not only has good high temperature resistance, wear-resisting property and non-skid property, even if in high temperature
Under it is not easy to wear and scratch, and transparency with higher and lower glossiness occur yet, to guarantee that anti-skid wearable is easy
The continuity and clarity of ceramic brick decoration layer pattern texture, improve aesthetics and the safety of product.
In the present invention, anti-skid wearable particle is mainly prepared by the raw material of following mass fraction meter: aluminium oxide 12-18
Part, 35-45 parts of potassium feldspar, 0.1-3 parts of soda ash, 1-8 parts of calcite and 35-40 parts of quartz.
In the raw material provided by the invention for preparing anti-skid wearable particle, the typical but non-limiting mass parts of aluminium oxide
Number for example 12,12.5,13.13.5,14,14.5,15,15.5,16,16.5,17,17.5 or 18 part；Potassium feldspar it is typical but non-
Restrictive mass fraction for example 35,35.5,36,36.5,37,37.5,38,38.5,39,39.5,40,40.5,41,41.5,
42,42.5,43,43.5,44,44.5 or 45 parts；The typical but non-limiting mass fraction for example 35 of quartz, 35.5,36,
36.5,37,37.5,38,38.5,39 or 40 parts；The typical but non-limiting mass fraction for example 1 of calcite, 1.5,2,
2.5,3,3.5,4,4.5,5,5.5,6,6.5,7,7.5 or 8 parts；The typical but non-limiting mass fraction for example 0.1 of soda ash,
0.2、0.3、0.4、0.5、0.6、0.7、0.8、0.9、1、1.1、1.2、1.3、1.4、1.5、1.6、1.7、1.8、1.9、2、2.1、
2.2,2.3,2.4,2.5,2.6,2.7,2.8,2.9 or 3 parts.
In the present invention, cooperated by the aluminium oxide of extra fine quality number, potassium feldspar, soda ash, quartz and calcite, make to burn
Anti-skid wearable particle is formed by after knot not only has good high temperature resistance, wear-resisting property and non-skid property, even if in height
It is not easy to wear and scratch, and transparency with higher and lower glossiness occur under temperature yet.
In easy clean protection particle provided by the invention, SiO2Typical but non-limiting mass fraction for example 60,
60.5、61、61.5、62、62.5、63、63.5、64、64.5、65、65.5、66、66.5、67、67.5、68、68.5、69、69.5
Or 70 parts；Al2O3Typical but non-limiting mass fraction for example 15,15.5,16,16.5,17,17.5,18,18.5,19,
19.5,20,20.5,21,21.5,22,22.5,23,23.5,24,24.5 or 25 parts；Fe2O3Typical but non-limiting quality
Number for example 0.1,0.11,0.12,0.13,0.14,0.15,0.16,0.17,0.18,0.19,0.2,0.21,0.22,0.23,
0.24,0.25,0.26,0.27,0.28,0.29 or 0.3 part；TiO2Typical but non-limiting mass fraction for example 0.01,
0.02,0.03,0.04,0.05,0.06,0.07,0.08,0.09 or 0.1 part；Na2The typical but non-limiting mass fraction of O
For example 4.1,4.2,4.3,4.4,4.5,4.6,4.7,4.8,4.9,5,5.1,5.2,5.3,5.4,5.5,5.6,5.7,5.8,
5.9、6、6.1、6.2、6.3、6.4、6.5、6.6、6.7、6.8、6.9、7、7.1、7.2、7.3、7.4、7.5、7.6、7.7、7.8、
7.9 or 8 parts；K2The typical but non-limiting mass fraction for example 2.1 of O, 2.2,2.3,2.4,2.5,2.6,2.7,2.8,
2.9、3、3.1、3.2、3.3、3.4、3.5、3.6、3.7、3.8、3.9、4、4.1、4.2、4.3、4.4、4.5、4.6、4.7、4.8、
4.9,5,5.1,5.2,5.3,5.4,5.5,5.6,5.7,5.8,5.9 or 6 parts；The typical but non-limiting mass fraction of MgO
For example 0.05,0.06,0.07,0.08,0.09,0.1,0.11,0.12,0.13,0.14,0.15,0.16,0.17,0.18,
0.19,0.2,0.21,0.22,0.23,0.24,0.25,0.26,0.27,0.28,0.29 or 0.3 part；Loss on ignition it is typical but non-
Restrictive mass fraction for example 0.05,0.06,0.07,0.08,0.09,0.1,0.11,0.12,0.13,0.14,0.15,
0.16,0.17,0.18,0.19,0.2,0.21,0.22,0.23,0.24,0.25,0.26,0.27,0.28,0.29 or 0.3 part.
Easy clean protection particle passes through the SiO of extra fine quality number2、Al2O3、Fe2O3、TiO2、Na2O、K2O, MgO and CaO association
With cooperation, so that easy clean protection particle not only softening melting temperature with higher and wider firing range, and can burn
At rear glossiness with higher, makes product that there is resistance to soiling and easy clean property, it is made to be easier to arrange.
In the present invention, easy clean protection particle is mainly prepared by the following raw material according to the mass fraction: aluminium oxide 10-
20-30 parts of 15 parts, 40-45 parts of potassium feldspar, 8-13 parts of soda ash, 7-12 parts of zinc oxide and quartz.
In the raw material provided by the invention for preparing easy clean protection particle, the typical but non-limiting mass parts of aluminium oxide
For example 10,10.5,11,11.5,12,12.5,13,13.5,14,14.5 or 15 parts of number；Potassium feldspar it is typical but non-limiting
For example 40,40.5,41,41.5,42,42.5,43,43.5,44,44.5 or 45 parts of mass fraction；Soda ash it is typical but unrestricted
For example 8,8.5,9,9.5,10,10.511,11.5,12,12.5 or 13 parts of mass fraction of property；Zinc oxide it is typical but unrestricted
For example 7,7.5,8,8.5,9,9.5,10,10.5,11,11.5 or 12 parts of mass fraction of property；Quartzy is typical but non-limiting
Mass fraction for example 20,20.5,21,21.5,22,22.5,23,23.5,24,24.5,25,25.5,26,26.5,27,
27.5,28,28.5,29,29.5 or 30 parts.
In the present invention, by the aluminium oxide of extra fine quality number, potassium feldspar, soda ash, zinc oxide and quartzy coordinated,
It is formed by easy clean protection particle not only softening melting temperature with higher and wider firing range after making sintering, and can
The glossiness with higher after firing.
In a preferred embodiment of the invention, the primary raw material of anti-skid wearable glaze further includes print cream according to the mass fraction
90~110 parts and 0.2~0.4 part of sodium tripolyphosphate；Wherein, print cream is mainly grouped as by the group of following mass fraction meter: carboxylic first
2~3 parts of base sodium cellulosate, 40~60 parts of ethylene glycol and 40~60 parts of water.
In the anti-skid wearable glaze that the preferred embodiment of the present invention provides, the typical but non-limiting mass parts of cream are printed
Number for example 91,92,93,94,95,96,97,98,99,100,101,102,103,104,105,106,107,108,109 or 110
Part；The typical but non-limiting mass fraction for example 0.2 of sodium tripolyphosphate, 0.21,0.22,0.23,0.24,0.25,0.26,
0.27,0.28,0.29,0.3,0.31,0.32,0.33,0.34,0.35,0.36,0.37,0.38,0.39 or 0.4 part.
In a preferred embodiment of the invention, anti-skid wearable glaze passes through print cream, the sodium tripolyphosphate of extra fine quality number
It is mutually cooperateed with anti-skid wearable particle, anti-skid wearable can be formed in the surface of decorative layer by silk-screen printing uniform fold
Layer, increases the wear-resisting and skid resistance of product.
In the print cream that the preferred embodiment of the present invention provides, the typical but non-limiting matter of sodium carboxymethylcellulose
Measure number for example 2,2.1,2.2,2.3,2.4,2.5,2.6,2.7,2.8,2.9 or 3；The typical but non-limiting matter of ethylene glycol
For example 41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59 or 60 parts of number of amount；Water
Typical but non-limiting mass fraction for example 41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,
57,58,59 or 60 parts.
In a preferred embodiment of the invention, pass through sodium carboxymethylcellulose, ethylene glycol and the mutual coordinated system of water phase
The print cream obtained has suitable viscosity, in order to carry out the charity of anti-skid wearable glaze.
In a preferred embodiment of the invention, the primary raw material of easy clean protection glaze further includes stamp-pad ink according to the mass fraction
230-270 parts, 20-40 parts of clear frit；Stamp-pad ink is mainly grouped as by the group of following mass fraction meter: sodium carboxymethylcellulose 1~2
Part, 20~40 parts of ethylene glycol, 1~5 part of bentonite and 60~80 parts of water.
In the easy clean protection glaze that the preferred embodiment of the present invention provides, the typical but non-limiting mass parts of stamp-pad ink
Number for example 230,232,234,236,238,240,242,244,246,248,250,252,254,256,258,260,262,
264,266,268,270,272,274,276,278 or 280 parts；The typical but non-limiting mass fraction of clear frit is for example
21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39 or 40 parts.
The easy clean protection glaze that the preferred embodiment of the present invention provides passes through the stamp-pad ink of extra fine quality number, clear frit and easily
Clean protection particle mutually cooperates with, can by way of drenching glaze uniform fold in the surface of anti-skid wearable layer, and keep compared with
High glossiness is easier to arrange so that the easy clean Ceramic Tiles of anti-skid wearable provided by the invention are more beautiful.
In the stamp-pad ink that the preferred embodiment of the present invention provides, the typical but non-limiting matter of sodium carboxymethylcellulose
Measure number for example 1,1.05,1.1,1.15,1.2,1.25,1.3,1.35,1.4,1.45,1.5,1.55,1.6,1.65,1.7,
1.75,1.8,1.85,1.9,1.95 or 2 parts；The typical but non-limiting mass fraction for example 20 of ethylene glycol, 21,22,23,
24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39 or 40 parts；It is bentonitic typical but non-limiting
Mass fraction for example 1,1.2,1.4,1.6,1.8,2,2.2,2.4,2.6,2.8,3,3.2,3.4,3.6,3.8,4,4.2,
4.4,4.6,4.8 or 5 parts；The typical but non-limiting mass fraction for example 61 of water, 62,63,64,65,66,67,68,69,
70,71,72,73,74,75,76,77,78,79 or 80 parts.
In a preferred embodiment of the invention, stamp-pad ink passes through sodium carboxymethylcellulose, ethylene glycol, bentonite and water collaboration
Cooperation, so that obtained stamp-pad ink has suitable viscosity, so that obtained easy clean protection glaze can either carry out quickly drenching glaze,
Again can uniform fold in the surface of anti-skid wearable layer.
In a preferred embodiment of the invention, clear frit is mainly grouped as by the group of following mass fraction meter: albite
12~16 parts, 20~24 parts of potassium feldspar, burn 13~17 parts of talcum, 7~11 parts of lime stone, 8~12 parts of barium carbonate and zinc oxide 1~
5 parts.
In the clear frit that the preferred embodiment of the present invention provides, the typical but non-limiting mass fraction of albite
For example 12,12.2,12.4,12.6,12.8,13,13.2,13.4,13.6,13.8,14,14.2,14.4,14.6,14.8,15,
15.2,15.4,15.6,15.8 or 16 parts；The typical but non-limiting mass fraction for example 20.2 of potassium feldspar, 20.4,20.6,
20.8,21,21.2,21.4,21.6,21.8,22,22.2,22.4,22.6,22.8,23,23.2,23.4,23.6,23.8 or
24；Burn talcum typical but non-limiting mass fraction for example 13.2,13.4,13.6,13.8,14,14.2,14.4,14.6,
14.8,15,15.2,15.4,15.6,15.8,16,16.2,16.4,16.8 or 17 parts；Lime stone it is typical but non-limiting
Mass fraction for example 7,7.2,7.4,7.6,7.8,8,8.2,8.4,8.6,8.8,9,9.2,9.4,9.6,9.8,10,10.2,
10.4,10.6,10.8 or 11 parts；The typical but non-limiting mass fraction for example 8 of barium sulfate, 8.2,8.4,8.6,8.8,9,
9.2,9.4,9.6,9.8,10,10.2,10.4,10.6,10.8,11,11.2,11.4,11.6,11.8 or 12 parts；Zinc oxide
Typical but non-limiting mass fraction for example 1,1.2,1.4,1.6,1.8,2,2.2,2.4,2.6,2.8,3,3.2,3.4,
3.6,3.8,4,4.2,4.4,4.6,4.8 or 5 parts.
In a preferred embodiment of the invention, clear frit is slided by the albite of extra fine quality number, potassium feldspar, burning
The coordinated of stone, lime stone, barium carbonate and zinc oxide, so that clear frit can not only fill up the easy clean intergranular sky of protection
Gap, while also ensuring certain high temperature viscosity, reach preferable antifouling, wear-resisting and easy clean effect together with easy clean protection particle
Fruit.
In a preferred embodiment of the invention, the grain composition of anti-skid wearable particle are as follows: 80~120 mesh 20%~
30%, 120~180 mesh 50%~60%, remaining is below 200 mesh；Preferably, the specific gravity of anti-skid wearable particle be 1.2~
1.8g/cm3, flow velocity is 80~100 seconds.
It should be noted that the percentage composition (%) in the present invention is mass percentage.
In above-mentioned anti-skid wearable particle, the typical but non-limiting content of 80-120 purpose are as follows: 20%, 21%, 22%,
23%, 24%, 25%, 26%, 27%, 28%, 29% or 30%.The typical but non-limiting content of 120-180 purpose are as follows:
50%, 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58%, 59% or 60%.Anti-skid wearable particle is selected above-mentioned
Gradation can make the gap between particle less, and charity is even closer uniform after product surface.
In the present invention, the specific gravity of above-mentioned anti-skid wearable particle is typical but non-limiting are as follows: 1.2g/cm3、1.3g/cm3、
1.4g/cm3、1.5g/cm3、1.6g/cm3、1.7g/cm3Or 1.8g/cm3.Flow velocity is typical but non-limiting are as follows: 80 seconds, 81 seconds,
82 seconds, 83 seconds, 84 seconds, 85 seconds, 86 seconds, 87 seconds, 88 seconds, 89 seconds, 90 seconds, 91 seconds, 92 seconds, 93 seconds, 94 seconds, 95 seconds, 96 seconds, 97
Second, 98 seconds, 99 seconds or 100 seconds.Above-mentioned specific gravity and flow velocity can make the good fluidity of anti-skid wearable glaze, can pass through silk
Net, and not sticky net, and then improve printing efficiency and anti-skid wearable performance.
In a preferred embodiment of the invention, the grain composition of easy clean protection particle are as follows: 80~120 mesh 50%~
60%, 120~200 mesh 20%~30%, remaining is below 200 mesh；Preferably, it is easy clean protection particle specific gravity be 1.2~
1.4g/cm3。
In above-mentioned easy clean protection particle, according to the mass fraction, the typical but non-limiting content of 80-120 purpose are as follows:
50%, 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58%, 59% or 60%.120-200 mesh is typical but unrestricted
The content of property are as follows: 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29% or 30%.
In the present invention, the typical but non-limiting specific gravity of above-mentioned easy clean protection particle are as follows: 1.2g/cm3、1.22g/
cm3、1.24g/cm3、1.26g/cm3、1.28g/cm3、1.3g/cm3、1.32g/cm3、1.34g/cm3、1.36g/cm3、1.38g/
cm3Or 1.4g/cm3。
Above-mentioned specific gravity can make the good fluidity of easy clean protection glaze, accelerate leaching glaze efficiency.
In a preferred embodiment of the invention, cover coat is mainly prepared by overglaze, and overglaze is mainly by following quality
The raw material of number meter is prepared: 20~30 parts of potassium feldspar, quartzy 15~30 parts, 15~25 parts of nepheline, calcined kaolin 5~10
Part, 5~15 parts of aluminium oxide, 1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, column kaolin 10~20
Part, 0.1~0.3 part of sodium humate, 0.1~0.3 part of sodium carboxymethylcellulose and 0.1~0.3 part of sodium tripolyphosphate.
In preparing in raw material for the overglaze that the preferred embodiment for the present invention provides, the typical but non-limiting matter of potassium feldspar
Measuring number is 20,21,22,23,24,25,26,27,28,29 or 30 parts；The typical but non-limiting mass fraction of quartz is such as
It is 15,15.5,16,16.5,17,17.5,18,18.5,19,19.5 or 20 parts；The typical but non-limiting mass parts of nepheline
For example 15,16,17,18,19,20,21,22,23,24 or 25 parts of number；The typical but non-limiting mass parts of calcined kaolin
For example 5,5.5,6,6.5,7,7.5,8,8.5,9,9.5 or 10 parts of number；The typical but non-limiting mass fraction of aluminium oxide is such as
It is 5,6,7,8,9,10,11,12,13,14 or 15 parts；The typical but non-limiting mass fraction for example 1 of wollastonite, 1.5,2,
2.5,3,3.5,4,4.5,5,5.5,6,6.5,7,7.5 or 8 parts；The typical but non-limiting mass fraction of zirconium silicate is for example
10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29 or 30 parts；Column kaolin
For example 10,11,12,13,14,15,16,17,18,19 or 20 parts of typical but non-limiting mass fraction；Sodium humate
Typical but non-limiting mass fraction for example 0.1,0.11,0.12,0.13,0.14,0.15,0.16,0.17,0.18,0.19,
0.2,0.21,0.22,0.23,0.24,0.25,0.26,0.27,0.28,0.29 or 0.3 part；The typical case of sodium carboxymethylcellulose
But unrestricted mass fraction for example 0.1,0.11,0.12,0.13,0.14,0.15,0.16,0.17,0.18,0.19,0.2,
0.21,0.22,0.23,0.24,0.25,0.26,0.27,0.28,0.29 or 0.3 part；Sodium tripolyphosphate it is typical but unrestricted
The mass fraction for example 0.1 of property, 0.11,0.12,0.13,0.14,0.15,0.16,0.17,0.18,0.19,0.2,0.21,
0.22,0.23,0.24,0.25,0.26,0.27,0.28,0.29 or 0.3 part.
The preferred embodiment for the present invention provide overglaze in, by the potassium feldspar of extra fine quality number, quartz, nepheline,
Calcined kaolin, aluminium oxide, wollastonite, zinc oxide, zirconium silicate, column kaolin, sodium humate, sodium carboxymethylcellulose and three
Polyphosphate sodium coordinated so that cover coat not only has good mechanical strength, but also can drop the water absorption rate of green body layer.
In a preferred embodiment of the invention, green body layer is prepared by blank, and blank is mainly by according to the mass fraction
The following raw material be prepared: 18~22 parts of quartz sand, 12~18 parts of potassium sodium sand, washing 16~20 parts of mud, 9~13 parts of white mud,
28~33 parts of potassium sand, 0.5~1.5 part of bentonite and 2~3 parts of black talc.
Green body layer provided by the invention passes through quartz sand, potassium sodium sand, washing mud, white mud, potassium sand, bentonite and black talc association
With the blank prepared, the green body layer formed it into has good mechanical strength.
In the green body layer blank that the preferred embodiment for the present invention provides, the typical but non-limiting mass parts of quartz sand
Number for example 18,18.2,18.4,18.6,19,19.2,19.4,19.6,19.8,20,20.2,20.4,20.6,20.8,21,
21.2,21.4,21.6,21.8 or 22 parts；The typical but non-limiting mass fraction for example 12 of potassium sodium sand, 12.2,12.4,
12.6、12.8、13、13.2、13.4、13.6、13.8、14、14.2、14.4、14.6、14.8、15、15.2、15.4、15.6、
15.8,16,16.2,16.4,16.6,16.8,17,17.2,17.4,17.6,17.8 or 18；Wash the typical but non-limiting of mud
Mass fraction for example 16,16.2,16.4,16.6,16.8,17,17.2,17.4,17.6,17.8,18,18.2,18.4,
18.6,18.8,19,19.2,19.4,19.6,19.8 or 20 parts；The typical but non-limiting mass fraction for example 9.2 of white mud,
9.4、9.6、9.8、10、10.2、10.4、10.6、10.8、11、11.2、11.4、11.6、11.8、12、12.2、12.4、12.6、
12.8 or 13 parts；The typical but non-limiting mass fraction for example 28.2 of potassium sand, 28.4,28.6,28.8,29,29.2,
29.4、29.6、29.8、30、30.2、30.4、30.6、30.8、31、31.2、31.4、31.6、31.8、32、32.2、32.4、
32.6,32.8 or 33 parts；Bentonitic typical but non-limiting mass fraction for example 0.5,0.55,0.6,0.65,0.7,
0.75,0.8,0.85,0.9,0.95,1,1.05,1.1,1.15,1.2,1.25,1.3,1.35,1.4,1.45 or 1.5 part；Black cunning
The typical but non-limiting mass fraction for example 2 of stone, 2.05,2.1,2.15,2.2,2.25,2.3,2.35,2.4,2.45,
2.5,2.55,2.6,2.65,2.7,2.75,2.8,2.85,2.9,2.95 or 3 parts.
In order to make it easy to understand, being further described below with reference to embodiment to technical solution provided by the invention.
Embodiment 1
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, be disposed with from bottom to up green body layer, cover coat,
Decorative layer, anti-skid wearable layer and easy clean protective layer,
Wherein, green body layer is prepared by blank, and blank is prepared by the following raw material as mass fraction: quartz sand
20 parts, 15 parts of potassium sodium sand, 18 parts of mud of washing, 44 parts of white mud, 31 parts of potassium sand, 1 part of bentonite and 2.5 parts of black talc；
Cover coat is prepared by overglaze, and overglaze is prepared by the following raw material based on mass fraction number: potassium feldspar 25
Part, quartz 23 parts, 20 parts of nepheline, 7 parts of calcined kaolin, 10 parts of aluminium oxide, 4 parts of wollastonite, 1 part of zinc oxide, 20 parts of zirconium silicate,
15 parts of column kaolin, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and 0.15 part of sodium tripolyphosphate；
Decorative layer is decorated stamp by ink-jet and is prepared；
Anti-skid wearable layer is prepared by anti-skid wearable glaze: anti-skid wearable glaze is prepared by the following raw material according to the mass fraction
Form: 100 parts of cream of print, 100 parts of anti-skid wearable particle, 0.3 part of sodium tripolyphosphate, print cream is grouped by the group of following mass fraction meter
At: 2.5 parts of sodium carboxymethylcellulose, 49 parts of ethylene glycol, 48.5 parts of water, anti-skid wearable particle is by as follows based on mass fraction agent
Group is grouped as: SiO260 parts, Al2O330 parts, Fe2O30.01 part, TiO20.88 part, Na25 parts of O, K21 part of O, MgO 0.11
Part, 2 parts of CaO and 1 part of loss on ignition；
Easy clean protective layer is prepared by easy clean protection glaze, it is easy clean protection glaze by following mass fraction meter raw material preparation and
At: 250 parts of stamp-pad ink, 30 parts of clear frit, easy clean 100 parts of protection particle, stamp-pad ink is grouped as by the group of following mass fraction meter: carboxylic first
1.2 parts of base sodium cellulosate, 30 parts of ethylene glycol, 3 parts of bentonite, 70 parts of water；Clear frit is by the following raw material system according to the mass fraction
Standby to form: 14 parts of albite, 8 parts of kaolin, 12 parts of calcined kaolin, 12 parts of quartz, burns 15 parts of talcum, stone at 22 parts of potassium feldspar
9 parts of lime stone, 10 parts of barium carbonate and 3 parts of zinc oxide；Easy clean protection particle is grouped as by following group as mass fraction: SiO2
61.7 parts, Al2O325 parts, Fe2O30.1 part, TiO20.1 part, Na24 parts of O, K26 parts of O, 0.05 part of MgO, 3 parts of CaO and
0.05 part of loss on ignition.
Embodiment 2
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment difference from example 1 is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO270 parts, Al2O320 parts, Fe2O3 0.1
Part, TiO22 parts, Na21 part of O, K25 parts of O, 1 part of MgO, 0.8 part of CaO and 0.1 part of loss on ignition；
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO270 parts, Al2O318.59 part, Fe2O3
0.3 part, TiO20.01 part, Na28 parts of O, K22 parts of O, 0.3 part of MgO, 0.5 part of CaO and 0.3 part of loss on ignition.
Embodiment 3
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment difference from example 1 is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO262 parts, Al2O325 parts, Fe2O3 0.05
Part, TiO21.5 parts, Na22 parts of O, K25 parts of O, 0.2 part of MgO, 4 parts of CaO and 0.25 part of loss on ignition；
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO268 parts, Al2O318 parts, Fe2O3 0.2
Part, TiO20.02 part, Na25 parts of O, K26 parts of O, 0.1 part of MgO, 2.38 parts of CaO and 0.3 part of loss on ignition.
Embodiment 4
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment difference from example 1 is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO268 parts, Al2O320 parts, Fe2O3 0.1
Part, TiO20.5 part, Na23 parts of O, K22.1 parts of O, 0.8 part of MgO, 4 parts of CaO and 1.5 parts of loss on ignition；
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO262.52 part, Al2O323 parts, Fe2O3
0.1 part, TiO20.08 part, Na27 parts of O, K26 parts of O, 0.2 part of MgO, 1 part of CaO and 0.1 part of loss on ignition.
Embodiment 5
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment difference from example 1 is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO265 parts, Al2O323 parts, Fe2O3 0.07
Part, TiO21.1 parts, Na22 parts of O, K24.53 parts of O, 0.5 part of MgO, 3 parts of CaO and 0.8 part of loss on ignition；
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO267 parts, Al2O320 parts, Fe2O3 0.2
Part, TiO20.05 part, Na25.55 parts of O, K25 parts of O, 0.1 part of MgO, 2 parts of CaO and 0.1 part of loss on ignition.
Embodiment 6
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment difference from example 1 is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO266 parts, Al2O322 parts, Fe2O3 0.09
Part, TiO20.9 part, Na22.5 parts of O, K25 parts of O, 0.3 part of MgO, 2.51 parts of CaO and 0.7 part of loss on ignition；
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO266 parts, Al2O322 parts, Fe2O3 0.15
Part, TiO20.07 part, Na25.93 parts of O, K24 parts of O, 0.15 part of MgO, 1.5 parts of CaO and 0.2 part of loss on ignition.
Embodiment 7
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment difference from example 1 is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO265.87 part, Al2O322.86 part, Fe2O3
0.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and 0.75 part of loss on ignition.
Easy clean protection particle is made of the component of following mass fraction meter: SiO266.38 part, Al2O320.99 part, Fe2O3
0.17 part, TiO20.06 part, Na26 parts of O, K24.42 parts of O, 0.13 part of MgO, 1.7 parts of CaO and 0.15 part of loss on ignition.
Embodiment 8
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment and embodiment 7 the difference is that,
Anti-skid wearable glaze is prepared by the following raw material as mass fraction: 150 parts of anti-skid wearable particle, printing 50 parts of cream and trimerization phosphorus
1 part of sour sodium.
Embodiment 9
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment and embodiment 7 the difference is that,
Anti-skid wearable glaze is prepared by the following raw material as mass fraction: 50 parts of anti-skid wearable particle, printing 150 parts of cream and trimerization phosphorus
0.1 part of sour sodium.
Embodiment 10
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment and embodiment 7 the difference is that,
Easy clean protection glaze is prepared by the following raw material as mass fraction: easy clean 60 parts of protection particle, 310 parts of stamp-pad ink, clear frit
10 parts.
Embodiment 11
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment and embodiment 7 the difference is that,
Easy clean protection glaze is prepared by the following raw material as mass fraction: easy clean 150 parts of protection particle, 180 parts of stamp-pad ink, clear frit
50 parts.
Embodiment 12
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, the present embodiment and embodiment 7 the difference is that,
Anti-skid wearable glaze is prepared by the following raw material as mass fraction: 150 parts of anti-skid wearable particle, printing 50 parts of cream
With 0.3 part of sodium tripolyphosphate；
Easy clean protection glaze is prepared by the following raw material as mass fraction: easy clean 150 parts of protection particle, stamp-pad ink 180
Part, 50 parts of clear frit.
The easy clean Ceramic Tiles of anti-skid wearable that above-described embodiment 1-12 is provided, are prepared in accordance with the following steps:
(a) first by blank by the way of wet ball grinding, it is 6.3% that moisture content, which is made, and grain composition is 20 mesh or more
1%, -20~40 mesh 45%, -20~60 mesh 80%, 3% below 100 mesh, surplus is the slurry of -60~100 mesh；Again by slurry
The green body layer with concave-convex effect is pressed by male and female mold；
(b) green body layer is put into dry kiln and carries out primary drying, drying temperature be 130 DEG C, arid cycle 60min；
(c) in the green body layer after primary drying by the way of drenching glaze charity overglaze, formed cover coat, wherein overglaze
Using wet ball grinding mode, leaching glaze is carried out again after ball milling 4.5 hours, and the speed for drenching glaze is 321g/m2；
(d) decoration stamp is carried out by ink-jet printing apparatus on cover coat, forms decorative layer；
(e) anti-skid wearable layer is prepared by silk-screen printing anti-skid wearable glaze in decorative layer；
(f) on anti-skid wearable layer using straight line drench glaze by the way of according to 321g/m2The easy clean protection of leaching glaze speed charity
Glaze prepares easy clean protective layer, wherein it is easy clean protection particle grain composition are as follows: 80~120 mesh 55%, 120~200 mesh 30%,
Remaining is below 200 mesh；
(g) the above-mentioned green body layer being cascading, cover coat, decorative layer, anti-skid wearable layer and easy clean protective layer are put
Enter and carry out redrying in dry kiln, drying temperature is 150 DEG C；
(h) by the green body layer being cascading after redrying, cover coat, decorative layer, anti-skid wearable layer and easy clean
Protective layer is put into kiln and is fired, and firing temperature is 1180 DEG C, firing period 65min, and the easy clean pottery of anti-skid wearable is made
Ceramic tile blank；
(i) the easy clean Ceramic Tiles green body of anti-skid wearable is carried out soft mode brush throwing technique to polish, polishing mold puts in order
It is as follows: 3 kilograms of pressure are added using 4 group of 400 mesh flexible glue profiling mold, 6 group of 600 mesh flexible glue profiling 2 kilograms of pressure of mould pressurizing, 6
800 mesh flexible glue profiling 1 kilogram of pressure of mould pressurizing of group, 6 group of 120 mesh abrasive brush are not pressurized, and 6 group of 200 mesh abrasive brush is not pressurized, and 4
320 mesh abrasive brush of group are not pressurized, and 4 group of 100 mesh sponge mold is not pressurized, and 8 group of 1000 mesh flexible glue profiling mold is not pressurized, linear velocity
10 cm/s.After completing polishing, then upper dumb light wax water, edging is carried out to get the easy clean Ceramic Tiles of anti-skid wearable.
Comparative example 1
This comparative example provides a kind of easy clean Ceramic Tiles of anti-skid wearable, this comparative example and embodiment 7 the difference is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO280 parts, Al2O310 parts, Fe2O30.2 part, TiO2
0.02 part, Na27 parts of O, K20.1 part of O, 2 parts of MgO, 0.02 part of CaO and 0.66 part of loss on ignition.
Comparative example 2
This comparative example provides a kind of easy clean Ceramic Tiles of anti-skid wearable, this comparative example and embodiment 7 the difference is that,
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO250 parts, Al2O335 parts, Fe2O30.5 part, TiO2
0.2 part, Na22 parts of O, K28 parts of O, 0.02 part of MgO, 4 parts of CaO and 0.28 part of loss on ignition.
Comparative example 3
This comparative example provides a kind of easy clean Ceramic Tiles of anti-skid wearable, this comparative example and embodiment 7 the difference is that,
Anti-skid wearable particle is grouped as by the group of following mass fraction meter: SiO250 parts, Al2O340 parts, Al2O310 parts,
Fe2O30.2 part, TiO20.02 part, Na27 parts of O, K20.1 part of O, 2 parts of MgO, 0.02 part of CaO and 0.66 part of loss on ignition；
Easy clean protection particle is grouped as by the group of following mass fraction meter: SiO280 parts, Al2O35 parts, Fe2O30.5 part,
TiO20.2 part, Na29 parts of O, K21 part of O, 0.02 part of MgO, 4 parts of CaO and 0.28 part of loss on ignition.
Comparative example 4
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, this comparative example and embodiment 7 the difference is that,
Not set anti-skid wearable layer.
Comparative example 5
Present embodiments provide a kind of easy clean Ceramic Tiles of anti-skid wearable, this comparative example and embodiment 7 the difference is that,
Not set easy clean protective layer.
The preparation method for the easy clean Ceramic Tiles of anti-skid wearable that comparative example 1-3 is provided is with embodiment 7, and details are not described herein；It is right
The easy clean Ceramic Tiles of anti-skid wearable that ratio 4 provides do not carry out the preparation of anti-skid wearable layer, and other steps are same as Example 7,
Details are not described herein；The easy clean Ceramic Tiles of anti-skid wearable that comparative example 5 provides do not carry out the preparation of easy clean protective layer, and other steps are equal
Same as Example 7, details are not described herein.
The easy clean Ceramic Tiles of anti-skid wearable that above-described embodiment 1-12 is provided and the anti-skid wearable that comparative example 1-5 is provided are easy clean
Ceramic Tiles carry out wear-resisting property, non-skid property and cleaning property of easy-cleaning test, as a result as shown in the table:
The easy clean Ceramic Tiles performance test results table of 1 anti-skid wearable of table
Above-mentioned wear-resisting property is tested according to GB/T3810.7, if sample has no wear trace under 12000 turns, still
By method listed by GB/T3810.14, pollution cannot all be wiped, and wear-resisting grade is set to 4 grades.
Above-mentioned cleaning property of easy-cleaning test is tested according to GB/T23764, and cleaning property of easy-cleaning uses unit area greasy dirt residual volume A
Characterize Ceramic Tiles complexity easy to clean, A≤0.50 be it is easy to clean, 0.50 A≤1.00 < are more easy to clean, 1.00 < A
≤ 1.5 is cleanable, and A > 1.5 is not easy to clean.
As it can be seen from table 1 the easy clean Ceramic Tiles of anti-skid wearable that embodiment 1-7 is provided, wearing coefficient are below 0.5,
Wear-resisting grade is 5 grades, and unit area greasy dirt residual volume is no more than 0.5g/m2, this illustrates the anti-skid wearable that embodiment 1-7 is provided
Not only wear-resistant strength is high for easy clean Ceramic Tiles, not easy to wear, and the anti-skid factor of product is high, effectively people can be avoided to fall down,
The safety of product is improved, while also there is excellent stain resistance, is not easy hiding dirt, it is easy to clean, it is provided for daily arrange
Convenience, meets people for Ceramic Tiles anti-skid wearable and easy clean functional requirement.
By the comparison of embodiment 1-7 and comparative example 1 and 3 as can be seen that comparative example 1 and comparative example 3 provide it is anti-skidding resistance to
The anti-skid factor for grinding easy clean Ceramic Tiles is below 0.5, and wear-resisting grade is 3 grades, this illustrates the SiO by extra fine quality number2、
Al2O3、Fe2O3、TiO2、Na2O、K2O, anti-skid wearable made of anti-skid wearable particle preparation made from MgO and CaO coordinated
Layer can significantly improve the non-skid property and wear-resisting property of the easy clean Ceramic Tiles of anti-skid wearable, so that it is met people resistance to for Ceramic Tiles
The functional requirement of mill and non-skid property.
By the comparison of embodiment 1-7 and comparative example 2 and 3 as can be seen that comparative example 2 and comparative example 3 provide it is anti-skidding resistance to
The cleaning property of easy-cleaning for grinding easy clean Ceramic Tiles is only capable of reaching cleanable standard, and cannot reach standard easy to clean, this explanation is by specific matter
Measure the SiO of number2、Al2O3、Fe2O3、TiO2、Na2O、K2O, easy clean protection particle preparation made from MgO and CaO coordinated and
At easy clean protective layer, the cleaning property of easy-cleaning of the easy clean Ceramic Tiles of anti-skid wearable can be significantly improved, make it be easier to arrange, meet people
For Ceramic Tiles beauty and functional requirement easy to clean.
By the comparison of embodiment 1-7 and comparative example 4 as can be seen that the easy clean Ceramic Tiles of anti-skid wearable that comparative example 4 provides
Anti-skid factor be only 0.31, wear-resisting grade be 2 grades, this explanation by the way that anti-skid wearable is arranged in the easy clean Ceramic Tiles of anti-skid wearable
Layer, can significantly improve its wear-resisting property and non-skid property, people is avoided to fall down, improve the security performance of product.
By the comparison of embodiment 1-7 and comparative example 5 as can be seen that the easy clean Ceramic Tiles of anti-skid wearable that comparative example 5 provides
Belong to and be not easy clean classification, this explanation makes its pollution resistance by the way that easy clean protective layer is arranged in the easy clean Ceramic Tiles of anti-skid wearable
It can be significantly improved with performance easy to clean, so that Ceramic Tiles are easier to arrange, it is also more attractive.
By the comparison of embodiment 1-7 and embodiment 8 and 9 and embodiment 12 as can be seen that the present invention use it is anti-skidding resistance to
Mill glaze is mutually cooperateed with by print cream, sodium tripolyphosphate and the anti-skid wearable particle of extra fine quality number, can more evenly more
Stable cloth imposes on the surface of cover coat, so that the wear-resisting and non-skid property of the easy clean Ceramic Tiles of anti-skid wearable is more excellent.
By the comparison of embodiment 1-7 and embodiment 10 and 11 and embodiment 12 as can be seen that the present invention use it is easy clean
Protection glaze is mutually cooperateed with by stamp-pad ink, clear frit and the easy clean protection particle of extra fine quality number, makes it in anti-skid wearable layer table
Face covers more evenly, so as to be easier to clean-up performance more excellent for the easy clean Ceramic Tiles of anti-skid wearable provided by the invention.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (12)
1. a kind of easy clean Ceramic Tiles of anti-skid wearable, which is characterized in that including set gradually from bottom to up green body layer, cover coat,
Decorative layer, anti-skid wearable layer and easy clean protective layer, the anti-skid wearable layer are prepared by anti-skid wearable glaze, the anti-skid wearable
Glaze is mainly formed by anti-skid wearable particle preparation, and the anti-skid wearable particle is mainly grouped as by the group of following mass fraction meter:
SiO260~70 parts, Al2O320~30 parts, Fe2O30.01~0.1 part, TiO20.1~2 part, Na21~5 part of O, K2O 1~
10 parts, 0.1~1 part of MgO, 0.1~5 part of CaO and 0.1~2 part of loss on ignition, the sum of above-mentioned each component are 100 parts；It is described easy clean
Protective layer is prepared by easy clean protection glaze, and the easy clean protection glaze is mainly formed by easy clean protection particle preparation, described easy clean
Protection particle is mainly grouped as by the group of following mass fraction meter: SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~
0.3 part, TiO20.01~0.1 part, Na24~8 parts of O, K22~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and burning
0.05~0.3 part of vector, the sum of above-mentioned each component is 100 parts.
2. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1, which is characterized in that the anti-skid wearable particle mainly by
The group of following mass fraction meter is grouped as: SiO262~68 parts, Al2O320~25 parts, Fe2O30.05~0.1 part, TiO2
0.5~1.5 part, Na22~3 parts of O, K22~6 parts of O, 0.2~0.8 part of MgO, 2~4 parts of CaO and 0.1~1.5 part of loss on ignition,
The sum of above-mentioned each component is 100 parts；The easy clean protection particle is mainly grouped as by the group of following mass fraction meter: SiO2 62
~68 parts, Al2O318~23 parts, Fe2O30.1~0.2 part, TiO20.02~0.08 part, Na25~7 parts of O, K23~6 parts of O,
0.1~0.2 part of MgO, 1-3 parts of CaO and 0.1~0.3 part of loss on ignition, the sum of above-mentioned each component are 100 parts.
3. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1, which is characterized in that the anti-skid wearable particle mainly by
The group of following mass fraction meter is grouped as: SiO265~66 parts, Al2O322~23 parts, Fe2O30.07~0.09 part, TiO2
0.9~1.1 part, Na22~2.5 parts of O, K24~5 parts of O, 0.3~0.5 part of MgO, 2~3 parts of CaO and loss on ignition 0.7~0.8
Part, the sum of above-mentioned each component is 100 parts；The easy clean protection particle is mainly grouped as by the group of following mass fraction meter: SiO2
66~67 parts, Al2O320~22 parts, Fe2O30.15~0.2 part, TiO20.05~0.07 part, Na25~7 parts of O, K2O 4~5
Part, 0.1~0.15 part of MgO, 1.5~2 parts of CaO and 0.1~0.2 part of loss on ignition, the sum of above-mentioned each component are 100 parts.
4. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1-3, which is characterized in that the anti-skid wearable glaze
Primary raw material further include 90~110 parts of print cream according to the mass fraction and 0.2~0.4 part of sodium tripolyphosphate；Wherein, cream master is printed
It to be grouped as by the group of following mass fraction meter: 2~3 parts of sodium carboxymethylcellulose, 40~60 parts of ethylene glycol and 40~60 parts of water.
5. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1-3, which is characterized in that the easy clean protection glaze
Primary raw material further include 20~40 parts of 230~270 parts of stamp-pad ink, clear frit according to the mass fraction；The stamp-pad ink mainly by with
The group of lower mass fraction meter is grouped as: 1~2 part of sodium carboxymethylcellulose, 20~40 parts of ethylene glycol, 1~5 part of bentonite and water 60
~80 parts.
6. the easy clean Ceramic Tiles of anti-skid wearable according to claim 5, which is characterized in that the clear frit is mainly by following matter
The group of amount number meter is grouped as: 12~16 parts of albite, burns 13~17 parts of talcum, lime stone 7~11 at 20~24 parts of potassium feldspar
Part, 8~12 parts of barium carbonate and 1~5 part of zinc oxide.
7. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1-3, which is characterized in that the anti-skid wearable
The grain composition of grain are as follows: 80~120 mesh 20%~30%, 120~180 mesh 50%~60%, remaining is below 200 mesh.
8. the easy clean Ceramic Tiles of anti-skid wearable according to claim 7, which is characterized in that the specific gravity of the anti-skid wearable particle
For 1.2~1.8g/cm3。
9. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1-3, which is characterized in that the easy clean protection
The grain composition of grain are as follows: 80~120 mesh 50%~60%, 120~200 mesh 20%~30%, remaining is below 200 mesh.
10. the easy clean Ceramic Tiles of anti-skid wearable according to claim 9, which is characterized in that the ratio of the easy clean protection particle
Weight is 1.2~1.4g/cm3。
11. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1-3, which is characterized in that the cover coat by
Overglaze is prepared, and the overglaze is mainly prepared by the raw material of following mass parts: 20~30 parts of potassium feldspar, quartz 15~30
Part, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, 5~15 parts of aluminium oxide, 1~8 part of wollastonite, 0.1~2 part of zinc oxide,
10~30 parts of zirconium silicate, 10~20 parts of column kaolin, 0.1~0.3 part of sodium humate, 0.1~0.3 part of sodium carboxymethylcellulose
With 0.1~0.3 part of sodium tripolyphosphate.
12. the easy clean Ceramic Tiles of anti-skid wearable according to claim 1-3, which is characterized in that the green body layer by
Blank is prepared, and blank is mainly prepared by the following raw material according to the mass fraction: 18~22 parts of quartz sand, potassium sodium sand 12
~18 parts, 16~20 parts of mud of washing, 9~13 parts of white mud, 28~33 parts of potassium sand, 0.5~1.5 part of bentonite and black talc 2~3
Part.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710600631.0A CN107285737B (en) | 2017-07-21 | 2017-07-21 | The easy clean Ceramic Tiles of anti-skid wearable |
| PCT/CN2017/116013 WO2019015237A1 (en) | 2017-07-21 | 2017-12-13 | Anti-slip wear-resistant glaze, anti-slip wear-resistant easy-clean ceramic tile, and preparation method therefor |
| KR1020187032929A KR102189847B1 (en) | 2017-07-21 | 2017-12-13 | Anti-slip abrasion resistant glaze, anti-slip abrasion resistant easy cleaning ceramic tile and its manufacturing method |
| US16/071,888 US11479513B2 (en) | 2017-07-21 | 2017-12-13 | Antiskid and wear-resistant glaze, antiskid, wear-resistant and easy-to-clean ceramic tile and preparation method thereof |
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| CN201710600631.0A CN107285737B (en) | 2017-07-21 | 2017-07-21 | The easy clean Ceramic Tiles of anti-skid wearable |
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| KR102189847B1 (en) | 2017-07-21 | 2020-12-11 | 광동 키토 세라믹 그룹 컴퍼니 리미티드 | Anti-slip abrasion resistant glaze, anti-slip abrasion resistant easy cleaning ceramic tile and its manufacturing method |
| US10475264B2 (en) | 2017-08-14 | 2019-11-12 | Q & K International Group Limited | Application method of Bluetooth low-energy electronic lock based on built-in offline pairing passwords, interactive unlocking method of a Bluetooth electronic lock and electronic lock system |
| CN109989546B (en) * | 2017-12-29 | 2022-03-11 | 上海劲嘉建材科技有限公司 | Antifouling decorative brick and manufacturing method thereof |
| CN108752057B (en) * | 2018-06-29 | 2020-06-05 | 佛山石湾鹰牌陶瓷有限公司 | Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees |
| CN110054510B (en) * | 2019-06-20 | 2019-09-13 | 蒙娜丽莎集团股份有限公司 | A kind of anti-skidding ink-jet Ceramic Tiles of wet water height and preparation method thereof with sagging glaze effect |
| CN111533452B (en) * | 2020-04-24 | 2021-12-07 | 佛山科学技术学院 | Glaze composition and preparation method and application thereof |
| CN112876077B (en) * | 2021-03-05 | 2022-05-27 | 广东新润成陶瓷有限公司 | Protective glaze for matte antique brick, antique brick and preparation method of protective glaze |
| CN115626775A (en) * | 2022-10-20 | 2023-01-20 | 新明珠集团股份有限公司 | Quick-drying printing fancy glaze, preparation method thereof and ceramic tile |
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| CN104261897B (en) * | 2014-09-25 | 2015-12-02 | 佛山市三水新明珠建陶工业有限公司 | A kind of ceramic tile and manufacture method thereof with skidproof effect |
| CN106336198B (en) * | 2016-08-30 | 2019-03-12 | 王爱纯 | A kind of inner container of electric cooker ceramic material and preparation method thereof |
| CN106673435A (en) * | 2016-12-26 | 2017-05-17 | 澧县新鹏陶瓷有限公司 | Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof |
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