CN108752057B - Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees - Google Patents
Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
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- Engineering & Computer Science (AREA)
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- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Compositions Of Oxide Ceramics (AREA)
- Surface Treatment Of Glass (AREA)
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Abstract
The invention relates to a 4-8-degree flexible wear-resistant easy-to-clean antique brick, which sequentially comprises the following components from bottom to top: a blank body, a bottom glaze layer with the glossiness of 2-3 degrees, a printing layer and a surface glaze layer; the overglaze layer comprises a first frit, a matte transparent glaze and wear-resistant particles; the method comprises the following steps of processing a glaze layer by adopting a multi-pass polishing process, and specifically comprises three steps, wherein in step 1, a grinding tool with elastic characteristics is used for polishing, wherein a polishing medium of the grinding tool is an abrasive material bonded by elastic resin, the fineness of the abrasive material is 128 meshes, in step 2, grinding friction is used as a polishing grinding tool for polishing, the fineness of the abrasive material is 320 meshes, in step 3, a grinding sheet is used as a polishing grinding tool for polishing, and the fineness of the abrasive material of the grinding sheet is 500 meshes; the invention greatly improves the wear-resisting strength, the anti-skid property, the anti-dirt absorption and the glossiness of the glaze surface by optimizing the formula and improving the polishing means.
Description
Technical Field
The invention belongs to the field of ceramic building materials, and particularly relates to a soft-surface wear-resistant easy-cleaning antique brick with the surface glossiness of 4-8 degrees.
Background
The ancient-recovering brick has been developed in the Chinese market for several years, and the ancient brick is brought into the mainland of China by the typhoon at first, and the ancient-recovering brick enterprises emerge like bamboo shoots in spring after the rain. Under the large background of intense market competition, ceramic enterprises and technicians pay more attention to the texture, surface hardness and surface flatness of products besides innovations in product design, and the production cost can be reduced in an effort. The ancient-recovering brick is characterized by the fact that the color and appearance of the ancient-recovering brick are embodied by the style returning to nature, the ancient-recovering brick has the characteristics of country flavor, simplicity and roughness, the glaze surface mainly comprises matt, the ancient-recovering brick is wide in application range and has the development trend of wall-ground integration, and the ancient-recovering brick is endowed with higher market value and vitality through innovative design and innovative technology. The antique brick is required to have certain wear resistance, skid resistance and antifouling capacity, and professionals in the field can know that the antique brick has the important influence on the quality of the antique brick, namely the formula of the antique brick and the glazing process are repeated, however, the antique brick in the prior art has low wear resistance, poor antifouling capacity and high glossiness, and causes environmental pollution.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide a soft-surface wear-resistant easy-to-clean antique brick with the surface gloss of 4-8 degrees. The invention starts with the formula of the ancient brick, optimizes the formula, improves the wear-resisting strength of the glaze surface, improves the anti-skid property, prevents dirt absorption, improves the glossiness and the like.
The application provides a gentle wear-resisting easy clean ancient brick of face that surface gloss is 4-8 degrees, it includes from bottom to top in proper order: a blank body, a bottom glaze layer with the glossiness of 2-3 degrees, a printing layer and a surface glaze layer; the overglaze layer comprises a first frit, a matte transparent glaze and wear-resistant particles.
The formula of the frit I comprises the following components in percentage by weight: loss on ignition: 0.13 wt%; silicon dioxide: 49.13 wt%; : aluminum oxide: 18.79 wt%; calcium oxide: 7.5 wt%; magnesium oxide: 3.55 wt%; potassium oxide: 7.87 wt%; sodium oxide: 3.60 wt%; zinc oxide: 3.82 wt%; strontium oxide: 5.61 wt%; the fineness of the wear-resistant particles is 235 meshes, the wear-resistant particles are easily melted in the frit and the matte transparent glaze, and the weight percentage of the wear-resistant particles is 8%.
The retro brick adopts a multi-pass polishing process after a glaze layer is sprayed, and specifically comprises three steps, wherein in the step 1, a grinding tool with elastic characteristics is used for polishing, wherein a grinding medium of the grinding tool is an abrasive material bonded by elastic resin, the fineness of the abrasive material is 128 meshes, in the step 2, grinding friction is used as a polishing grinding tool for polishing, the fineness of the abrasive material of the grinding friction is 320 meshes, in the step 3, a grinding sheet is used as a polishing grinding tool for polishing, and the fineness of the abrasive material of the grinding sheet is 500 meshes.
Further, the base coat layer with the glossiness of 2-3 degrees comprises the following components: loss on ignition: 5.02 wt%; silicon dioxide: 35.45 wt%; aluminum oxide: 35.96 wt%; calcium oxide: 10.44 wt%; magnesium oxide: 3.67 wt%; potassium oxide: 2.59 wt%; sodium oxide: 1.29 wt%; zinc oxide: 1.02 wt%; zirconium oxide: 4.56 wt%.
Further, the printing layer is formed by printing ceramic ink on the ground glaze layer according to a color pattern prepared in advance through an ink-jet printer to form a decorative pattern.
Further, the grinding wiper is provided with bristles for grinding, and the bristles are made of hard plastics and grinding materials.
Further, the polishing medium of the grinding sheet is an abrasive combined with fibers.
Further, the overglaze layer is uniformly distributed with rod-shaped anorthite crystals, and the length of the overglaze layer is 12-15 mu m.
Further, the wear-resistant particles comprise the following components in percentage by weight: loss on ignition: 0.96-1.05 wt%; silicon dioxide: 51.06-53 wt%, and aluminum oxide: 10-19 wt%, calcium oxide: 7-12 wt%, magnesium oxide: 0.2 to 0.4 wt%, potassium oxide: 1-3.1 wt%, sodium oxide: 0.5 to 3.5 wt%, zinc oxide: 1-6 wt%; strontium oxide: 3-5.2 wt%, wherein the ratio of the alumina to the silica is 1: 5 or 2: 5, the wear-resistant particles are processed into particles with the fineness of 80-100 or 140-160, and the addition amount of the wear-resistant particles is preferably 9-11 when the glaze is used.
Further, the wear resistant granules are produced from a frit feedstock and a green stock by heating the frit feedstock to a molten state; microcrystallizing the frit raw material in a molten state at a suitable temperature; and performing water quenching treatment on the microcrystallized frit raw material to obtain the second frit.
Further, crushing the second frit to enable the second frit to reach a certain ball milling fineness; and mixing and ball-milling the crushed frit II and the raw material, and achieving the use requirement of wear-resistant particles after ball milling.
Has the advantages that: compared with the prior art, the soft-surface wear-resistant easy-cleaning antique brick effectively combines weak luster, transparency, wear resistance, smooth and fine texture and skid resistance, and is suitable for various application occasions. Compared with the common glazed brick, the soft-surface wear-resistant porcelain antique brick has the following characteristics: the surface glossiness is 4-8 degrees, the glass has soft glossiness under the side light, and the front view basically has no glossiness; the touch feeling is smooth and fine, and the surface has no obvious defects of pinholes, glaze bubbles and the like; the wear resistance reaches 4-5 grades; the color development is bright and the color is strong.
The invention can be applied to glazed tiles, marble archaized tiles and other products or other similar ceramic tile products besides the archaized tiles.
Detailed Description
Technical solutions between various embodiments may be combined with each other, but must be realized by those skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention.
In order that the present invention may be further understood, there shall now be described by way of illustration and example only, the invention being with reference to the accompanying illustrative embodiments, it being understood that the same is by way of illustration and not by way of limitation, and that the following amounts are by weight unless otherwise specified.
The embodiment of the invention provides a flexible-surface wear-resistant easy-cleaning antique brick. The preparation steps of the soft-surface wear-resistant porcelain antique brick can comprise: collecting raw materials, crushing, preparing materials by a forklift, ball-milling by a wet method, sieving to remove iron, spraying to prepare powder, ageing, forming, drying, applying ground coat, ink-jet printing, spraying overglaze, sintering, polishing a plurality of procedures and packaging in stages.
Example 1
The application provides a gentle wear-resisting easy clean ancient brick of face that surface gloss is 4-8 degrees, it includes from bottom to top in proper order: a blank body, a bottom glaze layer with the glossiness of 2-3 degrees, a printing layer and a surface glaze layer; the overglaze layer comprises a frit, a matte transparent glaze and wear-resistant particles.
The frit comprises the following formula components in percentage by weight: loss on ignition: 0.13 wt%; silicon dioxide: 49.13 wt%; aluminum oxide: 18.79 wt%; calcium oxide: 7.5 wt%; magnesium oxide: 3.55 wt%; potassium oxide: 7.87 wt%; sodium oxide: 3.60 wt%; zinc oxide: 3.82 wt%; strontium oxide: 5.61 wt%; the fineness of the wear-resistant particles is 235 meshes, the wear-resistant particles are easily melted in the frit and the matte transparent glaze, and the weight percentage of the wear-resistant particles is 8%; the fineness of the wear-resistant particles is 235 meshes, the wear-resistant particles are easily melted in the frit and the matte transparent glaze, and the weight percentage of the wear-resistant particles is 8%.
Further, the base coat layer with the glossiness of 2-3 degrees comprises the following components: loss on ignition: 5.02 wt%; silicon dioxide: 35.45 wt%; aluminum oxide: 35.96 wt%; calcium oxide: 10.44 wt%; magnesium oxide: 3.67 wt%; potassium oxide: 2.59 wt%; sodium oxide: 1.29 wt%; zinc oxide: 1.02 wt%; zirconium oxide: 4.56 wt%.
After applying the ground coat, carrying out ink-jet printing to print a printing layer, wherein the printing layer is formed by printing ceramic ink on the ground coat layer according to a color pattern prepared in advance through an ink-jet printer to form a decorative pattern. Preferably, the multicolor ink-jet printing of pattern colors is performed by a multichannel ink-jet machine. After inkjet printing, drying, e.g., electro-drying, may be performed; the drying temperature can be 220 ℃; the drying time may be 80 seconds.
Then, uniformly applying a surface glaze layer on the surface of the color pattern brick; the overglaze layer may be transparent, which may preserve the transparency of the color.
The retro brick adopts a multi-pass polishing process after a glaze layer is sprayed, and specifically comprises three steps, wherein in the step 1, a grinding tool with elastic characteristics is used for polishing, wherein a grinding medium of the grinding tool is an abrasive material bonded by elastic resin, the fineness of the abrasive material is 128 meshes, in the step 2, grinding friction is used as a polishing grinding tool for polishing, the fineness of the abrasive material of the grinding friction is 320 meshes, in the step 3, a grinding sheet is used as a polishing grinding tool for polishing, and the fineness of the abrasive material of the grinding sheet is 500 meshes.
Preferably, the grinding brush is provided with bristles for grinding, and the bristles are made of hard plastics and grinding materials.
Preferably, the polishing medium of the abrasive sheet is an abrasive material combined with fibers.
Example 2
In addition to the above features, further research on the wear-resistant particles is carried out in this embodiment, and further, the wear-resistant particles are prepared according to the following components: loss on ignition: 0.96-1.05 wt%, silica: 51.06-53 wt%, and aluminum oxide: 10-19 wt%, calcium oxide: 7-12 wt%, magnesium oxide: 0.2 to 0.4 wt%, potassium oxide: 1-3.1 wt%, sodium oxide: 0.5 to 3.5 wt%, zinc oxide: 1-6 wt%; strontium oxide: 3-5.2 wt%, wherein the ratio of the alumina to the silica is 1: 5 or 2: 5, the wear-resistant particles are processed into particles with the fineness of 80-100 or 140-160, and the addition amount of the wear-resistant particles is preferably 9-11 when the glaze is used.
Further, the wear resistant granules are produced from a frit feedstock and a green stock by heating the frit feedstock to a molten state; microcrystallizing the frit raw material in a molten state at a suitable temperature; and performing water quenching treatment on the microcrystallized frit raw material to obtain the second frit.
Further, crushing the second frit to enable the second frit to reach a certain ball milling fineness; and mixing and ball-milling the crushed frit II and the raw material, and achieving the use requirement of wear-resistant particles after ball milling.
XRD test and scanning electron microscope test show that the overglaze layer is uniformly distributed with rod-shaped anorthite crystals with the length of 12-15 μm; due to the optimization of the components and the proportion of the formula, the anorthite is easier to wash out from the glaze, the size distribution is uniform, and further the light diffuse reflection is caused, so that the glossiness of 4-8 degrees is realized.
And (3) performance test results:
the abrasion resistance test is carried out according to the regulation of GB/T3810.7, and after 12000 turns of abrasion: (1) if no visible abrasion exists on the surface of the product, then testing according to the regulation of GB/T3810.14, if the pollution cannot be erased, the abrasion-resistant grade is 4 grade, and if the pollution can be erased, the abrasion-resistant grade is 5 grade; (2) if there is visible wear on the surface of the product, the abrasion resistance rating is 3.
The performance test results show that the anti-skid coefficients of the embodiments 1-2 are all higher than 0.5, the wear-resistant grades are all 5 grades, the easy-cleaning performance adopts the oil stain residual amount A per unit area to represent the difficulty of easy cleaning of the ceramic tile, and A is less than or equal to 0.50, so that the ceramic tile is easy to clean, and the anti-skid wear-resistant ceramic tile provided by the invention has good anti-skid performance, wear resistance and easy cleaning performance.
The invention has the following beneficial effects:
1. compared with the common glazed brick, the soft-surface wear-resistant porcelain antique brick has the following characteristics: the surface glossiness is 4-8 degrees, the glass has soft glossiness under the side light, and the front view basically has no glossiness; the touch feeling is smooth and fine, and the surface has no obvious defects of pinholes, glaze bubbles and the like; in order to increase the durability of the product, the wear resistance reaches 4 grades;
2. the application range is wide: the invention is not influenced by environmental factors, and can be widely applied to various interior and exterior walls and ground decoration;
3. easy cleaning: the retro ceramic tile is completely sintered, the water absorption is controlled within 0.5%, and through the use of high-proportion pre-sintering frits, the sintered exhaust holes are reduced, the surface antifouling effect is good, and the tile is easy to clean;
4. durable: the invention has stable performance, less time and environment influence factors, high wear resistance, long service life and wide market economic benefit, and can keep new feeling for a long time.
Although specific embodiments of the invention have been described above, it will be understood by those skilled in the art that the specific embodiments described are illustrative only and are not limiting upon the scope of the invention, and that equivalent modifications and variations can be made by those skilled in the art without departing from the spirit of the invention, which is to be limited only by the appended claims.
Claims (5)
1. The utility model provides a gentle wear-resisting easy clean ancient brick of face that surface gloss is 4-8 degrees, ancient brick includes from bottom to top in proper order: a blank body, a bottom glaze layer with the glossiness of 2-3 degrees, a printing layer and a surface glaze layer; the overglaze layer comprises a first frit, a matte transparent glaze and wear-resistant particles; the formula of the frit I comprises the following components: loss on ignition: 0.13 wt%; silicon dioxide: 49.13 wt%; : aluminum oxide: 18.79 wt%; calcium oxide: 7.5 wt%; magnesium oxide: 3.55 wt%; potassium oxide: 7.87 wt%; sodium oxide: 3.60 wt%; zinc oxide: 3.82 wt%; strontium oxide: 5.61 wt%; the fineness of the wear-resistant particles is 235 meshes, the wear-resistant particles are easily melted in the frit and the matte transparent glaze, and the weight percentage of the wear-resistant particles is 8%; the method is characterized in that the retro brick is fired after a glaze layer is sprayed, a multi-pass polishing process is adopted, and the method specifically comprises three steps, wherein in the step 1, a grinding tool with elastic characteristics is used for polishing, wherein a grinding medium of the grinding tool is an abrasive material bonded by elastic resin, the fineness of the abrasive material is 128 meshes, in the step 2, grinding friction is used as a polishing grinding tool for polishing, the fineness of the abrasive material of the grinding friction is 320 meshes, in the step 3, a grinding sheet is used as a polishing grinding tool for polishing, and the fineness of the abrasive material of the grinding sheet is 500 meshes;
after the surface glaze layer is fired, rod-shaped anorthite crystals are uniformly distributed on the surface, and the length of the anorthite crystals is 12-15 mu m.
2. The soft-surface abrasion-resistant easy-to-clean antique brick with the surface gloss of 4-8 degrees according to claim 1, wherein the ground glaze layer with the gloss of 2-3 degrees comprises the following components: loss on ignition: 5.02 wt%; silicon dioxide: 35.45 wt%; aluminum oxide: 35.96 wt%; calcium oxide: 10.44 wt%; magnesium oxide: 3.67 wt%; potassium oxide: 2.59 wt%; sodium oxide: 1.29 wt%; zinc oxide: 1.02 wt%; zirconium oxide: 4.56 wt%.
3. The flexible wear-resistant easy-to-clean ancient brick with the surface gloss of 4-8 degrees as claimed in claim 2, wherein the printed layer is formed by printing ceramic ink on the ground coat layer according to a pre-prepared color pattern through an ink-jet printer to form a decorative pattern.
4. The soft wear-resistant easy-to-clean antique brick with the surface gloss of 4-8 degrees according to claim 1, wherein: wherein, the grinding brush is provided with bristles for grinding, and the bristles are made of hard plastics and grinding materials.
5. The soft wear-resistant easy-to-clean antique brick with the surface gloss of 4-8 degrees according to claim 1, wherein: the polishing medium of the grinding sheet is an abrasive combined with fibers.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810721310.0A CN108752057B (en) | 2018-06-29 | 2018-06-29 | Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees |
| PCT/CN2018/114112 WO2020000850A1 (en) | 2018-06-29 | 2018-11-06 | 4-8 degree soft-surface wear-resistant and easy-to-clean rustic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810721310.0A CN108752057B (en) | 2018-06-29 | 2018-06-29 | Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees |
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| Publication Number | Publication Date |
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| CN108752057A CN108752057A (en) | 2018-11-06 |
| CN108752057B true CN108752057B (en) | 2020-06-05 |
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| WO (1) | WO2020000850A1 (en) |
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| CN109455936B (en) * | 2019-01-07 | 2021-07-23 | 佛山市东鹏陶瓷有限公司 | Non-slip matt glaze with silk texture, preparation method and ceramic tile using non-slip matt glaze |
| CN111233333B (en) * | 2020-03-13 | 2021-10-22 | 东莞市唯美陶瓷工业园有限公司 | Anti-slip glaze, anti-slip ceramic tile and preparation method thereof |
| CN111423124B (en) * | 2020-03-23 | 2022-05-20 | 广西欧神诺陶瓷有限公司 | Wear-resistant transparent glaze, wear-resistant polished glazed brick and preparation method thereof |
| CN112225454B (en) * | 2020-09-30 | 2022-03-15 | 广东清远蒙娜丽莎建陶有限公司 | Low-glossiness high-stain-resistance composite glaze, granite ceramic tile using composite glaze and preparation method of granite ceramic tile |
| CN112279516A (en) * | 2020-12-19 | 2021-01-29 | 佛山市玉矶材料科技有限公司 | High-wear-resistance and high-transparency satin glaze, preparation method and large-size satin rock plate |
| CN113955942B (en) * | 2021-12-22 | 2022-03-15 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
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| CN103030298B (en) * | 2012-12-31 | 2015-07-15 | 佛山欧神诺陶瓷股份有限公司 | Once-firing colored crystalline glass ceramic composite brick and production method |
| CN105293912B (en) * | 2015-11-20 | 2017-08-29 | 佛山市三水新明珠建陶工业有限公司 | A kind of glaze brick producing process with matte surface |
| CN107344814B (en) * | 2017-07-11 | 2020-02-07 | 佛山市华力达材料科技有限公司 | Soft light brick surface glaze and soft light brick |
| CN107285737B (en) * | 2017-07-21 | 2019-09-06 | 广东金意陶陶瓷集团有限公司 | The easy clean Ceramic Tiles of anti-skid wearable |
| CN107963814B (en) * | 2017-11-16 | 2021-05-07 | 蒙娜丽莎集团股份有限公司 | Composite glaze, composite glaze slip and 4-8 degree soft surface wear-resistant porcelain archaized brick |
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- 2018-11-06 WO PCT/CN2018/114112 patent/WO2020000850A1/en active Application Filing
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| Publication number | Publication date |
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| CN108752057A (en) | 2018-11-06 |
| WO2020000850A1 (en) | 2020-01-02 |
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