CN107285812B - Easy clean Ceramic Tiles - Google Patents
Easy clean Ceramic Tiles Download PDFInfo
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- CN107285812B CN107285812B CN201710605577.9A CN201710605577A CN107285812B CN 107285812 B CN107285812 B CN 107285812B CN 201710605577 A CN201710605577 A CN 201710605577A CN 107285812 B CN107285812 B CN 107285812B
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- ceramic tiles
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- 239000000919 ceramic Substances 0.000 title claims abstract description 65
- 239000002245 particle Substances 0.000 claims abstract description 53
- 239000008187 granular material Substances 0.000 claims abstract description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 39
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 34
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 34
- 239000005995 Aluminium silicate Substances 0.000 claims description 29
- 235000012211 aluminium silicate Nutrition 0.000 claims description 29
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 29
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000002994 raw material Substances 0.000 claims description 21
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 18
- 239000011787 zinc oxide Substances 0.000 claims description 17
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 16
- 239000010453 quartz Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052681 coesite Inorganic materials 0.000 claims description 13
- 229910052593 corundum Inorganic materials 0.000 claims description 13
- 229910052906 cristobalite Inorganic materials 0.000 claims description 13
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052682 stishovite Inorganic materials 0.000 claims description 13
- 229910052905 tridymite Inorganic materials 0.000 claims description 13
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 13
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 12
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 12
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 12
- 239000000454 talc Substances 0.000 claims description 12
- 235000012222 talc Nutrition 0.000 claims description 12
- 229910052623 talc Inorganic materials 0.000 claims description 12
- 239000000440 bentonite Substances 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 235000019738 Limestone Nutrition 0.000 claims description 8
- 229910052656 albite Inorganic materials 0.000 claims description 8
- 239000006028 limestone Substances 0.000 claims description 8
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 5
- 239000010434 nepheline Substances 0.000 claims description 4
- 229910052664 nepheline Inorganic materials 0.000 claims description 4
- 239000010410 layer Substances 0.000 claims 6
- 238000010020 roller printing Methods 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- 230000003670 easy-to-clean Effects 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 7
- 230000003373 anti-fouling effect Effects 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000012423 maintenance Methods 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 24
- 239000000203 mixture Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 13
- 239000011449 brick Substances 0.000 description 9
- 239000004576 sand Substances 0.000 description 9
- 238000005034 decoration Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 238000007641 inkjet printing Methods 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000010835 comparative analysis Methods 0.000 description 3
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000010427 ball clay Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 210000000498 stratum granulosum Anatomy 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention belongs to ceramic technology fields, are related to a kind of easy clean Ceramic Tiles.Easy clean Ceramic Tiles provided by the invention successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer from bottom to top, and the easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；The easy clean protection glaze includes the component of following mass fraction: easy clean 90~110 parts of protection particle, 230~270 parts of stamp-pad ink and 20~40 parts of clear frit.Easy clean Ceramic Tiles provided by the invention have the excellent easy clean property of anti-pollution, and anti-fouling performance is good, easy to clean, convenient for daily maintenance and arrange, and have been effectively relieved existing for existing Ceramic Tiles and have been easy hiding dirt, have been not easy the technical issues of cleaning.
Description
Technical field
The invention belongs to ceramics to fill technical field, and in particular to a kind of easy clean Ceramic Tiles.
Background technique
With the rapid development of science and technology, people's lives are maked rapid progress, while having been cast one and having been followed the fashion, and are shown
The epoch of individual character, architectural decoration material field are no exception.Ceramic Tiles are with its superior performance and decorative effect, by increasingly
The favor of more consumers, and be widely used in people's daily life.And ceramic antique bricks are in recent years popular rise
A kind of building decoration materials come, the pattern that it has had both the splendid and tile of polished bricks is rich and varied, have the modern times or
Pseudo-classic charm, and it is personalized many advantages, such as, be received by the market in recent years and consumer like.
With the continuous utilization of the fast development of architectural pottery and new technology, new material, new process etc., building has been pushed
Ceramic product constantly develops towards better direction, and architectural pottery product has been broken through is only limitted to durable and decoration model in the past
It encloses, develops towards the direction of functional diversities, and then push the continuous development for building potler's industry and ceramic product.However, existing
Ceramic product development process in, pay attention to how to improve the intensity of product, wear-resisting durability and rich in color and pattern more
Good etc. the research and development of texture.It is difficult for removing surface present in existing ceramic product, hiding is dirty, anti-fouling effect is poor, when
Between long product blackening the defects of, do not find very good solution method also.Therefore, for the easy clean property of anti-pollution of raising ceramic product
Research and development and design there are also considerable room for improvement.
In consideration of it, the present invention is specifically proposed.
Summary of the invention
The purpose of the present invention is to provide a kind of easy clean Ceramic Tiles, have the easy clean property of excellent anti-pollution, i.e. anti-fouling performance
It is good, it is easy to clean, greatly promote product quality.
To achieve the above object, the technical solution adopted by the present invention are as follows:
The present invention provides a kind of easy clean Ceramic Tiles, the easy clean Ceramic Tiles successively include from bottom to top green body layer, cover coat,
Printed layer and easy clean protection dry granule layer, the easy clean protection dry granule layer are formed by the easy clean protection glaze of charity；
The easy clean protection glaze includes the component of following mass fraction: easy clean 90~110 parts of protection particle, stamp-pad ink 230~
270 parts and 20~40 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO20.01~0.1 part, Na2O 4~
8 parts, K22~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and 0.05~0.3 part of loss on ignition.
As further preferred technical solution, the easy clean protection glaze includes the component of following mass fraction: easy clean protection
92~108 parts of particle, 240~260 parts of stamp-pad ink and 22~38 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO265~68 parts, Al2O318~22 parts, Fe2O30.12~0.22 part, TiO20.02~0.08 part, Na2O
5~7 parts, K23~5 parts of O, 0.1~0.2 part of MgO, 1~2 part of CaO and 0.1~0.2 part of loss on ignition.
As further preferred technical solution, the easy clean protection glaze includes the component of following mass fraction: easy clean protection
95~105 parts of particle, 245~250 parts of stamp-pad ink and 28~32 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO266~67 parts, Al2O320~21 parts, Fe2O30.15~0.2 part, TiO20.04~0.07 part, Na2O
5.5~6.5 parts, K24~4.8 parts of O, 0.12~0.15 part of MgO, 1.5~1.8 parts of CaO and 0.14~0.18 part of loss on ignition.
As further preferred technical solution, the stamp-pad ink is mainly made of the component of following mass fraction: carboxymethyl is fine
Plain 1~2 part of the sodium of dimension, 20~40 parts of ethylene glycol, 1~5 part of bentonite and 60~80 parts of water.
As further preferred technical solution, the clear frit is mainly made of the component of following mass fraction:
12~16 parts of albite, 20~24 parts of potassium feldspar, 6~10 parts of kaolin, 10~14 parts of calcined kaolin, quartz 10
~14 parts, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and 1~5 part of zinc oxide.
As further preferred technical solution, the specific gravity of the easy clean protection glaze is 1.2~1.5g/cm3。
As further preferred technical solution, the grain composition of the easy clean protection particle are as follows: 80 mesh~120 mesh are 50%
~60%, 120~200 mesh are 20%~30%, remaining is below 200 mesh.
As further preferred technical solution, the green body layer is the green body layer with convex-concave surface.
As further preferred technical solution, the cover coat is mainly prepared by overglaze, the overglaze mainly by with
The raw material of lower mass parts is prepared:
20~30 parts of potassium feldspar, 15~30 parts of quartz, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, aluminium oxide 5~
15 parts, 1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate
0.1~0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and 0.1~0.3 part of sodium tripolyphosphate.
As further preferred technical solution, the printed layer includes one or multi-channel lamina printing decoration, one or multi-channel roller
Cylinder stamp and one or more of ink-jet printed combination.
Compared with prior art, the beneficial effects of the present invention are:
Easy clean Ceramic Tiles provided by the invention pass through green body layer, the cooperation of cover coat, printed layer and easy clean protection dry granule layer
The reasonable cooperation of setting, the especially easy clean each raw material protected in dry granule layer and its component has so that the Ceramic Tiles are finer and close
The easy clean property of excellent anti-pollution, anti-fouling performance is good, easy to clean, convenient for daily maintenance with arrange, be effectively relieved existing
It is dirty that it is easy hiding existing for Ceramic Tiles, is not easy the technical issues of cleaning.
At the same time, Ceramic Tiles glossiness also with higher, solid layer feeling is strong, and clarity is good, surface transparency
Height, advantage rich in color, pattern texture is good greatly improve the product of product so that product has good comprehensive performance
Matter.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiments and examples, but this field skill
Art personnel will be understood that following embodiments and embodiment are merely to illustrate the present invention, and are not construed as limiting model of the invention
It encloses.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.Actual conditions person is indicated, according to normal conditions or manufacturer suggests
Condition carry out.Reagents or instruments used without specified manufacturer is the conventional products that can be obtained by commercially available purchase.
Present embodiment provides a kind of easy clean Ceramic Tiles, and the easy clean Ceramic Tiles successively include green body layer, face from bottom to top
Glaze layer, printed layer and easy clean protection dry granule layer, the easy clean protection dry granule layer are formed by the easy clean protection glaze of charity；
The easy clean protection glaze includes the component of following mass fraction: easy clean 90~110 parts of protection particle, stamp-pad ink 230~
270 parts and 20~40 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO20.01~0.1 part, Na2O 4~
8 parts, K22~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and 0.05~0.3 part of loss on ignition.
In view of ceramic brick product in the prior art, that there is surfaces is not fine and close enough, and flat and smooth degree is poor, and it is dirty to be easy hiding, anti-
Dirty effect is poor, the defect of removing surface difficulty, and present embodiment provides a kind of easy clean property of anti-pollution that can effectively provide product
Easy clean Ceramic Tiles, and then the quality of Ceramic Tiles is promoted, promote application of the Ceramic Tiles in building field.
Present embodiment mainly in such a way that the easy clean protection glaze of stamp layer surface charity forms easy clean protection dry granule layer,
Enable the easy clean protection dry granule layer uniform fold in ceramic brick surface and effectively fill up the gap of ceramic brick surface, improves
The compactness of Ceramic Tiles, and then the stain resistance of product is improved, the easy clean property of excellent anti-pollution is made it have, it is easy to clean, it is convenient for
Daily maintenance with arrange, while ceramic brick surface transparency is high, glossiness is high, clarity is good, both beautiful and practical.
In some specific embodiments, based on mass fraction, the typical but non-limiting content of easy clean protection particle
Are as follows: 90 parts, 91 parts, 92 parts, 93 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 99 parts, 100 parts, 101 parts, 102 parts, 103 parts,
104 parts, 105 parts, 106 parts, 107 parts, 108 parts, 109 parts or 110 parts.The typical but non-limiting content of stamp-pad ink are as follows: 230 parts,
235 parts, 240 parts, 245 parts, 250 parts, 255 parts, 260 parts, 265 parts or 270 parts.The typical but non-limiting content of clear frit
Are as follows: 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34
Part, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts or 40 parts.
The easy clean protection particle that present embodiment provides, should be able to preferably melt mutually, and can guarantee one at high temperature
Fixed granular sensation can be uniformly covered on product surface, and the clear frit added can fill up void among particles, and guarantee certain
High temperature viscosity, reach preferable antifouling, wear-resisting and easy clean and other effects together with temperature resistant transparent light dry granular.
The easy clean protection glaze that present embodiment provides mainly is made of easy clean protection particle, stamp-pad ink and clear frit, on the one hand,
Above-mentioned easy clean protection particle melting temperature with higher and wider firing range, can at a temperature of 1175~1185 DEG C,
Preferably melts and have higher gloss degree to guarantee the easy clean purpose of Ceramic Tiles；On the other hand, it is easy to primarily serve raising for above-mentioned stamp-pad ink
It is clean protection glaze high temperature viscosity effect, make its be unlikely to melt at high temperature it is flat, to improve the stereoscopic effect of ceramic brick surface；This
Outside, above-mentioned clear frit primarily serve improve it is above-mentioned it is easy clean protection glaze transparency and glossiness effect, enhance product texture and
Solid layer feeling.
In some specific embodiments, based on mass fraction, SiO2Typical but non-limiting content are as follows: 60 parts,
61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 66 parts, 67 parts, 68 parts, 69 parts or 70 parts.Al2O3Typical but non-limiting content
Are as follows: 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts or 25 parts.Fe2O3It is typical but non-limiting
Content are as follows: 0.1 part, 0.12 part, 0.14 part, 0.15 part, 0.16 part, 0.18 part, 0.2 part, 0.22 part, 0.24 part, 0.25 part,
0.26 part, 0.28 part or 0.3 part.TiO2Typical but non-limiting content are as follows: 0.01 part, 0.02 part, 0.03 part, 0.04 part,
0.05 part, 0.06 part, 0.07 part, 0.08 part, 0.09 part or 0.1 part.Na2The typical but non-limiting content of O are as follows: 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts or 8 parts.K2The typical but non-limiting content of O are as follows: 2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts or 6 parts.The typical but non-limiting content of MgO are as follows: 0.05 part, 0.1 part, 0.15
Part, 0.2 part, 0.25 part or 0.3 part.The typical but non-limiting content of CaO are as follows: 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts or 3
Part.The typical but non-limiting content of loss on ignition are as follows: 0.05 part, 0.1 part, 0.15 part, 0.2 part, 0.25 part or 0.3 part.
It should be noted that loss on ignition (Loss on ignition, be abbreviated as LOI) is common technology in ceramic field
Term understands, the weight ratio before weight and firing after referring to raw material calcination according to the routine of this field.
Present embodiment is improved by being equipped with for green body layer, cover coat, printed layer and easy clean protection dry granule layer
The easy clean property of the anti-pollution of product, solid layer feeling, glossiness and transparency, so that the ceramic product is with good comprehensive
Can, intensity with higher and hardness, pattern texture is strong, good decorating effect, it is durable while there is good stain resistance,
It is easy to clean.In addition, when above-mentioned easy clean protection glaze and easy clean protection particle are formed and matched using said components, synergistic effect
More preferably, the easy clean property of anti-pollution of product can be enhanced.
In a kind of optional embodiment, the easy clean protection glaze includes the component of following mass fraction: easy clean protection
92~108 parts of particle, 240~260 parts of stamp-pad ink and 22~38 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO265~68 parts, Al2O318~22 parts, Fe2O30.12~0.22 part, TiO20.02~0.08 part, Na2O
5~7 parts, K23~5 parts of O, 0.1~0.2 part of MgO, 1~2 part of CaO and 0.1~0.2 part of loss on ignition.
In a kind of optional embodiment, the easy clean protection glaze includes the component of following mass fraction: easy clean protection
95~105 parts of particle, 245~250 parts of stamp-pad ink and 28~32 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO266~67 parts, Al2O320~21 parts, Fe2O30.15~0.2 part, TiO20.04~0.07 part, Na2O
5.5~6.5 parts, K24~4.8 parts of O, 0.12~0.15 part of MgO, 1.5~1.8 parts of CaO and 0.14~0.18 part of loss on ignition.
By reasonably adjusting proportion and the easy clean each group for protecting particle to be included in easy clean protection glaze between each component
Divide content, the stain resistance of Ceramic Tiles can be further increased, convenient for daily cleaning and maintenance, and there is higher gloss
Degree, transparency, solid layer feeling and pattern texture.
In a kind of optional embodiment, the stamp-pad ink is mainly made of the component of following mass fraction: carboxymethyl is fine
Plain 1~2 part of the sodium of dimension, 20~40 parts of ethylene glycol, 1~5 part of bentonite and 60~80 parts of water.
Preferably, the stamp-pad ink is mainly made of the component of following mass fraction: 1.2~1.8 parts of sodium carboxymethylcellulose,
25~35 parts of ethylene glycol, 2~4 parts of bentonite and 65~75 parts of water.
In some specific embodiments, based on mass fraction, sodium carboxymethylcellulose is typical but non-limiting to be contained
Amount are as follows: 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts or 2 parts.Ethylene glycol allusion quotation
Type but unrestricted content are as follows: 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts,
31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts or 40 parts.The typical but non-limiting content of bentonite
It is 1 part, 2 parts, 3 parts, 4 parts or 5 parts.The typical but non-limiting content of water are as follows: 60 parts, 61 parts, 62 parts, 63 parts, 64 parts, 65
Part, 66 parts, 67 parts, 68 parts, 69 parts, 70 parts, 71 parts, 72 parts, 73 parts, 74 parts, 75 parts, 76 parts, 77 parts, 78 parts, 79 parts or 80
Part.
The stamp-pad ink that present embodiment provides primarily serves the effect for improving easy clean protection glaze high temperature viscosity, makes it at high temperature
Be unlikely to melt it is flat, to improve the stereoscopic effect of ceramic brick surface.
In a kind of optional embodiment, the clear frit is mainly made of the component of following mass fraction:
12~16 parts of albite, 20~24 parts of potassium feldspar, 6~10 parts of kaolin, 10~14 parts of calcined kaolin, quartz 10
~14 parts, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and 1~5 part of zinc oxide.
Preferably, the clear frit is mainly made of the component of following mass fraction: 13~15 parts of albite, potassium feldspar 21
~23 parts, 7~9 parts of kaolin, 11~13 parts of calcined kaolin, quartz 11~13 parts, burn 14~16 parts of talcum, lime stone 8~
10 parts, 9~11 parts of barium carbonate and 2~4 parts of zinc oxide.
In some specific embodiments, based on mass fraction, the typical but non-limiting content of albite are as follows: 12
Part, 12.5 parts, 13 parts, 13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts or 16 parts.Potassium feldspar is typical but non-limiting to be contained
Amount are as follows: 20 parts, 21 parts, 22 parts, 23 parts or 24 parts.The typical but non-limiting content of kaolin are as follows: 6 parts, 6.5 parts, 7 parts, 7.5
Part, 8 parts, 8.5 parts, 9 parts, 9.5 parts or 10 parts.The typical but non-limiting content of calcined kaolin are as follows: 10 parts, 10.5 parts, 11
Part, 11.5 parts, 12 parts, 12.5 parts, 13 parts, 13.5 parts or 14 parts.The typical but non-limiting content of quartz are as follows: 10 parts, 10.5
Part, 11 parts, 11.5 parts, 12 parts, 12.5 parts, 13 parts, 13.5 parts or 14 parts.It is typical but non-limiting to burn talcum are as follows: 13 parts,
13.5 parts, 14 parts, 14.5 parts, 15 parts, 15.5 parts, 16 parts, 16.5 parts or 17 parts.Lime stone is typical but non-limiting are as follows: 7
Part, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, 10 parts, 10.5 parts or 11 parts.Barium carbonate is typical but non-limiting are as follows: 8 parts,
8.5 parts, 9 parts, 9.5 parts, 10 parts, 10.5 parts, 11 parts, 11.5 parts or 12 parts.Zinc oxide is typical but non-limiting are as follows: 1 part,
1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts.
The clear frit that present embodiment provides primarily serves the effect for improving easy clean protection glaze transparency and glossiness；Using
The clear frit being formulated above, transparency is higher, color development ability is more preferable, and brightness is high, it is ensured that the pattern of product and clear
Degree.
In a kind of optional embodiment, the specific gravity of the easy clean protection glaze is 1.2~1.5g/cm3。
Preferably, the specific gravity of the easy clean protection glaze is 1.25~1.35g/cm3。
In a specific embodiment, optionally, the specific gravity of easy clean protection glaze is 1.2g/cm3、1.25g/cm3、1.3g/
cm3、1.35g/cm3、1.4g/cm3、1.45g/cm3Or 1.5g/cm3。
In a kind of optional embodiment, the grain composition of the easy clean protection particle are as follows: 80 mesh~120 mesh are 50%
~60%, 120~200 mesh are 20%~30%, remaining is below 200 mesh.
In some embodiments, optionally, the grain composition of easy clean protection particle are as follows: 80 mesh~120 mesh are
60%, 120~200 mesh are 30%, and the following are 10% for 200 mesh；Alternatively, 80 mesh~120 mesh are 55%, 120~200 mesh are
30%, the following are 15% for 200 mesh.
It should be noted that above-mentioned % refers to mass percent.
Easy clean protection particle selects above-mentioned grain composition that the gap between particle can be made less, after charity is in printed layer
It is even closer uniform, it is substantially reduced intergranular space, the compactness of product is improved, further improves stain resistance.
In the present invention, the easy clean protection particle can be by the silicon containing elements Si, Al, Fe, Ti, Na, K, Mg and Ca
Silicate material is melted, then water quenching and crush obtain.Optionally, the silicate material is mainly by the original of following mass parts
Material composition: 10~20 parts of alumina powder, 36~45 parts of potassium feldspar, 8~16 parts of soda ash, 5~15 parts of zinc oxide and quartz 15~35
Part.Further, 25 parts of 13 parts of alumina powder, 42 parts of potassium feldspar, 10 parts of soda ash, 10 parts of zinc oxide and quartz.
In some embodiments, according to the mass fraction, the typical but non-limiting content of alumina powder are as follows: 10
Part, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts；Potassium feldspar is typical but unrestricted
The content of property are as follows: 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts；Soda ash typical case but non-limit
Property processed are as follows: 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts or 16 parts；Zinc oxide is typical but non-limiting
Are as follows: 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts 13 parts, 14 parts or 15 parts；Quartz is typical but non-limiting are as follows:
15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30
Part, 31 parts, 32 parts, 33 parts, 34 parts or 35 parts.
In a kind of optional embodiment, the green body layer is the green body layer with convex-concave surface.
The Ceramic Tiles of different colours and texture can be presented in green body layer with convex-concave surface, so that the product produced
Case shell is richer；Help to improve the antiskid effect of product and the stereovision of product, solid sense.
Optionally, blank formulation uses the body recipe of common glazed ceramic brick, and present embodiment offer one is exemplary
Formula.For the flatness and ripple glaze deformation for guaranteeing product, green body aluminum content is 21% or so, and whiteness is at 35 degree or so.Institute
State the raw material that blank includes following mass parts: 10~30 parts of Yichuan sand, 10~20 parts of Ganzhou low temperature potassium sodium sand, Qianshan washing mud 16
~20 parts, 6~10 parts of Guangxi White mud, 1~5 part of the white mud in Ji'an, 25~35 parts of Guangchang potassium sand, 0.5~1.5 part of Fuzhou City's bentonite and
2~3 parts of black talc.
Optionally, the moisture content of blank is 6%~6.5%；The grain composition of the blank are as follows: 20 mesh the above are 0~
1.5%, -20~+40 mesh are 30%~60%, and -20~+60 mesh are 72%~88%, and 100 mesh are remaining the following are 0~6%
For -60~+100 mesh.
Mesh indicates that particle is thinner through frequently as the unit for measuring granular size, mesh number is bigger.For those skilled in the art
Member for, often before the Arabic numerals of mesh number be added "-(negative sign) " come indicate particle can by selected sieve, "+(just
Number) " indicate that particle by selected sieve cannot indicate that the particle of 20 meshes can be passed through if " -20 mesh "；"+100 mesh "
It then indicates that the particle sieved with 100 mesh sieve cannot be led to.
In a kind of optional embodiment, the cover coat is mainly prepared by overglaze, the overglaze mainly by with
The raw material of lower mass parts is prepared:
20~30 parts of potassium feldspar, 15~30 parts of quartz, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, aluminium oxide 5~
15 parts, 1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate
0.1~0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and 0.1~0.3 part of sodium tripolyphosphate.
Preferably, the overglaze is mainly prepared by the raw material of following mass parts: 22~28 parts of potassium feldspar, quartz 18~
25 parts, 18~22 parts of nepheline, 6~8 parts of calcined kaolin, 6~12 parts of aluminium oxide, 3~6 parts of wollastonite, zinc oxide 0.5~1.5
Part, 15~25 parts of zirconium silicate, 12~18 parts of column kaolin, 0.15~0.25 part of sodium humate, sodium carboxymethylcellulose 0.15
~0.25 part and 0.15~0.2 part of sodium tripolyphosphate.
The cover coat that present embodiment provides can be improved the mechanical strength of easy clean Ceramic Tiles, reduce the water absorption rate of green body.
In addition, the whiteness for enabling to product using above-mentioned green body layer and cover coat is suitable for that not only ensure that the inherent and external of product
Quality, promotes the comprehensive performance of product, and reduces production cost, with good economic efficiency.
In a kind of optional embodiment, the printed layer includes one or multi-channel lamina printing decoration, one or multi-channel roller
Cylinder stamp and one or more of ink-jet printed combination.
Preferably, the printed layer is ink-jet printed layer.
The printed layer of present embodiment carries out decoration stamp preferably by ink-jet printing apparatus and obtains.
On the one hand, pattern decorative is carried out to Ceramic Tiles by the way of inkjet printing, so that printed layer texture variations are abundant
Vividly, color is naturally true to nature, shows individual character fully and makes widely known glamour.On the other hand, the pattern texture of printed layer and easy clean protection dry granule layer
It is interlaced, not only there is the aesthetic feeling of perspective, solid layer feeling is strong, and smooth and clean, clean mark is graceful, bright in luster not lose
Very, and glossiness is good, and transparency is high, and anti-fouling performance is good, enriches the level of product, improves product specification, has good
Good decorative effect.
Combined with specific embodiments below and comparative example, the invention will be further described.
Embodiment 1-3
A kind of easy clean protection tile, from bottom to top successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；The easy clean ratio for protecting glaze according to the mass parts of raw material shown in table 1
Example is prepared.
The easy clean protection glaze raw material composition of 1 embodiment 1-3 of table
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Easy clean protection glaze | 90 parts | 100 parts | 110 parts |
| Stamp-pad ink | 230 parts | 250 parts | 270 parts |
| Clear frit | 20 parts | 30 parts | 40 parts |
Wherein, easy clean protection particle is mainly made of the component of following mass fraction: SiO266 parts, Al2O321 parts,
Fe2O30.15 part, TiO20.06 part, Na26 parts of O, K24 parts of O, 0.15 part of MgO, 1.5 parts of CaO and 0.15 part of loss on ignition.
The grain composition of easy clean protection particle are as follows: 80 mesh~120 mesh are 60%, and 120~200 mesh are 30%, below 200 mesh
It is 10%.
Stamp-pad ink is mainly made of the component of following mass fraction: 1.2 parts of sodium carboxymethylcellulose, 30 parts of ethylene glycol, swelling
3 parts and 70 parts of water of soil.
Clear frit is mainly made of the component of following mass fraction: 14 parts of albite, 8 parts of kaolin, is forged 22 parts of potassium feldspar
12 parts of kaolin of burning, 12 parts of quartz, 15 parts of talcum of burning, 9 parts of lime stone, 10 parts of barium carbonate and 3 parts of zinc oxide.
Embodiment 4-6
A kind of easy clean protection tile, from bottom to top successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection glaze is made of the raw material of following mass fraction: easy clean
100 parts of particle of protection, 250 parts of stamp-pad ink and 30 parts of clear frit.Wherein, the mass fraction of easy clean protection particle mainly as shown in Table 2
Component constitute.
The easy clean protection grain fraction of 2 embodiment 4-6 of table is constituted
| Component | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| SiO2 | 60 parts | 63 parts | 70 parts |
| Al2O3 | 15 parts | 18 parts | 25 parts |
| Fe2O3 | 0.1 part | 0.18 part | 0.3 part |
| TiO2 | 0.01 part | 0.04 part | 0.1 part |
| Na2O | 4 parts | 5 parts | 8 parts |
| K2O | 2 parts | 5 parts | 6 parts |
| MgO | 0.05 part | 0.1 part | 0.3 part |
| CaO | 0.5 part | 1 part | 3 parts |
| Loss on ignition | 0.05 part | 0.1 part | 0.3 part |
Wherein, the component of the grain composition of easy clean protection particle, stamp-pad ink and clear frit is constituted same as Example 1.
Embodiment 7
A kind of easy clean protection tile, unlike the first embodiment, the component of stamp-pad ink and clear frit are constituted, remaining with implement 1
It is identical.
In the present embodiment, stamp-pad ink is mainly made of the component of following mass fraction: 2 parts of sodium carboxymethylcellulose, ethylene glycol
35 parts, 5 parts of bentonite and 80 parts of water.
Clear frit is mainly made of the component of following mass fraction: 16 parts of albite, 24 parts of potassium feldspar, 10 parts of kaolin,
14 parts of calcined kaolin, 13 parts of quartz, 17 parts of talcum of burning, 10 parts of lime stone, 12 parts of barium carbonate and 5 parts of zinc oxide.
Embodiment 8
A kind of easy clean protection tile, unlike the first embodiment, it is easy clean protection particle grain composition, remaining with implement 1
It is identical.
In the present embodiment, the grain composition of easy clean protection particle are as follows: 80 mesh~120 mesh are 55%, and 120~200 mesh are
30%, the following are 15% for 200 mesh.
Embodiment 9
A kind of easy clean protection tile, from bottom to top successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection dry granule layer in the present embodiment is same as Example 1.
In the present embodiment, green body aluminum content is 21%, and whiteness is 35 degree, and the moisture content of blank is 6%.Blank includes following
The raw material of mass parts: 20 parts of Yichuan sand, 15 parts of Ganzhou low temperature potassium sodium sand, 18 parts of mud of Qianshan washing, 8 parts of Guangxi White mud, Ji'an are white
3 parts of mud, 31 parts of Guangchang potassium sand, 1 part of Fuzhou City's bentonite and 2.5 parts of black talc.
The grain composition of blank are as follows: 20 mesh are 30% the above are 1%, -20~+40 mesh, and -20~+60 mesh are 72%,
For 100 mesh the following are 0, remainder is -60~+100 mesh.
In the present embodiment, overglaze is mainly prepared by the raw material of following mass parts: 25 parts of potassium feldspar, quartzy 20 parts, rosy clouds
20 parts of stone, 7 parts of calcined kaolin, 10 parts of aluminium oxide, 4 parts of wollastonite, 1 part of zinc oxide, 20 parts of zirconium silicate, column kaolin 15
Part, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and 0.15 part of sodium tripolyphosphate.
In the present embodiment, the printed layer carries out decoration stamp by ink-jet printing apparatus and obtains.
Embodiment 10
A kind of easy clean protection tile, from bottom to top successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection dry granule layer in the present embodiment is same as Example 1.
In the present embodiment, green body aluminum content is 21%, and whiteness is 35 degree, and the moisture content of blank is 6.5%.Blank include with
The raw material of lower mass parts: 20 parts of mud, 10 parts of Guangxi White mud, Ji'an are washed in 30 parts of Yichuan sand, 20 parts of Ganzhou low temperature potassium sodium sand, Qianshan
5 parts of white mud, 35 parts of Guangchang potassium sand, 1.5 parts of Fuzhou City's bentonite and 3 parts of black talc.
The grain composition of blank are as follows: 20 mesh are 50% the above are 0%, -20~+40 mesh, and -20~+60 mesh are 88%,
For 100 mesh the following are 2%, remainder is -60~+100 mesh.
In the present embodiment, overglaze is mainly prepared by the raw material of following mass parts: 30 parts of potassium feldspar, quartzy 30 parts, rosy clouds
25 parts of stone, 10 parts of calcined kaolin, 15 parts of aluminium oxide, 8 parts of wollastonite, 2 parts of zinc oxide, 30 parts of zirconium silicate, column kaolin 20
Part, 0.3 part of sodium humate, 0.3 part of sodium carboxymethylcellulose and 0.3 part of sodium tripolyphosphate.
In the present embodiment, the printed layer carries out decoration stamp by ink-jet printing apparatus and obtains.
Comparative example 1
A kind of easy clean protection tile, from bottom to top successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection glaze is made of the raw material of following mass fraction: easy clean
60 parts of particle of protection, 220 parts of stamp-pad ink and 15 parts of clear frit.
Comparative example 1 unlike the first embodiment it is easy clean protection glaze raw material proportioning, remaining is same as Example 1.
Comparative example 2
A kind of easy clean protection tile, from bottom to top successively include green body layer, cover coat, printed layer and easy clean protection dry granule layer,
Easy clean protection dry granule layer is formed by the easy clean protection glaze of charity；Easy clean protection glaze is made of the raw material of following mass fraction: easy clean
90 parts of particle of protection, 230 parts of stamp-pad ink and 20 parts of clear frit.Wherein, easy clean protection particle is made of the component of following mass fraction:
SiO285 parts, Al2O310 parts, Fe2O30.08 part, TiO20.15 part, Na22 parts of O, K21 part of O, 0.02 part of MgO, CaO
0.2 part and 0.35 part of loss on ignition.
Comparative example 2 unlike the first embodiment it is easy clean protection particle component proportion, remaining is same as Example 1.
Comparative example 3
The easy clean protection grains gradation unlike the first embodiment of comparative example 3, remaining is same as Example 1.
In comparative example 3, the grain composition of easy clean protection particle are as follows: 80 mesh~120 mesh are 30%, and 120~200 mesh are
40%, the following are 30% for 200 mesh.
Comparative example 4
For comparative example 4 difference from example 1 is that clear frit, remaining is same as Example 1.
In comparative example 4, clear frit is the clear frit of ceramics Co., Ltd, Huanghua City Xingda production.
Comparative example 5
For comparative example 5 difference from example 1 is that stamp-pad ink and clear frit, remaining is same as Example 1.
In comparative example 5, stamp-pad ink is mainly made of the component of following mass fraction: 0.5 part of sodium carboxymethylcellulose, ethylene glycol
18 parts, 0.8 part of bentonite and 50 parts of water.
Clear frit is mainly made of the component of following mass fraction: 10 parts of albite, 5 parts of kaolin, is forged 18 parts of potassium feldspar
6 parts of kaolin of burning, 7 parts of quartz, 10 parts of talcum of burning, 5 parts of lime stone, 7 parts of barium carbonate and 0.5 part of zinc oxide.
Comparative example 6
Easy clean protection dry granule layer is replaced using existing common glaze.The formula of the common glaze are as follows: 20 mass parts of ball clay,
30 mass parts of kaolin, 10 mass parts of 15 mass parts of talcum, 10 mass parts of potassium feldspar and quartz sand.
Comparative example 7
It is not provided with easy clean protection dry granule layer.
Respectively to the easy clean Ceramic Tiles in embodiment 1-10 and comparative example 1-7, cleaning property of easy-cleaning test, test result are carried out
As shown in table 1.
1 performance test results of table
Note: according to national standard: the rule in " photocatalytic self-cleaning material performance test method (GB/T23764-2009) "
It is fixed, cleaning property of easy-cleaning test is carried out to the easy clean Ceramic Tiles in embodiment 1-10 and comparative example 1-7, wherein A indicates Ceramic Tiles table
Face unit area greasy dirt residual volume, unit g/m2。
As shown in Table 1, the performance easy to clean of the easy clean Ceramic Tiles of embodiment 1-10, hence it is evident that be better than comparative example 1-7, especially
It is easy clean Ceramic Tiles provided by embodiment 2 and embodiment 5, more preferably, greasy dirt residual volume is respectively 0.40g/m to the easy clean property of anti-pollution2
And 0.41g/m2.Thus illustrate, using easy clean Ceramic Tiles provided by the invention, there is the easy clean property of good anti-pollution and anti-pollution
Property, convenient for daily maintenance with arrange, application value is high.
By the comparative analysis of comparative example 1-3 and embodiment 1 it is found that changing the proportion of each raw material in easy clean protection glaze, make it
Raw material proportioning is not within the protection scope of the present invention；Or change the component composition of easy clean protection particle；Or change easy clean guarantor
The grain composition for protecting particle, can not achieve said effect, performance easy to clean is poor.Comparative example 1 and comparative example 2 are also into one
Step illustrates that each raw material mutual cooperation in easy clean protection glaze and easy clean protection particle in the present invention acts on, in the present invention
Under the proportion of restriction, the easy clean property of the anti-pollution of Ceramic Tiles is more preferable, is more able to satisfy the demand in market.
As the comparative analysis of comparative example 4-5 and embodiment 1 it is found that using stamp-pad ink and clear frit defined by the present invention, energy
It is enough to cooperate with above-mentioned easy clean protection glaze, the easy clean property of anti-pollution of easy clean protection stratum granulosum is further increased, using effect is more preferable.
By the comparative analysis of comparative example 6-7 and embodiment 1 it is found that easy clean protection dry granule layer provided by the invention is arranged
On the surface of Ceramic Tiles, the easy clean property of anti-pollution of Ceramic Tiles can be significantly improved, performance easy to clean will be substantially better than existing general
Logical Ceramic Tiles.In addition, easy clean Ceramic Tiles glossiness also with higher provided by the invention, solid layer feeling is strong, and clarity is good,
The high advantage of surface transparency.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of easy clean Ceramic Tiles, which is characterized in that the easy clean Ceramic Tiles from bottom to top successively include green body layer, cover coat,
Printed layer and easy clean protection dry granule layer, the easy clean protection dry granule layer are formed by the easy clean protection glaze of charity；
The easy clean protection glaze includes the component of following mass fraction: easy clean 90~110 parts of protection particle, 230~270 parts of stamp-pad ink
With 20~40 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO260~70 parts, Al2O315~25 parts, Fe2O30.1~0.3 part, TiO20.01~0.1 part, Na24~8 parts of O,
K22~6 parts of O, 0.05~0.3 part of MgO, 0.5~3 part of CaO and 0.05~0.3 part of loss on ignition.
2. easy clean Ceramic Tiles according to claim 1, which is characterized in that the easy clean protection glaze includes following mass fraction
Component: easy clean 92~108 parts of protection particle, 240~260 parts of stamp-pad ink and 22~38 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO265~68 parts, Al2O318~22 parts, Fe2O30.12~0.22 part, TiO20.02~0.08 part, Na2O 5~7
Part, K23~5 parts of O, 0.1~0.2 part of MgO, 1~2 part of CaO and 0.1~0.2 part of loss on ignition.
3. easy clean Ceramic Tiles according to claim 1, which is characterized in that the easy clean protection glaze includes following mass fraction
Component: easy clean 95~105 parts of protection particle, 245~250 parts of stamp-pad ink and 28~32 parts of clear frit；
Wherein, the easy clean protection particle is mainly made of the component of following mass fraction:
SiO266~67 parts, Al2O320~21 parts, Fe2O30.15~0.2 part, TiO20.04~0.07 part, Na2O 5.5~
6.5 parts, K24~4.8 parts of O, 0.12~0.15 part of MgO, 1.5~1.8 parts of CaO and 0.14~0.18 part of loss on ignition.
4. described in any item easy clean Ceramic Tiles according to claim 1~3, which is characterized in that the stamp-pad ink is mainly by following matter
The component for measuring number is constituted: 1~2 part of sodium carboxymethylcellulose, 20~40 parts of ethylene glycol, 1~5 part of bentonite and water 60~80
Part.
5. described in any item easy clean Ceramic Tiles according to claim 1~3, which is characterized in that the clear frit is mainly by following
The component of mass fraction is constituted:
12~16 parts of albite, 20~24 parts of potassium feldspar, 6~10 parts of kaolin, 10~14 parts of calcined kaolin, quartz 10~14
Part, 13~17 parts of talcum of burning, 7~11 parts of lime stone, 8~12 parts of barium carbonate and 1~5 part of zinc oxide.
6. described in any item easy clean Ceramic Tiles according to claim 1~3, which is characterized in that the specific gravity of the easy clean protection glaze
For 1.2~1.5g/cm3。
7. described in any item easy clean Ceramic Tiles according to claim 1~3, which is characterized in that of the easy clean protection particle
Grade is matched are as follows: 80 mesh~120 mesh are 50%~60%, and 120~200 mesh are 20%~30%, remaining is below 200 mesh.
8. easy clean Ceramic Tiles according to claim 1, which is characterized in that the green body layer is the green body with convex-concave surface
Layer.
9. easy clean Ceramic Tiles according to claim 1, which is characterized in that the cover coat is mainly prepared by overglaze,
The overglaze is mainly prepared by the raw material of following mass parts:
20~30 parts of potassium feldspar, quartz 15~30 parts, 15~25 parts of nepheline, 5~10 parts of calcined kaolin, 5~15 parts of aluminium oxide,
1~8 part of wollastonite, 0.1~2 part of zinc oxide, 10~30 parts of zirconium silicate, 10~20 parts of column kaolin, sodium humate 0.1~
0.3 part, 0.1~0.3 part of sodium carboxymethylcellulose and 0.1~0.3 part of sodium tripolyphosphate.
10. easy clean Ceramic Tiles according to claim 1, which is characterized in that the printed layer includes one or multi-channel web plate
Stamp, one or multi-channel roller printing and one or more of ink-jet printed combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710605577.9A CN107285812B (en) | 2017-07-21 | 2017-07-21 | Easy clean Ceramic Tiles |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710605577.9A CN107285812B (en) | 2017-07-21 | 2017-07-21 | Easy clean Ceramic Tiles |
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| Publication Number | Publication Date |
|---|---|
| CN107285812A CN107285812A (en) | 2017-10-24 |
| CN107285812B true CN107285812B (en) | 2019-07-26 |
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| WO2019015237A1 (en) * | 2017-07-21 | 2019-01-24 | 广东金意陶陶瓷集团有限公司 | Anti-slip wear-resistant glaze, anti-slip wear-resistant easy-clean ceramic tile, and preparation method therefor |
| US10475264B2 (en) | 2017-08-14 | 2019-11-12 | Q & K International Group Limited | Application method of Bluetooth low-energy electronic lock based on built-in offline pairing passwords, interactive unlocking method of a Bluetooth electronic lock and electronic lock system |
| CN108793960B (en) * | 2018-08-23 | 2021-06-29 | 广西亚欧瓷业有限公司 | Preparation method of wear-resistant ceramic tile capable of releasing negative ions |
| CN109095910A (en) * | 2018-08-31 | 2018-12-28 | 湖北省当阳豪山建材有限公司 | Anion environmental protection self-cleaning ceramic tile and preparation method thereof |
| CN111333433B (en) * | 2020-05-19 | 2020-09-18 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance far-infrared ceramic glazed brick and preparation method thereof |
| CN115626775A (en) * | 2022-10-20 | 2023-01-20 | 新明珠集团股份有限公司 | Quick-drying printing fancy glaze, preparation method thereof and ceramic tile |
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| CN104261897A (en) * | 2014-09-25 | 2015-01-07 | 佛山市三水新明珠建陶工业有限公司 | Ceramic tile having antiskid effect and manufacturing method thereof |
| CN106336198A (en) * | 2016-08-30 | 2017-01-18 | 王爱纯 | Ceramic material for electric cooker inner tank use |
| CN106673435A (en) * | 2016-12-26 | 2017-05-17 | 澧县新鹏陶瓷有限公司 | Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof |
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Address after: 528000 No. 1-3, Liyuan 2nd Road, Geely Industrial Park, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province (residence declaration) Patentee after: GUANGDONG KITO CERAMICS GROUP Co.,Ltd. Patentee after: FOSHAN SANSHUI JINYITAO CERAMIC Co.,Ltd. Patentee after: JINGDEZHEN KITO CERAMICS Co.,Ltd. Address before: 528133 Zuotian Private Development Zone, Southwest Street, Sanshui District, Foshan City, Guangdong Province (F6) (Residence Declaration) Patentee before: GUANGDONG KITO CERAMICS GROUP Co.,Ltd. Patentee before: FOSHAN SANSHUI JINYITAO CERAMIC Co.,Ltd. Patentee before: JINGDEZHEN KITO CERAMICS Co.,Ltd. |
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Address after: 528000, Floor 3, Building 5, No. 3 Jiaxue Road, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province (Residence application) Patentee after: GUANGDONG KITO CERAMICS GROUP Co.,Ltd. Patentee after: FOSHAN SANSHUI JINYITAO CERAMIC Co.,Ltd. Patentee after: JINGDEZHEN KITO CERAMICS Co.,Ltd. Address before: 528000 No. 1-3, Liyuan 2nd Road, Geely Industrial Park, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province (residence declaration) Patentee before: GUANGDONG KITO CERAMICS GROUP Co.,Ltd. Patentee before: FOSHAN SANSHUI JINYITAO CERAMIC Co.,Ltd. Patentee before: JINGDEZHEN KITO CERAMICS Co.,Ltd. |
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