CN107311457B - Anti-skid wearable Ceramic Tiles - Google Patents

Anti-skid wearable Ceramic Tiles Download PDF

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Publication number
CN107311457B
CN107311457B CN201710605622.0A CN201710605622A CN107311457B CN 107311457 B CN107311457 B CN 107311457B CN 201710605622 A CN201710605622 A CN 201710605622A CN 107311457 B CN107311457 B CN 107311457B
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China
Prior art keywords
parts
skid wearable
ceramic tiles
mainly
glaze
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CN107311457A (en
Inventor
李德英
钟礼丰
戴永刚
喻劲军
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Foshan Sanshui Jinyitao Ceramic Co ltd
Guangdong Kito Ceramics Group Co ltd
Jingdezhen Kito Ceramics Co ltd
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Guangdong Kito Ceramics Group Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions

Abstract

The present invention relates to Ceramic Tiles fields, specifically, providing a kind of anti-skid wearable Ceramic Tiles.The anti-skid wearable Ceramic Tiles include green body layer and the main anti-skid wearable layer formed after green body layer surface using the charity of anti-skid wearable glaze, and the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 90-110 parts of anti-skid wearable particle, cream 90-110 parts and 0.2-0.4 parts of sodium tripolyphosphate of print；The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260-70 parts, Al2O320-30 parts, Fe2O30.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and 0.1-2 parts of loss on ignition.The anti-skid wearable Ceramic Tiles have excellent antiskid effect and abrasion resistant effect, and product quality is high, durable, safe and reliable.

Description

Anti-skid wearable Ceramic Tiles
Technical field
The present invention relates to Ceramic Tiles fields, in particular to a kind of anti-skid wearable Ceramic Tiles.
Background technique
With the rapid development of science and technology, people's lives are maked rapid progress, while having been cast one and having been followed the fashion, and are shown The epoch of individual character, architectural decoration material field are no exception.Ceramic Tiles are with its superior performance and decorative effect, by increasingly The favor of more consumers, and be widely used in people's daily life.And ceramic antique bricks are in recent years popular rise A kind of building decoration materials come, the pattern that it has had both the splendid and tile of polished bricks is rich and varied, have the modern times or Pseudo-classic charm, and it is personalized many advantages, such as, be received by the market and consumer like.
With the continuous improvement of people's living standards, client also can be more and more to the demand in terms of product function, have The demand of personalized, long-lived, safe and reliable high-end ceramic brick product also can be more and more.Current ceramic product (such as Ceramic Tiles) there are surface hardnesses inadequate and not wear-resisting, easy scuffing, to influence the beauty of product；Surface of ceramic products Coefficient of friction is relatively low, not anti-skidding, easily fall down, to influence the safe handling of product.Therefore, it is necessary to carry out the prior art into one The improvement of step provides a kind of wear-resisting property and the good Ceramic Tiles of non-skid property.
In view of this, the present invention is specifically proposed.
Summary of the invention
The purpose of the present invention is to provide a kind of anti-skid wearable Ceramic Tiles, which has excellent anti-skidding Effect and abrasion resistant effect, product quality are high, durable, safe and reliable.
In order to realize above-mentioned purpose of the invention, the following technical scheme is adopted:
The present invention provides a kind of anti-skid wearable Ceramic Tiles, including green body layer to use the charity of anti-skid wearable glaze in base with main The anti-skid wearable layer formed after body layer surface, the anti-skid wearable glaze are mainly prepared by the raw material of following mass parts: anti-skidding 90-110 parts of abrasion resistant particles, cream 90-110 parts and 0.2-0.4 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260-70 parts, Al2O320-30 parts, Fe2O30.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and burning 0.1-2 parts of vector.
As further preferably technical solution, the anti-skid wearable glaze mainly by following mass parts raw material preparation and At: 92-108 parts of anti-skid wearable particle, cream 92-108 parts and 0.22-0.38 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO261-69 parts, Al2O321-29 parts, Fe2O30.02-0.09 parts, TiO20.2-1.9 parts, Na21.5-4.5 parts of O, K22-9 parts of O, 0.1-0.9 parts of MgO, CaO 1-4 Part and loss on ignition 0.2-1.9 parts.
As further preferably technical solution, the anti-skid wearable glaze mainly by following mass parts raw material preparation and At: 94-106 parts of anti-skid wearable particle, cream 94-106 parts and 0.24-0.36 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO262-68 parts, Al2O322-28 parts, Fe2O30.04-0.08 parts, TiO20.4-1.8 parts, Na22-4 parts of O, K23-8 parts of O, 0.2-0.8 parts of MgO, 2-3 parts of CaO and 0.3-1.8 parts of loss on ignition.
As further preferably technical solution, the print cream is mainly grouped as by the group of following mass parts: carboxymethyl is fine Plain 2-3 parts of the sodium of dimension, 40-60 parts of ethylene glycol and 40-60 parts of water.
As further preferably technical solution, the grain composition of the anti-skid wearable particle are as follows: 80-120 mesh 20%- 30%, 120-180 mesh 50%-60%, remaining is below 200 mesh.
As further preferably technical solution, the specific gravity of the anti-skid wearable glaze is 1.2-1.8g/cm3。
As further preferably technical solution, the flow velocity of the anti-skid wearable glaze is 80-100 seconds.
As further preferably technical solution, cover coat is additionally provided between the green body layer and the anti-skid wearable layer And decorative layer, the decorative layer are set between the cover coat and the anti-skid wearable layer.
As further preferably technical solution, the cover coat is mainly prepared by overglaze, the overglaze mainly by The raw material of following mass parts is prepared: 20-30 parts of potassium feldspar, 15-30 parts of quartz, 15-25 parts of nepheline, calcined kaolin 5-10 Part, 5-15 parts of aluminium oxide, 1-8 parts of wollastonite, 0.1-2 parts of zinc oxide, 10-30 parts of zirconium silicate, 10-20 parts of column kaolin, corruption Grow sour sodium 0.1-0.3 parts, 0.1-0.3 parts of sodium carboxymethylcellulose and 0.1-0.3 parts of sodium tripolyphosphate.
As further preferably technical solution, the decorative layer includes one or multi-channel lamina printing decoration, one or multi-channel Roller printing and one or more of ink-jet printed combination.
Compared with prior art, the invention has the benefit that
Anti-skid wearable Ceramic Tiles provided by the invention include green body layer and mainly use the charity of anti-skid wearable glaze in green body layer The anti-skid wearable layer formed behind surface, anti-skid wearable glaze is mainly by anti-skid wearable particle, print three kinds of raw materials of cream and sodium tripolyphosphate Composition has good anti-skid wearable effect, while product by the reasonable cooperation of each raw material and anti-skid wearable particle each component Surface transparency also with higher and lower glossiness.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific Condition person carries out according to conventional conditions or manufacturer's recommended conditions.
The present invention provides a kind of anti-skid wearable Ceramic Tiles, including green body layer to use the charity of anti-skid wearable glaze in base with main The anti-skid wearable layer formed after body layer surface, the anti-skid wearable glaze are mainly prepared by the raw material of following mass parts: anti-skidding 90-110 parts of abrasion resistant particles, cream 90-110 parts and 0.2-0.4 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260-70 parts, Al2O320-30 parts, Fe2O30.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and burning 0.1-2 parts of vector.
Unless otherwise stated, the quality criteria of each product is all the same in the present invention；For example, anti-skid wearable glaze and anti-skid wearable The quality criteria of particle is identical, is all such as 1 gram.
It should be noted that loss on ignition is common technical terms in ceramic field, it is according to the conventional understanding of this field Can, the mass ratio before quality and firing after referring to raw material calcination.
In anti-skid wearable glaze of the invention, according to the mass fraction, the typical but non-limiting content of anti-skid wearable particle are as follows: 90 parts, 91 parts, 92 parts, 93 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 99 parts, 100 parts, 101 parts, 102 parts, 103 parts, 104 Part, 105 parts, 106 parts, 107 parts, 108 parts, 109 parts or 110 parts；Print the typical but non-limiting content of cream are as follows: 90 parts, 91 parts, 92 parts, 93 parts, 94 parts, 95 parts, 96 parts, 97 parts, 98 parts, 99 parts, 100 parts, 101 parts, 102 parts, 103 parts, 104 parts, 105 parts, 106 parts, 107 parts, 108 parts, 109 parts or 110 parts；The typical but non-limiting content of sodium tripolyphosphate are as follows: 0.2 part, 0.21 part, 0.22 part, 0.23 part, 0.24 part, 0.25 part, 0.26 part, 0.27 part, 0.28 part, 0.29 part, 0.3 part, 0.31 part, 0.32 part, 0.33 part, 0.34 part, 0.35 part, 0.36 part, 0.37 part, 0.38 part, 0.39 part or 0.4 part.Above-mentioned anti-skid wearable particle is main Play the role of anti-skidding and wear-resisting effect, print cream primarily serves the viscosity for adjusting anti-skid wearable glaze, and sodium tripolyphosphate mainly rises To the effect for the suspended dispersed for adjusting anti-skid wearable particle.
In anti-skid wearable particle of the invention, according to the mass fraction, SiO2Typical but non-limiting content are as follows: 60 parts, 61 parts, 62 parts, 63 parts, 64 parts, 65 parts, 65.87 parts, 66 parts, 67 parts, 68 parts, 69 parts or 70 parts；Al2O3It is typical but non-limiting Content are as follows: 20 parts, 21 parts, 22 parts, 22.86 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or 30 parts；Fe2O3 Typical but non-limiting content are as follows: 0.01 part, 0.08 part, 0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7 Part, 0.8 part, 0.9 part or 1 part；TiO2Typical but non-limiting content are as follows: 0.1 part, 0.2 part, 0.3 part, 0.4 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, 0.99 part, 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts or 2 parts；Na2The typical but non-limiting content of O are as follows: 1 part, 1.5 parts, 2 parts, 2.22 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts；K2The typical but non-limiting content of O are as follows: 1 part, 2 parts, 3 parts, 4 parts, 4.11 parts, 5 parts, 6 Part, 7 parts, 8 parts, 9 parts or 10 parts；The typical but non-limiting content of MgO are as follows: 0.01 part, 0.1 part, 0.2 part, 0.3 part, 0.4 Part, 0.43 part, 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part or 1 part；The typical but non-limiting content of CaO are as follows: 0.1 part, 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 2.69 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts or 5 parts；Loss on ignition is typical but unrestricted The content of property are as follows: 0.1 part, 0.2 part, 0.4 part, 0.6 part, 0.75 part, 0.8 part, 1 part, 1.2 parts, 1.4 parts, 1.6 parts, 1.8 parts or 2 parts.
Above-mentioned anti-skid wearable Ceramic Tiles include green body layer and mainly use anti-skid wearable glaze charity shape after green body layer surface At anti-skid wearable layer, anti-skid wearable glaze mainly by anti-skid wearable particle, print three kinds of raw materials of cream and sodium tripolyphosphate form, pass through The reasonable cooperation of each raw material and anti-skid wearable particle each component has good anti-skid wearable effect, while product surface also has There are higher transparency and lower glossiness.
Preferably, the anti-skid wearable particle in the present invention is mainly prepared by the raw material of following mass parts: aluminium oxide 10- 20 parts, 35-45 parts of potassium feldspar, 1-10 parts of soda ash, 35-45 parts of quartz and 1-8 parts of calcite.It is further preferred that in the present invention Anti-skid wearable particle be mainly prepared by the raw material of following mass parts: 15 parts of aluminium oxide, 40 parts of potassium feldspar, 2 parts of soda ash, stone 38 parts and 5 parts of calcite of English.
Using the anti-skid wearable particle of above-mentioned formula with softening temperature is moderate, be easy to be sintered, transparency is high, glossiness is high And the advantages of good antiskid effect.
In the present invention, according to the mass fraction, the typical but non-limiting content of aluminium oxide are as follows: 10 parts, 11 parts, 12 parts, 13 Part, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts；The typical typical but non-limiting content of potassium feldspar are as follows: 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts；Soda ash is typical but non-limiting are as follows: 1 Part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts；Quartz is typical but non-limiting are as follows: 35 parts, 36 parts, 37 Part, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts or 45 parts；The typical but non-limiting content of calcite is 1 part, 2 Part, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts or 8 parts.
It is preferably carried out in mode in one kind, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 92-108 parts of anti-skid wearable particle, cream 92-108 parts and 0.22-0.38 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO261-69 parts, Al2O321-29 parts, Fe2O30.02-0.09 parts, TiO20.2-1.9 parts, Na21.5-4.5 parts of O, K22-9 parts of O, 0.1-0.9 parts of MgO, CaO 1-4 Part and loss on ignition 0.2-1.9 parts.
It is preferably carried out in mode in one kind, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 94-106 parts of anti-skid wearable particle, cream 94-106 parts and 0.24-0.36 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO262-68 parts, Al2O322-28 parts, Fe2O30.04-0.08 parts, TiO20.4-1.8 parts, Na22-4 parts of O, K23-8 parts of O, 0.2-0.8 parts of MgO, 2-3 parts of CaO and 0.3-1.8 parts of loss on ignition.
It is preferably carried out in mode in one kind, the print cream is mainly grouped as by the group of following mass parts: carboxymethyl cellulose Plain sodium 2-3 parts, 40-60 parts of ethylene glycol and 40-60 parts of water.It is prepared using the print cream of above-mentioned specific components and content anti-skidding The non-skid property and wear-resisting property of wear-resisting glaze are more preferable.
The present invention preferably prints in cream, according to the mass fraction, the typical but non-limiting content of sodium carboxymethylcellulose are as follows: 2 parts, 2.1 parts, 2.2 parts, 2.3 parts, 2.4 parts, 2.5 parts, 2.6 parts, 2.7 parts, 2.8 parts, 2.9 parts or 3 parts；Ethylene glycol is typical but non- Restrictive content are as follows: 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 Part, 53 parts, 54 parts, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts or 60 parts；The typical but non-limiting content of water are as follows: 40 parts, 41 Part, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 parts, 55 parts, 56 Part, 57 parts, 58 parts, 59 parts or 60 parts.
It is preferably carried out in mode in one kind, the grain composition of the anti-skid wearable particle are as follows: 80-120 mesh 20%- 30%, 120-180 mesh 50%-60%, remaining is below 200 mesh.
In above-mentioned anti-skid wearable particle, the typical but non-limiting content of 80-120 purpose are as follows: 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29% or 30%.The typical but non-limiting content of 120-180 purpose are as follows: 50%, 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58%, 59% or 60%.Anti-skid wearable particle is selected above-mentioned Gradation can make the gap between particle less, and charity is even closer uniform after product surface.
It is preferably carried out in mode in one kind, the specific gravity of the anti-skid wearable glaze is 1.2-1.8g/cm3.In the present invention, on The specific gravity for stating anti-skid wearable glaze is typical but non-limiting are as follows: 1.2g/cm3、1.3g/cm3、1.4g/cm3、1.5g/cm3、1.6g/ cm3、1.7g/cm3Or 1.8g/cm3.The good fluidity of the anti-skid wearable glaze of above-mentioned specific gravity can pass through silk screen, and not glue Net, and then improve printing efficiency and anti-skid wearable performance.
It is preferably carried out in mode in one kind, the flow velocity of the anti-skid wearable glaze is 80-100 seconds.Flow velocity typical case but non-limit Property processed are as follows: 80 seconds, 81 seconds, 82 seconds, 83 seconds, 84 seconds, 85 seconds, 86 seconds, 87 seconds, 88 seconds, 89 seconds, 90 seconds, 91 seconds, 92 seconds, 93 Second, 94 seconds, 95 seconds, 96 seconds, 97 seconds, 98 seconds, 99 seconds or 100 seconds.The good fluidity of the anti-skid wearable glaze of above-mentioned flow velocity, Neng Goushun Benefit passes through silk screen, and not sticky net, and then improves printing efficiency and anti-skid wearable performance.
Be preferably carried out in mode in one kind, be additionally provided between the green body layer and the anti-skid wearable layer cover coat and Decorative layer, the decorative layer are set between the cover coat and the anti-skid wearable layer.Cover coat can be improved easy ceramic The mechanical strength of brick, the water absorption rate for reducing green body；Decorative layer can enrich the diversity of ceramic brick surface pattern, make Ceramic Tiles more Adding beauty, decorative layer and the pattern texture of both anti-skid wearable layers are interlaced, changeable level and stereoscopic effect can be increased, It produces some parts of pattern texture to may be seen indistinctly, seems the effect come out from brick borough chief.
Be preferably carried out in mode in one kind, the cover coat is mainly prepared by overglaze, the overglaze mainly by with The raw material of lower mass parts is prepared: 20-30 parts of potassium feldspar, 15-30 parts of quartz, 15-25 parts of nepheline, calcined kaolin 5-10 Part, 5-15 parts of aluminium oxide, 1-8 parts of wollastonite, 0.1-2 parts of zinc oxide, 10-30 parts of zirconium silicate, 10-20 parts of column kaolin, corruption Grow sour sodium 0.1-0.3 parts, 0.1-0.3 parts of sodium carboxymethylcellulose and 0.1-0.3 parts of sodium tripolyphosphate.Using green body layer and above-mentioned It is suitable for that not only ensure that inherence and the external quality of product, promote the comprehensive of product that cover coat, which enables to the whiteness of product, Can, and production cost is reduced, it is with good economic efficiency.
In the present invention preferably overglaze, according to the mass fraction, the typical but non-limiting content of potassium feldspar are as follows: 20 parts, 21 Part, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or 30 parts；The typical but non-limiting content of quartz are as follows: 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts or 30 parts；The typical but non-limiting content of nepheline are as follows: 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts or 25 parts；The typical but non-limiting content of calcined kaolin are as follows: 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 Part, 8.5 parts, 9 parts, 9.5 parts or 10 parts；The typical but non-limiting content of aluminium oxide are as follows: 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 Part, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts；The typical but non-limiting content of wollastonite are as follows: 1 part, 2 parts, 3 parts, 4 parts, 5 Part, 6 parts, 7 parts or 8 parts；The typical but non-limiting content of zinc oxide is 0.1 part, 0.2 part, 0.4 part, 0.6 part, 0.8 part, 1 Part, 1.2 parts, 1.4 parts, 1.6 parts, 1.8 parts or 2 parts；The typical but non-limiting content of zirconium silicate are as follows: 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 Part, 29 parts or 30 parts；The typical but non-limiting content of column kaolin are as follows: 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts or 20 parts；The typical but non-limiting content of sodium humate are as follows: 0.1 part, 0.12 part, 0.14 part, 0.18 part, 0.2 part, 0.22 part, 0.24 part, 0.26 part, 0.28 part or 0.3 part；Sodium carboxymethylcellulose is typical but non-limiting Content are as follows: 0.1 part, 0.12 part, 0.14 part, 0.18 part, 0.2 part, 0.22 part, 0.24 part, 0.26 part, 0.28 part or 0.3 part； The typical but non-limiting content of sodium tripolyphosphate are as follows: 0.1 part, 0.12 part, 0.14 part, 0.18 part, 0.2 part, 0.22 part, 0.24 Part, 0.26 part, 0.28 part or 0.3 part.
Preferably, the overglaze is mainly prepared by the raw material of following mass parts: 22-28 parts of potassium feldspar, quartz 18-25 Part, 18-22 parts of nepheline, 6-8 parts of calcined kaolin, 6-12 parts of aluminium oxide, 3-6 parts of wollastonite, 0.5-1.5 parts of zinc oxide, silicic acid 15-25 parts of zirconium, 12-18 parts of column kaolin, 0.15-0.25 parts of sodium humate, 0.15-0.25 parts of sodium carboxymethylcellulose and three 0.15-0.2 parts of polyphosphate sodium.
Optionally, blank formulation uses the body recipe of common glazed ceramic brick, and present embodiment offer one is exemplary Formula.For the flatness and ripple glaze deformation for guaranteeing product, green body aluminum content is 21% or so, and whiteness is at 35 degree or so.Institute State the raw material that blank includes following mass parts: sand 10-30 parts of Yichuan, 10-20 parts of Ganzhou low temperature potassium sodium sand, Qianshan washing mud 16- 20 parts, 6-10 parts of Guangxi White mud, Ji'an is mud 1-5 parts white, 25-35 parts of Guangchang potassium sand, bentonite 0.5-1.5 parts of Fuzhou City and black talc 2-3 parts.
Optionally, the moisture content of blank is 6%-6.5%；The grain composition of the blank are as follows: the above 0-1.5% of 20 mesh, 20-40 mesh 30%-60%, 20-60 mesh 72%-88%, 0-6% below 100 mesh, remainder are 60-100 mesh.
It is preferably carried out in mode in one kind, the decorative layer includes one or multi-channel lamina printing decoration, one or multi-channel roller Cylinder stamp and one or more of ink-jet printed combination.
The decorative layer of present embodiment carries out decoration stamp preferably by ink-jet printing apparatus and obtains.On the one hand, it uses The mode of inkjet printing carries out pattern decorative to Ceramic Tiles, so that decorative layer texture variations are abundant lively, color is naturally true to nature, to the greatest extent Aobvious individual character makes widely known glamour.On the other hand, decorative layer and the pattern texture of anti-skid wearable layer are interlaced, can increase changeable layer Secondary and stereoscopic effect produces some parts of pattern texture and mays be seen indistinctly, and seems the effect come out from brick borough chief, enriches product Level, improve product specification, have good decorative effect.
It should be noted that the preparation method of the anti-skid wearable Ceramic Tiles in the present invention does not have special limitation, using this It is prepared by technical solution known to the technical staff of field.
Below with reference to embodiment and comparative example, the present invention will be further described in detail.
Embodiment 1
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 90 parts of anti-skid wearable particle, Print 90 parts and 0.2 part of sodium tripolyphosphate of cream；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260 parts, Al2O320 parts, Fe2O3 0.01 part, TiO20.1 part, Na21 part of O, K21 part of O, 0.01 part of MgO, 0.1 part of CaO and 0.1 part of loss on ignition；It is main to print cream It is grouped as by the group of following mass parts: 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and 40 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Embodiment 2
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 110 Part, 110 parts of cream of print and 0.4 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO270 parts, Al2O330 parts, Fe2O3 1 part, TiO22 parts, Na25 parts of O, K210 parts of O, 1 part of MgO, 5 parts of CaO and 2 parts of loss on ignition；Cream is printed mainly by following mass parts Group be grouped as: 8 parts of sodium carboxymethylcellulose, 60 parts of ethylene glycol and 60 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
The content of each raw material of anti-skid wearable glaze of the present embodiment and the constituent content of each raw material are different from embodiment 1.
Embodiment 3
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 100 Part, 100 parts of cream of print and 0.3 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO265 parts, Al2O325 parts, Fe2O3 0.5 part, TiO21 part, Na22.5 parts of O, K25 parts of O, 0.5 part of MgO, 2.5 parts of CaO and 1.5 parts of loss on ignition；Print cream mainly by The group of following mass parts is grouped as: 10 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and 50 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
The content of each raw material of the anti-skid wearable glaze of the present embodiment and the constituent content of each raw material are different from embodiment 1.
Embodiment 4
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 100 Part, 100 parts of cream of print and 0.3 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO268 parts, Al2O322 parts, Fe2O3 0.25 part, TiO20.8 part, Na22.4 parts of O, K23 parts of O, 0.8 part of MgO, 1.8 parts of CaO and 0.9 part of loss on ignition；It is main to print cream It is grouped as by the group of following mass parts: 1 part of sodium carboxymethylcellulose, 55 parts of ethylene glycol and 45 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
The constituent content of each raw material of the anti-skid wearable glaze of the present embodiment is different from embodiment 3.
Embodiment 5
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 100 Part, 100 parts of cream of print and 0.3 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO265.87 part, Al2O3 22.86 Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost 0.75 part of amount；Print cream is mainly grouped as by the group of following mass parts: 2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50 Part；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Embodiment 6
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 100 Part, 100 parts of cream of print and 0.3 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO265.87 part, Al2O3 22.86 Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost 0.75 part of amount；Print cream is mainly grouped as by the group of following mass parts: 2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50 Part；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 25%, 120-180 mesh 55%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
In the present embodiment, the grain composition of anti-skid wearable particle and the difference of embodiment 5.
Embodiment 7
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 100 Part, 100 parts of cream of print and 0.3 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO265.87 part, Al2O3 22.86 Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost 0.75 part of amount；Print cream is mainly grouped as by the group of following mass parts: 2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50 Part；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.2g/cm3, flow velocity is 90 seconds.
In the present embodiment, the specific gravity and flow velocity of anti-skid wearable glaze and the difference of embodiment 5.
Embodiment 8
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: anti-skid wearable particle 100 Part, 100 parts of cream of print and 0.3 part of sodium tripolyphosphate；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO265.87 part, Al2O3 22.86 Part, Fe2O30.08 part, TiO20.99 part, Na22.22 parts of O, K24.11 parts of O, 0.43 part of MgO, 2.69 parts of CaO and burning are lost 0.75 part of amount；Print cream is mainly grouped as by the group of following mass parts: 2.5 parts of sodium carboxymethylcellulose, 50 parts of ethylene glycol and water 50 Part；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 25%, 120-180 mesh 55%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.2g/cm3, flow velocity is 90 seconds.
In the present embodiment, the grain composition of anti-skid wearable particle, the specific gravity of anti-skid wearable glaze and flow velocity with embodiment 5 It is different.
Embodiment 9
A kind of anti-skid wearable Ceramic Tiles successively include green body layer, cover coat, decorative layer from bottom to top and are mainly used anti-skidding The anti-skid wearable layer that wear-resisting glaze charity is formed after green body layer surface,
The cover coat is mainly prepared by overglaze, and the overglaze is mainly prepared by the raw material of following mass parts: 20 parts of potassium feldspar, quartzy 15 parts, 15 parts of nepheline, 5 parts of calcined kaolin, 5 parts of aluminium oxide, 1 part of wollastonite, 0.1 part of zinc oxide, silicon 10 parts of sour zirconium, 10 parts of column kaolin, 0.1 part of sodium humate, 0.1 part of sodium carboxymethylcellulose and 0.1 part of sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, it further include cover coat and decorative layer in the present embodiment.
Embodiment 10
A kind of anti-skid wearable Ceramic Tiles successively include green body layer, cover coat, decorative layer from bottom to top and are mainly used anti-skidding The anti-skid wearable layer that wear-resisting glaze charity is formed after green body layer surface,
The cover coat is mainly prepared by overglaze, and the overglaze is mainly prepared by the raw material of following mass parts: 30 parts of potassium feldspar, quartzy 30 parts, 25 parts of nepheline, 10 parts of calcined kaolin, 15 parts of aluminium oxide, 8 parts of wollastonite, 2 parts of zinc oxide, silicon 30 parts of sour zirconium, 20 parts of column kaolin, 0.3 part of sodium humate, 0.3 part of sodium carboxymethylcellulose and 0.3 part of sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, it further include cover coat and decorative layer in the present embodiment.
Embodiment 11
A kind of anti-skid wearable Ceramic Tiles successively include green body layer, cover coat, decorative layer from bottom to top and are mainly used anti-skidding The anti-skid wearable layer that wear-resisting glaze charity is formed after green body layer surface,
The cover coat is mainly prepared by overglaze, and the overglaze is mainly prepared by the raw material of following mass parts: 25 parts of potassium feldspar, quartzy 23 parts, 23 parts of nepheline, 8 parts of calcined kaolin, 10 parts of aluminium oxide, 5 parts of wollastonite, 1 part of zinc oxide, silicon 20 parts of sour zirconium, 15 parts of column kaolin, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and 0.2 part of sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, it further include cover coat and decorative layer in the present embodiment.
Embodiment 12
A kind of anti-skid wearable Ceramic Tiles successively include green body layer, cover coat, decorative layer from bottom to top and are mainly used anti-skidding The anti-skid wearable layer that wear-resisting glaze charity is formed after green body layer surface,
The cover coat is mainly prepared by overglaze, and the overglaze is mainly prepared by the raw material of following mass parts: 25 parts of potassium feldspar, quartzy 23 parts, 23 parts of nepheline, 8 parts of calcined kaolin, 10 parts of aluminium oxide, 5 parts of wollastonite, 1 part of zinc oxide, silicon 20 parts of sour zirconium, 15 parts of column kaolin, 0.2 part of sodium humate, 0.2 part of sodium carboxymethylcellulose and 0.2 part of sodium tripolyphosphate；
Anti-skid wearable layer is same as Example 8, unlike, it further include cover coat and decorative layer in the present embodiment；It is described Cover coat by ink-jet printing apparatus carry out decoration stamp obtain.
Embodiment 13
A kind of anti-skid wearable Ceramic Tiles, as different from Example 12, green body layer include the raw material of following mass parts: Yichuan 18 parts of mud, 8 parts of Guangxi White mud, 3 parts of the white mud in Ji'an, Guangchang potassium sand 30 are washed in 20 parts of sand, 15 parts of Ganzhou low temperature potassium sodium sand, Qianshan Part, 1 part of Fuzhou City's bentonite and 2.5 parts of black talc；The moisture content of blank is 6%；The grain composition of the blank are as follows: more than 20 mesh 1%, 20-40 mesh 55%, 20-60 mesh 80%, 3% below 100 mesh, remainder is 60-100 mesh；Remaining is all the same with embodiment 12.
Comparative example 1
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 80 parts of anti-skid wearable particle, Print 120 parts and 0.1 part of sodium tripolyphosphate of cream；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260 parts, Al2O320 parts, Fe2O3 0.01 part, TiO20.1 part, Na21 part of O, K21 part of O, 0.01 part of MgO, 0.1 part of CaO and 0.1 part of loss on ignition；It is main to print cream It is grouped as by the group of following mass parts: 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and 40 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Unlike the first embodiment, the content of anti-skid wearable particle, print cream and sodium tripolyphosphate does not exist in this comparative example In range provided by the present invention.
Comparative example 2
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 80 parts of anti-skid wearable particle, Print 80 parts and 0.1 part of sodium tripolyphosphate of cream；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO255 parts, Al2O332 parts, Fe2O3 2 parts, TiO23 parts, Na26 parts of O, K20.1 part of O, 1.1 parts of MgO, 0.01 part of CaO and 3 parts of loss on ignition；Cream is printed mainly by following The group of mass parts is grouped as: 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and 40 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Unlike the first embodiment, anti-skid wearable particle in this comparative example, print the content of cream and sodium tripolyphosphate, and The constituent content of anti-skid wearable particle is not in range provided by the present invention.
Comparative example 3
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 90 parts of anti-skid wearable particle With 90 parts of cream of print；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260 parts, Al2O320 parts, Fe2O3 0.01 part, TiO20.1 part, Na21 part of O, K21 part of O, 0.01 part of MgO, 0.1 part of CaO and 0.1 part of loss on ignition；It is main to print cream It is grouped as by the group of following mass parts: 5 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and 40 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Unlike the first embodiment, sodium tripolyphosphate is free of in the raw material of this comparative example.
Comparative example 4
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 90 parts of anti-skid wearable particle, Print 90 parts and 0.2 part of sodium tripolyphosphate of cream；
Wherein, anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260 parts, Al2O320 parts, Fe2O3 0.01 part, Na21 part of O, K21 part of O, 0.01 part of MgO, 0.1 part of CaO and 0.1 part of loss on ignition；Cream is printed mainly by following mass parts Group be grouped as: 2 parts of sodium carboxymethylcellulose, 40 parts of ethylene glycol and 40 parts of water；
The grain composition of anti-skid wearable particle are as follows: 80-120 mesh 35%, 120-180 mesh 45%, remaining is below 200 mesh； The specific gravity of the anti-skid wearable glaze is 1.1g/cm3, flow velocity is 120 seconds.
Unlike the first embodiment, TiO is free of in the component of the anti-skid wearable particle of this comparative example2。
Comparative example 5
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: common high temperature light is transparent 90 parts of glaze block, 90 parts of cream of print and 0.2 part of sodium tripolyphosphate.
Unlike the first embodiment, in this comparative example, common high temperature light clear frit block is selected from: clear frit, model TC1168, Zibo day are produced at enamel frit makeing Co., Ltd.
Comparative example 6
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: common high temperature matt is transparent 90 parts of glaze block, 90 parts of cream of print and 0.2 part of sodium tripolyphosphate.
Unlike the first embodiment, in this comparative example, common high temperature matt clear frit block is selected from: matt fused block, model TC9071, Zibo day are produced at enamel frit makeing Co., Ltd.
Comparative example 7
A kind of anti-skid wearable Ceramic Tiles, including green body layer use anti-skid wearable glaze charity shape after green body layer surface with main At anti-skid wearable layer, the anti-skid wearable glaze is mainly prepared by the raw material of following mass parts: 90 parts of normal transparent dry granular, Print 90 parts and 0.2 part of sodium tripolyphosphate of cream.
Unlike the first embodiment, in this comparative example, common dry granular is selected from: three degree dryout grain, model TC2600, Zibo It is produced at enamel frit makeing Co., Ltd.
Table 1 is the performance test results of the anti-skid wearable Ceramic Tiles in embodiment 1-13 and comparative example 1-7.
1 the performance test results of table
It explains: carrying out abrasion test first, in accordance with the regulation of GB/T3810.7, go round and round a millstone after damage through 12000: if (1) product table Then face is tested without appreciable wear according to the regulation of GB/T3810.14, if pollution cannot wipe, wear-resisting grade is set to 4 grades, if Pollution can wipe, and wear-resisting grade is set to 5 grades；(2) if product surface has appreciable wear, wear-resisting grade is set to 3 grades.
By the performance test results of table 1 it is found that the anti-skid factor of embodiment 1-13 is above 0.5, wear-resisting grade is at 4 grades Or more, and the anti-skid factor of comparative example 1-7 is not higher than 0.5, wear-resisting grade is 3 grades, is thus illustrated, provided by the present invention Anti-skid wearable Ceramic Tiles have good non-skid property and wear-resisting property, change anti-skid wearable glaze raw material composition or raw material contain Amount can make its anti-skid wearable degradation using existing glaze.
In addition, from the performance test results of embodiment 5-8 it is found that using the present invention be preferably carried out mode obtain it is anti-skidding The non-skid property and wear-resisting property of wear-resistant ceramic brick are more preferable, illustrate the above-mentioned object for being preferably carried out each raw material of mode comprehensive consideration Physicochemical property, it is scientific and reasonable, and then the non-skid property and wear-resisting property of Ceramic Tiles can be further increased.
In addition, after from the performance test results of embodiment 9-13 it is found that increasing cover coat and decorative layer, Ceramic Tiles it is anti- Sliding coefficient and wear-resisting grade are showed no and are substantially reduced, and it is good to illustrate that above-mentioned cover coat and decorative layer can be formed with anti-skid wearable layer In conjunction with, and the non-skid property and wear-resisting property of product will not be damaged；Through observation shows that increasing cover coat and decorative layer Afterwards, the case shell of Ceramic Tiles is more abundant, and picture on surface is more diversified, and aesthetics is more preferable, with good economic efficiency.
Although illustrate and describing the present invention with specific embodiment, it will be appreciated that without departing substantially from of the invention Many other change and modification can be made in the case where spirit and scope.It is, therefore, intended that in the following claims Including belonging to all such changes and modifications in the scope of the invention.

Claims (10)

1. a kind of anti-skid wearable Ceramic Tiles, which is characterized in that including green body layer and mainly using the charity of anti-skid wearable glaze in green body The anti-skid wearable layer formed after layer surface, the anti-skid wearable glaze are mainly prepared by the raw material of following mass parts: anti-skidding resistance to 90-110 parts of abrasive particle, cream 90-110 parts and 0.2-0.4 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO260-70 parts, Al2O320-30 parts, Fe2O3 0.01-1 parts, TiO20.1-2 parts, Na21-5 parts of O, K21-10 parts of O, 0.01-1 parts of MgO, 0.1-5 parts of CaO and loss on ignition 0.1-2 parts.
2. anti-skid wearable Ceramic Tiles according to claim 1, which is characterized in that the anti-skid wearable glaze is mainly by following matter The raw material of amount part is prepared: 92-108 parts of anti-skid wearable particle, cream 92-108 parts and 0.22-0.38 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO261-69 parts, Al2O321-29 parts, Fe2O3 0.02-0.09 parts, TiO20.2-1.9 parts, Na21.5-4.5 parts of O, K22-9 parts of O, 0.1-0.9 parts of MgO, 1-4 parts of CaO and 0.2-1.9 parts of loss on ignition.
3. anti-skid wearable Ceramic Tiles according to claim 1, which is characterized in that the anti-skid wearable glaze is mainly by following matter The raw material of amount part is prepared: 94-106 parts of anti-skid wearable particle, cream 94-106 parts and 0.24-0.36 parts of sodium tripolyphosphate of print；
The anti-skid wearable particle is mainly grouped as by the group of following mass parts: SiO262-68 parts, Al2O322-28 parts, Fe2O3 0.04-0.08 parts, TiO20.4-1.8 parts, Na22-4 parts of O, K23-8 parts of O, 0.2-0.8 parts of MgO, 2-3 parts of CaO and burning are lost 0.3-1.8 parts of amount.
4. anti-skid wearable Ceramic Tiles according to claim 1-3, which is characterized in that the print cream is mainly by following The group of mass parts is grouped as: 2-3 parts of sodium carboxymethylcellulose, 40-60 parts of ethylene glycol and 40-60 parts of water.
5. anti-skid wearable Ceramic Tiles according to claim 1-3, which is characterized in that the anti-skid wearable particle Grain composition are as follows: 80-120 mesh 20%-30%, 120-180 mesh 50%-60%, remaining is below 200 mesh.
6. anti-skid wearable Ceramic Tiles according to claim 1-3, which is characterized in that the ratio of the anti-skid wearable glaze Weight is 1.2-1.8g/cm3。
7. anti-skid wearable Ceramic Tiles according to claim 1-3, which is characterized in that the stream of the anti-skid wearable glaze Speed is 80-100 seconds.
8. anti-skid wearable Ceramic Tiles according to claim 1, which is characterized in that the green body layer and the anti-skid wearable layer Between be additionally provided with cover coat and decorative layer, the decorative layer is set between the cover coat and the anti-skid wearable layer.
9. anti-skid wearable Ceramic Tiles according to claim 8, which is characterized in that the cover coat mainly by overglaze prepare and At the overglaze is mainly prepared by the raw material of following mass parts: 20-30 parts of potassium feldspar, 15-30 parts of quartz, nepheline 15-25 Part, 5-10 parts of calcined kaolin, 5-15 parts of aluminium oxide, 1-8 parts of wollastonite, 0.1-2 parts of zinc oxide, 10-30 parts of zirconium silicate, column 10-20 parts of kaolin, 0.1-0.3 parts of sodium humate, 0.1-0.3 parts of sodium carboxymethylcellulose and 0.1-0.3 parts of sodium tripolyphosphate.
10. anti-skid wearable Ceramic Tiles according to claim 8 or claim 9, which is characterized in that the decorative layer includes together or more Road lamina printing decoration, one or multi-channel roller printing and one or more of ink-jet printed combination.
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Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019015237A1 (en) * 2017-07-21 2019-01-24 广东金意陶陶瓷集团有限公司 Anti-slip wear-resistant glaze, anti-slip wear-resistant easy-clean ceramic tile, and preparation method therefor
US10475264B2 (en) 2017-08-14 2019-11-12 Q & K International Group Limited Application method of Bluetooth low-energy electronic lock based on built-in offline pairing passwords, interactive unlocking method of a Bluetooth electronic lock and electronic lock system
CN107963814B (en) * 2017-11-16 2021-05-07 蒙娜丽莎集团股份有限公司 Composite glaze, composite glaze slip and 4-8 degree soft surface wear-resistant porcelain archaized brick
CN108298950A (en) * 2018-01-29 2018-07-20 佛山生态海绵城市科技发展有限公司 A kind of preparation method of the sponge water-permeable brick with marble grain
CN108383386A (en) * 2018-01-29 2018-08-10 佛山生态海绵城市科技发展有限公司 A kind of protection glaze applied in water-permeable brick and application method
CN108505715B (en) * 2018-04-16 2020-01-17 广东金意陶陶瓷集团有限公司 High-heat-conductivity long-service-life electric heating ceramic tile and manufacturing method thereof
CN110092590B (en) * 2019-04-26 2022-05-17 江西和美陶瓷有限公司 Antiskid glaze and antiskid ceramic tile
CN112851369A (en) * 2021-01-28 2021-05-28 成都新西南陶瓷艺术股份公司 Production process of anti-skid ceramic tile
CN112723743B (en) * 2021-03-30 2021-06-25 广东欧文莱陶瓷有限公司 Dry grain rock plate and preparation method thereof
CN113429130B (en) * 2021-08-30 2021-11-30 佛山市大角鹿大理石瓷砖有限公司 Flash super-wear-resistant diamond glaze, ceramic tile and preparation method thereof
CN115745568B (en) * 2022-12-02 2023-11-17 淄博锦昊陶瓷有限公司 Wear-resistant ceramic tile and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104261897A (en) * 2014-09-25 2015-01-07 佛山市三水新明珠建陶工业有限公司 Ceramic tile having antiskid effect and manufacturing method thereof
CN106336198A (en) * 2016-08-30 2017-01-18 王爱纯 Ceramic material for electric cooker inner tank use
CN106673435A (en) * 2016-12-26 2017-05-17 澧县新鹏陶瓷有限公司 Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104261897A (en) * 2014-09-25 2015-01-07 佛山市三水新明珠建陶工业有限公司 Ceramic tile having antiskid effect and manufacturing method thereof
CN106336198A (en) * 2016-08-30 2017-01-18 王爱纯 Ceramic material for electric cooker inner tank use
CN106673435A (en) * 2016-12-26 2017-05-17 澧县新鹏陶瓷有限公司 Wearproof frit dry granules using waste glaze as main raw material and preparation method thereof

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