CN106396407A - Mineral crystal fancy glaze capable of releasing negative ions and ceramic tile produced by using mineral crystal fancy glaze - Google Patents
Mineral crystal fancy glaze capable of releasing negative ions and ceramic tile produced by using mineral crystal fancy glaze Download PDFInfo
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- CN106396407A CN106396407A CN201610788750.9A CN201610788750A CN106396407A CN 106396407 A CN106396407 A CN 106396407A CN 201610788750 A CN201610788750 A CN 201610788750A CN 106396407 A CN106396407 A CN 106396407A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
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Abstract
The invention provides a mineral crystal fancy glaze capable of releasing negative ions and a ceramic tile produced by using the mineral crystal fancy glaze. The mineral crystal fancy glaze capable of releasing the negative ions is prepared from the following components in parts by mass: 100 parts of mineral crystal dry pellets, 0 to 50 parts of transparent glaze, 1 to 3 parts of tourmaline powder, 0.01 to 0.05 part of light rare earth oxide, 60 to 80 parts of printing paste, 0.2 part of carboxymethylcellulose and 25 to 40 parts of water; the mineral crystal dry pellets are prepared from the following chemical components in parts by weight of oxides: 8 parts of SiO2, 3 parts of Al2O3, 20 parts of B2O3, 9 parts of Fe2O3, 46 parts of MnO and 8 parts of TiO2. The fancy glaze contains a large amount of color development oxides, the small amount of tourmaline powder and the trace amount of light rare earth oxides; electrostatic voltage difference of the fancy glaze can be improved; a higher release effect of the negative ions is realized at less dosage. The ceramic tile produced by using the mineral crystal fancy glaze capable of releasing the negative ions can release the negative ions.
Description
Technical field
The present invention relates to architectural pottery production field, more particularly, to a kind of mineral crystal fancy glaze capable of releasing negative ion and its
The Ceramic Tiles of preparation.
Background technology
Anion is a kind of negatively charged gas ion of in the air.Various gas componants in air are not exclusively to divide
Submode exists, and a portion is existed with the free state of ion.Wherein electronegative molecule or microgranule (be commonly called as bearing from
Son) human body synthesis and vitamin storage can not only be facilitated, the physiological activity of strengthening and human activin, to human body and other biological
Vital movement has highly important impact, and therefore it is otherwise known as " air vitamin ".
Ceramic Tiles are the conventional building materials of house decoration, it is combined function capable of releasing negative ion and can adjust room air matter
Amount, improves comfort level.In the prior art, it is typically employed in composition of raw materials and adds a certain proportion of tourmaline powder, utilize and work as
When temperature and pressure changes, electric heating difference and voltage difference between tourmaline crystal can be caused, this electrostatic potential difference can be high
Reach 1.0 × 106EV, this energy be enough to make air ionize, and is converted into negative aeroion.But it is main because of tourmaline powder
Composition be characterized with boracic aluminum, sodium, ferrum, the silicate material of lithium circulus, a large amount of introducings in base substrate can cause base
Body deforms, and introduces in glaze, also the characteristic of glaze can be produced with certain impact, especially for marzacotto, though therefore
Correlation function product is so had to occur, but overall performance not up to optimum.
Ceramic Tiles therefore how are made to have negative ion-releasing function, and the change of product while obtaining abundant decorative effect
It to be the R＆D direction of those skilled in the art that shape degree is little.
Content of the invention
The present invention is directed to the technical problem propose in prior art, and the present invention provides a kind of mineral capable of releasing negative ion brilliant
Body fancy glaze, contains substantial amounts of color development metal-oxide and a small amount of tourmaline part and the oxidation of micro light rare earth in this fancy glaze
Thing, so that its electrostatic potential difference lifting, can be issued to higher anion releasing effect in less consumption.Using this
The Ceramic Tiles planting mineral crystal fancy glaze production capable of releasing negative ion can be with anion releasing.
A kind of mineral crystal fancy glaze capable of releasing negative ion, it is calculated with mass fraction, including following component：
100 parts of mineral crystal dry granular, clear frit 0-50 part, tourmaline powder 1-3 part, light rare earth oxide 0.01-0.05 part,
Print cream 60-80 part, 0.2 part of carboxymethyl cellulose, water 25-40 part,
The chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including following component：
SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
Here clear frit known to clear frit Ceramics production.Contain in the mineral crystal dry granular that the present invention provides
Substantial amounts of ferrum, manganese and titanium elements, under different firing conditions and have multiple change under base glaze component, particularly with apply
In the mode of glaze and/or printing ornament combination, because its fusing point is relatively low, how can be formed down depression, so also reduce follow-up rubbing down
The abrasion to it for the processing.And, using the mineral crystal fancy glaze of the mineral crystal dry granular preparation of multiple color development combination of oxides, will
On base substrate, particularly charity is in the billet surface through stamp and/or glazing for its charity, it is possible to obtain especially abundant mineral are brilliant
Body effect, it is possible to achieve the decorative effect that chromatography etc. is enriched.
Add tourmaline powder and light rare earth oxide in mineral crystal fancy glaze, so that its electrostatic potential difference lifting,
Higher anion releasing effect can be issued in less consumption.The mineral capable of releasing negative ion that therefore present invention provides
Crystal fancy glaze and the crystallize fancy glaze that existing use zinc oxide is primary raw material have abundant mineral crystal effect, and to have right again
The water power of in the air is from formation anion.
Preferably, before charity mineral crystal fancy glaze on Ceramic Tiles base substrate, stamp and charity protection are first carried out on base substrate
Glaze, protection glaze is known clear frit here.Here clear frit preferably has higher hardness, further illustrates, it is preferred to use 60
Purpose thickeies effect net and is printed.Mineral crystal fancy glaze can be merged with following glaze after high temperature sintering,
Form nested brilliant flower decorative effect.And, after charity protection glaze, colour generation enriches mineral crystal fancy glaze, reaches similar natural
The effect of stone material.
The present invention also provides a kind of production technology of Ceramic Tiles capable of releasing negative ion, and it comprises the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) in cover-coat enamel known to billet surface charity, form cover coat；
Step 3) stamp is carried out on cover coat, form printed layer；
Step 4) protect glaze in stamp layer surface charity；
Step 5) charity mineral crystal fancy glaze, mineral crystal fancy glaze is calculated with mass fraction, including following component：Mineral are brilliant
100 parts of soma grain, clear frit 0-50 part, tourmaline powder 1-3 part, light rare earth oxide 0.01-0.05 part, print cream 60-80 part, carboxylic
0.2 part of methylcellulose, water 25-40 part, the chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including
Following component：SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts；
Step 6) enter kiln and fire；
Step 7) base substrate after burning till is polished and edging process, obtain ceramic brick product.
Step 6) firing temperature be 1175～1185 DEG C, firing period be 60～70min.
Preferably, in the above-mentioned methods, step 2) and step 3) between also include brightening the step of glaze by silk screen printing
Suddenly, the described glaze that brightens is calculated with mass fraction, including following component：Clear frit：50 parts, Zirconium orthosilicate.：50 parts, print cream：65
Part, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
Here Zirconium orthosilicate. is to brighten Main Ingredients and Appearance, and it is coordinated with special clear frit, adjusts it using print cream
Printing effect, to reach the effect that base substrate is preferably brightened.Here print cream is the print of commercially available traditional regulation glaze charity effect
Cream, its exemplary group is divided into, and calculates according to the mass fraction：Methyl：1.3 parts, ethylene glycol：35 parts, water：35 parts, preservative：0.001
Part.This brightens glaze, and using clear frit and Zirconium orthosilicate. as Main Ingredients and Appearance, wherein clear frit is to firing temperature and sintering effect
It is adjusted, Zirconium orthosilicate. is brightened, combined by both, on the premise of production cost is relatively low, so that the base substrate after burning is had
Higher whiteness, and can be with effective control blank deformation by way of screen printing.
In order to ensure whitening effect, the Ceramic Tiles that produced using it, brightening glaze is by silk screen printing side at least twice
In billet surface, the number of times of silk screen printing is more for formula charity, the glaze layer being correspondingly formed thicker it is however generally that, need to carry out two
Secondary printing, can reach cost whiteness 60-68 degree after burning twice afterwards, can reach 72-78 degree for three times, can reach 80- four times
83 degree.By the way of drenching glaze, whiteness is substantially stationary, and selects the mode of silk screen printing, can print number of times pair by different
After base substrate burns, whiteness is adjusted, and so that process matching width is greatly promoted, in the situation of corresponding difference whiteness demand
Under, it is possible to use lower cost realizes technological requirement.
Preferably, in step 3) and step 4) between also include charity increase pink blossom glaze step, in printed layer pass through silk
Wire mark flower mode prints the increasing pink blossom glaze for complementary color, and described increasing pink blossom glaze is calculated with mass fraction, including following component：High boron
Calcareous clear frit：12 parts, complementary color colorant 0.1-10 part, carboxymethyl cellulose：1.3 parts, ethylene glycol：45 parts, water：40 parts；Institute
The chemical constituent stating the calcareous clear frit of high boron is calculated with oxide weight number, including following component：Na2O:6 parts, CaO:12
Part, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；Described complementary color colorant is one kind of known pottery glaze stain
Or multiple combination.
When carrying out printing ornament, for the color of high saturation, it is extremely difficult to corresponding color saturation, therefore in print
It can be carried out after spending with hyperchromic process, complementary color colorant used herein above is the inorganic pigment well known to Production of Ceramics, its choosing
Select and organic assembling can be carried out according to different complementary color effects.Frit used herein is the calcareous clear frit of high boron, frit
In also have higher calcium boron matter raw material, simultaneously also using the zinc oxide of larger consumption, also adjust while promoting pigment color development
Hardness after glaze burning.Here the printing mode increasing pink blossom glaze is preferably after stamp, using consistent with decalcomania texture
Set floral pattern (depending on meshcount is according to the required depth heightening the color and clear patterns degree, mesh number scope is in 80-250
Mesh, bigger using meshcount, pattern definition is higher, but the amplitude that can heighten the color is less；And use the mesh number of silk screen
Less, then the definition of pattern and fine and smooth degree are lower, but the effect that heightens the color can be higher).
Further preferably, in step 3) and step 4) between also include the step that color fancy glaze supported by cloth, described help color fancy glaze
Calculated with mass fraction, including following component：100 parts of high zinc matter frit, prints 130 parts of cream, 0.3 part of sodium tripolyphosphate, 40 parts of water；
The chemical constituent of described high zinc matter frit is calculated with oxide weight number, including following component：SiO2:53 parts, ZnO:21 parts,
K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
Preferably, in above-mentioned technique, color fancy glaze is helped to adopt silk-screen printing technique to print 140 mesh full impregnated nets, for ensureing fancy glaze
Uniform fold, will not cause because of the thickness difference helping color fancy glaze and help aberration different thus producing two tone colour, using print twice 140 purpose
Full impregnated net is carrying out complementation.
Preferably, in above-mentioned technique, described printing helps the step of color fancy glaze after printing increasing pink blossom glaze step.
Compared to the prior art, the mineral crystal fancy glaze that the present invention provides, the pottery by its charity on base substrate, after burning till
Brick can assume the grain effect of abundant natural minerals crystal, obtains the decoration texture of similar lithotome.And because it contains
After substantial amounts of burning, the metallic element of colour generation, can make the tourmaline of wherein interpolation and light rare earth oxide play one's part to the full.Will
This glaze charity can obtain mineral crystal fancy glaze capable of releasing negative ion after billet surface, sintering.
Specific embodiment
Below by some specific embodiments, the present invention program to be described.
Embodiment 1
The present embodiment provides a kind of mineral crystal fancy glaze, and it is calculated with mass fraction, including following component：
100 parts of mineral crystal dry granular, clear frit 0-50 part, print cream 60-80 part, 0.2 part of carboxymethyl cellulose, water 25-40
Part,
The chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including following component：
SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
Here clear frit known to clear frit Ceramics production.Contain in the mineral crystal dry granular that the present invention provides
Substantial amounts of ferrum, manganese and titanium elements, under different firing conditions and have multiple change under base glaze component, particularly with apply
In the mode of glaze and/or printing ornament combination, because its fusing point is relatively low, how can be formed down depression, so also reduce follow-up rubbing down
The abrasion to it for the processing.
Embodiment 2
The present embodiment provides the technique producing pottery using the mineral crystal fancy glaze implementing 1 offer.
A kind of ceramic tile production technique, it comprises the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) billet surface by drench glaze by way of cover-coat enamel known to charity, formed cover coat；
Step 3) stamp is carried out on cover coat, form printed layer；
Step 4) protect glaze in stamp layer surface charity；
Step 5) charity mineral crystal fancy glaze, mineral crystal fancy glaze is calculated with mass fraction, including following component：Mineral are brilliant
100 parts of soma grain, clear frit 0-50 part, print cream 60-80 part, 0.2 part of carboxymethyl cellulose, water 25-40 part, described mineral crystal
The chemical constituent of dry granular is calculated with oxide weight number, including following component：SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts,
Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts；
Step 6) enter kiln and fire；
Step 7) base substrate after burning till is polished and edging process, obtain ceramic brick product.
Step 6) firing temperature be 1175～1185 DEG C, firing period be 60～70min.
Wherein, described step 1) in blank formulation be common glazed ceramic brick body recipe, here provide one show
The formula of example property.For ensureing the flatness of product and ripple glaze deformation, 21% about, whiteness is on 35 degree left sides for base substrate aluminum content
The right side, it is as follows that its formula presses mass fraction：Yichuan sand：20 parts, Ganzhou low temperature potassium sodium sand：15 parts, mud is washed in Qianshan：16～20 parts,
Guangxi White mud：8 parts, 3 parts of the white mud in Ji'an, Guangchang potassium sand：31 parts, Fuzhou City's bentonite：1 part, black talc：2～3 parts.Using wet method
Ball milling method, Ball-milling Time 11～12 hours；After slurry fineness was 250 mesh sieves, tail over as 1.6～2.0 grams；Blank moisture content
For 6～6.5%, its grain composition：More than 20 mesh 0～1.5%, -20～+40 mesh 30～60%, -20～+60 mesh 72～88%,
0～6% below 100 mesh, remaining is -60～+100 mesh.
Step 2) cover-coat enamel that uses is to ensure product sintering temperature, brick, the common ceramic glaze of effect fancy glaze stereoeffect
The conventional cover-coat enamel of surface ceramic tile, as follows by mass fraction：Potassium feldspar：25 parts, quartz：15～30 parts, nepheline：15～25 parts, forge
Burn Kaolin：7 parts, aluminium oxide：10 parts, wollastonite：4 parts, zinc oxide：1 part, Zirconium orthosilicate.：20 parts, CNH00058：10～15 parts,
Sodium humate：0.2, carboxymethyl cellulose:0.2 part, sodium tripolyphosphate：0.15 part, by the way of wet ball grinding, ball milling 4～5
Hour；Cover-coat enamel proportion 1.75～1.85g/cm3, the flow velocity 30-35 second, after crossing 325 mesh sieves, tail over as 3～4 grams.Cover-coat enamel is to base substrate
Covered, reduced the impact to glaze paint for the impurity in base substrate.
Embodiment 3
A kind of Ceramic Tiles, it by the structure on lower is：Including green body layer, cover coat, brighten glaze layer, decalcomania
Layer, increase pink blossom glaze layer, help color fancy glaze layer, protection glaze layer and mineral crystal fancy glaze layer.
Its preparation technology comprises the steps：
The present invention also provides a kind of production technology of Ceramic Tiles, and it comprises the steps：
Step 1) base raw material through dispensing, ball milling be obtained slurry, then remove ferrum, sieve, old, powder by spraying after sieve,
Prepared blank；
Step 2) by press, blank is pressed, prepare base substrate；
Step 3) base substrate is put into dry kiln it is dried；
Step 4) carry out charity cover-coat enamel by the way of drenching glaze；
Step 5) glaze is brightened using silk screen printing brightened；
Step 6) carry out decorating stamp by ink-jet printing apparatus；
Step 7) color that pink blossom glaze compensates needs reinforcement is increased by silk screen printing；
Step 8) help color fancy glaze to help color development by silk screen printing；
Step 9) protect glaze layer that ink-jetting pattern is protected by silk screen printing；
Step 10) pass through silk screen printing mineral crystal fancy glaze；
Step 11) enter kiln and be fired；
Step 12) polishing；
Step 13) edging, quality inspection, packaging obtain final product.
Wherein, the blank formulation in described step 1 is the body recipe of common glazed ceramic brick, provides an example here
The formula of property.For ensureing the flatness of product and ripple glaze deformation, base substrate aluminum content 21% about, whiteness at 35 degree about,
It is as follows that its formula presses mass fraction：Yichuan sand：20 parts, Ganzhou low temperature potassium sodium sand：15 parts, mud is washed in Qianshan：16～20 parts, Guangxi
White mud：8 parts, 3 parts of the white mud in Ji'an, Guangchang potassium sand：31 parts, Fuzhou City's bentonite：1 part, black talc：2～3 parts.Using wet ball grinding
Mode, Ball-milling Time 11～12 hours；After slurry fineness was 250 mesh sieves, tail over as 1.6～2.0 grams；Blank moisture content is 6
～6.5%, its grain composition：More than 20 mesh 0～1.5%, -20～+40 mesh 30～60%, -20～+60 mesh 72～88%, 100
0～6% below mesh, remaining is -60～+100 mesh.
Baking temperature in step 3 is 100～160 DEG C, and arid cycle is 50～70min.Drying is to remove base substrate
In unnecessary moisture content, this guarantee product quality, be typically dried process.
Cover-coat enamel formula in step 4, for ensureing the common porcelain of product sintering temperature, brick, effect fancy glaze stereoeffect
The conventional cover-coat enamel of glazed ceramic brick, as follows by mass fraction：Potassium feldspar：25 parts, quartz：15～30 parts, nepheline：15～25 parts,
Calcined kaolin：7 parts, aluminium oxide：10 parts, wollastonite：4 parts, zinc oxide：1 part, Zirconium orthosilicate.：20 parts, CNH00058：10～15
Part, sodium humate：0.2, carboxymethyl cellulose:0.2 part, sodium tripolyphosphate：0.15 part, by the way of wet ball grinding, ball milling 4
～5 hours；Cover-coat enamel proportion 1.75～1.85g/cm3, the flow velocity 30-35 second, after crossing 325 mesh sieves, tail over as 3～4 grams.Cover-coat enamel is to base
Body is covered, and reduces the impact to glaze paint for the impurity in base substrate.
Brighten fancy glaze in described step 5,80 mesh full impregnated nets are printed using silk-screen printing technique, print twice brighten fancy glaze, burn
After one-tenth, in 60-68 degree, Yin Sandao brightens fancy glaze to finished product whiteness, and in 72-78 degree, Yin Sidao brightens fancy glaze to finished product whiteness, and finished product is white
Degree is in 80-83 degree.Brighten fancy glaze as follows by mass fraction：Clear frit:50 parts, Zirconium orthosilicate.：50 parts, print cream:65 parts, trimerization phosphorus
Sour sodium：0.3 part, water：35 parts.The glaze slip using after ball milling needs to reach following requirement：325 mesh sieves tail over 0.05-0.1%, than
1.55-1.58 gram/cc of weight.The composition of clear frit is following (calculating of oxide mass number):Na2O:5 parts, CaO:9
Part, ZnO:8,Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.Print cream is that common fancy glaze print cream (is chosen as Dow in the present embodiment
The DS4003 of science and technology), it is counted as point as follows according to the mass fraction：Carboxymethyl cellulose：1.3 parts, ethylene glycol：35 parts, water：35 parts,
Preservative：0.001 part.
Brighten mode in view of glaze for glazed tile, can by improve base substrate whiteness and raising cover-coat enamel whiteness reach similar
Effect, brightens mode around these three in experimentation and does a lot of work.
The serial example 1 of contrast：Under the experiment condition of fixing step 2,3,4,5,6,7,8,9,10,11,12,13, only to step
Base substrate whiteness in rapid 1 is adjusted, and draws following table：
Base substrate is the basis of product, and its deformation has a direct impact to follow-up finished product glacing flatness and ripple glaze, by adopting
Selected raw material can improve finished product whiteness to a certain extent, but raw material is required too high.Also indivedual enterprises are had to be to reach in industry
To preferable base substrate whiteness, to be realized by slow burning (reducing more than half yield), thus can relax to base substrate composition
Require, the problems such as without excessively considering the deformation producing due to due to base substrate composition, a large amount of blank raw materials using high whiteness,
But because yield is too low, cost input is too big, also do not reach preferable whiteness simultaneously.Adjust the mode of whiteness using body recipe
Sexual valence is poor.
The serial example 2 of contrast：Under the experiment condition of fixing step 1,2,3,5,6,7,8,9,10,11,12,13, only to step
Cover-coat enamel formula in rapid 4 is adjusted, simultaneously remaining component in fixing step 4, only the Zirconium orthosilicate. to impact whiteness most critical
Number be adjusted, draw following table：
| Zirconium orthosilicate. number in cover-coat enamel | Finished product whiteness | Cost | Finished product deforms (mm) |
| 10 | 42 | 0.6 yuan/square metre | Positive and negative 0.1 |
| 20 | 51 | 1.2 yuan/square metre | Positive 0.2 |
| 30 | 56 | 1.8 yuan/square metre | Positive 0.4 |
| 40 | 60 | 2.4 yuan/square metre | Positive 0.55 |
| 60 | 65 | 3.6 yuan/square metre | Positive more than 0.8 |
Because the coefficient of expansion of Zirconium orthosilicate. is less, if excessive add the deformation that can have a strong impact on product in cover-coat enamel so that producing
Product increasingly encircle with the increase adding Zirconium orthosilicate. amount, product.Simultaneously in cover-coat enamel after addition is a certain amount of, the impact to whiteness is got over
Come weaker, and the glaze volume of cover-coat enamel is relatively thick, so this scheme is also with high costs in the case of not reaching preferable whiteness,
But comparatively brightened using cover-coat enamel plus Zirconium orthosilicate. and either will be better than for the lifting of whiteness still becomes present aspect
Increase the input of base substrate whiteness and the effect of generation.
The serial example 3 of contrast：Under the experiment condition of fixing step 1,2,3,4,6,7,8,9,10,11,12,13, only to step
Rapid 5 brighten glaze is adjusted, and draws following table：
By the research of three of the above mode, we can draw, brightens fancy glaze layer come improving product by silk screen printing
The technical scheme of whiteness, to consider from the whitening effect that can reach, production stability, product quality and integrated cost hence it is evident that
Better than the technical scheme lifting whiteness in terms of base substrate and cover-coat enamel.Preferable whiteness can be reached moreover it is possible to ensure the deformation of product
Deng in product in, external quality, and Optimum cost.This also exactly the present invention program advantage be located, by change tradition
Improve base substrate whiteness using drenching glaze mode, glaze layer is thicker and is difficult to adjust, the scheme that the present invention provides, there is provided a kind of suitable
Silk screen printing brighten glaze, it is used for ceramic tile production, can be reached different white by way of printing the different numbers of plies
Degree effect, makes process window more wide in range, is issued to best effect in the minimum situation of cost.
Increasing pink blossom glaze in step 7, using silk-screen printing technique, prints the set floral pattern consistent with ink-jetting pattern texture
(depending on meshcount is according to the required depth heightening the color and clear patterns degree, mesh number scope in 80-250 mesh, in this product
Use 160 mesh effect nets.Bigger using meshcount, pattern definition is higher, but the amplitude that can heighten the color is less；
And use silk screen mesh number less, then the definition of pattern and fine and smooth degree are lower, but the effect that heightens the color can be higher) so that
The color that InkJet printing processes do not reach can be compensated by increasing powder craft, thus reaching more abundant, face true to nature
Color effect.In product development and production process, can according to product need adjust silk-screen patterns and colorant proportioning, thus reaching
To the various patterns wanted and color.It is as follows that increasing pink blossom glaze presses mass fraction：The calcareous clear frit of high boron：12 parts, Jin Zong：3.3
Part, reddish brown：0.6 part, parcel is red：3 parts, parcel is yellow：0.6 part, carboxymethyl cellulose：1.3 parts, ethylene glycol：45 parts, water：40 parts.
Here the calcareous frit of high boron is calculated with oxide mass number：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3
Part, SiO2:54 parts.Need exist for illustrating, Jin Zong, reddish brown, parcel is red and parcel Huang is the inorganic pigment of glaze, its select and
Proportioning, to need the color increasing powder as reference, is mated according to actual toning experience.Ink-jet can be realized using increasing pink blossom glaze
The unapproachable gray scale of stamp.
Help color fancy glaze in step 8,140 mesh full impregnated nets are printed using silk-screen printing technique, for ensureing fancy glaze uniform fold, no
Can cause because of the thickness difference helping color fancy glaze helps aberration different thus producing two tone colour, and the full impregnated net using print twice 140 mesh to enter
Row is complementary.Help color fancy glaze as follows by mass fraction：High zinc matter frit:100 parts, DS4003 (the print cream of Dow):130 parts, trimerization：
0.3 part, water：40 parts.325 mesh sieves tail over as 0.1-0.2%, and proportion is 1.32-1.35 gram/cc.High zinc matter frit with
Chemical oxide mass fraction calculates：SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
Under the experiment condition of fixing step 1,2,3,4,5,6,7,9,10,11,12,13, only step 8 is adjusted,
Show that print helps color fancy glaze and not printing to help color fancy glaze to contrast：Coloring intensity lifting more than 10%, so can save the ink of costliness
And colorant, advantageously reduce production cost.
Protection glaze layer in described step 9, prints 80 mesh full impregnated nets using silk-screen printing technique or carries veined effect net,
Textured effect net would generally be nested flower with the inkjet printing pattern of the step 6 of as described before, and according to protection glaze thickness
Thin needs select print 1-3 road silk screen fancy glaze, for ensureing the needs of later stage cold working polishing, generally select using print 3 road silk screens
Fancy glaze, by print clear frit or complete throw glaze and other effects glaze so that ink-jetting pattern be difficult to be worn during routine use or
Be conducive to this series of products is carried out with the cold work in later stage.It is as follows that protection glaze fancy glaze presses mass fraction：DJY801-G2 is (big
The low-temperature transparent protection glaze of border science and technology):70 parts, DJY801-121 (the temperature resistant transparent protection glaze of big border science and technology):30 parts, DS4003
(the print cream of Dow):47 parts, sodium tripolyphosphate：0.3 part, water：25 parts.250 mesh sieves tail over 0.7-1.0%, proportion 1.60-1.63
Gram/cc.This protection glaze layer can also be other clear frits or entirely throw glaze.DJY801-G2 composition presses the matter of oxide
Amount number is calculated as follows：SiO2:67 parts, Al2O3:14 parts, CaO:12 parts, B2O3:5 parts.DJY801-121 composition presses oxidation material
Amount number is calculated as follows：SiO2:51 parts, Al2O3:15,K2O part:2,Na2O:5 parts, MgO:3.2 parts, CaO:10 parts, B2O3:8 parts.
Mineral crystal fancy glaze in step 10, prints 60 mesh effect nets, this effect net pattern texture using silk-screen printing technique
It is mutually matched (set flower) with the inkjet printing pattern of as described before step 6, in the place printing to mineral crystal fancy glaze, mineral crystal
Fancy glaze can be merged with following fancy glaze, and (high temperature viscosity of mineral crystal fancy glaze is relatively low, and metal oxide content is higher and molten
Also ratio is relatively low to melt temperature, can melt and arrange following glaze layer during burning till) so that this local pattern sink (under
Sunken effect can ensure that the pattern of mineral crystal, effect will not be disposed when product is carried out with cold working polishing), produce simultaneously
Raw mineral crystal effect.It is as follows that mineral crystal fancy glaze formula presses mass fraction：100 parts of mineral crystal dry granular, clear frit 0-50 part
(needing to change according to calcining system), print cream (the print cream of Dow) 60-80 (change adjustment usage amount according to formula and reach need
The fancy glaze proportion wanted) part, 0.2 part of carboxymethyl cellulose, water 25-40 part, the particle diameter of mineral crystal dry granular：80～120 mesh account for 70
～80%, remainder is by 120 mesh, fancy glaze proportion 1.6～1.7g/cm3, after crossing 320 mesh sieves, tail over as 0.1 gram.Mineral crystal
Fancy glaze thickeies effect net by 60 mesh together and is printed.Mineral crystal dry granular is as follows with chemical oxide composition：SiO2:8 parts,
Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
Clear frit is calculated with oxide component, and its chemical constituent is as follows：SiO2:55 parts, Al2O3:14 parts, K2O:2 parts,
Na2O:6 parts, MgO:2 parts, CaO:10 parts, B2O3:8 parts.
Firing temperature in step 11 is 1175～1185 DEG C, and firing period is 60～70min.
Polishing edging is the common process of Production of Ceramics, and correspondence carries out selecting here.
Embodiment 4
In the present embodiment, give this product with negative ion health function.
Anion is a kind of negatively charged gas ion of in the air.Various gas componants in air are not exclusively to divide
Submode exists, and a portion is existed with the free state of ion.Wherein electronegative molecule or microgranule (be commonly called as bearing from
Son) human body synthesis and vitamin storage can not only be facilitated, the physiological activity of strengthening and human activin, to human body and other biological
Vital movement has highly important impact, and therefore it is otherwise known as " air vitamin ".
In the prior art, be typically employed in composition of raw materials and add a certain proportion of tourmaline powder, using when temperature and
When pressure changes, electric heating difference and voltage difference can be caused between tourmaline crystal, this electrostatic potential difference can be up to 1.0 ×
106EV, this energy be enough to make air ionize, and is converted into negative aeroion.But the main component because of tourmaline powder is
The aluminum that is characterized with boracic, sodium, ferrum, the silicate material of lithium circulus, a large amount of introducings in base substrate can cause blank deformation,
And introduce in glaze, also the characteristic of glaze can be produced with certain impact, especially for marzacotto, thus while there being correlation
Functional product occurs, but overall performance not up to optimum.
Pin in this regard, the present embodiment provide corresponding solution, because tourmaline powder need and air contact could produce right
The effect answered.Therefore, in the present embodiment, the component of mineral crystal fancy glaze is improved, introduce tourmaline powder wherein
With improvement component, it is allowed to both there is abundant brilliant flower decorative effect, with more negative ion health function.
Concrete scheme is as follows：
It is as follows that the present embodiment provides mineral crystal fancy glaze formula to press mass fraction：100 parts of mineral crystal dry granular, tourmaline powder
1-3 part, light rare earth oxide 0.01-0.05 part, 20 parts of clear frit (corresponding firing temperature is suitably selected), print cream
(the print cream of Dow) 60-80 (the fancy glaze proportion that adjustment usage amount reaches needs is changed according to formula) part, carboxymethyl cellulose
0.2 part, water 25-40 part, the particle diameter of mineral crystal dry granular：80～120 mesh account for 70～80%, and remainder is by 120 mesh, fancy glaze ratio
Weigh 1.6～1.7g/cm3, after crossing 320 mesh sieves, tail over as 0.1 gram.Mineral crystal fancy glaze thickeies effect net by 60 mesh together and enters
Row printing.
The use number of clear frit can be 0-50 part, and it uses root in order to adjust firing temperature and effect, marzacotto
Suitably adjusted according to firing temperature and service condition.
This programme adds a small amount of tourmaline powder and micro light rare earth oxide in mineral crystal fancy glaze, so that
Its electrostatic potential difference lifting, can be issued to higher anion releasing effect in less consumption.
The process being provided using such as embodiment 3, prepared Ceramic Tiles, under 25 degrees Celsius, relative humidity 60%
Under the conditions of test, anion-generating capacity be 1800-2000/cm3.Because producing anion needs in the larger ring of relative humidity
Border, therefore such brick is suitable for using in the larger space of the humidity such as bathroom.
Certainly, tourmaline can also be replaced using rare ice stone, opal or QICAISHI here.Because generation provided above
The material of anion has considerable influence to the firing temperature of base substrate and blank deformation, and in the present invention, the mineral being used are brilliant
Body fancy glaze contains substantial amounts of metallic element, and the glaze that it can arrange below in sintering forms depression, so both can report barrier
The anion effect layer being formed will not be skimmed when follow-up rubbing down is processed, and meanwhile, this being applied in combination also makes Ceramic Tiles produce
The anti-pollution characteristic of product and finished product deformation all control in less scope, essentially identical with un-added effect.
And adopt traditional the tradition anion powder such as tourmaline is used as added material, add in conventional glaze,
The addition reaching the negative ion concentration of the present invention is needed to need to increase 1.5-2 times.So anion powder burns till to glaze
Effect has considerable influence, and then affects anti-pollution characteristic and the deformation of finished product.
Embodiment 5
In the present embodiment, give this product antibacterial functions, in traditional handicraft, product surface material introduces antibacterial
Agent is conventional selection.The antibacterial such as example common silver, copper, zinc.But because product needed passes through high temperature sintering, this can be to product
Antibacterial effect produce deleterious effect, in this regard, people select using above antibacterial phosphate.But be given with prior art
Scheme from the point of view of, all cannot solve the problems, such as the deformation of products after there is good antibacterial effect very well.
Pin, in this regard, the present invention introduces a certain amount of antibacterial components in above mineral crystal fancy glaze, is spent using mineral crystal
The a large amount of metallic elements containing in glaze, glaze can melt at a lower temperature, concave downward, it is to avoid follow-up rubbing down is to antibacterial
The destruction of layer, the metallic element simultaneously containing in mineral crystal fancy glaze is also so that the antibacterial effect of its antibacterial is enhanced.
It is as follows that the present embodiment provides mineral crystal fancy glaze formula to press mass fraction：100 parts of mineral crystal dry granular, antibacterial
1.5 parts, 10 parts of clear frit (corresponding firing temperature suitably selected), print cream (the print cream of Dow) 60-80 (according to formula
Change adjustment usage amount is reaching the fancy glaze proportion of needs) part, 0.2 part of carboxymethyl cellulose, water 25-40 part, mineral crystal does
The particle diameter of grain：80～120 mesh account for 70～80%, and remainder is by 120 mesh, fancy glaze proportion 1.6～1.7g/cm3, cross 320 mesh sieves
Afterwards, tail over as 0.1 gram.
Here antibacterial is chosen as the mixture of silver phosphate and zirconium phosphate, the wherein 5- accounting for antibacterial quality of zirconium phosphate
15%.The combination selecting silver phosphate and zirconium phosphate is as antibacterial, it is possible to reduce the silver in antibacterial to mineral crystal fancy glaze is in
The impact of color.Here the used in amounts of zirconium phosphate will control below 15%, otherwise because the covering of brightening of zirconium acts on, can make whole
The decorative effect of brick is affected.
The above-mentioned description to embodiment is to be understood that and use invention for ease of those skilled in the art.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiment without through performing creative labour.Therefore, the invention is not restricted to above-described embodiment, ability
, according to the announcement of the present invention, the improvement made without departing from scope and modification all should be the present invention's for field technique personnel
Within protection domain.
Claims (8)
1. a kind of mineral crystal fancy glaze capable of releasing negative ion is it is characterised in that calculated with mass fraction, including following component：
100 parts of mineral crystal dry granular, clear frit 0-50 part, tourmaline powder 1-3 part, light rare earth oxide 0.01-0.05 part, print cream
60-80 part, 0.2 part of carboxymethyl cellulose, water 25-40 part；
The chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including following component：
SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
2. a kind of Ceramic Tiles being produced using mineral crystal fancy glaze capable of releasing negative ion as claimed in claim 1, its feature exists
In described mineral crystal fancy glaze capable of releasing negative ion is located at adobe surface.
3. a kind of production technology of Ceramic Tiles capable of releasing negative ion is it is characterised in that comprise the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) in cover-coat enamel known to billet surface charity, form cover coat；
Step 3) stamp is carried out on cover coat, form printed layer；
Step 4) protect glaze in stamp layer surface charity；
Step 5) charity mineral crystal fancy glaze, mineral crystal fancy glaze is calculated with mass fraction, including following component：Mineral crystal is done
100 parts of grain, clear frit 0-50 part, tourmaline powder 1-3 part, light rare earth oxide 0.01-0.05 part, print cream 60-80 part, carboxymethyl
0.2 part of cellulose, water 25-40 part, the chemical constituent of described mineral crystal dry granular is calculated with oxide weight number, including as follows
Component：SiO2:8 parts, Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts；
Step 6) enter kiln and fire；
Step 7) base substrate after burning till is polished and edging process, obtain ceramic brick product.
4. as claimed in claim 3 a kind of production technology of Ceramic Tiles it is characterised in that step 2) and step 3) between also wrap
Include the step that glaze is brightened by silk screen printing, the described glaze that brightens is calculated with mass fraction, including following component：Transparent molten
Block：50 parts, Zirconium orthosilicate.：50 parts, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
5. as claimed in claim 4 a kind of production technology of Ceramic Tiles it is characterised in that the described glaze that brightens is at least through silk
Wire mark system is twice.
6. as claimed in claim 3 a kind of production technology of Ceramic Tiles it is characterised in that described step 3) and step 4) between
Also include the step that charity increases pink blossom glaze, printed layer prints the increasing pink blossom glaze for complementary color, institute by screen printing mode
State increasing pink blossom glaze to calculate with mass fraction, including following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part,
Carboxymethyl cellulose：1.3 parts, ethylene glycol：45 parts, water：40 parts；The chemical constituent of the calcareous clear frit of described high boron is with oxide
Parts by weight calculate, including following component：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54
Part；Described complementary color colorant is one or more combination of known pottery glaze stain.
7. as claimed in claim 3 a kind of production technology of Ceramic Tiles it is characterised in that described step 3) and step 4) between
Also include the step that color fancy glaze supported by cloth, described help color fancy glaze to calculate with mass fraction, including following component：High zinc matter frit
100 parts, print 130 parts of cream, 0.3 part of sodium tripolyphosphate, 40 parts of water；The chemical constituent of described high zinc matter frit is with oxide weight part
Number calculates, including following component：SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
8. as claimed in claim 7 a kind of production technology of Ceramic Tiles it is characterised in that the mode of color fancy glaze supported by described cloth
It is using full impregnated silk screen printing twice.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107021625A (en) * | 2017-05-23 | 2017-08-08 | 张福利 | A kind of bluish white glaze of pottery |
| CN107698250A (en) * | 2017-09-11 | 2018-02-16 | 佛山市高明区新粤丰建材有限公司 | A kind of anion green ceramic tile and preparation method thereof |
| CN108516683A (en) * | 2018-04-23 | 2018-09-11 | 广东宏陶陶瓷有限公司 | It can continue the crystallization glazed tile and preparation method thereof of generation anion |
| CN109250900A (en) * | 2018-12-07 | 2019-01-22 | 佛山市东鹏陶瓷有限公司 | A kind of negative ion powder, glaze and preparation method thereof |
| CN109384476A (en) * | 2018-11-05 | 2019-02-26 | 广东金意陶陶瓷集团有限公司 | A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof |
| CN111848223A (en) * | 2020-07-22 | 2020-10-30 | 晋大纳米科技（厦门）有限公司 | Highly-antibacterial functional glazed brick and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587186A (en) * | 2004-09-03 | 2005-03-02 | 佛山欧神诺陶瓷有限公司 | Method for producing health ceramic brick capable of releasing negative ion |
| CN102219559A (en) * | 2011-04-06 | 2011-10-19 | 广东金意陶陶瓷有限公司 | Light glazed ceramic tile with anion function and low water absorption and production method thereof |
| CN102219498A (en) * | 2011-03-31 | 2011-10-19 | 厦门建霖工业有限公司 | Water purification ceramic material and preparation method thereof |
| CN102515875A (en) * | 2011-12-26 | 2012-06-27 | 广东金意陶陶瓷有限公司 | Full polished glaze porcelain tile capable of self-exciting to produce negative ions, and preparation method for full polished glaze porcelain tile |
| CN103626523A (en) * | 2013-11-26 | 2014-03-12 | 广东金意陶陶瓷有限公司 | Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof |
| CN103664236A (en) * | 2013-12-18 | 2014-03-26 | 广东金意陶陶瓷有限公司 | Metal fancy glaze as well as whole cast glaze ceramic tile with metal effect and production technology thereof |
| CN104129996A (en) * | 2014-08-06 | 2014-11-05 | 淄博百康经贸有限公司 | Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof |
| CN104557144A (en) * | 2014-12-29 | 2015-04-29 | 广东家美陶瓷有限公司 | Colorful transparent polished-glazed brick and production method thereof |
| CN104829133A (en) * | 2015-03-30 | 2015-08-12 | 佛山市新战略知识产权文化有限公司 | Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze |
-
2016
- 2016-08-31 CN CN201610788750.9A patent/CN106396407A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587186A (en) * | 2004-09-03 | 2005-03-02 | 佛山欧神诺陶瓷有限公司 | Method for producing health ceramic brick capable of releasing negative ion |
| CN102219498A (en) * | 2011-03-31 | 2011-10-19 | 厦门建霖工业有限公司 | Water purification ceramic material and preparation method thereof |
| CN102219559A (en) * | 2011-04-06 | 2011-10-19 | 广东金意陶陶瓷有限公司 | Light glazed ceramic tile with anion function and low water absorption and production method thereof |
| CN102515875A (en) * | 2011-12-26 | 2012-06-27 | 广东金意陶陶瓷有限公司 | Full polished glaze porcelain tile capable of self-exciting to produce negative ions, and preparation method for full polished glaze porcelain tile |
| CN103626523A (en) * | 2013-11-26 | 2014-03-12 | 广东金意陶陶瓷有限公司 | Ceramic tile with dry particle glaze-decorated surface and manufacturing method thereof |
| CN103664236A (en) * | 2013-12-18 | 2014-03-26 | 广东金意陶陶瓷有限公司 | Metal fancy glaze as well as whole cast glaze ceramic tile with metal effect and production technology thereof |
| CN104129996A (en) * | 2014-08-06 | 2014-11-05 | 淄博百康经贸有限公司 | Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof |
| CN104557144A (en) * | 2014-12-29 | 2015-04-29 | 广东家美陶瓷有限公司 | Colorful transparent polished-glazed brick and production method thereof |
| CN104829133A (en) * | 2015-03-30 | 2015-08-12 | 佛山市新战略知识产权文化有限公司 | Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze |
Non-Patent Citations (2)
| Title |
|---|
| 王芬等: "《硅酸盐制品的装饰及装饰材料》", 31 August 2004, 化学工业出版社 * |
| 轻工业部第一轻工业局: "《日用陶瓷工业手册》", 31 July 1987 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107021625A (en) * | 2017-05-23 | 2017-08-08 | 张福利 | A kind of bluish white glaze of pottery |
| CN107698250A (en) * | 2017-09-11 | 2018-02-16 | 佛山市高明区新粤丰建材有限公司 | A kind of anion green ceramic tile and preparation method thereof |
| CN108516683A (en) * | 2018-04-23 | 2018-09-11 | 广东宏陶陶瓷有限公司 | It can continue the crystallization glazed tile and preparation method thereof of generation anion |
| CN108516683B (en) * | 2018-04-23 | 2020-09-29 | 广东宏陶陶瓷有限公司 | Crystal glazed tile capable of continuously generating negative ions and preparation method thereof |
| CN109384476A (en) * | 2018-11-05 | 2019-02-26 | 广东金意陶陶瓷集团有限公司 | A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof |
| CN109384476B (en) * | 2018-11-05 | 2021-08-17 | 广东金意陶陶瓷集团有限公司 | Anti-skid wear-resistant negative ion ceramic tile and preparation method thereof |
| CN109250900A (en) * | 2018-12-07 | 2019-01-22 | 佛山市东鹏陶瓷有限公司 | A kind of negative ion powder, glaze and preparation method thereof |
| CN111848223A (en) * | 2020-07-22 | 2020-10-30 | 晋大纳米科技（厦门）有限公司 | Highly-antibacterial functional glazed brick and preparation method thereof |
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Application publication date: 20170215 |