CN107021625A - A kind of bluish white glaze of pottery - Google Patents

A kind of bluish white glaze of pottery Download PDF

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Publication number
CN107021625A
CN107021625A CN201710368984.2A CN201710368984A CN107021625A CN 107021625 A CN107021625 A CN 107021625A CN 201710368984 A CN201710368984 A CN 201710368984A CN 107021625 A CN107021625 A CN 107021625A
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parts
pottery
bluish white
glaze
white glaze
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CN201710368984.2A
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张福利
张恺
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00Glasses, glazes or enamels with special properties
    • C03C2204/02Antibacterial glass, glaze or enamel
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00Glasses, glazes or enamels with special properties
    • C03C2204/04Opaque glass, glaze or enamel

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

A kind of bluish white glaze of pottery, it is prepared from by the raw material of following parts by weight:Red 55 60 parts of feldspar, 13 15 parts of calcite, 11 13 parts of quartz, 1.5 2.5 parts of perlite, 2.5 3.5 parts of tourmaline, 1.8 2.3 parts of lime stone, 1.8 2.2 parts of zinc oxide, 1.4 1.6 parts of tin oxide.The present invention is compared with prior art, by scientific and reasonable raw material proportioning and control burning process, a glazing is only needed, the relatively stable bluish white glaze of colour generation just can be prepared, yield rate can reach more than 80%, and the bluish white glaze glaze colours burnt out is blue or green lustrous and transparent, beautiful texture is strong, in addition, introducing tourmaline in the feed can make product slowly discharge anion to surrounding environment, certain antibacterial and deodorization, the certain bioactivity of imparting product is played, is beneficial to human body health.

Description

A kind of bluish white glaze of pottery
Technical field
The present invention relates to a kind of glaze, and in particular to a kind of bluish white glaze of pottery.
Background technology
Pottery is one of five big kiln porcelain of China's Song Dynasty, using transmutation as god, and natural transmutation is the elite institute of pottery art It is being the distinctive gem of art in Countermeasure In Yuzhou City of Henan Province.Chun glaze is the decoration and protective layer on pottery surface, is to determine the life of pottery glaze colours Into principal element, its colour generation and quality have much relations with glaze formula and burning process.Bluish white glaze, is commonly called as shadow green grass or young crops, glaze colours Between blue or green and white, chromaticness such as jade;Tradition has ten multiple working procedures when firing, and any one process, which goes wrong, can cause product to go out The defect that can not now make up, causes its yield rate relatively low, less than 50%.It can improve above-mentioned by adding some industrial chemicals at present Problem, improves the stability of colour generation, improves yield rate, but the use of industrial chemicals easily causes harm human body health and dirty The problem of contaminating environment.
The content of the invention
The purpose of the present invention is that provides a kind of bluish white glaze of the pottery of high yield rate to solve the deficiencies in the prior art.
The purpose of the present invention is realized with following technical proposals:
A kind of bluish white glaze of pottery, it is prepared from by the raw material of following parts by weight:Red feldspar 55-60 parts, calcite 13-15 Part, 11-13 parts of quartz, 1.5-2.5 parts of perlite, 2.5-3.5 parts of tourmaline, 1.8-2.3 parts of lime stone, zinc oxide 1.8-2.2 Part, 1.4-1.6 parts of tin oxide.
It is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartzy 12 parts, pearl 2 parts of rock, 3 parts of tourmaline, 2.1 parts of lime stone, 2 parts of zinc oxide, 1.5 parts of tin oxide
The preparation method of the bluish white glaze of pottery as described above, comprises the following steps:
(1)Above-mentioned raw materials are added water mixing, ball milling obtains glaze slip;
(2)Glazing;
(3)Burn till, firing temperature is 1280-1300 DEG C.
Step(3)Middle firing process specifically includes following steps:1. heat of oxidation:Base substrate after glazing is put into kiln, Fired under oxidizing atmosphere, temperature is ramped up 900-1000 DEG C in 3.5-5h;2. under reducing atmosphere, make temperature equal in 4-6h It is ramped up 1280-1300 DEG C;3. under reducing atmosphere, 1.5-2h is kept under the conditions of 1280-1300 DEG C;4. room temperature is cooled to, It is made.
The present invention compared with prior art, by scientific and reasonable raw material proportioning and control burning process, only need to be applied once Glaze, just can prepare the relatively stable bluish white glaze of colour generation, yield rate can reach more than 80%, and the bluish white glaze glaze colours burnt out is blue or green Jade-like stone, beautiful texture is strong, in addition, and tourmaline is introduced in the feed product is slowly discharged anion to surrounding environment, played Certain antibacterial and deodorization, assign product certain bioactivity, are beneficial to human body health.
Embodiment
Embodiment 1
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red feldspar 55-60 parts, 13-15 parts of calcite, stone 11-13 parts of English, 1.5-2.5 parts of perlite, 2.5-3.5 parts of tourmaline, 1.8-2.3 parts of lime stone, 1.8-2.2 parts of zinc oxide, oxygen Change 1.4-1.6 parts of tin.
The preparation method of the above-mentioned bluish white glaze of pottery, comprises the following steps:
(1)Above-mentioned raw materials are added water mixing, ball milling obtains glaze slip;
(2)Glazing;
(3)Burn till, firing temperature is 1280-1300 DEG C.
Firing process specifically includes following steps:1. heat of oxidation:Base substrate after glazing is put into kiln, under oxidizing atmosphere Fire, temperature is ramped up 900-1000 DEG C in 3.5-5h;2. under reducing atmosphere, temperature is made to be ramped up in 4-6h 1280-1300℃;3. under reducing atmosphere, 1.5-2h is kept under the conditions of 1280-1300 DEG C;4. room temperature is cooled to, is made.
The present invention is using red feldspar as primary solvent, and red feldspar iron-holder is higher, is primary solvent and photoghraphic coupler;Calcite rises Hydrotropy is acted on, and quartz can improve the mobility of glaze, and tin oxide and zinc oxide are main hyperchromic and toner, and tourmaline has The electromagnetic radiation of far infrared band, can produce the functions such as certain negative oxygen ion and antibacterial, deodorization, assign product certain biology Active function, is reduced using defect caused by industrial chemicals.
Red feldspar is higher due to iron-holder, and glaze is easily precipitated, and addition lime stone can increase the suspension of glaze, add Plus perlite high temperature lower volume can expand, improve glaze mobility, further prevent glaze from precipitating;Therefore, The present invention scientific and reasonable formula new by providing and control burning process, improve the stability and glass of bluish white glaze colour generation The stability of matter glaze formation, improves yield rate, and assign product certain bioactive functions.
Embodiment 2
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartz 12 Part, 2 parts of perlite, 3 parts of tourmaline, 2.1 parts of lime stone, 2 parts of zinc oxide, 1.5 parts of tin oxide.
The preparation method of the above-mentioned bluish white glaze of pottery, comprises the following steps:
(1)Above-mentioned raw materials are added water mixing, ball milling obtains glaze slip;
(2)Glazing;
(3)Burn till, firing temperature is 1290 DEG C.
Firing process specifically includes following steps:1. heat of oxidation:Base substrate after glazing is put into kiln, under oxidizing atmosphere Fire, temperature is ramped up 950 DEG C in 4h;2. under reducing atmosphere, temperature is made to be ramped up 1290 DEG C in 5h;3. in reduction Under atmosphere, 100min is kept under the conditions of 1290 DEG C;4. room temperature is cooled to, is made.
The blue or green jade-like stone of the bluish white glaze glaze colours of pottery obtained using said ratio and method, beautiful texture is strong, makees with antibacterial and deodorization With yield rate is more than 82%.
Embodiment 3
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartz 12 Part, 2 parts of perlite, 3 parts of tourmaline, 2.1 parts of lime stone, 2 parts of zinc oxide, 1.5 parts of tin oxide.
The preparation method of the above-mentioned bluish white glaze of pottery, comprises the following steps:
(1)Above-mentioned raw materials are added water mixing, ball milling obtains glaze slip;
(2)Glazing;
(3)Burn till, firing temperature is 1300 DEG C.
Firing process specifically includes following steps:1. heat of oxidation:Base substrate after glazing is put into kiln, under oxidizing atmosphere Fire, temperature is ramped up 900 DEG C in 5h;2. under reducing atmosphere, temperature is made to be ramped up 1300 DEG C in 4h;3. in reduction Under atmosphere, 2h is kept under the conditions of 1300 DEG C;4. room temperature is cooled to, is made.
The blue or green jade-like stone of the bluish white glaze glaze colours of pottery obtained using said ratio and method, beautiful texture is strong, makees with antibacterial and deodorization With yield rate is 80% or so.
Embodiment 4
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 60 parts of feldspar, 13 parts of calcite, quartz 13 parts, 2 parts of perlite, 3 parts of tourmaline, 2 parts of lime stone, 2 parts of zinc oxide, 1.5 parts of tin oxide.Preparation method be the same as Example 2.
The blue or green jade-like stone of the bluish white glaze glaze colours of pottery obtained using said ratio and method, beautiful texture is strong, with antibacterial and deodorization, into Product rate is 80% or so.
Comparative example 1
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartz 12 Part, 2 parts of perlite, 2.1 parts of lime stone, 2 parts of zinc oxide, 1.5 parts of tin oxide.Preparation method be the same as Example 2.This example and embodiment 2 compare, and tourmaline is not used, and the blue or green jade-like stone of the bluish white glaze glaze colours of pottery obtained using said ratio and method, beautiful texture is strong, but not Possess antibacterial and deodorization.
Comparative example 2
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartz 12 Part, 2 parts of perlite, 3 parts of tourmaline, 2 parts of zinc oxide, 1.5 parts of tin oxide.Preparation method be the same as Example 2.This example and embodiment 2 Compare, lime stone is not used, the blue or green jade-like stone of the bluish white glaze of pottery obtained using said ratio and method possesses the work of antibacterial and deodorization With, but texture is poor.
Comparative example 3
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartz 12 Part, 2 parts of vermiculite, 3 parts of tourmaline, 2 parts of zinc oxide, 1.5 parts of tin oxide, 2.1 parts of lime stone.Preparation method be the same as Example 2.This example Compared with Example 2, perlite is changed to vermiculite, although perlite and vermiculite may expand at high temperature, but be sent out in experiment The bluish white glaze glaze mobility of pottery for now using said ratio and method to obtain is poor, and yield rate only has 60%.
Comparative example 4
A kind of bluish white glaze of pottery, is prepared from by the raw material of following parts by weight:Red 57.5 parts of feldspar, 14 parts of calcite, quartz 12 Part, 3 parts of tourmaline, 2 parts of zinc oxide, 1.5 parts of tin oxide.Preparation method be the same as Example 2.This example compared with Example 2, is not used Perlite and lime stone, the bluish white glaze of pottery obtained using said ratio and method possess the effect of antibacterial and deodorization, but glaze Color is poor, colour generation is uneven, and beautiful texture is poor, and yield rate only has 45% or so.
The formula for the bluish white glaze of pottery that 5-17 of the embodiment of the present invention is provided is shown in Table 1-2
Table 1
Table 2

Claims (4)

1. a kind of bluish white glaze of pottery, it is characterised in that:It is prepared from by the raw material of following parts by weight:Red feldspar 55-60 parts, 13-15 parts of calcite, 11-13 parts of quartz, 1.5-2.5 parts of perlite, 2.5-3.5 parts of tourmaline, 1.8-2.3 parts of lime stone, oxygen Change 1.8-2.2 parts of zinc, 1.4-1.6 parts of tin oxide.
2. the bluish white glaze of pottery as claimed in claim 1, it is characterised in that:It is prepared from by the raw material of following parts by weight: Red 57.5 parts of feldspar, 14 parts of calcite, 12 parts of quartz, 2 parts of perlite, 3 parts of tourmaline, 2.1 parts of lime stone, 2 parts of zinc oxide, oxygen Change 1.5 parts of tin.
3. the preparation method of the bluish white glaze of pottery as described in claim any one of 1-2, it is characterised in that comprise the following steps:
(1)Above-mentioned raw materials are added water mixing, ball milling obtains glaze slip;
(2)Glazing;
(3)Burn till, firing temperature is 1280-1300 DEG C.
4. the preparation method of the bluish white glaze of pottery as claimed in claim 3, it is characterised in that step(3)Middle firing process is specifically wrapped Include following steps:1. heat of oxidation:Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, is made temperature equal in 3.5-5h It is ramped up 900-1000 DEG C;2. under reducing atmosphere, temperature is made to be ramped up 1280-1300 DEG C in 4-6h;3. in reducing atmosphere Under, 1.5-2h is kept under the conditions of 1280-1300 DEG C;4. room temperature is cooled to, is made.
CN201710368984.2A 2017-05-23 2017-05-23 A kind of bluish white glaze of pottery Pending CN107021625A (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN107602152A (en) * 2017-09-28 2018-01-19 禹州市正玉钧窑有限公司 A kind of pottery is with bluish white glaze and the technique for preparing pottery with bluish white glaze using pottery
CN107721179A (en) * 2017-09-28 2018-02-23 禹州市正玉钧窑有限公司 A kind of preparation method of pottery ultramarine glaze
CN108623157A (en) * 2018-06-29 2018-10-09 福建省德化县福德丰陶瓷有限公司 A kind of glaze water and preparation method thereof with negative ion-releasing function
CN114853339A (en) * 2021-01-20 2022-08-05 上海朗亿功能材料有限公司 Antibacterial glaze, antibacterial ceramic tableware and preparation method thereof
CN115572066A (en) * 2021-12-30 2023-01-06 李晓倩 Ceramic glaze with blue-white crackle effect and preparation method thereof

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602152A (en) * 2017-09-28 2018-01-19 禹州市正玉钧窑有限公司 A kind of pottery is with bluish white glaze and the technique for preparing pottery with bluish white glaze using pottery
CN107721179A (en) * 2017-09-28 2018-02-23 禹州市正玉钧窑有限公司 A kind of preparation method of pottery ultramarine glaze
CN107721179B (en) * 2017-09-28 2020-06-26 禹州市正玉钧窑有限公司 Preparation method of Jun porcelain bluish-blue glaze
CN107602152B (en) * 2017-09-28 2021-04-13 禹州市正玉钧窑有限公司 Green and white glaze for Jun porcelain and process for preparing Jun porcelain by using green and white glaze for Jun porcelain
CN108623157A (en) * 2018-06-29 2018-10-09 福建省德化县福德丰陶瓷有限公司 A kind of glaze water and preparation method thereof with negative ion-releasing function
CN114853339A (en) * 2021-01-20 2022-08-05 上海朗亿功能材料有限公司 Antibacterial glaze, antibacterial ceramic tableware and preparation method thereof
CN115572066A (en) * 2021-12-30 2023-01-06 李晓倩 Ceramic glaze with blue-white crackle effect and preparation method thereof
CN115572066B (en) * 2021-12-30 2024-03-26 李晓倩 Ceramic glaze with blushing effect and preparation method thereof

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Application publication date: 20170808