CN103819225A - Preparation method for celeste glaze of Yaozhou porcelain at oxidizing atmosphere - Google Patents
Preparation method for celeste glaze of Yaozhou porcelain at oxidizing atmosphere Download PDFInfo
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- CN103819225A CN103819225A CN201410037851.3A CN201410037851A CN103819225A CN 103819225 A CN103819225 A CN 103819225A CN 201410037851 A CN201410037851 A CN 201410037851A CN 103819225 A CN103819225 A CN 103819225A
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Abstract
The invention discloses a preparation method of celeste glazeof Yaozhou porcelain at the oxidizing atmosphere. The preparation method comprises the steps: using potash feldspar, quartz, clay, calcite, Suzhou clay and talc as glaze preparing raw materials and using ferric oxide as a colorant; mixing the raw materials and the colorant with zinc oxide, silicon carbide, sodium methylcellulose and sodium polyphosphate to prepare glaze slip; uniformly applying the glaze slip on a ceramic green body after biscuit firing, and preparing the celeste glaze of Yaozhou porcelain at the oxidizing atmosphere. With the adoption of the preparation method, the raw materials are basically generalized, and the production cost is effectively lowered; as carbon monoxide generated by decomposition reaction of the silicon carbide in the glaze firing process is utilized to reduce the ferric oxide, and the atmosphere reduction action is replaced and can be quantitatively controlled, the color generation stability of the celeste glaze of Yaozhou porcelain is greatly improved, a foundation of large-scale production of the celeste glaze of Yaozhou porcelain is laid, the range of the celeste glaze of Yaozhou porcelain is expanded to domestic ceramic from the range of art porcelain, and a mature preparation process is provided for the industrial production of the celeste glaze of Yaozhou porcelain in future.
Description
Technical field
The present invention relates to ceramic materials preparation technology field, the preparation method of the state kiln celeste glaze of particularly shining under a kind of oxidizing atmosphere.
Background technology
Five generations credit state kiln celadon, is light greenish blue, light reddish black, bluish white, pale blue isochrome more, and minority is lake green grass or young crops and Garden Pond.Reddish black glaze colours is in light evolution, to be produced by green grass or young crops through overtone.The transparency of its enamel is good, also hacks, and is the simple the most and elegant porcelain of glaze colours in this kiln successive dynasties institute's cloisonne porcelain.
For reheating goes out the superior celeste glaze of glaze colours, modern adopts the burning fabrication technique in ancient times, and take glaze stone as enamel frit makeing raw material, burn till the lower 1300 ℃ of left and right of reducing atmosphere.Although burnt out the good celeste glaze of color, complicated component and the output of glaze stone are little, can only be applied in artistic porcelain, are not suitable for scale operation household china.And glaze firing process be under reducing atmosphere, carry out and temperature higher, these have all increased the consumption of the energy, contaminate environment, the propagation of be unfavorable for shining state kiln celeste glaze widespread adoption and credit state kiln culture.
Summary of the invention
In order to overcome the shortcoming of above-mentioned prior art, the object of the present invention is to provide the preparation method of the state kiln celeste glaze of shining under a kind of oxidizing atmosphere, the carbon monoxide that can utilize the reaction of silicon carbide decomposition in glaze firing process to generate reduces ferric oxide, replace the reductive action of atmosphere, improve the stability of credit state kiln celeste glaze colour generation, make raw material substantially realize generalization simultaneously, effectively reduce production costs, for the scale operation of the reddish black vitreous enamel of credit state kiln is laid a good foundation.
In order to achieve the above object, the technical scheme that the present invention takes is:
Shine under the oxidizing atmosphere preparation method of state kiln celeste glaze, its step is as follows:
Step 1: by mass percentage the Suzhou soil of the calcite of the quartz of the potassium felspar sand of 58-63%, 18-22%, 12-18%, 1-5%, the talcum of 1-4% are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% the sodium polyphosphate of ferric oxide, the 0.5-2% of zinc oxide, the 1-2% of 2-5% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.70-1.80g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled within the scope of 0.7-1.0mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1250 ℃-1300 ℃, under this temperature condition, be incubated 20-30 minute, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
Described oxidizing atmosphere is air.
In described electric furnace sintering procedure, coefficient of excess air is greater than 1.
It is enamel frit makeing raw material that the present invention adopts raw mineral materials, utilize conventional ceramic raw material, take ferric oxide as tinting material, under oxidizing atmosphere, make credit state kiln celeste glaze, fire on the transparent simple and elegant basis of celeste glaze in maintenance traditional method, not only make raw material substantially realize generalization, effectively reduce production costs, save energy, and the carbon monoxide that utilizes the reaction of silicon carbide decomposition in glaze firing process to generate reduces ferric oxide, replace the reductive action of atmosphere, make reduction there is quantified controlling, thereby greatly improve the stability of credit state kiln celeste glaze colour generation, for the scale operation of the reddish black vitreous enamel of credit state kiln is laid a good foundation, the porcelain that makes to shine expands domestic ceramics to from artistic porcelain category, for the suitability for industrialized production of the state kiln celeste glaze of shining from now on provides ripe preparation technology.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment mono-:
Step 1: by mass percentage 60% potassium felspar sand, 22% quartz, 12% calcite, 2% Suzhou soil, 4% talcum are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be the sodium polyphosphate of 2% zinc oxide, 1.5% ferric oxide, 0.5% silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.80g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled at 0.85mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1250 ℃, under this temperature condition, be incubated 27 minutes, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
Embodiment bis-:
Step 1: by mass percentage 58% potassium felspar sand, 20% quartz, 18% calcite, 1% Suzhou soil, 3% talcum are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be the sodium polyphosphate of 5% zinc oxide, 1% ferric oxide, 2% silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.77g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled at 0.7mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1300 ℃, under this temperature condition, be incubated 20 minutes, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
Embodiment tri-:
Step 1: by mass percentage 63% potassium felspar sand, 18% quartz, 13% calcite, 5% Suzhou soil, 1% talcum are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be the sodium polyphosphate of 4% zinc oxide, 2% ferric oxide, 1.2% silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.70g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled at 1.0mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1270 ℃, under this temperature condition, be incubated 30 minutes, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
Claims (6)
1. shine under the oxidizing atmosphere preparation method of state kiln celeste glaze, is characterized in that, step is as follows:
Step 1: by mass percentage the Suzhou soil of the calcite of the quartz of the potassium felspar sand of 58-63%, 18-22%, 12-18%, 1-5%, the talcum of 1-4% are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% the sodium polyphosphate of ferric oxide, the 0.5-2% of zinc oxide, the 1-2% of 2-5% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.70-1.80g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled within the scope of 0.7-1.0mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1250 ℃-1300 ℃, under this temperature condition, be incubated 20-30 minute, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
2. shine under a kind of oxidizing atmosphere according to claim 1 preparation method of state kiln celeste glaze, is characterized in that, step is as follows:
Step 1: by mass percentage 60% potassium felspar sand, 22% quartz, 12% calcite, 2% Suzhou soil, 4% talcum are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be the sodium polyphosphate of 2% zinc oxide, 1.5% ferric oxide, 0.5% silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.80g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled at 0.85mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1250 ℃, under this temperature condition, be incubated 27 minutes, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
3. shine under a kind of oxidizing atmosphere according to claim 1 preparation method of state kiln celeste glaze, is characterized in that, step is as follows:
Step 1: by mass percentage 58% potassium felspar sand, 20% quartz, 18% calcite, 1% Suzhou soil, 3% talcum are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be the sodium polyphosphate of 5% zinc oxide, 1% ferric oxide, 2% silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.77g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled at 0.7mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1300 ℃, under this temperature condition, be incubated 20 minutes, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
4. shine under a kind of oxidizing atmosphere according to claim 1 preparation method of state kiln celeste glaze, is characterized in that, step is as follows:
Step 1: by mass percentage 63% potassium felspar sand, 18% quartz, 13% calcite, 5% Suzhou soil, 1% talcum are mixed and made into mixture;
Step 2: to add mass ratio in the mixture making to above-mentioned steps 1 be the sodium polyphosphate of 4% zinc oxide, 2% ferric oxide, 1.2% silicon carbide, 0.8% sodium carboxymethylcellulose pyce and 0.3% and mix, be placed in mortar and be finely ground to 250 orders, modulation glaze slip proportion is 1.70g/cm
3;
Step 3: glaze slip is evenly imposed on the ceramic body of biscuiting, glaze layer thickness is controlled at 1.0mm, ceramic body is positioned in electric furnace and is fired, under oxidizing atmosphere, be warming up to 1270 ℃, under this temperature condition, be incubated 30 minutes, then naturally cool to room temperature, state kiln celeste glaze can obtain shining.
5. according to the imitating technology method of a kind of state kiln celeste glaze of shining described in the arbitrary claim of claim 1-4, it is characterized in that, described oxidizing atmosphere is air.
6. according to the imitating technology method of a kind of state kiln celeste glaze of shining described in the arbitrary claim of claim 1-4, it is characterized in that, in described electric furnace sintering procedure, coefficient of excess air is greater than 1.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104446663A (en) * | 2014-12-15 | 2015-03-25 | 郑州鸿宾木艺有限公司 | Ru porcelain matte celeste glaze |
| CN106064888A (en) * | 2016-06-06 | 2016-11-02 | 陕西科技大学 | The preparation method of imitative pottery celeste glaze under a kind of oxidizing atmosphere |
| CN106082656A (en) * | 2016-06-06 | 2016-11-09 | 陕西科技大学 | The preparation method of bluish white glaze under a kind of oxidizing atmosphere |
| CN107915410A (en) * | 2017-11-28 | 2018-04-17 | 陕西科技大学 | A kind of reddish black glaze and the method that day celadon glaze is copied using this glaze |
| CN112430064A (en) * | 2020-11-30 | 2021-03-02 | 江西和美陶瓷有限公司 | Ceramic tile containing silicon carbide waste and preparation method thereof |
| CN112573824A (en) * | 2020-10-15 | 2021-03-30 | 宁国市众鑫陶业有限公司 | Antique foaming glaze and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103288493A (en) * | 2013-05-29 | 2013-09-11 | 陕西科技大学 | Reddish-black jun porcelain glaze prepared by utilizing metal copper and iron and preparation method of reddish-black jun porcelain glaze |
| CN103408329A (en) * | 2013-08-27 | 2013-11-27 | 中国科学院上海硅酸盐研究所 | Preparation method of self-reduced greenish glaze |
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2014
- 2014-01-26 CN CN201410037851.3A patent/CN103819225A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103288493A (en) * | 2013-05-29 | 2013-09-11 | 陕西科技大学 | Reddish-black jun porcelain glaze prepared by utilizing metal copper and iron and preparation method of reddish-black jun porcelain glaze |
| CN103408329A (en) * | 2013-08-27 | 2013-11-27 | 中国科学院上海硅酸盐研究所 | Preparation method of self-reduced greenish glaze |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104446663A (en) * | 2014-12-15 | 2015-03-25 | 郑州鸿宾木艺有限公司 | Ru porcelain matte celeste glaze |
| CN106064888A (en) * | 2016-06-06 | 2016-11-02 | 陕西科技大学 | The preparation method of imitative pottery celeste glaze under a kind of oxidizing atmosphere |
| CN106082656A (en) * | 2016-06-06 | 2016-11-09 | 陕西科技大学 | The preparation method of bluish white glaze under a kind of oxidizing atmosphere |
| CN106064888B (en) * | 2016-06-06 | 2018-10-30 | 广东怡泰龙实业发展股份有限公司 | The preparation method of pottery celeste glaze is imitated under a kind of oxidizing atmosphere |
| CN106082656B (en) * | 2016-06-06 | 2018-12-25 | 福建省德化县继裕陶瓷有限公司 | The preparation method of bluish white glaze under a kind of oxidizing atmosphere |
| CN107915410A (en) * | 2017-11-28 | 2018-04-17 | 陕西科技大学 | A kind of reddish black glaze and the method that day celadon glaze is copied using this glaze |
| CN112573824A (en) * | 2020-10-15 | 2021-03-30 | 宁国市众鑫陶业有限公司 | Antique foaming glaze and preparation method thereof |
| CN112430064A (en) * | 2020-11-30 | 2021-03-02 | 江西和美陶瓷有限公司 | Ceramic tile containing silicon carbide waste and preparation method thereof |
| CN112430064B (en) * | 2020-11-30 | 2022-12-16 | 江西和美陶瓷有限公司 | Ceramic tile containing silicon carbide waste and preparation method thereof |
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Application publication date: 20140528 |