CN104129996A - Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof - Google Patents
Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof Download PDFInfo
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- CN104129996A CN104129996A CN201410384605.5A CN201410384605A CN104129996A CN 104129996 A CN104129996 A CN 104129996A CN 201410384605 A CN201410384605 A CN 201410384605A CN 104129996 A CN104129996 A CN 104129996A
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Abstract
The invention belongs to the technical field of ceramics, and particularly relates to an anion easy-cleaning functional ceramic additive and a preparation method thereof, a ceramic prepared by using the additive and a preparation method thereof. The additive is prepared from the following raw materials in percentage by mass: 10-16% of Chongguang stones with a particle size of 5-20 microns, 16-25% of tourmaline with a particle size of 5-15 microns, 5-15% of copper pectolite with a particle size of 5-20 microns, 8-12% of nano titanium dioxide, 6-8% of nano zinc oxide, 5-10% of lead-free frits, 7-20% of rare earth materials, 8-10% of superfine alumina, 8-15% of superfine quartz powder and 5-10% of sodium carbonate. The preparation method of the additive comprises the following steps of carrying out mixed ball-milling on the lead-free frits, the rare earth materials, the superfine alumina, the superfine quartz powder and the sodium carbonate firstly; and then, adding the Chongguang stones, the tourmaline, the copper pectolite, the nano titanium dioxide and the nano zinc oxide into the obtained product, and ball-milling the obtained mixture, so that the additive with a particle size of 1-10 microns is obtained. The additive disclosed by the invention has a self-polarizing performance, and has strong adsorption and decomposition functions, so that negative ions are produced; and after the additive is added into a ceramic, the ceramic is extremely easy to clean and not stained, and has no hidden dirt, therefore, the ceramic has a strong affinity to water.
Description
Technical field
The invention belongs to ceramic technology field, be specifically related to pottery and the ceramic preparation method of a kind of negative ion easily cleaning function ceramic additive, its preparation method and preparation thereof.
Background technology
Current, the product that indoor environment and the mankind are edible and water class are polluted aggravation gradually, and its principal pollutant are formaldehyde, lead, cadmium, mercury, the harmful chemicals such as prussiate.People live in such contaminate environment for a long time, are contacting the food being polluted, very large to health harm, usually can bring out various diseases.Simultaneously, the use of various liquid detergents also can cause groundwater pollution and endanger the healthy of the mankind, relevant data shows, the usage quantity of the annual liquid detergent of China is between 300,000 tons to 400,000 tons, although liquid detergent is nontoxic in theory, but some harmful material monomer can be absorbed by the body in body by skin Digestive tract, in the time that these objectionable impuritiess acquire a certain degree in human body, will endanger healthy.Positively charged ion, anion surfactant that liquid detergent the inside is contained, can remove the oiliness protective layer of skin surface, and then corrode skin; The activity of the chemicals mass-energy inhibited oxidation enzymes such as the alkylsulfonate of liquid detergent the inside, causes melanochrome in skin to be become black and occurred a large amount of butterfly spot from colourless; Some chemical substance can cause that resistance of human body declines etc. by infringement lymphsystem after entering human body.
Therefore, one is made in research can improve environment and food contamination, improves water quality and activated water, and it is imperative to have the ceramic of easy clean anti-pollution function.Like this need not any chemical substance or liquid detergent just ceramic can be rinsed well, both eliminated the chemical pollution of food, activated water, again can water saving, eliminated the pollution that various chemical substances cause environment and human body.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of negative ion easily cleaning function ceramic additive that has electric self poling performance, can produce negative ion under light source condition, and the present invention provides the preparation method of additive and the pottery of preparation and ceramic preparation method simultaneously.
Negative ion easily cleaning function ceramic additive of the present invention, made by the raw material of following mass percent:
Extra large aragonite 5-15%, the nano titanium oxide 8-12% of the Chong Guang stone 10-16% of 5-20 micron, the tourmalinite 16-25% of 5-15 micron, 5-20 micron, nano zine oxide 6-8%, without lead frit 5-10%, rare earth material 7-20%, ultra-fine alumina 8-10%, ultrafine quartz powder 8-15% and sodium carbonate 5-10%.
Wherein, preferred technical scheme is as follows:
Described rare earth material is cerous nitrate and/or Neodymium trioxide; When rare earth material is cerous nitrate and Neodymium trioxide, in additive total mass 100%, the content of cerous nitrate is 4-10wt.%.
The described raw material without the preferred following mass percent of lead frit is made according to following steps:
By feldspar 30%, quartz 9%, calcium carbonate 6%, reason pyroxene 10%, ripe talcum 9%, sodium carbonate 13%, zinc oxide 10%, barium carbonate 5%, ripe in soil 8%, mix, be sized to 10 order-20 orders, in 1560-1580 DEG C of fusing, after shrend, be milled to 250-300 order, oven dry makes.
The preparation method of described negative ion easily cleaning function ceramic additive is first will be without lead frit, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling 8-10 hour, add again the Chong Guangshi of 5-20 micron, the tourmalinite of 5-15 micron, extra large aragonite, nano titanium oxide and the nano zine oxide ball milling 8-10 hour of 5-20 micron, obtain the negative ion easily cleaning function ceramic additive of particle diameter 1-10 micron.
Described negative ion easily cleaning function ceramic additive can add in ceramic raw material makes pottery, and described pottery comprises idiosome and glaze,
The additional negative ion easily cleaning function of idiosome ceramic additive, in the raw materials used total mass 100% of idiosome, additive amount accounts for the 5-10% of the raw materials used total mass of idiosome;
The additional negative ion easily cleaning function of glaze ceramic additive, in the raw materials used total mass 100% of glaze, additive amount accounts for the 5-10% of the raw materials used total mass of glaze.
Wherein, idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 43-45%, feldspar 10-12%, quartzy 5-7%, hard kaoline 35-38% and soft clay 3-5%;
Glaze: feldspar 20-25%, quartzy 23-26%, boric acid 10-13%, borax 12-15%, aluminium hydroxide 4-6%, ripe talcum 5-7%, barium carbonate 4-6%, zinc oxide 8-10%, Strontium carbonate powder 6-9% and Quilonum Retard 1-3%.
Idiosome and glaze are further preferably made up of the raw material of following mass percent:
Idiosome: bone meal 43%, feldspar 12%, quartz 7%, hard kaoline 35% and soft clay 3%;
Glaze: feldspar 21%, quartz 23%, boric acid 11%, borax 13%, aluminium hydroxide 5%, ripe talcum 6%, barium carbonate 5%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 2%.
Base substrate is with Ca
3(PO
4)
2, SiO
2and AL
2o
3for the high-grade carcass of main body, all right additional mud adjusting agent in idiosome, mud adjusting agent comprises one or more in water glass, ground caustic, Mierocrystalline cellulose, in the raw materials used total mass 100% of idiosome, the consumption of mud adjusting agent is 0.01-0.4%.
The preparation method of described pottery, comprises the following steps:
(1) batching: the formula ratio according to idiosome, glaze, negative ion easily cleaning function ceramic additive is ready to raw material;
(2) idiosome materials preparation: by raw materials used idiosome mix with negative ion easily cleaning function ceramic additive after, pack ball mill into and carry out 70-75 hour ball milling, being milled to fineness of materials reaches 200 mesh sieves and all passes through, and then levigate material is passed through to 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of emitting passes through mud press, make the mud cake that water ratio is 23-26wt.%, mud cake stirs mud machine by vacuum, stir continuously mud 2-3 time, airtight placement 5-7 days, for subsequent use afterwards;
(3) glaze materials preparation: by after raw materials used glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, dry; Add after negative ion easily cleaning function ceramic additive to glaze the inside, pack ball mill into and carry out 75-80 hour ball milling, being milled to fineness of materials reaches 250 mesh sieves and all passes through, test glaze slip proportion is between 1.85-1.90, and then levigate material is passed through to 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use;
The scope of glaze slip proportion is between 1.85-1.90, if proportion is less than normal a little, after needing glaze slip to place precipitation, gradually emit unnecessary water, if proportion is bigger than normal a little, need gradually to add water until within proportion reaches rational scope, generally, as long as when filling with substance recently controls add-on in strict accordance with the weight of material and water, the glaze slip proportion after ground does not need to adjust substantially within zone of reasonableness.
(4) burn till: adopt two step calcining systems,
The first step, the burning till of base substrate:
Step (2) idiosome materials are made after idiosome, first carried out biscuiting, firing temperature 1270-1310 DEG C, firing time 20-30h;
Second step, the burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, firing temperature 1130-1190 DEG C, firing time 10-15 h.
Product after glaze firing can also carry out decal paper, after decal paper, need to burn till firing temperature 1100-1150 DEG C, firing time 6-8 hour again.
Described base substrate is thin and light, permeability is strong, thermostability is strong, the high brightness glaze that glaze is lead-free and cadmium-free, and glaze is bright and clean as beautiful, and transparency is high, and whiteness is good.
Described negative ion ceramic products lives through after three high temperature burn till, and its picture immerses in glaze completely, has fundamentally stopped the color of marble paper and other materials as stripping plumbous, cadmium, fades never.
The present invention's raw material used is commercially available prod.Wherein the particle diameter of ultra-fine alumina, ultrafine quartz powder is 100 ± 10 nanometers.
Compared with prior art, beneficial effect of the present invention is as follows:
Negative ion easily cleaning function ceramic additive of the present invention, is a kind of novel functional materials, and described additive is the ring texture silicate minerals taking boracic as main aluminium, sodium, iron, magnesium, lithium, and allotment simultaneously has the rare-earth-type material such as cerous nitrate, Neodymium trioxide.In its materials, Chong Guangshi is the rare precious ore of one that produce locality, Zibo, and its formation has 200,000,000 years apart from the present, and the negative ion burst size that detects Chong Guang stone flour body through national authority mechanism is very high.Tourmalinite and Chong Guangshi have similar mineral structure, are a kind of silicates mineral, have equally the function that produces negative ion.Sea aragonite belongs to a kind of sodium calcium stone, also contains iron, copper, vanadium etc., itself has and melts the function discharging, and releives, and stablizes the mood of human body and the energy of adjusting human body arteries and veins wheel.Rationally the composition of composite three kinds of ores, makes it to influence each other, synergy.Tourmalinite and Chong Guangshi belong to trigonal system in mineral, its cross section is the trilateral with circular arc, but its two kinds of leg-of-mutton size and shapes are also different, and extra large aragonite belongs to triclinic(crystalline)system in mineral, crystal is shown as prismatic tabular body, above three kinds of mineral are in their single existence, the potential difference that the variation of pressure or temperature produces is single, and in three kinds of simultaneous situations of mineral, different lattices can be in pressure or the vicissitudinous situation of temperature, the potential difference producing complements each other, discharge maximum electronics, and then maximized its contiguous air or water molecules that have influence on forms more negative ion, the vibration of ore lattice and electric polarity can not disappear in time, therefore anion releasing continues, permanent.Being a kind of for example fusing assistant of lead, cadmium etc. of any heavy metal that do not contain without lead frit, is the combination of a lot of mineral and chemical material, and a large amount of alkali and alkaline earth metal ions is contained in the inside simultaneously, can reduce the surface tension of Ceramic glaze; Aluminum oxide, quartz is the framework ingredient in ceramic product, by with rational allocation without lead frit and zinc oxide, the temperature of fusion of powder is reached in the scope matching with ceramic firing temperature, while this additive being added in pottery, can put forward the surface tension of Ceramic glaze simultaneously.Nano-titanium oxide has extraordinary opaque effect, then coordinates under the katalysis with rare-earth substance cerium oxide or cerous nitrate, can produce very strong hydrophilicly on Ceramic glaze, hates oily effect.Under the interaction of above-mentioned various raw materials, the glaze of ceramic product, will have permanent oily dirt free, the characteristic of very easily cleaning.
In addition, negative ion easily cleaning function ceramic additive has certain purification energy, cell actification to blood, can strengthen the resistibility of human body, can also remove various peculiar smell, has stronger adsorption and dissociation effect.Negative ion easily cleaning function ceramic additive self has electromagnetic field, has self poling performance.In the time that temperature and pressure has subtle change, can make to produce between ore crystal potential difference (voltage).This energy can impel water molecules in ambient air to ionize, the electron attachment detaching is in contiguous water and oxygen molecule, make them be converted into airborne negative ion, the sedimentation of suspended substance in the hazardous organic molecules such as catalytic decomposition formaldehyde, promotion air, thus purify air; This additive is added to and in pottery, makes ceramic product, and through the water of ceramic product processing, not only can increase the several mineral materials that needed by human body is wanted, and it is active that water intermediate ion is changed, can regulating water quality; Simultaneously, in can planar water because the microtoxicity material due to polluting is as mercury, cadmium, phthalic acid ester, prussiate, chlorine and multiple unwanted bacteria, regulate the pH value of water to neutrality or weakly alkaline, there is the effect of activated water molecule, thereby water is become to clean active mineral water.This pottery has the function of sustained release negative ion and far infrared rays, has activated water, removes peculiar smell, very easily cleans (not needing liquid detergent), the antibacterial healthy functions that waits.
After testing, the negative ion concentration that pottery of the present invention discharges is far longer than the burst size under conventional ceramic equal conditions, and its burst size is 500-600/cubic centimetre.Use the water quality after pottery, its mouthfeel obviously changes.In addition, because Ceramic glaze contains higher alkaline metal ions, titanium oxide, cerium oxide, water is had to very strong avidity, significantly hate oil, compared with conventional ceramic, be stained with oil negative ion ceramic porcelain products afterwards, very easily clean, do not need liquid detergent, do not hide dirt and do not stain, a water rinses can remove greasy dirt.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
In embodiment, made according to following steps by the raw material of following mass percent without lead frit:
By feldspar 30%, quartz 9%, calcium carbonate 6%, reason pyroxene 10%, ripe talcum 9%, sodium carbonate 13%, zinc oxide 10%, barium carbonate 5%, ripe in soil 8%, mix, be sized to 10 order-20 orders, in 1560-1580 DEG C of fusing, after shrend, be milled to 250-300 order, oven dry makes.
Embodiment 1
Negative ion easily cleaning function ceramic additive of the present invention, made by the raw material of following mass percent:
The extra large aragonite 12% of the Chong Guang stone 16% of 5-20 micron, the tourmalinite 19% of 5-15 micron, 5-20 micron, nano titanium oxide 8%, nano zine oxide 6%, without lead frit 6%, cerous nitrate 8%, ultra-fine alumina 9%, ultrafine quartz powder 11% and sodium carbonate 5%.
Preparation method is first will be without lead frit, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling 9 hours, add again the extra large aragonite, nano titanium oxide of tourmalinite, the 5-20 micron of Chong Guangshi, the 5-15 micron of 5-20 micron and nano zine oxide ball milling 9 hours, obtain the negative ion easily cleaning function ceramic additive of particle diameter 1-10 micron.
Embodiment 2
Negative ion easily cleaning function ceramic additive of the present invention, made by the raw material of following mass percent:
The extra large aragonite 10% of the Chong Guang stone 10% of 5-20 micron, the tourmalinite 25% of 5-15 micron, 5-20 micron, nano titanium oxide 8%, nano zine oxide 6%, without lead frit 5%, Neodymium trioxide 10%, ultra-fine alumina 8%, ultrafine quartz powder 12% and sodium carbonate 6%.
Preparation method is with embodiment 1.
Embodiment 3
Negative ion easily cleaning function ceramic additive of the present invention, made by the raw material of following mass percent:
The extra large aragonite 5% of the Chong Guang stone 12% of 5-20 micron, the tourmalinite 23% of 5-15 micron, 5-20 micron, nano titanium oxide 10%, nano zine oxide 7%, without lead frit 5%, cerous nitrate 4%, Neodymium trioxide 5%, ultra-fine alumina 9%, ultrafine quartz powder 13% and sodium carbonate 7%.
Preparation method is with embodiment 1.
Embodiment 4
Negative ion easily cleaning function ceramic additive of the present invention, made by the raw material of following mass percent:
The extra large aragonite 8% of the Chong Guang stone 10% of 5-20 micron, the tourmalinite 25% of 5-15 micron, 5-20 micron, nano titanium oxide 10%, nano zine oxide 7%, without lead frit 5%, cerous nitrate 6%, Neodymium trioxide 3%, ultra-fine alumina 10%, ultrafine quartz powder 8% and sodium carbonate 8%.
Preparation method is with embodiment 1.
Embodiment 5
Negative ion easily cleaning function ceramic additive of the present invention, made by the raw material of following mass percent:
The extra large aragonite 11% of the Chong Guang stone 12% of 5-20 micron, the tourmalinite 18% of 5-15 micron, 5-20 micron, nano titanium oxide 10%, nano zine oxide 6%, without lead frit 7%, cerous nitrate 8%, ultra-fine alumina 9%, ultrafine quartz powder 14% and sodium carbonate 5%.
Embodiment 6
The pottery of interpolation negative ion easily cleaning function ceramic additive of the present invention, comprises idiosome and glaze, and idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 43%, feldspar 12%, quartz 7%, hard kaoline 35% and soft clay 3%; Negative ion easily cleaning function ceramic additive prepared by additional 5% embodiment 1.
Glaze: feldspar 21%, quartz 23%, boric acid 11%, borax 13%, aluminium hydroxide 5%, ripe talcum 6%, barium carbonate 5%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 2%; Negative ion easily cleaning function ceramic additive prepared by additional 8% embodiment 1.
The preparation method of described pottery, comprises the following steps:
(1) batching: the formula ratio according to idiosome, glaze, negative ion easily cleaning function ceramic additive is ready to raw material;
(2) idiosome materials preparation: by raw materials used idiosome mix with negative ion easily cleaning function ceramic additive after, pack ball mill into and carry out 75 hours ball millings, be milled to fineness of materials and reach 200 mesh sieves and all pass through, and then by levigate material by 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of emitting passes through mud press, make the mud cake that water ratio is 25wt.%, mud cake stirs mud machine by vacuum, stirs continuously mud 3 times, airtight placement afterwards 7 days, for subsequent use; When ball milling, material, water, ballstone three mass ratio are 1:1:2;
(3) glaze materials preparation: by after raw materials used glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, dry; Add after negative ion easily cleaning function ceramic additive to glaze the inside, pack ball mill into and carry out 75 hours ball millings, being milled to fineness of materials reaches 250 mesh sieves and all passes through, test glaze slip proportion is 1.86, and then levigate material is passed through to 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use; When ball milling, material, water, ballstone three mass ratio are 1:0.33:2;
(4) burn till:
The first step, the burning till of base substrate:
Step (2) idiosome materials are made after idiosome, first carried out biscuiting, 1300 DEG C of firing temperatures, firing time 25h;
Second step, the burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, 1150 DEG C of firing temperatures, firing time 12 h.
Embodiment 7
The pottery of interpolation negative ion easily cleaning function ceramic additive of the present invention, comprises idiosome and glaze, and idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 45%, feldspar 11%, quartz 6%, hard kaoline 35% and soft clay 3%; Negative ion easily cleaning function ceramic additive prepared by additional 8% embodiment 2.
Glaze: feldspar 25%, quartz 24%, boric acid 10%, borax 12%, aluminium hydroxide 4%, ripe talcum 5%, barium carbonate 4%, zinc oxide 9%, Strontium carbonate powder 6% and Quilonum Retard 1%; Negative ion easily cleaning function ceramic additive prepared by additional 10% embodiment 2.
The preparation method of described pottery, comprises the following steps:
(1) batching: the formula ratio according to idiosome, glaze, negative ion easily cleaning function ceramic additive is ready to raw material;
(2) idiosome materials preparation: by raw materials used idiosome mix with negative ion easily cleaning function ceramic additive after, pack ball mill into and carry out 70 hours ball millings, be milled to fineness of materials and reach 200 mesh sieves and all pass through, and then by levigate material by 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of emitting passes through mud press, make the mud cake that water ratio is 26wt.%, mud cake stirs mud machine by vacuum, stirs continuously mud 3 times, airtight placement afterwards 6 days, for subsequent use; When ball milling, material, water, ballstone three mass ratio are 1:1:2;
(3) glaze materials preparation: by after raw materials used glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, dry; Add after negative ion easily cleaning function ceramic additive to glaze the inside, pack ball mill into and carry out 78 hours ball millings, being milled to fineness of materials reaches 250 mesh sieves and all passes through, test glaze slip proportion is 1.88, and then levigate material is passed through to 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use; When ball milling, material, water, ballstone three mass ratio are 1:0.35:2;
(4) burn till:
The first step, the burning till of base substrate:
Step (2) idiosome materials are made after idiosome, first carried out biscuiting, 1280 DEG C of firing temperatures, firing time 22h;
Second step, the burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, 1180 DEG C of firing temperatures, firing time 10 h.
Embodiment 8
The pottery of interpolation negative ion easily cleaning function ceramic additive of the present invention, comprises idiosome and glaze, and idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 44%, feldspar 10%, quartz 5%, hard kaoline 37% and soft clay 4%; Negative ion easily cleaning function ceramic additive prepared by additional 10% embodiment 3.
Glaze: feldspar 23%, quartz 25%, boric acid 10%, borax 14%, aluminium hydroxide 4%, ripe talcum 5%, barium carbonate 4%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 1%; Negative ion easily cleaning function ceramic additive prepared by additional 8% embodiment 3.
Preparation method, as embodiment 6, just, by after the product decal paper after glaze firing, burns till 1130 DEG C of firing temperatures, firing time 7 hours.
Ceramic product prepared by embodiment 6-8, according to testing below:
The ceramic product of embodiment 6: use anion test instrument COM-3010PRO at ceramic product surface test, require tester to be placed in after ceramic surface upper 20 second, read observed value, test altogether eight times, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is 513,543,564,509,567,512,523,549, and mean value is: 535ion/cc (individual/cubic centimetre).
The ceramic product of embodiment 7: use anion test instrument COM-3010PRO at ceramic product surface test, require tester to be placed in after ceramic surface upper 20 second, read observed value, test altogether eight times, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 544,545,565,510,533,576,529,527, and mean value is: 541ion/cc (individual/cubic centimetre).
The ceramic product of embodiment 8: use anion test instrument COM-3010PRO at ceramic product surface test, require tester to be placed in after ceramic surface upper 20 second, read observed value, test altogether eight times, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is 555,546,576,529,538,540,566,539, and mean value is: 549ion/cc (individual/cubic centimetre).
Comparative example 1
Chong Guangshi in embodiment 1 and extra large aragonite are all replaced with to tourmalinite, and preparation method, as embodiment 1, after preparing additive, then prepares pottery according to embodiment 6, and according to testing below:
Use anion test instrument COM-3010PRO at ceramic product surface test, require tester to be placed in after ceramic surface upper 20 second, read observed value, test altogether eight times, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 213,198,265,176,301,209,198,199, and mean value is: 220ion/cc (individual/cubic centimetre).
Comparative example 2
Chong Guangshi in embodiment 1 is all replaced with to tourmalinite, and preparation method, as embodiment 1, after preparing additive, then prepares pottery according to embodiment 6, and according to testing below:
Use anion test instrument COM-3010PRO at ceramic product surface test, require tester to be placed in after ceramic surface upper 20 second, read observed value, test altogether eight times, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 312,356,298,333,367,289,359,342, and mean value is: 332ion/cc (individual/cubic centimetre).
Comparative example 3
Extra large aragonite in embodiment 1 is all replaced with to tourmalinite, and preparation method, as embodiment 1, after preparing additive, then prepares pottery according to embodiment 6, and according to testing below:
Use anion test instrument COM-3010PRO at ceramic product surface test, require tester to be placed in after ceramic surface upper 20 second, read observed value, test altogether eight times, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 358,367,296,337,376,341,310,376, and mean value is: 345ion/cc (individual/cubic centimetre).
Claims (10)
1. a negative ion easily cleaning function ceramic additive, is characterized in that being made up of the raw material of following mass percent:
Extra large aragonite 5-15%, the nano titanium oxide 8-12% of the Chong Guang stone 10-16% of 5-20 micron, the tourmalinite 16-25% of 5-15 micron, 5-20 micron, nano zine oxide 6-8%, without lead frit 5-10%, rare earth material 7-20%, ultra-fine alumina 8-10%, ultrafine quartz powder 8-15% and sodium carbonate 5-10%.
2. negative ion easily cleaning function ceramic additive according to claim 1, is characterized in that: rare earth material is cerous nitrate and/or Neodymium trioxide; When rare earth material is cerous nitrate and Neodymium trioxide, in additive total mass 100%, the content of cerous nitrate is 4-10wt.%.
3. negative ion easily cleaning function ceramic additive according to claim 1, is characterized in that: be made up according to following steps of the raw material of following mass percent without lead frit:
By feldspar 30%, quartz 9%, calcium carbonate 6%, reason pyroxene 10%, ripe talcum 9%, sodium carbonate 13%, zinc oxide 10%, barium carbonate 5%, ripe in soil 8%, mix, be sized to 10 order-20 orders, in 1560-1580 DEG C of fusing, after shrend, be milled to 250-300 order, oven dry makes.
4. the preparation method of the arbitrary described negative ion easily cleaning function ceramic additive of claim 1-3, it is characterized in that: first will be without lead frit, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling 8-10 hour, add again the Chong Guangshi of 5-20 micron, the tourmalinite of 5-15 micron, extra large aragonite, nano titanium oxide and the nano zine oxide ball milling 8-10 hour of 5-20 micron, obtain the negative ion easily cleaning function ceramic additive of particle diameter 1-10 micron.
5. a pottery that adds the arbitrary described negative ion easily cleaning function ceramic additive of claim 1-3, comprises idiosome and glaze, it is characterized in that:
The additional negative ion easily cleaning function of idiosome ceramic additive, in the raw materials used total mass 100% of idiosome, additive amount accounts for the 5-10% of the raw materials used total mass of idiosome;
The additional negative ion easily cleaning function of glaze ceramic additive, in the raw materials used total mass 100% of glaze, additive amount accounts for the 5-10% of the raw materials used total mass of glaze.
6. pottery according to claim 5, is characterized in that idiosome and glaze be made up of the raw material of following mass percent:
Idiosome: bone meal 43-45%, feldspar 10-12%, quartzy 5-7%, hard kaoline 35-38% and soft clay 3-5%;
Glaze: feldspar 20-25%, quartzy 23-26%, boric acid 10-13%, borax 12-15%, aluminium hydroxide 4-6%, ripe talcum 5-7%, barium carbonate 4-6%, zinc oxide 8-10%, Strontium carbonate powder 6-9% and Quilonum Retard 1-3%.
7. pottery according to claim 6, is characterized in that idiosome and glaze be made up of the raw material of following mass percent:
Idiosome: bone meal 43%, feldspar 12%, quartz 7%, hard kaoline 35% and soft clay 3%;
Glaze: feldspar 21%, quartz 23%, boric acid 11%, borax 13%, aluminium hydroxide 5%, ripe talcum 6%, barium carbonate 5%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 2%.
8. pottery according to claim 5, it is characterized in that: additional mud adjusting agent in idiosome, mud adjusting agent comprises one or more in water glass, ground caustic, Mierocrystalline cellulose, and in the raw materials used total mass 100% of idiosome, the consumption of mud adjusting agent is 0.01-0.4%.
9. a preparation method for pottery described in claim 5, is characterized in that comprising the following steps:
(1) batching: the formula ratio according to idiosome, glaze, negative ion easily cleaning function ceramic additive is ready to raw material;
(2) idiosome materials preparation: by raw materials used idiosome mix with negative ion easily cleaning function ceramic additive after, pack ball mill into and carry out 70-75 hour ball milling, being milled to fineness of materials reaches 200 mesh sieves and all passes through, and then levigate material is passed through to 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of emitting passes through mud press, make the mud cake that water ratio is 23-26wt.%, mud cake stirs mud machine by vacuum, stir continuously mud 2-3 time, airtight placement 5-7 days, for subsequent use afterwards;
(3) glaze materials preparation: by after raw materials used glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, dry; Add after negative ion easily cleaning function ceramic additive to glaze the inside, pack ball mill into and carry out 75-80 hour ball milling, being milled to fineness of materials reaches 250 mesh sieves and all passes through, test glaze slip proportion is between 1.85-1.90, and then levigate material is passed through to 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use;
(4) burn till:
The first step, the burning till of base substrate:
Step (2) idiosome materials are made after idiosome, first carried out biscuiting, firing temperature 1270-1310 DEG C, firing time 20-30h;
Second step, the burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, firing temperature 1130-1190 DEG C, firing time 10-15 h.
10. the preparation method of pottery according to claim 9, is characterized in that: by after the product decal paper after glaze firing, burn till firing temperature 1100-1150 DEG C, firing time 6-8 hour.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102126828A (en) * | 2010-12-19 | 2011-07-20 | 景德镇陶瓷学院 | Lead-less cadmium-less low-temperature fusion cake and tourmaline-cordierite health care ceramic material and preparation method thereof |
| CN102584343A (en) * | 2012-01-16 | 2012-07-18 | 淄博博纳科技发展有限公司 | Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic |
| CN103253929A (en) * | 2012-02-21 | 2013-08-21 | 李心红 | Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof |
| CN103396090A (en) * | 2013-07-26 | 2013-11-20 | 陈建华 | Preparation method and glazing method for negative oxygen ion releasing far infrared purple sand utensil |
-
2014
- 2014-08-06 CN CN201410384605.5A patent/CN104129996B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102126828A (en) * | 2010-12-19 | 2011-07-20 | 景德镇陶瓷学院 | Lead-less cadmium-less low-temperature fusion cake and tourmaline-cordierite health care ceramic material and preparation method thereof |
| CN102584343A (en) * | 2012-01-16 | 2012-07-18 | 淄博博纳科技发展有限公司 | Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic |
| CN103253929A (en) * | 2012-02-21 | 2013-08-21 | 李心红 | Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof |
| CN103396090A (en) * | 2013-07-26 | 2013-11-20 | 陈建华 | Preparation method and glazing method for negative oxygen ion releasing far infrared purple sand utensil |
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