CN111646700B - Fly ash-based antibacterial glaze powder - Google Patents
Fly ash-based antibacterial glaze powder Download PDFInfo
- Publication number
- CN111646700B CN111646700B CN202010373959.5A CN202010373959A CN111646700B CN 111646700 B CN111646700 B CN 111646700B CN 202010373959 A CN202010373959 A CN 202010373959A CN 111646700 B CN111646700 B CN 111646700B
- Authority
- CN
- China
- Prior art keywords
- parts
- fly ash
- deflocculant
- glaze powder
- kaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
Abstract
The invention discloses a fly ash-based antibacterial glaze powder which is characterized by comprising the following raw materials in parts by mass: the material comprises fly ash, borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate, alumina, nano zirconium phosphate silver-carrying antibacterial agent, titanium dioxide, rare earth oxide, far infrared material oxide, a proper amount of kaolin and deflocculant, wherein the kaolin is added when other raw materials are stirred uniformly and then subjected to wet ball milling. The fly ash is added into the glaze powder raw material, the production cost of the glaze powder is reduced, a new way is opened for the comprehensive utilization of the fly ash, the environment is protected, the waste of resources is avoided, and the sodium dodecyl benzene sulfonate solution is added into the glaze slip to be used as a deflocculant, so that the suspension can be stabilized, the particles in the suspension can be uniformly dispersed, the antibacterial agent is uniformly mixed with other powder materials, and the ceramic prepared from the glaze powder has strong antibacterial property.
Description
The application is a divisional application of an invention patent application named as 'a high heat-resistant antibacterial glaze powder and a preparation method thereof', and the application date of the original application is 2017-07-07, and the application number is 201710550025.2.
Technical Field
The invention relates to ceramic glaze powder, in particular to fly ash-based antibacterial glaze powder.
Background
With the improvement of living standard of people, cookers such as barbecue ovens, ovens and barbecue type microwave ovens are more and more popular, but when in use, the inner walls of the cookers are easily polluted by oil stains and are troublesome to clean. Therefore, the surface of the kitchen ware is generally coated with enamel, and the enamel coating is made of glaze powder. At present, the production of glaze powder basically continues the traditional preparation technology, and the basic process is as follows; coating enamel slip; drying the glaze slip; and firing the porcelain glaze in a kiln. Because the traditional glaze powder preparation technology adopts the process of firing the porcelain glaze in a kiln, the production process of the glaze powder is complex, the energy consumption is large, and the cost of the porcelain enamel product is greatly increased. In addition, common glaze powder has no antibacterial property, if the produced product is used for kitchen ware, the kitchen ware can be easily infected by bacteria, and if the surface of the kitchen ware is only cleaned, the sanitation of the kitchen ware cannot be guaranteed. The invention provides a method for preparing enamel coating by using glaze powder to keep antibacterial property, thus solving the problem of kitchen ware sanitation. In addition, the enamel coating prepared by adding the far infrared material into the titanium dioxide antibacterial agent can emit far infrared rays with the wavelength of 8-18 microns at normal temperature, can promote human microcirculation in medical care and is beneficial to human health. Therefore, the material is added with a new health care function on the basis of the original function, and is more popular with people. The types of the commonly used far infrared materials are shown in table 1.
TABLE 1 far-infrared material types
Disclosure of Invention
The invention aims to provide fly ash-based antibacterial glaze powder and a preparation method thereof, wherein the fly ash-based antibacterial glaze powder reduces the cost of producing glaze powder, enables an antibacterial agent to be stably and uniformly distributed in glaze slip and enables the glaze powder to keep good antibacterial performance. Therefore, the following technical scheme is proposed:
the invention provides fly ash-based antibacterial glaze powder which is prepared from the following raw materials in parts by mass: 50-60 parts of fly ash, 8-13 parts of borax, 4-8 parts of boric acid, 35-45 parts of anorthite, 15-25 parts of quartz, 7-8 parts of calcium carbonate, 1-1.5 parts of barium carbonate, 12-15 parts of alumina, 10-25 parts of nano zirconium phosphate silver-carrying antibacterial agent, 10-20 parts of titanium dioxide, 5-8 parts of rare earth oxide, 4-5 parts of far infrared material oxide and a proper amount of kaolin and deflocculant, wherein the kaolin is added when all other raw materials are stirred uniformly and then subjected to wet ball milling.
Preferably, the feed consists of the following raw materials in parts by mass: 55 parts of fly ash, 10 parts of borax, 6 parts of boric acid, 40 parts of anorthite, 20 parts of quartz, 8 parts of calcium carbonate, 1.5 parts of barium carbonate, 13 parts of alumina, 15 parts of nano zirconium phosphate silver-carrying antibacterial agent, 15 parts of titanium dioxide, 6 parts of rare earth oxide, 5 parts of far infrared material oxide and a proper amount of kaolin and deflocculant, wherein the kaolin is added when all other raw materials are stirred uniformly and then subjected to wet ball milling.
The invention also provides a preparation method of the fly ash-based antibacterial glaze powder, which comprises the following steps:
(1) taking the following raw materials in parts by mass: 8-13 parts of borax; 4-8 parts of boric acid; 35-45 parts of anorthite; 15-25 parts of quartz; 7-8 parts of calcium carbonate; 1-1.5 parts of barium carbonate; 12-15 parts of alumina; 10-25 parts of a nano zirconium phosphate silver-loaded antibacterial agent; 10-20 parts of titanium dioxide; 5-8 parts of rare earth oxide, 50-60 parts of fly ash and 4-5 parts of far infrared material oxide; weighing borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate, alumina and fly ash according to the proportion, uniformly mixing, then melting the mixed powder, and dripping into water for extraction to form granular clinker, thus obtaining a rough base material;
(2) weighing the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the far infrared material oxide and the rare earth oxide according to the proportion, adding the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the far infrared material oxide and the rare earth oxide into deionized water, and then stirring the mixture by using an electric stirrer to obtain a mixed solution, namely preparing the antibacterial agent;
(3) and (3) uniformly mixing the rough base material prepared in the step (1) with the antibacterial agent prepared in the step (2), adding a deflocculant into the mixture, uniformly stirring the mixture, performing wet ball milling, sieving the mixture through a 250-mesh sieve after ball milling, pressing the mixture into mud pieces, drying, crushing, and packaging and forming the mud pieces to obtain the glaze powder.
In step (1), the melting temperature of the mixed powder is 1450-1600 ℃, and the melting time is 15-16 h.
In a further improvement of the scheme, in the step (3), the added deflocculant is sodium dodecyl benzene sulfonate solution, the pH value is 7, and the concentration is 10 mmol/l.
In step (3), when the raw materials are subjected to wet ball milling, a certain amount of water and kaolin are added, wherein the amount of the water is 70% of the mass of the clinker prepared in step (1), and the amount of the kaolin is 10% of the mass of the clinker prepared in step (1).
In step (3), the drying temperature of the mud pieces does not exceed 100 ℃.
Compared with the prior art, the invention has the beneficial effects that:
(1) the invention adds the fly ash into the raw material of the glaze powder, then adds the boric acid compound, the boric acid compound is added into the fly ash, the melting point is reduced, the glass material is easy to generate, the generated glass material can be used as the glaze powder of coal, porcelain and ceramic, the fly ash is used as the base material, the dosage is large, the economic benefit is obvious, on one hand, the production cost of the glaze powder can be reduced, on the other hand, a new way is opened up for the comprehensive utilization of the fly ash, the environment is protected, and the waste of resources is avoided.
(2) In the invention, the sodium dodecyl benzene sulfonate solution is added in the process of preparing the glaze powder, the sodium dodecyl benzene sulfonate is added as an active agent of an antibacterial agent, the dispersion stability of the mixed powder is changed by utilizing the adsorption of micro particles on the surface active agent, and the sodium dodecyl benzene sulfonate solution is added in the glaze slurry as a deflocculant to stabilize the suspension and uniformly disperse the particles in the suspension, so that the antibacterial agent is uniformly mixed with other powder, and the ceramic prepared from the glaze powder has strong antibacterial property.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
In the embodiments 1 to 3, the far infrared material oxide is adopted, the adopted far infrared material oxide is any one of ferric oxide, magnesium oxide and manganese oxide, and the adopted nano silver-loaded zirconium phosphate antibacterial agent is a VK-T08 nano antibacterial agent.
Example 1
The embodiment provides a fly ash-based antibacterial glaze powder, which comprises the following raw materials in parts by mass: 8 parts of borax; 4 parts of boric acid; 35 parts of anorthite; 15 parts of quartz; 7 parts of calcium carbonate; 1 part of barium carbonate; 12 parts of aluminum oxide; 10 parts of nano zirconium phosphate silver-loaded antibacterial agent; 10 parts of titanium dioxide; 5 parts of rare earth oxide; 4 parts of ferric oxide and 50 parts of fly ash.
The embodiment also provides a preparation method of the fly ash-based antibacterial glaze powder, which comprises the following steps:
(1) weighing borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate, alumina and fly ash according to a ratio, uniformly mixing, then melting the mixed powder, wherein the melting temperature of the mixed powder is 1450 ℃, the melting time is 15 hours, and then dripping water to extract the mixed powder to form granular clinker so as to obtain a rough base material;
(2) weighing the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the rare earth oxide and the ferric oxide according to the proportion, adding the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the rare earth oxide and the ferric oxide into deionized water, and then violently stirring by using an electric stirrer to obtain a mixed solution, namely the antibacterial agent is prepared;
(3) uniformly mixing the rough base material prepared in the step (1) with the antibacterial agent prepared in the step (2), adding a deflocculant sodium dodecyl benzene sulfonate solution with the pH of 7 and the concentration of 10mmol/l, uniformly stirring, adding a certain amount of water and kaolin for ball milling, wherein in the wet ball milling process, the amount of the water is 70% of the mass of the frit prepared in the step (1), the amount of the kaolin is 10% of the mass of the frit prepared in the step (1), sieving with a 250-mesh sieve after ball milling, pressing into mud pieces, drying at the temperature of not more than 100 ℃, crushing, packaging and forming to obtain the glaze powder.
Example 2
The fly ash-based antibacterial glaze powder comprises the following raw materials in parts by mass: 10 parts of borax; 6 parts of boric acid; 40 parts of anorthite; 20 parts of quartz; 8 parts of calcium carbonate; 1.5 parts of barium carbonate; 13 parts of aluminum oxide; 15 parts of nano zirconium phosphate silver-loaded antibacterial agent and 15 parts of titanium dioxide; 6 parts of rare earth oxide; 5 parts of magnesium oxide and 55 parts of fly ash.
The embodiment also provides a preparation method of the fly ash-based antibacterial glaze powder, which comprises the following steps:
(1) weighing borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate, alumina and fly ash according to a ratio, uniformly mixing, then melting mixed powder, wherein the melting temperature of the mixed powder is 1550 ℃, the melting time is 15 hours, and then dripping water to extract, so as to form granular clinker, thus obtaining a rough base material;
(2) weighing the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the rare earth oxide and the magnesium oxide according to the proportion, adding the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the rare earth oxide and the magnesium oxide into deionized water, and then violently stirring the mixture by using an electric stirrer to obtain a mixed solution, namely the antibacterial agent is prepared;
(3) uniformly mixing the rough base material prepared in the step (1) with the antibacterial agent prepared in the step (2), adding a deflocculant sodium dodecyl benzene sulfonate solution with the pH of 7 and the concentration of 10mmol/l, uniformly stirring, adding a certain amount of water and kaolin for ball milling, wherein in the wet ball milling process, the amount of the water is 70% of the mass of the frit prepared in the step (1), the amount of the kaolin is 10% of the mass of the frit prepared in the step (1), sieving with a 250-mesh sieve after ball milling, pressing into mud pieces, drying at the temperature of not more than 100 ℃, crushing, packaging and forming to obtain the glaze powder.
Example 3
The embodiment provides a fly ash-based antibacterial glaze powder, which comprises the following raw materials in parts by mass: 13 parts of borax; 8 parts of boric acid; 45 parts of anorthite; 25 parts of quartz; 8 parts of calcium carbonate; 1.5 parts of barium carbonate; 15 parts of aluminum oxide; 25 parts of nano zirconium phosphate silver-loaded antibacterial agent and 20 parts of titanium dioxide; 8 parts of rare earth oxide; 5 parts of manganese oxide and 60 parts of fly ash.
The embodiment also provides a preparation method of the fly ash-based antibacterial glaze powder, which comprises the following steps:
(1) weighing borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate, alumina and fly ash according to a ratio, uniformly mixing, then melting the mixed powder, wherein the melting temperature of the mixed powder is 1600 ℃, the melting time is 16 hours, and then dripping the mixed powder into water for extraction to form granular clinker, thus obtaining a rough base material;
(2) weighing the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the rare earth oxide and the manganese oxide according to the proportion, adding the nano zirconium phosphate silver-loaded antibacterial agent, the titanium dioxide, the rare earth oxide and the manganese oxide into deionized water, and then violently stirring by using an electric stirrer to obtain a mixed solution, namely preparing the antibacterial agent;
(3) uniformly mixing the rough base material prepared in the step (1) with the antibacterial agent prepared in the step (2), adding a deflocculant sodium dodecyl benzene sulfonate solution with the pH of 7 and the concentration of 10mmol/l, uniformly stirring, adding a certain amount of water and kaolin for ball milling, wherein in the wet ball milling process, the amount of the water is 70% of the mass of the frit prepared in the step (1), the amount of the kaolin is 10% of the mass of the frit prepared in the step (1), sieving with a 250-mesh sieve after ball milling, pressing into mud pieces, drying at the temperature of not more than 100 ℃, crushing, packaging and forming to obtain the glaze powder.
The results of the antibacterial property tests of the products prepared in the above examples after 2 hours, 24 hours and 5 days are shown in the following table 2:
TABLE 2 antibacterial test results of the products prepared in the above examples
In the embodiments 1 to 3, the fly ash is added into the raw material of the glaze powder, then the boric acid compound is added, the boric acid compound is added into the fly ash, the melting point of the boric acid compound is reduced, the vitreous material is easy to generate, the generated vitreous material can be used as the glaze powder of coal, porcelain and ceramic, the fly ash is used as the base material, the using amount is large, the economic benefit is remarkable, the production cost of the glaze powder can be reduced, a new path is opened for the comprehensive utilization of the fly ash, the glaze powder is more environment-friendly, and the waste of resources is avoided. And as shown in the above table 2, the sodium dodecyl benzene sulfonate solution is added in the process of making the glaze powder, the sodium dodecyl benzene sulfonate is added as the active agent of the antibacterial agent, the adsorption of the micro particles on the surface active agent can be utilized, the dispersion stability of the mixed powder can be changed, the sodium dodecyl benzene sulfonate is added in the glaze slurry as the deflocculant to stabilize the suspension and uniformly disperse the particles in the suspension, so that the antibacterial agent is uniformly mixed with other powder materials, and the enamel coating made of the glaze powder has strong antibacterial property, and the antibacterial property is more than 99%.
It should be understood by those skilled in the art that the above embodiments are only for illustrating the present invention and are not to be used as a limitation of the present invention, and that changes and modifications to the above embodiments are within the scope of the claims of the present invention as long as they are within the spirit and scope of the present invention.
Claims (4)
1. The fly ash-based antibacterial glaze powder is characterized by comprising the following raw materials in parts by mass: 50-60 parts of fly ash, 8-13 parts of borax, 4-8 parts of boric acid, 35-45 parts of anorthite, 15-25 parts of quartz, 7-8 parts of calcium carbonate, 1-1.5 parts of barium carbonate, 12-15 parts of alumina, 10-25 parts of nano zirconium phosphate silver-carrying antibacterial agent, 10-20 parts of titanium dioxide, 5-8 parts of rare earth oxide, 4-5 parts of far infrared material oxide and a proper amount of kaolin and deflocculant;
wherein: uniformly mixing the fly ash, borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate and alumina, then melting, and then dripping into water for extraction to form granular clinker; the deflocculant is sodium dodecyl benzene sulfonate solution, the pH value of the deflocculant is 7, and the concentration of the deflocculant is 10 mmol/l; the amount of the kaolin is 10% of the mass of the frit, and the kaolin is added when all other raw materials are stirred uniformly and then subjected to wet ball milling.
2. The fly ash-based antibacterial glaze powder according to claim 1, wherein: the composite material is prepared from the following raw materials in parts by mass: 55 parts of fly ash, 10 parts of borax, 6 parts of boric acid, 40 parts of anorthite, 20 parts of quartz, 8 parts of calcium carbonate, 1.5 parts of barium carbonate, 13 parts of alumina, 15 parts of nano zirconium phosphate silver-carrying antibacterial agent, 15 parts of titanium dioxide, 6 parts of rare earth oxide, 5 parts of far infrared material oxide and a proper amount of kaolin and deflocculant;
wherein: uniformly mixing the fly ash, borax, boric acid, anorthite, quartz, calcium carbonate, barium carbonate and alumina, then melting, and then dripping into water for extraction to form granular clinker; the deflocculant is sodium dodecyl benzene sulfonate solution, the pH value of the deflocculant is 7, and the concentration of the deflocculant is 10 mmol/l; the amount of the kaolin is 10% of the mass of the clinker, and the kaolin is added when all other raw materials are stirred uniformly and then subjected to wet ball milling.
3. The fly ash-based antibacterial glaze powder according to claim 1 or 2, wherein: the far infrared material oxide is one of ferric oxide, magnesium oxide and manganese oxide.
4. The fly ash-based antibacterial glaze powder according to claim 1 or 2, wherein: the nano silver-loaded zirconium phosphate antibacterial agent is a VK-T08 nano antibacterial agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010373959.5A CN111646700B (en) | 2017-07-07 | 2017-07-07 | Fly ash-based antibacterial glaze powder |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010373959.5A CN111646700B (en) | 2017-07-07 | 2017-07-07 | Fly ash-based antibacterial glaze powder |
| CN201710550025.2A CN107188419B (en) | 2017-07-07 | 2017-07-07 | High-heat-resistance antibacterial glaze powder and preparation method thereof |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710550025.2A Division CN107188419B (en) | 2017-07-07 | 2017-07-07 | High-heat-resistance antibacterial glaze powder and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111646700A CN111646700A (en) | 2020-09-11 |
| CN111646700B true CN111646700B (en) | 2022-05-13 |
Family
ID=59882393
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010373959.5A Active CN111646700B (en) | 2017-07-07 | 2017-07-07 | Fly ash-based antibacterial glaze powder |
| CN201710550025.2A Active CN107188419B (en) | 2017-07-07 | 2017-07-07 | High-heat-resistance antibacterial glaze powder and preparation method thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710550025.2A Active CN107188419B (en) | 2017-07-07 | 2017-07-07 | High-heat-resistance antibacterial glaze powder and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN111646700B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178516A (en) * | 2018-02-06 | 2018-06-19 | 福建工程学院 | A kind of preparation and application of ceramic color glaze |
| CN109293395A (en) * | 2018-10-24 | 2019-02-01 | 东莞唛铂纳米科技有限公司 | A kind of manufacturing process of anti-bacteria ceramic |
| CN109399932A (en) * | 2018-12-25 | 2019-03-01 | 佛山科学技术学院 | A kind of ceramic glaze and ceramics |
| CN111423124B (en) * | 2020-03-23 | 2022-05-20 | 广西欧神诺陶瓷有限公司 | Wear-resistant transparent glaze, wear-resistant polished glazed brick and preparation method thereof |
| CN111499413B (en) * | 2020-04-30 | 2022-09-13 | 佛山科学技术学院 | Green antibacterial glaze |
| CN111333430B (en) * | 2020-05-19 | 2020-11-13 | 佛山市东鹏陶瓷发展有限公司 | Deodorizing glaze and preparation method of glazed tile using same |
| CN111559864A (en) * | 2020-07-01 | 2020-08-21 | 福建省德化县瓷国文化有限公司 | Environment-friendly ceramic glaze, thermal shock resistant environment-friendly ceramic product prepared from environment-friendly ceramic glaze and preparation method of ceramic product |
| CN111747649A (en) * | 2020-07-13 | 2020-10-09 | 卓开权 | Environment-friendly antibacterial ceramic glaze |
| CN112250305A (en) * | 2020-10-26 | 2021-01-22 | 辽宁大学 | Antibacterial ceramic glaze based on boric sludge and preparation method and application thereof |
| CN112408796B (en) * | 2020-11-27 | 2022-07-12 | 景德镇陶瓷大学 | Antibacterial, easy-to-clean and zirconium-free whitening functional glaze and preparation method and application thereof |
| CN112429968A (en) * | 2020-12-28 | 2021-03-02 | 湖州南浔百迪电子商务有限公司 | Antibacterial glaze for bathroom products and preparation method thereof |
| CN113248147B (en) * | 2021-06-07 | 2021-11-02 | 佛山瑭虹釉料科技有限公司 | Wear-resistant antibacterial glaze and preparation method thereof |
| ES2928896B2 (en) * | 2022-06-10 | 2023-10-09 | Consejo Superior Investigacion | ENAMELED CERAMIC PIECE |
| CN115073003B (en) * | 2022-07-07 | 2023-12-12 | 佛山市东鹏陶瓷发展有限公司 | Antibacterial ceramic tile and preparation method thereof |
| CN115745405A (en) * | 2022-12-30 | 2023-03-07 | 福建省德化县心友工贸有限公司 | Ceramic glaze with antibacterial effect and application thereof |
| CN117859768A (en) * | 2024-03-11 | 2024-04-12 | 佛山市东鹏陶瓷有限公司 | Composite antiviral agent and preparation method thereof, protective glaze, ceramic tile and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003146736A (en) * | 2001-11-16 | 2003-05-21 | Nagasaki Prefecture | Heat insulating lightweight reinforced porcelain |
| CN103253909A (en) * | 2013-04-18 | 2013-08-21 | 深圳市爱思宝科技发展有限公司 | Glaze material and preparation method of glaze material plate |
| CN104496408A (en) * | 2015-01-01 | 2015-04-08 | 陈星延 | Ceramic matrix composition and use and method of ceramic matrix composition for preparing bone ash memorial box |
| CN106082968A (en) * | 2016-06-23 | 2016-11-09 | 安徽省含山瓷业股份有限公司 | A kind of ceramic ware for daily use adding flyash |
| CN106278171A (en) * | 2016-08-22 | 2017-01-04 | 关宝强 | A kind of floor tile and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54155190A (en) * | 1978-05-30 | 1979-12-06 | Mitsubishi Heavy Ind Ltd | Production of catalyst using metal as base material |
| CN106116150A (en) * | 2016-06-30 | 2016-11-16 | 安徽省德邦瓷业有限公司 | A kind of ceramic glaze and preparation method thereof |
| CN106348608A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Antibacterial glaze material |
| CN106746668B (en) * | 2016-12-14 | 2019-05-14 | 江西精隆陶瓷有限公司 | A kind of antibacterial ceramic glaze liquid and preparation method thereof |
-
2017
- 2017-07-07 CN CN202010373959.5A patent/CN111646700B/en active Active
- 2017-07-07 CN CN201710550025.2A patent/CN107188419B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003146736A (en) * | 2001-11-16 | 2003-05-21 | Nagasaki Prefecture | Heat insulating lightweight reinforced porcelain |
| CN103253909A (en) * | 2013-04-18 | 2013-08-21 | 深圳市爱思宝科技发展有限公司 | Glaze material and preparation method of glaze material plate |
| CN104496408A (en) * | 2015-01-01 | 2015-04-08 | 陈星延 | Ceramic matrix composition and use and method of ceramic matrix composition for preparing bone ash memorial box |
| CN106082968A (en) * | 2016-06-23 | 2016-11-09 | 安徽省含山瓷业股份有限公司 | A kind of ceramic ware for daily use adding flyash |
| CN106278171A (en) * | 2016-08-22 | 2017-01-04 | 关宝强 | A kind of floor tile and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111646700A (en) | 2020-09-11 |
| CN107188419B (en) | 2020-06-12 |
| CN107188419A (en) | 2017-09-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111646700B (en) | Fly ash-based antibacterial glaze powder | |
| CN103896634B (en) | High-temperature domestic porcelain metallic bright glaze and product decorated by same | |
| CN102060571A (en) | Green glaze for daily porcelain | |
| CN104926281A (en) | Preparation method of low-cost ultra-white porcelain tile | |
| CN107140948A (en) | A kind of daily bone china of high whiteness and preparation method thereof | |
| CN104150965A (en) | Copper red glaze formula and manufacturing process of copper red glaze porcelain | |
| CN105315015A (en) | Preparation method for architectural decoration flambe art ceramic tile | |
| CN109293395A (en) | A kind of manufacturing process of anti-bacteria ceramic | |
| CN106747277A (en) | Magnesium soil ceramic batch and preparation method thereof | |
| CN109650859A (en) | A kind of high whiteness Ceramic Tiles of no zirconium and preparation method thereof | |
| CN101973788A (en) | Preparation method of phase-separation peacock blue glaze | |
| CN102173740A (en) | Method for manufacturing glazed brick by utilizing silico-calcium slag | |
| WO2018000562A1 (en) | Compound zirconium silicate opacifying agent, preparation method therefor and application thereof | |
| CN103896557B (en) | Jade porcelain and making method thereof | |
| CN102020459A (en) | Feldspar-free ecological daily fine porcelain and manufacturing method thereof | |
| CN106365673A (en) | Low-temperature quick burning daily ceramic and production process thereof | |
| CN107266024A (en) | A kind of antibacterial wearable environment protection ceramic tile and preparation method thereof | |
| CN103553566A (en) | Preparation method of material for electrical porcelain body and electrical porcelain body | |
| CN113800770A (en) | Intermediate-temperature double-layer transmutation fancy glaze and manufacturing method thereof | |
| CN101508598B (en) | Rare earth neodymium red flambe glaze pigment and method of producing the same | |
| CN102206097A (en) | Additive of compound zirconium silicate for glaze and use method thereof | |
| CN102010232A (en) | Building ceramic aventurine glaze and preparation method thereof | |
| CN103030366A (en) | Red porcelain and method for producing same | |
| CN107043243A (en) | A kind of new type bone china mud and preparation method thereof | |
| CN111548015A (en) | Ceramic glaze with antibacterial and mildew-proof effects and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |