CN106348608A - Antibacterial glaze material - Google Patents

Antibacterial glaze material Download PDF

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Publication number
CN106348608A
CN106348608A CN201610833598.1A CN201610833598A CN106348608A CN 106348608 A CN106348608 A CN 106348608A CN 201610833598 A CN201610833598 A CN 201610833598A CN 106348608 A CN106348608 A CN 106348608A
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CN
China
Prior art keywords
parts
glaze
antibacterial
oxide
zirconium phosphate
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Pending
Application number
CN201610833598.1A
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Chinese (zh)
Inventor
崔松伟
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Individual
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Individual
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Priority to CN201610833598.1A priority Critical patent/CN106348608A/en
Publication of CN106348608A publication Critical patent/CN106348608A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00Glasses, glazes or enamels with special properties
    • C03C2204/02Antibacterial glass, glaze or enamel

Abstract

An antibacterial glaze material comprises a nano zirconium phosphate silver-loaded antibacterial agent, nano titanium dioxide, zinc oxide, copper oxide, Jiushan local glaze stone, quartz, talcum, copper ores and calcite. The antibacterial glaze material has the advantages that the nano zirconium phosphate silver-loaded antibacterial agent and the nano titanium dioxide are added into the glaze material, so that the glaze material has good antibacterial property, is non-toxic and pollution-free, and is suitable for the glaze formula of Jun porcelain kitchenware such as plates and bowls; the glaze material is good in fluidity, less prone to blistering and good in glossiness, and Jun porcelain glaze prepared by the glaze material is stable and uniform in color.

Description

A kind of antibacterial glaze
Technical field
The invention belongs to pottery manufacturing technology field is and in particular to a kind of antibacterial glaze.
Background technology
Pottery with glaze thick for this, in its color or heavy glaze bottom or outstanding glaze or floating glaze table, the thick muddy work of glaze, glaze layer opalescence jade-like stone profit, Work of being administrations with multiplied departments is intended to drip, and third dimension is extremely strong.With transmutation as god, natural transmutation is that the elite of pottery art is located to pottery, is also Pottery is rely the four seas of becoming famous, the rare part of porcelain woods of making a name.With applying a kind of glaze in firing, once burning till in multicoloured it is then " entering kiln of the same colour, kiln discharge ten thousand is color ".Protean transmutation effect, defines the infinite mystery of colors changing hue, in red inner purple, purple General red, multicolored imbibition during residence is white, white in dark blue, blue or green, forms a brightening, and has the title of " pottery is no right, and transmutation is unparalleled ".
With the raising of people's living standard and life taste, people are to public place, living space, daily life and doctor Treat the environment optimization of facility and purify growing interest, be continually changing development, people with scientific and technological progress and mainstream of society value To decoration pottery and pottery requirement more and more higher, this just in the urgent need to constantly putting out a new product, to adapt to consumer not With needs.
The colored glaze on ceramic surface on market is likely to become Health Killer, and lead in colored glaze, hydrargyrum, radium, cadmium etc. are all Insalubrious element, during using underproof ceramic product, the meeting dissolution of these harmful substances, enter human body with food, Time one is long, can cause chronic poisoning.
The present invention provides a kind of pottery glaze with antibacterial functions, is in process of production, adds inorganic antiseptic, from And making pottery surface have a kind of new function pottery glaze of antibacterial action, antibacterial pottery is as feature pottery product, energy Enough it is prevented effectively from the infringement to human body for the various infectious disease, the particularly sanitary precaution of public place.
Content of the invention
In order to solve the above problems, the present invention provides a kind of antibacterial glaze.
The technical solution used in the present invention is:
A kind of antibacterial glaze, it is made up of following raw materials according: nanometer silver-zirconium phosphate antimicrobial, nano titanium oxide, oxidation Zinc, copper oxide, turtledove Yamamoto medicine, quartz, Talcum, Copper Ores, calcite.
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: nanometer silver-zirconium phosphate antimicrobial 10-20 Part, nano titanium oxide 10-20 part, zinc oxide 3-5 part, copper oxide 3-5 part, turtledove Yamamoto medicine 60-70 part, quartzy 20-30 part, cunning Stone 10-20 part, Copper Ores 5-10 part, calcite 10-20 part.
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: 15 parts of nanometer silver-zirconium phosphate antimicrobial, receives Rice 15 parts of titanium dioxide, 4 parts of zinc oxide, 4 parts of copper oxide, 65 parts of turtledove Yamamoto medicine, quartz 25 parts, 15 parts of Talcum, 8 parts of Copper Ores, 15 parts of calcite.
The preparation method of the antibacterial glaze of the present invention is as follows:
(1) pulverize: first take the zinc oxide of above-mentioned weight portion, copper oxide, turtledove Yamamoto medicine, quartz, Talcum, Copper Ores, calcite to put Enter in ball milling and pulverize, sieve as mix powder after mix homogeneously;
(2) melting: mix powder is placed in melting in crucible, crucible is generally located on the flue between kiln and chimney, Separately set one on stove and supplement dye chamber, when flue gas shortage of heat or kiln stop burning, you can with the roasting of aftercombustion room, crucible bottom There is an aperture in portion, is blocked with admant English bead, to mix powder be melt into fluidised form melt matter when, bead is floated, and molten matter flows Enter quenching in following tank, make molten matter split into crisp and transparent fritter;
(3) fritter that molten matter splits into is placed in powder in ball milling together with nanometer silver-zirconium phosphate antimicrobial, nano titanium oxide Broken filtration, finally obtain is glaze.
Nanometer silver-zirconium phosphate antimicrobial: product is white powder, this product belongs to broad spectrum antimicrobicide, its sterilization, antibacterial effect Fruit is persistently, harmless, to no skin irritation, belongs to safety non-toxic product;1300 DEG C of high temperature can be stood, and not easy to change; Diameter of particle is little, even particle size distribution, and specific surface area is big, with various kinds of resin phase mixing, material can be added after surface treated Work performance and other performance no affect;Can for good and all combine with macromolecular material, chemical stability is good.In wider ph scope Interior chemically stable, is amenable to surfactant and repeatedly washs, and its antimicrbial power does not decline;Can require to carry out powder surface according to user Process, to reach the optimum dispersion in dielectric matrix;It is better than zeolite type, silica gel type antibacterial with resin compatibility;Ultralow poison Property, ld value is much larger than other inorganic antiseptics;High transparent, is applied in clear plastic articles not affect its transparency.
Nano titanium oxide, also known as titanium dioxide, below 100 nanometers, product appearance is white powder to diameter, has anti- Line, antibacterial, self-cleaning, ageing resistace.
Turtledove Yamamoto medicine, is a kind of natural glaze stone, mainly originates in Yuzhou turtledove mountain area Li Cun.
The invention has the beneficial effects as follows: the present invention is added to using nanometer silver-zirconium phosphate antimicrobial and nano titanium oxide In glaze, make glaze have good anti-microbial property, nontoxic pollution-free, be suitable for the glaze formula of the kitchen tools pottery such as dish, bowl, Glaze good fluidity, not easy to foaming, good luster, the pottery glaze of making is in colour-stable, uniform color.
Specific embodiment
A kind of antibacterial glaze, it is made up of following raw materials according: nanometer silver-zirconium phosphate antimicrobial, nano titanium oxide, Zinc oxide, copper oxide, turtledove Yamamoto medicine, quartz, Talcum, Copper Ores, calcite.
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: nanometer silver-zirconium phosphate antimicrobial 10-20 Part, nano titanium oxide 10-20 part, zinc oxide 3-5 part, copper oxide 3-5 part, turtledove Yamamoto medicine 60-70 part, quartzy 20-30 part, cunning Stone 10-20 part, Copper Ores 5-10 part, calcite 10-20 part.
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: 15 parts of nanometer silver-zirconium phosphate antimicrobial, receives Rice 15 parts of titanium dioxide, 4 parts of zinc oxide, 4 parts of copper oxide, 65 parts of turtledove Yamamoto medicine, quartz 25 parts, 15 parts of Talcum, 8 parts of Copper Ores, 15 parts of calcite.
The preparation method of the antibacterial glaze of the present invention is as follows:
(1) pulverize: first take the zinc oxide of above-mentioned weight portion, copper oxide, turtledove Yamamoto medicine, quartz, Talcum, Copper Ores, calcite to put Enter in ball milling and pulverize, sieve as mix powder after mix homogeneously;
(2) melting: mix powder is placed in melting in crucible, crucible is generally located on the flue between kiln and chimney, Separately set one on stove and supplement dye chamber, when flue gas shortage of heat or kiln stop burning, you can with the roasting of aftercombustion room, crucible bottom There is an aperture in portion, is blocked with admant English bead, to mix powder be melt into fluidised form melt matter when, bead is floated, and molten matter flows Enter quenching in following tank, make molten matter split into crisp and transparent fritter;
(3) fritter that molten matter splits into is placed in powder in ball milling together with nanometer silver-zirconium phosphate antimicrobial, nano titanium oxide Broken filtration, finally obtain is glaze.
Embodiment 1
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: nanometer silver-zirconium phosphate antimicrobial 15 part, nanometer two 15 parts of titanium oxide, 4 parts of zinc oxide, 4 parts of copper oxide, 65 parts of turtledove Yamamoto medicine, 25 parts of quartz, 15 parts of Talcum, 8 parts of Copper Ores, Fang Xie 15 parts of stone.
The preparation method of the antibacterial glaze of the present invention is as follows:
(1) pulverize: first take the zinc oxide of above-mentioned weight portion, copper oxide, turtledove Yamamoto medicine, quartz, Talcum, Copper Ores, calcite to put Enter in ball milling and pulverize, sieve as mix powder after mix homogeneously;
(2) melting: mix powder is placed in melting in crucible, crucible is generally located on the flue between kiln and chimney, Separately set one on stove and supplement dye chamber, when flue gas shortage of heat or kiln stop burning, you can with the roasting of aftercombustion room, crucible bottom There is an aperture in portion, is blocked with admant English bead, to mix powder be melt into fluidised form melt matter when, bead is floated, and molten matter flows Enter quenching in following tank, make molten matter split into crisp and transparent fritter;
(3) fritter that molten matter splits into is placed in powder in ball milling together with nanometer silver-zirconium phosphate antimicrobial, nano titanium oxide Broken filtration, finally obtain is glaze.
Embodiment 2
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: nanometer silver-zirconium phosphate antimicrobial 10 part, nanometer two 10 parts of titanium oxide, 3 parts of zinc oxide, 3 parts of copper oxide, 60 parts of turtledove Yamamoto medicine, 20 parts of quartz, 10 parts of Talcum, 5 parts of Copper Ores, Fang Xie 10 parts of stone.
Embodiment 3
A kind of antibacterial glaze, it is made up of the raw material of following weight portion: nanometer silver-zirconium phosphate antimicrobial 20 part, nanometer two 20 parts of titanium oxide, 5 parts of zinc oxide, 5 parts of copper oxide, 70 parts of turtledove Yamamoto medicine, 30 parts of quartz, 20 parts of Talcum, 10 parts of Copper Ores, Fang Xie 20 parts of stone.

Claims (3)

1. a kind of antibacterial glaze it is characterised in that: it is made up of following raw materials according: nanometer silver-zirconium phosphate antimicrobial, nanometer Titanium dioxide, zinc oxide, copper oxide, turtledove Yamamoto medicine, quartz, Talcum, Copper Ores, calcite.
2. a kind of antibacterial glaze according to claim 1 it is characterised in that: it is made up of the raw material of following weight portion : nanometer silver-zirconium phosphate antimicrobial 10-20 part, nano titanium oxide 10-20 part, zinc oxide 3-5 part, copper oxide 3-5 part, turtledove Yamamoto medicine 60-70 part, quartzy 20-30 part, Talcum 10-20 part, Copper Ores 5-10 part, calcite 10-20 part.
3. a kind of antibacterial glaze according to claim 1 it is characterised in that: it is made up of the raw material of following weight portion : 15 parts of nanometer silver-zirconium phosphate antimicrobial, 15 parts of nano titanium oxide, 4 parts of zinc oxide, 4 parts of copper oxide, turtledove Yamamoto medicine 65 Part, 25 parts of quartz, 15 parts of Talcum, 8 parts of Copper Ores, 15 parts of calcite.
CN201610833598.1A 2016-09-20 2016-09-20 Antibacterial glaze material Pending CN106348608A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610833598.1A CN106348608A (en) 2016-09-20 2016-09-20 Antibacterial glaze material

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Application Number Priority Date Filing Date Title
CN201610833598.1A CN106348608A (en) 2016-09-20 2016-09-20 Antibacterial glaze material

Publications (1)

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CN106348608A true CN106348608A (en) 2017-01-25

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106986542A (en) * 2017-05-15 2017-07-28 晋大纳米科技(厦门)有限公司 A kind of far-infrared anti-biotic ceramic glaze and preparation method thereof
CN107021630A (en) * 2017-03-17 2017-08-08 界首市伟盛古窑彩陶制作发展有限公司 A kind of high-temperature environmental-protection antibacterial glaze
CN107188419A (en) * 2017-07-07 2017-09-22 福建省德化县联达陶瓷有限公司 A kind of high heat-resistance antibacterial powdered frit and preparation method thereof
CN107365081A (en) * 2017-09-05 2017-11-21 赵永强 A kind of pottery glaze with anti-microbial property and preparation method thereof
CN108585497A (en) * 2018-07-21 2018-09-28 张家港市沐和新材料技术开发有限公司 A kind of formula of anti-bacteria ceramic glaze
CN108618634A (en) * 2017-03-20 2018-10-09 佛山市顺德区美的电热电器制造有限公司 The production method of interior pot, cooking apparatus and interior pot
CN108751713A (en) * 2018-08-17 2018-11-06 张家港市沐和新材料技术开发有限公司 A kind of anti-bacteria ceramic and preparation method thereof
CN109970341A (en) * 2019-04-23 2019-07-05 廖祥胜 Antifouling and antibiosis ceramic glaze and preparation method thereof
CN110397126A (en) * 2019-07-16 2019-11-01 凌贯 A kind of enamel nano-antibacterial sink and its production technology
CN112960990A (en) * 2021-02-08 2021-06-15 同曦集团有限公司 Antibacterial, mildewproof and antiviral porous ceramic and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036812A (en) * 2015-07-28 2015-11-11 郏县宏大瓷业有限公司 Glaze material for Jun red glaze and process for preparing Jun porcelain from glaze material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105036812A (en) * 2015-07-28 2015-11-11 郏县宏大瓷业有限公司 Glaze material for Jun red glaze and process for preparing Jun porcelain from glaze material

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107021630A (en) * 2017-03-17 2017-08-08 界首市伟盛古窑彩陶制作发展有限公司 A kind of high-temperature environmental-protection antibacterial glaze
CN108618634A (en) * 2017-03-20 2018-10-09 佛山市顺德区美的电热电器制造有限公司 The production method of interior pot, cooking apparatus and interior pot
CN108618634B (en) * 2017-03-20 2021-10-08 佛山市顺德区美的电热电器制造有限公司 Inner pot, cooking utensil and manufacturing method of inner pot
CN106986542A (en) * 2017-05-15 2017-07-28 晋大纳米科技(厦门)有限公司 A kind of far-infrared anti-biotic ceramic glaze and preparation method thereof
CN107188419A (en) * 2017-07-07 2017-09-22 福建省德化县联达陶瓷有限公司 A kind of high heat-resistance antibacterial powdered frit and preparation method thereof
CN107188419B (en) * 2017-07-07 2020-06-12 福建省德化县联达陶瓷有限公司 High-heat-resistance antibacterial glaze powder and preparation method thereof
CN107365081A (en) * 2017-09-05 2017-11-21 赵永强 A kind of pottery glaze with anti-microbial property and preparation method thereof
CN108585497A (en) * 2018-07-21 2018-09-28 张家港市沐和新材料技术开发有限公司 A kind of formula of anti-bacteria ceramic glaze
CN108751713A (en) * 2018-08-17 2018-11-06 张家港市沐和新材料技术开发有限公司 A kind of anti-bacteria ceramic and preparation method thereof
CN109970341A (en) * 2019-04-23 2019-07-05 廖祥胜 Antifouling and antibiosis ceramic glaze and preparation method thereof
CN110397126A (en) * 2019-07-16 2019-11-01 凌贯 A kind of enamel nano-antibacterial sink and its production technology
CN112960990A (en) * 2021-02-08 2021-06-15 同曦集团有限公司 Antibacterial, mildewproof and antiviral porous ceramic and preparation method and application thereof

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Application publication date: 20170125