CN109399932A - A kind of ceramic glaze and ceramics - Google Patents
A kind of ceramic glaze and ceramics Download PDFInfo
- Publication number
- CN109399932A CN109399932A CN201811586968.1A CN201811586968A CN109399932A CN 109399932 A CN109399932 A CN 109399932A CN 201811586968 A CN201811586968 A CN 201811586968A CN 109399932 A CN109399932 A CN 109399932A
- Authority
- CN
- China
- Prior art keywords
- mass parts
- rare earth
- ceramic glaze
- rare
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
It is suitble to the ceramic glaze and ceramics used in everyday with antibacterial action the invention discloses a kind of.The ceramic glaze includes following components: kaolin, glassy feldspar, rare earth material, zircon, diatomite, aluminium oxide, nano-titanium dioxide, and the rare earth material is rare-earth salts or rare earth oxide.The nano-titanium dioxide ingredient that the present invention uses has preferable antibacterial action, the rare earth material of addition can make titania be unlikely to excessively to grow up, simultaneously, by the component of raw material and the adjustment of component proportion, to control the size of crystal grain, there can be higher specific surface area, it is also beneficial to glaze and forms fine and close nanostructure, in the same time, it can be contacted with more air, effective killing effect is formed to the various harmful bacterias wherein contained.
Description
Technical field
The present invention relates to ceramic glazes, more particularly, to a kind of ceramic glaze and ceramics.
Background technique
It is gradually increased with the continuous development of society with living standard, requirement of the people for quality of life be increasingly
Height, the idea of sanitary antimicrobial health care are also rooted in the hearts of the people therewith, and in order to meet standard of the people in terms of health, anti-bacteria ceramic is met the tendency of
And it gives birth to and has obtained faster development.Anti-bacteria ceramic, which refers to, is keeping ceramic original using the same of function and decorative effect
When, increase a kind of ceramic product of disinfection, sterilization and chemical degradation function.These antimicrobial ceramic products be widely used in health,
The industries such as medical treatment, family room, civilian or industrial building.
Except in ceramic batch add dependent antimicrobial ingredient in addition to, imposed in ceramic glaze certain antimicrobial component be also can
A kind of scheme of choosing.But after introducing antimicrobial component, there is also some problems to be solved, for example, prepared by part anti-bacteria ceramic
Complex process requires action condition high.A kind of it is suitble to the ceramics used in everyday with antibacterial action therefore, it is necessary to explore
Glaze.
Summary of the invention
The technical problem to be solved by the present invention is to how provide a kind of to be suitble to the pottery used in everyday with antibacterial action
Glaze and ceramics.
The technical solution used in the present invention is:
A kind of ceramic glaze, including following components: the kaolin of 30-50 mass parts, 10-30 mass parts glassy feldspar,
The rare earth material of 0.1-4 mass parts, the zircon of 1-3 mass parts, the diatomite of 1-5 mass parts, the aluminium oxide of 2-10 mass parts, 2-
The nano-titanium dioxide of 8 mass parts, the rare earth material are rare-earth salts or rare earth oxide.
Preferably, further include 0.5-3 mass parts tourmaline and 0.1-1.5 mass parts sierozem power.
Preferably, diatomite has been also loaded silver ion.
Preferably, the rare earth element of rare earth material is at least one of cerium, lanthanum, europium, samarium.
It is further preferred that rare-earth salts is at least one of cerous nitrate, lanthanum chloride, acetic acid europium, samaric nitrate.
Still more preferably, rare-earth salts is cerous nitrate, lanthanum chloride, acetic acid europium, any two kinds in samaric nitrate.
Preferably, the partial size of nano-titanium dioxide is 50-100nm.
It is further preferred that further including the adhesive remover of 0.1-1.2 mass parts and the water of 20-40 mass parts.
Still more preferably, adhesive remover is at least one of sodium tripolyphosphate, sodium humate.
A kind of ceramics fire formation after imposing on green body using the ceramic glaze of preceding claim.
The beneficial effects of the present invention are:
The nano-titanium dioxide ingredient that the present invention uses has preferable antibacterial action, and the rare earth material of addition can make two
Titanium oxide grain is unlikely to excessively to grow up, meanwhile, by the component of raw material and the adjustment of component proportion, to control the ruler of crystal grain
It is very little, can have higher specific surface area, be also beneficial to glaze form fine and close nanostructure in the same time can
It is contacted with more air, effective killing effect is formed to the various harmful bacterias wherein contained.
The further beneficial effect of the present invention also resides in, and adds sierozem power and tourmaline, glaze slip can be made to have more preferable
Viscosity, facilitate the progress of glazing process.
The further beneficial effect of the present invention also resides in, and the ingredient for limiting specific rare-earth salts is conducive to improve in preparation process
The release efficiency of middle rare earth element.
The further beneficial effect of the present invention also resides in, and sodium tripolyphosphate selected by the present invention or sodium humate have suction
Attached exchange, complexing isocolloid chemical property, can improve pug performance, improve blank strength, reduce half after adding in process
The breakage of finished product reduces production cost, improves product quality and other effects, has highly significant economic benefit and use value.
Specific embodiment
It is carried out below with reference to technical effect of the embodiment to design of the invention, specific structure and generation clear, complete
Ground description, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is of the invention one
Section Example, rather than whole embodiments, based on the embodiment of the present invention, those skilled in the art are not paying creativeness
Other embodiments obtained, belong to the scope of protection of the invention under the premise of labour.
Embodiment 1
A kind of ceramic glaze, including following components: the kaolin of 50 mass parts, the glassy feldspar of 30 mass parts, 4 mass parts
Rare earth material, the zircon of 3 mass parts, the diatomite of 5 mass parts, the aluminium oxide of 10 mass parts, 8 mass parts nanometer titanium dioxide
Titanium；
Wherein, the rare earth material of 4 mass parts is the cerous nitrate of 2 mass parts and the lanthanum chloride of 2 mass parts.
Use the preparation method of the ceramics of the glaze, comprising the following steps:
1. preparing blank:
Using a kind of ceramic body formula well known in the prior art (for example, it may be CN108503357A,
CN107746248A or the scheme disclosed in other patent documents) each raw material of selection is pre-processed, slurry is made in mixing and ball milling
Body.
2. suppressing biscuit:
Powder is made in above-mentioned slurry, re-compacted molding obtains biscuit, natural drying；
3. blank sintering:
Biscuit is entered into kiln sintering, for sintering temperature at 900-1100 degrees Celsius, the firing time is 15-20 hours；
4. preparing glaze:
It is prepared in proportion according to above-mentioned glaze formula, is put into ball milling in ball mill, obtain above-mentioned glaze；
5. glazing is sintered:
By the glaze prepared in the burned uniform glazing of billet surface, the green body after glazing is entered into kiln sintering, firing temperature
It is 140-160 degrees Celsius, firing time 20-24 hour, keeps the temperature 30min, natural cooling is come out of the stove.
Embodiment 2
A kind of ceramic glaze, including following components: the kaolin of 30 mass parts, the glassy feldspar of 10 mass parts, 0.1 mass parts
Rare earth material, the zircon of 1 mass parts, the diatomite of 1 mass parts, the aluminium oxide of 2 mass parts, 2 mass parts nanometer titanium dioxide
The sierozem power of titanium, the tourmaline of 0.5 mass parts and 0.1 mass parts；
Wherein, the rare earth material of 0.1 mass parts is the acetic acid europium of 0.1 mass parts.
Embodiment 3
A kind of ceramic glaze, including following components: the kaolin of 40 mass parts, the glassy feldspar of 20 mass parts, 2 mass parts
Rare earth material, the zircon of 2 mass parts, the diatomite of 3 mass parts, the aluminium oxide of 6 mass parts, 5 mass parts nano-titanium dioxide,
The sierozem power of the tourmaline of 3 mass parts and 1.5 mass parts；
Wherein, the rare earth material of 2 mass parts is the lanthanum chloride and 1 mass parts of the cerous nitrate of 0.5 mass parts, 0.5 mass parts
Samaric nitrate.
Embodiment 4
A kind of ceramic glaze, including following components: the kaolin of 50 mass parts, the glassy feldspar of 30 mass parts, 4 mass parts
Rare earth material, the zircon of 3 mass parts, the diatomite of 5 mass parts, the aluminium oxide of 10 mass parts, 8 mass parts nanometer titanium dioxide
The water of titanium, the adhesive remover of 1.2 mass parts and 20 mass parts；
Wherein, the rare earth material of 4 mass parts be the cerous nitrate of 1 mass parts, the lanthanum chloride of 1 mass parts, 1 mass parts acetic acid
The samaric nitrate of europium and 1 mass parts；The adhesive remover of 1.2 mass parts is the sodium humate of 1.2 mass parts.
Embodiment 5
A kind of ceramic glaze, including following components: the kaolin of 50 mass parts, the glassy feldspar of 30 mass parts, 4 mass parts
Rare earth material, the zircon of 3 mass parts, the diatomite of 5 mass parts, the aluminium oxide of 10 mass parts, 8 mass parts nanometer titanium dioxide
Titanium, the tourmaline of 3 mass parts, the sierozem power of 1.5 mass parts, the adhesive remover of 0.1 mass parts and 20 mass parts water；
Wherein, the rare earth material of 4 mass parts is the cerous nitrate of 2 mass parts and the lanthanum chloride of 2 mass parts；0.1 mass parts
Adhesive remover is the sodium tripolyphosphate of 0.1 mass parts；The partial size of nano-titanium dioxide is 50-100nm.
Embodiment 6
A kind of ceramic glaze, including following components: the kaolin of 50 mass parts, the glassy feldspar of 30 mass parts, 4 mass parts
Rare earth material, the zircon of 3 mass parts, the diatomite of 5 mass parts, the aluminium oxide of 10 mass parts, 8 mass parts nanometer titanium dioxide
Titanium, the tourmaline of 3 mass parts, the sierozem power of 1.5 mass parts, the adhesive remover of 0.1 mass parts and 20 mass parts water；
Wherein, the rare earth material of 4 mass parts is the cerous nitrate of 2 mass parts and the lanthanum chloride of 2 mass parts；Nano-titanium dioxide
Partial size be 30-50nm.
It is to be illustrated to presently preferred embodiments of the present invention, but the present invention is not limited to the embodiment above,
Those skilled in the art can also make various equivalent deformation or replacement on the premise of without prejudice to spirit of the invention, this
Equivalent deformation or replacement are all included in the scope defined by the claims of the present application a bit.
Claims (10)
1. a kind of ceramic glaze, which is characterized in that including following components: the kaolin of 30-50 mass parts, 10-30 mass parts
Glassy feldspar, the rare earth material of 0.1-4 mass parts, the zircon of 1-3 mass parts, the diatomite of 1-5 mass parts, 2-10 mass parts oxygen
Change the nano-titanium dioxide of aluminium, 2-8 mass parts, the rare earth material is rare-earth salts or rare earth oxide.
2. ceramic glaze according to claim 1, which is characterized in that further include the tourmaline and 0.1- of 0.5-3 mass parts
The sierozem power of 1.5 mass parts.
3. ceramic glaze according to claim 1, which is characterized in that the diatomite has been also loaded silver ion.
4. ceramic glaze according to claim 1, which is characterized in that the rare earth element of the rare earth material be cerium, lanthanum,
At least one of europium, samarium.
5. ceramic glaze according to claim 4, which is characterized in that the rare-earth salts is cerous nitrate, lanthanum chloride, acetic acid
At least one of europium, samaric nitrate.
6. ceramic glaze according to claim 5, which is characterized in that the rare-earth salts is cerous nitrate, lanthanum chloride, acetic acid
Any two kinds in europium, samaric nitrate.
7. ceramic glaze according to claim 1-6, which is characterized in that the partial size of the nano-titanium dioxide is
50-100nm。
8. ceramic glaze according to claim 7, which is characterized in that further include the adhesive remover and 20- of 0.1-1.2 mass parts
The water of 40 mass parts.
9. ceramic glaze according to claim 8, which is characterized in that the adhesive remover is sodium tripolyphosphate, sodium humate
At least one of.
10. a kind of ceramics, which is characterized in that fired after imposing on green body using the described in any item ceramic glazes of claim 1-9
It is formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811586968.1A CN109399932A (en) | 2018-12-25 | 2018-12-25 | A kind of ceramic glaze and ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811586968.1A CN109399932A (en) | 2018-12-25 | 2018-12-25 | A kind of ceramic glaze and ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109399932A true CN109399932A (en) | 2019-03-01 |
Family
ID=65461196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811586968.1A Pending CN109399932A (en) | 2018-12-25 | 2018-12-25 | A kind of ceramic glaze and ceramics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109399932A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110040960A (en) * | 2019-05-28 | 2019-07-23 | 包头中科陶瓷科技有限公司 | A kind of rare earth anti-bacteria ceramic glaze and preparation method thereof |
| CN110467350A (en) * | 2019-09-16 | 2019-11-19 | 扬州工业职业技术学院 | A kind of cucurbit urea-modified europium doping heatproof and shockproof ceramic glaze and preparation method thereof |
| CN110510877A (en) * | 2019-09-16 | 2019-11-29 | 扬州工业职业技术学院 | A kind of europium doped ceramics glaze and the preparation method and application thereof |
| CN111377612A (en) * | 2020-04-26 | 2020-07-07 | 佛山科学技术学院 | Antifouling glaze |
| CN112759262A (en) * | 2021-03-05 | 2021-05-07 | 德化县嘉翔工艺品有限公司 | Wear-resistant diamond transparent glaze, wear-resistant diamond transparent glaze ceramic product and preparation method thereof |
| ES2843267A1 (en) * | 2020-01-15 | 2021-07-16 | Coloronda S L | Ceramic glaze with a warm, wood-like feel (Machine-translation by Google Translate, not legally binding) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102138569A (en) * | 2010-01-28 | 2011-08-03 | 广东炜林纳功能材料有限公司 | Rare-earth composite antibacterial agent and application thereof |
| CN102584343A (en) * | 2012-01-16 | 2012-07-18 | 淄博博纳科技发展有限公司 | Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic |
| CN104607039A (en) * | 2015-01-20 | 2015-05-13 | 济南木齐健康科技有限公司 | Composite material with anti-bacterial and purifying functions and preparation method of composite material |
| CN106242525A (en) * | 2016-08-05 | 2016-12-21 | 佛山市寰田陶瓷有限公司 | A kind of nano-antibacterial ceramic tile and preparation method thereof |
| CN107129151A (en) * | 2017-07-06 | 2017-09-05 | 高慧芹 | Anion function ceramic tile glaze and preparation method thereof |
| CN107188419A (en) * | 2017-07-07 | 2017-09-22 | 福建省德化县联达陶瓷有限公司 | A kind of high heat-resistance antibacterial powdered frit and preparation method thereof |
| CN107663083A (en) * | 2017-09-30 | 2018-02-06 | 武汉马腾科技发展有限公司 | A kind of ceramics with high-wearing feature and antibiotic property and preparation method thereof |
-
2018
- 2018-12-25 CN CN201811586968.1A patent/CN109399932A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102138569A (en) * | 2010-01-28 | 2011-08-03 | 广东炜林纳功能材料有限公司 | Rare-earth composite antibacterial agent and application thereof |
| CN102584343A (en) * | 2012-01-16 | 2012-07-18 | 淄博博纳科技发展有限公司 | Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic |
| CN104607039A (en) * | 2015-01-20 | 2015-05-13 | 济南木齐健康科技有限公司 | Composite material with anti-bacterial and purifying functions and preparation method of composite material |
| CN106242525A (en) * | 2016-08-05 | 2016-12-21 | 佛山市寰田陶瓷有限公司 | A kind of nano-antibacterial ceramic tile and preparation method thereof |
| CN107129151A (en) * | 2017-07-06 | 2017-09-05 | 高慧芹 | Anion function ceramic tile glaze and preparation method thereof |
| CN107188419A (en) * | 2017-07-07 | 2017-09-22 | 福建省德化县联达陶瓷有限公司 | A kind of high heat-resistance antibacterial powdered frit and preparation method thereof |
| CN107663083A (en) * | 2017-09-30 | 2018-02-06 | 武汉马腾科技发展有限公司 | A kind of ceramics with high-wearing feature and antibiotic property and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 中国轻工业信息中心等编: "《中国日用陶瓷年鉴 2017年版》", 31 October 2017, 中国轻工业出版社 * |
| 徐建华等编著: "《陶瓷花釉与装饰技术》", 30 April 2011, 中国轻工业出版社 * |
| 杨守仁等主编: "《中国地学通鉴 地质卷 上》", 30 June 2018, 陕西师范大学出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110040960A (en) * | 2019-05-28 | 2019-07-23 | 包头中科陶瓷科技有限公司 | A kind of rare earth anti-bacteria ceramic glaze and preparation method thereof |
| CN110467350A (en) * | 2019-09-16 | 2019-11-19 | 扬州工业职业技术学院 | A kind of cucurbit urea-modified europium doping heatproof and shockproof ceramic glaze and preparation method thereof |
| CN110510877A (en) * | 2019-09-16 | 2019-11-29 | 扬州工业职业技术学院 | A kind of europium doped ceramics glaze and the preparation method and application thereof |
| ES2843267A1 (en) * | 2020-01-15 | 2021-07-16 | Coloronda S L | Ceramic glaze with a warm, wood-like feel (Machine-translation by Google Translate, not legally binding) |
| WO2021144490A1 (en) * | 2020-01-15 | 2021-07-22 | Coloronda, S.L. | Ceramic glaze with a warm feel like wood |
| CN111377612A (en) * | 2020-04-26 | 2020-07-07 | 佛山科学技术学院 | Antifouling glaze |
| CN112759262A (en) * | 2021-03-05 | 2021-05-07 | 德化县嘉翔工艺品有限公司 | Wear-resistant diamond transparent glaze, wear-resistant diamond transparent glaze ceramic product and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109399932A (en) | A kind of ceramic glaze and ceramics | |
| CN104058795B (en) | A kind of nano-antibacterial ceramic utensil and manufacture craft thereof | |
| CN106242525A (en) | A kind of nano-antibacterial ceramic tile and preparation method thereof | |
| CN105777068B (en) | Your a kind of pea green porcelain and preparation method thereof | |
| CN111995364B (en) | Antibacterial rock plate and preparation method thereof | |
| CN103396090A (en) | Preparation method and glazing method for negative oxygen ion releasing far infrared purple sand utensil | |
| CN105541288B (en) | A kind of high-performance low bulk and function far infrared radiation function heat-proof purple sand cooker and preparation method thereof | |
| CN105669252B (en) | A kind of scale inhibition function sanitary ceramics and preparation method thereof | |
| CN106348787A (en) | Rare earth added antibacterial ceramic glaze and preparation method thereof | |
| CN109896839A (en) | A kind of antibacterial and mouldproof ceramic tile and preparation method thereof | |
| CN110256048A (en) | A kind of easy clean anti-bacteria ceramic and its manufacture craft | |
| CN109052952A (en) | A kind of antibacterial glaze composition and with its ceramic obtained | |
| CN109437924B (en) | Antibacterial ceramic product and preparation method thereof | |
| CN106957168A (en) | One kind can antibiotic ceramic tile and preparation method thereof | |
| CN111548122B (en) | Antibacterial carved stone ceramic tile and preparation method thereof | |
| CN115180967B (en) | Environment-friendly and healthy household ceramic and preparation method thereof | |
| CN105967642A (en) | Functional active purifying ceramic and preparation method and application thereof | |
| CN103641439A (en) | Antibacterial ceramic tile and preparation method thereof | |
| CN114409398A (en) | Antibacterial high-strength white porcelain and processing technology thereof | |
| CN104876586A (en) | Production method of novel ceramic tile | |
| CN101611718B (en) | Dragon spring celadon antibacterial agent and application thereof | |
| CN110256041A (en) | A kind of photocatalysis antibacterial ceramics easy to clean and preparation method thereof | |
| CN107721174A (en) | A kind of glazing process of pottery glaze with health role | |
| CN107266024A (en) | A kind of antibacterial wearable environment protection ceramic tile and preparation method thereof | |
| CN100594192C (en) | Ferric titanium dull kiln star spot variable composite color material and star spot glaze |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |