CN105967642A - Functional active purifying ceramic and preparation method and application thereof - Google Patents
Functional active purifying ceramic and preparation method and application thereof Download PDFInfo
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- CN105967642A CN105967642A CN201610265911.6A CN201610265911A CN105967642A CN 105967642 A CN105967642 A CN 105967642A CN 201610265911 A CN201610265911 A CN 201610265911A CN 105967642 A CN105967642 A CN 105967642A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
Abstract
The invention relates to a functional active purifying ceramic and a preparation method and an application thereof, wherein a functional active purifying ceramic blank material is prepared from the following components by the weight percentage: 13%-15% of quartz stone, 6%-8% of albite, 3%-5% of potassium feldspar, 5%-6% of medical stone, 5.9%-7% of a rare earth element, 2%-3% of borax, 47%-59% of clay, 1.5%-2.5% of barium carbonate, 2.1%-3.2% of spinel, and 2.5%-3% of cordierite. A functional active purifying ceramic glaze material is prepared from the following components by the weight percentage: 4%-5% of nanosilver, 4%-4.8% of tourmaline, 7%-8% of medical stone, 5.5%-6.5% of Muyu-stone, 11%-13% of negative ions, 2%-3% of a germanium powder, 2.3%-3% of borax, and 56%-65% of clay. The invention has the beneficial effects that the functional active purifying ceramic and the preparation method and the application thereof are provided, and the active purifying ceramic material can play a role in purifying water quality, and can purify water quality while playing a container role when applied in ceramic products, so as to achieve an efficacy of promoting human body health.
Description
Technical field
The invention belongs to ceramic technology field, relate to a kind of clean porcelain of functional work and its preparation method and application.
Background technology
Ceramic product is the most more and more applied in daily life, also carries in addition to as traditional decoration
For certain storage effect, but for ceramic product essence, its be to provide a carrier held,
Platform, and more beneficial effect cannot be provided, how to improve to providing from the material of pottery itself
More beneficial effect becomes problem and the main flow direction of research.
Summary of the invention
It is an object of the invention to, it is provided that a kind of clean porcelain of functional work, to solve the problems referred to above.
Another object of the present invention is to, it is provided that the preparation method of above-mentioned functions clean porcelain alive.
Third object of the present invention is, it is provided that the application of above-mentioned functions clean porcelain alive.
The present invention is accomplished by:
A kind of clean porcelain of functional work, the described clean porcelain of functional work is made up of following components in percentage by weight:
Quartz 13%-15%, albite 6%-8%, potassium feldspar 3%-5%, tourmaline 4%-5%, Maifanitum 5%-6%,
Rare earth element 5.9%-7%, Borax 2%-3%, clay 47%-59%, brium carbonate 1.5%-2.5%, spinelle
2.1%-3.2%, cordierite 2.5%-3%;The described clean glaze of functional work is by following components in percentage by weight
Make: nanometer silver 4%-5%, tourmaline 4%-4.8%, Maifanitum 7%-8%, Muyu-Stone 5.5%-6.5%, negative
Ion 11%-13%, germanium powder 2%-3%, Borax 2.3%-3%, clay 52%-60%.
Further, the described clean porcelain of functional work is made up of following components in percentage by weight: quartz
14%, albite 7%, potassium feldspar 4%, tourmaline 4.5%, Maifanitum 5.5%, rare earth element 6.5%, Borax
2.5%, clay 48.4%, brium carbonate 2%, spinelle 2.8%, cordierite 2.8%;The described clean porcelain of functional work
Glaze is made up of following components in percentage by weight: nanometer silver 4.5%, tourmaline 4.5%, Maifanitum 7.5%,
Muyu-Stone 6%, anion 12%, germanium powder 2.5%, Borax 2.6%, clay 60.4%.
The preparation method of above-mentioned functions clean porcelain alive comprises the steps:
S1. pre-treatment of raw material:
The most respectively albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C, and it is laggard to be cooled to room temperature
Row grinds, and crosses 120 mesh sieves.
The most respectively quartz, Maifanitum, spinelle, cordierite, Muyu-Stone are calcined at 870 DEG C 8.5
Hour, and it is cooled to grinding after room temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and be cooled to grinding after room temperature, cross 120 mesh sieves.
S2. preparation is expected
By weight percentage, quartz 14%, albite 7%, potassium feldspar 4%, tourmaline 4.5%, wheat are taken
Meal stone 5.5%, rare earth element 6.5%, Borax 2.5%, clay 48.4%, brium carbonate 2%, spinelle 2.8%,
Cordierite 2.8% as material raw material, knock down ball mill, feed stock gross weight 80~the water of 100%,
It is ground 24 hours, then stands 40 hours, remove water float thing, then use Magnet remove impurity, then
Except hydraulic pressure mud, pugging are 19~25% to pug wet weight percentage ratio, finish mix;
S3. prepared by glaze
By weight percentage, take nanometer silver 4.5%, tourmaline 4.5%, Maifanitum 7.5%, Muyu-Stone 6%,
Anion 12%, germanium powder 2.5%, Borax 2.6%, clay 60.4%, as glaze raw material, knock down ball mill,
Add 80~the water of 100% of enamel raw material gross weight, be ground 24 hours, then stand 40 hours, remove
Water float thing, then use Magnet remove impurity, then except hydraulic pressure mud, pugging to pug wet weight percentage ratio it is
19~25%, make glaze;
S4. the material prepared by S2 is shaped by traditional ceramics production method, is dried, then element at 900 DEG C
Burn 7 hours, and naturally cool to room temperature, obtain biscuiting product;
S5. pressing traditional ceramics production method, the biscuiting product that the glaze using S3 to prepare is prepared to S4 is executed
Glaze, is subsequently placed in kiln and burns till, and obtains the described clean porcelain of functional work.
The clean porcelain of functional work that above-mentioned preparation method prepares.
Above-mentioned functions clean porcelain application in preparing ceramic alive.
Above-mentioned functions clean porcelain application in preparing drinking water treatment equipment alive.
The core content of the present invention is in raw material to add germanium powder and anion, and by raw-material rationally
Proportioning so that germanium powder and anion can play the purification of maximum, and finished product can be container, it is also possible to be to carry
Article for purification function.
The product that the present invention makes has a following net work energy alive:
Checking through " Beijing public health drinking water institute ", bacteriostasis rate reaches 75.76%.
Checking through " Beijing public health drinking water institute ", free chlorine residual clearance reaches 24.3%.
Through " country is infrared and industrial electroheat product quality supervision and inspection " center " is checked, product infrared energy
Metric density is 9.22x102W/m2。
The invention has the beneficial effects as follows, clean ceramic material of living can play the effect purified water, and is applied to pottery
Can also purify water after goods can play the effect of container, thus reach the effect promoted health.
Detailed description of the invention
A kind of preparation method of the clean porcelain of functional work:
S1. pre-treatment of raw material:
The most respectively albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C, and it is laggard to be cooled to room temperature
Row grinds, and crosses 120 mesh sieves.
The most respectively quartz, Maifanitum, spinelle, cordierite, Muyu-Stone are calcined at 870 DEG C 8.5
Hour, and it is cooled to grinding after room temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and be cooled to grinding after room temperature, cross 120 mesh sieves.
S2. preparation is expected
By weight percentage, quartz 13%-15%, albite 6%-8%, potassium feldspar 3%-5%, wheat meal are taken
Stone 5%-6%, rare earth element 5.9%-7%, Borax 2%-3%, clay 47%-59%, brium carbonate 1.5%-2.5%,
Spinelle 2.1%-3.2%, cordierite 2.5%-3%, as material raw material, knock down ball mill, and feed stock is total
Weight 80~the water of 100%, be ground 24 hours, then stand 40 hours, remove water float thing,
Using Magnet remove impurity again, then removing hydraulic pressure mud, pugging is 19~25% to pug wet weight percentage ratio, system
Become material;
S3. prepared by glaze
By weight percentage, nanometer silver 4%-5%, tourmaline 4%-4.8%, Maifanitum 7%-8%, wooden fish are taken
Stone 5.5%-6.5%, anion 11%-13%, germanium powder 2%-3%, Borax 2.3%-3%, clay 56%-65% conduct
Glaze raw material, knocks down ball mill, adds 80~the water of 100% of enamel raw material gross weight, is ground 24 hours,
Stand 40 hours again, remove water float thing, then use Magnet remove impurity, then except hydraulic pressure mud, pugging are to mud
Material wet weight percentage ratio is 19~25%, makes glaze;
S4. the material prepared by S2 is shaped by traditional ceramics production method, is dried, then element at 900 DEG C
Burn 7 hours, and naturally cool to room temperature, obtain biscuiting product;
S5. pressing traditional ceramics production method, the biscuiting product that the glaze using S3 to prepare is prepared to S4 is executed
Glaze, is subsequently placed in kiln and burns till, and obtains the described clean porcelain of functional work.
Optimum implementation:
S1. pre-treatment of raw material:
The most respectively albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C, and it is laggard to be cooled to room temperature
Row grinds, and crosses 120 mesh sieves.
The most respectively quartz, Maifanitum, spinelle, cordierite, Muyu-Stone are calcined at 870 DEG C 8.5
Hour, and it is cooled to grinding after room temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and be cooled to grinding after room temperature, cross 120 mesh sieves.
S2. preparation is expected
By weight percentage, quartz 14%, albite 7%, potassium feldspar 4%, Maifanitum 5.5%, dilute is taken
Earth elements 6.5%, Borax 2.5%, clay 52.9%, brium carbonate 2%, spinelle 2.8%, cordierite 2.8%
As material raw material, knock down ball mill, feed stock gross weight 80~the water of 100%, be ground
24 hours, it is stirred simultaneously, then stands 40 hours, remove water float thing, then use Magnet remove impurity,
Then removing hydraulic pressure mud, pugging is 19~25% to pug wet weight percentage ratio, finish mix;
S3. prepared by glaze
By weight percentage, take nanometer silver 4.5%, tourmaline 4.4%, Maifanitum 7.5%, Muyu-Stone 6%,
Anion 12%, germanium powder 2.5%, Borax 2.6%, clay 60.5%, as glaze raw material, knock down ball mill,
Add 80~the water of 100% of enamel raw material gross weight, be ground 24 hours, then stand 40 hours, remove
Water float thing, then use Magnet remove impurity, then except hydraulic pressure mud, pugging to pug wet weight percentage ratio it is
19~25%, make glaze;
S4. the material prepared by S2 is shaped by traditional ceramics production method, is dried, then element at 900 DEG C
Burn 7 hours, and naturally cool to room temperature, obtain biscuiting product;
S5. pressing traditional ceramics production method, the biscuiting product that the glaze using S3 to prepare is prepared to S4 is executed
Glaze, is subsequently placed in kiln and burns till, and obtains the described clean porcelain of functional work.
The foregoing is only presently preferred embodiments of the present invention, be not used for limiting the practical range of the present invention;I.e.
The equivalents that all right under this invention are done, is scope of the presently claimed invention and is covered
Lid.
Claims (6)
1. the clean porcelain of functional work, it is characterised in that: the described clean porcelain of functional work is by following weight hundred
The component of proportion by subtraction is made: quartz 13%-15%, albite 6%-8%, potassium feldspar 3%-5%, tourmaline 4%-5%,
Maifanitum 5%-6%, rare earth element 5.9%-7%, Borax 2%-3%, clay 47%-59%, brium carbonate 1.5%-2.5%,
Spinelle 2.1%-3.2%, cordierite 2.5%-3%;The described clean glaze of functional work is by following percentage by weight
Component make: nanometer silver 4%-5%, tourmaline 4%-4.8%, Maifanitum 7%-8%, Muyu-Stone 5.5%-6.5%,
Anion 11%-13%, germanium powder 2%-3%, Borax 2.3%-3%, clay 52%-60%.
The clean porcelain of functional work the most according to claim 1, it is characterised in that: the described clean porcelain of functional work
Material is made up of following components in percentage by weight: quartz 14%, albite 7%, potassium feldspar 4%, electrically
Stone 4.5%, Maifanitum 5.5%, rare earth element 6.5%, Borax 2.5%, clay 48.4%, brium carbonate 2%,
Spinelle 2.8%, cordierite 2.8%;The described clean glaze of functional work is by following components in percentage by weight system
Become: nanometer silver 4.5%, tourmaline 4.5%, Maifanitum 7.5%, Muyu-Stone 6%, anion 12%, germanium powder
2.5%, Borax 2.6%, clay 60.4%.
The preparation method of the clean porcelain of functional work the most according to claim 1 and 2, it is characterised in that: bag
Include following steps:
S1. pre-treatment of raw material:
The most respectively albite, potassium feldspar are calcined 5.5 hours at 1020 DEG C, and grind after being cooled to room temperature
Mill, crosses 120 mesh sieves.
The most respectively quartz, Maifanitum, spinelle, cordierite, Muyu-Stone are calcined 8.5 hours at 870 DEG C,
And grind after being cooled to room temperature, cross 120 mesh sieves.
S13. clay is calcined 10 hours at 600 DEG C, and be cooled to grinding after room temperature, cross 120 mesh sieves.
S2. preparation is expected
By weight percentage, quartz 14%, albite 7%, potassium feldspar 4%, tourmaline 4.5%, Maifanitum are taken
5.5%, rare earth element 6.5%, Borax 2.5%, clay 48.4%, brium carbonate 2%, spinelle 2.8%, violet green grass or young crops
Stone 2.8%, as material raw material, is knocked down ball mill, the 80 of feed stock gross weight~the water of 100%, is carried out
Grind 24 hours, then stand 40 hours, remove water float thing, then use Magnet remove impurity, then except water
Pressure mud, pugging are 19~25% to pug wet weight percentage ratio, finish mix;
S3. prepared by glaze
By weight percentage, take nanometer silver 4.5%, tourmaline 4.5%, Maifanitum 7.5%, Muyu-Stone 6%, bear
Ion 12%, germanium powder 2.5%, Borax 2.6%, clay 60.4%, as glaze raw material, are knocked down ball mill, are added
80~the water of 100% of enamel raw material gross weight, is ground 24 hours, then stands 40 hours, removes water
Middle floating thing, then use Magnet remove impurity, then except hydraulic pressure mud, pugging to pug wet weight percentage ratio be 19~
25%, make glaze;
S4. the material prepared by S2 is shaped by traditional ceramics production method, is dried, then biscuiting 7 at 900 DEG C
Hour, and naturally cool to room temperature, obtain biscuiting product;
S5. pressing traditional ceramics production method, the biscuiting product that the glaze using S3 to prepare is prepared to S4 carries out glazing,
It is subsequently placed in kiln and burns till, obtain the described clean porcelain of functional work.
4. the clean porcelain of functional work that preparation method described in claim 3 prepares.
5. functional work clean porcelain application in preparing ceramic described in claim 4.
6. functional work clean porcelain application in preparing drinking water treatment equipment described in claim 4.
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CN106630629A (en) * | 2016-10-20 | 2017-05-10 | 淄博百康经贸有限公司 | Ceramic glaze with water activating function, preparation method thereof, ceramic prepared by ceramic glaze and preparation method of ceramic |
CN108640514A (en) * | 2018-06-25 | 2018-10-12 | 浙江东度文化创意有限公司 | Secret color glaze layer of celadon of sustained-release antibacterial and preparation method thereof |
CN108675766A (en) * | 2018-06-05 | 2018-10-19 | 浙江纳巍负离子科技有限公司 | A kind of graphene anion bone shellfish porcelain tea set and preparation method thereof |
CN108675767A (en) * | 2018-08-07 | 2018-10-19 | 张维亮 | A kind of health porcelain and preparation method thereof |
CN112110651A (en) * | 2020-09-14 | 2020-12-22 | 九牧厨卫股份有限公司 | Preparation method of ultra-smooth sanitary ceramic antibacterial glaze |
CN115433002A (en) * | 2022-08-23 | 2022-12-06 | 秦皇岛日福陶瓷有限公司 | Medical stone ceramic product and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106630629A (en) * | 2016-10-20 | 2017-05-10 | 淄博百康经贸有限公司 | Ceramic glaze with water activating function, preparation method thereof, ceramic prepared by ceramic glaze and preparation method of ceramic |
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CN108640514A (en) * | 2018-06-25 | 2018-10-12 | 浙江东度文化创意有限公司 | Secret color glaze layer of celadon of sustained-release antibacterial and preparation method thereof |
CN108675767A (en) * | 2018-08-07 | 2018-10-19 | 张维亮 | A kind of health porcelain and preparation method thereof |
CN112110651A (en) * | 2020-09-14 | 2020-12-22 | 九牧厨卫股份有限公司 | Preparation method of ultra-smooth sanitary ceramic antibacterial glaze |
CN115433002A (en) * | 2022-08-23 | 2022-12-06 | 秦皇岛日福陶瓷有限公司 | Medical stone ceramic product and preparation method thereof |
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