CN103936405A - Ceramic tile capable of emitting far infrared and preparation method thereof - Google Patents
Ceramic tile capable of emitting far infrared and preparation method thereof Download PDFInfo
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- CN103936405A CN103936405A CN201410137662.3A CN201410137662A CN103936405A CN 103936405 A CN103936405 A CN 103936405A CN 201410137662 A CN201410137662 A CN 201410137662A CN 103936405 A CN103936405 A CN 103936405A
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Abstract
The invention discloses a ceramic tile capable of emitting far infrared and a preparation method thereof. The ceramic tile is prepared from the following raw materials in parts by weight: 32-44 parts of siltstone, 14-22 parts of olivine, 12-18 parts of fly ash, 10-15 parts of apatite, 5-10 parts of aluminum dross, 6-12 parts of boric sludge, 24-36 parts of yellow sand, 10-15 parts of dravite, 7-14 parts of cordierite, 5-10 parts of germanite, 15-20 parts of hexacyclic stone, 4-8 parts of nano zirconium carbide and 18-26 parts of modified clay. Under the coaction of the dravite, the cordierite, the germanite, the hexacyclic stone, the nano zirconium carbide and the like in the ceramic tile, the effects of emitting the far infrared beneficial to the human body, exciting the vitality of human tissue cells, improving the microcirculation, reducing the acidity of blood, improving the oxygen supply of tissues, promoting the metabolism, accelerating the decomposition of lactic acid, eliminating the fatigue and enhancing the immunity can be achieved, so that the ceramic tile achieves a health-care effect on the human body, fulfills the purpose of preventing and treating diseases and has a huge market prospect.
Description
Technical field
The present invention relates to a kind of ceramic tile that can emitting far infrared ray and preparation method thereof, belong to building ceramics field.
Background technology
ceramic tile is by clay, quartz sand and other inorganic non-metallic raw materials, through the tabular or block ceramic of the explained hereafter such as batching, ball milling, powder process, moulding, sintering, is widely used in decorating and metope and the ground of protecting buildings, structures.Along with developing rapidly of real estate, the production and consumption of ceramic tile is all got a larger development, yet ceramic tile is in the market only as decorating, there is no nourishing function, if can develop, be a kind ofly applied in family or the health tile of office space, for improving people's body constitution and environment purification, huge social benefit and economic interests will be there are.
Summary of the invention
The object of the present invention is to provide a kind of ceramic tile that can emitting far infrared ray and preparation method thereof, make the health-care effect that ceramic tile tool is higher.
For achieving the above object, the technical solution used in the present invention is as follows:
Ceramic tile that can emitting far infrared ray, is made by the raw material of following weight part: siltstone 32-44, peridotites 14-22, flyash 12-18, phosphatic rock 10-15, aluminium slag 5-10, boron mud 6-12, yellow ground 24-36, dravite 10-15, trichroite 7-14, germanite 5-10, six ring stone 15-20, nano-zirconium carbide 4-8, modified clay 18-26;
The preparation method of described modified clay is as follows: a, 4-8:3-6:2-3 takes bauxitic clay, kaolin, attapulgite in mass ratio, mix, put into the hydrochloric acid soln that concentration is 15-20%, heating in water bath is to 60-70 ℃, insulation 0.5-1h, filter, be washed with distilled water to neutrality, dry, 460-520 ℃ of calcining 1-2h, pulverize, cross 150-250 mesh sieve, stand-by; B, take a certain amount of chitosan and be added in the acetum that volumetric concentration is 1-2%, stirring and dissolving, being mixed with concentration expressed in percentage by weight is the chitosan gum liquid solution of 10-15%, then the poly-Union carbide A-162 that adds the nanometer silver of solution weight 3-4%, the nano zine oxide of the gac of 2-3%, 1-2% and 2-3%, stir 20-30min, stand-by; The chitosan gum liquid solution that c, the clay that step a is processed are processed with step b mixes by weight the ratio of 2-3:1, stirs into pasty state, dries, and pulverizes, and crosses 200-300 mesh sieve.
The present invention can emitting far infrared ray the preparation method of ceramic tile, comprise the following steps:
(1) getting peridotites, flyash, phosphatic rock, aluminium slag, boron mud, yellow ground mixes, pulverize, cross 200-250 mesh sieve, then the spent pulping liquor that adds powder weight 15-20%, stirs, and then makes the particle that particle diameter is 2-3mm, dry, 1180-1240 ℃ of roasting 10-15min, naturally cools to normal temperature, stand-by;
(2) get siltstone, dravite, trichroite, germanite, six ring stones mix, pulverize, cross the particle mixing 4-6min making with step (1) after 100-150 mesh sieve, then add remaining raw material mixing 2-4min, then the water glass mixing 20-25min that the solid content that adds compound weight 3-4% is 30%, standing 8-12h;
(3) compound step (2) being made is delivered to forming machine compression moulding under 70-80MPa, and then the adobe suppressing being delivered to and being dried to water content in dry kiln is 1.5-2.5%;
(4) dry adobe is warming up to 1310-1360 ℃ with the speed of 15-20 ℃/min, insulation 2-3h, then with the speed of 5-10 ℃/min, be cooled to 840-880 ℃, insulation 1-2h, speed with 4-8 ℃/min is cooled to 470-510 ℃ again, insulation 0.5-1h, then the speed with 8-12 ℃/min is warming up to 1140-1180 ℃, insulation 1.5-2.5h, speed with 5-10 ℃/min is cooled to 680-720 ℃ again, insulation 1-1.5h, naturally cools to normal temperature, through edging, packing, gets product.
Above-mentioned modified clay adopts the collaborative Chitosan-coated clay of the materials such as nanometer silver, gac, nano zine oxide and poly-Union carbide A-162; not only there is good anti-microbial activity; the growth and breeding that can suppress some fungies, bacterium and virus; the indoor harmful gas such as all right adsorption-decomposition function formaldehyde, benzene, ammonia, sulfurous gas;, lavatory smelly, rubbish smelly, animal smelly etc. smelly to cigarette plays deodourizing effect; to protect mankind is healthy; can improve the performances such as the uvioresistant of ceramic tile, ageing-resistant, water tolerance simultaneously, extend the use work-ing life of ceramic tile.
Beneficial effect of the present invention:
The composition actings in conjunction such as the dravite in ceramic tile of the present invention, trichroite, germanite, six ring stones, nano-zirconium carbide, can launch the far infrared rays useful to human body, the histiocytic vigor of exciting human, improves microcirculation, reduce blood acid, improve and organize oxygen supply, enhance metabolism, accelerate lactic acid and decompose, Ginseng Extract, strengthening immunity, thus reach body-care effect and the object of preventing and curing diseases, there are huge market outlook.
Embodiment
Ceramic tile that can emitting far infrared ray, is made by the raw material of following weight (kg): siltstone 38, peridotites 20, flyash 16, phosphatic rock 12, aluminium slag 8, boron mud 9, yellow ground 32, dravite 12, trichroite 11, germanite 8, six ring stones 16, nano-zirconium carbide 6, modified clay 22;
The preparation method of described modified clay is as follows: a, 8:6:3 takes bauxitic clay, kaolin, attapulgite in mass ratio, mix, put into concentration and be 20% hydrochloric acid soln, heating in water bath to 70 ℃, insulation 0.5h, filter, be washed with distilled water to neutrality, dry, 520 ℃ of calcining 1h, pulverize, cross 200 mesh sieves, stand-by; B, taking a certain amount of chitosan, to be added to volumetric concentration be in 2% acetum, stirring and dissolving, be mixed with concentration expressed in percentage by weight and be 15% chitosan gum liquid solution, then the nanometer silver, 2% gac, 1.5% nano zine oxide and 2% the poly-Union carbide A-162 that add solution weight 3%, stir 25min, stand-by; The chitosan gum liquid solution that c, the clay that step a is processed are processed with step b mixes by weight the ratio of 3:1, stirs into pasty state, dries, and pulverizes, and crosses 250 mesh sieves.
The preparation method of ceramic tile that can emitting far infrared ray, comprises the following steps:
(1) get peridotites, flyash, phosphatic rock, aluminium slag, boron mud, yellow ground and mix, pulverize, cross 200 mesh sieves, then add the spent pulping liquor of powder weight 15%, stir, then make the particle that particle diameter is 2mm, dry, 1220 ℃ of roasting 12min, naturally cool to normal temperature, stand-by;
(2) get siltstone, dravite, trichroite, germanite, six ring stones mix, pulverize, cross the particle mixing 5min making with step (1) after 150 mesh sieves, then add remaining raw material mixing 3min, then the water glass mixing 20min that the solid content that adds compound weight 3% is 30%, standing 10h;
(3) compound step (2) being made is delivered to forming machine compression moulding under 75MPa, and then the adobe suppressing being delivered to and being dried to water content in dry kiln is 2%;
(4) dry adobe is warming up to 1340 ℃ with the speed of 20 ℃/min, insulation 2h, then with the speed of 10 ℃/min, be cooled to 860 ℃, insulation 1h, speed with 6 ℃/min is cooled to 490 ℃ again, insulation 0.5h, then the speed with 10 ℃/min is warming up to 1160 ℃, insulation 2h, speed with 8 ℃/min is cooled to 700 ℃ again, insulation 1h, naturally cools to normal temperature, through edging, packing, gets product.
The ceramic tile of producing, its water-intake rate is 6.6%, folding strength is 18.4MPa.
The composition actings in conjunction such as the dravite in this ceramic tile, trichroite, germanite, six ring stones, nano-zirconium carbide, can launch the far infrared rays useful to human body, the histiocytic vigor of exciting human, improves microcirculation, reduces blood acid, improve and organize oxygen supply, enhance metabolism, accelerate lactic acid and decompose, Ginseng Extract, strengthening immunity, thus reach body-care effect and the object of preventing and curing diseases.
Claims (2)
- One kind can emitting far infrared ray ceramic tile, it is characterized in that, by the raw material of following weight part, made: siltstone 32-44, peridotites 14-22, flyash 12-18, phosphatic rock 10-15, aluminium slag 5-10, boron mud 6-12, yellow ground 24-36, dravite 10-15, trichroite 7-14, germanite 5-10, six ring stone 15-20, nano-zirconium carbide 4-8, modified clay 18-26;The preparation method of described modified clay is as follows: a, 4-8:3-6:2-3 takes bauxitic clay, kaolin, attapulgite in mass ratio, mix, put into the hydrochloric acid soln that concentration is 15-20%, heating in water bath is to 60-70 ℃, insulation 0.5-1h, filter, be washed with distilled water to neutrality, dry, 460-520 ℃ of calcining 1-2h, pulverize, cross 150-250 mesh sieve, stand-by; B, take a certain amount of chitosan and be added in the acetum that volumetric concentration is 1-2%, stirring and dissolving, being mixed with concentration expressed in percentage by weight is the chitosan gum liquid solution of 10-15%, then the poly-Union carbide A-162 that adds the nanometer silver of solution weight 3-4%, the nano zine oxide of the gac of 2-3%, 1-2% and 2-3%, stir 20-30min, stand-by; The chitosan gum liquid solution that c, the clay that step a is processed are processed with step b mixes by weight the ratio of 2-3:1, stirs into pasty state, dries, and pulverizes, and crosses 200-300 mesh sieve.
- 2. the preparation method of ceramic tile that can emitting far infrared ray as claimed in claim 1, is characterized in that comprising the following steps:(1) getting peridotites, flyash, phosphatic rock, aluminium slag, boron mud, yellow ground mixes, pulverize, cross 200-250 mesh sieve, then the spent pulping liquor that adds powder weight 15-20%, stirs, and then makes the particle that particle diameter is 2-3mm, dry, 1180-1240 ℃ of roasting 10-15min, naturally cools to normal temperature, stand-by;(2) get siltstone, dravite, trichroite, germanite, six ring stones mix, pulverize, cross the particle mixing 4-6min making with step (1) after 100-150 mesh sieve, then add remaining raw material mixing 2-4min, then the water glass mixing 20-25min that the solid content that adds compound weight 3-4% is 30%, standing 8-12h;(3) compound step (2) being made is delivered to forming machine compression moulding under 70-80MPa, and then the adobe suppressing being delivered to and being dried to water content in dry kiln is 1.5-2.5%;(4) dry adobe is warming up to 1310-1360 ℃ with the speed of 15-20 ℃/min, insulation 2-3h, then with the speed of 5-10 ℃/min, be cooled to 840-880 ℃, insulation 1-2h, speed with 4-8 ℃/min is cooled to 470-510 ℃ again, insulation 0.5-1h, then the speed with 8-12 ℃/min is warming up to 1140-1180 ℃, insulation 1.5-2.5h, speed with 5-10 ℃/min is cooled to 680-720 ℃ again, insulation 1-1.5h, naturally cools to normal temperature, through edging, packing, gets product.
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| CN201410137662.3A CN103936405B (en) | 2014-04-08 | 2014-04-08 | Ceramic tile capable of emitting far infrared and preparation method thereof |
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| CN201410137662.3A CN103936405B (en) | 2014-04-08 | 2014-04-08 | Ceramic tile capable of emitting far infrared and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496418A (en) * | 2014-12-24 | 2015-04-08 | 唐山立雄峰汇材料科技有限公司 | Negative oxygen ion far-infrared sleeping pillow filled ceramic ball |
| CN106082955A (en) * | 2016-06-12 | 2016-11-09 | 安徽省亚欧陶瓷有限责任公司 | A kind of ceramic tile producing ultrasonic pulse and preparation method thereof |
| CN106083015A (en) * | 2016-06-12 | 2016-11-09 | 安徽省亚欧陶瓷有限责任公司 | A kind of ceramic tile producing magnetic field and preparation method thereof |
| CN110041105A (en) * | 2019-05-23 | 2019-07-23 | 佛山市东鹏陶瓷有限公司 | High-concentration anion glaze layer structure, ceramic tile and the ceramic tile preparation method of low-activity |
| CN114276119A (en) * | 2022-01-25 | 2022-04-05 | 深圳永润瓷商贸有限公司 | Health-preserving mineral porcelain |
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| JP2004168633A (en) * | 2002-11-20 | 2004-06-17 | Hideo Mizukami | Healing clay, china clay and sand |
| JP2005325010A (en) * | 2004-05-13 | 2005-11-24 | Sumiko Murakami | Ceramic for use in tempura |
| CN101805191A (en) * | 2010-02-24 | 2010-08-18 | 李永军 | Spectrum functional ceramic powder capable of accelerating heat exchange and preparation method thereof |
| CN102030503A (en) * | 2009-09-25 | 2011-04-27 | 上海金樱环保科技有限公司 | Anion multifunctional culture stone material and preparation method thereof |
| CN103232230A (en) * | 2013-04-23 | 2013-08-07 | 陆连锁 | Low-expansion barbecue ceramic having antibacterial function and grill made of same |
-
2014
- 2014-04-08 CN CN201410137662.3A patent/CN103936405B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004168633A (en) * | 2002-11-20 | 2004-06-17 | Hideo Mizukami | Healing clay, china clay and sand |
| JP2005325010A (en) * | 2004-05-13 | 2005-11-24 | Sumiko Murakami | Ceramic for use in tempura |
| CN102030503A (en) * | 2009-09-25 | 2011-04-27 | 上海金樱环保科技有限公司 | Anion multifunctional culture stone material and preparation method thereof |
| CN101805191A (en) * | 2010-02-24 | 2010-08-18 | 李永军 | Spectrum functional ceramic powder capable of accelerating heat exchange and preparation method thereof |
| CN103232230A (en) * | 2013-04-23 | 2013-08-07 | 陆连锁 | Low-expansion barbecue ceramic having antibacterial function and grill made of same |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496418A (en) * | 2014-12-24 | 2015-04-08 | 唐山立雄峰汇材料科技有限公司 | Negative oxygen ion far-infrared sleeping pillow filled ceramic ball |
| CN106082955A (en) * | 2016-06-12 | 2016-11-09 | 安徽省亚欧陶瓷有限责任公司 | A kind of ceramic tile producing ultrasonic pulse and preparation method thereof |
| CN106083015A (en) * | 2016-06-12 | 2016-11-09 | 安徽省亚欧陶瓷有限责任公司 | A kind of ceramic tile producing magnetic field and preparation method thereof |
| CN110041105A (en) * | 2019-05-23 | 2019-07-23 | 佛山市东鹏陶瓷有限公司 | High-concentration anion glaze layer structure, ceramic tile and the ceramic tile preparation method of low-activity |
| CN114276119A (en) * | 2022-01-25 | 2022-04-05 | 深圳永润瓷商贸有限公司 | Health-preserving mineral porcelain |
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| CN103936405B (en) | 2015-04-01 |
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