CN107129151A - Anion function ceramic tile glaze and preparation method thereof - Google Patents
Anion function ceramic tile glaze and preparation method thereof Download PDFInfo
- Publication number
- CN107129151A CN107129151A CN201710545269.1A CN201710545269A CN107129151A CN 107129151 A CN107129151 A CN 107129151A CN 201710545269 A CN201710545269 A CN 201710545269A CN 107129151 A CN107129151 A CN 107129151A
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- China
- Prior art keywords
- component
- function
- base material
- ceramic tile
- anion
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
Abstract
The present invention relates to a kind of anion function ceramic tile glaze and preparation method thereof, glaze is made up of base material A component and function B component, base material A component is made up of feldspar, kaolin, zinc oxide, barium carbonate, schmigel and quartz, or be made up of feldspar, kaolin, zinc oxide, calcite, zircon and talcum powder, function B component is made up of six ring stone flours, germanite powder, titanium dioxide, rare earth component and silicone emulsion, wherein, base material A component accounts for 93~99%, and function B component accounts for 7~1%；The anion function ceramic tile glaze that the present invention is provided can long-acting negative ion release, purify air, remove removing and harmful gas, improve body immunity；Preparation method production of the present invention is wide in variety, and manufacturing cost is low, simple and easy to do, and the ceramic glaze material quality of production produced is stable, and anion burst size can be controllable according to demand, and indoor purifying effect is good, safety and environmental protection.
Description
Technical field
The present invention relates to architectural pottery technical field, and in particular to a kind of anion function ceramic tile glaze and its preparation side
Method.
Background technology
With the improvement of living standards, requirement of the people to ornament materials is also from single decoration functions towards multi-functional side
To development, such as air-cleaning function, anti-haze, except formaldehyde, phenalgin, TVOC, eliminate electromagnetic radiation and release has to health
Negative aeroion far infrared of benefit etc..Although above-mentioned functions can be met in the ornament materials of various species to be had a lot, such as diatom
Mud, activated carbon, photocatalyst etc., but serious limitation is there is again.Diatom ooze, activated carbon class sorbing material, although right
Harmful substance has certain adsorptivity, but application time is shorter, and its function will lose because adsorption saturation is unable to desorption and regeneration
Function, or even will also become pollution source.Although luminous energy matchmaker's class material can be produced under the irradiation of specific ultraviolet (UV) A light sources
Luminous energy matchmaker's effect, discharges hydroxyl group anion, has strong reduction-oxidation to act on to poisonous organic substance, but general occupies indoor glass
Curtain wall there is no the condition for producing photocatalyst effect to the obstruction rate nearly more than 90% of ultraviolet.Wherein, anion occurs
Material is due to can have under conditions of no light day and night, constantly discharging negative aeroion, and can have good within 24 hours
Air-filtering ability, thus with wide market application foreground.Many wall materials have negative ion generating function in ornament materials, so
And although these wall materials can discharge anion, anion is produced, the time of release is very of short duration.Anion is warm with rising simultaneously
Air-flow is flowed up, typically within from wall 500mm, is not spread substantially to indoor intermediate zone space, and has the pollution of pollution
Source furniture is basic most of not close to wall, even if therefore wall material has the function of release anion, do not have preferable effect yet.
If but floor tile discharges anion, and the whole interior space will be spread in ascending air, purification degradative reduction is played
The effect of organic toxic substance, therefore feature anion floor tile clean-up effect unique in existing ornament materials is existing wall
Material is incomparable.
Traditional existing anion patent document is many most early in 2004, and application quantity in recent years is seldom, market
On it is also many take conceptual publicity as many, few preferable products appearance.Or anion burst size is low, and what does not have substantially
Effect, or the exceeded unsuitable health of radioactivity；Or decay too fast；Or the poisonous and harmful substance such as heavy metal it is exceeded the problems such as, it is impossible to it is full
The sufficient market demand.
The content of the invention
It is an object of the invention to provide a kind of anion function ceramic tile glaze and preparation method thereof, the ceramic glaze produced
The material quality of production is stable, and anion burst size can be controllable according to demand, and indoor purifying effect is good, and manufacturing cost is low, production
It is wide in variety, safety and environmental protection.
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein, function B
Component is：Six ring stone flours, germanite powder, titanium dioxide, rare earth component and silicone emulsion.
Preferably, foregoing rare earth component includes praseodymium oxide and indium sesquioxide, and praseodymium oxide is titanium dioxide praseodymium or three oxidations two
Praseodymium.
Preferably, the weight proportion of each component is in foregoing function B component：Six ring stone flours：30~35%, germanite powder 25~
35%, titanium dioxide 25~30%, praseodymium oxide 3~10%, indium sesquioxide 2~5%, silicone emulsion 0.2~0.5%.
Preferably, foregoing base material A component and the weight composition of function B component are：Base material A component 93~99%, function B groups
Part 7~1%.
Preferably, foregoing base material A component is feldspar, kaolin, zinc oxide, barium carbonate, schmigel and quartz.
Preferably, each component weight proportion is in foregoing base material A component：Feldspar 40~50%, zinc oxide 1~5%, carbonic acid
Barium 1~5%, schmigel 5~9%, kaolin 20~30%, quartz 10~15%.
Preferably, foregoing base material A component is feldspar, kaolin, zinc oxide, calcite, zircon and talcum powder.
Preferably, each component weight proportion is in foregoing base material A component：Feldspar 45~50%, kaolin 5~10%, side
Solve stone 10~15%, zircon 20~25%, zinc oxide 1~2%, talcum powder 3~4%.
The preferred potassium feldspar of feldspar in base material A component, the preferred white fused alumina of corundum.
Preferably, the feeding sequence of the material mixing of foregoing function B component：Six ring stone flours and the mixing of germanite powder are first put into,
Titanium dioxide is put into again, rare earth component is then added successively, and silicone emulsion is added when batch mixing is scattered.Rare earth component addition sequence
For：The high person of weight proportion first adds.
Preferably, in foregoing base material A component the titanium dioxide of each batch ingredients and function B component particle diameter for 50nm~
300nm。
Beneficial effects of the present invention are as follows：
(1) the ceramic tile glaze produced of the present invention can long-acting negative ion release, decompose the PM2.5 removed in air, first
The pernicious gases such as aldehyde, benzene, purification air, improve body immunity, and playing improves sleep, purification blood, protects cardiovascular and cerebrovascular
Beneficial effect.
(2) present invention uses natural mineral matter and anion-generating material, without adding the poisonous and harmful substances such as heavy metal,
Safety and environmental protection, is preferable marketing product.
(3) preparation method that the present invention is provided is simple to operation, and the manufacturing cost of glaze is low, and production kind can be according to market
Demand regulation proportioning, kind is varied.
Embodiment
The present invention is described further with reference to embodiments.
Embodiment 1
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein
Base material A component is formulated：
Potassium feldspar 50%, kaolin 8%, calcite 12%, zircon 23%, zinc oxide 1.6%, talcum powder 5.4%.
Function B component is formulated：
Six ring stone flours 35%, germanite 30%, titanium dioxide 25%, titanium dioxide praseodymium 7%, indium sesquioxide 2.5% emulsifies silicon
Oil 0.5%.
Take base material A component 98%, function B component 2%.
Add suitable quantity of water by above-mentioned formula, after being mixed on dispersion machine, after being ground on grinder, into production line,
Coating weight 90g/ pieces (600*600), 160g/ pieces (800*800), producible kind is Antique Imitation Tiles, imitation wood bar brick.
Product properties index is as follows：
1st, anion burst size >=3000/cm3*s
2nd, radiation value：Interior photograph index≤0.2
Outer photograph index≤0.5
3rd, formaldehyde clearance >=60%.
Embodiment 2
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein
Base material A component is formulated：
Potassium feldspar 50%, kaolin 8%, calcite 12%, zircon 23%, zinc oxide 1.6%, talcum powder 5.4%.
Function B component is formulated：
Six ring stone flours 35%, germanite 30%, titanium dioxide 25%, titanium dioxide praseodymium 7%, indium sesquioxide 2.5% emulsifies silicon
Oil 0.5%.
Take base material A component 95%, function B component 5%.
Add suitable quantity of water by above-mentioned formula, after being mixed on dispersion machine, after being ground on grinder, into production line,
Coating weight 90g/ pieces (600*600), 160g/ pieces (800*800), producible kind is Antique Imitation Tiles, imitation wood bar brick.
The following performance indications of product：
1st, anion burst size >=8000/cm3*s
2nd, radiation value：Interior photograph index≤0.3
Outer photograph index≤0.7
3rd, formaldehyde clearance >=75%.
Embodiment 3
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein
Base material A component is formulated：
Potassium feldspar 50%, kaolin 8%, calcite 12%, zircon 23%, zinc oxide 1.6%, talcum powder 5.4%.
Function B component is formulated：
Six ring stone flours 35%, germanite 30%, titanium dioxide 25%, titanium dioxide praseodymium 7%, indium sesquioxide 2.5% emulsifies silicon
Oil 0.5%.
Take base material A component 93%, function B component 7%.
Add suitable quantity of water by above-mentioned formula, after being mixed on dispersion machine, after being ground on grinder, into production line,
Coating weight 90g/ pieces (600*600), 160g/ pieces (800*800), producible kind is Antique Imitation Tiles, imitation wood bar brick.
The following performance indications of product：
1st, anion burst size >=1200/cm3*s
2nd, radiation value：Interior photograph index≤0.35
Outer photograph index≤1.0
3rd, formaldehyde clearance >=93%.
Embodiment 4
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein
Base material A component is formulated：
Potassium feldspar 45%, zinc oxide 4%, barium carbonate 5%, kaolin 25%, quartz 13%, white alundum powder 8%.
Function B component is formulated：
Six ring stone flours 33%, germanite powder 30%, titanium dioxide 25%, praseodymium sesquioxide 8%, indium sesquioxide 3.6%, oxygen
SiClx oil 0.4%.
Base material A component 97%, function B component 3%.
Add suitable quantity of water by above-mentioned formula, after being mixed on dispersion machine, after being ground on grinder, into production line,
Coating weight 800g/ pieces (800*800), can produce Buddha's warrior attendant glazed tile.
The following performance indications of product：
1st, anion burst size >=3500/cm3*s
2nd, radiation value：Interior photograph index≤0.3
Outer photograph index≤0.8
3rd, formaldehyde clearance >=62%.
Embodiment 5
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein
Base material A component is formulated：
Potassium feldspar 45%, zinc oxide 4%, barium carbonate 5%, kaolin 25%, quartz 13%, white alundum powder 8%.
Function B component is formulated：
Six ring stone flours 33%, germanite powder 30%, titanium dioxide 25%, praseodymium sesquioxide 8%, indium sesquioxide 3.6%, oxygen
SiClx oil 0.4%.
Base material A component 95%, function B component 5%.
Add suitable quantity of water by above-mentioned formula, after being mixed on dispersion machine, after being ground on grinder, into production line,
Coating weight 800g/ pieces (800*800), can produce Buddha's warrior attendant glazed tile.
The following performance indications of product：
1st, anion burst size >=7800/cm3*s
2nd, radiation value：Interior photograph index≤0.6
Outer photograph index≤1.0
3rd, formaldehyde clearance >=75%
Embodiment 6
Anion function ceramic tile glaze of the present invention, is made up of base material A component and function B component, wherein
Base material A component is formulated：
Potassium feldspar 45%, zinc oxide 4%, barium carbonate 5%, kaolin 25%, quartz 13%, white alundum powder 8%.
Function B component is formulated：
Six ring stone flours 33%, germanite powder 30%, titanium dioxide 25%, praseodymium sesquioxide 8%, indium sesquioxide 3.6%, oxygen
SiClx oil 0.4%.
Base material A 93%, function B7%.
Add suitable quantity of water by above-mentioned formula, after being mixed on dispersion machine, after being ground on grinder, into production line,
Coating weight 800g/ pieces (800*800), can produce Buddha's warrior attendant glazed tile.
The following performance indications of product：
1st, anion burst size >=13000/cm3*s
2nd, radiation value：Interior photograph index≤0.9
Outer photograph index≤1.2
3rd, formaldehyde clearance >=94%.
The glaze of the anion ecological function ceramic tile of the present invention when in use, by base material A component and function B component according to needing
Want after ratio mixing, glaze slurry is made in ball mill wet ball grinding after sieving, base brick is put into glazing machine, vaporific spraying shape
Into glaze, kiln calcining is then placed in, 1150-1250 degrees Celsius of calcining heat, firing period is 50-55 minutes, is burnt till rear cold
But deburring etc., remaining technique, parameter etc. are identical with conventional traditional glaze material manufacturing technique.
Claims (10)
1. a kind of anion function ceramic tile glaze, it is characterised in that be made up of base material A component and function B component, wherein, function B
Component is：Six ring stone flours, germanite powder, titanium dioxide, rare earth component and silicone emulsion.
2. anion function ceramic tile glaze as claimed in claim 1, it is characterised in that the rare earth component include praseodymium oxide and
Indium sesquioxide.
3. anion function ceramic tile glaze as claimed in claim 2, it is characterised in that each component in the function B component
Weight proportion is：Six ring stone flours：30~35%, germanite powder 25~35%, titanium dioxide 25~30%, praseodymium oxide 3~10%, three
Aoxidize two indiums 2~5%, silicone emulsion 0.2~0.5%.
4. anion function ceramic tile glaze as claimed in claim 1, it is characterised in that the base material A component and function B component
Weight composition be：Base material A component 93~99%, function B component 7~1%.
5. anion function ceramic tile glaze as claimed in claim 1, it is characterised in that the base material A component is feldspar, kaolinite
Soil, zinc oxide, barium carbonate, schmigel and quartz.
6. anion function ceramic tile glaze as claimed in claim 5, it is characterised in that each component weight in the base material A component
Measuring proportioning is：Feldspar 40~50%, zinc oxide 1~5%, barium carbonate 1~5%, schmigel 5~9%, kaolin 20~30%,
Quartz 10~15%.
7. anion function ceramic tile glaze as claimed in claim 1, it is characterised in that the base material A component is feldspar, kaolinite
Soil, zinc oxide, calcite, zircon and talcum powder.
8. anion function ceramic tile glaze as claimed in claim 7, it is characterised in that each component weight in the base material A component
Measuring proportioning is：Feldspar 45~50%, kaolin 5~10%, calcite 10~15%, zircon 20~25%, zinc oxide 1~
2%, talcum powder 3~4%.
9. the preparation method of anion function ceramic tile glaze as claimed in claim 1, it is characterised in that the function B component
Material mixing feeding sequence：Six ring stone flours and the mixing of germanite powder are first put into, then put into titanium dioxide, then add dilute successively
Local soil type part, silicone emulsion is added when batch mixing is scattered.
10. the preparation method of anion function ceramic tile glaze as claimed in claim 9, it is characterised in that the base material A component
In each batch ingredients and function B component titanium dioxide particle diameter be 50nm~300nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710545269.1A CN107129151A (en) | 2017-07-06 | 2017-07-06 | Anion function ceramic tile glaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710545269.1A CN107129151A (en) | 2017-07-06 | 2017-07-06 | Anion function ceramic tile glaze and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107129151A true CN107129151A (en) | 2017-09-05 |
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Family Applications (1)
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| CN201710545269.1A Pending CN107129151A (en) | 2017-07-06 | 2017-07-06 | Anion function ceramic tile glaze and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107686246A (en) * | 2017-09-22 | 2018-02-13 | 江苏昶浩建材有限公司 | A kind of preparation method of anion function ceramic tile glaze |
| CN107686244A (en) * | 2017-09-22 | 2018-02-13 | 江苏昶浩建材有限公司 | A kind of anion function ceramic tile glaze |
| CN108298820A (en) * | 2018-05-11 | 2018-07-20 | 唐山兴象达艺文化发展有限公司 | A kind of production method of anion fine pottery color glaze |
| CN108821585A (en) * | 2018-09-12 | 2018-11-16 | 德化恒瀚艺品有限公司 | A kind of ceramics modified verdelite anion glaze and its preparation method and application |
| CN109399932A (en) * | 2018-12-25 | 2019-03-01 | 佛山科学技术学院 | A kind of ceramic glaze and ceramics |
| CN115448597A (en) * | 2022-08-31 | 2022-12-09 | 湖南省醴陵市浦口电瓷有限公司 | Bonding glaze and preparation process and application thereof |
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| CN103864464A (en) * | 2014-03-08 | 2014-06-18 | 朱仙炳 | Ceramic basic glaze with health maintenance function and environment-friendly function and use method thereof |
| CN105461228A (en) * | 2015-08-06 | 2016-04-06 | 惠州市惠阳皇磁陶瓷有限公司 | Thin plate glaze capable of continuously generating negative ions, and thin plate made therefrom |
| CN106430972A (en) * | 2016-09-30 | 2017-02-22 | 董爱凤 | Ceramic glaze for ceramic vessel |
| CN106739737A (en) * | 2016-12-15 | 2017-05-31 | 淄博统领陶瓷有限公司 | Plastic relief metal spraying ceramic tile and production technology |
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Patent Citations (4)
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| CN103864464A (en) * | 2014-03-08 | 2014-06-18 | 朱仙炳 | Ceramic basic glaze with health maintenance function and environment-friendly function and use method thereof |
| CN105461228A (en) * | 2015-08-06 | 2016-04-06 | 惠州市惠阳皇磁陶瓷有限公司 | Thin plate glaze capable of continuously generating negative ions, and thin plate made therefrom |
| CN106430972A (en) * | 2016-09-30 | 2017-02-22 | 董爱凤 | Ceramic glaze for ceramic vessel |
| CN106739737A (en) * | 2016-12-15 | 2017-05-31 | 淄博统领陶瓷有限公司 | Plastic relief metal spraying ceramic tile and production technology |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107686246A (en) * | 2017-09-22 | 2018-02-13 | 江苏昶浩建材有限公司 | A kind of preparation method of anion function ceramic tile glaze |
| CN107686244A (en) * | 2017-09-22 | 2018-02-13 | 江苏昶浩建材有限公司 | A kind of anion function ceramic tile glaze |
| CN108298820A (en) * | 2018-05-11 | 2018-07-20 | 唐山兴象达艺文化发展有限公司 | A kind of production method of anion fine pottery color glaze |
| CN108821585A (en) * | 2018-09-12 | 2018-11-16 | 德化恒瀚艺品有限公司 | A kind of ceramics modified verdelite anion glaze and its preparation method and application |
| CN109399932A (en) * | 2018-12-25 | 2019-03-01 | 佛山科学技术学院 | A kind of ceramic glaze and ceramics |
| CN115448597A (en) * | 2022-08-31 | 2022-12-09 | 湖南省醴陵市浦口电瓷有限公司 | Bonding glaze and preparation process and application thereof |
| CN115448597B (en) * | 2022-08-31 | 2023-06-30 | 湖南省醴陵市浦口电瓷有限公司 | Bonding glaze and preparation process and application thereof |
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Application publication date: 20170905 |