CN109485257A - A kind of ceramic basic glaze materials and its application method with health care and environment-protection functional - Google Patents

A kind of ceramic basic glaze materials and its application method with health care and environment-protection functional Download PDF

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Publication number
CN109485257A
CN109485257A CN201710808569.4A CN201710808569A CN109485257A CN 109485257 A CN109485257 A CN 109485257A CN 201710808569 A CN201710808569 A CN 201710808569A CN 109485257 A CN109485257 A CN 109485257A
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glaze
ceramic
materials according
ceramic basic
glaze materials
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吴鹃
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention relates to a kind of ceramic basic glaze materials and its application method with health care and environment-protection functional, using natural mineral raw and industrial pure material, its weight percent composition are as follows: feldspar 30~55%, quartzy 15~30%, calcite 10~25%, talcum 1~8%, barium carbonate 3~8%, strontium carbonate 1~3%, lithium carbonate 1~3%, zinc oxide 1~8%, rutile 1~8%, kaolin 3~8%, anion propellant 3~10%, through mixing, ball milling, being sieved is made glaze.The glaze manufacture craft is essentially identical with the technique of conventional ceramic glaze, cost is relatively low, it can be made single colour glaze, fancy glaze or furnace transmutation glaze by adding different ceramic pigments, ceramic product obtained integrates functional and aesthetics, practicability than similar techniques principle product currently on the market is stronger, technology content is higher, and technique applicability is more preferable, therefore has broad application prospects.

Description

A kind of ceramic basic glaze materials and its use with health care and environment-protection functional Method
Technical field
The invention belongs to inorganic non-metallic material (ceramics) fields, and in particular to one kind has health care and environment-friendly function The ceramic basic glaze materials and its application method of property.
Background technique
Anion is the very useful far-infrared radiation material of a kind of pair of human health, is suitable for the far infrared of absorption of human body Optimal wavelength is 9.6 μm, and the radiation infrared wavelength of anion mineral crystal is in 2-18 μ m, and radiant power is sent out Penetrating density is that 0.04w/cm2 is slightly higher, and above data can be confirmed sufficiently, and the far infrared and human body of anion mineral crystal radiation are assisted It adjusts very well, can all be absorbed by human body.In general, people needs about 13,000,000,000 anions daily, and our room, office Room, the environment such as public place of entertainment can only provide about 1-20 hundred million, and the huge contrast between this supply and demand tends to lead to pneumonia, The disease of the respiratory systems such as tracheitis.Negative aeroion can restore polluter, nitrogen oxides, cigarette from atmosphere etc. simultaneously The active oxygen (oxygen radical) of generation, reduces harm of the excessive active oxygen to human body, neutralizes positively charged floating dust in air without charge After settle, be purified air.Our domestic water, wherein contain a certain amount of dissolubility pollutant, such as high fluorine, disinfection By-product etc., far-infrared ray ceramic can cross various harmful substances in drainage, and discharge a variety of pairs of beneficial microelements of human body. Far-infrared ray ceramic with activated water, can enhance the penetration of water, dissolving power, metabolism power, have mind to human health is improved Odd effect.Therefore the health product of anion emerges one after another at present, deep to be liked by the majority of consumers.But due to anion Mineral hold burn temperature it is lower, and be added ceramic batch in, can to some extent influence Ceramic glaze presentation quality, such as color Pool, brightness, artistic effect of furnace transmutation glaze etc..Therefore the functionality of glaze can not only have been kept by finding one kind, but also can meet the appearance of glaze The parent glaze side of quality and artistry is the research and development project of current ceramic technology circle.Nowadays the most meal tea of people's routine use Tool, drinking utensils, artistic porcelain etc. are all using the firing of high temperature degree and appearance requirement higher ceramic, therefore the technology Lack the biggish application and performance for hindering anion material technology.
Summary of the invention
That the technical problem to be solved in the present invention is to provide a kind of firing ranges is wider, anion emission amount is larger, raw material at The simple ceramic basic glaze materials formula of this lower and manufacture craft and its application method.
In order to solve the above technical problems, the technical scheme is that it is a kind of with health care and environment-protection functional Ceramic basic glaze materials, using natural negative ion raw mineral materials and conventional ceramic raw material, weight percent composition are as follows: feldspar 30~ 55%, quartzy 15~30%, calcite 10~20%, talcum 1~8%, barium carbonate 3~8%, strontium carbonate 1~3%, lithium carbonate 1 ~3%, zinc oxide 1~8%, rutile 1~8, kaolin 3~8%, anion propellant 3~10%, through mixing, ball milling, mistake It sieves and glaze is made.
The anion propellant is the opal and the nano combined micro mist of rare talent's stone that average grain diameter is less than 50nm.
The weight ratio of opal and rare talent's stone is 50:50 in the anion propellant.
The fineness of the industrial pure material is 200 mesh.
The sieve fineness of the sieving process is 325 mesh, the surplus 0.2~0.5% after sieving.
The moisture content of the obtained glaze is 50%.
The application method of above-mentioned ceramic basic glaze materials, it is characterised in that: the glaze can be used for inside ceramic body and table Face, glazed thickness are 0.3~0.5mm, and the firing range of glaze is 1150~1300 DEG C.
Glaze materials can be made by the ceramic pigment that added weight percentage is 3~10% in the glaze.
The ceramic pigment is one or more ceramic pigment mixtures.
Anion emission amount after the glaze firing is 1000-3000/cm3.
According to the physicalchemical structure characteristics of anion mineral, specially develop can be improved anion mineral and holds the present invention It burns temperature and is suitble to the ceramic basic glaze materials of most of ceramic body performances again, which has health care and environmentally friendly dual Function, without any side effects, safety and environmental protection, the beneficial microelement of releasable a variety of pairs of human bodies, and also it is efficacy lasting.Such Glaze applicable surface is extensive, use flexibly, can inherence according to different product and appearance requirement, adjust different formulas, directly It connects and is used as interior glaze and outer glaze, be such as used for teacup, can purify and activated water, make water sweetness free from extraneous odour, and have antibacterial Effect;Such as that can accelerate hotel catering speed, make wine more glycol, improve the quality of wine in bottle;For ceramic wall On floor tile, the pernicious gas and peculiar smell in room air can be removed, improves air quality, artistic porcelain is used for, ring can be beautified Border, and air quality can be improved.The production technique is essentially identical with the technique of conventional ceramic glaze, and cost is relatively low, by adding Add different ceramic pigments to can be made single colour glaze, fancy glaze or furnace transmutation glaze, ceramic product obtained collect functional and aesthetics in One, the practicability than similar techniques principle product currently on the market is stronger, and technology content is higher, and technique applicability is more preferable, compared with Solves the narrow technical problem of anion mineral use scope well.
Specific embodiment
Implementation column one:
Function equipment glaze material composition is as follows: unit: wt%
The base glaze that obtained moisture content is 50% after forming first by upper table and carry out mixing, ball milling, crossing 325 meshes;
Then glaze obtained is imposed on into ceramic body inside and surface, glazed thickness 0.3mm, after drying in kiln The glaze of the present invention with health care and environment-protection functional is obtained through 1180 DEG C of firings, anion emission amount is 1500 A/cm3.
Implementation column two:
Function equipment glaze material composition is as follows: unit: wt%
The base glaze that obtained moisture content is 50% after forming first by upper table and carry out mixing, ball milling, crossing 325 meshes;
Then glaze obtained is imposed on into ceramic body inside and surface, glazed thickness 0.35mm, in kiln after drying In 1200 DEG C of firings obtain the glaze of the present invention with health care and environment-protection functional, anion emission amount is 2500 A/cm3.
Implementation column three:
Function equipment glaze material composition is as follows: unit: wt%
The base glaze that obtained moisture content is 50% after forming first by upper table and carry out mixing, ball milling, crossing 325 meshes;
Then glaze obtained is imposed on into ceramic body inside and surface, glazed thickness 0.4mm, after drying in kiln In 1220 DEG C of firings obtain the glaze of the present invention with health care and environment-protection functional, anion emission amount is 2500 A/cm3.
Implementation column four:
It prepares red function coloured glaze material composition and is as follows: unit: wt%
First by upper table form carry out mixing, again plus additional 10% zirconium-iron pink pigment carry out ball milling, cross 325 meshes after make Obtain the base glaze that moisture content is 50%;
Then glaze obtained is imposed on into ceramic body surface, glazed thickness 0.4mm, through 1280 in kiln after drying DEG C fire and to obtain the red glaze of the present invention with health care and environment-protection functional, anion emission amount for 2600/ cm3。
Implementation column five:
It prepares black function coloured glaze material composition and is as follows: unit: wt%
It is formed first by upper table obtained after carrying out mixing, additional 9% cobalt black colorant being added to carry out ball milling, cross 325 meshes again The basic colour glaze that moisture content is 50%;
Then glaze obtained is imposed on into ceramic body surface, glazed thickness 0.3mm, through 1290 in kiln after drying DEG C fire and to obtain the black glaze of the present invention with health care and environment-protection functional, anion emission amount for 2500/ cm3。
Implementation column six:
It prepares colorful function coloured glaze material composition and is as follows: unit: wt%
Mixing is carried out by upper table composition first, adds additional 5% Red pigment and the 1% dark blue colorant in sea to carry out ball again The basic colour glaze that moisture content is 50% is made after crossing 325 meshes in mill;
Then glaze obtained is imposed on into ceramic body surface, glazed thickness 0.5mm is passed through in kiln after drying 1300 DEG C of firings obtain the purple glaze of the present invention with health care and environment-protection functional, and anion emission amount is 2400 A/cm3.
The fineness of above-mentioned industrial pure material is 200 mesh.
The average grain diameter of above-mentioned opal and rare talent's stone is less than 50nm.

Claims (7)

1. a kind of ceramic basic glaze materials with health care and environment-protection functional, former using natural mineral raw and technical pure Material, weight percent composition are as follows: feldspar 30~55%, quartzy 15~30%, calcite 10~25%, talcum 1~8%, carbon Sour barium 3~8%, strontium carbonate 1~3%, lithium carbonate 1~3%, zinc oxide 1~8%, rutile 1~8%, kaolin 3~8%, Anion propellant 3~10%, through mixing, ball milling, being sieved is made base glaze;The base glaze is for inside ceramic body And surface, glazed thickness are 0.3~0.5mm, the firing range of base glaze is 1150~1300 DEG C;The parent glaze Glaze materials can be made by the ceramic pigment that added weight percentage is 3~10% in material;The anion propellant is flat Equal partial size is less than the opal and the nano combined micro mist of rare talent's stone of 50nm.
2. ceramic basic glaze materials according to claim 1, it is characterised in that: opal and rare talent in the anion propellant The weight ratio of stone is 50:50.
3. ceramic basic glaze materials according to claim 1, it is characterised in that: the fineness of the industrial pure material is 200 mesh.
4. ceramic basic glaze materials according to claim 1, it is characterised in that: the sieve fineness of the sieving process is 325 mesh, Surplus 0.2~0.5% after sieving.
5. ceramic basic glaze materials according to claim 1, it is characterised in that: the moisture content of the obtained base glaze is 50%.
6. the application method of ceramic basic glaze materials according to claim 1, it is characterised in that: the ceramic pigment be it is a kind of or A variety of ceramic pigment mixtures.
7. the application method of ceramic basic glaze materials according to claim 1, it is characterised in that: after the base glaze firing Anion emission amount is 1000-3000/cm3.
CN201710808569.4A 2017-09-09 2017-09-09 A kind of ceramic basic glaze materials and its application method with health care and environment-protection functional Withdrawn CN109485257A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110668784A (en) * 2019-07-17 2020-01-10 嘉兴市辰毅太赫兹技术有限公司 Terahertz health-preserving ceramic cooking pot and manufacturing method thereof
CN115745581A (en) * 2022-09-02 2023-03-07 江西财经大学 Preparation method of ceramic wine container for reducing fusel oil content in wine

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040100308A (en) * 2003-05-22 2004-12-02 동서산업주식회사 Anion generation tile and process for the preparation thereof
CN103864464A (en) * 2014-03-08 2014-06-18 朱仙炳 Ceramic basic glaze with health maintenance function and environment-friendly function and use method thereof
CN104129996A (en) * 2014-08-06 2014-11-05 淄博百康经贸有限公司 Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof
CN105541410A (en) * 2016-02-02 2016-05-04 福建省威尔陶瓷股份有限公司 Modified tourmaline powder for ceramic glaze, anion ceramic glaze and preparation method
CN106673606A (en) * 2017-01-04 2017-05-17 江苏地球蓝环保科技有限公司 Anion glaze, blank, preparation method and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040100308A (en) * 2003-05-22 2004-12-02 동서산업주식회사 Anion generation tile and process for the preparation thereof
CN103864464A (en) * 2014-03-08 2014-06-18 朱仙炳 Ceramic basic glaze with health maintenance function and environment-friendly function and use method thereof
CN104129996A (en) * 2014-08-06 2014-11-05 淄博百康经贸有限公司 Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof
CN105541410A (en) * 2016-02-02 2016-05-04 福建省威尔陶瓷股份有限公司 Modified tourmaline powder for ceramic glaze, anion ceramic glaze and preparation method
CN106673606A (en) * 2017-01-04 2017-05-17 江苏地球蓝环保科技有限公司 Anion glaze, blank, preparation method and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110668784A (en) * 2019-07-17 2020-01-10 嘉兴市辰毅太赫兹技术有限公司 Terahertz health-preserving ceramic cooking pot and manufacturing method thereof
CN115745581A (en) * 2022-09-02 2023-03-07 江西财经大学 Preparation method of ceramic wine container for reducing fusel oil content in wine

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Application publication date: 20190319