CN107721174A - A kind of glazing process of pottery glaze with health role - Google Patents
A kind of glazing process of pottery glaze with health role Download PDFInfo
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- CN107721174A CN107721174A CN201710898303.3A CN201710898303A CN107721174A CN 107721174 A CN107721174 A CN 107721174A CN 201710898303 A CN201710898303 A CN 201710898303A CN 107721174 A CN107721174 A CN 107721174A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catalysts (AREA)
Abstract
A kind of glazing process of pottery glaze with health role, pottery glaze of the invention are divided into two layers, and internal layer is the ground-coat enamel containing accumulating type luminescent material, and outer layer is the surface layer of the antiseptic containing nano-photocatalyst material and magnet powder, and its preparation technology is as follows:The glaze slip containing accumulating type luminescent material is first prepared, the surface coated in biscuit, kiln-firing after drying;The titanium dioxide anti-bacterial agent of load antibacterial metal ions is prepared using infusion process again, and add magnet powder thereto and antibacterial catalytic solution is made, billet surface after being fired coated in first time, enter kiln after drying to calcine at 500 ~ 550 DEG C, you can complete the glazing process of pottery glaze with health role;The present invention absorbs sunshine by accumulating type luminescent material, sends faint photocatalytic nanometer catalysis material and produces catharsis, while sends the low-lights of different colours using the long after glow luminous material of different colours, plays a part of decoration.
Description
Technical field
The present invention relates to ceramic technology field, specifically a kind of glazing work of pottery glaze with health role
Skill.
Background technology
Pottery is originated in the Eastern Han Dynasty, is one of five big kiln porcelain of Song Dynasty, the treasure in Han nationality's tradition technology in producing porcelain, is referred to as
National treasure, rarity, it is world-famous for the transmutation art of uniqueness, is known as " the valuable an ancient unit of weight of gold is priceless " and " there is ten thousand strings of cash in family, not as pottery
One " good reputation, be the exclusive national treasure porcelain in Countermeasure In Yuzhou City of Henan Province god Hou towns, by its simple and unsophisticated moulding, consummate technique, multiple
The miscellaneous change nothing such as magical transmutation, the beautiful scenery of lakes and mountains, rosy clouds fog, people's beast flower, bird, insect, and fish with glaze, " it is color to enter kiln kiln discharge ten thousand of the same colour "
Poor figure color and marvellous charm, it is described as first of Chinese " five big porcelain ".
China has the history with more than one thousand years using porcelain, and such as cup, bowls and chopsticks, vase, porcelain pillow porcelain tool are that the common people are daily
The part that can not be lacked in life, with the fast development of economy with people to growth in the living standard, ceramic is
As the ornamental ceramics in the places such as people family, office, market, the existing Ceramic glaze for having technology, although smooth
Degree is high, various colors, but have specific health care and antibacterial functions, as the improvement of people's living standards, with sterilization with
The material of antimicrobial effect by the concern and attention of people, according to the difference of material, can increasingly be had basic antiseptic by antibacterial
Effect composition is divided into inorganic antiseptic and organic antibacterial agent.At present, organic antibacterial agent is widely used in most of anti-biotic materials, tool
There is very strong anti-mycotic efficiency, but anti-bacterial effect is poor, heat resistance equistability is low, and catabolite or volatility product may be right
Human body is harmful to, moreover, in recent years due to drug resistance pathogenic bacteria appearance, limit the use of organic antibacterial agent, it is inorganic
Antiseptic is to be based on utilizing metal ion or oxide or some catalysis materials such as silver, copper, zinc(TiO2, ZnO2Deng)Etc. inorganic
The antimicrbial power that thing has plays antibacterial, the antiseptic of bactericidal action, has strong antibiotic property, high temperature resistant, stability and security good
Etc. characteristic.It is therefore an object of the present invention to reference to catalysis material provide it is a kind of have purification, antibacterial functions pottery glaze and
Its glazing process.
The content of the invention
The invention aims to solve the deficiency of above-mentioned technical problem, the present invention proposes a kind of with health role
The glazing process of pottery glaze.
The present invention is for the insufficient technical scheme that uses for solving above-mentioned technical problem:
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, take 30 ~ 50 parts of accumulating type luminescent material, 30 ~ 40 parts of albite, quartz 50 ~ 60 parts, calcite 10 ~
2 ~ 3 parts of 15 parts, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and tin oxide, by above-mentioned various raw materials
It is put into after crushing in ball mill plus water carries out 5 ~ 6h of wet-milling, glaze slip is obtained after sieving, it is standby;
(2)Prepare particle diameter be 30 ~ 32nm titanium dioxide microballoon sphere carrier, use infusion process according to antibacterial metal ions load capacity for
The 1 ~ 1.5% of titanium dioxide microballoon sphere mass fraction, the titanium dioxide anti-bacterial agent of load antibacterial metal ions is prepared, it is standby;
(3)Take step(2)The titanium dioxide anti-bacterial agent of the load antibacterial metal ions of preparation, addition deionized water are prepared into molten
Liquid, the magnet powder of the titanium dioxide anti-bacterial agent quality 20 ~ 30% of load antibacterial metal ions is then added thereto, is stirred
Afterwards, antibacterial catalytic solution is obtained, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
Preferably, the titanium dioxide anti-bacterial agent for loading antibacterial metal ions is load silver, carries cerium composite titanium dioxide antiseptic.
Preferably, the accumulating type luminescent material is long after glow luminous material.
Preferably, silver is carried, the preparation method of load cerium composite titanium dioxide antiseptic is:It is titanium dioxide according to silver load capacity
Microspheres quality fraction 0.5 ~ 1%, cerium load capacity be titanium dioxide microballoon sphere mass fraction 0.3 ~ 0.5%, titanium dioxide is added
In the mixed aqueous solution of silver nitrate and cerous nitrate, stirred under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control with 200 ~ 300r/min speed,
Then filtered, dried, be put into sintering furnace 4 ~ 6h of calcining at 400 ~ 600 DEG C, be made and carry silver, carry cerium composite titanium dioxide
Antiseptic.
Preferably, the long after glow luminous material is green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy,
Eu。
Preferably, the long after glow luminous material is blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:
Nd, Eu.
The beneficial effects of the invention are as follows:
The present invention is to provide a kind of glazing process of pottery glaze with health role, the pottery glaze is divided into two layers, interior
Layer is the ground-coat enamel containing accumulating type luminescent material, and outer layer is the surface layer of the antiseptic containing nano-photocatalyst material and magnet powder;
Nano-photocatalyst material can effectively decompose organic pollution and bacterium in surrounding environment under the irradiation of ambient light, be people
A clean environment, but nano-photocatalyst material competence exertion catharsis only under the irradiation of light are provided, if close
Black out source, just do not possess photo-catalysis function in the environment of dark, therefore it combined with the accumulating type luminescent material in ground-coat enamel,
Sunshine is absorbed on daytime by accumulating type luminescent material, sends faint light at night, on the one hand can catalytic nanometer photocatalysis material
Material produces catharsis, and the long after glow luminous material of different colours on the other hand can be selected in the glaze, can send different face
The low-light of color, it may also function as the effect of decoration;
The present invention has done modification to nano-photocatalyst material, and antibacterial metal is loaded on nanometer titanium dioxide micro-sphere using infusion process
Ion, such as silver ion, cerium ion, when can effectively play the sterilization of nano titanium oxide itself, kill the virus, and photocatalysis drop
Solve the effect of bacterium, virus, organic matter;Second, in no light source or light lack environment, effectively play on carrier and adhere to antibacterial
The antibacterial of metal ion, the effect for killing virus, can kill bacterium, virus, and and can thoroughly decomposes elimination carefully using photocatalysis
Bacterium, the residue of virus;In addition, being also added into a small amount of magnetite in surface layer, first, the endocrine of human body can be improved, can promote
Cell metabolism, internal low quality cell is activated, accelerates the exclusion of bodily waste, so as to the cellular environment in cleaning body, improved
The blood quality of human body, second, body immunity, anti-aging can be improved, third, the fatigue of body can be reduced, promote energy
Recovery, and improve the state of human-body sub-health, abirritative mood;
In summary, pottery glaze of the invention, after being applied on biscuit, the pottery of preparation can be made there is antibacterial, purification and dress
The effect of decorations.
Embodiment
With reference to specific embodiment, the present invention is further elaborated.
Embodiment is as follows:
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, take 30 ~ 50 parts of accumulating type luminescent material, 30 ~ 40 parts of albite, quartz 50 ~ 60 parts, calcite 10 ~
2 ~ 3 parts of 15 parts, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and tin oxide, by above-mentioned various raw materials
It is put into after crushing in ball mill plus water carries out 5 ~ 6h of wet-milling, glaze slip is obtained after sieving, it is standby;
(2)Prepare particle diameter be 30 ~ 32nm titanium dioxide microballoon sphere carrier, use infusion process according to antibacterial metal ions load capacity for
The 1 ~ 1.5% of titanium dioxide microballoon sphere mass fraction, the titanium dioxide anti-bacterial agent of load antibacterial metal ions is prepared, it is standby;
(3)Take step(2)The titanium dioxide anti-bacterial agent of the load antibacterial metal ions of preparation, addition deionized water are prepared into molten
Liquid, the magnet powder of the titanium dioxide anti-bacterial agent quality 20 ~ 30% of load antibacterial metal ions is then added thereto, is stirred
Afterwards, antibacterial catalytic solution is obtained, it is standby;Magnetite one is the endocrine that can improve human body, can promote cell metabolism, activation is in vivo
Low quality cell, accelerate the exclusion of bodily waste, so as to the cellular environment in cleaning body, improve the blood quality of human body, two
It is that can improve body immunity, anti-aging, third, the fatigue of body can be reduced, promotes the recovery of energy, and improve human body
The state of inferior health, abirritative mood.
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxic gas
Atmosphere, on an hourly basis 150 ~ 170 DEG C of programming rate be increased to 900 ~ 920 DEG C, then using reducing atmosphere, temperature is pressed per small
When 150 ~ 170 DEG C of programming rate continue to be increased to 1250 ~ 1300 DEG C, be cooled to room temperature after being incubated 20 ~ 30min, it is standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role;Nano-photocatalyst material is outside
Under the irradiation of boundary's light, organic pollution and bacterium in surrounding environment can be effectively decomposed, the ring of a cleaning is provided for people
Border, but nano-photocatalyst material competence exertion catharsis only under the irradiation of light, if turned off light source, in the ring of dark
Just do not possess photo-catalysis function in border, therefore it is combined with the accumulating type luminescent material in ground-coat enamel, lighted material by accumulating type
Material daytime absorb sunshine, send faint light at night, on the one hand can catalytic nanometer catalysis material produce catharsis, separately
On the one hand the long after glow luminous material of different colours can be selected in the glaze, the low-light of different colours can be sent, may also function as
The effect of decoration.
Preferably, the titanium dioxide anti-bacterial agent for loading antibacterial metal ions is load silver, carries cerium composite titanium dioxide antiseptic;
First, can effectively play the sterilization of nano titanium oxide itself, kill the virus, and photocatalytic degradation bacterium, virus, organic matter
Effect;Second, in no light source or light lack environment, effectively play and adhere to the antibacterial of antibacterial metal ions on carrier, kill disease
The effect of poison, bacterium, virus can be killed, and can is thoroughly decomposed using photocatalysis eliminates bacterium, the residue of virus.
Preferably, the accumulating type luminescent material is long after glow luminous material.
Preferably, silver is carried, the preparation method of load cerium composite titanium dioxide antiseptic is:It is titanium dioxide according to silver load capacity
Microspheres quality fraction 0.5 ~ 1%, cerium load capacity be titanium dioxide microballoon sphere mass fraction 0.3 ~ 0.5%, titanium dioxide is added
In the mixed aqueous solution of silver nitrate and cerous nitrate, stirred under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control with 200 ~ 300r/min speed,
Then filtered, dried, be put into sintering furnace 4 ~ 6h of calcining at 400 ~ 600 DEG C, be made and carry silver, carry cerium composite titanium dioxide
Antiseptic.
Preferably, the long after glow luminous material is green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy,
Eu。
Preferably, the long after glow luminous material is blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:
Nd, Eu.
Embodiment 1
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, 30 ~ 50 parts of green long afterglow luminescenjt powder SrOAl are taken2O3·0.05B2O3:Dy, Eu, sodium length
30 ~ 40 parts of stone, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcite, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, talcum powder 5 ~ 8
Part and 2 ~ 3 parts of tin oxide, will above-mentioned various raw materials crush after be put into ball mill plus water carries out 5 ~ 6h of wet-milling, obtain glaze after sieving
Slurry, it is standby;
(2)The titanium dioxide microballoon sphere carrier that particle diameter is 30 ~ 32nm is prepared, is titanium dioxide microballoon sphere mass fraction according to silver load capacity
0.5 ~ 1%, 0.3 ~ 0.5% that cerium load capacity is titanium dioxide microballoon sphere mass fraction, titanium dioxide is added into silver nitrate and nitric acid
In the mixed aqueous solution of cerium, stirred with 200 ~ 300r/min speed under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control, then taken out
Filter, drying, 4 ~ 6h of calcining at 400 ~ 600 DEG C is put into sintering furnace, is made and carries silver, carry cerium composite titanium dioxide antiseptic, it is standby
With;
(3)Take step(2)The load silver of preparation, cerium composite titanium dioxide antiseptic is carried, add deionized water and be prepared into solution, then
The magnet powder for add thereto and carry silver, carrying cerium composite titanium dioxide antiseptic quality 20 ~ 30%, after stirring, obtains antibacterial and urges
Change solution, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
Pottery glaze made above, pass through green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy, Eu exist
Daytime absorb sunshine, faint green glow can be sent at night, on the one hand can catalytic nanometer catalysis material produce catharsis, separately
On the one hand decoration can be played a part of.
Embodiment 2
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, 30 ~ 50 parts of blue long-afterglow luminescent powder end 4SrO7Al are taken2O3·0.07B2O3:Nd, Eu, sodium
30 ~ 40 parts of feldspar, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcite, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, talcum powder 5
~ 8 parts and 2 ~ 3 parts of tin oxide, are put into ball mill after above-mentioned various raw materials are crushed plus water carries out 5 ~ 6h of wet-milling, are obtained after sieving
Glaze slip, it is standby;
(2)The titanium dioxide microballoon sphere carrier that particle diameter is 30 ~ 32nm is prepared, is titanium dioxide microballoon sphere mass fraction according to silver load capacity
0.5 ~ 1%, 0.3 ~ 0.5% that cerium load capacity is titanium dioxide microballoon sphere mass fraction, titanium dioxide is added into silver nitrate and nitric acid
In the mixed aqueous solution of cerium, stirred with 200 ~ 300r/min speed under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control, then taken out
Filter, drying, 4 ~ 6h of calcining at 400 ~ 600 DEG C is put into sintering furnace, is made and carries silver, carry cerium composite titanium dioxide antiseptic, it is standby
With;
(3)Take step(2)The load silver of preparation, cerium composite titanium dioxide antiseptic is carried, add deionized water and be prepared into solution, then
The magnet powder for add thereto and carry silver, carrying cerium composite titanium dioxide antiseptic quality 20 ~ 30%, after stirring, obtains antibacterial and urges
Change solution, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
Pottery glaze made above, pass through blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:Nd, Eu
Daytime absorb sunshine, faint blue light can be sent at night, on the one hand can catalytic nanometer catalysis material produce catharsis,
On the other hand decoration can be played a part of.
Embodiment 3
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, 10 ~ 20 parts of blue long-afterglow luminescent powder end 4SrO7Al are taken2O3·0.07B2O3:It is Nd, Eu, green
The long-persistence luminous powder SrOAl of color2O3·0.05B2O3:Dy, Eu, 30 ~ 40 parts of albite, quartz 50 ~ 60 parts, calcite 10 ~
2 ~ 3 parts of 15 parts, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and tin oxide, by above-mentioned various raw materials
It is put into after crushing in ball mill plus water carries out 5 ~ 6h of wet-milling, glaze slip is obtained after sieving, it is standby;
(2)The titanium dioxide microballoon sphere carrier that particle diameter is 30 ~ 32nm is prepared, is titanium dioxide microballoon sphere mass fraction according to silver load capacity
0.5 ~ 1%, 0.3 ~ 0.5% that cerium load capacity is titanium dioxide microballoon sphere mass fraction, titanium dioxide is added into silver nitrate and nitric acid
In the mixed aqueous solution of cerium, stirred with 200 ~ 300r/min speed under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control, then taken out
Filter, drying, 4 ~ 6h of calcining at 400 ~ 600 DEG C is put into sintering furnace, is made and carries silver, carry cerium composite titanium dioxide antiseptic, it is standby
With;
(3)Take step(2)The load silver of preparation, cerium composite titanium dioxide antiseptic is carried, add deionized water and be prepared into solution, then
The magnet powder for add thereto and carry silver, carrying cerium composite titanium dioxide antiseptic quality 20 ~ 30%, after stirring, obtains antibacterial and urges
Change solution, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
Pottery glaze made above, pass through blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:Nd, Eu,
Green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy, Eu absorb sunshine on daytime, can send at night faint
Blue green light, on the one hand can catalytic nanometer catalysis material produce catharsis, on the other hand can play a part of decoration.
Embodiment 4
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, 10 ~ 20 parts of blue long-afterglow luminescent powder end 4SrO7Al are taken2O3·0.07B2O3:It is Nd, Eu, green
The long-persistence luminous powder SrOAl of color2O3·0.05B2O3:Dy, Eu, 30 ~ 40 parts of albite, quartz 50 ~ 60 parts, calcite 10 ~
2 ~ 3 parts of 15 parts, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and tin oxide, by above-mentioned various raw materials
It is put into after crushing in ball mill plus water carries out 5 ~ 6h of wet-milling, glaze slip is obtained after sieving, it is standby;
(2)The titanium dioxide microballoon sphere carrier that particle diameter is 30 ~ 32nm is prepared, is titanium dioxide microballoon sphere mass fraction according to silver load capacity
0.8 ~ 1.5%, by titanium dioxide add silver nitrate aqueous solution in, with 200 ~ 300r/min under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control
Speed stirring, then filtered, dried, be put into sintering furnace at 400 ~ 600 DEG C 4 ~ 6h of calcining, be made and carry silver-colored titanium dioxide
Titanium antiseptic, it is standby;
(3)Take step(2)The load silver titanium dioxide anti-bacterial agent of preparation, add deionized water and be prepared into solution, then add thereto
Enter the magnet powder for carrying silver-colored titanium dioxide anti-bacterial agent quality 20 ~ 30%, after stirring, obtain antibacterial catalytic solution, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
Pottery glaze made above, pass through blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:Nd, Eu,
Green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy, Eu absorb sunshine on daytime, can send at night faint
Blue green light, on the one hand can catalytic nanometer catalysis material produce catharsis, on the other hand can play a part of decoration.
Embodiment 5
A kind of glazing process of pottery glaze with health role, comprises the following steps:
(1)In parts by weight, 10 ~ 20 parts of blue long-afterglow luminescent powder end 4SrO7Al are taken2O3·0.07B2O3:It is Nd, Eu, green
The long-persistence luminous powder SrOAl of color2O3·0.05B2O3:Dy, Eu, 30 ~ 40 parts of albite, quartz 50 ~ 60 parts, calcite 10 ~
2 ~ 3 parts of 15 parts, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and tin oxide, by above-mentioned various raw materials
It is put into after crushing in ball mill plus water carries out 5 ~ 6h of wet-milling, glaze slip is obtained after sieving, it is standby;
(2)The titanium dioxide microballoon sphere carrier that particle diameter is 30 ~ 32nm is prepared, is titanium dioxide microballoon sphere mass fraction according to cerium load capacity
0.8 ~ 1.5%, by titanium dioxide add the cerous nitrate aqueous solution in, with 200 ~ 300r/min under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control
Speed stirring, then filtered, dried, be put into sintering furnace at 400 ~ 600 DEG C 4 ~ 6h of calcining, be made and carry cerium titanium dioxide
Titanium antiseptic, it is standby;
(3)Take step(2)The load cerium titanium dioxide anti-bacterial agent of preparation, add deionized water and be prepared into solution, then add thereto
Enter to carry the magnet powder of cerium titanium dioxide anti-bacterial agent quality 20 ~ 30%, after stirring, obtain antibacterial catalytic solution, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
Pottery glaze made above, pass through blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:Nd, Eu,
Green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy, Eu absorb sunshine on daytime, can send at night faint
Blue green light, on the one hand can catalytic nanometer catalysis material produce catharsis, on the other hand can play a part of decoration.
The foregoing description of the disclosed embodiments, only for enabling professional and technical personnel in the field to realize or using this
Invention.A variety of modifications to these embodiments will be apparent for those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent most wide scope of point.
Claims (6)
1. a kind of glazing process of pottery glaze with health role, it is characterised in that comprise the following steps:
(1)In parts by weight, take 30 ~ 50 parts of accumulating type luminescent material, 30 ~ 40 parts of albite, quartz 50 ~ 60 parts, calcite 10 ~
2 ~ 3 parts of 15 parts, 15 ~ 20 parts of calcined kaolin, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and tin oxide, by above-mentioned various raw materials
It is put into after crushing in ball mill plus water carries out 5 ~ 6h of wet-milling, glaze slip is obtained after sieving, it is standby;
(2)Prepare particle diameter be 30 ~ 32nm titanium dioxide microballoon sphere carrier, use infusion process according to antibacterial metal ions load capacity for
The 1 ~ 1.5% of titanium dioxide microballoon sphere mass fraction, the titanium dioxide anti-bacterial agent of load antibacterial metal ions is prepared, it is standby;
(3)Take step(2)The titanium dioxide anti-bacterial agent of the load antibacterial metal ions of preparation, addition deionized water are prepared into molten
Liquid, the magnet powder of the titanium dioxide anti-bacterial agent quality 20 ~ 30% of load antibacterial metal ions is then added thereto, is stirred
Afterwards, antibacterial catalytic solution is obtained, it is standby;
(4)By step(1)The glaze slip of preparation is coated in the surface of biscuit, and kiln-firing after drying, kiln uses oxidizing atmosphere, pressed
150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C per hour, then using reducing atmosphere, by temperature on an hourly basis 150 ~
170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C, and room temperature is cooled to after being incubated 20 ~ 30min, standby;
(5)By step(3)The antibacterial catalytic solution of preparation is sprayed on step(4)The surface of the base substrate of preparation, sprayed again after drying
Apply, until coating thickness is 1 ~ 2mm, kiln calcining is entered after drying, calcining heat is 500 ~ 550 DEG C, and soaking time is 1 ~ 2h, calcining
After be cooled to room temperature, you can complete the glazing process of pottery glaze with health role.
2. a kind of glazing process of pottery glaze with health role as claimed in claim 1, it is characterised in that load is anti-
The titanium dioxide anti-bacterial agent of bacterium metal ion is load silver, carries cerium composite titanium dioxide antiseptic.
A kind of 3. glazing process of pottery glaze with health role as claimed in claim 1, it is characterised in that the storage
Energy type luminescent material is long after glow luminous material.
A kind of 4. glazing process of pottery glaze with health role as claimed in claim 2, it is characterised in that load silver,
Carry cerium composite titanium dioxide antiseptic preparation method be:According to silver load capacity for titanium dioxide microballoon sphere mass fraction 0.5 ~
1%th, cerium load capacity is the 0.3 ~ 0.5% of titanium dioxide microballoon sphere mass fraction, and titanium dioxide is added into the mixed of silver nitrate and cerous nitrate
In Heshui solution, stirred under the conditions of 50 ~ 70 DEG C of waters bath with thermostatic control with 200 ~ 300r/min speed, then filtered, dried,
4 ~ 6h of calcining at 400 ~ 600 DEG C is put into sintering furnace, is made and is carried silver, carries cerium composite titanium dioxide antiseptic.
A kind of 5. glazing process of pottery glaze with health role as claimed in claim 3, it is characterised in that the length
Afterglow materials are green long afterglow luminescenjt powder SrOAl2O3·0.05B2O3:Dy, Eu.
A kind of 6. glazing process of pottery glaze with health role as claimed in claim 3, it is characterised in that the length
Afterglow materials are blue long-afterglow luminescent powder end 4SrO7Al2O3·0.07B2O3:Nd, Eu.
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CN111548122A (en) * | 2020-06-17 | 2020-08-18 | 山东兴豪陶瓷有限公司 | Antibacterial carved stone ceramic tile and preparation method thereof |
CN113198480A (en) * | 2021-04-27 | 2021-08-03 | 上海应用技术大学 | La/Co @ TiO2Nanosphere catalyst and preparation method and application thereof |
CN117567029A (en) * | 2023-11-27 | 2024-02-20 | 揭阳市栢轩顺陶瓷有限公司 | Antibacterial ceramic glaze and preparation method thereof |
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