CN107651951A - A kind of environment-friendly and green anion tile and its production method - Google Patents
A kind of environment-friendly and green anion tile and its production method Download PDFInfo
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- CN107651951A CN107651951A CN201710811921.XA CN201710811921A CN107651951A CN 107651951 A CN107651951 A CN 107651951A CN 201710811921 A CN201710811921 A CN 201710811921A CN 107651951 A CN107651951 A CN 107651951A
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/19—Alkali metal aluminosilicates, e.g. spodumene
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
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- C—CHEMISTRY; METALLURGY
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/425—Graphite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
Abstract
A kind of environment-friendly and green anion tile of the present invention and its production method, including ceramic tile blank and glaze layer, the ceramic tile blank includes sea-gull stone, bentonite, diatomite, zebra stone, shell, black phosphorus, graphene, albite and potassium feldspar, glaze layer includes negative ion powder, nanometer elbaite powder, zeolite, titanium dioxide, micro-crystal powder, devitrified glass, graphene, kaolin and potassium feldspar, the efficient release of anion is realized, possesses nontoxic, ornamental strong and health-caring function.
Description
Technical field
The present invention relates to a kind of ceramic tile, specifically, is related to a kind of environment-friendly and green anion tile and its production method.
Background technology
When people stroll by the sea, waterfall and during forest, can feel to breathe happy, relaxing, one of them is most important
The reason for be containing abundant anion in air.Anion can facilitate human body synthesis and vitamin storage, strengthen and activate people
The physiological activity of body, therefore it is referred to as " air vitamin ", it is as the vitamin of food, to human body and other biological
Vital movement has highly important influence.After thunderstorm, the anion of air increases, and people feel happy.If
We suck appropriate anion daily, persevere, of great advantage to health:Make one full of vitality, dispelling fatigue and burnout,
Improve operating efficiency.Improve sleep, eliminate neurasthenia.Reduce disease incidence, preventing cold and breathing problem.Improve
The symptom of Cardial or cerebral vascular diseases.
As important architectural decorative and fitting materialses, Ceramic Tiles are in the energy, medical treatment, national defence, space flight and aviation, electronics, oil
There is wide application in chemical industry and domestic life field.In recent years, people progressively attempt to change the single decoration of Ceramic Tiles
Function, assign its more utility function.
The content of the invention
Instant invention overcomes in the prior art the shortcomings that, there is provided a kind of environment-friendly and green anion tile and its producer
Method, IAQ can be effectively improved, sustained release anion, anion burst size is reached optimal.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of environment-friendly and green anion tile, including ceramic tile blank and glaze layer, the ceramic tile blank include sea-gull stone, swollen
Moisten soil, diatomite, zebra stone, shell, black phosphorus, graphene, albite and potassium feldspar, glaze layer includes negative ion powder, nanometer lithium
Tourmaline powder, zeolite, titanium dioxide, micro-crystal powder, devitrified glass, graphene, kaolin and potassium feldspar.
Further, sea-gull stone 3-5%, bentonite 5-10%, diatomite are included according to mass percent, the ceramic tile blank
5-10%, zebra stone 3-5%, shell 5-8%, black phosphorus 1-2%, graphene 2-3%, albite 30-40% and potassium feldspar 30-
40%.
Further, negative ion powder 7-10%, nanometer elbaite powder 5- are included according to mass percent, the glaze layer
8%th, zeolite 5-10%, titanium dioxide 3-5%, micro-crystal powder 3-5%, devitrified glass 3-5%, graphene 1-2%, kaolin 30-
40% and potassium feldspar 30-40%.
Further, medical stone 30-40%, tourmaline 30-40%, oxygen are included according to mass percent, the negative ion powder
Change zirconium 2-5%, diatomite 10-15%, graphene 1-3% and sepiolite 4-8%.
A kind of production method of environment-friendly and green anion tile, comprises the following steps:
Step 1:Ball mill is added after the raw material of glaze layer is mixed and carries out ball milling, anion glaze slurry is made after sieving;
Step 2:The raw material of ceramic tile blank is mixed evenly, ball mill is added and carries out ball milling, 250 mesh sieves is crossed and forms material
Slurry, and is stirred old 2-3 days, the slurry is dried ceramic body powder is made, then old 3 days, using press by powder
Base substrate is pressed into, and in 130 DEG C of drying;In a nitrogen atmosphere, 1150-1200 DEG C is sintered into ceramic tile blank to base substrate.
Step 3:The anion glaze slurry glazing is pressed into ceramic body surface, the ceramic body that glazing is finished
Type, drying, ooze spend after Ceramic Tiles semi-finished product are made;
Step 4:Ceramic Tiles semi-finished product feeding tunnel cave is burnt till, elder generation is heated for 350-400 DEG C again, in 1280-
40-50 minutes are sintered under 1300 DEG C of nitrogen atmospheres.
Further, the glazing mode of the step 3 uses glaze spraying.
Compared with prior art, the beneficial effects of the invention are as follows:
It is green using the anion tile prepared by a kind of environment-friendly and green anion tile of the present invention and its production method
Color safety, has good decoration functions concurrently, realizes the efficient release of anion, possesses nontoxic, ornamental strong and health care work(
Energy.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1:
A kind of environment-friendly and green anion tile of the present invention, including ceramic tile blank and glaze layer, according to mass percent,
Ceramic tile blank includes sea-gull stone 4%, bentonite 6%, diatomite 6%, zebra stone 4%, shell 6%, black phosphorus 1.5%, graphene
2.5%th, albite 35% and potassium feldspar 35%.
According to mass percent, glaze layer includes negative ion powder 8%, nanometer elbaite powder 6%, zeolite 8%, titanium dioxide
Titanium 3.5%, micro-crystal powder 4%, devitrified glass 4%, graphene 1.5%, kaolin 32% and potassium feldspar 33%.
Wherein, medical stone 38%, tourmaline 38%, zirconium oxide 4%, diatom are included according to mass percent, negative ion powder
Soil 12%, graphene 2% and sepiolite 6%.
The burst size of black phosphorus and graphene increase anion, and graphene strengthens glaze layer, and it is wear-resisting to improve its
Property.
A kind of production method of environment-friendly and green anion tile, comprises the following steps:
Step 1:Ball mill is added after the raw material of glaze layer is mixed and carries out ball milling, anion glaze slurry is made after sieving;
Step 2:The raw material of ceramic tile blank is mixed evenly, ball mill is added and carries out ball milling, 250 mesh sieves is crossed and forms material
Slurry, and is stirred old 2-3 days, the slurry is dried ceramic body powder is made, then old 3 days, using press by powder
Base substrate is pressed into, and in 130 DEG C of drying;In a nitrogen atmosphere, 1150-1200 DEG C is sintered into ceramic tile blank to base substrate.
Step 3:The anion glaze slurry glazing is pressed into ceramic body surface, the ceramic body that glazing is finished
Type, drying, ooze spend after Ceramic Tiles semi-finished product are made, glazing mode uses glaze spraying.
Step 4:Ceramic Tiles semi-finished product feeding tunnel cave is burnt till, elder generation is heated for 350-400 DEG C again, in 1280-
40-50 minutes are sintered under 1300 DEG C of nitrogen atmospheres.
A kind of environmentally friendly anion tile of the present patent application, ceramic surface measure the average release concentration of anion be 1700/
cm3, apart from 1 meter of position of ceramic tile surface, it is 1250/cm to measure the average release concentration of anion3。
Embodiment 2:
A kind of environment-friendly and green anion tile of the present invention, including ceramic tile blank and glaze layer, according to mass percent,
Ceramic tile blank includes sea-gull stone 3.5%, bentonite 8%, diatomite 7%, zebra stone 3.5%, shell 7%, black phosphorus 1.2%, stone
Black alkene 2.8%, albite 31% and potassium feldspar 36%.
According to mass percent, glaze layer includes negative ion powder 9%, nanometer elbaite powder 7%, zeolite 6%, titanium dioxide
Titanium 4%, micro-crystal powder 3.5%, devitrified glass 3.5%, graphene 1.2%, kaolin 33.8% and potassium feldspar 32%.
According to mass percent, negative ion powder includes medical stone 36%, tourmaline 36%, zirconium oxide 4.5%, diatomite
14%th, graphene 2.5% and sepiolite 7%.
Finally it should be noted that:The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in
Within the scope of.
Claims (6)
- A kind of 1. environment-friendly and green anion tile, it is characterised in that:Including ceramic tile blank and glaze layer, the ceramic tile blank includes Sea-gull stone, bentonite, diatomite, zebra stone, shell, black phosphorus, graphene, albite and potassium feldspar, glaze layer include anion Powder, nanometer elbaite powder, zeolite, titanium dioxide, micro-crystal powder, devitrified glass, graphene, kaolin and potassium feldspar.
- A kind of 2. environment-friendly and green anion tile according to claim 1, it is characterised in that:It is described according to mass percent Ceramic tile blank includes sea-gull stone 3-5%, bentonite 5-10%, diatomite 5-10%, zebra stone 3-5%, shell 5-8%, black phosphorus 1-2%, graphene 2-3%, albite 30-40% and potassium feldspar 30-40%.
- A kind of 3. environment-friendly and green anion tile according to claim 1, it is characterised in that:It is described according to mass percent Glaze layer includes negative ion powder 7-10%, nanometer elbaite powder 5-8%, zeolite 5-10%, titanium dioxide 3-5%, micro-crystal powder 3-5%, devitrified glass 3-5%, graphene 1-2%, kaolin 30-40% and potassium feldspar 30-40%.
- 4. according to a kind of any one of claims 1 to 3 environment-friendly and green anion tile, it is characterised in that:According to quality hundred Divide ratio, the negative ion powder includes medical stone 30-40%, tourmaline 30-40%, zirconium oxide 2-5%, diatomite 10-15%, stone Black alkene 1-3% and sepiolite 4-8%.
- A kind of 5. production method of environment-friendly and green anion tile according to claim 1, it is characterised in that:Including following step Suddenly:Step 1:Ball mill is added after the raw material of glaze layer is mixed and carries out ball milling, anion glaze slurry is made after sieving;Step 2:The raw material of ceramic tile blank is mixed evenly, ball mill is added and carries out ball milling, 250 mesh sieves is crossed and forms slurry, And stir old 2-3 days, the slurry is dried ceramic body powder is made, then old 3 days, using press by powder pressing Into base substrate, and in 130 DEG C of drying;In a nitrogen atmosphere, 1150-1200 DEG C is sintered into ceramic tile blank to base substrate.Step 3:By the anion glaze slurry glazing in ceramic body surface, ceramic body that glazing is finished is compressing, Dry, ooze spend after Ceramic Tiles semi-finished product are made;Step 4:Ceramic Tiles semi-finished product feeding tunnel cave is burnt till, elder generation is heated for 350-400 DEG C again, in 1280-1300 40-50 minutes are sintered under DEG C nitrogen atmosphere.
- A kind of 6. production method of environment-friendly and green anion tile according to claim 5, it is characterised in that:The glazing mode of the step 3 uses glaze spraying.
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108530030A (en) * | 2018-04-11 | 2018-09-14 | 江西新瑞景陶瓷有限公司 | A kind of preparation method of anion glazed ceramic wall tile |
CN108558379A (en) * | 2018-04-11 | 2018-09-21 | 南安市创培电子科技有限公司 | A kind of processing method of ceramic tile |
CN108675754A (en) * | 2018-04-20 | 2018-10-19 | 淄博锦昊陶瓷有限公司 | Anion titanium brick and its preparation process |
CN108751931A (en) * | 2018-05-18 | 2018-11-06 | 赵顺全 | A kind of preparation method of anion brick |
CN108794070A (en) * | 2018-06-25 | 2018-11-13 | 佛山市三水宏源陶瓷企业有限公司 | Energy material and preparation method and application, energy ceramic tile and preparation method |
CN108793751A (en) * | 2018-07-02 | 2018-11-13 | 福建省德化祥裕陶瓷文化有限责任公司 | A kind of glaze water and preparation method thereof with far infrared activation |
CN109265006A (en) * | 2018-10-26 | 2019-01-25 | 广东能强陶瓷有限公司 | A kind of Ceramic Tiles and preparation process capable of releasing negative ion |
CN110683866A (en) * | 2019-12-10 | 2020-01-14 | 广东欧文莱陶瓷有限公司 | Ceramic tile with air purifying effect and preparation method thereof |
CN111072281A (en) * | 2018-12-11 | 2020-04-28 | 广东特地陶瓷有限公司 | Rare earth doped negative ion ceramic glaze and production method thereof |
CN111848121A (en) * | 2020-07-30 | 2020-10-30 | 福建省德化鲁闽怡家陶瓷文创有限公司 | Production process of ceramic containing graphene |
CN115745406A (en) * | 2022-12-15 | 2023-03-07 | 北京旭华时代科技有限公司 | Ceramic tile glaze capable of continuously releasing negative oxygen ions as well as preparation method and application thereof |
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Cited By (14)
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CN108558379B (en) * | 2018-04-11 | 2021-05-18 | 朔州恒锐达建陶有限公司 | Ceramic tile processing method |
CN108558379A (en) * | 2018-04-11 | 2018-09-21 | 南安市创培电子科技有限公司 | A kind of processing method of ceramic tile |
CN108530030A (en) * | 2018-04-11 | 2018-09-14 | 江西新瑞景陶瓷有限公司 | A kind of preparation method of anion glazed ceramic wall tile |
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CN108675754A (en) * | 2018-04-20 | 2018-10-19 | 淄博锦昊陶瓷有限公司 | Anion titanium brick and its preparation process |
CN108751931A (en) * | 2018-05-18 | 2018-11-06 | 赵顺全 | A kind of preparation method of anion brick |
CN108794070A (en) * | 2018-06-25 | 2018-11-13 | 佛山市三水宏源陶瓷企业有限公司 | Energy material and preparation method and application, energy ceramic tile and preparation method |
CN108793751A (en) * | 2018-07-02 | 2018-11-13 | 福建省德化祥裕陶瓷文化有限责任公司 | A kind of glaze water and preparation method thereof with far infrared activation |
CN109265006A (en) * | 2018-10-26 | 2019-01-25 | 广东能强陶瓷有限公司 | A kind of Ceramic Tiles and preparation process capable of releasing negative ion |
CN111072281A (en) * | 2018-12-11 | 2020-04-28 | 广东特地陶瓷有限公司 | Rare earth doped negative ion ceramic glaze and production method thereof |
CN110683866A (en) * | 2019-12-10 | 2020-01-14 | 广东欧文莱陶瓷有限公司 | Ceramic tile with air purifying effect and preparation method thereof |
CN111848121A (en) * | 2020-07-30 | 2020-10-30 | 福建省德化鲁闽怡家陶瓷文创有限公司 | Production process of ceramic containing graphene |
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