CN107651951A - A kind of environment-friendly and green anion tile and its production method - Google Patents

A kind of environment-friendly and green anion tile and its production method Download PDF

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Publication number
CN107651951A
CN107651951A CN201710811921.XA CN201710811921A CN107651951A CN 107651951 A CN107651951 A CN 107651951A CN 201710811921 A CN201710811921 A CN 201710811921A CN 107651951 A CN107651951 A CN 107651951A
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powder
anion
friendly
environment
stone
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林柱权
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FOSHAN CITY GAOMING DISTRICT XINYUEFENG BUILDING MATERIAL Co Ltd
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FOSHAN CITY GAOMING DISTRICT XINYUEFENG BUILDING MATERIAL Co Ltd
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    • CCHEMISTRY; METALLURGY
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/19Alkali metal aluminosilicates, e.g. spodumene
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon
    • C04B2235/425Graphite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/442Carbonates

Abstract

A kind of environment-friendly and green anion tile of the present invention and its production method, including ceramic tile blank and glaze layer, the ceramic tile blank includes sea-gull stone, bentonite, diatomite, zebra stone, shell, black phosphorus, graphene, albite and potassium feldspar, glaze layer includes negative ion powder, nanometer elbaite powder, zeolite, titanium dioxide, micro-crystal powder, devitrified glass, graphene, kaolin and potassium feldspar, the efficient release of anion is realized, possesses nontoxic, ornamental strong and health-caring function.

Description

A kind of environment-friendly and green anion tile and its production method
Technical field
The present invention relates to a kind of ceramic tile, specifically, is related to a kind of environment-friendly and green anion tile and its production method.
Background technology
When people stroll by the sea, waterfall and during forest, can feel to breathe happy, relaxing, one of them is most important The reason for be containing abundant anion in air.Anion can facilitate human body synthesis and vitamin storage, strengthen and activate people The physiological activity of body, therefore it is referred to as " air vitamin ", it is as the vitamin of food, to human body and other biological Vital movement has highly important influence.After thunderstorm, the anion of air increases, and people feel happy.If We suck appropriate anion daily, persevere, of great advantage to health:Make one full of vitality, dispelling fatigue and burnout, Improve operating efficiency.Improve sleep, eliminate neurasthenia.Reduce disease incidence, preventing cold and breathing problem.Improve The symptom of Cardial or cerebral vascular diseases.
As important architectural decorative and fitting materialses, Ceramic Tiles are in the energy, medical treatment, national defence, space flight and aviation, electronics, oil There is wide application in chemical industry and domestic life field.In recent years, people progressively attempt to change the single decoration of Ceramic Tiles Function, assign its more utility function.
The content of the invention
Instant invention overcomes in the prior art the shortcomings that, there is provided a kind of environment-friendly and green anion tile and its producer Method, IAQ can be effectively improved, sustained release anion, anion burst size is reached optimal.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of environment-friendly and green anion tile, including ceramic tile blank and glaze layer, the ceramic tile blank include sea-gull stone, swollen Moisten soil, diatomite, zebra stone, shell, black phosphorus, graphene, albite and potassium feldspar, glaze layer includes negative ion powder, nanometer lithium Tourmaline powder, zeolite, titanium dioxide, micro-crystal powder, devitrified glass, graphene, kaolin and potassium feldspar.
Further, sea-gull stone 3-5%, bentonite 5-10%, diatomite are included according to mass percent, the ceramic tile blank 5-10%, zebra stone 3-5%, shell 5-8%, black phosphorus 1-2%, graphene 2-3%, albite 30-40% and potassium feldspar 30- 40%.
Further, negative ion powder 7-10%, nanometer elbaite powder 5- are included according to mass percent, the glaze layer 8%th, zeolite 5-10%, titanium dioxide 3-5%, micro-crystal powder 3-5%, devitrified glass 3-5%, graphene 1-2%, kaolin 30- 40% and potassium feldspar 30-40%.
Further, medical stone 30-40%, tourmaline 30-40%, oxygen are included according to mass percent, the negative ion powder Change zirconium 2-5%, diatomite 10-15%, graphene 1-3% and sepiolite 4-8%.
A kind of production method of environment-friendly and green anion tile, comprises the following steps:
Step 1:Ball mill is added after the raw material of glaze layer is mixed and carries out ball milling, anion glaze slurry is made after sieving;
Step 2:The raw material of ceramic tile blank is mixed evenly, ball mill is added and carries out ball milling, 250 mesh sieves is crossed and forms material Slurry, and is stirred old 2-3 days, the slurry is dried ceramic body powder is made, then old 3 days, using press by powder Base substrate is pressed into, and in 130 DEG C of drying;In a nitrogen atmosphere, 1150-1200 DEG C is sintered into ceramic tile blank to base substrate.
Step 3:The anion glaze slurry glazing is pressed into ceramic body surface, the ceramic body that glazing is finished Type, drying, ooze spend after Ceramic Tiles semi-finished product are made;
Step 4:Ceramic Tiles semi-finished product feeding tunnel cave is burnt till, elder generation is heated for 350-400 DEG C again, in 1280- 40-50 minutes are sintered under 1300 DEG C of nitrogen atmospheres.
Further, the glazing mode of the step 3 uses glaze spraying.
Compared with prior art, the beneficial effects of the invention are as follows:
It is green using the anion tile prepared by a kind of environment-friendly and green anion tile of the present invention and its production method Color safety, has good decoration functions concurrently, realizes the efficient release of anion, possesses nontoxic, ornamental strong and health care work( Energy.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1:
A kind of environment-friendly and green anion tile of the present invention, including ceramic tile blank and glaze layer, according to mass percent, Ceramic tile blank includes sea-gull stone 4%, bentonite 6%, diatomite 6%, zebra stone 4%, shell 6%, black phosphorus 1.5%, graphene 2.5%th, albite 35% and potassium feldspar 35%.
According to mass percent, glaze layer includes negative ion powder 8%, nanometer elbaite powder 6%, zeolite 8%, titanium dioxide Titanium 3.5%, micro-crystal powder 4%, devitrified glass 4%, graphene 1.5%, kaolin 32% and potassium feldspar 33%.
Wherein, medical stone 38%, tourmaline 38%, zirconium oxide 4%, diatom are included according to mass percent, negative ion powder Soil 12%, graphene 2% and sepiolite 6%.
The burst size of black phosphorus and graphene increase anion, and graphene strengthens glaze layer, and it is wear-resisting to improve its Property.
A kind of production method of environment-friendly and green anion tile, comprises the following steps:
Step 1:Ball mill is added after the raw material of glaze layer is mixed and carries out ball milling, anion glaze slurry is made after sieving;
Step 2:The raw material of ceramic tile blank is mixed evenly, ball mill is added and carries out ball milling, 250 mesh sieves is crossed and forms material Slurry, and is stirred old 2-3 days, the slurry is dried ceramic body powder is made, then old 3 days, using press by powder Base substrate is pressed into, and in 130 DEG C of drying;In a nitrogen atmosphere, 1150-1200 DEG C is sintered into ceramic tile blank to base substrate.
Step 3:The anion glaze slurry glazing is pressed into ceramic body surface, the ceramic body that glazing is finished Type, drying, ooze spend after Ceramic Tiles semi-finished product are made, glazing mode uses glaze spraying.
Step 4:Ceramic Tiles semi-finished product feeding tunnel cave is burnt till, elder generation is heated for 350-400 DEG C again, in 1280- 40-50 minutes are sintered under 1300 DEG C of nitrogen atmospheres.
A kind of environmentally friendly anion tile of the present patent application, ceramic surface measure the average release concentration of anion be 1700/ cm3, apart from 1 meter of position of ceramic tile surface, it is 1250/cm to measure the average release concentration of anion3
Embodiment 2:
A kind of environment-friendly and green anion tile of the present invention, including ceramic tile blank and glaze layer, according to mass percent, Ceramic tile blank includes sea-gull stone 3.5%, bentonite 8%, diatomite 7%, zebra stone 3.5%, shell 7%, black phosphorus 1.2%, stone Black alkene 2.8%, albite 31% and potassium feldspar 36%.
According to mass percent, glaze layer includes negative ion powder 9%, nanometer elbaite powder 7%, zeolite 6%, titanium dioxide Titanium 4%, micro-crystal powder 3.5%, devitrified glass 3.5%, graphene 1.2%, kaolin 33.8% and potassium feldspar 32%.
According to mass percent, negative ion powder includes medical stone 36%, tourmaline 36%, zirconium oxide 4.5%, diatomite 14%th, graphene 2.5% and sepiolite 7%.
Finally it should be noted that:The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., the protection of the present invention should be included in Within the scope of.

Claims (6)

  1. A kind of 1. environment-friendly and green anion tile, it is characterised in that:Including ceramic tile blank and glaze layer, the ceramic tile blank includes Sea-gull stone, bentonite, diatomite, zebra stone, shell, black phosphorus, graphene, albite and potassium feldspar, glaze layer include anion Powder, nanometer elbaite powder, zeolite, titanium dioxide, micro-crystal powder, devitrified glass, graphene, kaolin and potassium feldspar.
  2. A kind of 2. environment-friendly and green anion tile according to claim 1, it is characterised in that:It is described according to mass percent Ceramic tile blank includes sea-gull stone 3-5%, bentonite 5-10%, diatomite 5-10%, zebra stone 3-5%, shell 5-8%, black phosphorus 1-2%, graphene 2-3%, albite 30-40% and potassium feldspar 30-40%.
  3. A kind of 3. environment-friendly and green anion tile according to claim 1, it is characterised in that:It is described according to mass percent Glaze layer includes negative ion powder 7-10%, nanometer elbaite powder 5-8%, zeolite 5-10%, titanium dioxide 3-5%, micro-crystal powder 3-5%, devitrified glass 3-5%, graphene 1-2%, kaolin 30-40% and potassium feldspar 30-40%.
  4. 4. according to a kind of any one of claims 1 to 3 environment-friendly and green anion tile, it is characterised in that:According to quality hundred Divide ratio, the negative ion powder includes medical stone 30-40%, tourmaline 30-40%, zirconium oxide 2-5%, diatomite 10-15%, stone Black alkene 1-3% and sepiolite 4-8%.
  5. A kind of 5. production method of environment-friendly and green anion tile according to claim 1, it is characterised in that:Including following step Suddenly:
    Step 1:Ball mill is added after the raw material of glaze layer is mixed and carries out ball milling, anion glaze slurry is made after sieving;
    Step 2:The raw material of ceramic tile blank is mixed evenly, ball mill is added and carries out ball milling, 250 mesh sieves is crossed and forms slurry, And stir old 2-3 days, the slurry is dried ceramic body powder is made, then old 3 days, using press by powder pressing Into base substrate, and in 130 DEG C of drying;In a nitrogen atmosphere, 1150-1200 DEG C is sintered into ceramic tile blank to base substrate.
    Step 3:By the anion glaze slurry glazing in ceramic body surface, ceramic body that glazing is finished is compressing, Dry, ooze spend after Ceramic Tiles semi-finished product are made;
    Step 4:Ceramic Tiles semi-finished product feeding tunnel cave is burnt till, elder generation is heated for 350-400 DEG C again, in 1280-1300 40-50 minutes are sintered under DEG C nitrogen atmosphere.
  6. A kind of 6. production method of environment-friendly and green anion tile according to claim 5, it is characterised in that:
    The glazing mode of the step 3 uses glaze spraying.
CN201710811921.XA 2017-09-11 2017-09-11 A kind of environment-friendly and green anion tile and its production method Pending CN107651951A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108530030A (en) * 2018-04-11 2018-09-14 江西新瑞景陶瓷有限公司 A kind of preparation method of anion glazed ceramic wall tile
CN108558379A (en) * 2018-04-11 2018-09-21 南安市创培电子科技有限公司 A kind of processing method of ceramic tile
CN108675754A (en) * 2018-04-20 2018-10-19 淄博锦昊陶瓷有限公司 Anion titanium brick and its preparation process
CN108751931A (en) * 2018-05-18 2018-11-06 赵顺全 A kind of preparation method of anion brick
CN108794070A (en) * 2018-06-25 2018-11-13 佛山市三水宏源陶瓷企业有限公司 Energy material and preparation method and application, energy ceramic tile and preparation method
CN108793751A (en) * 2018-07-02 2018-11-13 福建省德化祥裕陶瓷文化有限责任公司 A kind of glaze water and preparation method thereof with far infrared activation
CN109265006A (en) * 2018-10-26 2019-01-25 广东能强陶瓷有限公司 A kind of Ceramic Tiles and preparation process capable of releasing negative ion
CN110683866A (en) * 2019-12-10 2020-01-14 广东欧文莱陶瓷有限公司 Ceramic tile with air purifying effect and preparation method thereof
CN111072281A (en) * 2018-12-11 2020-04-28 广东特地陶瓷有限公司 Rare earth doped negative ion ceramic glaze and production method thereof
CN111848121A (en) * 2020-07-30 2020-10-30 福建省德化鲁闽怡家陶瓷文创有限公司 Production process of ceramic containing graphene
CN115745406A (en) * 2022-12-15 2023-03-07 北京旭华时代科技有限公司 Ceramic tile glaze capable of continuously releasing negative oxygen ions as well as preparation method and application thereof

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CN102697351A (en) * 2012-01-12 2012-10-03 上海韬鸿化工科技有限公司 Anion healthy boccaro teapot
CN103253929A (en) * 2012-02-21 2013-08-21 李心红 Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof
CN104829133A (en) * 2015-03-30 2015-08-12 佛山市新战略知识产权文化有限公司 Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze
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CN102697351A (en) * 2012-01-12 2012-10-03 上海韬鸿化工科技有限公司 Anion healthy boccaro teapot
CN103253929A (en) * 2012-02-21 2013-08-21 李心红 Ceramic tile capable of generating negative ions and effectively improving indoor air quality, and production method thereof
CN104829133A (en) * 2015-03-30 2015-08-12 佛山市新战略知识产权文化有限公司 Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108558379B (en) * 2018-04-11 2021-05-18 朔州恒锐达建陶有限公司 Ceramic tile processing method
CN108558379A (en) * 2018-04-11 2018-09-21 南安市创培电子科技有限公司 A kind of processing method of ceramic tile
CN108530030A (en) * 2018-04-11 2018-09-14 江西新瑞景陶瓷有限公司 A kind of preparation method of anion glazed ceramic wall tile
CN108530030B (en) * 2018-04-11 2021-06-29 江西新瑞景陶瓷有限公司 Preparation method of negative ion glazed ceramic tile
CN108675754A (en) * 2018-04-20 2018-10-19 淄博锦昊陶瓷有限公司 Anion titanium brick and its preparation process
CN108751931A (en) * 2018-05-18 2018-11-06 赵顺全 A kind of preparation method of anion brick
CN108794070A (en) * 2018-06-25 2018-11-13 佛山市三水宏源陶瓷企业有限公司 Energy material and preparation method and application, energy ceramic tile and preparation method
CN108793751A (en) * 2018-07-02 2018-11-13 福建省德化祥裕陶瓷文化有限责任公司 A kind of glaze water and preparation method thereof with far infrared activation
CN109265006A (en) * 2018-10-26 2019-01-25 广东能强陶瓷有限公司 A kind of Ceramic Tiles and preparation process capable of releasing negative ion
CN111072281A (en) * 2018-12-11 2020-04-28 广东特地陶瓷有限公司 Rare earth doped negative ion ceramic glaze and production method thereof
CN110683866A (en) * 2019-12-10 2020-01-14 广东欧文莱陶瓷有限公司 Ceramic tile with air purifying effect and preparation method thereof
CN111848121A (en) * 2020-07-30 2020-10-30 福建省德化鲁闽怡家陶瓷文创有限公司 Production process of ceramic containing graphene
CN115745406A (en) * 2022-12-15 2023-03-07 北京旭华时代科技有限公司 Ceramic tile glaze capable of continuously releasing negative oxygen ions as well as preparation method and application thereof
CN115745406B (en) * 2022-12-15 2023-09-08 北京旭华时代科技有限公司 Ceramic tile glaze capable of continuously releasing negative oxygen ions and preparation method and application thereof

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Application publication date: 20180202