CN104829133A - Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze - Google Patents

Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze Download PDF

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Publication number
CN104829133A
CN104829133A CN201510143715.7A CN201510143715A CN104829133A CN 104829133 A CN104829133 A CN 104829133A CN 201510143715 A CN201510143715 A CN 201510143715A CN 104829133 A CN104829133 A CN 104829133A
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China
Prior art keywords
negative ion
glaze
nanometer
ceramic
ion ceramic
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CN201510143715.7A
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Chinese (zh)
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周克芳
麦晓君
刘江峰
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Doshan New Strategy Intellectual Property Culture Co Ltd
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Doshan New Strategy Intellectual Property Culture Co Ltd
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Priority to CN201510143715.7A priority Critical patent/CN104829133A/en
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Abstract

The invention relates to a negative ion ceramic glaze and a method for preparation of a negative ion ceramic brick from the negative ion ceramic glaze, and belongs to the ceramic processing technical field. The negative ion ceramic glaze comprises the following components: kaolin, potassium feldspar, nano titanium dioxide, nano tourmaline powder, nano lithium tourmaline powder, nano magnesium tourmaline powder, praseodymium oxide and water. The above materials are filled into a ball mill for ball milling for 12-58 h, the negative ion ceramic glaze is obtained by deironing and sieving processes, a dried ceramic body is applied with the negative ion ceramic glaze in glaze spraying manner, the glaze thickness is 0.35-0.35 mm, and a negative ion glaze brick with health care and environmental protection functions can be obtained by firing for 2-8 h at 1000-1280 DEG C. The negative ion glaze brick can release negative ions to increase indoor air negative ion concentration, improve sleep, smooth respiration, enhance immunity, normalize blood pressure, purify blood, and so on.

Description

A kind of negative ion ceramic glaze and use it to prepare the method for negative ion ceramic ceramic tile
Technical field
The present invention relates to a kind of ceramic glaze and prepare the method for ceramic tile, be specifically related to a kind of negative ion ceramic glaze and preparation thereof negative ion ceramic ceramic tilemethod, belongs to ceramic processing technique field.
Background technology
When people stroll by the sea, waterfall and forest time, can feel to breathe happy, relaxed and joyful, one of them most important reason is containing abundant negative ion in air.Negative ion can facilitate human body to synthesize and vitamin storage, and the physiological activity of strengthening and human activin, therefore it is called as " air VITAMIN ", and it is as the VITAMIN of food, has very important impact to the vital movement of human body and other biological.After thunderstorm, the negative ion of air increases, and people feel happy.And at air-conditioned room, because negative ion in air almost all disappears after a series of air conditioning purge process and very long ventilator trunk, extended stationary periods can feel uncomfortable in chest, dizzy, weak to people wherein, working efficiency and healthy state declines, and is referred to as " air conditioner comprehensive disease ".In medical circle, it is the effective means having killing pathogenic bacteria and purify air that negative ion is identified.After its mechanism is mainly that negative ion is combined with bacterium, makes bacterium produce the change of structure or the transfer of energy, cause bacterial death, most final decline is sunken to ground.Medical research shows, in air, electronegative particulate makes oxygen level in blood increase, and is conducive to blood Oxygen deliver, absorption and utilization, has promotion human metabolism, improve human immunological competence, strengthens human body flesh energy, regulates the effect of human body function balance.According to textual criticism, negative ion is to human body 7 systems, and nearly 30 various diseases have suppression, alleviate and auxiliary therapeutic action, especially more obvious to the health-care effect of human body.It is mainly manifested in: on neural impact, the impact on cardiovascular systems, the impact on blood system, promote body redox processes, the most obvious on the impact of respiratory system.In addition, negative aeroion also has effect that is calm, hypnosis.If we suck appropriate negative ion every day, persevering, of great advantage to health: to make people full of vitality, Ginseng Extract and burnout, increase work efficiency.Improving water flood, eliminates neurasthenia.Reduce disease incidence, preventing cold and respiratory tract disease.Improve the symptom of Cardial or cerebral vascular diseases.
For environment protection aspect, negative aeroion can eliminate foreign flavor indoors and various obnoxious flavour.Leftovers leftovers acid smell in the irritant gass such as the benzene that the art work used in interior decoration process evaporates, formaldehyde, ketone, ammonia and daily life, the peculiar smell that cigarette etc. are harmful, with the material being rich in negative ion, the negative aeroion of its release can be eliminated effectively, reach the object purified air, and have good restraining effect to golden staphylococci, intestinal bacteria, candidiasis and mould etc.
Chinese invention " a kind of Negative-ion eco-ceramic tile and preparation method thereof ", application number: CN201310389173; Chinese invention " a kind of Anti-static negative-ion eco-ceramic tile and preparation method thereof ", application number: CN201310390730, is all the high temperature resistant rare earth composite material powder added in conventional ceramic glaze containing indium, makes negative ion ceramic glaze.But indium is heavy metal, toxic; To the hazard ratio lead also poison of HUMAN HEALTH, people is allowed to have difficulty in breathing, breathless; Flammable, there is the danger fired.And the abundance of indium in the earth's crust is smaller, as industrialization scale operation, there is no sustainability.
Summary of the invention
The object of this invention is to provide a kind of natural, tasteless, nontoxic, that safety performance is good negative ion ceramic.
In order to solve the problem, the technical solution adopted in the present invention is:
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 15 ~ 55%, potassium felspar sand 15 ~ 35%, nano titanium oxide 5 ~ 10%, nanometer Mg tourmaline powder 5 ~ 15%, nanometer elbaite powder 20 ~ 40%, praseodymium sesquioxide 5 ~ 12%, water: surplus.
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 15 ~ 35%, potassium felspar sand 15 ~ 25%, nano titanium oxide 5 ~ 7%, nanometer Mg tourmaline powder 5 ~ 10%, nanometer elbaite powder 20 ~ 30%, praseodymium sesquioxide 5 ~ 9%, water: surplus.
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 35 ~ 55%, potassium felspar sand 25 ~ 35%, nano titanium oxide 7 ~ 10%, nanometer Mg tourmaline powder 10 ~ 15%, nanometer elbaite powder 30 ~ 40%, praseodymium sesquioxide 9 ~ 12%, water: surplus.
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 25 ~ 45%, potassium felspar sand 20 ~ 30%, nano titanium oxide 6 ~ 9%, nanometer Mg tourmaline powder 7 ~ 12%, nanometer elbaite powder 25 ~ 35%, praseodymium sesquioxide 6 ~ 10%, water: surplus.
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 33%, potassium felspar sand 18%, nano titanium oxide 8%, nanometer Mg tourmaline powder 8%, nanometer elbaite powder 20%, praseodymium sesquioxide 7%, water 6%.
Another object of the present invention is to provide a kind of preparation method of negative ion ceramic ceramic tile, comprises the following steps:
By the formula provided above, raw material is loaded ball milling 12 ~ 58h in ball mill, deironing, sieve, 220 ~ 250 mesh screen residues 0.5% ~ 0.8%, make negative ion ceramic glaze; Give the ceramic body glazing after drying by the mode of glaze spraying, glaze thickness 0.35 ~ 0.55mm, fires 2 ~ 8h at temperature 1000 ~ 1280 DEG C, obtains the negative ion ornamental brick with health care, environment-friendly function.
The invention has the beneficial effects as follows: adopt the negative ion pottery prepared of present method to have anion releasing, decomposing formaldehyde, dispelling abnormal flavor, purify air, health care's five functional.
Embodiment
Be described in further details the present invention below by example, these examples are only used for the present invention is described, do not limit the scope of the invention;
Embodiment 1
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 33%, potassium felspar sand 18%, nano titanium oxide 8%, nanometer Mg tourmaline powder 8%, nanometer elbaite powder 20%, praseodymium sesquioxide 7%, water 6%;
Its preparation method, comprises the following steps:
The raw material mixing prepared is loaded ball milling 12h in ball mill, deironing, sieves, 220 mesh screen residues 0.8%, make negative ion ceramic glaze; Give the ceramic body glazing after drying by the mode of glaze spraying, glaze thickness 0.35mm, fires 8h at temperature 1000 DEG C, obtains the negative ion ornamental brick with health care, environment-friendly function.
Embodiment 2
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 15%, potassium felspar sand 21%, nano titanium oxide 5%, nanometer Mg tourmaline powder 12%, nanometer elbaite powder 28%, praseodymium sesquioxide 12%, water: 7%;
Its preparation method, comprises the following steps:
The raw material for preparing is loaded ball milling 58h in ball mill, deironing, sieves, 250 mesh screen residues 0.5%, make negative ion ceramic glaze; Give the ceramic body glazing after drying by the mode of glaze spraying, glaze thickness 0.55mm, fires 2h at temperature 1280 DEG C, obtains the negative ion ornamental brick with health care, environment-friendly function.
Embodiment 3
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 25%, potassium felspar sand 15%, nano titanium oxide 9%, nanometer Mg tourmaline powder 5%, nanometer elbaite powder 33%, praseodymium sesquioxide 5%, water: 8%;
Its preparation method, comprises the following steps:
The raw material for preparing is loaded ball milling 36h in ball mill, deironing, sieves, 230 mesh screen residues 0.7%, make negative ion ceramic glaze; Give the ceramic body glazing after drying by the mode of glaze spraying, glaze thickness 0.45mm, fires 5h at temperature 1150 DEG C, obtains the negative ion ornamental brick with health care, environment-friendly function.
Embodiment 4
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 27%, potassium felspar sand 20%, nano titanium oxide 6%, nanometer Mg tourmaline powder 7%, nanometer elbaite powder 22%, praseodymium sesquioxide 8%, water: 10%;
Its preparation method, comprises the following steps:
The raw material for preparing is loaded ball milling 24h in ball mill, deironing, sieves, 250 mesh screen residues 0.5%, make negative ion ceramic glaze; Give the ceramic body glazing after drying by the mode of glaze spraying, glaze thickness 0.40mm, fires 4h at temperature 1080 DEG C, obtains the negative ion ornamental brick with health care, environment-friendly function.
Embodiment 5
A kind of negative ion ceramic glaze, is made up of the component of following weight percentage:
Kaolin 16%, potassium felspar sand 27%, nano titanium oxide 7%, nanometer Mg tourmaline powder 6%, nanometer elbaite powder 25%, praseodymium sesquioxide 10%, water: 9%;
Its preparation method, comprises the following steps:
The raw material for preparing is loaded ball milling 45h in ball mill, deironing, sieves, 220 mesh screen residues 0.6%, make negative ion ceramic glaze; Give the ceramic body glazing after drying by the mode of glaze spraying, glaze thickness 0.45mm, fires 6h at temperature 1220 DEG C, obtains the negative ion ornamental brick with health care, environment-friendly function.
The negative ion release of testing example 1-5, result is as following table one.
Table one
As can be seen from table one, the lasting anion releasing of negative ion pottery energy prepared by the present invention, burst size reaches more than 1500/cubic centimetre, and to dispelling obnoxious flavour, Efficient antibacterial is degerming, and the fresh air continued has unusual effect.

Claims (8)

1. a negative ion ceramic glaze, is characterized in that: be made up of the component of following weight percentage:
Kaolin 15 ~ 55%, potassium felspar sand 15 ~ 35%, nano titanium oxide 5 ~ 10%, nanometer Mg tourmaline powder 5 ~ 15%, nanometer elbaite powder 20 ~ 40%, praseodymium sesquioxide 5 ~ 12%, water: surplus.
2. a kind of negative ion ceramic glaze according to claim 1, is characterized in that: be made up of the component of following weight percentage:
Kaolin 15 ~ 35%, potassium felspar sand 15 ~ 25%, nano titanium oxide 5 ~ 7%, nanometer Mg tourmaline powder 5 ~ 10%, nanometer elbaite powder 20 ~ 30%, praseodymium sesquioxide 5 ~ 9%, water: surplus.
3. a kind of negative ion ceramic glaze according to claim 1, is characterized in that: be made up of the component of following weight percentage:
Kaolin 35 ~ 55%, potassium felspar sand 25 ~ 35%, nano titanium oxide 7 ~ 10%, nanometer Mg tourmaline powder 10 ~ 15%, nanometer elbaite powder 30 ~ 40%, praseodymium sesquioxide 9 ~ 12%, water: surplus.
4. a kind of negative ion ceramic glaze according to claim 1, is characterized in that: be made up of the component of following weight percentage:
Kaolin 25 ~ 45%, potassium felspar sand 20 ~ 30%, nano titanium oxide 6 ~ 9%, nanometer Mg tourmaline powder 7 ~ 12%, nanometer elbaite powder 25 ~ 35%, praseodymium sesquioxide 6 ~ 10%, water: surplus.
5. a kind of negative ion ceramic glaze according to claim 4, is characterized in that: be made up of the component of following weight percentage:
Kaolin 33%, potassium felspar sand 18%, nano titanium oxide 8%, nanometer Mg tourmaline powder 8%, nanometer elbaite powder 20%, praseodymium sesquioxide 7%, water 6%.
6. a preparation method for negative ion ceramic ceramic tile, is characterized in that: comprise the following steps:
Kaolin, potassium felspar sand, nano titanium oxide, nanometer Mg tourmaline powder, nanometer elbaite powder, praseodymium sesquioxide, water are mixed and loads ball milling in ball mill, by making glaze after deironing, technique of sieving, execute above-mentioned glaze to the ceramic body after drying by the mode of glaze spraying, glaze thickness 0.35 ~ 0.55mm, at temperature 1000 ~ 1280 DEG C, fire 2 ~ 8h, obtain the negative ion ornamental brick with health care, environment-friendly function.
7. the preparation method of a kind of negative ion ceramic ceramic tile according to claim 6, is characterized in that: the Ball-milling Time of described ball milling is 12 ~ 58h.
8. the preparation method of a kind of negative ion ceramic ceramic tile according to claim 6, is characterized in that: described sieve as 220 ~ 250 mesh screen residues 0.5% ~ 0.8%.
CN201510143715.7A 2015-03-30 2015-03-30 Negative ion ceramic glaze and method for preparation of negative ion ceramic brick from negative ion ceramic glaze Pending CN104829133A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106007664A (en) * 2016-05-26 2016-10-12 淄博成畅建筑陶瓷有限公司 Photocatalytic sterilization self-cleaning ink-jet micro-powder brick and preparation method thereof
CN106396407A (en) * 2016-08-31 2017-02-15 广东金意陶陶瓷有限公司 Mineral crystal fancy glaze capable of releasing negative ions and ceramic tile produced by using mineral crystal fancy glaze
CN107056056A (en) * 2017-05-04 2017-08-18 钦州学院 Explosion-proof frit for porcelain enamel
CN107288293A (en) * 2017-06-21 2017-10-24 信益陶瓷(中国)有限公司 A kind of negative ion health ceramic tile
CN107651951A (en) * 2017-09-11 2018-02-02 佛山市高明区新粤丰建材有限公司 A kind of environment-friendly and green anion tile and its production method
CN108530030A (en) * 2018-04-11 2018-09-14 江西新瑞景陶瓷有限公司 A kind of preparation method of anion glazed ceramic wall tile
CN108558209A (en) * 2018-06-29 2018-09-21 福建省德化县福德丰陶瓷有限公司 A kind of green, antibacterial glaze water and preparation method thereof
CN108675754A (en) * 2018-04-20 2018-10-19 淄博锦昊陶瓷有限公司 Anion titanium brick and its preparation process
CN108689605A (en) * 2018-06-29 2018-10-23 佛山石湾鹰牌陶瓷有限公司 The preparation method of far infrared ceramic tile
CN108689604A (en) * 2018-06-29 2018-10-23 佛山石湾鹰牌陶瓷有限公司 The preparation method of far infrared ceramic tile
CN108706882A (en) * 2018-06-29 2018-10-26 佛山石湾鹰牌陶瓷有限公司 Far infrared ceramic tile
CN108793751A (en) * 2018-07-02 2018-11-13 福建省德化祥裕陶瓷文化有限责任公司 A kind of glaze water and preparation method thereof with far infrared activation
CN108821585A (en) * 2018-09-12 2018-11-16 德化恒瀚艺品有限公司 A kind of ceramics modified verdelite anion glaze and its preparation method and application
CN108911788A (en) * 2018-07-24 2018-11-30 信阳市上天梯非金属矿管理区非金属矿技术开发应用研究所 With the function ceramics brick and preparation method thereof that can excite releasing negative oxygen ion surface layer
CN109095910A (en) * 2018-08-31 2018-12-28 湖北省当阳豪山建材有限公司 Anion environmental protection self-cleaning ceramic tile and preparation method thereof
CN109384453A (en) * 2018-11-05 2019-02-26 福建省德化县合和陶瓷技术开发有限公司 A kind of domestic ceramics of low temperature moulding and preparation method thereof

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CN1985603A (en) * 2005-12-19 2007-06-27 深圳市海川实业股份有限公司 Inorganic disinfectant and its preparing method
CN102276293A (en) * 2011-06-20 2011-12-14 华北水利水电学院 Kieselguhr-based environmentally-friendly glaze material for inner wall brick and inner wall brick prepared by utilizing same

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CN1566218A (en) * 2003-06-19 2005-01-19 北京立高高新技术研究所 Functional filler and its preparing process
CN1478755A (en) * 2003-06-24 2004-03-03 北京天之岩健康科技有限公司 Negative ion air purifying material and its preparation method
CN1587186A (en) * 2004-09-03 2005-03-02 佛山欧神诺陶瓷有限公司 Method for producing health ceramic brick capable of releasing negative ion
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106007664B (en) * 2016-05-26 2019-03-22 淄博成畅建筑陶瓷有限公司 Photo-catalyst self-cleaning ink-jet micro-powder brick and preparation method thereof
CN106007664A (en) * 2016-05-26 2016-10-12 淄博成畅建筑陶瓷有限公司 Photocatalytic sterilization self-cleaning ink-jet micro-powder brick and preparation method thereof
CN106396407A (en) * 2016-08-31 2017-02-15 广东金意陶陶瓷有限公司 Mineral crystal fancy glaze capable of releasing negative ions and ceramic tile produced by using mineral crystal fancy glaze
CN107056056A (en) * 2017-05-04 2017-08-18 钦州学院 Explosion-proof frit for porcelain enamel
CN107288293A (en) * 2017-06-21 2017-10-24 信益陶瓷(中国)有限公司 A kind of negative ion health ceramic tile
CN107651951A (en) * 2017-09-11 2018-02-02 佛山市高明区新粤丰建材有限公司 A kind of environment-friendly and green anion tile and its production method
CN108530030A (en) * 2018-04-11 2018-09-14 江西新瑞景陶瓷有限公司 A kind of preparation method of anion glazed ceramic wall tile
CN108530030B (en) * 2018-04-11 2021-06-29 江西新瑞景陶瓷有限公司 Preparation method of negative ion glazed ceramic tile
CN108675754A (en) * 2018-04-20 2018-10-19 淄博锦昊陶瓷有限公司 Anion titanium brick and its preparation process
CN108689605A (en) * 2018-06-29 2018-10-23 佛山石湾鹰牌陶瓷有限公司 The preparation method of far infrared ceramic tile
CN108706882A (en) * 2018-06-29 2018-10-26 佛山石湾鹰牌陶瓷有限公司 Far infrared ceramic tile
CN108689604A (en) * 2018-06-29 2018-10-23 佛山石湾鹰牌陶瓷有限公司 The preparation method of far infrared ceramic tile
CN108558209A (en) * 2018-06-29 2018-09-21 福建省德化县福德丰陶瓷有限公司 A kind of green, antibacterial glaze water and preparation method thereof
CN108793751A (en) * 2018-07-02 2018-11-13 福建省德化祥裕陶瓷文化有限责任公司 A kind of glaze water and preparation method thereof with far infrared activation
CN108911788A (en) * 2018-07-24 2018-11-30 信阳市上天梯非金属矿管理区非金属矿技术开发应用研究所 With the function ceramics brick and preparation method thereof that can excite releasing negative oxygen ion surface layer
CN109095910A (en) * 2018-08-31 2018-12-28 湖北省当阳豪山建材有限公司 Anion environmental protection self-cleaning ceramic tile and preparation method thereof
CN108821585A (en) * 2018-09-12 2018-11-16 德化恒瀚艺品有限公司 A kind of ceramics modified verdelite anion glaze and its preparation method and application
CN109384453A (en) * 2018-11-05 2019-02-26 福建省德化县合和陶瓷技术开发有限公司 A kind of domestic ceramics of low temperature moulding and preparation method thereof

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