CN104129996B - Negative ion easily cleaning function ceramic additive, its preparation method and the pottery of preparation thereof and the preparation method of pottery - Google Patents
Negative ion easily cleaning function ceramic additive, its preparation method and the pottery of preparation thereof and the preparation method of pottery Download PDFInfo
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Abstract
The invention belongs to ceramic technology field, be specifically related to a kind of negative ion easily cleaning function ceramic additive, its preparation method and the pottery of preparation thereof and the preparation method of pottery.Described additive is made up of the raw material of following mass percent: extra large aragonite 5-15%, the nano titanium oxide 8-12% of tourmalinite 16-25%, 5-20 micron of Chong Guang stone 10-16%, 5-15 micron of 5-20 micron, nano zine oxide 6-8%, lead free soldering 5-10%, rare earth material 7-20%, ultra-fine alumina 8-10%, ultrafine quartz powder 8-15% and sodium carbonate 5-10%.Its preparation method is first by lead free soldering, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling, add Chong Guangshi, tourmalinite, extra large aragonite, nano titanium oxide and nano zine oxide ball milling again, obtain the additive of particle diameter 1-10 micron.Additive of the present invention has self poling performance, has stronger adsorption and dissociation effect, thus produces negative ion; Above-mentioned additive added to after in pottery, pottery very easily cleans, do not hide dirt and do not stain, have very strong avidity to water.
Description
Technical field
The invention belongs to ceramic technology field, be specifically related to a kind of negative ion easily cleaning function ceramic additive, its preparation method and the pottery of preparation thereof and the preparation method of pottery.
Background technology
Current, the product that indoor environment and the mankind eat and water class are polluted and are aggravated gradually, and its principal pollutant are formaldehyde, plumbous, cadmium, mercury, the harmful chemicals such as prussiate.People live in such contaminate environment for a long time, contact the food polluted, very large to body harm, usually can bring out various disease.Simultaneously, the use of various liquid detergent also can cause groundwater pollution and endanger the healthy of the mankind, relevant data shows, the usage quantity of the annual liquid detergent of China is between 300,000 tons to 400,000 tons, although liquid detergent is nontoxic in theory, but some harmful material monomer can be absorbed by the body in body by skin Digestive tract, when these objectionable impuritiess acquire a certain degree in human body, will endanger healthy.The positively charged ion contained inside liquid detergent, anion surfactant, can remove the oiliness protective layer of skin surface, and then corrosion skin; The activity of the chemicals mass-energy inhibited oxidation enzymes such as the alkylsulfonate inside liquid detergent, causes the melanochrome in skin become black from colourless and occurred a large amount of butterfly spot; Can damage lymphsystem after some chemical substance enters human body causes resistance of human body to decline etc.
Therefore, research make a kind of can environmental protect and food contamination, improve water quality and activated water, and the ceramic with easy clean anti-pollution function is imperative.Any chemical substance or liquid detergent just ceramic need not can be rinsed well like this, both eliminate the chemical pollution of food, activated water, again can water saving, eliminate the pollution that various chemical substance causes environment and human body.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of negative ion easily cleaning function ceramic additive having electric self poling performance, can produce negative ion under light conditions, invention also provides the preparation method of the preparation method of additive and the pottery of preparation and pottery.
Negative ion easily cleaning function ceramic additive of the present invention, be made up of the raw material of following mass percent:
Extra large aragonite 5-15%, the nano titanium oxide 8-12% of tourmalinite 16-25%, 5-20 micron of Chong Guang stone 10-16%, 5-15 micron of 5-20 micron, nano zine oxide 6-8%, lead free soldering 5-10%, rare earth material 7-20%, ultra-fine alumina 8-10%, ultrafine quartz powder 8-15% and sodium carbonate 5-10%.
Wherein, preferred technical scheme is as follows:
Described rare earth material is cerous nitrate and/or Neodymium trioxide; Rare earth material be cerous nitrate and Neodymium trioxide time, in additive total mass 100%, the content of cerous nitrate is 4-10wt.%.
The raw material of the preferred following mass percent of described lead free soldering is made according to following steps:
By feldspar 30%, quartz 9%, calcium carbonate 6%, reason pyroxene 10%, ripe talcum 9%, sodium carbonate 13%, zinc oxide 10%, barium carbonate 5%, ripe same soil 8%, mixing, is sized to 10 order-20 orders, in 1560-1580 DEG C of fusing, be milled to 250-300 order after shrend, dry obtained.
The preparation method of described negative ion easily cleaning function ceramic additive is first by lead free soldering, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling 8-10 hour, add the tourmalinite of Chong Guangshi, 5-15 micron of 5-20 micron, the extra large aragonite of 5-20 micron, nano titanium oxide and nano zine oxide ball milling 8-10 hour again, obtain the negative ion easily cleaning function ceramic additive of particle diameter 1-10 micron.
Described negative ion easily cleaning function ceramic additive can add in ceramic raw material makes pottery, and described pottery comprises idiosome and glaze,
Idiosome additional negative ion easily cleaning function ceramic additive, in the raw materials used total mass 100% of idiosome, additive amount accounts for the 5-10% of the raw materials used total mass of idiosome;
Glaze additional negative ion easily cleaning function ceramic additive, in the raw materials used total mass 100% of glaze, additive amount accounts for the 5-10% of the raw materials used total mass of glaze.
Wherein, idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 43-45%, feldspar 10-12%, quartzy 5-7%, hard kaoline 35-38% and soft clay 3-5%;
Glaze: feldspar 20-25%, quartzy 23-26%, boric acid 10-13%, borax 12-15%, aluminium hydroxide 4-6%, ripe talcum 5-7%, barium carbonate 4-6%, zinc oxide 8-10%, Strontium carbonate powder 6-9% and Quilonum Retard 1-3%.
Idiosome and the glaze further preferred raw material by following mass percent are made:
Idiosome: bone meal 43%, feldspar 12%, quartz 7%, hard kaoline 35% and soft clay 3%;
Glaze: feldspar 21%, quartz 23%, boric acid 11%, borax 13%, aluminium hydroxide 5%, ripe talcum 6%, barium carbonate 5%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 2%.
Base substrate is with Ca
3(PO
4)
2, SiO
2and AL
2o
3for the high-grade carcass of main body, can also additional mud adjusting agent in idiosome, mud adjusting agent comprise in water glass, ground caustic, Mierocrystalline cellulose one or more, in the raw materials used total mass 100% of idiosome, the consumption of mud adjusting agent is 0.01-0.4%.
The preparation method of described pottery, comprises the following steps:
(1) prepare burden: get out raw material according to the formula ratio of idiosome, glaze, negative ion easily cleaning function ceramic additive;
(2) idiosome materials preparation: by raw materials used for idiosome mix with negative ion easily cleaning function ceramic additive after, load ball mill and carry out 70-75 hour ball milling, be milled to fineness of materials to reach 200 mesh sieves and all pass through, and then by levigate material by 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of releasing passes through mud press, make the mud cake that water ratio is 23-26wt.%, mud cake stirs mud machine by vacuum, stir mud 2-3 time continuously, airtight placement 5-7 days, for subsequent use afterwards;
(3) glaze materials preparation: after raw materials used for glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, drying; Add negative ion easily cleaning function ceramic additive inside glaze after, load ball mill and carry out 75-80 hour ball milling, be milled to fineness of materials to reach 250 mesh sieves and all pass through, test glaze slip proportion is between 1.85-1.90, and then by levigate material by 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use;
The scope of glaze slip proportion is between 1.85-1.90, if proportion is less than normal a little, unnecessary water is gradually released after then needing glaze slip to place precipitation, if proportion is bigger than normal a little, then need gradually to add water until proportion reaches within rational scope, generally, as long as when filling with substance controls add-on in strict accordance with the weight ratio of material and water, the glaze slip proportion after ground does not need adjustment substantially within zone of reasonableness.
(4) burn till: adopt two step calcining systems,
The first step, burning till of base substrate:
After step (2) idiosome materials are made idiosome, first carry out biscuiting, firing temperature 1270-1310 DEG C, firing time 20-30h;
Second step, burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, firing temperature 1130-1190 DEG C, firing time 10-15 h.
Product after glaze firing can also carry out decal paper, after decal paper, needs to burn till, firing temperature 1100-1150 DEG C, firing time 6-8 hour again.
Described base substrate thin and light, permeability is strong, thermostability is strong, glaze is the high brightness glaze of lead-free and cadmium-free, and glaze paint is bright and clean as beautiful, and transparency is high, and whiteness is good.
Described negative ion ceramic products lives through after three high temperature burn till, and its picture immerses in glaze paint completely, has fundamentally stopped the color of marble paper and other materials as stripping that is plumbous, cadmium, has faded never.
The present invention's raw material used is commercially available prod.Wherein the particle diameter of ultra-fine alumina, ultrafine quartz powder is 100 ± 10 nanometers.
Compared with prior art, beneficial effect of the present invention is as follows:
Negative ion easily cleaning function ceramic additive of the present invention is a kind of novel functional materials, and described additive is the ring texture silicate minerals of aluminium based on boracic, sodium, iron, magnesium, lithium, and allotment simultaneously has cerous nitrate, the rare-earth-type material such as Neodymium trioxide.In its materials, Chong Guangshi is the rare precious ore of one that is produced from locality, Zibo, and its formation has 200,000,000 years apart from the present, and the negative ion burst size detecting Chong Guang stone flour body through national authority mechanism is very high.Tourmalinite and Chong Guangshi have similar mineral structure, are a kind of silicates mineral, have the function producing negative ion equally.Sea aragonite belongs to a kind of sodium calcium stone, also containing iron, copper, vanadium etc., itself has the function melting release, releives, and stablizes the mood of human body and regulates the energy of human body arteries and veins wheel.Rationally the composition of composite three kinds of ores, makes it to influence each other, synergy.Tourmalinite and Chong Guangshi belong to trigonal system in mineral, its cross section is the trilateral of band circular arc, but its two kinds of leg-of-mutton size and shapes are also different, and extra large aragonite belongs to triclinic(crystalline)system in mineral, crystal is shown as prismatic tabular body, above three kinds of mineral are when their single existence, the potential difference that the change of pressure or temperature produces is single, and in three kinds of simultaneous situations of mineral, different lattices can under pressure or the vicissitudinous situation of temperature, the potential difference produced complements each other, discharge maximum electronics, and then maximizedly have influence on its contiguous air or water molecules forms more negative ion, the vibration of ore lattice and electric polarity can not disappear in time, therefore anion releasing is lasting, permanent.Lead free soldering is a kind of is the combination of a lot of mineral and chemical material not containing the fusing assistant of any heavy metal such as lead, cadmium etc., and the inside is containing a large amount of alkali and alkaline earth metal ions simultaneously, can reduce the surface tension of Ceramic glaze; Aluminum oxide, quartz is the framework ingredient in ceramic product, by the rational allocation with lead free soldering and zinc oxide, in the scope temperature of fusion of powder being reached match with ceramic firing temperature, when being added in pottery by this additive, the surface tension of Ceramic glaze can be put forward simultaneously.Nano-titanium oxide has extraordinary opaque effect, then under coordinating the katalysis with rare-earth substance cerium oxide or cerous nitrate, Ceramic glaze can produce very strong hydrophilic, hate effect of oil.Under the interaction of above-mentioned various raw material, the glaze paint of ceramic product, will have permanent oily dirt free, the characteristic of very easily cleaning.
In addition, negative ion easily cleaning function ceramic additive has certain purification energy, cell actification to blood, can strengthen the resistibility of human body, can also remove various peculiar smell, has stronger adsorption and dissociation effect.Negative ion easily cleaning function ceramic additive self has electromagnetic field, has self poling performance.When temperature and pressure has subtle change, can make between ore crystal, to produce potential difference (voltage).This energy can impel water molecules in ambient air to ionize, what detach is electronically attached to contiguous water and oxygen molecule, make them be converted into negative ion in air, the hazardous organic molecules such as catalytic decomposition formaldehyde, promote the sedimentation of suspended substance in air, thus purify air; This additive is added in pottery and makes ceramic product, and through the water of ceramic product process, not only can increase the several mineral materials that needed by human body is wanted, and it is active that water intermediate ion is changed, can regulating water quality; Simultaneously, because polluting caused microtoxicity material as mercury, cadmium, phthalic acid ester, prussiate, chlorine and multiple unwanted bacteria in energy planar water, regulate the pH value of water to neutral or weakly alkaline, there is the effect of activated water molecule, thus water is become clean active mineral water.This pottery has the function of sustained release negative ion and far infrared rays, has activated water, removes peculiar smell, very easily cleans (not needing liquid detergent), antibacterial healthy functions such as grade.
After testing, the negative ion concentration that pottery of the present invention discharges is far longer than the burst size under conventional ceramic equal conditions, and its burst size is 500-600/cubic centimetre.Use the water quality after pottery, its mouthfeel obviously changes.In addition, because Ceramic glaze contains higher alkaline metal ions, titanium oxide, cerium oxide, very strong avidity is had to water, significantly hate oil, compared with conventional ceramic, the negative ion ceramic porcelain products after being stained with oil, very easily clean, do not need liquid detergent, do not hide dirt and do not stain, only rinse can remove greasy dirt with water.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
In embodiment, lead free soldering is made up according to following steps of the raw material of following mass percent:
By feldspar 30%, quartz 9%, calcium carbonate 6%, reason pyroxene 10%, ripe talcum 9%, sodium carbonate 13%, zinc oxide 10%, barium carbonate 5%, ripe same soil 8%, mixing, is sized to 10 order-20 orders, in 1560-1580 DEG C of fusing, be milled to 250-300 order after shrend, dry obtained.
Embodiment 1
Negative ion easily cleaning function ceramic additive of the present invention, be made up of the raw material of following mass percent:
The extra large aragonite 12% of the Chong Guang stone 16% of 5-20 micron, the tourmalinite 19% of 5-15 micron, 5-20 micron, nano titanium oxide 8%, nano zine oxide 6%, lead free soldering 6%, cerous nitrate 8%, ultra-fine alumina 9%, ultrafine quartz powder 11% and sodium carbonate 5%.
Preparation method is first by lead free soldering, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling 9 hours, add the tourmalinite of Chong Guangshi, 5-15 micron of 5-20 micron, the extra large aragonite of 5-20 micron, nano titanium oxide and nano zine oxide ball milling again 9 hours, obtain the negative ion easily cleaning function ceramic additive of particle diameter 1-10 micron.
Embodiment 2
Negative ion easily cleaning function ceramic additive of the present invention, be made up of the raw material of following mass percent:
The extra large aragonite 10% of the Chong Guang stone 10% of 5-20 micron, the tourmalinite 25% of 5-15 micron, 5-20 micron, nano titanium oxide 8%, nano zine oxide 6%, lead free soldering 5%, Neodymium trioxide 10%, ultra-fine alumina 8%, ultrafine quartz powder 12% and sodium carbonate 6%.
Preparation method is with embodiment 1.
Embodiment 3
Negative ion easily cleaning function ceramic additive of the present invention, be made up of the raw material of following mass percent:
The extra large aragonite 5% of the Chong Guang stone 12% of 5-20 micron, the tourmalinite 23% of 5-15 micron, 5-20 micron, nano titanium oxide 10%, nano zine oxide 7%, lead free soldering 5%, cerous nitrate 4%, Neodymium trioxide 5%, ultra-fine alumina 9%, ultrafine quartz powder 13% and sodium carbonate 7%.
Preparation method is with embodiment 1.
Embodiment 4
Negative ion easily cleaning function ceramic additive of the present invention, be made up of the raw material of following mass percent:
The extra large aragonite 8% of the Chong Guang stone 10% of 5-20 micron, the tourmalinite 25% of 5-15 micron, 5-20 micron, nano titanium oxide 10%, nano zine oxide 7%, lead free soldering 5%, cerous nitrate 6%, Neodymium trioxide 3%, ultra-fine alumina 10%, ultrafine quartz powder 8% and sodium carbonate 8%.
Preparation method is with embodiment 1.
Embodiment 5
Negative ion easily cleaning function ceramic additive of the present invention, be made up of the raw material of following mass percent:
The extra large aragonite 11% of the Chong Guang stone 12% of 5-20 micron, the tourmalinite 18% of 5-15 micron, 5-20 micron, nano titanium oxide 10%, nano zine oxide 6%, lead free soldering 7%, cerous nitrate 8%, ultra-fine alumina 9%, ultrafine quartz powder 14% and sodium carbonate 5%.
Embodiment 6
The pottery of interpolation negative ion easily cleaning function ceramic additive of the present invention, comprise idiosome and glaze, idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 43%, feldspar 12%, quartz 7%, hard kaoline 35% and soft clay 3%; Negative ion easily cleaning function ceramic additive prepared by additional 5% embodiment 1.
Glaze: feldspar 21%, quartz 23%, boric acid 11%, borax 13%, aluminium hydroxide 5%, ripe talcum 6%, barium carbonate 5%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 2%; Negative ion easily cleaning function ceramic additive prepared by additional 8% embodiment 1.
The preparation method of described pottery, comprises the following steps:
(1) prepare burden: get out raw material according to the formula ratio of idiosome, glaze, negative ion easily cleaning function ceramic additive;
(2) idiosome materials preparation: by raw materials used for idiosome mix with negative ion easily cleaning function ceramic additive after, load ball mill and carry out 75 hours ball millings, be milled to fineness of materials to reach 200 mesh sieves and all pass through, and then by levigate material by 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of releasing passes through mud press, make the mud cake that water ratio is 25wt.%, mud cake stirs mud machine by vacuum, stirs mud continuously 3 times, airtight placement afterwards 7 days, for subsequent use; During ball milling, material, water, ballstone three mass ratio are 1:1:2;
(3) glaze materials preparation: after raw materials used for glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, drying; Add negative ion easily cleaning function ceramic additive inside glaze after, load ball mill and carry out 75 hours ball millings, be milled to fineness of materials to reach 250 mesh sieves and all pass through, test glaze slip proportion is 1.86, and then by levigate material by 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use; During ball milling, material, water, ballstone three mass ratio are 1:0.33:2;
(4) burn till:
The first step, burning till of base substrate:
After step (2) idiosome materials are made idiosome, first carry out biscuiting, firing temperature 1300 DEG C, firing time 25h;
Second step, burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, firing temperature 1150 DEG C, firing time 12 h.
Embodiment 7
The pottery of interpolation negative ion easily cleaning function ceramic additive of the present invention, comprise idiosome and glaze, idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 45%, feldspar 11%, quartz 6%, hard kaoline 35% and soft clay 3%; Negative ion easily cleaning function ceramic additive prepared by additional 8% embodiment 2.
Glaze: feldspar 25%, quartz 24%, boric acid 10%, borax 12%, aluminium hydroxide 4%, ripe talcum 5%, barium carbonate 4%, zinc oxide 9%, Strontium carbonate powder 6% and Quilonum Retard 1%; Negative ion easily cleaning function ceramic additive prepared by additional 10% embodiment 2.
The preparation method of described pottery, comprises the following steps:
(1) prepare burden: get out raw material according to the formula ratio of idiosome, glaze, negative ion easily cleaning function ceramic additive;
(2) idiosome materials preparation: by raw materials used for idiosome mix with negative ion easily cleaning function ceramic additive after, load ball mill and carry out 70 hours ball millings, be milled to fineness of materials to reach 200 mesh sieves and all pass through, and then by levigate material by 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of releasing passes through mud press, make the mud cake that water ratio is 26wt.%, mud cake stirs mud machine by vacuum, stirs mud continuously 3 times, airtight placement afterwards 6 days, for subsequent use; During ball milling, material, water, ballstone three mass ratio are 1:1:2;
(3) glaze materials preparation: after raw materials used for glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, drying; Add negative ion easily cleaning function ceramic additive inside glaze after, load ball mill and carry out 78 hours ball millings, be milled to fineness of materials to reach 250 mesh sieves and all pass through, test glaze slip proportion is 1.88, and then by levigate material by 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use; During ball milling, material, water, ballstone three mass ratio are 1:0.35:2;
(4) burn till:
The first step, burning till of base substrate:
After step (2) idiosome materials are made idiosome, first carry out biscuiting, firing temperature 1280 DEG C, firing time 22h;
Second step, burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, firing temperature 1180 DEG C, firing time 10 h.
Embodiment 8
The pottery of interpolation negative ion easily cleaning function ceramic additive of the present invention, comprise idiosome and glaze, idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 44%, feldspar 10%, quartz 5%, hard kaoline 37% and soft clay 4%; Negative ion easily cleaning function ceramic additive prepared by additional 10% embodiment 3.
Glaze: feldspar 23%, quartz 25%, boric acid 10%, borax 14%, aluminium hydroxide 4%, ripe talcum 5%, barium carbonate 4%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 1%; Negative ion easily cleaning function ceramic additive prepared by additional 8% embodiment 3.
Preparation method, as embodiment 6, just by after the product decal paper after glaze firing, burns till, firing temperature 1130 DEG C, firing time 7 hours.
Ceramic product prepared by embodiment 6-8, test according to following:
The ceramic product of embodiment 6: use anion test instrument COM-3010PRO to test at surface of ceramic products, after requiring that tester is placed in ceramic surface upper 20 second, read observed value, test eight times altogether, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is 513,543,564,509,567,512,523,549, and mean value is: 535ion/cc (individual/cubic centimetre).
The ceramic product of embodiment 7: use anion test instrument COM-3010PRO to test at surface of ceramic products, after requiring that tester is placed in ceramic surface upper 20 second, read observed value, test eight times altogether, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 544,545,565,510,533,576,529,527, and mean value is: 541ion/cc (individual/cubic centimetre).
The ceramic product of embodiment 8: use anion test instrument COM-3010PRO to test at surface of ceramic products, after requiring that tester is placed in ceramic surface upper 20 second, read observed value, test eight times altogether, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is 555,546,576,529,538,540,566,539, and mean value is: 549ion/cc (individual/cubic centimetre).
Comparative example 1
Chong Guangshi in embodiment 1 and extra large aragonite are all replaced with tourmalinite, and preparation method, as embodiment 1, after preparing additive, then prepares pottery according to embodiment 6, and tests according to following:
Use anion test instrument COM-3010PRO to test at surface of ceramic products, after requiring that tester is placed in ceramic surface upper 20 second, read observed value, test eight times altogether, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 213,198,265,176,301,209,198,199, and mean value is: 220ion/cc (individual/cubic centimetre).
Comparative example 2
Chong Guangshi in embodiment 1 is all replaced with tourmalinite, and preparation method, as embodiment 1, after preparing additive, then prepares pottery according to embodiment 6, and tests according to following:
Use anion test instrument COM-3010PRO to test at surface of ceramic products, after requiring that tester is placed in ceramic surface upper 20 second, read observed value, test eight times altogether, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 312,356,298,333,367,289,359,342, and mean value is: 332ion/cc (individual/cubic centimetre).
Comparative example 3
Extra large aragonite in embodiment 1 is all replaced with tourmalinite, and preparation method, as embodiment 1, after preparing additive, then prepares pottery according to embodiment 6, and tests according to following:
Use anion test instrument COM-3010PRO to test at surface of ceramic products, after requiring that tester is placed in ceramic surface upper 20 second, read observed value, test eight times altogether, get its mean value, be the observed value of ceramic surface anion releasing.Observed value is: 358,367,296,337,376,341,310,376, and mean value is: 345ion/cc (individual/cubic centimetre).
Claims (8)
1. a negative ion easily cleaning function ceramic additive, is characterized in that being made up of the raw material of following mass percent:
The extra large line stone 5-15% of tourmalinite 16-25%, 5-20 micron of Chong Guang stone 10-16%, 5-15 micron of 5-20 micron, nano titanium oxide 8-12%, nano zine oxide 6-8%, lead free soldering 5-10%, rare earth material 7-20%, ultra-fine alumina 8-10%, ultrafine quartz powder 8-15% and sodium carbonate 5-10%;
Rare earth material is cerous nitrate and/or Neodymium trioxide; Rare earth material be cerous nitrate and Neodymium trioxide time, in additive total mass 100%, the content of cerous nitrate is 4-10wt.%;
Lead free soldering is made up according to following steps of the raw material of following mass percent:
By feldspar 30%, quartz 9%, calcium carbonate 6%, triphane 10%, ripe talcum 9%, sodium carbonate 13%, zinc oxide 10%, barium carbonate 5%, ripe same soil 8%, mixing, is sized to 10 order-20 orders, in 1560-1580 DEG C of fusing, be milled to 250-300 orders after shrend, dry obtained.
2. the preparation method of a negative ion easily cleaning function ceramic additive according to claim 1, it is characterized in that: first by lead free soldering, rare earth material, ultra-fine alumina, ultrafine quartz powder and sodium carbonate mixing and ball milling 8-10 hour, add the tourmalinite of Chong Guangshi, 5-15 micron of 5-20 micron, the extra large line stone of 5-20 micron, nano titanium oxide and nano zine oxide ball milling 8-10 hour again, obtain the negative ion easily cleaning function ceramic additive of particle diameter 1-10 micron.
3. add a pottery for negative ion easily cleaning function ceramic additive according to claim 1, comprise idiosome and glaze, it is characterized in that:
Idiosome additional negative ion easily cleaning function ceramic additive, in the raw materials used total mass 100% of idiosome, additive amount accounts for the 5-10% of the raw materials used total mass of idiosome;
Glaze additional negative ion easily cleaning function ceramic additive, in the raw materials used total mass 100% of glaze, additive amount accounts for the 5-10% of the raw materials used total mass of glaze.
4. pottery according to claim 3, is characterized in that idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 43-45%, feldspar 10-12%, quartzy 5-7%, hard kaoline 35-38% and soft clay 3-5%;
Glaze: feldspar 20-25%, quartzy 23-26%, boric acid 10-13%, borax 12-15%, aluminium hydroxide 4-6%, ripe talcum 5-7%, barium carbonate 4-6%, zinc oxide 8-10%, Strontium carbonate powder 6-9% and Quilonum Retard 1-3%.
5. pottery according to claim 4, is characterized in that idiosome and glaze are made up of the raw material of following mass percent:
Idiosome: bone meal 43%, feldspar 12%, quartz 7%, hard kaoline 35% and soft clay 3%;
Glaze: feldspar 21%, quartz 23%, boric acid 11%, borax 13%, aluminium hydroxide 5%, ripe talcum 6%, barium carbonate 5%, zinc oxide 8%, Strontium carbonate powder 6% and Quilonum Retard 2%.
6. pottery according to claim 3, it is characterized in that: additional mud adjusting agent in idiosome, mud adjusting agent comprise in water glass, ground caustic, Mierocrystalline cellulose one or more, in the raw materials used total mass 100% of idiosome, the consumption of mud adjusting agent is 0.01-0.4%.
7. a preparation method for pottery described in claim 3, is characterized in that comprising the following steps:
(1) prepare burden: get out raw material according to the formula ratio of idiosome, glaze, negative ion easily cleaning function ceramic additive;
(2) idiosome materials preparation: by raw materials used for idiosome mix with negative ion easily cleaning function ceramic additive after, load ball mill and carry out 70-75 hour ball milling, be milled to fineness of materials to reach 200 mesh sieves and all pass through, and then by levigate material by 200 mesh sieve blowings, 200 mesh sieve tops arrange iron removing stick and carry out deironing, the material of releasing passes through mud press, make the mud cake that water ratio is 23-26wt.%, mud cake stirs mud machine by vacuum, stirs mud 2-3 time continuously, airtight placement 5-7 days, for subsequent use afterwards;
(3) glaze materials preparation: after raw materials used for glaze mixing, be milled to 10-20 order, in 1560-1580 DEG C of fusing, then carry out shrend, drying; Add negative ion easily cleaning function ceramic additive inside glaze after, load ball mill and carry out 75-80 hour ball milling, be milled to fineness of materials to reach 250 mesh sieves and all pass through, test glaze slip proportion is between 1.85-1.90, and then by levigate material by 250 mesh sieve blowings, 250 mesh sieve tops arrange iron removing stick and carry out deironing, for subsequent use;
(4) burn till:
The first step, burning till of base substrate:
After step (2) idiosome materials are made idiosome, first carry out biscuiting, firing temperature 1270-1310 DEG C, firing time 20-30h;
Second step, burning till of glazed body:
By the product glazing after biscuiting, then carry out glaze firing, firing temperature 1130-1190 DEG C, firing time 10-15 h.
8. preparation method ceramic according to claim 7, is characterized in that: after the product decal paper after glaze firing, burn till, firing temperature 1100-1150 DEG C, firing time 6-8 hour.
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