CN107056052B - A kind of high additive ferrochrome waste residue brown ceramic glaze and its application method - Google Patents
A kind of high additive ferrochrome waste residue brown ceramic glaze and its application method Download PDFInfo
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- CN107056052B CN107056052B CN201710360396.4A CN201710360396A CN107056052B CN 107056052 B CN107056052 B CN 107056052B CN 201710360396 A CN201710360396 A CN 201710360396A CN 107056052 B CN107056052 B CN 107056052B
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- 229910000604 Ferrochrome Inorganic materials 0.000 title claims abstract description 54
- 239000002699 waste material Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 30
- 239000000919 ceramic Substances 0.000 title claims abstract description 25
- 239000000654 additive Substances 0.000 title claims abstract description 21
- 230000000996 additive effect Effects 0.000 title claims abstract description 21
- 238000000227 grinding Methods 0.000 claims abstract description 22
- 238000001354 calcination Methods 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052656 albite Inorganic materials 0.000 claims abstract description 9
- 239000010453 quartz Substances 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003317 industrial substance Substances 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 238000007873 sieving Methods 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000003837 high-temperature calcination Methods 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 13
- 238000010304 firing Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 238000013329 compounding Methods 0.000 claims description 7
- 230000005484 gravity Effects 0.000 claims description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 7
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 7
- 239000004575 stone Substances 0.000 claims 1
- 229910021532 Calcite Inorganic materials 0.000 abstract description 9
- 239000002994 raw material Substances 0.000 abstract description 4
- 229910052573 porcelain Inorganic materials 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 6
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- 241000238370 Sepia Species 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000010563 solid-state fermentation Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The present invention relates to a kind of high additive ferrochrome waste residue brown ceramic glaze and its application methods, using technical grade industrial chemicals, be made of by weight percentage following components: calcining 30~45wt% of ferrochrome waste residue, 24~28wt% of albite, 9~14wt% of potassium feldspar, 11~20wt% of calcite, 3~15wt% of quartz, 5~7wt% of kaolin, through mixing, wet ball grinding, being sieved is made glaze.Not only there is brown ceramic glaze prepared by the present invention good pool degree and glaze surface evenness to be widely used in daily porcelain products, but also prepare low raw-material cost, had not only reduced the wasting of resources but also had reduced environmental pollution, therefore has had broad application prospects.
Description
Technical field
The invention belongs to inorganic non-metallic material (ceramics) field, specifically a kind of high additive ferrochrome waste residue brown ceramic glaze
And its application method.
Background technique
At present in world's ferrochrome product, high carbon ferro-chrome yield accounts for the 91~93% of ferrochrome product population.It is bright to open up
Group is the maximum high carbon ferro-chrome manufacturing enterprise in the whole nation, produces 300000 tons of high carbon ferro-chrome per year, Zhan Quanguo high carbon ferro-chrome yield 15% with
On.After the second stage of item of Ming Tuo group plan is built up, high carbon ferro-chrome annual output is up to 1,000,000 tons, for the maximum high-carbon in the whole world
Ferrochrome manufacturing enterprise.Ferrochrome waste residue is the slag being discharged in high carbon ferro-chrome production process, and discharge amount is huge, and usually cinder field
It stacks, not only wastes land occupation, but also pollute environment.Since heavy metal Cr concentration is higher in ferrochrome waste residue, in extreme feelings
There is the possibility of release under condition, if long-term stockpiling or on the spot landfill may generate pollution, shadow to peripheral ground water and underground water
Nearby residents health is rung, therefore the ferrochrome waste residue of stockpiling should be handled as early as possible.Optimal processing method is exactly to chromium slag
It is comprehensively utilized.Contain more Fe in ferrochrome waste residue2O3And Cr2O3, these transition metal oxides are in traditional white glaze
For objectionable impurities metal oxide, there is stain in glaze after firing, brings detrimental effect to glaze quality and whiteness, incorporation
Therefore amount is also restricted and cannot utilize in large quantities.However due in ferrochrome waste residue also containing the SiO of high level2With
Al2O3, raw material chemical composition is often used close to enamel frit makeing；There is the MgO of high-content to introduce as fluxing agent again simultaneously, improves and promote glaze
Melting behaviour and pyroreaction；For Fe more in ferrochrome waste residue2O3And Cr2O3, pass through suitable formula composition and preparation work
The combination of skill makes to form sepia in the high additive ferrochrome waste slag ceramics glaze prepared under certain thermodynamic condition
Crystal.These colored crystals are distributed in glaze layer, and hot properties is stablized, and the decorative effect for making glaze that brown be presented has again simultaneously
Good color development stability；And during the preparation process, by using the control etc. of calcining and firing process to ferrochrome waste residue
Means facilitate chromium ion and become insoluble ion and be dissolved into form stable Mg(Al in lattice2-xCrx) O4, Fe(Al2-xCrx)
O4, detoxifying effect is good, without secondary pollution.Therefore, the characteristic of ferrochrome waste residue can be reasonably utilized by this preparation method,
It is applied in large quantities and is prepared in ceramic color glaze, changing disadvantage is benefit, is turned waste into wealth, and has not only reduced the pollution to environment, but also rise
To the effect for reducing cost, increasing benefit；While reducing the waste of land resource during ferrochrome Solid state fermentation again, have good
Good social benefit.
Summary of the invention
The technical problem to be solved in the present invention is to provide it is a kind of it is low in cost, simple process is easily-controllable, environmentally protective highly doped
Measure ferrochrome waste residue brown ceramic glaze and its application method.
In order to solve the above technical problems, the technical scheme is that a kind of high additive ferrochrome waste residue brown ceramic glaze,
It is characterized by: being made of by weight percentage using technical grade industrial chemicals following components: calcining ferrochrome waste residue 30~
45wt%, 24~28wt% of albite, 9~14wt% of potassium feldspar, 11~20wt% of calcite, quartz 3~15wt%, kaolin
5~7wt%, through mixing, wet ball grinding, being sieved is made glaze.
The burning ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying, the temperature of the high-temperature calcination using preceding
It is 1250~1300 DEG C, crossing grit number is 200 mesh.
It is 70wt% water, 0.1wt% sodium carboxymethylcellulose, 0.01wt% beauty that weight percent is added in the compounding process
State Xian Shui.
Ball in the wet ball grinding process: material: water ratio is 2:1:0.7, and grinding glaze specific gravity out is 1.6~1.64g/
cm3。
The sieve fineness of the sieving process is 300 mesh, and tailing over after sieving is 0.1%.
The application method of above-mentioned high additive ferrochrome waste residue brown ceramic glaze, it is characterised in that: the glaze is imposed on into base
After body dry tack free, product is obtained through 1300~1380 DEG C of firings, the chromatic value of the product glaze is L*=36~50, a*=10
~15, b*=25~30.
It researchs and analyses and shows by XRD, TG/DTA and other means of testing: high additive ferrochrome waste residue brown ceramic glaze
Material, the mechanism that sepia is presented is that Fe(Al is generated in glaze layerx,Cr2-x) O4, Mg(Alx,Cr2-x) O4、FeSiO4Several different colorings
The secondary colour of crystal introduces ferrochrome waste residue and other enamel frit makeing raw materials, such as quartz, calcite and potassium albite by large scale, and
Enamel frit makeing oxide ratios such as n (SiO in feed change2)/n(Al2O3) and the content of calcite control glaze glossiness and smooth
Degree, to prepare low cost, high benefit has good decorating effect, the flat and smooth high additive ferrochrome waste residue brown of glaze
Glaze, so that realize turns waste into wealth well, the effect of green environment.
Present invention advantage compared with traditional brown ceramic glaze is:
Use for the first time a large amount of industrial waste ferrochrome waste residues and common minerals as preparation brown ceramic glaze primary raw material,
Its is from a wealth of sources, low in cost, can not only reduce environmental pollution, and reduces production cost, reduces the wasting of resources；It first passes through to chromium
Iron waste residue carries out calcination processing, is allowed to form relatively stable coloring compound crystal, and the brown ceramic glaze tool prepared
Standby good color development and glossiness are widely used in daily porcelain products, therefore have a vast market.
Detailed description of the invention
Ferrochrome waste residue XRD test result after 1280 DEG C of calcinings in Fig. 1 embodiment 4；
The XRD test result of 1 high additive ferrochrome waste residue brown glaze of Fig. 2 embodiment；
The XRD test result of 5 high additive ferrochrome waste residue brown glaze of Fig. 3 embodiment.
Specific embodiment
The chemical percents of ferrochrome waste residue of the embodiment of the present invention form are as follows:
| SiO2 | Al2O3 | Fe2O3 | Cr2O3 | CaO | MgO | Na2O | SO3 | I.L. |
| 34.4 | 30.1 | 3.7 | 7.4 | 2.6 | 19.5 | 0.3 | 0.3 | 1.7 |
Green bodies used therein of the embodiment of the present invention is the daily porcelain billet of high temperature.
Embodiment 1:
A kind of high additive ferrochrome waste residue brown ceramic glaze, using technical grade industrial chemicals, formula composition are as follows: calcining chromium
Iron waste residue 30g, albite 25g, potassium feldspar 13g, calcite 19g, quartz 6g, kaolin 7g, through mixing, wet ball grinding, sieving
Glaze is made；
The burning ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying, the temperature of the high-temperature calcination using preceding
It is 1250 DEG C, crossing grit number is 200 mesh；
70g water, 0.1g sodium carboxymethylcellulose, the U.S. 0.01g Xian Shui are added in the compounding process;
Ball in the wet ball grinding process: material: the weight ratio of water is 2:1:0.7, and grinding glaze specific gravity out is 1.6g/
cm3;
The sieve fineness of the sieving process is 300 mesh, and tailing over after sieving is 0.1%;
After the glaze is imposed on billet surface drying, products, the coloration of the product glaze are obtained through 1300 DEG C of firings
Value is L*=48.87, a*=11.64, b*=25.61.
Embodiment 2:
A kind of high additive ferrochrome waste residue brown ceramic glaze, using technical grade industrial chemicals, formula composition are as follows: calcining chromium
Iron waste residue 38g, albite 24g, potassium feldspar 13g, calcite 14g, quartz 6g, kaolin 5g, through mixing, wet ball grinding, sieving
Glaze is made；
The burning ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying, the temperature of the high-temperature calcination using preceding
It is 1260 DEG C, crossing grit number is 200 mesh；
70g water, 0.1g sodium carboxymethylcellulose, the U.S. 0.01g Xian Shui are added in the compounding process;
Ball in the wet ball grinding process: material: the weight ratio of water is 2:1:0.7, and grinding glaze specific gravity out is 1.63g/
cm3;
The sieve fineness of the sieving process is 300 mesh, and tailing over after sieving is 0.1%;
After the glaze is imposed on billet surface drying, products, the coloration of the product glaze are obtained through 1310 DEG C of firings
Value is L*=42.59, a*=12.88, b*=26.11.
Embodiment 3:
A kind of high additive ferrochrome waste residue brown ceramic glaze, using technical grade industrial chemicals, formula composition are as follows: calcining chromium
Iron waste residue 43g, albite 24g, potassium feldspar 10g, calcite 14g, quartz 3g, kaolin 6g, through mixing, wet ball grinding, sieving
Glaze is made；
The burning ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying, the temperature of the high-temperature calcination using preceding
It is 1270 DEG C, crossing grit number is 200 mesh；
70g water, 0.1g sodium carboxymethylcellulose, the U.S. 0.01g Xian Shui are added in the compounding process;
Ball in the wet ball grinding process: material: the weight ratio of water is 2:1:0.7, and grinding glaze specific gravity out is 1.63g/
cm3;
The sieve fineness of the sieving process is 300 mesh, and tailing over after sieving is 0.1%;
After the glaze is imposed on billet surface drying, products, the coloration of the product glaze are obtained through 1330 DEG C of firings
Value is L*=43.02, a*=13.14, b*=26.30.
Embodiment 4:
A kind of high additive ferrochrome waste residue brown ceramic glaze, using technical grade industrial chemicals, formula composition are as follows: calcining chromium
Iron waste residue 32g, albite 27g, potassium feldspar 13g, calcite 14g, quartz 9g, kaolin 5g, through mixing, wet ball grinding, sieving
Glaze is made；
The burning ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying, the temperature of the high-temperature calcination using preceding
It is 1280 DEG C, crossing grit number is 200 mesh；
70g water, 0.1g sodium carboxymethylcellulose, the U.S. 0.01g Xian Shui are added in the compounding process;
Ball in the wet ball grinding process: material: the weight ratio of water is 2:1:0.7, and grinding glaze specific gravity out is 1.61g/
cm3;
The sieve fineness of the sieving process is 300 mesh, and tailing over after sieving is 0.1%;
After the glaze is imposed on billet surface drying, products, the coloration of the product glaze are obtained through 1350 DEG C of firings
Value is L*=37.99, a*=14.11, b*=29.69.
Embodiment 5:
A kind of high additive ferrochrome waste residue brown ceramic glaze, using technical grade industrial chemicals, formula composition are as follows: calcining chromium
Iron waste residue 32g, albite 27g, potassium feldspar 13g, calcite 14g, quartz 9g, kaolin 5g, through mixing, wet ball grinding, sieving
Glaze is made；
The burning ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying, the temperature of the high-temperature calcination using preceding
It is 1290 DEG C, crossing grit number is 200 mesh；
70g water, 0.1g sodium carboxymethylcellulose, the U.S. 0.01g Xian Shui are added in the compounding process;
Ball in the wet ball grinding process: material: the weight ratio of water is 2:1:0.7, and grinding glaze specific gravity out is 1.6g/
cm3;
The sieve fineness of the sieving process is 300 mesh, and tailing over after sieving is 0.1%;
After the glaze is imposed on billet surface drying, products, the coloration of the product glaze are obtained through 1370 DEG C of firings
Value is L*=37.92, a*=14.03, b*=28.38.
Claims (5)
1. a kind of high additive ferrochrome waste residue brown ceramic glaze, it is characterised in that: technical grade industrial chemicals is used, by following components
It forms by weight percentage: calcining 30~45wt% of ferrochrome waste residue, 24~28wt% of albite, 9~14wt% of potassium feldspar, Fang Xie
11~20wt% of stone, 3~15wt% of quartz, 5~7wt% of kaolin, through mixing, wet ball grinding, being sieved is made glaze；
The calcining ferrochrome waste residue first carries out high-temperature calcination, crushing, sieving, drying using preceding, and the temperature of the high-temperature calcination is
1250~1300 DEG C, crossing grit number is 200 mesh.
2. high additive ferrochrome waste residue brown ceramic glaze according to claim 1, it is characterised in that: in the compounding process
Addition weight percent is 70wt% water, 0.1wt% sodium carboxymethylcellulose, the U.S. 0.01wt% Xian Shui.
3. high additive ferrochrome waste residue brown ceramic glaze according to claim 1, it is characterised in that: the wet ball grinding work
Ball in sequence: material: the weight ratio of water is 2:1:0.7, and grinding glaze specific gravity out is 1.6~1.64g/cm3。
4. high additive ferrochrome waste residue brown ceramic glaze according to claim 1, it is characterised in that: the sieving process
Sieve fineness is 300 mesh, and tailing over after sieving is 0.1%.
5. the application method of -4 any high additive ferrochrome waste residue brown ceramic glazes according to claim 1, it is characterised in that:
After the glaze is imposed on billet surface drying, products, the chromatic value of the product glaze are obtained through 1300~1380 DEG C of firings
For L*=36~50, a*=10~15, b*=25~30.
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| CN1310207A (en) * | 2000-10-20 | 2001-08-29 | 佛山科学技术学院 | Preparing process of iron oxide red pigment for high-temperature ceramic with iron-containing industrial sludge |
| CN103086748A (en) * | 2013-02-06 | 2013-05-08 | 陕西科技大学 | Preparation method of slag bicrystal gold fancy glaze |
| CN105884197A (en) * | 2016-04-07 | 2016-08-24 | 陕西科技大学 | Method for preparing series iron-series colored glaze from iron-ore slag and decoration method based on colored glaze |
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| CN1310207A (en) * | 2000-10-20 | 2001-08-29 | 佛山科学技术学院 | Preparing process of iron oxide red pigment for high-temperature ceramic with iron-containing industrial sludge |
| CN103086748A (en) * | 2013-02-06 | 2013-05-08 | 陕西科技大学 | Preparation method of slag bicrystal gold fancy glaze |
| CN105884197A (en) * | 2016-04-07 | 2016-08-24 | 陕西科技大学 | Method for preparing series iron-series colored glaze from iron-ore slag and decoration method based on colored glaze |
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