CN103102078B - A kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof - Google Patents
A kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof Download PDFInfo
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- CN103102078B CN103102078B CN201310005972.5A CN201310005972A CN103102078B CN 103102078 B CN103102078 B CN 103102078B CN 201310005972 A CN201310005972 A CN 201310005972A CN 103102078 B CN103102078 B CN 103102078B
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Abstract
The invention discloses a kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof, according to the preparation method of described crystallite dry granular, selected raw material is through raw mill, and raw material mixes, and founds, obtained finished product after granulation, deferrization process step.Utilize the crystallite dry granular obtained to adopt once-firing technology to suppress through adobe, drying also spreads cosmetic soil, roller printing, and execute protection glaze, charity crystallite dry granular, is fixed agent, enters klining system and obtains microlite ceramic tile finished product.Relative to existing microlite ceramic tile, hardness and the fastness to rubbing index of microlite ceramic tile of the present invention significantly improve, solve the problem that twice firing micro-crystalline ceramic brick hardness is low, fastness to rubbing is low, and process energy consumption also reduces more than 30%, microlite ceramic tile crystallization pattern of the present invention is graceful, it is infinite to change irregularly, naturally true to nature, there is the extremely strong market competitiveness.
Description
Technical field
The present invention relates to crystallite class manufacturing technology field, particularly relate to a kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof.
Background technology
Microlite has another name called devitrified glass ceramics, belongs to high-grade finishing material.Traditional microlite ceramic tiles in advance low temperature sinter again after the biscuiting of base substrate high temperature, two steps burn till cause finished product to exist fastness to rubbing is low, hardness is low, base substrate and crystallite be in conjunction with the defect such as undesirable.And once burn crystallite and achieve more environmental protection, high rigidity, the complete upgrading of the indexs such as high abrasion degree.These excellent physicochemical properties be all secondary burn crystallite and lithotome incomparable.Also there is the deficiencies such as cloth is complicated, crystallite color is single, color pattern is simple, details is abundant not in the devitrified glass ceramics produced in existing once-firing technology, these also counteracts that the application and development of once-firing microlite ceramic tile technology.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, the object of the present invention is to provide a kind of preparation method of crystallite dry granular, microlite ceramic tile and production method, be intended to solve that current once-firing devitrified glass ceramics method cloth is complicated, crystallite color is single and color pattern simple question.
Technical scheme of the present invention is as follows:
A preparation method for crystallite dry granular, wherein, comprises the following steps:
S1, raw mill: silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground respectively, make each feed particles globule size consistent;
S2, raw material mix: the mixing of ground raw material is made into powder;
S3, to found: mixed powder is entered in kiln and is melting into crystallite frit;
S4, granulation: the frit founded out is dried, then pulverizes, sieve;
S5, deironing: deironing is carried out to the particulate material after sieving, obtained finished product.
The preparation method of described crystallite dry granular, wherein, in described step S1, each raw material particle size size is 90-110 order.
The preparation method of described crystallite dry granular, wherein, in described step S2, each raw materials by weight is counted:
Silica powder 18-27%;
Aluminum oxide 15-20%;
Rhombspar 18-25%;
Boric acid 5-10%;
Lithium porcelain stone 28-38%;
Potassium felspar sand 5-10 %.
The preparation method of described crystallite dry granular, wherein, controlling blast in kiln in described step S3 is 0.01-0.4Mpa, and oil pressure is 0.2-0.6Mpa, and in-furnace temperature is 1490-1510 DEG C.Made frit output per hour can reach 1 ton.
The preparation method of described crystallite dry granular, wherein, after sieving in described step S4, the granularity of gained crystallite dry granular is 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 60-70%;
20-40 order 15-25%;
40-60 order 5-15%;
The above 0-10% of 60 order.
Use the tramp iron separator with magnetic force to carry out deironing in described step S5, the quantity of tramp iron separator is 3-5, and the connection of tramp iron separator adopts plural serial stage mode.
A production method for microlite ceramic tile, wherein, the preparation method that have employed crystallite dry granular as above in the production method of described microlite ceramic tile produces the crystallite dry granular obtained; The production method of described microlite ceramic tile comprises the following steps:
A, by be used for adobe processing raw material mixing after carry out adobe compacting;
B, carrying out surface cleaning after drying to suppressing adobe, having spread the cosmetic soil of decoration function on adobe surface;
C, roller printing pattern;
D, be printed on decorative pattern adobe surface charity one deck protection glaze, for the protection of printed decorative pattern described;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, the fixing agent being used for fixing crystallite dry granular sprayed in described adobe surface;
G, enter klining system, once-firing compound;
The production method of described microlite ceramic tile, wherein, further comprising the steps of:
H, described in burn till kiln discharge product obtained finished product after polishing, edging technique.
The production method of described microlite ceramic tile, is characterized in that, in described step G, firing temperature is 1130 DEG C ~ 1270 DEG C.
The described microlite ceramic tile made by microlite ceramic tile production method; wherein; described microlite ceramic tile comprises adobe, cosmetic soil layer, protection glaze layer and crystallite dry granule layer, and described cosmetic soil layer, protection glaze layer and crystallite dry granule layer are set in turn in adobe surface from the inside to surface.
Beneficial effect: the production method of a kind of crystallite dry granular provided by the present invention and microlite ceramic tile and a kind of microlite ceramic tile, the present invention adopts once-firing compounding technology that the hardness of microlite ceramic tile and fastness to rubbing index are significantly improved, solve the problem that twice firing micro-crystalline ceramic brick hardness is low, fastness to rubbing is low, and the environmental protection more of once-firing technology, its energy consumption can reduce more than 30%, the microlite ceramic tile crystallization pattern that utilizes the bright crystallite dry granular provided of this law to produce is graceful, it is infinite, naturally true to nature to change irregularly; And greatly can reduce and collapse limit phenomenon when cutting ceramic tile, effectively solve cutting and collapse limit problem.
Accompanying drawing explanation
Fig. 1 is the production technological process of crystallite dry granular of the present invention.
Fig. 2 is the production technological process of microlite ceramic tile of the present invention.
Fig. 3 is the structural representation of microlite ceramic tile of the present invention.
Embodiment
The invention provides a kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof, for making object of the present invention, technical scheme and effect clearly, clearly, the present invention is described in more detail below.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
As shown in Figure 1, the preparation method of a kind of crystallite dry granular provided by the invention, by coloured crystallite frit that the basis of once burning crystallite frit in tradition is developed, namely on traditional once burning crystallite, introduce some as crystallization-promoters such as zirconiums, make originally small crystal grow up into the larger macroscopic crystal had compared with big-pattern gradually through one section of soak district, introduce some tinting materials make crystal and around color produce aberration, just generate exquisite beyond compare coloured crystallite.
This crystallite dry granular has filled up the blank of this series products domestic and international, specifically comprises the following steps:
Raw mill: silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground respectively, makes each raw material particle size size be 90-110 order, with 100 order size particles for the best.
Raw material mixes: be mixed in proportion by ground raw material and be made into powder, each raw materials by weight is counted:
Silica powder 18-27%;
Aluminum oxide 15-20%;
Rhombspar 18-25%;
Boric acid 5-10%;
Lithium porcelain stone 28-38%;
Potassium felspar sand 5-10 %.
Found: powder is sent in kiln and be melting into crystallite frit; Controlling blast in kiln is 0.01-0.4Mpa, and oil pressure is 0.2-0.6Mpa, and in-furnace temperature is 1490-1510 DEG C.
Granulation: the frit founded out is dried, then pulverizes, sieve.After sieving, the granularity of gained crystallite dry granular is, wherein each order array becomes proportion to be:
10-20 order 60-70%;
20-40 order 15-25%;
40-60 order 5-15%;
The above 0-10% of 60 order.
Deironing: enter magnetic separator de-ironing deironing.During the iron contamination adulterated in crystallite material, especially when white or light blank glaze, iron contamination after calcining can become black, yellow or blue spot, appearance luster and the smooth finish of product can be had a strong impact on, therefore need to carry out deironing to the microcrystal grain material after sieving, the tramp iron separator that usual use has magnetic force carries out deironing, and the quantity of tramp iron separator is 3-5, and the connection of tramp iron separator adopts plural serial stage mode.Such setting well can remove iron contamination, obtains crystallite dry granular finished product after removing iron contamination.
The making of frit is also a very large influence factor to the exhaust of technique to adobe and glaze.Glass melting temperature too high too low to the later stage produce brick all have a great impact.Glass melting temperature is too high, can make to obtain volatile component volatilization in formula, changes the chemical constitution of glaze, glaze is deteriorated.And temperature crosses low reaction not exclusively, some gas-forming substance not yet decomposes completely, and exhaust can be made when being fired into pottery to be deteriorated.Therefore temperature should be made to control do not have half-cooked material at frit when founding frit, fishplate bar does not have bubble or a little bubble to be advisable.According to the result feature of self formula in this present invention, the processing temperature of being burnt till by frit keeps 1500 degree positive and negative 10 degree, and guarantees that melting furnaces are in oxidizing atmosphere, makes fuel oil fully not pollute frit, and produces bubble.
In order to make adobe and glaze exhaust good, the selection of crystallite dry granular order number is extremely important, and crystallite dry granular is excessively thick, makes firing temperature cross raising, can cause color glaze fancy glaze oxygenolysis, the higher exhaust of glaze viscosity incomplete and there is more bubble and bubble larger.The meticulous firing temperature of crystallite dry granular is on the low side, and bubble is shut in glaze layer by the too low glaze premature melt of viscosity, and causes there is more bubble.Therefore the size of crystallite dry granular order number has larger impact to exhaust.In the preparation method of crystallite dry granular provided by the present invention; adopt the crystallite dry granular collocation of different size mixed in granulation making processes; the crystallite dry granular got between 10 orders to 60 orders is used in combination; the space between crystallite dry granular can be filled; gas in space is driven out of, like this firing range of temperature is also increased simultaneously.More be conducive to the exhaust of adobe and glaze.
As shown in Figure 2, produce microlite ceramic tile with above-mentioned crystallite dry granular, the production method of described microlite ceramic tile comprises the following steps:
A, by be used for adobe processing raw material mixing after carry out adobe compacting.
B, adobe will be suppressed carry out surface cleaning after drying, spread the cosmetic soil of decoration function on adobe surface.
C, roller printing pattern; Large gauge roller printing is adopted to decorate.
D, at described print dapple adobe surface charity one deck protection glaze, for the protection of printed decorative pattern;
E, on the protection glaze layer of described adobe even charity crystallite dry granular;
F, the fixing agent being used for fixing crystallite dry granular sprayed in described adobe surface;
G, enter klining system, once-firing compound; Firing temperature is 1130 DEG C ~ 1270 DEG C, and above-mentioned microcrystalline coating beginning fusing point is 1130 DEG C, temperature is controlled at 1130 DEG C ~ 1270 DEG C, can ensure that each layer raw material of adobe well forms by a firing.And can make crystallite dry granule layer melt molten before to allow adobe be vented complete, thus solve adobe bubbles problem.
Processing for some product needs, and the working method of described microlite ceramic tile can also comprise:
H, after polishing, edging technique obtained finished product.
As shown in Figure 3; utilize the above-mentioned microlite ceramic tile made by microlite ceramic tile production method to comprise adobe 4, cosmetic soil layer 3, protection glaze layer 2 and crystallite dry granule layer 1, described cosmetic soil layer 3, protection glaze layer 2 and crystallite dry granule layer 1 are set in turn in adobe 4 surface from the inside to surface.
The microlite ceramic tile utilizing technique scheme to produce detects through ceramic tile fastness to rubbing, and result shows, and the fastness to rubbing that microlite ceramic tile of the present invention detects has 4 grades, and hardness has 5 grades.Possess extremely strong hardness and fabulous wear resisting property.Why microlite ceramic tile of the present invention possesses so high hardness and fastness to rubbing, and bright in luster true to nature be because in product processing, this interiors of products can separate out a large amount of small β-triphane of being invisible to the naked eye and fluorine phosphorus amphibole, and the fastness to rubbing of these two kinds of microcrystals and hardness are suitable high, this product transparency is very high simultaneously, and can not eat look, therefore the product hardness fastness to rubbing made is high, rich color.Naturally true to nature.
On the other hand, burn in crystallite technique at traditional secondary, need first life embryo to be burnt till plain embryo at glazing Low fire ceramic product, technical scheme of the present invention is then directly on raw embryo, carry out glazing to generate ceramic product, compare in energy consumption like this secondary burn crystallite technique minimum can save 30% the energy.
Below by way of specific embodiment, the present invention will be further described.
Embodiment 1
A preparation method for crystallite dry granular, its processing step is as follows:
S1, raw mill: silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground respectively, make each feed particles globule size be 100 orders.
S2, raw material mix: the mixing of ground raw material is made into powder, and each raw materials by weight is counted:
Silica powder 22%;
Aluminum oxide 16%;
Rhombspar 20%;
Boric acid 7%;
Lithium porcelain stone 28%;
Potassium felspar sand 7 %.
S3, to found: mixed powder is entered in kiln and is melting into crystallite frit.Controlling blast in kiln is 0.2Mpa, and oil pressure is 0.4Mpa, and in-furnace temperature remains on 1500 DEG C.Made frit output per hour can reach 1 ton.
S4, granulation: the frit founded out is dried, then pulverizes, sieve.After sieving, the granularity of gained crystallite dry granular is 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 65 %;
20-40 order 20 %;
40-60 order 10%;
More than 60 orders 5%.
S5, deironing: use the tramp iron separator of plural serial stage to carry out deironing to the particulate material after sieving, obtained finished product.
Utilize the microlite ceramic tile that above-mentioned crystallite dry granular is produced, wherein, the production method of described microlite ceramic tile comprises the following steps:
A, by be used for adobe processing raw material mixing after carry out adobe compacting;
B, carrying out surface cleaning after drying to suppressing adobe, having spread the cosmetic soil of decoration function on adobe surface;
C, roller printing pattern;
D, be printed on decorative pattern adobe surface charity one deck protection glaze, for the protection of printed decorative pattern described;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, the fixing agent being used for fixing crystallite dry granular sprayed in described adobe surface;
G, enter klining system, once-firing compound; Firing temperature is 1130 DEG C.
The microlite ceramic tile utilizing the technical scheme of embodiment 1 to produce after testing its fastness to rubbing reaches 4 grades, and hardness reaches 5 grades.Generate ceramic product by directly carrying out glazing on raw embryo in the present embodiment, than traditional secondary burn crystallite technique minimum can save 30% energy consumption.
Embodiment 2
A preparation method for crystallite dry granular, its processing step is as follows:
S1, raw mill: silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground respectively, make each feed particles globule size be 90 orders.
S2, raw material mix: the mixing of ground raw material is made into powder, and each raw materials by weight is counted:
Silica powder 18%;
Aluminum oxide 15%;
Rhombspar 18%;
Boric acid 5%;
Lithium porcelain stone 38%;
Potassium felspar sand 6%.
S3, to found: mixed powder is entered in kiln and is melting into crystallite frit.Controlling blast in kiln is 0.4Mpa, and oil pressure is 0.6Mpa, and in-furnace temperature remains on 1500 ± 10 DEG C.Made frit output per hour can reach 1 ton.
S4, granulation: the frit founded out is dried, then pulverizes, sieve.After sieving, the granularity of gained crystallite dry granular is 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 60%;
20-40 order 15%;
40-60 order 15%;
More than 60 orders 10 %.
S5, deironing: use the tramp iron separator of plural serial stage to carry out deironing to the particulate material after sieving, obtained finished product.
Utilize the microlite ceramic tile that above-mentioned crystallite dry granular is produced, wherein, the production method of described microlite ceramic tile comprises the following steps:
A, by be used for adobe processing raw material mixing after carry out adobe compacting;
B, carrying out surface cleaning after drying to suppressing adobe, having spread the cosmetic soil of decoration function on adobe surface;
C, roller printing pattern;
D, be printed on decorative pattern adobe surface charity one deck protection glaze, for the protection of printed decorative pattern described;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, the fixing agent being used for fixing crystallite dry granular sprayed in described adobe surface;
G, enter klining system, once-firing compound; Firing temperature is 1200 DEG C.
The microlite ceramic tile utilizing the technical scheme of embodiment 2 to produce after testing its fastness to rubbing reaches 4 grades, and hardness reaches 5 grades.Generate ceramic product by directly carrying out glazing on raw embryo in the present embodiment, than traditional secondary burn crystallite technique minimum can save 30% energy consumption.
Embodiment 3
A preparation method for crystallite dry granular, its processing step is as follows:
S1, raw mill: silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground respectively, make each feed particles globule size be 110 orders.
S2, raw material mix: the mixing of ground raw material is made into powder, and each raw materials by weight is counted:
Silica powder 19%;
Aluminum oxide 19%;
Rhombspar 18%;
Boric acid 8%;
Lithium porcelain stone 28%;
Potassium felspar sand 8 %.
S3, to found: mixed powder is entered in kiln and is melting into crystallite frit.Controlling blast in kiln is 0.2Mpa, and oil pressure is 0.2 Mpa, and in-furnace temperature remains on 1500 DEG C.Made frit output per hour can reach 1 ton.
S4, granulation: the frit founded out is dried, then pulverizes, sieve.After sieving, the granularity of gained crystallite dry granular is 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 70%;
20-40 order 20 %;
40-60 order 5 %;
More than 60 orders 5%.
S5, deironing: use the tramp iron separator of plural serial stage to carry out deironing to the particulate material after sieving, obtained finished product.
Utilize the microlite ceramic tile that above-mentioned crystallite dry granular is produced, wherein, the production method of described microlite ceramic tile comprises the following steps:
A, by be used for adobe processing raw material mixing after carry out adobe compacting;
B, carrying out surface cleaning after drying to suppressing adobe, having spread the cosmetic soil of decoration function on adobe surface;
C, roller printing pattern;
D, be printed on decorative pattern adobe surface charity one deck protection glaze, for the protection of printed decorative pattern described;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, the fixing agent being used for fixing crystallite dry granular sprayed in described adobe surface;
G, enter klining system, once-firing compound; Firing temperature is 1270 DEG C.
The microlite ceramic tile utilizing the technical scheme of embodiment 3 to produce after testing its fastness to rubbing reaches 4 grades, and hardness reaches 5 grades.Generate ceramic product by directly carrying out glazing on raw embryo in the present embodiment, than traditional secondary burn crystallite technique minimum can save 30% energy consumption.
The present invention adopts once-firing compounding technology that the hardness of microlite ceramic tile and fastness to rubbing index are significantly improved, and its energy consumption can reduce more than 30% compared to traditional secondary firing process, the microlite ceramic tile crystallization pattern produced of the crystallite dry granular utilizing this law bright and related process is graceful, it is infinite, naturally true to nature to change irregularly.
Should be understood that, application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.
Claims (5)
1. a preparation method for crystallite dry granular, is characterized in that, comprises the following steps:
S1, raw mill: silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground respectively, make each feed particles globule size consistent;
S2, raw material mix: the mixing of ground raw material is made into powder;
S3, to found: mixed powder is entered in kiln and is melting into crystallite frit;
S4, granulation: the frit founded out is dried, then pulverizes, sieve;
S5, deironing: deironing is carried out to the particulate material after sieving, obtained finished product;
Controlling blast in kiln in described step S3 is 0.01-0.4Mpa, and oil pressure is 0.2-0.6Mpa, and in-furnace temperature is 1490-1510 DEG C;
After described frit sieves, the granularity of gained crystallite dry granular is 10-60 order;
In described step S2, each raw materials by weight is counted:
Silica powder 18-27%;
Aluminum oxide 15-20%;
Rhombspar 18-25%;
Boric acid 5-10%;
Lithium porcelain stone 28-38%;
Potassium felspar sand 5-10 %;
Gained crystallite dry granular after sieving in described S4, wherein each order array becomes proportion to be:
10-20 order 60-70%;
20-40 order 15-25%;
40-60 order 5-15%;
The above 0-10% of 60 order.
2. the preparation method of crystallite dry granular according to claim 1, is characterized in that, in described step S1, each raw material particle size size is 90-110 order.
3. a production method for the microlite ceramic tile utilizing the crystallite dry granular as described in any one of claim 1-2 to produce, it is characterized in that, the production method of described microlite ceramic tile comprises the following steps:
A, by be used for base substrate processing raw material mixing after carry out adobe compacting;
B, carrying out surface cleaning after drying to suppressing adobe, having spread the cosmetic soil of decoration function on adobe surface;
C, roller printing pattern;
D, at described print dapple adobe surface charity one deck protection glaze, for the protection of printed decorative pattern;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, the fixing agent being used for fixing crystallite dry granular sprayed in described adobe surface;
G, enter klining system, once-firing compound;
In described step G, firing temperature is 1130 DEG C ~ 1270 DEG C.
4. the production method of microlite ceramic tile according to claim 3, is characterized in that, further comprising the steps of:
H, described in burn till kiln discharge product obtained finished product after polishing, edging technique.
5. one kind with the microlite ceramic tile made by microlite ceramic tile production method as claimed in claim 3; it is characterized in that; described microlite ceramic tile comprises adobe, cosmetic soil layer, protection glaze layer and crystallite dry granule layer, and described cosmetic soil layer, protection glaze layer and crystallite dry granule layer are set in turn in adobe surface from the inside to surface.
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| CN1382666A (en) * | 2002-05-22 | 2002-12-04 | 三水市特地陶瓷有限公司 | Process for preparing microcrystal glass-ceramic tile |
| CN101138865A (en) * | 2006-09-08 | 2008-03-12 | 陈国雄 | Method for producing novel nucleated glass-ceramic tile |
| CN101982435A (en) * | 2010-11-05 | 2011-03-02 | 中材高新材料股份有限公司 | Method for preparing low-temperature lead-free near zero expansion microcrystalline ceramic coating |
| CN102390931A (en) * | 2011-08-02 | 2012-03-28 | 佛山石湾鹰牌陶瓷有限公司 | Method for manufacturing once calcined glass ceramic brick |
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