CN103102078A - Preparation method of microcrystal dry grains, microlite ceramic tile and production method of microlite ceramic tile - Google Patents

Preparation method of microcrystal dry grains, microlite ceramic tile and production method of microlite ceramic tile Download PDF

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Publication number
CN103102078A
CN103102078A CN2013100059725A CN201310005972A CN103102078A CN 103102078 A CN103102078 A CN 103102078A CN 2013100059725 A CN2013100059725 A CN 2013100059725A CN 201310005972 A CN201310005972 A CN 201310005972A CN 103102078 A CN103102078 A CN 103102078A
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ceramic tile
dry granular
crystallite
adobe
microlite ceramic
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CN103102078B (en
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何维恭
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GUANGDONG WEIBANG MICROCRYSTAL TECHNOLOGY Co Ltd
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GUANGDONG WEIBANG MICROCRYSTAL TECHNOLOGY Co Ltd
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Abstract

The invention discloses a preparation method for microcrystal dry grains, a microlite ceramic tile and a production method of the microlite ceramic tile. According to the preparation method of the microcrystal dry grains, the process steps such as material grinding, material mixing, melting, pelletizing, deironing and the like to the materials to prepare finished products. The obtained microcrystal drain grains are pressed into green bricks by adopting once-firing technology, dried and coated with engobe, printed by a roller, applied with protective glaze, applied with the microcrystal dry grains, added with a fixing agent, and fired in a kiln to obtain the microlite ceramic tile finished product. Relative to the existing the microlite ceramic tile, the hardness and the wear resistance indexes of the microlite ceramic tile are greatly improved, so that the problems that the twice-fired microlite ceramic tile is low in hardness and low in wear resistance; moreover, the process energy consumption also can be reduced by more than 30%. The microlite ceramic tile disclosed by the invention is exquisite, various and vivid in crystallization pattern, and strong in market competitiveness.

Description

A kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof
Technical field
The present invention relates to crystallite class manufacturing technology field, relate in particular to a kind of preparation method, microlite ceramic tile and production method thereof of crystallite dry granular.
Background technology
Microlite has another name called devitrified glass ceramics, belongs to high-grade finishing material.Traditional microlite ceramic tiles in advance through the biscuiting of base substrate high temperature after low temperature sinter again, two steps burnt till and cause that finished product exists that fastness to rubbing is low, hardness is low, base substrate is combined the defective such as undesirable with crystallite.Realized more environmental protection and once burn crystallite, high rigidity, the complete upgrading of the indexs such as high abrasion degree.These good physicochemical properties are all that secondary burning crystallite and lithotome are incomparable.The deficiencies such as cloth is complicated, the crystallite color is single, color pattern simple, details is abundant have not also appearred in the devitrified glass ceramics of producing in existing once-firing technology, and these have also hindered the application and development of once-firing microlite ceramic tile technology.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, the object of the present invention is to provide a kind of crystallite dry granular preparation method, microlite ceramic tile and production method, be intended to solve that present once-firing devitrified glass ceramics method cloth is complicated, the crystallite color is single and the color pattern simple question.
Technical scheme of the present invention is as follows:
A kind of preparation method of crystallite dry granular wherein, comprises the following steps:
S1, former abrasive lapping: respectively silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground, make each feed particles globule size consistent;
S2, raw material mix: ground raw material is mixed being made into powder;
S3, found: mixed powder is entered be melting into the crystallite frit in kiln;
S4, granulation: the frit of founding out is dried, then pulverize, sieve;
S5, deironing: the particulate material after sieving is carried out deironing, make finished product.
The preparation method of described crystallite dry granular, wherein, in described step S1, each raw material particle size size is the 90-110 order.
The preparation method of described crystallite dry granular, wherein, in described step S2, each raw materials by weight is counted:
Silica powder 18-27%;
Aluminum oxide 15-20%;
Rhombspar 18-25%;
Boric acid 5-10%;
Lithium porcelain stone 28-38%;
Potassium felspar sand 5-10 %.
The preparation method of described crystallite dry granular, wherein, controlling blast in kiln in described step S3 is 0.01-0.4Mpa, and oil pressure is 0.2-0.6Mpa, and in stove, temperature is 1490-1510 ℃.Per hour made frit output can reach 1 ton.
The preparation method of described crystallite dry granular, wherein, the granularity of the rear gained crystallite dry granular that sieves in described step S4 is the 10-60 order, wherein each order array becomes proportion to be:
10-20 order 60-70%;
20-40 order 15-25%;
40-60 order 5-15%;
The 60 above 0-10% of order.
Use the tramp iron separator with magnetic force to carry out deironing in described step S5, the quantity of tramp iron separator is 3-5, and the plural serial stage mode is adopted in the connection of tramp iron separator.
A kind of production method of microlite ceramic tile, wherein, the crystallite dry granular that has adopted preparation method's production of crystallite dry granular as above to obtain in the production method of described microlite ceramic tile; The production method of described microlite ceramic tile comprises the following steps:
A, carry out the adobe compacting after mixing for the raw material of adobe processing;
B, carry out after drying surface cleaning to suppressing adobe, spread the cosmetic soil of decoration function on the adobe surface;
C, roller printing pattern;
D, at described decorative pattern adobe surface charity one deck protection glaze that is printed on, for the protection of the decorative pattern of printing;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, will spray in described adobe surface for the fixing fixing agent of crystallite dry granular;
G, advance klining system, once-firing is compound;
The production method of described microlite ceramic tile, wherein, further comprising the steps of:
H, the described product that burns till kiln discharge make finished product after polishing, edging technique.
The production method of described microlite ceramic tile is characterized in that, in described step G, firing temperature is 1130 ℃ ~ 1270 ℃.
The made microlite ceramic tile of described microlite ceramic tile production method; wherein; described microlite ceramic tile comprises adobe, cosmetic soil layer, protection glaze layer and crystallite dry granular layer, and described cosmetic soil layer, protection glaze layer and crystallite dry granular layer are set in turn in the adobe surface from the inside to surface.
Beneficial effect: the production method of a kind of crystallite dry granular provided by the present invention and microlite ceramic tile and a kind of microlite ceramic tile, the present invention adopts the once-firing compounding technology to make the hardness of microlite ceramic tile and fastness to rubbing index significantly improve, solved the problem that twice firing micro-crystalline ceramic brick hardness is low, fastness to rubbing is low, and once-firing technology environmental protection more, its energy consumption can reduce more than 30%, the microlite ceramic tile crystallization pattern that utilizes the bright crystallite dry granular that provides of this law to produce is graceful, change is infinite, naturally true to nature; And can greatly reduce when the cutting ceramic tile and collapse the limit phenomenon, effectively solve cutting and collapse the limit problem.
Description of drawings
Fig. 1 is the production technological process of crystallite dry granular of the present invention.
Fig. 2 is the production technological process of microlite ceramic tile of the present invention.
Fig. 3 is the structural representation of microlite ceramic tile of the present invention.
Embodiment
The invention provides a kind of preparation method, microlite ceramic tile and production method thereof of crystallite dry granular, clearer, clear and definite for making purpose of the present invention, technical scheme and effect, below the present invention is described in more detail.Should be appreciated that specific embodiment described herein only in order to explain the present invention, is not intended to limit the present invention.
As shown in Figure 1, the preparation method of a kind of crystallite dry granular provided by the invention, coloured crystallite frit of developing by the basis of once burning the crystallite frit in tradition, namely on traditional once burning crystallite, introduce some as crystallization-promoters such as zirconiums, make original small crystal grow up into gradually the larger macroscopic crystal that has than big-pattern through one section soak district, making crystal and on every side color produce aberration introducing some tinting materials, just generating exquisite beyond compare coloured crystallite.
This crystallite dry granular has been filled up the blank of domestic and international this series products, specifically comprises the following steps:
Former abrasive lapping: respectively silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground, make each raw material particle size size be the 90-110 order, take 100 order size particles as best.
Raw material mixes: ground raw material is mixed in proportion is made into powder, each raw materials by weight is counted:
Silica powder 18-27%;
Aluminum oxide 15-20%;
Rhombspar 18-25%;
Boric acid 5-10%;
Lithium porcelain stone 28-38%;
Potassium felspar sand 5-10 %.
Found: powder is sent into be melting into the crystallite frit in kiln; Controlling blast in kiln is 0.01-0.4Mpa, and oil pressure is 0.2-0.6Mpa, and in stove, temperature is 1490-1510 ℃.
Granulation: the frit of founding out is dried, then pulverize, sieve.The granularity of rear gained crystallite dry granular of sieving is that wherein each order array becomes proportion to be:
10-20 order 60-70%;
20-40 order 15-25%;
40-60 order 5-15%;
The 60 above 0-10% of order.
Deironing: enter the magnetic separator de-ironing deironing.During the iron contamination that adulterates in the crystallite material, especially white or during light blank glaze, iron contamination after calcining can become black, yellow or blue spot, can have a strong impact on appearance luster and the smooth finish of product, therefore need to carry out deironing to the microcrystal grain material after sieving, usually use the tramp iron separator with magnetic force to carry out deironing, the quantity of tramp iron separator is 3-5, and the plural serial stage mode is adopted in the connection of tramp iron separator.Such setting can well be removed iron contamination, removes and obtains crystallite dry granular finished product after iron contamination.
The making of frit is also a very large influence factor to technique to the exhaust of adobe and glaze.Glass melting temperature is too high too lowly to be produced brick to the later stage and all has a great impact.Glass melting temperature is too high, can make to get the volatile component volatilization in formula, changes the chemical constitution of glaze, makes the glaze variation.And that temperature is crossed low reaction is incomplete, and some gas-forming substance not yet decomposes fully, can make the exhaust variation when being fired into pottery.Therefore should make temperature be controlled at frit when founding frit does not have half-cooked material, and fishplate bar does not have bubble or a little bubble to be advisable.In this present invention, according to the characteristics as a result of self filling a prescription, the processing temperature that frit is burnt till keeps positive and negative 10 degree of 1500 degree, and guarantees that melting furnaces are in oxidizing atmosphere, makes fuel oil fully not pollute frit, and produces bubble.
In order to make adobe and glaze exhaust good, the selection of crystallite dry granular order number is extremely important, and the crystallite dry granular is excessively thick, makes firing temperature cross raising, can cause color glaze fancy glaze oxygenolysis, and the higher exhaust of glaze viscosity not exclusively exists more bubble and bubble larger.The meticulous firing temperature of crystallite dry granular is on the low side, and the too early melting of the too low glaze of viscosity is shut bubble in the glaze layer, and causes that more bubble is arranged.Therefore the size of crystallite dry granular order number has larger impact to exhaust.In the preparation method of crystallite dry granular provided by the present invention; adopt the crystallite dry granular collocation of different sizes mixed in granulation making processes; get 10 orders and mix use to the crystallite dry granular between 60 orders; can fill the space between the crystallite dry granular; gas in the space is driven out of, and the while has also strengthened the firing range of temperature like this.More be conducive to the exhaust of adobe and glaze.
As shown in Figure 2, produce the microlite ceramic tile with above-mentioned crystallite dry granular, the production method of described microlite ceramic tile comprises the following steps:
A, carry out the adobe compacting after mixing for the raw material of adobe processing.
B, will suppress adobe and carry out after drying surface cleaning, spread the cosmetic soil of decoration function on the adobe surface.
C, roller printing pattern; Adopt large specification roller printing to decorate.
D, at the dapple adobe of described seal surface charity one deck protection glaze, for the protection of the decorative pattern of printing;
E, on the protection glaze layer of described adobe even charity crystallite dry granular;
F, will spray in described adobe surface for the fixing fixing agent of crystallite dry granular;
G, advance klining system, once-firing is compound; Firing temperature is 1130 ℃ ~ 1270 ℃, and above-mentioned microcrystalline coating beginning fusing point is 1130 ℃, and temperature is controlled at 1130 ℃ ~ 1270 ℃, can guarantee that each layer of adobe raw material well forms by a firing.And make the adobe exhaust complete before making crystallite dry granular layer molten molten, thereby solve adobe bubbles problem.
Processing for some product needs, and the working method of described microlite ceramic tile can also comprise:
H, make finished product after polishing, edging technique.
As shown in Figure 3; utilize the above-mentioned made microlite ceramic tile of microlite ceramic tile production method to comprise adobe 4, cosmetic soil layer 3, protection glaze layer 2 and crystallite dry granular layer 1, described cosmetic soil layer 3, protection glaze layer 2 and crystallite dry granular layer 1 are set in turn in adobe 4 surfaces from the inside to surface.
Utilize the microlite ceramic tile that technique scheme is produced to detect through the ceramic tile fastness to rubbing, the result demonstration, the fastness to rubbing that microlite ceramic tile of the present invention detects has 4 grades, and hardness has 5 grades.Possessed extremely strong hardness and fabulous wear resisting property.Why microlite ceramic tile of the present invention possesses so high hardness and fastness to rubbing, and bright in luster true to nature be because in product processing, this interiors of products can be separated out a large amount of small β-triphanes that is invisible to the naked eye and fluorine phosphorus amphibole, and the fastness to rubbing of these two kinds of microcrystals and hardness are suitable high, this product transparency is very high simultaneously, and can not eat look, and therefore the product hardness fastness to rubbing of making is high, rich color.Naturally true to nature.
On the other hand, burn in crystallite technique at traditional secondary, need first to give birth to embryo and burn till plain embryo at glazing Low fire ceramic product, technical scheme of the present invention is directly to carry out glazing on embryo and generate ceramic product giving birth to, and compares like this secondary and burn that crystallite technique is minimum can save 30% the energy aspect energy consumption.
Below the present invention will be further described by specific embodiment.
Embodiment 1
A kind of preparation method of crystallite dry granular, its processing step is as follows:
S1, former abrasive lapping: respectively silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground, make each feed particles globule size be 100 orders.
S2, raw material mix: ground raw material is mixed being made into powder, each raw materials by weight is counted:
Silica powder 22%;
Aluminum oxide 16%;
Rhombspar 20%;
Boric acid 7%;
Lithium porcelain stone 28%;
Potassium felspar sand 7 %.
S3, found: mixed powder is entered be melting into the crystallite frit in kiln.Controlling blast in kiln is 0.2Mpa, and oil pressure is 0.4Mpa, and in stove, temperature remains on 1500 ℃.Per hour made frit output can reach 1 ton.
S4, granulation: the frit of founding out is dried, then pulverize, sieve.The granularity of rear gained crystallite dry granular of sieving is the 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 65 %;
20-40 order 20 %;
40-60 order 10%;
60 orders above 5%.
S5, deironing: use the tramp iron separator of plural serial stage to carry out deironing to the particulate material after sieving, make finished product.
The microlite ceramic tile that utilizes above-mentioned crystallite dry granular to produce, wherein, the production method of described microlite ceramic tile comprises the following steps:
A, carry out the adobe compacting after mixing for the raw material of adobe processing;
B, carry out after drying surface cleaning to suppressing adobe, spread the cosmetic soil of decoration function on the adobe surface;
C, roller printing pattern;
D, at described decorative pattern adobe surface charity one deck protection glaze that is printed on, for the protection of the decorative pattern of printing;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, will spray in described adobe surface for the fixing fixing agent of crystallite dry granular;
G, advance klining system, once-firing is compound; Firing temperature is 1130 ℃.
Utilize microlite ceramic tile that the technical scheme of embodiment 1 produces after testing its fastness to rubbing reach 4 grades, hardness reaches 5 grades.By directly carrying out glazing on embryo and generate ceramic product giving birth to, burn minimum 30% the energy consumption of saving of crystallite technique than traditional secondary in the present embodiment.
Embodiment 2
A kind of preparation method of crystallite dry granular, its processing step is as follows:
S1, former abrasive lapping: respectively silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground, make each feed particles globule size be 90 orders.
S2, raw material mix: ground raw material is mixed being made into powder, each raw materials by weight is counted:
Silica powder 18%;
Aluminum oxide 15%;
Rhombspar 18%;
Boric acid 5%;
Lithium porcelain stone 38%;
Potassium felspar sand 6%.
S3, found: mixed powder is entered be melting into the crystallite frit in kiln.Controlling blast in kiln is 0.4Mpa, and oil pressure is 0.6Mpa, and in stove, temperature remains on 1500 ± 10 ℃.Per hour made frit output can reach 1 ton.
S4, granulation: the frit of founding out is dried, then pulverize, sieve.The granularity of rear gained crystallite dry granular of sieving is the 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 60%;
20-40 order 15%;
40-60 order 15%;
Above 10 % of 60 orders.
S5, deironing: use the tramp iron separator of plural serial stage to carry out deironing to the particulate material after sieving, make finished product.
The microlite ceramic tile that utilizes above-mentioned crystallite dry granular to produce, wherein, the production method of described microlite ceramic tile comprises the following steps:
A, carry out the adobe compacting after mixing for the raw material of adobe processing;
B, carry out after drying surface cleaning to suppressing adobe, spread the cosmetic soil of decoration function on the adobe surface;
C, roller printing pattern;
D, at described decorative pattern adobe surface charity one deck protection glaze that is printed on, for the protection of the decorative pattern of printing;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, will spray in described adobe surface for the fixing fixing agent of crystallite dry granular;
G, advance klining system, once-firing is compound; Firing temperature is 1200 ℃.
Utilize microlite ceramic tile that the technical scheme of embodiment 2 produces after testing its fastness to rubbing reach 4 grades, hardness reaches 5 grades.By directly carrying out glazing on embryo and generate ceramic product giving birth to, burn minimum 30% the energy consumption of saving of crystallite technique than traditional secondary in the present embodiment.
Embodiment 3
A kind of preparation method of crystallite dry granular, its processing step is as follows:
S1, former abrasive lapping: respectively silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground, make each feed particles globule size be 110 orders.
S2, raw material mix: ground raw material is mixed being made into powder, each raw materials by weight is counted:
Silica powder 19%;
Aluminum oxide 19%;
Rhombspar 18%;
Boric acid 8%;
Lithium porcelain stone 28%;
Potassium felspar sand 8 %.
S3, found: mixed powder is entered be melting into the crystallite frit in kiln.Controlling blast in kiln is 0.2Mpa, and oil pressure is 0.2 Mpa, and in stove, temperature remains on 1500 ℃.Per hour made frit output can reach 1 ton.
S4, granulation: the frit of founding out is dried, then pulverize, sieve.The granularity of rear gained crystallite dry granular of sieving is the 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 70%;
20-40 order 20 %;
40-60 order 5 %;
60 orders above 5%.
S5, deironing: use the tramp iron separator of plural serial stage to carry out deironing to the particulate material after sieving, make finished product.
The microlite ceramic tile that utilizes above-mentioned crystallite dry granular to produce, wherein, the production method of described microlite ceramic tile comprises the following steps:
A, carry out the adobe compacting after mixing for the raw material of adobe processing;
B, carry out after drying surface cleaning to suppressing adobe, spread the cosmetic soil of decoration function on the adobe surface;
C, roller printing pattern;
D, at described decorative pattern adobe surface charity one deck protection glaze that is printed on, for the protection of the decorative pattern of printing;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, will spray in described adobe surface for the fixing fixing agent of crystallite dry granular;
G, advance klining system, once-firing is compound; Firing temperature is 1270 ℃.
Utilize microlite ceramic tile that the technical scheme of embodiment 3 produces after testing its fastness to rubbing reach 4 grades, hardness reaches 5 grades.By directly carrying out glazing on embryo and generate ceramic product giving birth to, burn minimum 30% the energy consumption of saving of crystallite technique than traditional secondary in the present embodiment.
The present invention adopts the once-firing compounding technology to make the hardness of microlite ceramic tile and fastness to rubbing index significantly improve, and its energy consumption can reduce more than 30% than the traditional secondary firing process, the microlite ceramic tile crystallization pattern that utilizes the bright crystallite dry granular of this law and related process to produce is graceful, change is infinite, naturally true to nature.
Should be understood that, application of the present invention is not limited to above-mentioned giving an example, and for those of ordinary skills, can be improved according to the above description or conversion, and all these improve and conversion all should belong to the protection domain of claims of the present invention.

Claims (9)

1. the preparation method of a crystallite dry granular, is characterized in that, comprises the following steps:
S1, former abrasive lapping: respectively silica powder, aluminum oxide, rhombspar, boric acid, lithium porcelain stone, potassium felspar sand are ground, make each feed particles globule size consistent;
S2, raw material mix: ground raw material is mixed being made into powder;
S3, found: mixed powder is entered be melting into the crystallite frit in kiln;
S4, granulation: the frit of founding out is dried, then pulverize, sieve;
S5, deironing: the particulate material after sieving is carried out deironing, make finished product.
2. the preparation method of crystallite dry granular according to claim 1, is characterized in that, in described step S1, each raw material particle size size is the 90-110 order.
3. the preparation method of crystallite dry granular according to claim 1, is characterized in that, in described step S2, each raw materials by weight is counted:
Silica powder 18-27%;
Aluminum oxide 15-20%;
Rhombspar 18-25%;
Boric acid 5-10%;
Lithium porcelain stone 28-38%;
Potassium felspar sand 5-10 %.
4. the preparation method of crystallite dry granular according to claim 1, is characterized in that, controlling blast in kiln in described step S3 is 0.01-0.4Mpa, and oil pressure is 0.2-0.6Mpa, and in stove, temperature is 1490-1510 ℃.
5. the preparation method of crystallite dry granular according to claim 1, is characterized in that, the granularity of the rear gained crystallite dry granular that sieves in described S4 is the 10-60 order, and wherein each order array becomes proportion to be:
10-20 order 60-70%;
20-40 order 15-25%;
40-60 order 5-15%;
The 60 above 0-10% of order.
6. the production method of a microlite ceramic tile, is characterized in that, the crystallite dry granular that has adopted preparation method's production of crystallite dry granular as described in claim 1 ~ 5 any one to obtain in the production method of described microlite ceramic tile; The production method of described microlite ceramic tile comprises the following steps:
A, carry out the adobe compacting after mixing for the raw material of base substrate processing;
B, carry out after drying surface cleaning to suppressing adobe, spread the cosmetic soil of decoration function on the adobe surface;
C, roller printing pattern;
D, at the dapple adobe of described seal surface charity one deck protection glaze, for the protection of the decorative pattern of printing;
E, on the protection glaze layer on described adobe surface even charity crystallite dry granular;
F, will spray in described adobe surface for the fixing fixing agent of crystallite dry granular;
G, advance klining system, once-firing is compound.
7. the production method of microlite ceramic tile according to claim 6, is characterized in that, and is further comprising the steps of:
H, the described product that burns till kiln discharge make finished product after polishing, edging technique.
8. the production method of microlite ceramic tile according to claim 6, is characterized in that, in described step G, firing temperature is 1130 ℃ ~ 1270 ℃.
9. one kind with the made microlite ceramic tile of microlite ceramic tile production method as claimed in claim 6; it is characterized in that; described microlite ceramic tile comprises adobe, cosmetic soil layer, protection glaze layer and crystallite dry granular layer, and described cosmetic soil layer, protection glaze layer and crystallite dry granular layer are set in turn in the adobe surface from the inside to surface.
CN201310005972.5A 2013-01-08 2013-01-08 A kind of preparation method of crystallite dry granular, microlite ceramic tile and production method thereof Expired - Fee Related CN103102078B (en)

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CN109849163A (en) * 2019-03-28 2019-06-07 江西和美陶瓷有限公司 The decorations brick of stereoscopic glaze made from leftover bits and pieces of material and its manufacturing method are scraped in a kind of utilization
CN110317051A (en) * 2019-08-02 2019-10-11 佛山市陶莹新型材料有限公司 A kind of diamond dry granular and its processing method

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CN103304277A (en) * 2013-06-26 2013-09-18 佛山瑭虹釉料科技有限公司 Microcrystal glass ceramic composite plate and one-time rapid sintering method thereof
CN105016780B (en) * 2014-04-28 2017-02-08 佛山市纳来建材有限公司 Dry particle glaze rock simulated ceramic tile production process
CN105016780A (en) * 2014-04-28 2015-11-04 佛山市纳来建材有限公司 Dry particle glaze rock simulated ceramic tile production process
CN104311154A (en) * 2014-10-10 2015-01-28 杭州诺贝尔陶瓷有限公司 Underglazed polychrome ceramic tile and manufacturing method thereof
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CN104311162B (en) * 2014-10-11 2019-05-21 德清诺贝尔陶瓷有限公司 A kind of Z-Correct bump mapping Z-correct glazed tile and preparation method thereof
CN104311162A (en) * 2014-10-11 2015-01-28 德清诺贝尔陶瓷有限公司 Bump texture glazed tile and preparation method thereof
CN104878900A (en) * 2015-05-29 2015-09-02 柳州普亚贸易有限公司 Construction method for microcrystalline stone ceramic tiles
CN105175023A (en) * 2015-08-27 2015-12-23 福建省德化县冠鸿陶瓷有限公司 Imitated cement abrasive glaze formula, preparation method and use method
CN105272160A (en) * 2015-11-04 2016-01-27 东莞市唯美陶瓷工业园有限公司 Single-fired glass ceramic composite brick and production method thereof
CN105272160B (en) * 2015-11-04 2018-07-03 东莞市唯美陶瓷工业园有限公司 It is primary to burn microcrystallite glass-ceramic composite brick and its production method
CN105622168A (en) * 2015-12-23 2016-06-01 佛山市唯格瓷砖有限责任公司 Anti-slipping wearproof dry granules and application thereof to anti-slipping wearproof ceramic tile
CN105622168B (en) * 2015-12-23 2018-07-24 佛山市唯格瓷砖有限责任公司 A kind of anti-skid wearable dry granular and its application in anti-skid wearable ceramic tile
CN107382373A (en) * 2017-06-16 2017-11-24 江西和美陶瓷有限公司 A kind of wear-resisting antiskid Ceramic Tiles and preparation method thereof
CN107935386A (en) * 2017-11-15 2018-04-20 蒙娜丽莎集团股份有限公司 Graininess dry granular glaze, graininess dry granular glaze cloth ashlar brick and preparation method thereof
CN108424111A (en) * 2018-01-25 2018-08-21 广东金牌陶瓷有限公司 A kind of ceramic plate and preparation method thereof greatly of light dry granular polishing
CN108424111B (en) * 2018-01-25 2021-07-06 广东金牌陶瓷有限公司 Bright dry-particle polished ceramic large plate and preparation method thereof
CN108218398A (en) * 2018-03-01 2018-06-29 佛山市高明丰霖新型材料有限公司 A kind of ceramic exterior wall brick dry granular and the ceramic exterior wall brick containing the dry granular
CN109053226A (en) * 2018-08-27 2018-12-21 河源市东源鹰牌陶瓷有限公司 The method for preparing dumb light dry granular glazed tile
CN109849163A (en) * 2019-03-28 2019-06-07 江西和美陶瓷有限公司 The decorations brick of stereoscopic glaze made from leftover bits and pieces of material and its manufacturing method are scraped in a kind of utilization
CN110317051A (en) * 2019-08-02 2019-10-11 佛山市陶莹新型材料有限公司 A kind of diamond dry granular and its processing method

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