CN110317051A - A kind of diamond dry granular and its processing method - Google Patents

A kind of diamond dry granular and its processing method Download PDF

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Publication number
CN110317051A
CN110317051A CN201910713678.7A CN201910713678A CN110317051A CN 110317051 A CN110317051 A CN 110317051A CN 201910713678 A CN201910713678 A CN 201910713678A CN 110317051 A CN110317051 A CN 110317051A
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mesh
parts
dry granular
raw material
particle
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CN110317051B (en
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全春辉
司金凯
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FOSHAN YUANMU DIGITAL TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/195Alkaline earth aluminosilicates, e.g. cordierite or anorthite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646Optical properties
    • C04B2235/9653Translucent or transparent ceramics other than alumina

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
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  • Organic Chemistry (AREA)
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  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a kind of diamond dry granulars, including following raw material: potassium feldspar, cordierite, mullite, crystal powder.The processing method of the diamond dry granular, including step 1, stock;Raw material substep is added in batch mixer by step 2, filling in order;Step 3, mixing;Step 4, high-temperature calcination;Step 5 is crushed classification;Step 6 is examined;Step 7, packaging, and the application method in fired brick include the following steps: test proportion, according to the dry granular adding proportion of glaze melting and antifouling adjustment variable grain gradation;Pretreatment, sprays overglaze in adobe using bell jar slip shower;Ink-jet, according to design spraying ink pattern and color on brick face after the pre-treatment;Spray drying grain sprays diamond dry granular on brick face;It fires, the adobe after upper dry granular is sent into kiln and is fired, and it is an object of the present invention to provide a kind of diamond dry granular and its processing method and the application method in fired brick, make diamond dry granular have good flash effect, hardness.

Description

A kind of diamond dry granular and its processing method
Technical field
The present invention relates to a kind of tile product paint field, specifically a kind of diamond dry granular and its processing method.
Background technique
Antique Imitation Tiles flash effect decoration, mainly flash imprint powder and mica sheet.Flash imprint powder is burnt under the high temperature conditions Cheng Shi, flash effect can give a discount;Mica sheet is usually black and white, is unable to large area application, otherwise influences glaze effect Fruit.Antique Imitation Tiles flash effect ornament materials needs abundant.
Summary of the invention
The purpose of the present invention is to provide a kind of diamond dry granular and its processing methods, to solve to propose in above-mentioned background technique The problem of.
To achieve the above object, the invention provides the following technical scheme:
A kind of diamond dry granular, the raw material including following parts by weight: 20 parts of potassium feldspar, 50 parts of cordierite, 15 parts of mullite, crystalline substance 5 parts of body powder, wherein after the above raw material mixing high-temperature calcination, be broken into the particle that particle matches: greater than 80 mesh with mass percent Accounting 2%-8%, less than or equal to 80 mesh and it is greater than the particle accounting 60%-80% of 120 mesh, is less than or equal to 120 mesh and big Particle accounting 15%-30% in 200 mesh, the particle accounting 1%-3% less than 200 mesh.
Specifically, including the raw material of following parts by weight: 20 parts of potassium feldspar, 50 parts of cordierite, 15 parts of mullite, crystal powder 5 Part;Wherein, particle accounting of the particle with mass percent with: greater than 80 mesh will after the above raw material mixing high-temperature calcination, be broken into 3%-6%, less than or equal to 80 mesh and be greater than 120 mesh particle accounting 68%-80%, be less than or equal to 120 mesh and be greater than 200 Purpose particle accounting 20%-28%, the particle accounting 1%-3% less than 200 mesh.
Specifically, including the raw material of following parts by weight: 20 parts of potassium feldspar, 50 parts of cordierite, 15 parts of mullite, crystal powder 5 Part;Wherein, particle accounting of the particle with mass percent with: greater than 80 mesh will after the above raw material mixing high-temperature calcination, be broken into 3%, less than or equal to 80 mesh and be greater than 120 mesh particle accounting 75%, less than or equal to 120 mesh and be greater than 200 mesh particle Accounting 21%, the particle accounting 1% less than 200 mesh.
A kind of processing method of diamond dry granular, comprising the following steps:
A1, stock obtain the constituent and its parts by weight of diamond dry granular;
Raw material in step A1 is grouped by A2, filling, and potassium feldspar is first group, and crystal powder is second group, cordierite With mullite be third group, every kind of raw material with etc. parts by weight the above raw material is successively put into batch mixer according to order of packets, it is complete After successively above-mentioned raw materials investment, repeats the above steps and surplus stock substep is added in batch mixer;
A3, mixing, starting mixing work, continuous mixing 40-50 minutes;
A4, high-temperature calcination, mixed raw material are calcined through 1320 DEG C, keep the temperature 13-15 hours;
A5 is crushed classification, and the calcined material after drying is crushed, and sorts according to variable grain gradation;
Whether A6 is examined, examine dry granular qualified;
A7, packaging pack the variable grain gradation dry granular of specific needs.
A kind of diamond dry granular of the invention, the beneficial effect is that, by providing a kind of dry granular production formula, add wherein Add cordierite and crystal powder, and allotment ratio, so that diamond dry granular of the invention is obtained flash effect and high rigidity, and color development is good.
A kind of processing method of diamond dry granular of the invention, the beneficial effect is that: by adjusting filling step, make each ingredient Raw material be uniformly mixed, guarantee that mixed Glaze Composition is balanced, more conducively ingredient is uniform after high-temperature calcination, and then improves product Quality.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched The embodiment stated is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, originally Field those of ordinary skill every other embodiment obtained without making creative work, belongs to the present invention The range of protection.
Embodiment one
A kind of diamond dry granular, the raw material including following parts by weight: 20 parts of potassium feldspar, 50 parts of cordierite, 15 parts of mullite, crystalline substance 5 parts of body powder, wherein after the above raw material mixing high-temperature calcination, be broken into the particle that particle matches: greater than 80 mesh with mass percent Accounting 2%-8%, less than or equal to 80 mesh and it is greater than the particle accounting 60%-80% of 120 mesh, is less than or equal to 120 mesh and big Particle accounting 15%-30% in 200 mesh, the particle accounting 1%-3% less than 200 mesh.
The following steps are included:
A1, stock, obtains the constituent and its parts by weight of the diamond dry granular;
Raw material in step A1 is grouped by A2, filling, and potassium feldspar is first group, and crystal powder is second group, cordierite With mullite be third group, every kind of raw material with etc. parts by weight the above raw material is successively put into batch mixer according to order of packets, it is complete After successively above-mentioned raw materials investment, repeats the above steps and surplus stock substep is added in batch mixer;
A3, mixing, starting mixing work, continuous mixing 40-50 minutes;
A4, high-temperature calcination, mixed raw material are calcined through 1320 DEG C, keep the temperature 13-15 hours;
A5 is crushed classification, and the calcined material after drying is crushed, and sorts according to variable grain gradation;
Whether A6 is examined, examine dry granular qualified;
A7, packaging pack the variable grain gradation dry granular of specific needs.
Embodiment two
A kind of diamond dry granular, the raw material including following parts by weight: 20 parts of potassium feldspar, 50 parts of cordierite, 15 parts of mullite, crystalline substance 5 parts of body powder;Wherein, particle of the particle with mass percent with: greater than 80 mesh will after the above raw material mixing high-temperature calcination, be broken into Accounting 3%-6%, less than or equal to 80 mesh and it is greater than the particle accounting 68%-80% of 120 mesh, is less than or equal to 120 mesh and big Particle accounting 20%-28% in 200 mesh, the particle accounting 1%-3% less than 200 mesh.
The following steps are included:
B1, stock, obtains the constituent and its parts by weight of the diamond dry granular;
Raw material in step B1 is grouped by B2, filling, and potassium feldspar is first group, and crystal powder is second group, cordierite With mullite be third group, every kind of raw material with etc. parts by weight the above raw material is successively put into batch mixer according to order of packets, it is complete After successively above-mentioned raw materials investment, repeats the above steps and surplus stock substep is added in batch mixer;
B3, mixing, starting mixing work, continuous mixing 40-50 minutes;
B4, high-temperature calcination, mixed raw material are calcined through 1320 DEG C, keep the temperature 13-15 hours;
B5 is crushed classification, and the calcined material after drying is crushed, and sorts according to variable grain gradation;
Whether B6 is examined, examine dry granular qualified;
B7, packaging pack the variable grain gradation dry granular of specific needs.
Embodiment three
A kind of diamond dry granular, the raw material including following parts by weight: the raw material including following parts by weight: 20 parts of potassium feldspar, violet 50 parts of green stone, 15 parts of mullite, 5 parts of crystal powder;Wherein, by after the above raw material mixing high-temperature calcination, particle is broken into quality Percentage with: greater than 80 mesh particle accounting 3%, less than or equal to 80 mesh and be greater than 120 mesh particle accounting 75%, be less than or Equal to 120 mesh and it is greater than the particle accounting 21% of 200 mesh, less than the particle accounting 1% of 200 mesh.
The following steps are included:
C1, stock, obtains the constituent and its parts by weight of the diamond dry granular;
Raw material in step C1 is grouped by C2, filling, and potassium feldspar is first group, and crystal powder is second group, cordierite With mullite be third group, every kind of raw material with etc. parts by weight the above raw material is successively put into batch mixer according to order of packets, it is complete After successively above-mentioned raw materials investment, repeats the above steps and surplus stock substep is added in batch mixer;
C3, mixing, starting mixing work, continuous mixing 40-50 minutes;
C4, high-temperature calcination, mixed raw material are calcined through 1320 DEG C, keep the temperature 13-15 hours;
C5 is crushed classification, and the calcined material after drying is crushed, and sorts according to variable grain gradation;
Whether C6 is examined, examine dry granular qualified;
C7, packaging pack the variable grain gradation dry granular of specific needs.
Application Example one
Using the diamond dry granular as described in embodiment one, with diamond dry granular: suspending agent=100:250 ratio, by two Person is mixed evenly to obtain glaze slip, and the glaze slip is sprayed in the adobe for sprayed overglaze, fires into kiln, kiln discharge, and detection is hard Degree, anti-fouling effect, flash effect.
Application Example two
Using the diamond dry granular as described in embodiment two, with diamond dry granular: suspending agent=100:250 ratio, by two Person is mixed evenly to obtain glaze slip, and the glaze slip is sprayed in the adobe for sprayed overglaze, fires into kiln, kiln discharge, and detection is hard Degree, anti-fouling effect, flash effect.
Application Example three
Using the diamond dry granular as described in embodiment three, with diamond dry granular: suspending agent=100:250 ratio, by two Person is mixed evenly to obtain glaze slip, and the glaze slip is sprayed in the adobe for sprayed overglaze, fires into kiln, kiln discharge, and detection is hard Degree, anti-fouling effect, flash effect.
Detection effect
Table 1
Project Embodiment one Embodiment two Embodiment three Comparative example one Comparative example two Comparative example three
Hardness (Mohs degree) 6 6 6 6 6 6
Anti-fouling effect 5 grades 5 grades 5 grades 5 grades 5 grades 5 grades
Flash effect It is excellent It is excellent It is excellent It is excellent It is excellent It is excellent
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (4)

1. a kind of diamond dry granular, which is characterized in that the raw material including following parts by weight: 20 parts of potassium feldspar, 50 parts of cordierite, Mo Lai 15 parts of stone, 5 parts of crystal powder, wherein after the above raw material mixing high-temperature calcination, be broken into particle with mass percent with: greater than The particle accounting 2%-8% of 80 mesh, less than or equal to 80 mesh and be greater than 120 mesh particle accounting 60%-80%, be less than or equal to 120 mesh and particle accounting 15%-30%, the particle accounting 1%-3% less than 200 mesh for being greater than 200 mesh.
2. a kind of diamond dry granular according to claim 1, which is characterized in that the raw material including following parts by weight: potassium feldspar 20 parts, 50 parts of cordierite, 15 parts of mullite, 5 parts of crystal powder;Wherein, by after the above raw material mixing high-temperature calcination, it is broken into particle Match the particle accounting 3%-6% of: greater than 80 mesh, less than or equal to 80 mesh and greater than the particle accounting of 120 mesh with mass percent 68%-80%, less than or equal to 120 mesh and be greater than 200 mesh particle accounting 20%-28%, less than the particle accounting of 200 mesh 1%-3%.
3. a kind of diamond dry granular according to claim 1, which is characterized in that the raw material including following parts by weight: potassium feldspar 20 parts, 50 parts of cordierite, 15 parts of mullite, 5 parts of crystal powder;Wherein, by after the above raw material mixing high-temperature calcination, it is broken into particle With mass percent with: greater than 80 mesh particle accounting 3%, less than or equal to 80 mesh and be greater than 120 mesh particle accounting 75%, Less than or equal to 120 mesh and it is greater than the particle accounting 21% of 200 mesh, less than the particle accounting 1% of 200 mesh.
4. a kind of processing method using a kind of any diamond dry granular of claim 1-3, which is characterized in that including following Step:
A1, stock obtain the constituent and its parts by weight of any one of the claims 1 to 3 diamond dry granular;
Raw material in step A1 is grouped by A2, filling, and potassium feldspar is first group, and crystal powder is second group, cordierite and not Carrying out stone is third group, every kind of raw material with etc. parts by weight successively put into the above raw material into batch mixer according to order of packets, complete according to After secondary above-mentioned raw materials investment, repeats the above steps and surplus stock substep is added in batch mixer;
A3, mixing, starting mixing work, continuous mixing 40-50 minutes;
A4, high-temperature calcination, mixed raw material are calcined through 1320 DEG C, keep the temperature 13-15 hours;
A5 is crushed classification, and the calcined material after drying is crushed, and sorts according to variable grain gradation;
Whether A6 is examined, examine dry granular qualified;
A7, packaging pack the variable grain gradation dry granular of specific needs.
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CN113387580A (en) * 2021-07-14 2021-09-14 佛山市陶莹新型材料有限公司 Starlight glaze and preparation method thereof
CN113666729A (en) * 2021-08-20 2021-11-19 河源市东源鹰牌陶瓷有限公司 White diamond glittering diamond glaze ceramic tile and preparation method thereof

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CN110304945A (en) * 2019-06-21 2019-10-08 佛山市雨果陶瓷有限公司 A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect

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