CN102491787A - High-temperature mirror surface flashy fritted glaze and preparation method thereof - Google Patents
High-temperature mirror surface flashy fritted glaze and preparation method thereof Download PDFInfo
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- CN102491787A CN102491787A CN2011103596041A CN201110359604A CN102491787A CN 102491787 A CN102491787 A CN 102491787A CN 2011103596041 A CN2011103596041 A CN 2011103596041A CN 201110359604 A CN201110359604 A CN 201110359604A CN 102491787 A CN102491787 A CN 102491787A
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Abstract
The invention provides a high-temperature mirror surface flashy fritted glaze and a preparation method thereof. The high-temperature mirror surface flashy fritted glaze consists of the following components in percentage by weight: 50 to 60 percent of SiO2, 8 to 11 percent of Al2O3, 0.2 to 0.5 percent of Fe2O3, 2 to 6 percent of CaO, 1 to 3 percent of MgO, 3 to 5 percent of K2O, 1 to 3 percent of Na2O, 0.05 to 0.15 percent of TiO2, 4 to 8 percent of ZrO2, 6 to 10 percent of ZnO and 8 to 11 percent of CeO2. The high-temperature mirror surface flashy fritted glaze has the beneficial effects that: the fire degree of the fritted glaze is improved due to mica; mullite crystalline phase is produced, so that an abrasion resistance effect and a heat resistance effect are enhanced; and a mirror surface can be kept flashy. Furthermore, a lead oxide does not exist in the formula, so that the high-temperature mirror surface flashy fritted glaze meets the environmentally-friendly requirement.
Description
Technical field
The present invention relates to a kind of fritted glaze that is used for ceramic surface.
Background technology
Fritted glaze is a kind of compsn that is used for ceramic surface.Wherein, the flash of light fritted glaze is a kind of decorative art glaze that grew up in recent years.Can on wall floor tile and domestic ceramics, print various color patterns with it, have the reflecting effect as the minute surface after burning till, a part of user's that can suit appreciation requirement.But this product so far, and the cost of preparation is very high, and firing range is narrow; Prescription is mostly introduced the red lead and is fluxed with its enhancing metalluster, but the very much not environmental protection of red lead toxicity, and incompatibility high temperature burns till; Flash effect is poor when more than high temperature 1190 degree, burning till, and glaze is not wear-resisting.
Summary of the invention
The purpose of this invention is to provide a kind of high temperature minute surface flash of light fritted glaze and preparation method thereof,, make its environmental protection to overcome the above-mentioned defective that prior art exists, wear-resisting, high temperature resistant, keep the minute surface flash of light.
It is the basis that raw material adopts raw mineral materialss such as feldspar, quartz, talcum, coarse whiting, zircon, and chemical constitution is following:
High temperature minute surface flash of light fritted glaze of the present invention, form by following components in weight percentage:
Each percentages of ingredients sum is 100%.
Preferably, high temperature minute surface flash of light fritted glaze of the present invention, form by following components in weight percentage:
The preparation method of high temperature minute surface flash of light fritted glaze of the present invention comprises the steps:
With quartz, potassium felspar sand, albite, rhombspar, coarse whiting, talcum, zircon, mica, zinc oxide and cerium oxide; Ball milling to 200 order mixes respectively, fires 1.5～2 hours for 1530～1540 ℃; Obtain frit through shrend; Ball milling to fineness is 325 orders then, is crushed to 325 orders after the oven dry, is
Described high temperature minute surface flash of light fritted glaze;
Term " shrend " refers to high temp glass liquid that compound forms and slowly flows into the process that cool quickly in the water below 60 ℃ makes its quenching after high-temperature fusion;
The weight percent component of raw material is following:
Each percentages of ingredients sum is 100%.
Preferably, the weight percent of each component is:
In the raw material that the present invention adopts, added mica, can improve it and burn till warm territory, made softening temperature and firing temperature meet the requirement and the wear-resisting effect of raising overglaze of parent glaze;
The present invention selects ZrO
2, TiO
2And CeO
2As opacifying agent, have high refractivity, the tiny crystal of one deck is evenly separated out in the cooling back on glaze, can make glaze as bright as a sixpence, reaches the effect of flash of light.
In the prescription of the present invention; Higher ZnO and CaO are arranged, can improve the thermostability of overglaze planeness and glaze, strengthened the phase-splitting trend of glaze; Its result cause second in mother liquor isolated or continuous distribution, and through second with the optical effect generation flash effect of glassy phase.
The method of use of the high temperature minute surface flash of light fritted glaze of the present invention's preparation is following:
The high temperature minute surface flash of light fritted glaze that obtains is mixed with stamp-pad ink, and the furnishing creme is printed on creme the ceramic tile surface of executing one deck cover-coat enamel through silk screen printing; Drying is gone into stove and is burnt till, and firing temperature is 1100～1200 ℃; Time is 0.75～1 hour, can obtain to have flash of light overglaze ceramic tile.
Described stamp-pad ink, form by following components in weight percentage:
CMC 1.36％
Terepthaloyl moietie 54.20%
Water 44.44%
The invention has the beneficial effects as follows:
Having added mica makes it improve fiery degree and has produced the mullite crystalline phase and improve wear-resisting, high-temperature resistant result and the flash of light of maintenance minute surface.Prescription has been removed lead oxides and has been made its compliance with environmental protection requirements simultaneously.
Embodiment
The weight percent component of the raw material that embodiment adopts is following:
Embodiment 1
Prescription: (weight percent)
The preparation method:
With quartz, potassium felspar sand, albite, rhombspar, coarse whiting, talcum, zircon, mica, zinc oxide and cerium oxide, ball milling to 325 order mixes respectively; Fired 2 hours for 1540 ℃; Obtain frit, shrend, ball milling to fineness is 325 orders then; Be crushed to 325 orders after the oven dry, be described high temperature minute surface flash of light fritted glaze;
Method of use is following:
The high temperature minute surface flash of light fritted glaze that obtains is mixed with stamp-pad ink, and the furnishing creme is printed on creme the ceramic tile surface of executing one deck cover-coat enamel through silk screen printing; Drying is gone into stove and is burnt till, and firing temperature is 1100 ℃; Time is 1 hour, can obtain to have flash of light overglaze ceramic tile.
Described stamp-pad ink, form by following components in weight percentage:
CMC 1.36％
Terepthaloyl moietie 54.20%
Water 44.44%
Adopt range estimation to compare; This patent high temperature flash of light fritted glaze of firing according to method of use is put with the brick of other high temperature flash of light fritted glazes and is compared; Observe its glaze surface evenness, flash effect and fastness to rubbing, this patent glaze surface evenness is more smooth, and flash of light gloss is stronger than other high temperature flash of light fritted glazes; Fastness to rubbing removes to draw a glaze with broken ceramic tile, finds that this patent glaze is not easy to scratch and other high temperature flash of light fritted glaze ratios are easier to scratch.
Embodiment 2
Prescription: (weight percent)
The preparation method:
With quartz, potassium felspar sand, albite, rhombspar, coarse whiting, talcum, zircon, mica, zinc oxide and cerium oxide, ball milling to 200 order mixes respectively; Fired 2 hours for 1540 ℃; Obtain frit, shrend, ball milling to fineness is 325 orders then; Be crushed to 325 orders after the oven dry, be described high temperature minute surface flash of light fritted glaze;
Method of use is following:
The high temperature minute surface flash of light fritted glaze that obtains is mixed with stamp-pad ink, and the furnishing creme is printed on creme the ceramic tile surface of executing one deck cover-coat enamel through silk screen printing; Drying is gone into stove and is burnt till, and firing temperature is 1100 ℃; Time is 1 hour, can obtain to have flash of light overglaze ceramic tile.
Described stamp-pad ink, form by following components in weight percentage:
CMC 1.36％
Terepthaloyl moietie 54.20%
Water 44.44%
Through range estimation relatively; This patent high temperature flash of light fritted glaze of firing according to method of use is put with the brick of other high temperature flash of light fritted glazes and is compared; Observe its glaze surface evenness, flash effect and fastness to rubbing, this patent glaze surface evenness is more smooth, and flash of light gloss is stronger than other high temperature flash of light fritted glazes; Fastness to rubbing removes to draw a glaze with broken ceramic tile, finds that this patent glaze is not easy to scratch and other high temperature flash of light fritted glaze ratios are easier to scratch.
Claims (5)
1. high temperature minute surface flash of light fritted glaze is characterized in that, is made up of following components in weight percentage:
Each percentages of ingredients sum is 100%.
2. high temperature minute surface flash of light fritted glaze according to claim 1 is characterized in that, is made up of following components in weight percentage:
3. the preparation method of high temperature minute surface flash of light fritted glaze according to claim 1 and 2 is characterized in that, comprises the steps:
With quartz, potassium felspar sand, albite, rhombspar, coarse whiting, talcum, zircon, mica, zinc oxide and cerium oxide; Ball milling to 200 order mixes respectively, fires 1.5～2 hours for 1530～1540 ℃; Obtain frit through shrend; Ball milling to fineness is 325 orders then, is crushed to 325 orders after the oven dry, is described high temperature minute surface flash of light fritted glaze.
4. method according to claim 3 is characterized in that, the weight percent of each component is:
Each percentages of ingredients sum is 100%.
5. method according to claim 4 is characterized in that, preferred, the weight percent of each component is:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110359604 CN102491787B (en) | 2011-11-14 | 2011-11-14 | High-temperature mirror surface flashy fritted glaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110359604 CN102491787B (en) | 2011-11-14 | 2011-11-14 | High-temperature mirror surface flashy fritted glaze and preparation method thereof |
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| CN102491787A true CN102491787A (en) | 2012-06-13 |
| CN102491787B CN102491787B (en) | 2013-05-01 |
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| CN 201110359604 Expired - Fee Related CN102491787B (en) | 2011-11-14 | 2011-11-14 | High-temperature mirror surface flashy fritted glaze and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106746646A (en) * | 2016-12-15 | 2017-05-31 | 宜兴市吾牛陶紫砂艺术研究院 | A kind of equal bristol glaze |
| CN107021633A (en) * | 2017-03-17 | 2017-08-08 | 界首市伟盛古窑彩陶制作发展有限公司 | A kind of high-temperature environmental-protection colored glaze |
| CN110304945A (en) * | 2019-06-21 | 2019-10-08 | 佛山市雨果陶瓷有限公司 | A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect |
| CN110317051A (en) * | 2019-08-02 | 2019-10-11 | 佛山市陶莹新型材料有限公司 | A kind of diamond dry granular and its processing method |
| CN110452020A (en) * | 2019-08-22 | 2019-11-15 | 福建省太古陶瓷有限责任公司 | It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings |
| CN110482859A (en) * | 2019-09-17 | 2019-11-22 | 广东新润成陶瓷有限公司 | A kind of starlight glaze Ceramic Tiles and preparation method thereof |
| CN110698067A (en) * | 2019-11-15 | 2020-01-17 | 佛山市东鹏陶瓷有限公司 | Wear-resistant glaze for preparing sanitary ceramics and method for preparing sanitary ceramics |
| CN111423113A (en) * | 2020-06-09 | 2020-07-17 | 蒙娜丽莎集团股份有限公司 | Polished glazed brick with dry diamond grains and positioning diamond flashing effect and preparation method thereof |
| CN112174526A (en) * | 2020-10-12 | 2021-01-05 | 山东工艺美术学院 | Formula of glittering glaze for ceramic art manufacturing |
| CN112194369A (en) * | 2020-10-26 | 2021-01-08 | 佛山市东鹏陶瓷发展有限公司 | Wear-resistant frit, preparation method of frit and glaze using frit |
| CN112608029A (en) * | 2020-12-28 | 2021-04-06 | 肇庆乐华陶瓷洁具有限公司 | Dazzling archaized brick and preparation method thereof |
| CN114455840A (en) * | 2022-01-06 | 2022-05-10 | 蒙娜丽莎集团股份有限公司 | Ceramic plate with anti-counterfeiting visual effect and preparation method thereof |
| CN117105698A (en) * | 2023-09-12 | 2023-11-24 | 福建省德化县鹏立达陶瓷工艺有限公司 | Flash rock glaze ceramic imitating rough surface and preparation method thereof |
| CN117125896A (en) * | 2023-10-26 | 2023-11-28 | 佛山市东鹏陶瓷有限公司 | Archaized glaze easy to clean, preparation method thereof and archaized ceramic tile easy to clean |
| CN117700258A (en) * | 2024-02-05 | 2024-03-15 | 佛山市东鹏陶瓷有限公司 | Metal flash glaze, preparation method thereof and glazed tile |
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| CN102115342A (en) * | 2011-04-06 | 2011-07-06 | 湖南嘉盛电陶新材料股份有限公司 | Preparation method for low-expansion ceramic glaze |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1043290A1 (en) * | 1999-04-08 | 2000-10-11 | Ngk Insulators, Ltd. | Carbonaceous material having oxidation-resistant protective layer and method for producing the same |
| CN101671116A (en) * | 2009-10-15 | 2010-03-17 | 湖南泰鑫瓷业有限公司 | Preparation method for colorful snowflake crystallization glaze |
| CN102115342A (en) * | 2011-04-06 | 2011-07-06 | 湖南嘉盛电陶新材料股份有限公司 | Preparation method for low-expansion ceramic glaze |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106746646A (en) * | 2016-12-15 | 2017-05-31 | 宜兴市吾牛陶紫砂艺术研究院 | A kind of equal bristol glaze |
| CN107021633A (en) * | 2017-03-17 | 2017-08-08 | 界首市伟盛古窑彩陶制作发展有限公司 | A kind of high-temperature environmental-protection colored glaze |
| CN110304945A (en) * | 2019-06-21 | 2019-10-08 | 佛山市雨果陶瓷有限公司 | A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect |
| CN110317051A (en) * | 2019-08-02 | 2019-10-11 | 佛山市陶莹新型材料有限公司 | A kind of diamond dry granular and its processing method |
| CN110452020B (en) * | 2019-08-22 | 2023-09-01 | 福建省太古陶瓷有限责任公司 | Black matrix flash glaze ceramic prepared by introducing quartz ore tailings and manufacturing process thereof |
| CN110452020A (en) * | 2019-08-22 | 2019-11-15 | 福建省太古陶瓷有限责任公司 | It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings |
| CN110482859A (en) * | 2019-09-17 | 2019-11-22 | 广东新润成陶瓷有限公司 | A kind of starlight glaze Ceramic Tiles and preparation method thereof |
| CN110698067A (en) * | 2019-11-15 | 2020-01-17 | 佛山市东鹏陶瓷有限公司 | Wear-resistant glaze for preparing sanitary ceramics and method for preparing sanitary ceramics |
| CN111423113A (en) * | 2020-06-09 | 2020-07-17 | 蒙娜丽莎集团股份有限公司 | Polished glazed brick with dry diamond grains and positioning diamond flashing effect and preparation method thereof |
| CN112174526A (en) * | 2020-10-12 | 2021-01-05 | 山东工艺美术学院 | Formula of glittering glaze for ceramic art manufacturing |
| CN112194369A (en) * | 2020-10-26 | 2021-01-08 | 佛山市东鹏陶瓷发展有限公司 | Wear-resistant frit, preparation method of frit and glaze using frit |
| CN112194369B (en) * | 2020-10-26 | 2022-03-25 | 佛山市东鹏陶瓷发展有限公司 | Wear-resistant frit, preparation method of frit and glaze using frit |
| CN112608029A (en) * | 2020-12-28 | 2021-04-06 | 肇庆乐华陶瓷洁具有限公司 | Dazzling archaized brick and preparation method thereof |
| CN114455840B (en) * | 2022-01-06 | 2023-01-24 | 蒙娜丽莎集团股份有限公司 | Ceramic plate with anti-counterfeiting visual effect and preparation method thereof |
| WO2023130932A1 (en) * | 2022-01-06 | 2023-07-13 | 蒙娜丽莎集团股份有限公司 | Ceramic plate having anti-counterfeiting visual effect and preparation method therefor |
| CN114455840A (en) * | 2022-01-06 | 2022-05-10 | 蒙娜丽莎集团股份有限公司 | Ceramic plate with anti-counterfeiting visual effect and preparation method thereof |
| CN117105698A (en) * | 2023-09-12 | 2023-11-24 | 福建省德化县鹏立达陶瓷工艺有限公司 | Flash rock glaze ceramic imitating rough surface and preparation method thereof |
| CN117125896A (en) * | 2023-10-26 | 2023-11-28 | 佛山市东鹏陶瓷有限公司 | Archaized glaze easy to clean, preparation method thereof and archaized ceramic tile easy to clean |
| CN117125896B (en) * | 2023-10-26 | 2024-02-06 | 佛山市东鹏陶瓷有限公司 | Archaized glaze easy to clean, preparation method thereof and archaized ceramic tile easy to clean |
| CN117700258A (en) * | 2024-02-05 | 2024-03-15 | 佛山市东鹏陶瓷有限公司 | Metal flash glaze, preparation method thereof and glazed tile |
| CN117700258B (en) * | 2024-02-05 | 2024-05-14 | 佛山市东鹏陶瓷有限公司 | Metal flash glaze, preparation method thereof and glazed tile |
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| CN102491787B (en) | 2013-05-01 |
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Granted publication date: 20130501 Termination date: 20171114 |