CN110304945A - A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect - Google Patents

A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect Download PDF

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Publication number
CN110304945A
CN110304945A CN201910539744.3A CN201910539744A CN110304945A CN 110304945 A CN110304945 A CN 110304945A CN 201910539744 A CN201910539744 A CN 201910539744A CN 110304945 A CN110304945 A CN 110304945A
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China
Prior art keywords
flash
wear
coat enamel
ground coat
adobe
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麦永尤
潘杰生
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Foshan Hugo Ceramics Co Ltd
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Foshan Hugo Ceramics Co Ltd
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Priority to CN201910539744.3A priority Critical patent/CN110304945A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

Abstract

The present invention discloses a kind of wear-resistant ceramic brick with diamond luster effect, and the ceramic tile includes successively compound adobe, ground coat enamel and flash of light dry granule layer from the bottom to top;Preparation method are as follows: in adobe after charity ground coat enamel, flash of light dry granular is distributed in adobe surface, and the surface that fixative the is sprayed on flash of light dry granule layer dry granular that makes to glisten is fixed, adobe is delivered to roller kiln burning at obtaining Ceramic Tiles finished product through following process.The Mohs' hardness of Ceramic Tiles of the invention reaches 8-10 grades, wear-resisting grade, stain resistance reach 5 grades, other indices meet or exceed national standard, physicochemical property is excellent, especially under light-illuminating, ceramic tile surface has the flashing of diamond brilliance, as stars shining brightly in the clear sky in quiet space, so that decoration space is built unique romantic, there are good market prospects.

Description

A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect
Technical field
The present invention relates to technical field of ceramic production, more particularly relate to a kind of wear-resistant ceramic with diamond luster effect Brick and preparation method thereof.
Background technique
Ceramic Tiles be by clay, potassium feldspar, albite and other inorganic non-metallic raw materials, through ingredient, ball milling, powder processed, The plate or Bulk ceramic product of the techniques production such as molding, sintering, are widely used in the wall of decoration with protection building, structures Face and ground.
In the manufacture of Ceramic Tiles, the glossiness of various products has the different forms of expression, such as unglazed, dumb light, and satin is high Light, the different luster effect such as light.Common product is the whole glossiness be burnt by glaze itself to show the light of product Damp degree effect, conventional glaze brick product are mostly matte surface and shining surfaces, and polished bricks, full glaze product of throwing can be only achieved after polishing High gloss, it is not the luster effect reflected with glaze itself, and the glossiness in entire brick face reaches unanimity, and is not had too Big variation, visual glossiness do not have apparent contrast.
CN104529553A disclose a kind of surface manufacture with ceramic waste for example it is broken bore sand flash starlight glazed tile and Preparation method mainly keeps pico- concavo-convex using crystallization frit grain in the program after calcination at high temperature, and energy again after cooling down Again tiny such as pyroxene, aspidelite crystalline solid is precipitated, these crystal are tiny and quantity is more, can issue under light-illuminating as broken Bore sand shape twinkLing stars light.But the melted higher cost of such method frit, and complex process.Currently on the market to brill can be generated The glaze of stone luster effect and the research of Ceramic Tiles are less.
Summary of the invention
It is an object of the invention to overcome defect of the existing technology, provide a kind of with the wear-resisting of diamond luster effect Ceramic Tiles and preparation method thereof.
To achieve the goals above, The technical solution adopted by the invention is as follows:
The wear-resistant ceramic brick for flashing diamond luster effect of the invention, the ceramic tile include successively compound from the bottom to top Adobe, ground coat enamel and flash of light dry granule layer;Preparation method are as follows: in adobe after charity ground coat enamel, flash of light dry granular is distributed in adobe table Face, and fix flash of light dry granular the surface that fixative is sprayed on flash of light dry granule layer, adobe is delivered to roller kiln burning at after Continuous processing, obtains Ceramic Tiles finished product;
The flash of light dry granular presses 50-100:40-70:15- by corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet The mass ratio of 40:10-50:50-200 forms;
The ground coat enamel is by zinc oxide, zirconium silicate, albite, calcite, dolomite, kaolin, albite, talcum, dioxy SiClx colloidal sol, graphene are prepared.
Preferably, it is described flash of light dry granular the preparation method comprises the following steps: by raw material add water polo be milled to flash of light dry granular raw material partial size not Greater than 0.3mm, drying obtains flash of light dry granular.
Preferably, the Iron Ore Powder is micaceous iron oxide.
Preferably, the ground coat enamel is prepared by the raw material of following parts by weight: 8-20 parts of zinc oxide, 8-20 parts of zirconium silicate, 50-100 parts of albite, 80-150 parts of kaolin, 30-60 parts of talcum, 30-70 parts of silicon dioxide gel, 5-20 parts of graphene.
Preferably, the ground coat enamel the preparation method comprises the following steps: by the raw material ball milling 8-10h of ground coat enamel, cross 150-200 mesh, be added Concentration is the carboxymethyl cellulose aqueous solution of 1-5%, makes glaze specific gravity 1.4-1.5, obtains ground coat enamel.
Preferably, the firing temperature of the wear-resistant ceramic brick is 1150-1200 DEG C, firing time 45-75min.
Preferably, the fixative is made of the raw material of following weight percent: carboxymethyl cellulose 3-5%, stamp-pad ink 1- 5%, kaolin 0.5-2%, glue 89-95%.
The present invention is by adopting the above-described technical solution, have the advantages that
1, flash of light dry granular of the invention is by materials such as corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheets by certain ratio Example configures, and there is the claimed flare pellet of mica on surface, more approaches the true Shi Xiaoguo of lithotome, has evaded high-temperature fusion, quenched Take the technique for preparing dry granular, need to introduce a large amount of flux raw material, the increase of glass ingredient and cause the reduction of wearability to be asked Topic.This product sidelight under natural light is visual, it can be seen that ceramic brick surface has the claimed flare pellet of apparent fine particle shape, class Like the glistening reflecting effect of multiple very tiny diamonds;And under optically focused light irradiation, this similar diamond reflection light effect It is more obvious, it glitters, incomparably enhances the dicoration of ceramic brick product as diamond flashes under flash lamp.
2, applicant after test of many times is debugged, is mixing suitable ground coat enamel material formula, the brick face after high temperature firing It glitters like jet pierer and hard, after tested, the Mohs' hardness in brick face can reach 10 grades, and can match in excellence or beauty diamond, no It only glitters wear-resisting, there are also superpower skid resistance, and the glaze being closed completely can make Ceramic Tiles be more easier cleaning to arrange, have The stain resistance of color.
3, the present invention obtains this product using once-firing complex technique, so that the indexs such as hardness and wearability of this product It greatly improves, solves the problems, such as that twice firing Ceramic Tiles hardness is low, wears no resistance, and once-firing technology is more environmentally-friendly, Its energy consumption can reduce 30% or more, utilize the flash of light dry granular ceramic brick surface produced with diamond luster of the bright offer of this law Naturally true to nature, screen decorating machine charity flash glaze can also be used, keeps ceramic brick surface pattern graceful, changes infinite.
4, product water absorption rate of the invention is 0.19%, and Mohs' hardness reaches 8-10 grades, and wear-resisting grade, stain resistance reach To 5 grades, other indices meet or exceed national standard, and obtained product surface is flat and smooth, and water absorption rate is low, and intensity is high, no Easy fracture, physicochemical property is excellent, has good market prospects.
Detailed description of the invention
Fig. 1 is the photo for the wear-resistant ceramic brick that the present invention has diamond luster effect.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention more comprehensible, preferred embodiment is enumerated below, to this hair Bright further description.However, it is necessary to illustrate, many details listed in specification are used for the purpose of making reader to this The one or more aspects of invention have a thorough explanation, also may be implemented even without these specific details of the invention These aspects.
Embodiment 1
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) zinc oxide 8kg, zirconium silicate 8kg, albite 50kg, kaolin 80kg, talcum 30kg, silicon dioxide gel are taken Above-mentioned raw materials ball milling 3h is crossed 50 meshes by 30kg, graphene 5kg, and the carboxymethyl cellulose aqueous solution that concentration is 1% is added, makes Glaze specific gravity is 1.4, obtains ground coat enamel;
(2) corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet are mixed by the mass ratio of 50:70:15:10:200 Uniformly, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0.3mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 300g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 1.5kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1150 DEG C, and firing time is 75min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 3%, stamp-pad ink 5%, kaolin 0.5%, glue 91.5%.
Embodiment 2
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) take zinc oxide 10kg, zirconium silicate 10kg, albite 59kg, kaolin 92kg, talcum 35kg, silica molten Above-mentioned raw materials ball milling 3.8h is crossed 75 meshes by glue 37kg, graphene 7kg, and the carboxymethyl cellulose water that concentration is 1.7% is added Solution makes glaze specific gravity 1.42, obtains ground coat enamel;
(2) corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet are mixed by the mass ratio of 100:40:40:50:50 Uniformly, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0.3mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 360g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 1.6kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1160 DEG C, and firing time is 70min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 5%, stamp-pad ink 1%, kaolin 2%, glue 92%.
Embodiment 3
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) take zinc oxide 12kg, zirconium silicate 12kg, albite 68kg, kaolin 105kg, talcum 40kg, silica molten Glue 45kg, graphene 10kg sieve with 100 mesh sieve above-mentioned raw materials ball milling 4.6h, and the carboxymethyl cellulose that concentration is 2.5% is added Aqueous solution makes glaze specific gravity 1.45, obtains ground coat enamel;
(2) corundum, micaceous iron oxide, zirconium dioxide, titanium dioxide and mica sheet are pressed to the mass ratio of 89:46:18:24:188 It is uniformly mixed, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0.2mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 430g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 1.4kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1170 DEG C, and firing time is 65min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 5%, stamp-pad ink 5%, kaolin 1%, glue 89%.
Embodiment 4
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) take zinc oxide 14kg, zirconium silicate 14kg, albite 78kg, kaolin 120kg, talcum 48kg, silica molten Above-mentioned raw materials ball milling 5.5h is crossed 150 meshes by glue 53kg, graphene 12kg, and the carboxymethyl cellulose that concentration is 3.2% is added Aqueous solution makes glaze specific gravity 1.47, obtains ground coat enamel;
(2) corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet are mixed by the mass ratio of 56:68:17:43:105 Uniformly, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0.2mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 480g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 1.8kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1180 DEG C, and firing time is 60min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 3.2%, stamp-pad ink 1.1%, kaolinite Soil 0.7%, glue 95%.
Embodiment 5
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) take zinc oxide 16kg, zirconium silicate 16kg, albite 86kg, kaolin 128kg, talcum 52kg, silica molten Glue 60kg, graphene 15kg sieve with 100 mesh sieve above-mentioned raw materials ball milling 6.3h, and the carboxymethyl cellulose that concentration is 3.5% is added Aqueous solution makes glaze specific gravity 1.5, obtains ground coat enamel;
(2) corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet are mixed by the mass ratio of 88:60:20:35:90 Uniformly, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0.2mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 530g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 0.4kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1190 DEG C, and firing time is 55min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 4.3%, stamp-pad ink 2.7%, kaolinite Soil 1.4%, glue 91.6%.
Embodiment 6
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) take zinc oxide 18kg, zirconium silicate 18kg, albite 95kg, kaolin 140kg, talcum 56kg, silica molten Above-mentioned raw materials ball milling 7h is crossed 75 meshes by glue 65kg, graphene 18kg, and it is water-soluble that the carboxymethyl cellulose that concentration is 4.2% is added Liquid makes glaze specific gravity 1.45, obtains ground coat enamel;
(2) corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet are mixed by the mass ratio of 95:70:37:14:136 Uniformly, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0., 2mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 570g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 0.3kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1200 DEG C, and firing time is 50min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 3.3%, stamp-pad ink 3%, kaolin 0.9%, glue 92.8%.
Embodiment 7
Wear-resistant ceramic brick with diamond luster effect of the invention, including successively compound adobe, ground coat enamel from the bottom to top Layer and flash of light dry granule layer, preparation method include the following steps:
(1) zinc oxide 20kg, zirconium silicate 20kg, albite 100kg, kaolin 150kg, talcum 60kg, silica are taken Above-mentioned raw materials ball milling 8h is crossed 50 meshes by colloidal sol 70kg, graphene 20kg, and it is water-soluble that the carboxymethyl cellulose that concentration is 5% is added Liquid makes glaze specific gravity 1.46, obtains ground coat enamel;
(2) corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet are mixed by the mass ratio of 75:52:36:46:160 Uniformly, water is added in the mixed material, the partial size for being milled to above-mentioned raw materials is 0.3mm, and drying obtains flash of light dry granular;
(3) in raw adobe charity step (1) ground coat enamel, glaze volume 650g/m2, then by distributing device uniformly by step (2) flash of light dry granular cloth imposes on the surface of the life adobe of existing ground coat enamel, and the cloth total amount for the dry granular that glistens is 0.2kg/m2, then spray Applying fixative fixes flash of light dry granular, which is delivered to roller kiln burning at firing temperature is 1200 DEG C, and firing time is 45min, then processed through subsequent cutting, edging etc., obtain Ceramic Tiles finished product.
The fixative is made of the raw material of following weight percent: carboxymethyl cellulose 4.6%, stamp-pad ink 1.7%, kaolinite Soil 1%, glue 92.7%.
Properties of product test
Referred to according to the partial properties of Ceramic Tiles obtained by standard GB/T/T3810-2016 detection 1-7 of the embodiment of the present invention Mark, the results are shown in Table 1.
Water absorption rate (%) Confficient of static friction (dry method) Surface quality Stain resistance Wear-resisting grade
0.19 0.78 It is qualified 5 grades 5 grades
The chemical reagent of resistance to family Mohs' hardness Anti- glaze fragility Acid resistance Alkali resistance
GA grades 8-10 grades It is qualified GLA grades GLA grades
Table 1
As seen from the above table, Ceramic Tiles produced by the present invention have good wearability, corrosion resistance, stain resistance, acidproof The various performance indicators such as alkalinity, are applicable not only to daily household, are also very suitable for using in public places.Obtained Ceramic Tiles table Face is smooth, and water absorption rate is low, and intensity is high, and not easy to break, physicochemical property is excellent, and especially under light-illuminating, ceramic tile surface has brill Honorable flashing makes decoration space build unique romantic if stars shining brightly in the clear sky in quiet space as stone, has good city Field prospect.

Claims (7)

1. a kind of wear-resistant ceramic brick with diamond luster effect, which is characterized in that the ceramic tile includes successively multiple from the bottom to top Adobe, ground coat enamel and the flash of light dry granule layer of conjunction;Preparation method are as follows: in adobe after charity ground coat enamel, flash of light dry granular is distributed in brick Base surface, and by fixative be sprayed on flash of light dry granule layer surface make glisten dry granular fix, by adobe be delivered to roller kiln burning at, Through following process, Ceramic Tiles finished product is obtained;
The flash of light dry granular presses 50-100:40-70:15-40:10- by corundum, Iron Ore Powder, zirconium dioxide, titanium dioxide and mica sheet The mass ratio of 50:50-200 forms;
The ground coat enamel is by zinc oxide, zirconium silicate, albite, calcite, dolomite, kaolin, albite, talcum, silica Colloidal sol, graphene are prepared.
2. the wear-resistant ceramic brick according to claim 1 with diamond luster effect, which is characterized in that the flash of light dry granular The preparation method comprises the following steps: adding water polo to be milled to the partial size of flash of light dry granular raw material no more than 0.3mm raw material, drying obtains flash of light dry granular.
3. the wear-resistant ceramic brick according to claim 1 with diamond luster effect, which is characterized in that the Iron Ore Powder is Micaceous iron oxide.
4. the wear-resistant ceramic brick according to claim 1 with diamond luster effect, which is characterized in that the ground coat enamel is by such as The raw material of lower parts by weight is prepared: 8-20 parts of zinc oxide, 8-20 parts of zirconium silicate, 50-100 parts of albite, kaolin 80-150 Part, 30-60 parts of talcum, 30-70 parts of silicon dioxide gel, 5-20 parts of graphene.
5. the wear-resistant ceramic brick according to claim 4 with diamond luster effect, which is characterized in that the system of the ground coat enamel Preparation Method are as follows: by the raw material ball milling 8-10h of ground coat enamel, cross 150-200 mesh, the carboxymethyl cellulose water that concentration is 1-5% is added Solution makes glaze specific gravity 1.4-1.5, obtains ground coat enamel.
6. the wear-resistant ceramic brick according to claim 1 with diamond luster effect, which is characterized in that the wear-resistant ceramic The firing temperature of brick is 1150-1200 DEG C, firing time 45-75min.
7. the wear-resistant ceramic brick according to claim 1 with diamond luster effect, which is characterized in that the fixative by The raw material composition of following weight percent: carboxymethyl cellulose 3-5%, stamp-pad ink 1-5%, kaolin 0.5-2%, glue 89- 95%.
CN201910539744.3A 2019-06-21 2019-06-21 A kind of wear-resistant ceramic brick and preparation method thereof with diamond luster effect Pending CN110304945A (en)

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CN110317051A (en) * 2019-08-02 2019-10-11 佛山市陶莹新型材料有限公司 A kind of diamond dry granular and its processing method
CN112694344A (en) * 2020-12-18 2021-04-23 佛山市大角鹿大理石瓷砖有限公司 Preparation method of micro-carving super-wear-resistant diamond glaze ceramic tile and micro-carving super-wear-resistant diamond glaze ceramic tile

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CN206737329U (en) * 2017-03-21 2017-12-12 四川精科陶瓷研发有限公司 One kind flash of light dry granular candy glaze Ceramic Tiles
CN108218398A (en) * 2018-03-01 2018-06-29 佛山市高明丰霖新型材料有限公司 A kind of ceramic exterior wall brick dry granular and the ceramic exterior wall brick containing the dry granular
CN109761649A (en) * 2019-03-26 2019-05-17 东莞市唯美装饰材料有限公司 A kind of slate Ceramic Tiles and preparation method thereof with diamond luster effect

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110317051A (en) * 2019-08-02 2019-10-11 佛山市陶莹新型材料有限公司 A kind of diamond dry granular and its processing method
CN112694344A (en) * 2020-12-18 2021-04-23 佛山市大角鹿大理石瓷砖有限公司 Preparation method of micro-carving super-wear-resistant diamond glaze ceramic tile and micro-carving super-wear-resistant diamond glaze ceramic tile

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