CN106892683A - A kind of architectural pottery high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer - Google Patents

A kind of architectural pottery high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer Download PDF

Info

Publication number
CN106892683A
CN106892683A CN201710140146.XA CN201710140146A CN106892683A CN 106892683 A CN106892683 A CN 106892683A CN 201710140146 A CN201710140146 A CN 201710140146A CN 106892683 A CN106892683 A CN 106892683A
Authority
CN
China
Prior art keywords
parts
frit
glaze
abrasion
architectural pottery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710140146.XA
Other languages
Chinese (zh)
Other versions
CN106892683B (en
Inventor
肖卓豪
罗文艳
李秀英
汪永清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jingdezhen Ceramic Institute
Original Assignee
Jingdezhen Ceramic Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jingdezhen Ceramic Institute filed Critical Jingdezhen Ceramic Institute
Priority to CN201710140146.XA priority Critical patent/CN106892683B/en
Publication of CN106892683A publication Critical patent/CN106892683A/en
Application granted granted Critical
Publication of CN106892683B publication Critical patent/CN106892683B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0036Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
    • C03C10/0045Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/22Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C04B41/5023Glass-ceramics

Abstract

The invention discloses a kind of architectural pottery high abrasion transparent microcrystal fritted glaze, high-melting-point high rigidity glass material is constituted by main component of silica, aluminum oxide and magnesia, low melting point high rigidity glass material is constituted as main component with boric acid, silica;Both glass material proportion optimizings are mixed again forms high abrasion transparent microcrystal fritted glaze of the present invention.Additionally, also disclosing the preparation method and obtained product of above-mentioned fritted glaze and glaze layer.The adjusting and optimizing that the present invention passes through formula, the tiny micro crystal of a large amount of particles can be generated in glaze layer after burning till, while glaze paint wearability is increased substantially, reduce the influence to glaze layer glossiness and transmitance, so as to meet demand of the market to high abrasion glazed ceramic product well, while may advantageously facilitate transition and upgrade and the development of traditional ceramics industry.

Description

A kind of architectural pottery with the preparation method of high abrasion transparent microcrystal fritted glaze and glaze layer with And obtained product
Technical field
The present invention relates to building ceramics technical field, more particularly to a kind of architectural pottery glaze and glaze layer preparation Method and obtained product, it is adaptable to have ceramic wall and floor bricks and square brick of high abrasion demand etc..
Background technology
With the fast development of domestic real estate market in recent ten years, China's architectural pottery industry obtains unprecedented Opportunity to develop, however as the renewal of the new decoration technique application of architectural pottery and product type, glaze paint wearability is poor to ask Topic is increasingly becoming the bottleneck that restriction architectural pottery further develops, and the wear-resisting series of current overwhelming majority glaze paint brick product is 4 Level, it is difficult to reach 5 grades, the appearance of particularly high-end Full-glazed tile and crystallite brick product exacerbates architectural pottery industry resistance to height The pressing needs of glaze are ground, therefore the wear-resisting sex chromosome mosaicism of glaze paint has caused the extensive concern of domestic and international ceramic material industry.
At present, its wearability is improved by improving hardness of glaze surface has turned into the common recognition of industry, and prior art is mainly logical The crosslinking degree for increasing glaze layer glass structure is crossed, the raising of hardness of glaze surface and mechanical endurance is realized.For example, by glaze Ultra-fine corundum powder is introduced, to improve the content of aluminum oxide in glaze, due to [AlO4] and [SiO4] it is collectively forming glass network knot Structure, increased the crosslinking degree of structure, thus improve the wearability of glaze paint to a certain extent.However, in actual applications It was found that, although aluminum oxide can increase hardness of glaze surface, the glossiness of glaze paint can be also reduced simultaneously and increases glaze paint water ripples.This Because enamel needs to realize that vitrifying is flowed at 1200 DEG C or so, to be formed and the close binder of base substrate and obtain good Surface property, which has limited the amplitude that network structure crosslinking degree in glass frit is improved, because the degree of cross linking high will cause Glass frit softening temperature is significantly improved with flowing temperature.
Further to improve the wearability of glaze paint, the new think of as glaze using glass ceramics frit is it is also proposed at present Road, i.e., processed by carrying out controlled micro crystallization to glaze paint, significantly improves the hardness of glaze paint.However, the growth course of crystallite is difficult to control Make, and crystal is easily grown up in high temperature environments, and thick crystal not only influences glaze layer optical property, and it is easily caused glaze The deterioration of face mechanical performance.Therefore, how optimisation technique so that a large amount of particles are generated in glaze layer during ceramic firing tiny Micro crystal, be improve architectural pottery glaze paint wearability key.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, there is provided a kind of architectural pottery is molten with high abrasion transparent microcrystal Block glaze, by the adjusting and optimizing being formulated, promotes that the tiny micro crystal of a large amount of particles can be generated in glaze layer, is increasing substantially While glaze paint wearability, the influence to glaze layer glossiness and transmitance is reduced, so as to meet market to high abrasion glazed ceramic The demand of product, and promote the transition and upgrade of traditional ceramics industry.Another object of the present invention is to provide above-mentioned architectural pottery With high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer.
The purpose of the present invention is achieved by the following technical programs:
A kind of architectural pottery high abrasion transparent microcrystal fritted glaze that the present invention is provided, is melted by high alumina silicon frit, borosilicate high Block, kaolin composition;According to high alumina silicon frit described in mass ratio: borosilicate frit=1 high: 0.3~0.8, the kaolinic use It is high alumina silicon frit and the 1~3% of borosilicate frit weight sum high to measure;The high alumina silicon frit is according to its composition of parts by weight For:50~65 parts of silica, 12~20 parts of aluminum oxide, 3~8 parts of boric acid, 15~25 parts of magnesia, 1~5 part of zirconium oxide, nitre 1~6 part of sour sodium;The borosilicate frit high according to parts by weight consisting of:78~82 parts of silica, 1~5 part of aluminum oxide, 10~15 parts of boric acid, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
Fritted glaze of the present invention constitutes high-melting-point high rigidity glass material by main component of silica, aluminum oxide and magnesia Material, low melting point high rigidity glass material is constituted with boric acid, silica as main component;The optimization of both glass materials is matched somebody with somebody again High abrasion transparent microcrystal fritted glaze of the present invention is formed than mixing.
Preferably, fritted glaze of the present invention is according to high alumina silicon frit described in mass ratio: borosilicate frit=1 high: 0.3~0.5.Institute High alumina silicon frit is stated according to parts by weight consisting of:50~55 parts of silica, 12~15 parts of aluminum oxide, 3~8 parts of boric acid, 15~20 parts of magnesia, 1~5 part of zirconium oxide, 1~6 part of sodium nitrate;The borosilicate frit high according to parts by weight consisting of: 78~82 parts of silica, 2~5 parts of aluminum oxide, 10~13 parts of boric acid, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
Another object of the present invention is achieved by the following technical programs:
The above-mentioned architectural pottery that the present invention the is provided preparation method of high abrasion transparent microcrystal fritted glaze, including following step Suddenly:
(1) preparation of high alumina silicon frit
According to the proportioning, the high alumina silicon frit is respectively constituted after being well mixed and sieving, through high-temperature fusion to clarification With homogenizing, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, and drying cullet slag is to obtain high alumina silicon to melt Block;
(2) prepared by borosilicate frit high
According to the proportioning, the borosilicate frit high is respectively constituted after being well mixed and sieving, through high-temperature fusion to clarification With homogenizing, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, and drying cullet slag is to obtain borosilicate high to melt Block;
(3) preparation of glaze slip
According to the proportioning, by the high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and mixes equal It is even, obtain the glaze slip that fineness tails over 0.02~0.05% for 10000-hole sieve.
Further, step (1) high-temperature fusion temperature described in the preparation method of fritted glaze of the present invention is 1550~1580 DEG C, Soaking time is 2~5 hours.Step (2) the high-temperature fusion temperature is 1350~1450 DEG C, and soaking time is 2~5 hours.
A kind of architectural pottery that the present invention is provided is as follows with the preparation method of high abrasion transparent microcrystal frit glaze layer:Will be above-mentioned Glaze slip is imposed on architectural pottery base substrate, and 30~60 minutes are incubated at a temperature of 1200~1250 DEG C, obtains transparent after cooling Glaze layer containing a large amount of cordierite crystallites.
Using above-mentioned glaze layer preparation method obtained in architectural pottery product.
The invention has the advantages that:
(1) present invention can generate a large amount of tiny cordierite crystallites by the adjusting and optimizing being formulated after burning till in glaze layer (cordierite crystallite volume content is 35~45% in glaze layer).Due to the precipitation of a large amount of crystallites, ceramic glaze layer can be significantly improved Case hardness (microhardness of glaze layer surface be 685~706Hv), so as to improve its wearability, (wear-resisting series reaches 5 Level).
(2) the cordierite crystallite that is formed of the present invention due to crystalline size it is tiny (cordierite crystallite mean size is 50~ 60nm), significantly influence no on the optical property of glaze paint (glaze layer transmitance is 65~75%), it is adaptable to have high abrasion demand Ceramic wall and floor bricks and square brick etc..
(3) present invention can well meet demand of the market to high abrasion glazed ceramic product, while may advantageously facilitate The transition and upgrade of traditional ceramics industry and development.
Below in conjunction with embodiment, the present invention is described in further detail.
Specific embodiment
Embodiment one:
1st, a kind of architectural pottery of the present embodiment high abrasion transparent microcrystal fritted glaze, by high alumina silicon frit, borosilicate frit high, Kaolin is constituted;According to quality than high alumina silicon frit: borosilicate frit=1 high: 0.45, kaolinic consumption be high alumina silicon frit with The 1% of borosilicate frit weight sum high.Wherein:
High alumina silicon frit according to parts by weight consisting of:52 parts of silica, 15 parts of aluminum oxide, 5 parts of boric acid, magnesia 20 parts, 3 parts of zirconium oxide, 5 parts of sodium nitrate.
Borosilicate frit high according to parts by weight consisting of:81 parts of silica, 2 parts of aluminum oxide, 12 parts of boric acid, potassium carbonate 2 parts, 3 parts of sodium carbonate.
2nd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal fritted glaze, its step is as follows:
(1) preparation of high alumina silicon frit
According to said ratio, by high alumina silicon frit, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles Insulation makes it fully clarify and be homogenized for 4 hours at a temperature of 1560 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized is poured into Quenching and make its fragmentation in water, drying cullet slag is to obtain high alumina silicon frit;
(2) prepared by borosilicate frit high
According to said ratio, by borosilicate frit high, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles Insulation makes it fully clarify and be homogenized for 2 hours at a temperature of 1380 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized is poured into Quenching and make its fragmentation in water, drying cullet slag is to obtain borosilicate frit high;
(3) preparation of glaze slip
According to said ratio, by high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and is well mixed, and obtains 0.03% glaze slip is tailed over for 10000-hole sieve to fineness.
3rd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal frit glaze layer:
Above-mentioned glaze slip is imposed on architectural pottery base substrate using glaze spraying, pouring glaze or other modes, is protected at a temperature of 1210 DEG C Temperature 35 minutes, transparent, cordierite crystallite mean size 52nm, the high abrasion that crystallite volume content is 39% are obtained after cooling Glaze layer, and the architectural pottery product containing the glaze layer.
According to GB2680-1981 plate glass total visible light transmittance assay methods and GB/T3810.7-2016《Pottery Porcelain glazed tile surface abrasion resistance is determined》Detected, the transmitance of the present embodiment glaze layer is 72%, the microhardness of glaze layer surface It is 685Hv, the test of glaze paint anti-wear performance shows that its wear-resisting series is 5 grades.
Embodiment two:
1st, a kind of architectural pottery of the present embodiment high abrasion transparent microcrystal fritted glaze, by high alumina silicon frit, borosilicate frit high, Kaolin is constituted;According to quality than high alumina silicon frit: borosilicate frit=1 high: 0.35, kaolinic consumption be high alumina silicon frit with The 1% of borosilicate frit weight sum high.Wherein:
High alumina silicon frit according to parts by weight consisting of:54 parts of silica, 12 parts of aluminum oxide, 6 parts of boric acid, magnesia 18 parts, 4 parts of zirconium oxide, 6 parts of sodium nitrate.
Borosilicate frit high according to parts by weight consisting of:78 parts of silica, 4 parts of aluminum oxide, 13 parts of boric acid, potassium carbonate 2 parts, 3 parts of sodium carbonate.
2nd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal fritted glaze, its step is as follows:
(1) preparation of high alumina silicon frit
According to said ratio, by high alumina silicon frit, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles Insulation makes it fully clarify and be homogenized for 4 hours at a temperature of 1580 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized is poured into Quenching and make its fragmentation in water, drying cullet slag is to obtain high alumina silicon frit;
(2) prepared by borosilicate frit high
According to said ratio, by borosilicate frit high, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles Insulation makes it fully clarify and be homogenized for 2.5 hours at a temperature of 1360 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized falls Enter in water quenching and make its fragmentation, drying cullet slag is to obtain borosilicate frit high;
(3) preparation of glaze slip
According to said ratio, by high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and is well mixed, and obtains 0.04% glaze slip is tailed over for 10000-hole sieve to fineness.
3rd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal frit glaze layer:
Above-mentioned glaze slip is imposed on architectural pottery base substrate using glaze spraying, pouring glaze or other modes, is protected at a temperature of 1230 DEG C Temperature 30 minutes, transparent, cordierite crystallite mean size 57nm, the high abrasion that crystallite volume content is 42% are obtained after cooling Glaze layer, and the architectural pottery product containing the glaze layer.
According to GB2680-1981 plate glass total visible light transmittance assay methods and GB/T3810.7-2016《Pottery Porcelain glazed tile surface abrasion resistance is determined》Detected, the transmitance of the present embodiment glaze layer is 69%, the microhardness of glaze layer surface It is 706Hv, the test of glaze paint anti-wear performance shows that its wear-resisting series is 5 grades.

Claims (8)

1. a kind of architectural pottery high abrasion transparent microcrystal fritted glaze, it is characterised in that:By high alumina silicon frit, borosilicate frit high, Kaolin is constituted;According to high alumina silicon frit described in mass ratio: borosilicate frit=1 high: 0.3~0.8, the kaolinic consumption is High alumina silicon frit and the 1~3% of borosilicate frit weight sum high;The high alumina silicon frit according to parts by weight consisting of:Two 50~65 parts of silica, 12~20 parts of aluminum oxide, 3~8 parts of boric acid, 15~25 parts of magnesia, 1~5 part of zirconium oxide, sodium nitrate 1 ~6 parts;The borosilicate frit high according to parts by weight consisting of:78~82 parts of silica, 1~5 part of aluminum oxide, boric acid 10 ~15 parts, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
2. architectural pottery according to claim 1 high abrasion transparent microcrystal fritted glaze, it is characterised in that:According to mass ratio The high alumina silicon frit: borosilicate frit=1 high: 0.3~0.5.
3. architectural pottery according to claim 1 and 2 high abrasion transparent microcrystal fritted glaze, it is characterised in that:The height Aluminium silicon frit according to parts by weight consisting of:50~55 parts of silica, 12~15 parts of aluminum oxide, 3~8 parts of boric acid, oxidation 15~20 parts of magnesium, 1~5 part of zirconium oxide, 1~6 part of sodium nitrate;The borosilicate frit high according to parts by weight consisting of:Dioxy 78~82 parts of SiClx, 2~5 parts of aluminum oxide, 10~13 parts of boric acid, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
4. one of claim 1-3 architectural potteries preparation method of high abrasion transparent microcrystal fritted glaze, it is characterised in that Comprise the following steps:
(1) preparation of high alumina silicon frit
According to the proportioning, by the high alumina silicon frit, respectively composition is well mixed and after sieving, through high-temperature fusion to clarify with it is equal Change, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, drying cullet slag is to obtain high alumina silicon frit;
(2) prepared by borosilicate frit high
According to the proportioning, by the borosilicate frit high, respectively composition is well mixed and after sieving, through high-temperature fusion to clarify with it is equal Change, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, drying cullet slag is to obtain borosilicate frit high;
(3) preparation of glaze slip
According to the proportioning, by the high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and is well mixed, and obtains 0.02~0.05% glaze slip is tailed over for 10000-hole sieve to fineness.
5. the architectural pottery according to claim 4 preparation method of high abrasion transparent microcrystal fritted glaze, it is characterised in that: Step (1) the high-temperature fusion temperature is 1550~1580 DEG C, and soaking time is 2~5 hours.
6. the architectural pottery according to claim 4 preparation method of high abrasion transparent microcrystal fritted glaze, it is characterised in that: Step (2) the high-temperature fusion temperature is 1350~1450 DEG C, and soaking time is 2~5 hours.
7. a kind of architectural pottery preparation method of high abrasion transparent microcrystal frit glaze layer, it is characterised in that:By claim 4 or Glaze slip described in 5 or 6 is imposed on architectural pottery base substrate, and 30~60 minutes are incubated at a temperature of 1200~1250 DEG C, is obtained after cooling Obtain high abrasion glaze layer transparent, containing cordierite crystallite.
8. architectural pottery product obtained in the preparation method of glaze layer described in claim 7 is utilized.
CN201710140146.XA 2017-03-10 2017-03-10 A kind of preparation method and the product obtained of architectural pottery high abrasion transparent microcrystal fritted glaze and glaze layer Active CN106892683B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710140146.XA CN106892683B (en) 2017-03-10 2017-03-10 A kind of preparation method and the product obtained of architectural pottery high abrasion transparent microcrystal fritted glaze and glaze layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710140146.XA CN106892683B (en) 2017-03-10 2017-03-10 A kind of preparation method and the product obtained of architectural pottery high abrasion transparent microcrystal fritted glaze and glaze layer

Publications (2)

Publication Number Publication Date
CN106892683A true CN106892683A (en) 2017-06-27
CN106892683B CN106892683B (en) 2019-04-12

Family

ID=59185595

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710140146.XA Active CN106892683B (en) 2017-03-10 2017-03-10 A kind of preparation method and the product obtained of architectural pottery high abrasion transparent microcrystal fritted glaze and glaze layer

Country Status (1)

Country Link
CN (1) CN106892683B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107601891A (en) * 2017-11-02 2018-01-19 张韶璞 A kind of porcelain glaze and its preparation application method
CN109354406A (en) * 2018-11-14 2019-02-19 宁波联城住工科技有限公司 Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic
CN109369014A (en) * 2018-11-14 2019-02-22 宁波联城住工科技有限公司 Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic
CN110746114A (en) * 2019-11-18 2020-02-04 海南大学 Super-hydrophobic wear-resistant glaze coating and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999415A (en) * 2007-01-24 2007-07-18 唐山陶瓷股份有限公司 Leadless molten block enamel for bone porcelain
CN101289307A (en) * 2008-06-13 2008-10-22 唐山隆达骨质瓷有限公司 Bone porcelain with high resistance of heat shocks and production method thereof
CN101717276A (en) * 2009-11-20 2010-06-02 景德镇陶瓷学院 Transparent lead-free fritted glaze with low expansion coefficient and preparation method thereof
CN103332967A (en) * 2013-07-02 2013-10-02 泉州欧米克生态建材科技有限公司 Fluorescent glaze and preparation method thereof
CN105084940A (en) * 2014-05-07 2015-11-25 贾耀玺 Microcrystalline transparent leadless glaze-polycrystalline micropowder-ceramic composite glass tile
CN106396387A (en) * 2016-08-29 2017-02-15 佛山市高明区明城镇新能源新材料产业技术创新中心 Antibacterial radiation-proof ceramic tile and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999415A (en) * 2007-01-24 2007-07-18 唐山陶瓷股份有限公司 Leadless molten block enamel for bone porcelain
CN101289307A (en) * 2008-06-13 2008-10-22 唐山隆达骨质瓷有限公司 Bone porcelain with high resistance of heat shocks and production method thereof
CN101717276A (en) * 2009-11-20 2010-06-02 景德镇陶瓷学院 Transparent lead-free fritted glaze with low expansion coefficient and preparation method thereof
CN103332967A (en) * 2013-07-02 2013-10-02 泉州欧米克生态建材科技有限公司 Fluorescent glaze and preparation method thereof
CN105084940A (en) * 2014-05-07 2015-11-25 贾耀玺 Microcrystalline transparent leadless glaze-polycrystalline micropowder-ceramic composite glass tile
CN106396387A (en) * 2016-08-29 2017-02-15 佛山市高明区明城镇新能源新材料产业技术创新中心 Antibacterial radiation-proof ceramic tile and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107601891A (en) * 2017-11-02 2018-01-19 张韶璞 A kind of porcelain glaze and its preparation application method
CN109354406A (en) * 2018-11-14 2019-02-19 宁波联城住工科技有限公司 Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic
CN109369014A (en) * 2018-11-14 2019-02-22 宁波联城住工科技有限公司 Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic
CN110746114A (en) * 2019-11-18 2020-02-04 海南大学 Super-hydrophobic wear-resistant glaze coating and preparation method thereof

Also Published As

Publication number Publication date
CN106892683B (en) 2019-04-12

Similar Documents

Publication Publication Date Title
CN102826872B (en) Formula and preparation method of national flag bright red glazed brick
JP5227520B2 (en) Glaze composition
KR101036093B1 (en) Glaze compositions
US5091345A (en) Glass composition
US4814298A (en) Lead-free glasses for glaze materials
CN102584341B (en) Glaze slip for sanitary ceramics and preparation method for glaze slip
CN101243018B (en) High strain point glasses
CN101973758B (en) High transmittance fine household porcelain and production technology thereof
JP3917331B2 (en) Glass or glass ceramic glazing, hanging or decorative glass composition containing no lead and cadmium, and method for producing glass ceramic coated with the glass composition
CN101439932B (en) Low-expansion glass-ceramics with lithia ore tailings as principal raw material and manufacturing method thereof
JP5100922B2 (en) Lead-free glass composition containing no alkali metal
KR100509892B1 (en) Transparent beads and their production method
CN102249739B (en) Preparation method of carbon-golden metallic luster crystalline glaze
US6348425B1 (en) Crystallizing glaze system
US6132832A (en) Tile glaze
CN100447111C (en) Crystalline glaze of iron, zinc and augite and its material compounding process
US7268093B2 (en) Glaze composition and antifouling ceramic ware
CN106966598B (en) A kind of low temperature high-hardness, wearable throws glaze and preparation method thereof entirely
CN101348330B (en) Preparation of low temperature metal-lustrous glaze for ceramic
CN1126721C (en) Process for preparing decorative devitrified glass tile and its products
CN103553341B (en) A kind of floride-free granite mine slag microcrystalline glass and production method thereof
JP2980457B2 (en) Base for sanitary ware and its manufacturing method
CN104478419B (en) A kind of high white light-transmittance ceramics brick and production method thereof
US5649987A (en) Process for producing tabular building and decorative materials similar to natural stone
CN103332861B (en) Preparation method of metallic luster glaze

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20170627

Assignee: Tangshan IMEX Sanitary Ware Manufacturing Co. , Ltd.

Assignor: JINGDEZHEN CERAMIC INSTITUTE

Contract record no.: X2019990000079

Denomination of invention: Preparation method of high abrasion resistance transparent crystallite fritted glaze used for architectural ceramics and enamel layer and prepared product

Granted publication date: 20190412

License type: Exclusive License

Record date: 20190906

EE01 Entry into force of recordation of patent licensing contract