CN106892683A - A kind of architectural pottery high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer - Google Patents
A kind of architectural pottery high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer Download PDFInfo
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- CN106892683A CN106892683A CN201710140146.XA CN201710140146A CN106892683A CN 106892683 A CN106892683 A CN 106892683A CN 201710140146 A CN201710140146 A CN 201710140146A CN 106892683 A CN106892683 A CN 106892683A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
- C03C10/0045—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/22—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions containing two or more distinct frits having different compositions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
- C04B41/5023—Glass-ceramics
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Abstract
The invention discloses a kind of architectural pottery high abrasion transparent microcrystal fritted glaze, high-melting-point high rigidity glass material is constituted by main component of silica, aluminum oxide and magnesia, low melting point high rigidity glass material is constituted as main component with boric acid, silica；Both glass material proportion optimizings are mixed again forms high abrasion transparent microcrystal fritted glaze of the present invention.Additionally, also disclosing the preparation method and obtained product of above-mentioned fritted glaze and glaze layer.The adjusting and optimizing that the present invention passes through formula, the tiny micro crystal of a large amount of particles can be generated in glaze layer after burning till, while glaze paint wearability is increased substantially, reduce the influence to glaze layer glossiness and transmitance, so as to meet demand of the market to high abrasion glazed ceramic product well, while may advantageously facilitate transition and upgrade and the development of traditional ceramics industry.
Description
Technical field
The present invention relates to building ceramics technical field, more particularly to a kind of architectural pottery glaze and glaze layer preparation
Method and obtained product, it is adaptable to have ceramic wall and floor bricks and square brick of high abrasion demand etc..
Background technology
With the fast development of domestic real estate market in recent ten years, China's architectural pottery industry obtains unprecedented
Opportunity to develop, however as the renewal of the new decoration technique application of architectural pottery and product type, glaze paint wearability is poor to ask
Topic is increasingly becoming the bottleneck that restriction architectural pottery further develops, and the wear-resisting series of current overwhelming majority glaze paint brick product is 4
Level, it is difficult to reach 5 grades, the appearance of particularly high-end Full-glazed tile and crystallite brick product exacerbates architectural pottery industry resistance to height
The pressing needs of glaze are ground, therefore the wear-resisting sex chromosome mosaicism of glaze paint has caused the extensive concern of domestic and international ceramic material industry.
At present, its wearability is improved by improving hardness of glaze surface has turned into the common recognition of industry, and prior art is mainly logical
The crosslinking degree for increasing glaze layer glass structure is crossed, the raising of hardness of glaze surface and mechanical endurance is realized.For example, by glaze
Ultra-fine corundum powder is introduced, to improve the content of aluminum oxide in glaze, due to [AlO4] and [SiO4] it is collectively forming glass network knot
Structure, increased the crosslinking degree of structure, thus improve the wearability of glaze paint to a certain extent.However, in actual applications
It was found that, although aluminum oxide can increase hardness of glaze surface, the glossiness of glaze paint can be also reduced simultaneously and increases glaze paint water ripples.This
Because enamel needs to realize that vitrifying is flowed at 1200 DEG C or so, to be formed and the close binder of base substrate and obtain good
Surface property, which has limited the amplitude that network structure crosslinking degree in glass frit is improved, because the degree of cross linking high will cause
Glass frit softening temperature is significantly improved with flowing temperature.
Further to improve the wearability of glaze paint, the new think of as glaze using glass ceramics frit is it is also proposed at present
Road, i.e., processed by carrying out controlled micro crystallization to glaze paint, significantly improves the hardness of glaze paint.However, the growth course of crystallite is difficult to control
Make, and crystal is easily grown up in high temperature environments, and thick crystal not only influences glaze layer optical property, and it is easily caused glaze
The deterioration of face mechanical performance.Therefore, how optimisation technique so that a large amount of particles are generated in glaze layer during ceramic firing tiny
Micro crystal, be improve architectural pottery glaze paint wearability key.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, there is provided a kind of architectural pottery is molten with high abrasion transparent microcrystal
Block glaze, by the adjusting and optimizing being formulated, promotes that the tiny micro crystal of a large amount of particles can be generated in glaze layer, is increasing substantially
While glaze paint wearability, the influence to glaze layer glossiness and transmitance is reduced, so as to meet market to high abrasion glazed ceramic
The demand of product, and promote the transition and upgrade of traditional ceramics industry.Another object of the present invention is to provide above-mentioned architectural pottery
With high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer.
The purpose of the present invention is achieved by the following technical programs：
A kind of architectural pottery high abrasion transparent microcrystal fritted glaze that the present invention is provided, is melted by high alumina silicon frit, borosilicate high
Block, kaolin composition；According to high alumina silicon frit described in mass ratio: borosilicate frit=1 high: 0.3~0.8, the kaolinic use
It is high alumina silicon frit and the 1~3% of borosilicate frit weight sum high to measure；The high alumina silicon frit is according to its composition of parts by weight
For：50~65 parts of silica, 12~20 parts of aluminum oxide, 3~8 parts of boric acid, 15~25 parts of magnesia, 1~5 part of zirconium oxide, nitre
1~6 part of sour sodium；The borosilicate frit high according to parts by weight consisting of：78~82 parts of silica, 1~5 part of aluminum oxide,
10~15 parts of boric acid, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
Fritted glaze of the present invention constitutes high-melting-point high rigidity glass material by main component of silica, aluminum oxide and magnesia
Material, low melting point high rigidity glass material is constituted with boric acid, silica as main component；The optimization of both glass materials is matched somebody with somebody again
High abrasion transparent microcrystal fritted glaze of the present invention is formed than mixing.
Preferably, fritted glaze of the present invention is according to high alumina silicon frit described in mass ratio: borosilicate frit=1 high: 0.3~0.5.Institute
High alumina silicon frit is stated according to parts by weight consisting of：50~55 parts of silica, 12~15 parts of aluminum oxide, 3~8 parts of boric acid,
15~20 parts of magnesia, 1~5 part of zirconium oxide, 1~6 part of sodium nitrate；The borosilicate frit high according to parts by weight consisting of：
78~82 parts of silica, 2~5 parts of aluminum oxide, 10~13 parts of boric acid, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
Another object of the present invention is achieved by the following technical programs：
The above-mentioned architectural pottery that the present invention the is provided preparation method of high abrasion transparent microcrystal fritted glaze, including following step
Suddenly：
(1) preparation of high alumina silicon frit
According to the proportioning, the high alumina silicon frit is respectively constituted after being well mixed and sieving, through high-temperature fusion to clarification
With homogenizing, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, and drying cullet slag is to obtain high alumina silicon to melt
Block；
(2) prepared by borosilicate frit high
According to the proportioning, the borosilicate frit high is respectively constituted after being well mixed and sieving, through high-temperature fusion to clarification
With homogenizing, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, and drying cullet slag is to obtain borosilicate high to melt
Block；
(3) preparation of glaze slip
According to the proportioning, by the high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and mixes equal
It is even, obtain the glaze slip that fineness tails over 0.02~0.05% for 10000-hole sieve.
Further, step (1) high-temperature fusion temperature described in the preparation method of fritted glaze of the present invention is 1550~1580 DEG C,
Soaking time is 2~5 hours.Step (2) the high-temperature fusion temperature is 1350~1450 DEG C, and soaking time is 2~5 hours.
A kind of architectural pottery that the present invention is provided is as follows with the preparation method of high abrasion transparent microcrystal frit glaze layer：Will be above-mentioned
Glaze slip is imposed on architectural pottery base substrate, and 30~60 minutes are incubated at a temperature of 1200~1250 DEG C, obtains transparent after cooling
Glaze layer containing a large amount of cordierite crystallites.
Using above-mentioned glaze layer preparation method obtained in architectural pottery product.
The invention has the advantages that：
(1) present invention can generate a large amount of tiny cordierite crystallites by the adjusting and optimizing being formulated after burning till in glaze layer
(cordierite crystallite volume content is 35~45% in glaze layer).Due to the precipitation of a large amount of crystallites, ceramic glaze layer can be significantly improved
Case hardness (microhardness of glaze layer surface be 685~706Hv), so as to improve its wearability, (wear-resisting series reaches 5
Level).
(2) the cordierite crystallite that is formed of the present invention due to crystalline size it is tiny (cordierite crystallite mean size is 50~
60nm), significantly influence no on the optical property of glaze paint (glaze layer transmitance is 65~75%), it is adaptable to have high abrasion demand
Ceramic wall and floor bricks and square brick etc..
(3) present invention can well meet demand of the market to high abrasion glazed ceramic product, while may advantageously facilitate
The transition and upgrade of traditional ceramics industry and development.
Below in conjunction with embodiment, the present invention is described in further detail.
Specific embodiment
Embodiment one：
1st, a kind of architectural pottery of the present embodiment high abrasion transparent microcrystal fritted glaze, by high alumina silicon frit, borosilicate frit high,
Kaolin is constituted；According to quality than high alumina silicon frit: borosilicate frit=1 high: 0.45, kaolinic consumption be high alumina silicon frit with
The 1% of borosilicate frit weight sum high.Wherein：
High alumina silicon frit according to parts by weight consisting of：52 parts of silica, 15 parts of aluminum oxide, 5 parts of boric acid, magnesia
20 parts, 3 parts of zirconium oxide, 5 parts of sodium nitrate.
Borosilicate frit high according to parts by weight consisting of：81 parts of silica, 2 parts of aluminum oxide, 12 parts of boric acid, potassium carbonate
2 parts, 3 parts of sodium carbonate.
2nd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal fritted glaze, its step is as follows：
(1) preparation of high alumina silicon frit
According to said ratio, by high alumina silicon frit, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles
Insulation makes it fully clarify and be homogenized for 4 hours at a temperature of 1560 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized is poured into
Quenching and make its fragmentation in water, drying cullet slag is to obtain high alumina silicon frit；
(2) prepared by borosilicate frit high
According to said ratio, by borosilicate frit high, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles
Insulation makes it fully clarify and be homogenized for 2 hours at a temperature of 1380 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized is poured into
Quenching and make its fragmentation in water, drying cullet slag is to obtain borosilicate frit high；
(3) preparation of glaze slip
According to said ratio, by high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and is well mixed, and obtains
0.03% glaze slip is tailed over for 10000-hole sieve to fineness.
3rd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal frit glaze layer：
Above-mentioned glaze slip is imposed on architectural pottery base substrate using glaze spraying, pouring glaze or other modes, is protected at a temperature of 1210 DEG C
Temperature 35 minutes, transparent, cordierite crystallite mean size 52nm, the high abrasion that crystallite volume content is 39% are obtained after cooling
Glaze layer, and the architectural pottery product containing the glaze layer.
According to GB2680-1981 plate glass total visible light transmittance assay methods and GB/T3810.7-2016《Pottery
Porcelain glazed tile surface abrasion resistance is determined》Detected, the transmitance of the present embodiment glaze layer is 72%, the microhardness of glaze layer surface
It is 685Hv, the test of glaze paint anti-wear performance shows that its wear-resisting series is 5 grades.
Embodiment two：
1st, a kind of architectural pottery of the present embodiment high abrasion transparent microcrystal fritted glaze, by high alumina silicon frit, borosilicate frit high,
Kaolin is constituted；According to quality than high alumina silicon frit: borosilicate frit=1 high: 0.35, kaolinic consumption be high alumina silicon frit with
The 1% of borosilicate frit weight sum high.Wherein：
High alumina silicon frit according to parts by weight consisting of：54 parts of silica, 12 parts of aluminum oxide, 6 parts of boric acid, magnesia
18 parts, 4 parts of zirconium oxide, 6 parts of sodium nitrate.
Borosilicate frit high according to parts by weight consisting of：78 parts of silica, 4 parts of aluminum oxide, 13 parts of boric acid, potassium carbonate
2 parts, 3 parts of sodium carbonate.
2nd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal fritted glaze, its step is as follows：
(1) preparation of high alumina silicon frit
According to said ratio, by high alumina silicon frit, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles
Insulation makes it fully clarify and be homogenized for 4 hours at a temperature of 1580 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized is poured into
Quenching and make its fragmentation in water, drying cullet slag is to obtain high alumina silicon frit；
(2) prepared by borosilicate frit high
According to said ratio, by borosilicate frit high, respectively composition is well mixed and after 80 mesh standard sieves excessively, is placed in high-temperature crucibles
Insulation makes it fully clarify and be homogenized for 2.5 hours at a temperature of 1360 DEG C in kiln or tank furnace, and the glass metal that then will be homogenized falls
Enter in water quenching and make its fragmentation, drying cullet slag is to obtain borosilicate frit high；
(3) preparation of glaze slip
According to said ratio, by high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and is well mixed, and obtains
0.04% glaze slip is tailed over for 10000-hole sieve to fineness.
3rd, the present embodiment above-mentioned architectural pottery preparation method of high abrasion transparent microcrystal frit glaze layer：
Above-mentioned glaze slip is imposed on architectural pottery base substrate using glaze spraying, pouring glaze or other modes, is protected at a temperature of 1230 DEG C
Temperature 30 minutes, transparent, cordierite crystallite mean size 57nm, the high abrasion that crystallite volume content is 42% are obtained after cooling
Glaze layer, and the architectural pottery product containing the glaze layer.
According to GB2680-1981 plate glass total visible light transmittance assay methods and GB/T3810.7-2016《Pottery
Porcelain glazed tile surface abrasion resistance is determined》Detected, the transmitance of the present embodiment glaze layer is 69%, the microhardness of glaze layer surface
It is 706Hv, the test of glaze paint anti-wear performance shows that its wear-resisting series is 5 grades.
Claims (8)
1. a kind of architectural pottery high abrasion transparent microcrystal fritted glaze, it is characterised in that：By high alumina silicon frit, borosilicate frit high,
Kaolin is constituted；According to high alumina silicon frit described in mass ratio: borosilicate frit=1 high: 0.3~0.8, the kaolinic consumption is
High alumina silicon frit and the 1~3% of borosilicate frit weight sum high；The high alumina silicon frit according to parts by weight consisting of：Two
50~65 parts of silica, 12~20 parts of aluminum oxide, 3~8 parts of boric acid, 15~25 parts of magnesia, 1~5 part of zirconium oxide, sodium nitrate 1
~6 parts；The borosilicate frit high according to parts by weight consisting of：78~82 parts of silica, 1~5 part of aluminum oxide, boric acid 10
~15 parts, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
2. architectural pottery according to claim 1 high abrasion transparent microcrystal fritted glaze, it is characterised in that：According to mass ratio
The high alumina silicon frit: borosilicate frit=1 high: 0.3~0.5.
3. architectural pottery according to claim 1 and 2 high abrasion transparent microcrystal fritted glaze, it is characterised in that：The height
Aluminium silicon frit according to parts by weight consisting of：50~55 parts of silica, 12~15 parts of aluminum oxide, 3~8 parts of boric acid, oxidation
15~20 parts of magnesium, 1~5 part of zirconium oxide, 1~6 part of sodium nitrate；The borosilicate frit high according to parts by weight consisting of：Dioxy
78~82 parts of SiClx, 2~5 parts of aluminum oxide, 10~13 parts of boric acid, 2~5 parts of potassium carbonate, 2~5 parts of sodium carbonate.
4. one of claim 1-3 architectural potteries preparation method of high abrasion transparent microcrystal fritted glaze, it is characterised in that
Comprise the following steps：
(1) preparation of high alumina silicon frit
According to the proportioning, by the high alumina silicon frit, respectively composition is well mixed and after sieving, through high-temperature fusion to clarify with it is equal
Change, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, drying cullet slag is to obtain high alumina silicon frit；
(2) prepared by borosilicate frit high
According to the proportioning, by the borosilicate frit high, respectively composition is well mixed and after sieving, through high-temperature fusion to clarify with it is equal
Change, the glass metal that then will be homogenized is poured into water quenching and makes its fragmentation, drying cullet slag is to obtain borosilicate frit high；
(3) preparation of glaze slip
According to the proportioning, by the high alumina silicon frit, borosilicate frit high, kaolin is by ball mill crushing and is well mixed, and obtains
0.02~0.05% glaze slip is tailed over for 10000-hole sieve to fineness.
5. the architectural pottery according to claim 4 preparation method of high abrasion transparent microcrystal fritted glaze, it is characterised in that：
Step (1) the high-temperature fusion temperature is 1550~1580 DEG C, and soaking time is 2~5 hours.
6. the architectural pottery according to claim 4 preparation method of high abrasion transparent microcrystal fritted glaze, it is characterised in that：
Step (2) the high-temperature fusion temperature is 1350~1450 DEG C, and soaking time is 2~5 hours.
7. a kind of architectural pottery preparation method of high abrasion transparent microcrystal frit glaze layer, it is characterised in that：By claim 4 or
Glaze slip described in 5 or 6 is imposed on architectural pottery base substrate, and 30~60 minutes are incubated at a temperature of 1200~1250 DEG C, is obtained after cooling
Obtain high abrasion glaze layer transparent, containing cordierite crystallite.
8. architectural pottery product obtained in the preparation method of glaze layer described in claim 7 is utilized.
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| CN107601891A (en) * | 2017-11-02 | 2018-01-19 | 张韶璞 | A kind of porcelain glaze and its preparation application method |
| CN109354406A (en) * | 2018-11-14 | 2019-02-19 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
| CN109369014A (en) * | 2018-11-14 | 2019-02-22 | 宁波联城住工科技有限公司 | Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic |
| CN110317051A (en) * | 2019-08-02 | 2019-10-11 | 佛山市陶莹新型材料有限公司 | A kind of diamond dry granular and its processing method |
| CN110683767A (en) * | 2019-11-20 | 2020-01-14 | 佛山市东鹏陶瓷有限公司 | High-performance wear-resistant glaze and preparation method thereof |
| CN110746114A (en) * | 2019-11-18 | 2020-02-04 | 海南大学 | Super-hydrophobic wear-resistant glaze coating and preparation method thereof |
| CN111548014A (en) * | 2020-06-08 | 2020-08-18 | 广东家美陶瓷有限公司 | Microcrystal glaze, wear-resistant glaze, transparent microcrystal wear-resistant fully-polished glaze tile and preparation method |
| CN112408793A (en) * | 2020-11-24 | 2021-02-26 | 清远市简一陶瓷有限公司 | High-light-transmission wear-resistant frit, preparation method thereof, glaze and marble ceramic tile |
| CN112794645A (en) * | 2021-04-14 | 2021-05-14 | 佛山市东鹏陶瓷有限公司 | High-transparency wear-resistant glaze material and preparation method thereof |
| EP4230600A1 (en) | 2022-02-16 | 2023-08-23 | Guangdong Deer New Materials Co., Ltd. | Soft-light super-wear-resistant diamond glaze, ceramic tile and preparation method there of |
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Application publication date: 20170627 Assignee: Tangshan IMEX Sanitary Ware Manufacturing Co. , Ltd. Assignor: JINGDEZHEN CERAMIC INSTITUTE Contract record no.: X2019990000079 Denomination of invention: Preparation method of high abrasion resistance transparent crystallite fritted glaze used for architectural ceramics and enamel layer and prepared product Granted publication date: 20190412 License type: Exclusive License Record date: 20190906 |
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