CN103224329A - One-time sintered beige frit dry particles and preparation method thereof - Google Patents
One-time sintered beige frit dry particles and preparation method thereof Download PDFInfo
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- CN103224329A CN103224329A CN2013101530814A CN201310153081A CN103224329A CN 103224329 A CN103224329 A CN 103224329A CN 2013101530814 A CN2013101530814 A CN 2013101530814A CN 201310153081 A CN201310153081 A CN 201310153081A CN 103224329 A CN103224329 A CN 103224329A
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- 239000002245 particle Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004327 boric acid Substances 0.000 claims abstract description 18
- 239000010436 fluorite Substances 0.000 claims abstract description 18
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010453 quartz Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 3
- 229910021538 borax Inorganic materials 0.000 claims abstract description 3
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 3
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 19
- 238000005498 polishing Methods 0.000 claims description 18
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 17
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
- 239000011591 potassium Substances 0.000 claims description 16
- 235000010215 titanium dioxide Nutrition 0.000 claims description 16
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical class [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052726 zirconium Inorganic materials 0.000 claims description 14
- -1 zirconium silicates Chemical class 0.000 claims description 14
- 238000005303 weighing Methods 0.000 claims description 9
- 238000007664 blowing Methods 0.000 claims description 8
- 230000004927 fusion Effects 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 8
- 230000003179 granulation Effects 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 abstract description 11
- 238000005245 sintering Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000010459 dolomite Substances 0.000 abstract 1
- 229910000514 dolomite Inorganic materials 0.000 abstract 1
- 239000010433 feldspar Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 239000011449 brick Substances 0.000 description 18
- 238000010304 firing Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000011521 glass Substances 0.000 description 6
- 210000003298 dental enamel Anatomy 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000012938 design process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Glass Compositions (AREA)
Abstract
The invention discloses one-time sintered beige frit dry particles and a preparation method thereof. The frit dry particle preparation raw materials comprise boric acid, borax, feldspar, quartz, dolomite, barium carbonate, non-calcined alumina, zirconium silicate, fluorspar, and titanium dioxide. The frit dry particles have an intrinsic beige color and good gloss, and are semitransparent. The particles are shiny under light. The frit dry particles has high initial melting temperature, low high-temperature viscosity, appropriate expansion coefficient, wide sintering range, and good combination with a ceramic blank. The particles can be sintered in one time, such that energy consumption is reduced by approximately 15% than that of twice sintering.
Description
Technical field
The invention belongs to the preparing ceramic clinker production technical field, particularly a kind of beige frit dry granular and preparation method thereof that once burns.
Background technology
Natural stone material texture is soft elegant in appearance, elegant style.Yet big specification lithotome is extremely rare, have certain radioactivity.The devitrified glass microcrystal that to be a kind of glass by certain grain composition form through sintering and crystallization and the mixture of glass.Quality is hard, glittering and translucent.Yet but devitrified glass is single relatively in the design process.And brick modelled after an antique can remedy this point, thereby satisfies more human consumer by the design that micro mist cloth, silk screen, cylinder or ink-jet technology can obtain thousands of kinds.But it does not possess the space multistory sense and the glittering and translucent property of stone material and devitrified glass.And crystallite brick is a kind of novel product that integrates stone material, glass and brick advantage modelled after an antique.
On cloth on the surface of biscuit, have certain granules and give the compound frit powder of joining, be through the crystallite brick that obtains behind the twice firing and throw brilliant brick, claim that again two degree burnings are thrown brilliant brick, secondary burns the crystallite composition board.Throw brilliant brick through after polishing, the thickness of clear frit can reach 1～2mm, and the therefore surperficial lines that is printed has more gradation sense, stereoscopic sensation for people's the more common polished tile of artistic effect.Yet because the low temperature glaze firing cycle is generally about 160min, (cycle 50～70min) is wanted slow several times, will make thus to produce inconvenience to occur the high temperature biscuiting time of burning till for the first time.At first, burn till the more general once burning of cost and want high; In addition, the adobe that the biscuiting line is supplied is greater than the demand of glaze firing line, and unnecessary brick need manually be removed and unload down, after move back to the glaze firing line again, this has not only increased employee's labor capacity and has taken the warehouse storage space, has increased handling cost; The more important thing is that the biscuiting line can not empty kiln in the idle time, thereby can impel the biscuiting line other products of often changing the line of production, increased employee's labor capacity when changing the line of production again, and caused the instability of kiln, and then reduced product percent of pass.
If change the secondary burning into once burning, so Yi Shang problem just can fundamentally be resolved.Crystallite brick once burns, and refers to wall floor tile green compact through after the glazing, stamp, needs have certain granules at surperficial cloth last layer and gives the compound frit powder of joining, and enters the process that kiln burns till again.
React ripe together because the maximum characteristics of once-firing are the base glaze, this just requires base substrate before the glaze maturation, gets rid of all volatile components, especially crystal water.General volatile component is just got rid of about 950 ℃ fully, and this just requires the glaze frit to have high beginning fusing point, reduces or avoids glaze to generate pore.So the special-purpose frit of once burning crystallite brick that development is excellent, the premium grads rate of assurance crystallization brick is the technical barrier that the sector needs to be resolved hurrily.
The present invention once burns coloured frit dry granular and itself carries beige, therefore can remove silk screen, cylinder or the ink-jet printing process of ceramics factory's glaze line from, so reduced the glaze line length greatly, reduced the employee of related fields, improved production efficiency, promoted modularization set degree,, and promoted quality controllable degree for ceramic enterprise has reduced cost.Compared to other technologies, frit dry granular of the present invention can be used in the principle that the once-firing legal system is equipped with crystallite brick, and once burns special-purpose frit with other and compare, and performance is more superior.Once burn the crystallite composition board that coloured frit dry granular is produced in conjunction with ceramic body, have high rigidity, corrosion-resistant, resistance to compression, shock resistance, be stained with dirt, characteristics such as radiationless less.Coloured frit dry granular of several different colours, the different effect of also can arranging in pairs or groups out produces colorful crystallite brick.Coloured crystallite brick after polishing has unique artistic effect.
Summary of the invention
The object of the present invention is to provide a kind of beige frit dry granular and preparation method thereof that once burns.
The technical solution used in the present invention is:
A kind of beige frit dry granular that once burns, by mass percentage, main chemical constitution is as follows: SiO
244～50%, Al
2O
314～16%, Fe
2O
30.08～0.15%, CaO 12～15%, MgO 5～7%, K
2O 0.5～1.5%, Na
2O 1～1.5%, B
2O
31～4%, TiO
26～14%, ZrO
23～5%, Ba
2O
31～5%, F 1～4%.
Preferably, this frit dry granular with boric acid, borax, potassium felspar sand, quartz, rhombspar, barium carbonate, non-Calcined polishing aluminum oxide, zirconium silicate, fluorite, titanium dioxide as raw material.
Preferably, this frit dry granular is by the feedstock production of following mass parts: 2～6 parts of boric acid, 2～6 parts of boraxs, 8～15 parts of potassium felspar sands, quartzy 30～40 parts, 18～28 parts of rhombspars, 2～6 parts of barium carbonates, 7～15 parts of non-Calcined polishing aluminum oxides, 4～6 parts of zirconium silicates, 3～8 parts in fluorite, 6～12 parts of titanium dioxides.
More excellent, by the feedstock production of following mass parts: 3～4 parts of boric acid, 3～4 parts of boraxs, 8～15 parts of potassium felspar sands, quartzy 30～35 parts, 20～25 parts of rhombspars, 3～4 parts of barium carbonates, 11～13 parts of non-Calcined polishing aluminum oxides, 4～5 parts of zirconium silicates, 3～6 parts in fluorite, 8～12 parts of titanium dioxides.
Preferably, this frit dry granular is by the feedstock production of following mass parts: 4 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, quartzy 33 parts, 25 parts of rhombspars, 4 parts of barium carbonates, 11 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 5 parts in fluorite, 10 parts of titanium dioxides.
Preferably, this frit dry granular is by the feedstock production of following mass parts: 3 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, quartzy 30 parts, 25 parts of rhombspars, 3 parts of barium carbonates, 13 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 6 parts in fluorite, 10 parts of titanium dioxides.
A kind of preparation method who once burns beige frit dry granular may further comprise the steps:
Take by weighing raw material, mix;
Fusion under 1450～1550 ℃ of temperature is incubated 2～3 hours;
The blowing shrend, oven dry, granulation obtains beige frit dry granular;
Wherein, as mentioned above raw materials used.
Preferably, the particle fineness of frit dry granular is 10～30 orders.
The invention has the beneficial effects as follows:
Of the present inventionly once burn beige frit dry granular beginning fusing point height, temperature flowing is good, is layered on to make its base substrate at oxidation stage enough time exhausts be arranged on the ceramic board, the glaze bubble is few, the purpose of once-firing thereby reach; Once-firing can save energy reduction of discharging, and energy consumption reduces about 15% than twice firing;
The beige frit dry granular itself that once burns of the present invention carries beige, can remove the typography of ceramics factory's glaze line from, reduced the glaze line length, reduce the employee of related fields, promoted modularization set degree, improved production efficiency,, and promoted quality controllable degree for ceramic enterprise reduces cost;
Of the present invention once burn beige frit dry granular glossiness good, be translucent, glittering under the irradiation of light, have good artistic effect.
Description of drawings
Fig. 1 is the once burning beige frit dry granular of embodiment 1 preparation;
Fig. 2 is the once burning beige crystallite brick of embodiment 7 preparations.
Embodiment
Below in conjunction with example, further specify the present invention.
In following examples, if no special instructions, described umber all refers to mass parts.Calculate proportioning (mass percent) by following chemical constitution, take by weighing raw material, be used for preparation and once burn beige frit dry granular: SiO
244～50%, Al
2O
314～16%, Fe
2O
30.08～0.15%, CaO 12～15%, MgO 5～7%, K
2O 0.5～1.5%, Na
2O 1～1.5%, B
2O
31～4%, TiO
26～14%, ZrO
23～5%, Ba
2O
31～5%, F 1～4%.
Embodiment 1
Take by weighing 4 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, 33 parts in quartz, 25 parts of rhombspars, 4 parts of barium carbonates, 11 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 5 parts in fluorite, 10 parts of titanium dioxides, mix, fusion under 1460 ℃ of temperature, be incubated 2 hours, the blowing shrend, oven dry, it is 10～30 orders that granulation makes particle fineness, obtain beige frit dry granular, as shown in Figure 1.
Embodiment 2
Take by weighing 4 parts of boric acid, 2 parts of boraxs, 15 parts of potassium felspar sands, 33 parts in quartz, 25 parts of rhombspars, 2 parts of barium carbonates, 11 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 3 parts in fluorite, 7 parts of titanium dioxides, mix, fusion under 1480 ℃ of temperature, be incubated 2 hours, the blowing shrend, oven dry, it is 10～30 orders that granulation makes particle fineness, obtains beige frit dry granular.
Embodiment 3
Take by weighing 3 parts of boric acid, 4 parts of boraxs, 8 parts of potassium felspar sands, 35 parts in quartz, 28 parts of rhombspars, 4 parts of barium carbonates, 7 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 8 parts in fluorite, 6 parts of titanium dioxides, mix, fusion under 1460 ℃ of temperature, be incubated 2.5 hours, the blowing shrend, oven dry, it is 10～30 orders that granulation makes particle fineness, obtains beige frit dry granular.
Embodiment 4
Take by weighing 4 parts of boric acid, 6 parts of boraxs, 10 parts of potassium felspar sands, 40 parts in quartz, 20 parts of rhombspars, 6 parts of barium carbonates, 11 parts of non-Calcined polishing aluminum oxides, 4 parts of zirconium silicates, 5 parts in fluorite, 7 parts of titanium dioxides, mix, fusion under 1520 ℃ of temperature, be incubated 2 hours, the blowing shrend, oven dry, it is 10～30 orders that granulation makes particle fineness, obtains beige frit dry granular.
Embodiment 5
Take by weighing 6 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, 30 parts in quartz, 18 parts of rhombspars, 3 parts of barium carbonates, 15 parts of non-Calcined polishing aluminum oxides, 6 parts of zirconium silicates, 6 parts in fluorite, 6 parts of titanium dioxides, mix, fusion under 1480 ℃ of temperature, be incubated 2 hours, the blowing shrend, oven dry, it is 10～30 orders that granulation makes particle fineness, obtains beige frit dry granular.
Embodiment 6
Take by weighing 3 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, 30 parts in quartz, 25 parts of rhombspars, 3 parts of barium carbonates, 13 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 6 parts in fluorite, 10 parts of titanium dioxides, mix, fusion under 1550 ℃ of temperature, be incubated 2 hours, the blowing shrend, oven dry, it is 10～30 orders that granulation makes particle fineness, obtains beige frit dry granular.
Embodiment 7
Green compact apply ground-coat enamel, and consumption is 610 ± 2.5g/m
2, proportion 1.52 ± 0.01; At the beige frit dry granular of ground-coat enamel surface cloth last layer the foregoing description 1 preparation, consumption is 6000 ± 5g/m
2The adobe of having executed glaze and frit dry granular is fired 130min in 1200 ℃ kiln, obtain the beige crystallite brick.
Sintering character: the crystallite brick cover-coat enamel is as bright as a sixpence, is sparkling and crystal-clear soft beige, and is glittering and translucent under the irradiation of light, bright shinny, the visible pore of no naked eyes, pin hole, as shown in Figure 2.
Because this frit is close with the common brick glaze coefficient of expansion modelled after an antique, has certain base glaze key coat, combines better with adobe and cover-coat enamel.
The beige frit dry granular that once burns of the present invention is by a large amount of tests, prove out ground reduces boric acid component and increases alumina component, frit beginning fusing point is increased to about 1050 ℃, and before temperature rose to the beginning fusing point, the moisture in the green compact, organism had volatilized fully.By fluorite and rhombspar, reduce the high temperature viscosity of frit and reduce the beginning fusing point slowly, be beneficial to that bubble is gathered into air pocket under the high temperature, increase the buoyancy of bubble floating, thereby bubble is drained as far as possible fully, free of pinholes soil pick-up not after the throwing.Therefore the beige frit dry granular beginning fusing point height that once burns of the present invention, temperature flowing is good, is layered on to make its base substrate at oxidation stage enough time exhausts be arranged on the ceramic board, and the glaze bubble is few, the purpose of once-firing thereby reach, energy-saving and emission-reduction, energy consumption reduces about 15% than twice firing;
The beige frit dry granular itself that once burns of the present invention carries beige, so the typography that can remove ceramics factory's glaze line from, reduced the glaze line length, reduce the employee of related fields, promoted modularization set degree, improved production efficiency,, and promoted quality controllable degree for ceramic enterprise reduces cost.
Claims (8)
1. one kind is once burnt beige frit dry granular, and by mass percentage, main chemical constitution is as follows: SiO
244～50%, Al
2O
314～16%, Fe
2O
30.08～0.15%, CaO 12～15%, MgO 5～7%, K
2O 0.5～1.5%, Na
2O 1～1.5%, B
2O
31～4%, TiO
26～14%, ZrO
23～5%, Ba
2O
31～5%, F 1～4%.
2. a kind of beige frit dry granular that once burns according to claim 1 is characterized in that: this frit dry granular with boric acid, borax, potassium felspar sand, quartz, rhombspar, barium carbonate, non-Calcined polishing aluminum oxide, zirconium silicate, fluorite, titanium dioxide as raw material.
3. a kind of beige frit dry granular that once burns according to claim 2 is characterized in that: this frit dry granular is by the feedstock production of following mass parts: 2～6 parts of boric acid, 2～6 parts of boraxs, 8～15 parts of potassium felspar sands, quartzy 30～40 parts, 18～28 parts of rhombspars, 2～6 parts of barium carbonates, 7～15 parts of non-Calcined polishing aluminum oxides, 4～6 parts of zirconium silicates, 3～8 parts in fluorite, 6～12 parts of titanium dioxides.
4. according to any described a kind of beige frit dry granular that once burns of claim 1～3, it is characterized in that: by the feedstock production of following mass parts: 3～4 parts of boric acid, 3～4 parts of boraxs, 8～15 parts of potassium felspar sands, quartzy 30～35 parts, 20～25 parts of rhombspars, 3～4 parts of barium carbonates, 11～13 parts of non-Calcined polishing aluminum oxides, 4～5 parts of zirconium silicates, 3～6 parts in fluorite, 8～12 parts of titanium dioxides.
5. a kind of beige frit dry granular that once burns according to claim 4 is characterized in that: this frit dry granular is by the feedstock production of following mass parts: 4 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, quartzy 33 parts, 25 parts of rhombspars, 4 parts of barium carbonates, 11 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 5 parts in fluorite, 10 parts of titanium dioxides.
6. a kind of beige frit dry granular that once burns according to claim 4 is characterized in that: this frit dry granular is by the feedstock production of following mass parts: 3 parts of boric acid, 3 parts of boraxs, 10 parts of potassium felspar sands, quartzy 30 parts, 25 parts of rhombspars, 3 parts of barium carbonates, 13 parts of non-Calcined polishing aluminum oxides, 5 parts of zirconium silicates, 6 parts in fluorite, 10 parts of titanium dioxides.
7. preparation method who once burns beige frit dry granular may further comprise the steps:
Take by weighing raw material, mix;
Fusion under 1450～1550 ℃ of temperature is incubated 2～3 hours;
The blowing shrend, oven dry, granulation obtains beige frit dry granular;
Wherein, raw materials used as described in any one of the claim 2～6.
8. preparation method according to claim 7 is characterized in that: the particle fineness of frit dry granular is 10～30 orders.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317051A (en) * | 2019-08-02 | 2019-10-11 | 佛山市陶莹新型材料有限公司 | A kind of diamond dry granular and its processing method |
| CN110903033A (en) * | 2019-11-13 | 2020-03-24 | 蒙娜丽莎集团股份有限公司 | Crystal nucleating agent and positioning crystal pattern ceramic tile prepared by using same |
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| CN102515774A (en) * | 2011-11-02 | 2012-06-27 | 广东博德精工建材有限公司 | Method for producing transparent glass and overglazed color ceramic sandwich by single firing |
| CN102557756A (en) * | 2012-01-10 | 2012-07-11 | 广东道氏技术股份有限公司 | Preparation method of stone-pattern-simulating glazed brick |
| CN102746031A (en) * | 2012-06-15 | 2012-10-24 | 广东博德精工建材有限公司 | Preparation method of high-fidelity imitation jade microcrystalline glass ceramic composite board |
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| CN110317051A (en) * | 2019-08-02 | 2019-10-11 | 佛山市陶莹新型材料有限公司 | A kind of diamond dry granular and its processing method |
| CN110903033A (en) * | 2019-11-13 | 2020-03-24 | 蒙娜丽莎集团股份有限公司 | Crystal nucleating agent and positioning crystal pattern ceramic tile prepared by using same |
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