CN102390933B - Dry grain for crystal throwing brick and method for preparing crystal throwing brick - Google Patents
Dry grain for crystal throwing brick and method for preparing crystal throwing brick Download PDFInfo
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- CN102390933B CN102390933B CN 201110228467 CN201110228467A CN102390933B CN 102390933 B CN102390933 B CN 102390933B CN 201110228467 CN201110228467 CN 201110228467 CN 201110228467 A CN201110228467 A CN 201110228467A CN 102390933 B CN102390933 B CN 102390933B
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Abstract
The invention discloses a dry grain for a crystal throwing brick, comprising the following components of Al2O3, SiO2, K2O, CaO, Na2O, MgO, ZnO, BaO, B2O3 and the like. The invention also discloses a method for preparing the crystal throwing brick by using the dry grain. The crystal throwing brick prepared by using the dry grain for the crystal throwing brick in the invention is sintered at one step, therefore, a biscuitfiring process can be omitted, the energy consumption is greatly reduced, pollution is effectively reduced, the production cost can be reduced by about 15%, and the production benefit can be greatly increased. The produced crystal throwing brick has high glaze transparency and fewer air bubbles. The dry grain for the crystal throwing brick provided by the invention has high initial vitrifying temperature and small high-temperature viscosity, a blank can keep good gas exhaust, the air bubbles can be removed at high temperature as much as possible, the usage temperature of a fusion cake can be adjusted by changing the contents of potassium and sodium, a series of dry grain products can be obtained, and the compatibility of the products is good.
Description
Technical field
The present invention relates to a kind ofly throw brilliant brick with dry granular and use the preparation method of the brilliant brick of throwing of this dry granular.
Background technology
The texture of stone material is soft attractive in appearance serious, and elegant style is in a great variety, is the ideal material of decorating luxurious building, thereby the stone material product of high-grade high-quality is " distinguished guest " during many large-scale public spaces, villa big house are decorated always.But stone material is a kind of scarce resource, and the stone material of high-grade high-quality a thousand pieces of gold difficulty on market is asked.
Blemish in an otherwise perfect thing be, lithotome has radioactivity, use in the interior space and do not meet the environmental protection life idea, moreover, because lithotome is exploited out from natural rock mass, formed pattern texture is difficult to nature and is connected, and can't realize the big area paving when therefore using, and is difficult to form unified and complete style.And the exploitation of stone material, not only wasted a large amount of manpower and materials, and ecotope has been caused certain injury.
It is devitrified glass to be compounded in the composite board of Antique Imitation Tiles brick surface one deck 2-5mm that imitative stone is thrown brilliant brick, it integrates glass, pottery, stone material advantage, merge glass melting, ceramic tile shaping and crystallization and thermal treatment, polishing, cutting technique in one, devitrified glass piece pellet paving is applied on the ceramic tile base substrate form through crystallizing and sintering, compact product structure, clean mark, glittering and translucent, stereoscopic sensation is strong, has the sensation as beautiful matter.Soil pick-up not fully, maintenance convenient for cleaning, wear resistance, the aspect such as surface hardness, folding strength all is better than granite and marble, comprise again the glass matrix structure, its acid-alkali-resistant degree, corrosion resistance all are far more than lithotome, and especially weather resisteant is more outstanding, stand to expose to the weather for a long time also can not fade and weathering.Compare the radiation pollution of lithotome, imitative stone is thrown brilliant brick does not only have radioactivity, but also avoided the shortcoming of its aberration intensity inequality, can make the linking harmony and natural more between different ceramic tiles, not only avoided lithotome to have the shortcoming of flaw, also can be according to the paving of arbitrarily arranging in pairs or groups of individual's hobby.
Because the granularity of frit dry granular is between 20～100 orders, the ulking thickness of dry granular is 1～3mm, can not reach this thickness by drenching glaze or glaze spraying technique, and the transparency does not reach requirement yet.The at present imitative stone preparation of throwing brilliant brick is mainly to adopt the secondary burning technology, after stamp through the high temperature biscuiting after the base substrate upper berth apply one deck glass ceramics frit dry granular, twice firing at low temperatures.
Along with world population increases and Economic development, resource consumption and the disposal of pollutants of building and operation thereof economize on resources, protection of the environment, realize that building and natural harmony coexist, and are the common issues that the whole world faces.In the face of earth natural resource constantly utilize and non-renewable objective problem, it has been a large bottleneck on the ceramic boundary of puzzlement.The traditional ceramics industry is very high to the degree of complying with of resource and the energy, and ceramic industry will really become energy resource and save friendly type industry, energy-saving and emission-reduction, and the consumption reduction profit is useless etc., and the aspect also shoulders heavy responsibilities.Secondary is fired the standby brilliant brick of throwing, because base substrate will first pass through the high temperature biscuiting, by the low temperature biscuiting, the process for producing bricks of more once painting enamel metal ware is loaded down with trivial details again, and energy consumption is larger, kiln by 280 meters factories is standard, the market coal price calculates with 1100 yuan/tons, and kiln is fired every square metre of product and wanted many 4.5 yuan with coal, by 1,000,000 square metres of calculating of annual production, will increase the expense of 4,500,000 yuan, and twice firing can increase also manually, the cost in place, breakage etc.
Summary of the invention
The object of the present invention is to provide and a kind ofly once burn to throw brilliant brick with dry granular and use the preparation method of the brilliant brick of throwing of this dry granular.
The technical solution used in the present invention is:
The brilliant brick dry granular of a kind of throwing is by Al
2O
313～20 parts, SiO
256～63 parts, K
20.5～5 part of O, 8～18 parts of CaO, Na
23～6 parts of O, 0.5～3 part of MgO, 0.5～4 part of ZnO, 0～4 part of BaO, B
2O
30～4, Li
20 ~ 2 part of composition of O.
Preferably, the brilliant brick of described throwing uses dry granular by Al
2O
314～17 parts, SiO
256～60 parts, K
21～4 part of O, 10～16 parts of CaO, Na
24～6 parts of O, 1～2 part of MgO, 1～4 part of ZnO, 0～2 part of BaO, B
2O
31～3, Li
20 ~ 2 part of composition of O.
A kind of preparation method who throws brilliant brick that once burns, after being included in adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, the above-mentioned dry granular of cloth one deck, 1150 ℃～1230 ℃ once-firings.
The time of preferably, firing is 60～120 minutes.
The brilliant brick dry granular of the throwing of the application of the invention, the throwing that makes crystalline substance brick, once-firing can save high temperature biscuiting process, greatly reduces energy consumption, has effectively reduced pollution, can reduce production costs nearly 15%, has greatly improved productivity effect.The brilliant brick of the throwing that production obtains, the glaze transparency is high, and bubble is few.
Prepare this dry granular frit initial melting temperature used high, high-temperature viscosity is little, both can guarantee that the base substrate exhaust was good, the eliminating bubble that can at high temperature try one's best again, and the content of change potassium and the sodium use temperature that can regulate frit, obtain a series of dry granular product, and the compatibility performance between product is good.
The brilliant brick of the throwing of the inventive method preparation, owing to being the high temperature once-firing, the brilliant brick product of the throwing of the equal lower temperature twice firing of wear resistance and resistance to acids and bases has significantly raising, and once-firing, less energy consumption, technique is simple.
Embodiment
Below in conjunction with example, further illustrate the present invention.
In following examples, if no special instructions, described umber all refers to mass parts.
The melting method of dry granular is as follows:
Composition according to dry granular takes raw material, mixes, and founds in 1500～1580 ℃, is crushed to afterwards 20～100 orders.
Embodiment 1
The brilliant brick dry granular of a kind of throwing is by Al
2O
313 parts, SiO
260 parts, K
20.5 part of O, 14 parts of CaO, Na
25 parts of O, 1 part of MgO, 0.5 part of ZnO, 2 parts of BaO, B
2O
31 part, Li
22 parts of compositions of O.
Embodiment 2
The brilliant brick dry granular of a kind of throwing is by Al
2O
315 parts, SiO
263 parts, K
25 parts of O, 12 parts of CaO, Na
24 parts of O, 0.5 part of MgO, 2 parts of ZnO, B
2O
34 parts, Li
20.3 part of composition of O.
Embodiment 3
The brilliant brick dry granular of a kind of throwing is by Al
2O
320 parts, SiO
258 parts, K
23 parts of O, 8 parts of CaO, Na
25 parts of O, 1.5 parts of MgO, 1 part of ZnO, B
2O
34 parts, Li
21.5 parts of compositions of O.
Embodiment 4
The brilliant brick dry granular of a kind of throwing is by Al
2O
318 parts, SiO
256 parts, K
22 parts of O, 16 parts of CaO, Na
24 parts of O, 2 parts of MgO, 4 parts of ZnO, 2.5 parts of BaO, B
2O
32, Li
21 part of composition of O.
Embodiment 5
The brilliant brick dry granular of a kind of throwing is by Al
2O
316 parts, SiO
262 parts, K
23 parts of O, 11 parts of CaO, Na
26 parts of O, 3 parts of MgO, ZnO2 part, 0.5 part of BaO, B
2O
33 parts of compositions.
Embodiment 6
The brilliant brick dry granular of a kind of throwing is by Al
2O
316 parts, SiO
260 parts, K
21.5 parts of O, 15 parts of CaO, Na
24 parts of O, 2.5 parts of MgO, 3 parts of ZnO, 4 parts of BaO, Li
21.5 parts of compositions of O.
Embodiment 7
The brilliant brick dry granular of a kind of throwing is by Al
2O
316 parts, SiO
259 parts, K
23 parts of O, 14 parts of CaO, Na
23 parts of O, 2.0 parts of MgO, 2.5 parts of ZnO, 2 parts of BaO, Li
21 part of composition of O.
Embodiment 8
After adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, the dry granular of cloth one deck 1.8mm, dry granular is mixed by embodiment 1 and the described dry granular of embodiment 4 mass ratio by 1:2,1150 ℃, burns till in 120 minutes.
Embodiment 9
After adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, the dry granular of cloth one deck 2.3mm, dry granular is mixed by embodiment 2 and the described dry granular of embodiment 5 mass ratio by 2:1,1180 ℃, burns till in 90 minutes.
Embodiment 10
After adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, the dry granular of cloth one deck 2mm, dry granular is mixed by embodiment 1 and the described dry granular of embodiment 3 mass ratio by 1:1,1200 ℃, burns till in 90 minutes.
Embodiment 11
After adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, the dry granular of cloth one deck 2.5mm, dry granular is mixed by embodiment 2 and the described dry granular of embodiment 4 mass ratio by 2:3,1230 ℃, burns till in 50 minutes.
Embodiment 8～11 prepares and throws brilliant brick structure densification, transparency is high, bubble is few, greatly reduces production energy consumption, and environmental protection is attractive in appearance.
Embodiment 12
After adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, the described dry granular of embodiment 6 of cloth one deck 2mm, burnt till in 50 minutes by 1150 ℃.
The brilliant brick dry granular of the throwing of the application of the invention can save the sintering procedure of a kiln of biscuiting, and the throwing that makes crystalline substance brick has the energy consumption of greatly reducing, and has effectively reduced pollution, can reduce production costs nearly 15%, has greatly improved productivity effect.The brilliant brick of the throwing that production obtains, the glaze transparency is high, and bubble is few.
Prepare this dry granular frit initial melting temperature used high, high-temperature viscosity is little, both can guarantee that the base substrate exhaust was good, the eliminating bubble that can at high temperature try one's best again, and the content of change potassium and the sodium use temperature that can regulate frit, obtain a series of dry granular product, and the compatibility performance between product is good.
Claims (3)
1. an once-firing is thrown brilliant brick dry granular, by Al
2O
314～17 parts, SiO
256～60 parts, K
21～4 part of O, 10～16 parts of CaO, Na
24～6 parts of O, 1～2 part of MgO, 1～4 part of ZnO, 0～2 part of BaO, B
2O
31～3, Li
20～2 part of composition of O, described umber is mass parts, the melting method of dry granular is as follows:
Composition according to dry granular takes raw material, mixes, and founds in 1500～1580 ℃, is crushed to afterwards 20～100 orders.
2. one kind is once burnt the preparation method who throws brilliant brick, and after being included in adobe compression moulding, after executing ground-coat enamel, cover-coat enamel, fancy glaze, cloth one deck dry granular claimed in claim 1 burns till at 1150 ℃～1230 ℃ next time, obtains throwing brilliant brick product.
3. a kind of preparation method who throws brilliant brick according to claim 2, it is characterized in that: product forms for once firing, and firing time is 60～120 minutes.
Priority Applications (1)
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| CN 201110228467 CN102390933B (en) | 2011-08-10 | 2011-08-10 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
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|---|---|---|---|
| CN 201110228467 CN102390933B (en) | 2011-08-10 | 2011-08-10 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
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| CN102390933A CN102390933A (en) | 2012-03-28 |
| CN102390933B true CN102390933B (en) | 2013-11-06 |
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| CN102746031B (en) * | 2012-06-15 | 2013-09-11 | 广东博德精工建材有限公司 | Preparation method of high-fidelity imitation jade microcrystalline glass ceramic composite board |
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| CN105601109B (en) * | 2015-12-23 | 2019-01-22 | 江西宏瑞新材料有限公司 | A kind of frit and preparation method thereof of high beginning fusing point high expansion coefficient |
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| CN109665871B (en) * | 2018-12-27 | 2021-07-02 | 佛山欧神诺陶瓷有限公司 | Process method for improving surface wear resistance of polished crystal ceramic tile |
| CN110372209B (en) * | 2019-07-31 | 2022-08-16 | 佛山欧神诺陶瓷有限公司 | Polished crystal brick with starry sky effect and preparation method thereof |
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| CN110981197B (en) * | 2019-12-20 | 2022-05-24 | 佛山欧神诺陶瓷有限公司 | Preparation method of wet-process dry-grain polished crystal brick and polished crystal brick |
| CN111847877B (en) * | 2020-08-05 | 2022-07-01 | 佛山市华力达材料科技有限公司 | Metal dry particle glaze, metal luster ceramic tile and preparation method thereof |
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Effective date of registration: 20160307 Address after: 331100 Fengcheng Industrial Park, Jiangxi, Yichun Patentee after: JIANGXI HONGRUI NEW MATERIAL CO., LTD. Address before: 529400, Jiangmen, Guangdong, Enping temple town Sanlian Buddha son Patentee before: Guangdong Dowstone Technology Co., Ltd. |