CN108069732B - Metal travertine dry particles and preparation method thereof - Google Patents
Metal travertine dry particles and preparation method thereof Download PDFInfo
- Publication number
- CN108069732B CN108069732B CN201711224987.5A CN201711224987A CN108069732B CN 108069732 B CN108069732 B CN 108069732B CN 201711224987 A CN201711224987 A CN 201711224987A CN 108069732 B CN108069732 B CN 108069732B
- Authority
- CN
- China
- Prior art keywords
- parts
- travertine
- metal
- dry
- organic powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Road Paving Structures (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a metal travertine dry particle and a preparation method thereof. The metal cave stone brick obtained by firing the dry metal cave stone particles has the advantages of glaze layer on the inner surface of the cave, compact glaze surface, high strength, wear resistance and no dirt hiding. The hole glaze is smooth in sinking, has metal texture, is rich in color, clear in texture and rich and diverse in surface decoration, and the texture is matched with marble design, so that the effect is more vivid and natural, and the special effect of glittering gold holes is achieved. The required raw materials are few in variety, rich in resources, low in price, simple in preparation process and strong in operability, the gold holes on the surface of the product have a flashing effect, the color tone mainly based on beige is broken, the color is more rich and colorful, and the characteristic that natural stone is free and free is greatly restored. The floor can be paved on the ground or on the wall with good effect.
Description
Technical Field
The invention belongs to the technical field of ceramics, particularly relates to novel dry particles and a preparation method thereof, and particularly relates to metal travertine dry particles and a preparation method thereof.
Background
Travertine, with the scientific name travertine, the name english: (Travertine) is a porous rock and is therefore also commonly called Travertine. Travertine belongs to terrestrial sedimentary rock, and is a sediment of calcium carbonate. Travertine is mostly formed in limestone terrain rich in calcium carbonate, and is formed by calcium carbonate and other minerals dissolved in water deposited on river beds, lake bottoms and the like. Since pores are sometimes formed during the re-stacking process, and since calcium carbonate, which is a main component of the deposit, is easily dissolved by water and corroded, many natural irregular pores are formed in the stack. The natural travertine has clear texture, mild and rich texture, is natural but superior to natural, and has unique decorative effect which is popular with a plurality of architects.
In nature, the formation of the travertine is generally considered that a great amount of calcium carbonate in solution is taken away by circulating underground water containing carbon dioxide, when the underground water reaches the surface of a spring, some carbon dioxide is released and condensed in a deposition layer of the calcium carbonate, and rare bubbles, namely holes are formed, so that the travertine is formed, because of the holes, the unit density of the travertine is not large, the existence of a great amount of holes not only causes the increase of water absorption rate and the reduction of strength, but also more importantly causes the poor weather resistance of the material, and the phenomenon that a sample is frozen and cracked in a freeze-thaw test is common, and the travertine is not perfect after 150 cycles at the temperature of-20 ℃ to 70 ℃ according to the American standard. Therefore, the travertine is only suitable for covering materials and is not suitable for building structural materials and base materials. When the adhesive is used outdoors, proper adhesive materials are selected for hole filling treatment, so that the performance of the product is improved.
In 2006, the Dongpeng ceramic factory successfully develops the travertine product, retains the unique decorative effect of the travertine, and has the effects of water absorption and skid resistance. The travertine-effect ceramic tile is quickly advocated by consumers and designers, becomes one of preferred ceramic tiles for public installation and large-area paving and home decoration individuation, and forms the trend of one-piece hole.
Although the travertine-effect brick has a good decorative effect, the travertine-effect brick also has the problems of no wear resistance, dirt hiding and the like, for example, common Roman travertine has light color, obvious texture and good material quality; but the texture is loose and the strength is poor. The presence of these defects affects the range of uses thereof. Meanwhile, the preparation method is relatively complex, and the distribution of holes needs to be specially designed to ensure that the composite material has higher strength. Therefore, the travertine product with better decorative effect, more excellent product performance and simpler production process is developed, and has important market significance.
Disclosure of Invention
The invention aims to provide metal travertine dry particles for producing travertine products and travertine products prepared by applying the dry particles.
The technical scheme adopted by the invention is as follows:
the metal travertine dry particles comprise the following raw materials in parts by mass: 12-32 parts of feldspar, 4-29 parts of quartz, 5-8 parts of kaolin, 9-16 parts of calcined kaolin, 24-36 parts of iron phosphate, 8-12 parts of calcium phosphate, 0.5-3 parts of zinc oxide, 5-50 parts of viscous organic powder and 0-40 parts of barren organic powder.
It should be noted that the raw materials also include their precursors, i.e. minerals that form iron phosphate, calcium phosphate and zinc oxide after firing.
As a further improvement of the metal travertine dry granules, the metal travertine dry granules comprise the following raw materials in mass percentage: 18-26 parts of feldspar, 10-20 parts of quartz, 5-8 parts of kaolin, 9-16 parts of calcined kaolin, 24-36 parts of iron phosphate, 8-12 parts of calcium phosphate, 0.5-3 parts of zinc oxide, 15-30 parts of viscous organic powder and 10-25 parts of barren organic powder.
As a further improvement of the above-mentioned dry granules of metal travertine, the viscous organic powder is selected from flour, glutinous rice flour or organic powder added with tackifier.
As a further improvement of the above-mentioned dry particles of the metal travertine, the particle size of the barren organic powder is less than 80 mesh.
As a further improvement of the metal travertine dry granules, the water content of the dry granules is 4-6%.
As a further improvement of the metal travertine dry particles, the particle size distribution of the dry particles is 8-40 meshes.
The surface of the metal travertine dry particle brick is decorated with the surface obtained by firing the metal travertine dry particles.
A preparation method of a metal travertine dry particle brick comprises the steps of distributing the metal travertine dry particles on a glaze layer and sintering.
As a further improvement of the preparation method, the firing temperature of the metal travertine dry-grain brick is 1180-1230 ℃.
The invention has the beneficial effects that:
the metal cave stone brick obtained by firing the dry metal cave stone particles has the advantages of glaze layer on the inner surface of the cave, compact glaze surface, high strength, wear resistance and no dirt hiding. The hole glaze is smooth in sinking, has metal texture, is rich in color, clear in texture and rich and diverse in surface decoration, and the texture is matched with marble design, so that the effect is more vivid and natural, and the special effect of glittering gold holes is achieved. The required raw materials are few in variety, rich in resources, low in price, simple in preparation process and strong in operability, the gold holes on the surface of the product have a flashing effect, the color tone mainly based on beige is broken, the color is more rich and colorful, and the characteristic that natural stone is free and free is greatly restored. The floor can be paved on the ground or on the wall with good effect.
Drawings
Fig. 1 and 2 are photographs of products using the dry particles of the metal travertine of the present invention.
Detailed Description
The metal travertine dry particles comprise the following raw materials in parts by mass: 12-32 parts of feldspar, 4-29 parts of quartz, 5-8 parts of kaolin, 9-16 parts of calcined kaolin, 24-36 parts of iron phosphate, 8-12 parts of calcium phosphate, 0.5-3 parts of zinc oxide, 5-50 parts of viscous organic powder and 0-40 parts of barren organic powder.
Pulverizing the raw materials, adding appropriate amount of water, mixing, granulating, and drying to obtain the final product.
The viscous organic powder has the effects of better agglomerating other barren materials, having certain strength after granulation, facilitating the simplification of the production process, facilitating the operation and shortening the production time. Barren organic powder is a skeleton material, and is easy to granulate after being mixed with viscous organic powder and the like. After being burnt, the organic matters are completely burnt and lost, holes are left, and meanwhile, glaze surfaces can be formed in the holes, so that dirt is prevented from entering. The barren organic powder is preferably dense barren organic powder, such as barren organic powder prepared from wood waste such as hardwood leftovers and hard fruit shells. This is more advantageous in maintaining the dimensional stability of the dry pellets.
As a further improvement of the metal travertine dry granules, the metal travertine dry granules comprise the following raw materials in mass percentage: 18-26 parts of feldspar, 10-20 parts of quartz, 5-8 parts of kaolin, 9-16 parts of calcined kaolin, 24-36 parts of iron phosphate, 8-12 parts of calcium phosphate, 0.5-3 parts of zinc oxide, 15-30 parts of viscous organic powder and 10-25 parts of barren organic powder.
As a further improvement of the above-mentioned dry granules of metal travertine, the viscous organic powder is selected from flour, glutinous rice flour or organic powder added with tackifier. The tackifier may be an organic tackifier commonly used in the art, such as sodium carboxymethylcellulose, and the like.
In order to facilitate uniform mixing, the barren organic powder has a particle size of less than 80 meshes as a further improvement of the metal travertine dry particles.
As a further improvement of the metal travertine dry granules, the water content of the dry granules is 4-6%. Convenient to use, and is more favorable for ensuring the yield of the bricks.
As a further improvement of the metal travertine dry particles, the particle size distribution of the dry particles is 8-40 meshes.
The surface of the metal travertine dry particle brick is decorated with the surface obtained by firing the metal travertine dry particles.
A preparation method of a metal travertine dry particle brick comprises the steps of distributing the metal travertine dry particles on a glaze layer and sintering.
As a further improvement of the preparation method, the firing temperature of the metal travertine dry-grain brick is 1180-1230 ℃.
The technical scheme of the invention is further explained by combining the embodiment.
In the following examples, unless otherwise specified, the parts are parts by mass and the percentages are percentages by mass. The preparation method of the metal travertine dry granules comprises the steps of weighing raw materials in proportion, uniformly mixing, granulating and drying according to a conventional method. During the mixing process, a proper amount of organic tackifier is added as necessary to facilitate granulation.
Example 1
The metal travertine dry particles comprise the following raw materials: 12 parts of feldspar, 29 parts of quartz, 6 parts of kaolin, 9 parts of calcined kaolin, 24 parts of iron phosphate, 10 parts of calcium phosphate, 0.5 part of zinc oxide, 20 parts of flour and 20 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 2
The metal travertine dry particles comprise the following raw materials: 12 parts of feldspar, 25 parts of quartz, 6 parts of kaolin, 12 parts of calcined kaolin, 24 parts of iron phosphate, 10 parts of calcium phosphate, 1 part of zinc oxide, 25 parts of flour and 10 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 3
The metal travertine dry particles comprise the following raw materials: 32 parts of feldspar, 4 parts of quartz, 6 parts of kaolin, 9 parts of calcined kaolin, 36 parts of iron phosphate, 12 parts of calcium phosphate, 1 part of zinc oxide, 30 parts of flour and 5 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 4
The metal travertine dry particles comprise the following raw materials: 32 parts of feldspar, 16 parts of quartz, 6 parts of kaolin, 9 parts of calcined kaolin, 36 parts of iron phosphate, 12 parts of calcium phosphate, 0.5 part of zinc oxide, 35 parts of flour and 10 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 5
The metal travertine dry particles comprise the following raw materials: 30 parts of feldspar, 20 parts of quartz, 5 parts of kaolin, 10 parts of calcined kaolin, 36 parts of iron phosphate, 10 parts of calcium phosphate, 0.5 part of zinc oxide, 40 parts of flour and 15 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 6
The metal travertine dry particles comprise the following raw materials: 18 parts of feldspar, 15 parts of quartz, 8 parts of kaolin, 13 parts of calcined kaolin, 32 parts of iron phosphate, 8 parts of calcium phosphate, 3 parts of zinc oxide, 15 parts of flour and 25 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 7
The metal travertine dry particles comprise the following raw materials: 26 parts of feldspar, 10 parts of quartz, 7 parts of kaolin, 16 parts of calcined kaolin, 28 parts of iron phosphate, 8 parts of calcium phosphate, 2 parts of zinc oxide and 50 parts of flour. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Example 8
The metal travertine dry particles comprise the following raw materials: 26 parts of feldspar, 17 parts of quartz, 6.5 parts of kaolin, 13 parts of calcined kaolin, 24 parts of iron phosphate, 9 parts of calcium phosphate, 1.5 parts of zinc oxide, 5 parts of flour and 40 parts of walnut shell powder. And (3) drying after granulation until the water content is 4-6%, and the grain composition of the dry grains is 8-40 meshes.
Preparing the metal travertine dry granular bricks:
distributing dry metal travertine particles on the glaze surface by using a distributing system, pressing, drying, and sintering in a kiln 1180-1230 ℃; obtaining the dry granular metal travertine bricks.
Fig. 1 and 2 are photographs of the metal travertine dry-granulated bricks produced using the metal travertine dry granules of examples 1 and 2, respectively. It can be seen that the brick surface has obvious hole sense, is vivid and has unique decorative effect. The product with the metal travertine dry particles shown in figure 1 has clear texture and gives a mild and natural feeling. As shown in figure 2, the product with the metal travertine dry particles has strong sense of travertine and the brick surface has the vivid effect of imitating stone.
Water is poured on the surface of the brick, and the water is found to be not infiltrated into the brick basically, so that a compact glaze layer is formed in the hole on the surface of the brick, and the metal travertine dry particle brick is not easy to absorb dirt.
Claims (8)
1. The metal travertine dry particles comprise the following raw materials in parts by mass: 18-26 parts of feldspar, 10-20 parts of quartz, 5-8 parts of kaolin, 9-16 parts of calcined kaolin, 24-36 parts of iron phosphate, 8-12 parts of calcium phosphate, 0.5-3 parts of zinc oxide, 15-30 parts of viscous organic powder and 10-25 parts of barren organic powder, wherein the grain composition of dry grains is 8-40 meshes.
2. The dry metal travertine granule as defined in claim 1, wherein: the viscous organic powder is selected from flour, glutinous rice flour or organic powder added with tackifier.
3. The dry metal travertine granule as defined in claim 1, wherein: the particle size of the barren organic powder is less than 80 meshes.
4. The dry metal travertine granule according to any one of claims 1 to 3, wherein: the barren organic powder is selected from wood powder and artificial organic matter powder.
5. The dry metal travertine granule according to any one of claims 1 to 3, wherein: the water content of the dry granules is 4-6%.
6. The utility model provides a dry grain brick of metal travertine which characterized in that: the surface of the metal travertine is decorated with the surface obtained by firing the dried particles of the metal travertine as defined in any one of claims 1 to 5.
7. A method for preparing a metallic travertine dry-particle brick, which comprises applying the metallic travertine dry particles as defined in any one of claims 1 to 5 on a glaze layer, and firing the ceramic brick.
8. The method of claim 7, wherein: the firing temperature of the metal travertine dry-grain brick is 1180-1230 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711224987.5A CN108069732B (en) | 2017-11-29 | 2017-11-29 | Metal travertine dry particles and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711224987.5A CN108069732B (en) | 2017-11-29 | 2017-11-29 | Metal travertine dry particles and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108069732A CN108069732A (en) | 2018-05-25 |
| CN108069732B true CN108069732B (en) | 2020-10-27 |
Family
ID=62157793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711224987.5A Active CN108069732B (en) | 2017-11-29 | 2017-11-29 | Metal travertine dry particles and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108069732B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635259B (en) * | 2020-05-12 | 2022-02-11 | 蒙娜丽莎集团股份有限公司 | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3926555A1 (en) * | 1988-12-15 | 1990-06-21 | Medizin Labortechnik Veb K | Cordierite ceramic filter - esp. for sterile gas filtration, formed from spray-dried granulate |
| CN102390933A (en) * | 2011-08-10 | 2012-03-28 | 广东道氏技术股份有限公司 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
| CN102442842A (en) * | 2011-10-12 | 2012-05-09 | 上海高诚艺术包装有限公司 | Bead glaze and preparation and use methods thereof |
| CN102503142A (en) * | 2011-10-20 | 2012-06-20 | 广东道氏技术股份有限公司 | Dry particles for crystal polishing tiles sintered at one step and application thereof |
| CN102746031A (en) * | 2012-06-15 | 2012-10-24 | 广东博德精工建材有限公司 | Preparation method of high-fidelity imitation jade microcrystalline glass ceramic composite board |
| CN104058784A (en) * | 2014-06-30 | 2014-09-24 | 佛山市东鹏陶瓷有限公司 | Method for preparing travertine ceramic tile with three-dimensional holes formed in part of travertine ceramic tile |
| CN106673436A (en) * | 2017-01-03 | 2017-05-17 | 澧县新鹏陶瓷有限公司 | Travertine-like ceramic tile taking waste glaze as clinker raw material and preparation method of travertine-like ceramic tile |
-
2017
- 2017-11-29 CN CN201711224987.5A patent/CN108069732B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3926555A1 (en) * | 1988-12-15 | 1990-06-21 | Medizin Labortechnik Veb K | Cordierite ceramic filter - esp. for sterile gas filtration, formed from spray-dried granulate |
| CN102390933A (en) * | 2011-08-10 | 2012-03-28 | 广东道氏技术股份有限公司 | Dry grain for crystal throwing brick and method for preparing crystal throwing brick |
| CN102442842A (en) * | 2011-10-12 | 2012-05-09 | 上海高诚艺术包装有限公司 | Bead glaze and preparation and use methods thereof |
| CN102503142A (en) * | 2011-10-20 | 2012-06-20 | 广东道氏技术股份有限公司 | Dry particles for crystal polishing tiles sintered at one step and application thereof |
| CN102746031A (en) * | 2012-06-15 | 2012-10-24 | 广东博德精工建材有限公司 | Preparation method of high-fidelity imitation jade microcrystalline glass ceramic composite board |
| CN104058784A (en) * | 2014-06-30 | 2014-09-24 | 佛山市东鹏陶瓷有限公司 | Method for preparing travertine ceramic tile with three-dimensional holes formed in part of travertine ceramic tile |
| CN106673436A (en) * | 2017-01-03 | 2017-05-17 | 澧县新鹏陶瓷有限公司 | Travertine-like ceramic tile taking waste glaze as clinker raw material and preparation method of travertine-like ceramic tile |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108069732A (en) | 2018-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102417343B (en) | Production method of sandstone-like porcelain exterior wall tile | |
| CN101565311A (en) | Production method of imitation sandstone ceramic tile | |
| CN106854085A (en) | A kind of shraff water-permeable brick and preparation method thereof | |
| CN105130393A (en) | Method used for producing stone-like ceramic tiles from rare-earth tailing | |
| CN103708811B (en) | Polished tile and its preparation method and application | |
| CN108996909B (en) | Granite-stripe-imitated ceramic external wall tile and preparation method thereof | |
| CN114804845A (en) | Ceramic tile with travertine structure and preparation method thereof | |
| CN106518149A (en) | Method for sintering permeable brick with oil shale semi-coke and iron tailings | |
| CN108424119A (en) | A kind of preparation method of high-strength abrasion-proof Antique Imitation Tiles | |
| CN108249951A (en) | A kind of preparation method for the water-permeable brick that changes colour | |
| CN108069732B (en) | Metal travertine dry particles and preparation method thereof | |
| CN102659387B (en) | High-temperature far infrared radiation energy-saving composite coating and preparation method thereof | |
| CN201141187Y (en) | Stereo aperture decoration porcelain brick | |
| CN106045475A (en) | Method for preparing pearl porcelain sand from blank waste and pearl porcelain sand creative ceramic | |
| KR100599241B1 (en) | Manufacturing method for soil conditioner using zeolite | |
| CN102786297A (en) | Production method for natural sandstone-imitating ceramic tile | |
| CN104961437A (en) | Sandstone plate and process for manufacturing same | |
| CN102731075B (en) | Rustic tile prepared by utilization of Tenggeli yellow sand and preparation method thereof | |
| CN103979999B (en) | A kind of full impregnated hole stone porcelain brick | |
| CN104944924B (en) | Blank for preparing patting nixing pottery and preparation method of blank | |
| CN100436366C (en) | Making process of outer wall decorating tile with watertight surface and stone feeling | |
| CN105622158A (en) | Micro-crystal-face bee-hole double-layer regeneration material | |
| CN106220145A (en) | Utilize the method that granite waste material manufactures Antique Imitation Tiles | |
| CN1636925A (en) | Environment protecting dry brick and its production process | |
| CN108863220A (en) | A kind of building brick and its preparation process of Red Sandstone stone material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |