CN108069732A - A kind of metal hole stone dry granular and preparation method thereof - Google Patents
A kind of metal hole stone dry granular and preparation method thereof Download PDFInfo
- Publication number
- CN108069732A CN108069732A CN201711224987.5A CN201711224987A CN108069732A CN 108069732 A CN108069732 A CN 108069732A CN 201711224987 A CN201711224987 A CN 201711224987A CN 108069732 A CN108069732 A CN 108069732A
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- parts
- dry granular
- metal hole
- hole stone
- stone dry
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Road Paving Structures (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of metal hole stone dry granular and preparation method thereof, dry granular is by feldspar, quartz, kaolin, calcined kaolin, ferric phosphate, calcium phosphate, zinc oxide, the organic powder of viscosity, the lean organic powder of property.The metal hole stone brick that the metal hole stone dry granular of the present invention is fired into, hole inner surface have glaze layer, and glaze paint is fine and close, and intensity is high, has the advantages of wear-resisting, not hide dirt.Its hole glaze paint is sunk round and smooth, has metal-like, and glaze paint is rich in color, and clean mark, incrustation is rich and varied, and texture is arranged in pairs or groups marble design again, effect is more true to nature, naturally, have golden hole it is glittering as special-effect.Required raw material type is few, resourceful, cheap, and preparation process is simple, workable, and product surface has the glittering effect in golden hole, has broken the tone based on cream colour, and color is more rich and varied, greatly reduces the characteristic of lithotome arbitrarily freely.Either ground or upper wall can go out good effect with paving.
Description
Technical field
The invention belongs to ceramic technology fields, and in particular to a kind of new dry granular and preparation method thereof, it is more particularly to a kind of
Metal hole stone dry granular and preparation method thereof.
Background technology
Hole stone, scientific name are called calcareous tufa, English name：(Travertine) it is a kind of porous rock, so usual people
Also it is its hole stone.Hole stone belongs to continental deposit rock, it is a kind of deposit of calcium carbonate.Hole stone is mostly formed at rich in calcium carbonate
Lime stone landform, formed by calcium calcium carbonate soluble in water and other mineral depositions in riverbed, lakebed and other places.Due to
It sometimes appear that hole, simultaneously because the main component of its own is calcium carbonate again, itself just holds very much during accumulate again
Corrosion easily is dissolved in water, so being present with many natural random holes in these deposits.Natural cavity stone clean mark,
Mildly abundant texture from natural, but surmount natural, unique decorative effect and is liked deeply by numerous architects.
In the Nature, the formation of hole stone is commonly considered as big in the circulating groundwater containing carbon dioxide takes away solution
The calcareous carbonate of amount, when underground water reaches spring surface, some carbon dioxide release and condense upon calcareous carbonate
Sedimentary in, form the i.e. present hole of rare bubble, this just has hole stone, because hole, its unit intensity is simultaneously
Less, the presence of a large amount of holes not only causes water absorption rate to rise, intensity declines, it is often more important that causes the weatherability of this material
Can be poor, often there is sample, pass through 150 under -20 DEG C~70 DEG C temperature conditionss by Unite States Standard in freezing-thawing test the phenomenon that bursting by freezing
Hole stone is changed beyond recognition after a cycling.Therefore hole stone is only suitable for making covering material, structural material, basis without being suitable as building
Material.It has to that suitable binder material is selected to carry out filling-up hole processing in outdoor application, to improve the performance of product.
Guangdong Dong Peng ceramics factories successfully research and develop hole stone product within 2006, remain the decorative effect of hole stone uniqueness, while simultaneous
Tool water suction, anti-skidding effect.This hole stone effect Ceramic Tiles receive the high praise of consumer and designers soon, become public dress
One of large area paving and house ornamentation individual decoration first choice ceramic tile form the trend in " a piece of hole ".
Although hole stone effect brick has a preferable decorative effect, but there is also not wear-resisting, hide it is dirty wait some row problems, such as
Common Travertino Romano, color is shallower, and texture is more apparent, and material is preferable；But quality is loose, and intensity is poor.These defects
In the presence of affecting its use scope.Its preparation method is relative complex, it is necessary to the distribution of hole is specifically designed, to ensure its tool simultaneously
There is higher intensity.Therefore, excellent decoration effect is developed, properties of product are more excellent, the more simple hole stone of production technology
Product has important market significance.
The content of the invention
It is an object of the invention to provide a kind of for producing the metal hole stone dry granular of hole stone product and applying the dry granular system
Standby hole stone product.
The technical solution used in the present invention is：
A kind of metal hole stone dry granular, material quality composition are：12~32 parts of feldspar, quartzy 4~29 parts, kaolin 5~8
Part, 9~16 parts of calcined kaolin, 24~36 parts of ferric phosphate, 8~12 parts of calcium phosphate, 0.5~3 part of zinc oxide, the organic powder 5 of viscosity
~50 parts, 0~40 part of the organic powder of lean property.
It should be noted that raw material further includes its precursor, that is, the ore deposit of ferric phosphate, calcium phosphate and zinc oxide can be formed after firing
Object.
As being further improved for above-mentioned metal hole stone dry granular, material quality composition is：18~26 parts of feldspar, quartz 10
~20 parts, 5~8 parts of kaolin, 9~16 parts of calcined kaolin, 24~36 parts of ferric phosphate, 8~12 parts of calcium phosphate, zinc oxide 0.5
~3 parts, organic 15~30 parts of the powder of viscosity, 10~25 parts of the organic powder of lean property.
As being further improved for above-mentioned metal hole stone dry granular, the organic powder of viscosity is selected from flour, glutinous rice flour or added with increasing
The organic matter powder of stick.
As being further improved for above-mentioned metal hole stone dry granular, the grain size of the lean organic powder of property is less than 80 mesh.
As being further improved for above-mentioned metal hole stone dry granular, the water content of dry granular is 4~6%.
As being further improved for above-mentioned metal hole stone dry granular, the grain composition of dry granular is 8~40 mesh.
A kind of metal hole stone dry granular brick, incrustation have the surface that above-mentioned metal hole stone dry granular obtains after firing.
A kind of preparation method of metal hole stone dry granular brick is included in the above-mentioned metal hole stone dry granular of glaze layer charity, burns till
It arrives.
As being further improved for above-mentioned preparation method, the firing temperature of metal hole stone dry granular brick is 1180 DEG C~1230
℃。
The beneficial effects of the invention are as follows：
The metal hole stone brick that the metal hole stone dry granular of the present invention is fired into, hole inner surface have glaze layer, and glaze paint is fine and close, by force
Degree is high, has the advantages of wear-resisting, not hide dirt.Its hole glaze paint sink it is round and smooth, have metal-like, glaze paint is rich in color, and texture is clear
Clear, incrustation is rich and varied, and texture is arranged in pairs or groups marble design again, effect is more true to nature, naturally, have golden hole it is glittering as it is special
Effect.Required raw material type is few, resourceful, cheap, and preparation process is simple, workable, and product surface has Jin Dong
Glittering effect has broken the tone based on cream colour, and color is more rich and varied, greatly reduces lithotome arbitrarily certainly
Characteristic such as.Either ground or upper wall can go out good effect with paving.
Description of the drawings
Fig. 1 and Fig. 2 is the product photo using metal hole stone dry granular of the present invention.
Specific embodiment
A kind of metal hole stone dry granular, material quality composition are：12~32 parts of feldspar, quartzy 4~29 parts, kaolin 5~8
Part, 9~16 parts of calcined kaolin, 24~36 parts of ferric phosphate, 8~12 parts of calcium phosphate, 0.5~3 part of zinc oxide, the organic powder 5 of viscosity
~50 parts, 0~40 part of the organic powder of lean property.
Various raw materials are crushed, suitable quantity of water is added to mix, is granulated, dried and can obtain metal hole stone dry granular.
The effect of the organic powder of viscosity is other lean materials is made preferably to reunite have certain intensity, profit after granulation
It in simplifying production technology, is conveniently operated, shortens the production time.The lean organic powder of property is a kind of frame material, with the organic powder of viscosity etc.
After mixing, it is easy to be granulated.Burn till rear organic matter and burn mistake completely, leave hole, while glaze paint can be formed in hole, avoid dirt into
Enter.The lean organic powder of property is preferably the fine and close lean organic powder of property, lean as made of the wood wastes such as hardwood leftover pieces, hard fruit shell
The organic powder of property.So it is more advantageous to maintaining the dimensional stability of dry granular.
As being further improved for above-mentioned metal hole stone dry granular, material quality composition is：18~26 parts of feldspar, quartz 10
~20 parts, 5~8 parts of kaolin, 9~16 parts of calcined kaolin, 24~36 parts of ferric phosphate, 8~12 parts of calcium phosphate, zinc oxide 0.5
~3 parts, organic 15~30 parts of the powder of viscosity, 10~25 parts of the organic powder of lean property.
As being further improved for above-mentioned metal hole stone dry granular, the organic powder of viscosity is selected from flour, glutinous rice flour or added with increasing
The organic matter powder of stick.Tackifier can be organic tackifier commonly used in the art, such as sodium cellulose glycolate.
For ease of being uniformly mixed, as being further improved for above-mentioned metal hole stone dry granular, the grain size of the lean organic powder of property is less than
80 mesh.
As being further improved for above-mentioned metal hole stone dry granular, the water content of dry granular is 4~6%.It is easy to use, more favorably
In the yield rate for ensureing brick.
As being further improved for above-mentioned metal hole stone dry granular, the grain composition of dry granular is 8~40 mesh.
A kind of metal hole stone dry granular brick, incrustation have the surface that above-mentioned metal hole stone dry granular obtains after firing.
A kind of preparation method of metal hole stone dry granular brick is included in the above-mentioned metal hole stone dry granular of glaze layer charity, burns till
It arrives.
As being further improved for above-mentioned preparation method, the firing temperature of metal hole stone dry granular brick is 1180 DEG C~1230
℃。
With reference to embodiment, the technical solution further illustrated the present invention.
In following embodiment, unless otherwise instructed, the number is mass parts, and percentage is mass percent.
The preparation method of metal hole stone dry granular is weighs raw material in proportion, and mixing is granulated, is dried to obtain according to a conventional method.In mixed process
In, appropriate organic tackifier is added if necessary, in order to be granulated.
Embodiment 1
Metal hole stone dry granular, raw material composition are：12 parts of feldspar, 29 parts of quartz, 6 parts of kaolin, 9 parts of kaolinite of burning, phosphoric acid
24 parts of iron, 10 parts of calcium phosphate, 0.5 part of zinc oxide, 20 parts of flour, 20 parts of walnut shell powder.Dried after granulation to water content for 4~
6%, the grain composition of dry granular is 8~40 mesh.
Embodiment 2
Metal hole stone dry granular, raw material composition are：12 parts of feldspar, 25 parts of quartz, 6 parts of kaolin, 12 parts of kaolinite of burning, phosphoric acid
24 parts of iron, 10 parts of calcium phosphate, 1 part of zinc oxide, 25 parts of flour, 10 parts of walnut shell powder.It is 4~6% to be dried after granulation to water content,
The grain composition of dry granular is 8~40 mesh.
Embodiment 3
Metal hole stone dry granular, raw material composition are：32 parts of feldspar, 4 parts of quartz, 6 parts of kaolin, 9 parts of kaolinite of burning, ferric phosphate
36 parts, 12 parts of calcium phosphate, 1 part of zinc oxide, 30 parts of flour, 5 parts of walnut shell powder.It is 4~6% to be dried after granulation to water content, is done
The grain composition of grain is 8~40 mesh.
Embodiment 4
Metal hole stone dry granular, raw material composition are：32 parts of feldspar, 16 parts of quartz, 6 parts of kaolin, 9 parts of kaolinite of burning, phosphoric acid
36 parts of iron, 12 parts of calcium phosphate, 0.5 part of zinc oxide, 35 parts of flour, 10 parts of walnut shell powder.Dried after granulation to water content for 4~
6%, the grain composition of dry granular is 8~40 mesh.
Embodiment 5
Metal hole stone dry granular, raw material composition are：30 parts of feldspar, 20 parts of quartz, 5 parts of kaolin, 10 parts of kaolinite of burning, phosphoric acid
36 parts of iron, 10 parts of calcium phosphate, 0.5 part of zinc oxide, 40 parts of flour, 15 parts of walnut shell powder.Dried after granulation to water content for 4~
6%, the grain composition of dry granular is 8~40 mesh.
Embodiment 6
Metal hole stone dry granular, raw material composition are：18 parts of feldspar, 15 parts of quartz, 8 parts of kaolin, 13 parts of kaolinite of burning, phosphoric acid
32 parts of iron, 8 parts of calcium phosphate, 3 parts of zinc oxide, 15 parts of flour, 25 parts of walnut shell powder.It is 4~6% to be dried after granulation to water content,
The grain composition of dry granular is 8~40 mesh.
Embodiment 7
Metal hole stone dry granular, raw material composition are：26 parts of feldspar, 10 parts of quartz, 7 parts of kaolin, 16 parts of kaolinite of burning, phosphoric acid
28 parts of iron, 8 parts of calcium phosphate, 2 parts of zinc oxide, 50 parts of flour.It is 4~6% to be dried after granulation to water content, the grain composition of dry granular
For 8~40 mesh.
Embodiment 8
Metal hole stone dry granular, raw material composition are：26 parts of feldspar, 17 parts of quartz, 6.5 parts of kaolin, 13 parts of kaolinite of burning, phosphorus
Sour 24 parts of iron, 9 parts of calcium phosphate, 1.5 parts of zinc oxide, 5 parts of flour, 40 parts of walnut shell powder.Dried after granulation to water content for 4~
6%, the grain composition of dry granular is 8~40 mesh.
The preparation of metal hole stone dry granular brick：
It using cloth system cloth metal hole stone dry granular in glaze paint, suppresses, drying, into 1180 DEG C~1230 DEG C burnings of kiln
Into；Obtain metal hole stone dry granular brick.
Fig. 1 and Fig. 2 is the photograph for the metal hole stone dry granular brick being prepared using Examples 1 and 2 metal hole stone dry granular respectively
Piece.As can be seen that the sense of brick face hole is apparent, and it is true to nature, there is unique decorative effect.As shown in Figure 1 has metal hole stone dry granular
Product, it is seen that its clean mark gives people the sense of mild nature.As shown in Figure 2 has metal hole stone dry granular product, it is seen that hole stone
Sense is strong, and brick face has the vivid effect of imitative stone material.
Water is poured on brick face, it is found that water base is not penetrated into brick, shows there is fine and close glaze layer, explanation in the hole in brick face
The metal hole stone dry granular brick of the present invention is not easy soil pick-up.
Claims (10)
1. a kind of metal hole stone dry granular, material quality composition are：12~32 parts of feldspar, quartzy 4~29 parts, kaolin 5~8
Part, 9~16 parts of calcined kaolin, 24~36 parts of ferric phosphate, 8~12 parts of calcium phosphate, 0.5~3 part of zinc oxide, the organic powder 5 of viscosity
~50 parts, 0~40 part of the organic powder of lean property.
2. metal hole stone dry granular according to claim 1, it is characterised in that：Its material quality forms：Feldspar 18~26
Part, quartz 10~20 parts, 5~8 parts of kaolin, 9~16 parts of calcined kaolin, 24~36 parts of ferric phosphate, 8~12 parts of calcium phosphate,
0.5~3 part of zinc oxide, organic 15~30 parts of the powder of viscosity, 10~25 parts of the organic powder of lean property.
3. metal hole stone dry granular according to claim 1 or 2, it is characterised in that：The organic powder of viscosity is selected from flour, glutinous rice flour
Or the organic matter powder added with tackifier.
4. metal hole stone dry granular according to claim 1, it is characterised in that：The grain size of the lean organic powder of property is less than 80 mesh.
5. the metal hole stone dry granular according to claim 1,2 or 4, it is characterised in that：The lean organic powder of property is selected from wood powder, people
Make organic matter powder.
6. the metal hole stone dry granular according to claim 1,2 or 4, it is characterised in that：The water content of dry granular is 4~6%.
7. the metal hole stone dry granular according to claim 1,2 or 4, it is characterised in that：The grain composition of dry granular is 8~40
Mesh.
8. a kind of metal hole stone dry granular brick, it is characterised in that：Incrustation is had the right 1~8 any one of them metal hole of requirement
The surface that stone dry granular obtains after firing.
9. a kind of preparation method of metal hole stone dry granular brick is included in glaze layer charity claim 1~8 any one of them metal
Hole stone dry granular, is fired into.
10. preparation method according to claim 9, it is characterised in that：The firing temperature of metal hole stone dry granular brick is 1180
DEG C~1230 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711224987.5A CN108069732B (en) | 2017-11-29 | 2017-11-29 | Metal travertine dry particles and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711224987.5A CN108069732B (en) | 2017-11-29 | 2017-11-29 | Metal travertine dry particles and preparation method thereof |
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| CN108069732A true CN108069732A (en) | 2018-05-25 |
| CN108069732B CN108069732B (en) | 2020-10-27 |
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|---|---|---|---|
| CN201711224987.5A Active CN108069732B (en) | 2017-11-29 | 2017-11-29 | Metal travertine dry particles and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635259A (en) * | 2020-05-12 | 2020-09-08 | 蒙娜丽莎集团股份有限公司 | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof |
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| CN111635259A (en) * | 2020-05-12 | 2020-09-08 | 蒙娜丽莎集团股份有限公司 | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof |
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| CN108069732B (en) | 2020-10-27 |
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