CN111635259A - Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof - Google Patents
Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof Download PDFInfo
- Publication number
- CN111635259A CN111635259A CN202010397929.8A CN202010397929A CN111635259A CN 111635259 A CN111635259 A CN 111635259A CN 202010397929 A CN202010397929 A CN 202010397929A CN 111635259 A CN111635259 A CN 111635259A
- Authority
- CN
- China
- Prior art keywords
- golden
- glue
- glaze
- green brick
- dry particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/08—Frit compositions, i.e. in a powdered or comminuted form containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a marble ceramic tile with golden textures and a digital three-dimensional effect and a preparation method thereof. The preparation method of the marble ceramic tile with the digital three-dimensional effect and the golden texture comprises the following steps: applying base glaze on the surface of the green brick formed by pressing green body powder, and carrying out ink-jet printing on patterns; then positioning the glue to form a glue pattern, wherein the gray level of the glue pattern is 20-100%; distributing golden dry particles on the surface of the green brick after distributing the glue, so that at least part of the golden dry particles are adhered to the surface of the green brick; applying full-polished glaze on the surface of the green brick coated with the golden dry particles; and firing the green brick to obtain the digital three-dimensional golden texture marble ceramic tile.
Description
Technical Field
The invention relates to a marble ceramic tile with golden textures and a digital three-dimensional effect and a preparation method thereof, belonging to the technical field of ceramic tile production and manufacturing.
Background
Due to the environmental protection pressure, the irreproducibility of the stone and the very expensive price of the rare natural stone, the marble tile is favored by consumers as the best substitute, but the current mode of adopting the ink-jet printing metal ink (in-glaze color) is not vivid and stereoscopic all the time, the texture of the natural stone cannot be reflected, and especially, certain differences still exist in the imitation of the detailed texture and the stereoscopic special effect of some marble stones with golden textures. The invention adopts a digital glue dry grain machine to spray glue and distribute golden dry grains and applies full-polished glaze, thereby being capable of well imitating the golden texture three-dimensional effect of natural stone.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the marble ceramic tile with the golden texture and the digital three-dimensional effect and the preparation method thereof, so that the marble ceramic tile with the golden detailed texture and the three-dimensional effect can be obtained, and natural rare stone can be more realistically reduced.
In a first aspect, the invention provides a preparation method of a golden texture marble ceramic tile with a digital three-dimensional effect, which comprises the following steps: applying base glaze on the surface of the green brick formed by pressing green body powder, and carrying out ink-jet printing on patterns; then positioning the glue to form a glue pattern, wherein the gray level of the glue pattern is 20-100%; distributing golden dry particles on the surface of the green brick after distributing the glue, so that at least part of the golden dry particles are adhered to the surface of the green brick; applying full-polished glaze on the surface of the green brick coated with the golden dry particles; and firing the green brick to obtain the digital three-dimensional golden texture marble ceramic tile.
Preferably, the golden dry particle comprises a chemical composition packageComprises the following steps: by mass percent, SiO2:33.0~36.0%、Al2O3:12.0~15.0%、Fe2O3:15.0~20.0%、TiO2:0.15~1.50%、CaO:2.0~4.0%、MgO:0.1~0.5%、K2O:0.3~1.0%、Na2O:5.0~10.0%、P2O5:16.0~22.0%、ZnO:1.0~2.0%、Cr2O3: 0.50-1.50%, loss on ignition: 0.1 to 0.3 percent.
Preferably, the grain size of the golden dry particles is 40-150 meshes.
Preferably, the chemical composition of the full-polished glaze comprises: by mass percent, SiO2:43.0~50.0%、Al2O3:13.0~16.0%、Fe2O3:0.1~0.5%、TiO2:0.1~0.3%、CaO:7.0~9.0%、MgO:3.5~4.5%、K2O:3.5~4.5%、Na2O: 1.5-2.5%, ZnO: 3.0-5.0%, BaO: 7.0-12.0%, loss on ignition: 6.0 to 9.0 percent.
Preferably, the application mode of the full-polishing glaze is glaze pouring, the specific gravity of the full-polishing glaze is 1.76-1.81, and the glazing amount is 550-650 g/m2。
Preferably, the chemical composition of the ground glaze comprises: by mass percent, SiO2:55~60%、Al2O3:21~24%、Fe2O3:0.16~0.46%、TiO2:0.15~0.25%、CaO:0.1~0.3%、MgO:0.1~0.3%、K2O:4.0~5.0%、Na2O:2.0~3.0%、ZrO2: 6.0-10.0%, loss on ignition: 3.0 to 4.0 percent.
Preferably, the application mode of the ground coat is glaze spraying, the specific gravity of the ground coat is 1.40-1.45, and the glazing amount is 400-550 g/m2。
Preferably, the maximum firing temperature is 1210-1230 ℃, and the firing period is 60-70 minutes.
In a second aspect, the invention also provides the marble ceramic tile with the digital stereoscopic effect and the golden texture, which is obtained by the preparation method.
The marble ceramic tile disclosed by the invention is combined with the digital glue to position the golden dry particles of the cloth, so that a more vivid and three-dimensional natural stone effect can be achieved, golden detailed lines and textures can be changed along with the change of pattern textures, and a very good artistic effect is achieved.
Drawings
FIG. 1 is a flow chart of the preparation process of the digital three-dimensional effect golden texture marble ceramic tile according to one embodiment of the present invention;
FIG. 2 is a block surface effect diagram of the digital three-dimensional effect golden texture marble ceramic tile of example 1;
FIG. 3 is a block surface effect diagram of the digital three-dimensional effect golden texture marble ceramic tile of comparative example 3.
Detailed Description
The present invention is further illustrated by the following examples, which are to be understood as merely illustrative and not restrictive. Unless otherwise specified, each percentage means a mass percentage.
The following describes an exemplary method for preparing the marble ceramic tile with the digital stereoscopic effect and the golden texture with reference to fig. 1.
Firstly, pressing and forming green body powder to form a green brick. The green brick can be formed by dry pressing using a press. The composition of the green body powder is not limited, and the conventional ceramic tile green body powder in the field can be adopted. For example, the chemical composition of the green body powder comprises, in mass percent, SiO2:60.0~70.0%、Al2O3:19.0~25.0%、Fe2O3:0.5~1.5%、TiO2:0.2~0.5%、CaO:0.2~0.8%、MgO:0.3~0.8%、K2O:2.0~4.0%、Na2O: 1.5-3.5%, loss on ignition: 4.0 to 6.0 percent.
And drying the green brick. The drying time can be 1-1.5 h. And controlling the moisture of the dried green brick to be 0.3-0.5 wt%.
And applying base glaze on the surface of the dried green brick. The ground glaze is applied to improve the texture of the glaze and reduce pinholes and miliaria of the glaze. The ground coat can be applied by spraying glaze.
In some embodiments, the chemical composition of the ground glaze may include: by mass percent, SiO2:55~60%、Al2O3:21~24%、Fe2O3:0.16~0.46%、TiO2:0.15~0.25%、CaO:0.1~0.3%、MgO:0.1~0.3%、K2O:4.0~5.0%、Na2O:2.0~3.0%、ZrO2: 6.0-10.0%, loss on ignition: 3.0 to 4.0 percent.
The specific gravity of the ground coat can be 1.40-1.45, and the glazing amount can be 400-550 g/m2。
And (4) ink-jet printing patterns on the surface of the green brick after the ground glaze is applied. The color and pattern of the inkjet printed pattern vary according to the layout effect.
And (4) positioning and distributing glue on the surface of the green brick after ink-jet printing. The glue can be printed by a digital glue ink jet. The glue mainly plays a role in bonding. The gray scale of the glue pattern can be 20% -100%. Glue patterns with different gray scales correspond to different gold dry particle application amounts. The application amount of the glue patterns and the golden dry particles can be adjusted according to the actual effect of the layout design. If the gray level of the glue pattern is less than 20%, the glue is not firm in fixation of dry particles, the phenomenon that the dry particles to be fixed are taken away easily occurs, in addition, the dry particles with a small amount of glue adhered to the surface can enter a circulating system of a dry particle machine, the dry particle mobility is easy to deteriorate along with the lapse of time, and the phenomenon of uneven blanking occurs. In some embodiments, the desired portions of the pattern are selected in advance, depending on the pattern design, and the glue forms a glue pattern on the tile face by printing the glue with a digital glue jet. And the state of the spray head can be conveniently observed by adding pigment into the glue.
And golden dry particles are distributed on the surface of the green brick after the glue is distributed. For example, golden dry granules are distributed on the surface of a green brick by a digital glue dry granule machine, and the dry granules which are not adhered and fixed by the glue are pumped away and recycled by an exhaust fan. And in the glue pattern corresponding areas with different gray scales, the remained dry particles are pumped away by an exhaust fan to form certain pattern textures. In addition, glue patterns with different gray scales correspond to different golden dry particlesA fixed amount, and thus exhibits a concavo-convex effect due to the accumulation of the gold dry particles in at least a partial region. In addition, the thickness and the gray scale of the pattern (line part) can be adjusted according to the actual layout effect. If the gray level of the glue pattern is too high, the amount of the adhered golden dry particles is relatively large, and the glaze surface of the part of the burnt golden dry particles is relatively convex. If the gray scale of the glue pattern is too low, the adhesion amount of the golden dry particles is too small, so that the golden effect appears scattered and not coherent and natural enough, as shown in comparative example 1. The research shows that when the double-channel glue is adopted, the gray level is 45-55%, and the quantity of the adhered dry particles is 200-300 g/m2The effect is optimal. If the gray level of the double-channel glue is higher than 55%, the glaze stripping phenomenon can occur. The reason is that the glue can form a film prematurely in the drying process, so that the blank body is prevented from draining water, and when the water vapor of the blank body is too much, the film can be broken to cause the phenomenon of stripping. If the gray level of the double-channel glue is lower than 45%, the amount of the adhered golden dry particles is small, so that part of the golden dry particles are not firmly adhered to enter a circulating system of the glue dry particle machine, and the part of the golden dry particles adhered with a small amount of glue is easy to cause the poor flowability of the dry particles along with the time, so that the condition of uneven blanking is caused.
The chemical composition of the golden dry particles can comprise: by mass percent, SiO2:33.0~36.0%、Al2O3:12.0~15.0%、Fe2O3:15.0~20.0%、TiO2:0.15~1.50%、CaO:2.0~4.0%、MgO:0.1~0.5%、K2O:0.3~1.0%、Na2O:5.0~10.0%、P2O5:16.0~22.0%、ZnO:1.0~2.0%、Cr2O3: 0.50-1.50%, loss on ignition: 0.1 to 0.3 percent.
The golden dry granules comprise the following raw materials: 45-50% of albite, 30-35% of iron phosphate, 5-10% of calcium phosphate, 3-10% of silicon tripolyphosphate, 5-10% of kaolin, 1-2% of zinc oxide, 1-3% of ferrochrome brown and 1-3% of ferrotitanium yellow in percentage by mass. In the formula, iron chromium brown and ferrotitanium yellow are introduced as seed crystals, and zinc oxide plays roles in crystallization assistance and fluxing, so that a golden effect is realized.
In some embodiments, the method of preparing the gold-colored dry granules comprises: weighing the raw materials according to the formula ratio, putting the raw materials into a mixer, uniformly mixing, adding the uniformly mixed raw materials into a smelting furnace, melting the raw materials into liquid at a high temperature of 1500-1600 ℃, vertically flowing into water at a temperature of 20-70 ℃, and quenching to form a fusion cake. And (4) after the water content of the fusion cake is filtered, putting the fusion cake into a roll crusher for crushing and screening to obtain the golden dry particles with the required particle size distribution. The grain diameter of the golden dry particles is 40-150 meshes. And (3) circularly feeding the particles with the mesh number of less than 40 into a double-roller machine for circular crushing, and feeding the particles with the mesh number of more than 150 into a smelting furnace as a raw material for recycling.
The golden dry particles are particles with certain particle size distribution obtained after high-temperature melting, crushing and screening, and organic matters and carbonate in the golden dry particles are volatilized. In addition, after the pattern is printed by ink jet, the preparation method of the invention adopts a mode of spraying glue by a digital glue ink jet machine and distributing dry particles by a digital glue dry particle machine, and the three-dimensional effect and the golden texture are realized by adhering the golden dry particles by the glue gray scale and the texture of a design effect net (namely a pattern design layout).
And (4) fully polishing glaze on the surface of the green brick coated with the golden dry particles. The purpose of applying the full glaze after the golden dry particles are distributed is to ensure the antifouling effect of the part without the golden dry particles and the requirement of polishing processing at the later stage. The fully polished glaze can be a transparent fully polished glaze. The full-polishing glaze can adopt conventional full-polishing glaze. In some embodiments, the chemical composition of the fully polished glaze may include: by mass percent, SiO2:43.0~50.0%、Al2O3:13.0~16.0%、Fe2O3:0.1~0.5%、TiO2:0.1~0.3%、CaO:7.0~9.0%、MgO:3.5~4.5%、K2O:3.5~4.5%、Na2O: 1.5-2.5%, ZnO: 3.0-5.0%, BaO: 7.0-12.0% loss on ignition: 6.0 to 9.0 percent.
The application mode of the full-polishing glaze can be glaze pouring. The specific gravity of the full-polished glaze is 1.76-1.81, and the glazing amount is 550-650 g/m2。
Because polishing is needed finally, the golden dry particles and the full polishing are carried outThe portion of the glaze overlay was discarded, completely exposing the textured portion of the gold dry grain. The fully-polished glaze plays a role in adhesion in the firing process, so that the golden dry particles can be prevented from being pumped away by a kiln, and the close combination between the fired golden dry particles and the fully-polished glaze can also be ensured. Meanwhile, in order to avoid the phenomenon of stripping, the water can be smoothly discharged in the drying process by controlling the using amount of the digital glue and the using amount of the full-polished glaze. In some embodiments, the amount of the glue is 12-60 g/m2。
And drying the green brick after the full glaze polishing. The drying temperature can be 100-150 ℃, and the water content of the dried green brick is controlled within 0.9 wt%. The drying mode can be electric drying or hot air drying oven drying.
And sintering the dried green brick. The maximum firing temperature can be 1210-1230 ℃, and the firing period can be 60-70 minutes.
Polishing the sintered ceramic tile, and edging and grading to obtain the marble ceramic tile with golden texture.
The present invention will be described in detail by way of examples. It is also to be understood that the following examples are illustrative of the present invention and are not to be construed as limiting the scope of the invention, and that certain insubstantial modifications and adaptations of the invention by those skilled in the art may be made in light of the above teachings. The specific process parameters and the like of the following examples are also only one example of suitable ranges, i.e., those skilled in the art can select the appropriate ranges through the description herein, and are not limited to the specific values exemplified below.
Example 1
(1) Dry pressing the green body powder by a press to form a green brick;
(2) drying the green brick for 1-1.5 h, wherein the water content of the dried green brick is 0.3-0.5 wt%;
(3) spraying a ground coat on the surface of the dried green brick, wherein the specific gravity of the ground coat is 1.40-1.45, and the glazing amount is 400-550 g/m2;
(4) Printing a pattern on the surface of the green brick sprayed with the ground glaze in an ink-jet manner;
(5) spraying glue by using a digital glue ink jet printer, wherein the gray level of the double-channel digital glue pattern is 45% -55%; a layer of golden dry particles is fully distributed on the surface of the brick by using a digital glue dry particle machine, and the dry particles which are not stuck by the glue are pumped away and recycled by using an exhaust fan; meanwhile, the glue patterns with different gray scales are pumped away by an exhaust fan to form certain textures and show a concave-convex effect;
(6) spraying full-polished glaze on the surface of the green brick with the golden dry particles adhered to the surface, wherein the specific gravity of the full-polished glaze is 1.76-1.81, and the glazing amount is 550-650 g/m2;
(7) Drying the green brick after being sprayed with the full-glazed glaze, wherein the drying temperature is 100-150 ℃, and the moisture content of the dried brick is controlled within 0.9 wt%;
(8) sintering, wherein the maximum sintering temperature is 1220 ℃, and the sintering period is 60 minutes;
(9) and (5) polishing, edging and grading.
Comparative example 1
(1) Dry pressing the green body powder by a press to form a green brick;
(2) drying the green brick for 1-1.5 h, wherein the water content of the dried green brick is 0.3-0.5 wt%;
(3) spraying a ground coat on the surface of the dried green brick, wherein the specific gravity of the ground coat is 1.40-1.45, and the glazing amount is 400-550 g/m2;
(4) Printing a pattern on the surface of the green brick sprayed with the ground glaze in an ink-jet manner;
(5) spraying glue by adopting a digital glue ink jet machine, wherein the gray level of the double-channel digital glue pattern is 15%; a layer of golden dry particles is fully distributed on the surface of the brick by using a digital glue dry particle machine, and the dry particles which are not stuck by the glue are pumped away and recycled by using an exhaust fan; meanwhile, the glue patterns with different gray scales are pumped away by an exhaust fan to form certain texture and show a concave-convex effect;
(6) spraying full-polished glaze on the surface of the green brick with the golden dry particles adhered to the surface, wherein the specific gravity of the full-polished glaze is 1.76-1.81, and the glazing amount is 450-650 g/m2;
(7) Drying the green brick after being sprayed with the full-glazed glaze, wherein the drying temperature is 100-150 ℃, and the moisture content of the dried brick is controlled within 0.9 wt%;
(8) sintering, wherein the maximum sintering temperature is 1220 ℃, and the sintering period is 60 minutes;
(9) and (5) polishing, edging and grading.
The brick surface effect of this experimental scheme is relatively poor, and the gold texture that forms is not consecutive, and the punctiform is more scattered, mainly because the grey level of glue pattern is too low, leads to the dry grain volume of adhesion too little, can't realize three-dimensional gold marble texture effect after the polishing.
Comparative example 2
(1) The raw materials are as follows: 45-50 wt% of albite, 30-35 wt% of iron phosphate, 5-10 wt% of calcium phosphate, 3-10 wt% of silicon tripolyphosphate and 5-10 wt% of kaolin are mixed, melted, water quenched, granulated and screened to prepare metal dry particles for later use;
(2) dry pressing the green body powder by a press to form a green brick;
(3) drying the green brick for 1-1.5 h, wherein the water content of the dried green brick is 0.3-0.5 wt%;
(4) spraying a ground coat on the surface of the dried green brick, wherein the specific gravity of the ground coat is 1.40-1.45, and the glazing amount is 400-550 g/m2;
(5) Printing a pattern on the surface of the green brick sprayed with the ground glaze in an ink-jet manner;
(6) spraying glue by using a digital glue ink jet printer, wherein the gray level of the double-channel digital glue pattern is 45% -55%; a layer of metal dry particles is distributed on the surface of the brick by using a glue dry particle machine, and the dry particles which are not stuck by the glue are pumped out and recycled by using an exhaust fan; meanwhile, the glue patterns with different gray scales are formed into certain textures by pumping away the remained dry grain glaze through an exhaust fan to present a concave-convex effect;
(7) spraying full-polished glaze on the surface of the green brick with the golden dry particles adhered to the surface, wherein the specific gravity of the full-polished glaze is 1.76-1.81, and the glazing amount is 450-650 g/m2;
(8) Drying the green brick after being sprayed with the full-glazed glaze, wherein the drying temperature is 100-150 ℃, and the moisture content of the dried brick is controlled within 0.9 wt%;
(9) sintering, wherein the maximum sintering temperature is 1220 ℃, and the sintering period is 60 minutes;
(10) and (5) polishing, edging and grading.
The brick surface effect of this experimental scheme forms copper look metal texture.
Comparative example 3
(1) Dry pressing the green body powder by a press to form a green brick;
(2) drying the green brick for 1-1.5 h, wherein the water content of the dried green brick is 0.3-0.5 wt%;
(3) spraying a ground coat on the surface of the dried green brick, wherein the specific gravity of the ground coat is 1.40-1.45, and the glazing amount is 400-550 g/m2;
(4) Printing a pattern on the surface of the green brick sprayed with the ground glaze in an ink-jet manner;
(5) spraying glue by using a digital glue ink jet printer, wherein the gray level of the pattern of the double-channel digital glue is 65%; a layer of golden dry particles is fully distributed on the surface of the brick by using a glue dry particle machine, and the dry particles which are not stuck by the glue are pumped away and recycled by using an exhaust fan; meanwhile, the glue patterns with different gray scales are formed into certain textures by pumping away the remained dry grain glaze through an exhaust fan to present a concave-convex effect;
(6) spraying full-polished glaze on the surface of the green brick with the golden dry particles adhered to the surface, wherein the specific gravity of the full-polished glaze is 1.76-1.81, and the glazing amount is 450-650 g/m2;
(7) Drying the green brick after being sprayed with the full-glazed glaze, wherein the drying temperature is 100-150 ℃, and the moisture content of the dried brick is controlled within 0.9 wt%;
(8) sintering, wherein the maximum sintering temperature is 1220 ℃, and the sintering period is 60 minutes;
(9) and (5) polishing, edging and grading.
The stripping phenomenon appears on the surface of the ceramic tile in the experimental scheme, as shown in figure 3.
Claims (9)
1. The preparation method of the marble ceramic tile with the golden texture and the digital three-dimensional effect is characterized by comprising the following steps of: applying base glaze on the surface of the green brick formed by pressing green body powder, and carrying out ink-jet printing on patterns; then positioning the glue to form a glue pattern, wherein the gray level of the glue pattern is 20-100%; distributing golden dry particles on the surface of the green brick after distributing the glue, so that at least part of the golden dry particles are adhered to the surface of the green brick; applying full-polished glaze on the surface of the green brick coated with the golden dry particles; and firing the green brick to obtain the digital three-dimensional golden texture marble ceramic tile.
2. The method of claim 1, wherein the gold-colored dry granules have a chemical composition comprising: by mass percent, SiO2:33.0~36.0%、Al2O3:12.0~15.0%、Fe2O3:15.0~20.0%、TiO2:0.15~1.50%、CaO:2.0~4.0%、MgO:0.1~0.5%、K2O:0.3~1.0%、Na2O:5.0~10.0%、P2O5:16.0~22.0%、ZnO:1.0~2.0%、Cr2O3: 0.50-1.50%, loss on ignition: 0.1 to 0.3 percent.
3. The production method according to claim 1 or 2, wherein the gold-colored dry particles have a particle size of 40 to 150 mesh.
4. The method according to any one of claims 1 to 3, wherein the chemical composition of the full-polished glaze comprises: by mass percent, SiO2:43.0~50.0%、Al2O3:13.0~16.0%、Fe2O3:0.1~0.5%、TiO2:0.1~0.3%、CaO:7.0~9.0%、MgO:3.5~4.5%、K2O:3.5~4.5%、Na2O: 1.5-2.5%, ZnO: 3.0-5.0%, BaO: 7.0-12.0% loss on ignition: 6.0 to 9.0 percent.
5. The preparation method according to any one of claims 1 to 4, characterized in that the full-polished glaze is applied by means of pouring glaze, the specific gravity of the full-polished glaze is 1.76-1.81, and the glazing amount is 550-650 g/m2。
6. The method according to any one of claims 1 to 5, characterized in that the chemical composition of the under-glaze comprises: by mass percent, SiO2:55~60%、Al2O3:21~24%、Fe2O3:0.16~0.46%、TiO2:0.15~0.25%、CaO:0.1~0.3%、MgO:0.1~0.3%、K2O:4.0~5.0%、Na2O:2.0~3.0%、ZrO2: 6.0-10.0%, loss on ignition: 3.0 to 4.0 percent.
7. The method according to any one of claims 1 to 6, wherein the under coat is applied by spraying glaze, the under coat has a specific gravity of 1.40 to 1.45 and an application amount of 400 to 550g/m2。
8. The production method according to any one of claims 1 to 7, wherein the maximum firing temperature is 1210 to 1230 ℃ and the firing period is 60 to 70 minutes.
9. The golden grain marble ceramic tile with digital stereoscopic effect obtained by the preparation method according to any one of claims 1 to 8.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010397929.8A CN111635259B (en) | 2020-05-12 | 2020-05-12 | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010397929.8A CN111635259B (en) | 2020-05-12 | 2020-05-12 | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111635259A true CN111635259A (en) | 2020-09-08 |
CN111635259B CN111635259B (en) | 2022-02-11 |
Family
ID=72327864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010397929.8A Active CN111635259B (en) | 2020-05-12 | 2020-05-12 | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111635259B (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112279512A (en) * | 2020-10-16 | 2021-01-29 | 蒙娜丽莎集团股份有限公司 | Wear-resistant full-polished magnesia-alumina spinel glaze as well as preparation method and application thereof |
CN113232136A (en) * | 2021-07-13 | 2021-08-10 | 蒙娜丽莎集团股份有限公司 | Stereo relief ceramic artistic plate and preparation method thereof |
CN113896569A (en) * | 2021-09-26 | 2022-01-07 | 江西唯美陶瓷有限公司 | Ceramic rock plate with multicolor light-transmitting three-dimensional effect and manufacturing method thereof |
CN113979785A (en) * | 2021-09-28 | 2022-01-28 | 蒙娜丽莎集团股份有限公司 | Glazed brick with metal texture and preparation method thereof |
CN114804928A (en) * | 2022-05-24 | 2022-07-29 | 广西蒙娜丽莎新材料有限公司 | Preparation method of one-time sintered gold-plated dry grain glazed rock plate |
WO2022205988A1 (en) * | 2021-03-31 | 2022-10-06 | 蒙娜丽莎集团股份有限公司 | Ceramic slab having colored jade effect and preparation method therefor |
CN115196993A (en) * | 2022-07-13 | 2022-10-18 | 九江诺贝尔陶瓷有限公司 | Dry particles and production method of once-fired double-digital decorative colorful rock plate by using dry particles |
CN115215684A (en) * | 2022-07-12 | 2022-10-21 | 广东陶瓷共赢商科技有限公司 | Ceramic tile with three-dimensional color texture patterns and preparation method thereof |
CN115353288A (en) * | 2022-07-13 | 2022-11-18 | 九江诺贝尔陶瓷有限公司 | Production device and production method of double-digital decorative embossed three-dimensional effect face rock plate |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4501778A (en) * | 1983-05-06 | 1985-02-26 | Degussa Aktiengesellschaft | Metal effect glazes for ceramic bases |
CN108069732A (en) * | 2017-11-29 | 2018-05-25 | 广东道氏技术股份有限公司 | A kind of metal hole stone dry granular and preparation method thereof |
CN109293399A (en) * | 2018-11-09 | 2019-02-01 | 蒙娜丽莎集团股份有限公司 | One kind having stone pattern embossing feeling dry granular brick and preparation method thereof |
CN109437977A (en) * | 2018-11-09 | 2019-03-08 | 蒙娜丽莎集团股份有限公司 | A kind of dry granular brick and preparation method thereof with mold concave-convex effect |
CN110396005A (en) * | 2019-06-20 | 2019-11-01 | 蒙娜丽莎集团股份有限公司 | A kind of stereoscopic localized effect dry granular throws Ceramic Tiles and preparation method entirely |
CN110885256A (en) * | 2019-11-19 | 2020-03-17 | 蒙娜丽莎集团股份有限公司 | Digital dry particle inner wall brick with stereoscopic luminous effect and preparation method thereof |
-
2020
- 2020-05-12 CN CN202010397929.8A patent/CN111635259B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4501778A (en) * | 1983-05-06 | 1985-02-26 | Degussa Aktiengesellschaft | Metal effect glazes for ceramic bases |
CN108069732A (en) * | 2017-11-29 | 2018-05-25 | 广东道氏技术股份有限公司 | A kind of metal hole stone dry granular and preparation method thereof |
CN109293399A (en) * | 2018-11-09 | 2019-02-01 | 蒙娜丽莎集团股份有限公司 | One kind having stone pattern embossing feeling dry granular brick and preparation method thereof |
CN109437977A (en) * | 2018-11-09 | 2019-03-08 | 蒙娜丽莎集团股份有限公司 | A kind of dry granular brick and preparation method thereof with mold concave-convex effect |
CN110396005A (en) * | 2019-06-20 | 2019-11-01 | 蒙娜丽莎集团股份有限公司 | A kind of stereoscopic localized effect dry granular throws Ceramic Tiles and preparation method entirely |
CN110885256A (en) * | 2019-11-19 | 2020-03-17 | 蒙娜丽莎集团股份有限公司 | Digital dry particle inner wall brick with stereoscopic luminous effect and preparation method thereof |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112279512A (en) * | 2020-10-16 | 2021-01-29 | 蒙娜丽莎集团股份有限公司 | Wear-resistant full-polished magnesia-alumina spinel glaze as well as preparation method and application thereof |
CN112279512B (en) * | 2020-10-16 | 2022-07-01 | 蒙娜丽莎集团股份有限公司 | Wear-resistant full-polished magnesia-alumina spinel glaze as well as preparation method and application thereof |
WO2022205988A1 (en) * | 2021-03-31 | 2022-10-06 | 蒙娜丽莎集团股份有限公司 | Ceramic slab having colored jade effect and preparation method therefor |
CN113232136A (en) * | 2021-07-13 | 2021-08-10 | 蒙娜丽莎集团股份有限公司 | Stereo relief ceramic artistic plate and preparation method thereof |
CN113896569A (en) * | 2021-09-26 | 2022-01-07 | 江西唯美陶瓷有限公司 | Ceramic rock plate with multicolor light-transmitting three-dimensional effect and manufacturing method thereof |
CN113896569B (en) * | 2021-09-26 | 2022-08-19 | 江西唯美陶瓷有限公司 | Ceramic rock plate with multicolor light-transmitting three-dimensional effect and manufacturing method thereof |
CN113979785A (en) * | 2021-09-28 | 2022-01-28 | 蒙娜丽莎集团股份有限公司 | Glazed brick with metal texture and preparation method thereof |
CN114804928A (en) * | 2022-05-24 | 2022-07-29 | 广西蒙娜丽莎新材料有限公司 | Preparation method of one-time sintered gold-plated dry grain glazed rock plate |
CN115215684A (en) * | 2022-07-12 | 2022-10-21 | 广东陶瓷共赢商科技有限公司 | Ceramic tile with three-dimensional color texture patterns and preparation method thereof |
CN115196993A (en) * | 2022-07-13 | 2022-10-18 | 九江诺贝尔陶瓷有限公司 | Dry particles and production method of once-fired double-digital decorative colorful rock plate by using dry particles |
CN115353288A (en) * | 2022-07-13 | 2022-11-18 | 九江诺贝尔陶瓷有限公司 | Production device and production method of double-digital decorative embossed three-dimensional effect face rock plate |
Also Published As
Publication number | Publication date |
---|---|
CN111635259B (en) | 2022-02-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111635259B (en) | Marble ceramic tile with digital stereoscopic effect and golden texture and preparation method thereof | |
CN106518029B (en) | A kind of marble Ceramic Tiles preparation method with metallic luster recess texture | |
CN105272378B (en) | A kind of preparation method and product of the parian thickness glazed brick of the sagging texture of combination | |
CN105272375B (en) | A kind of Buddha's warrior attendant glaze of wear-resisting high rigidity, preparation method and application | |
CN106565281B (en) | A kind of full throwing glaze Ceramic Tiles and preparation method thereof with metallic particles and gloss | |
CN106986540B (en) | Formula for making sunken and peeled marble glaze | |
CN112456802B (en) | Giant crystal particles capable of forming crystal flowers, dry particle combination, particles for ceramics, ceramics and preparation method of ceramics | |
CN105565907B (en) | A kind of preparation method of transmutation crystalline substance flower seeding fixation Ceramic Tiles | |
CN112500196B (en) | Ceramic tile with stereoscopic gem particle feeling glaze and preparation method thereof | |
CN111423113A (en) | Polished glazed brick with dry diamond grains and positioning diamond flashing effect and preparation method thereof | |
CN102329152A (en) | Complete polishing glaze archaizing brick overglaze and preparation method thereof | |
CN109437977B (en) | Dry particle brick with concave-convex effect of mold and preparation method thereof | |
CN110845227A (en) | Positioning crystal-patterned light-transmitting ceramic tile and preparation method thereof | |
CN106278383B (en) | A method of manufacture surface has Z-Correct bump mapping Z-correct Ceramic Tiles | |
CN110451802A (en) | A kind of mica sheet decorative porcelain glazed tile and preparation method thereof | |
CN111646786B (en) | Ceramic brick prepared by micro powder composite ink-jet positioning dry particle process and preparation method thereof | |
CN105481478B (en) | A kind of preparation method of pattern permeating tile | |
CN110845252B (en) | Special blank large-particle combined digital cloth archaized brick and preparation method thereof | |
CN109534679A (en) | A kind of metal dry granular glaze and preparation method thereof and metal dry granular overglaze dazzle the preparation method for throwing brick | |
CN110885256A (en) | Digital dry particle inner wall brick with stereoscopic luminous effect and preparation method thereof | |
CN115677220B (en) | Waxy ceramic tile with three-dimensional decorative effect and preparation method thereof | |
CN106800422B (en) | A kind of manufacturing method of Ceramic Tiles | |
CN114702336A (en) | White polycrystalline dry-grain ceramic rock plate and preparation method thereof | |
CN105000865B (en) | A kind of preparation method of large-size ceramic tile | |
CN107963813B (en) | Preparation method of candy glaze and candy glaze ceramic tile prepared from raw glaze |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |