CN107266023A - Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface - Google Patents

Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface Download PDF

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CN107266023A
CN107266023A CN201710475109.4A CN201710475109A CN107266023A CN 107266023 A CN107266023 A CN 107266023A CN 201710475109 A CN201710475109 A CN 201710475109A CN 107266023 A CN107266023 A CN 107266023A
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ink
jet
penetration
base substrate
oozed
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CN107266023B (en
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曾凡平
邱金清
蔡伟强
侯斌
卢广坚
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GUANGDONG HONGHAI CERAMIC INDUSTRIAL DEVELOPMENT Co Ltd
Guangdong Hongwei Ceramic Industry Co Ltd
GUANGDONG WINTO CERAMICS CO Ltd
Guangdong Hongyu New Material Co Ltd
Original Assignee
GUANGDONG HONGHAI CERAMIC INDUSTRIAL DEVELOPMENT Co Ltd
Guangdong Hongwei Ceramic Industry Co Ltd
GUANGDONG WINTO CERAMICS CO Ltd
Guangdong Hongyu New Material Co Ltd
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Abstract

The surface of the present invention is gentle to include base substrate as colored polished brick in porcelain character and preparation method are oozed in ink-jet that jade has translucency, billet surface acidulant and penetration-assisting agent, on the basis of great change is not made to the production technologies of existing porcelain seep curlicue polished bricks, emphasis is constituted to the formula of base substrate, the formula composition of billet surface acidulant, the formula composition of penetration-assisting agent, spray spray amount and the adjustment and optimization of kiln firing process of surface acidulant and penetration-assisting agent, so that the gentle such as jade of colored polished brick in porcelain character product surface is oozed in obtained ink-jet, various colors, it is bright-coloured, ink-jet, which is oozed floral pattern and penetrated into, reaches 2mm inside base substrate, and pattern texture clear and natural, beautiful texture is strong, product is translucent shape, translucency is good, overleaf irradiated with flashlight or light, shadow and interiors of products pattern can be clearly seen in front, unique decorative effect such as rare natural penetrating jade and Agate;The technology possesses stronger universality simultaneously, it is easy in industry promote.

Description

Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface
Technical field:
The present invention relates to the preparing technical field of porcelain seep curlicue polished bricks, more particularly, to a kind of surface is gentle as jade has Colored polished brick in porcelain character and preparation method are oozed in the ink-jet of translucency.
Background technology:
The rare stone material such as jade, Agate is a kind of tcrude ore of bijouterie, and it has quality fine and smooth, soft and moist, logical Thoroughly, the features such as rich color, after chiseling and carving meticulously, your gas is full.Because their permeabilities are good, have fine-textured skin, soft and moist, these Raw ore stone material is used as wall by some high-grade places after sanding and polishing, the top grade decoration such as feature wall is interspersed, due to these The stone material of high value gemstone level has special permeability, under the irradiation of its back side light, and its internal stone material skin texture can be from just Face reveals out, and more seem splendid, high-grade elegance, and your gas is full, collection dicoration, appreciating and one, by numerous new High official scholar's pursues, and holds at high price, and conventional ceramic Wall or floor tile is with the continuous innovation of decoration technique, its picture on surface, Color, the effect of texture can reach the surface effect of the rare stone material such as jade, Agate, but the inside flesh of these stone materials Reason and the current conventional ceramic Wall or floor tile of permeability are also unable to reach, if can be the inside skin texture and permeability of these rare stone materials It is replicated on ceramic wall and floor bricks product, makes this increasingly rare, the rare Gem Grade stone material that somethings can only be found by accident, and not through seeking, by common wall The paving of brick, along with interspersing for light, so that splendid, high-grade grace at home, more dignitary's gas will necessarily be in ceramics dress Obvious technological innovation is produced in decorations technology, the new development of ceramic decoration technology is led, with considerable economic benefit.
The content of the invention:
It is an object of the invention to overcome disadvantages mentioned above gentle as colored porcelain is oozed in the beautiful ink-jet for having translucency there is provided a kind of surface Matter polished bricks and preparation method, on the basis of great change is not made to existing porcelain seep curlicue polished bricks production technology, pass through Being formulated for base substrate is constituted, the formula composition of billet surface acidulant, the formula of penetration-assisting agent constitute, spray billet surface acidulant Spray amount, the spray amount for spraying penetration-assisting agent, the adjustment and optimization of kiln firing process, so that obtained ink-jet, which is oozed, spends ceramic polished Brick product surface is gentle as floral pattern clear and natural is oozed in jade, various colors, ink-jet and pattern penetrates into and 2mm is reached inside base substrate, production Be translucent shape, translucency of product is good, and with flashlight or light in product back side illuminaton, shadow and inside can be clearly seen in front Pattern, while penetrating into, the color of interiors of products pattern, texture and surface are basically identical, and high-visible, third dimension is strong, with bird with red feathers Unique decorative effect as the rare penetrating Gem Grade stone material such as emerald stone, Agate, and product surface quality is good, resistant is strong, hard The defects such as height, strong, the pin-free, fusion hole of wearability are spent, through Micro-Structure Analysis, product surface analysis has been expired as in natural jadeite jade Sodium aluminum silicate mineral as lagoriolite (AlNaSi2O6) fine crystals.The technology possesses stronger universality simultaneously, easily Promoted in industry.
In order to solve the above technical problems, the present invention is achieved through the following technical solutions:
Colored polished brick in porcelain character is oozed in the gentle ink-jet as jade has translucency in surface of the present invention, and it includes:
Base substrate:Prepared by following weight percent composition:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2% ~0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3%~4%, all components sum is 100%;Added weight percentage is 0.8%~1.2% auxiliary material;
Wherein:Described auxiliary material includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate;The base substrate is 1200 DEG C~1220 DEG C of temperature lower calcinations after be translucent shape;
Billet surface acidulant:Prepared by following parts by weight of component:
20~40 parts of acetic acid, 60~80 parts of water;
The spray amount of described billet surface acidulant is 30~50g/ ㎡;
Penetration-assisting agent:Prepared by following parts by weight component:
60~80 parts of Ludox, 20~40 parts of acetate emulsion;
Described penetration-assisting agent spray amount is 40~60g/ ㎡.
The preparation method of colored polished brick in porcelain character is oozed the invention further relates to a kind of gentle ink-jet as jade has translucency in surface, its Comprise the following steps:
A, base substrate preparation:
The percentage by weight of the component of base substrate is:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2% ~0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3%~4%, all components sum is 100%;
By the weight percent content of the component of above-mentioned base substrate, the potassium feldspar and albite and quartz of corresponding proportion are chosen Mixed sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage are 0.8% ~1.2% auxiliary material, it into fineness is that 250 mesh sieves tail over as mass percent to add appropriate water in small, broken bits through ball milling 0.5%~0.7% and containing mass percent be 33%~35% moisture slurry, through except iron sieving spray drying be made containing quality Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2It is molded under pressure limit with automatic hydraulic press, then Base substrate is drying to obtain by throwing base, dry kiln;
Additional auxiliary material therein includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate;
Lithium porcelain stone raw material therein is containing P2O5The lithium porcelain stone raw material of composition;
B, billet surface acidulant preparation, are prepared by weight:
20~40 parts of acetic acid and 60~80 parts of water are mixed together to stir and produce billet surface acidulant;
C, penetration-assisting agent preparation, are prepared by weight:
60~80 parts of Ludox and 20~40 parts of acetate emulsion are mixed together to stir and produce penetration-assisting agent;
D, the preparation of product and burn till:
The base substrate that above-mentioned steps A is prepared, first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B systems Standby obtained billet surface acidulant, the spray amount of billet surface acidulant is 30~50g/ ㎡, then sprays above-mentioned steps C and be prepared into The penetration-assisting agent arrived, the spray amount of penetration-assisting agent is 40~60g/ ㎡, needs the ink-jet of different colours oozing flower further according to product design Ink carries out rational sorting, then carries out inkjet printing and oozes flower, enters back into roller kiln burning into maximum sintering temperature scope is 1200 DEG C~1220 DEG C, total firing time scope is 90~120 minutes, and when ensureing that 1100 DEG C~1150 DEG C of temperature province is burnt till Between account for the 20% of total firing time, then by edging, polishing, wax, get product.
The present invention passes through the described gentle preparation method system that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface Standby finished surface various colors, clear patterns are natural, bright in luster, third dimension is strong and ink-jet is oozed floral pattern penetration depth and reached 2mm;Finger touches gentle as beautiful, and product is translucent shape, and translucency is good, with flashlight or light in product back side illuminaton, Shadow and internal pattern can be clearly seen in front, through Micro-Structure Analysis, and lagoriolite (AlNaSi has been expired in product surface analysis2O6) Fine crystals.
Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface of the present invention:
By the optimization constituted to body recipe, introduced in body recipe containing P2O5Lithium porcelain stone raw material (such as river of composition The lithium porcelain stone of Xi great Feng porcelain stones company), the LiO in one side lithium porcelain stone2And P2O5It is strong flux, fusing point is low, can be with high temperature Accelerate the melting of Free quartz, increase the transparency of melt body, so as to ensure the light transmission of product;Another aspect LiO2、P2O5Also Help to penetrate into the color development that colored ink is oozed in the ink-jet in base substrate, make rich color, gorgeous.LiO is introduced simultaneously2It can also generate Tiny crystallization, P2O5It is Nucleating Agent, therefore LiO2、P2O5To lagoriolite AlNaSi2O4The generation of fine crystals also acts as rush Enter effect.
Nepheline syenite feedstock is introduced in body recipe, because the mineral of nepheline syenite are mainly feldspar and rosy clouds Stone (Na, K) AlSiO4Solid solution, it starts fusing at 1060 DEG C or so, can dissolve quartz at high temperature, therefore after its melting Viscosity is higher, therefore not only ensure that the light transmission of product, it is ensured that base substrate is unlikely to deform when high temperature is burnt till, and heat is steady Property and mechanical strength are all high.
Simultaneously body recipe composition optimization also assures that base substrate in high temperature with the nanosilicon in the Ludox of penetration-assisting agent Reaction, in Surface Creation lagoriolite (AlNaSi2O6) fine crystals, and this crystal is a kind of superfine impalpable structure Grain, spherical in shape, the particle diameter with very little, particle is present with the aggregation of different caking property, natural in such as jadeite (emerald) Sodium aluminum silicate mineral;These crystal can not only make light straight saturating and unobstructed, while also because its is spherical in shape, fine and closely woven degree Height, gentle exquisiteness after polished waxing, the emerald after such as processing, soft and moist, exquisiteness.
The optimization and spray of billet surface acidifying agent prescription composition are acidified the preferred of dosage, it is ensured that the degree of porosity of billet surface And the aperture of stomata, favourable ink-jet oozes the seepage velocity and depth of colored ink, it is ensured that the color of pattern and the plumpness of texture, So as to permeate not deep enough because of pattern, later stage polishing process cause to lack flower, pattern texture, the defect such as lack unity and coherence production It is raw.
Optimization and spray the preferred of penetration-assisting agent amount that penetration-assisting agent formula is constituted, on the one hand ensure that in penetration-assisting agent in Ludox Nano-silicon can generate lagoriolite (AlNaSi with base substrate in high temperature2O6) fine crystals, because nano-silicon particle diameter is small, distribution is equal Even, specific surface area is big, and high surface not only ensure that the color development of colored ink is oozed in ink-jet, also easily with the Na in base substrate2O、 Al2O3、SiO2Deng oxide reaction, in Surface Creation lagoriolite fine crystals;The acetate emulsion in penetration-assisting agent can be with simultaneously Ensure that ink-jet oozes colored ink rapid condensation into fine particle, be deposited to by formed by the effect of billet surface acidulant in stomata, It will not be spread to other places, so as to ensure the globality of pattern, definition and the depth of infiltration.
The optimization of firing process, is suitably incubated in 1100 DEG C~1150 DEG C temperature provinces, on the one hand ensure that base The transparency of body melt body in high temperature, it is ensured that the light transmission of product;On the other hand, it is incubated in this region, favorably In lagoriolite (AlNaSi2O6) fine crystals generation.
The surface of the present invention is gentle as colored polished brick in porcelain character is oozed in the beautiful ink-jet for having translucency and preparation method has the following advantages:
1st, due to optimize base substrate formula composition, billet surface acidulant formula composition, penetration-assisting agent formula composition, Adjustment and optimization of the spray amount of billet surface acidulant, the spray amount of penetration-assisting agent and firing process etc., so that the production of manufacture Product surface is gentle as beautiful, and product is translucent shape, and ink-jet oozes floral pattern clean mark, rich color, bright-coloured, and oozes floral pattern and ooze Saturating depth reaches 2mm, and translucency is good, and with flashlight or light in product back side illuminaton, shadow and product can be seen clearly that in front Pattern texture, color at internal pattern, and picture on surface and inside 2mm is basically identical, with natural penetrating jadeite jade Unique decorative effect as the rare Gem Grade stone material such as stone, Agate.Through Micro-Structure Analysis, alumina silicate has been expired in product surface analysis Sodium (AlNaSi2O6) fine crystals.
2nd, the product surface flatness, the modulus of rupture, rupture strength, wearability, thermal shock resistance, radioactivity reach GB/ A category alignment requests in T4100-2015 annex G, GB6566-2010.
3rd, the product oozes the production technology of colored polished bricks using existing ink-jet, it is easy to accomplish industrialized scale.
Brief description of the drawings:
Fig. 1 is the gentle technological process that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface for preparing the present invention Figure.
Embodiment:
The present invention is described in further detail with reference to embodiment.
Embodiment 1:
A kind of gentle preparation method that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface, it includes following step Suddenly:
A, prepare base substrate:
The chemical composition composition such as table 1 below of base substrate:
The chemical composition table (percentage by weight, %) of table 1, base substrate
Component SiO2 Al2O3 Fe2O3+TiO2 CaO+MgO K2O Na2O LiO2 P2O5 Loss on ignition
1# 68 22 0.4 0.2 4 2 0.2 0.2 3
2# 69 21 0.35 0.3 3 2.9 0.3 0.15 3
3# 70 20 0.3 0.4 2 3 0.2 0.1 4
4# 68.5 20.5 0.3 0.2 3.9 2.5 0.4 0.2 3.5
5# 68 21.3 0.4 0.3 2.4 4 0.3 0.1 3.2
Prepare base substrate:The potassium feldspar and albite of corresponding proportion and mixing for quartz are chosen by the base substrate chemical composition of table 1 Close sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage be 0.8%~ 1.2% auxiliary material, it into fineness is that 250 mesh sieves tail over as mass percent to add appropriate water in small, broken bits through ball milling 0.5%~0.7% and containing mass percent be 33%~35% moisture glaze slip, through except iron sieving spray drying be made containing quality Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2Pressure limit under be molded with automatic hydraulic press, Again base substrate is drying to obtain by throwing base, dry kiln;Additional auxiliary material therein include sodium tripolyphosphate, metasilicate pentahydrate sodium and Sodium carbonate;Lithium porcelain stone raw material therein, which is selected, contains P2O5The lithium porcelain stone of the lithium porcelain stone raw material, such as Jiangxi great Feng porcelain stones company of composition In, contain 1% or so P2O5
B, preparation billet surface acidulant:
The formula composition such as table 2 below of billet surface acidulant:
The formula composition table (parts by weight) of table 2, billet surface acidulant
Component Acetic acid Water
1# 20 80
2# 30 70
3# 40 60
Acetic acid is weighed by the formula composition of the billet surface acidulant of table 2 and water is mixed together to stir and produces billet surface Acidulant;
C, prepare penetration-assisting agent:
The formula composition such as table 3 below of penetration-assisting agent:
The formula composition table (parts by weight) of table 3, penetration-assisting agent
Component Ludox Acetate emulsion
1# 80 20
2# 60 40
3# 70 30
Ludox is weighed by the formula composition of the penetration-assisting agent of table 3 and acetate emulsion is mixed together to stir to produce to help and oozed Agent;
D, the preparation of product and burn till:
The base substrate that above-mentioned steps A is prepared, first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B systems Standby obtained billet surface acidulant, the spray amount of billet surface acidulant is 30~50g/ ㎡, then sprays above-mentioned steps C and be prepared into The penetration-assisting agent arrived, the spray amount of penetration-assisting agent is 40~60g/ ㎡, needs the ink-jet of different colours oozing flower further according to product design Ink carries out rational sorting, then carries out inkjet printing and oozes flower, enters back into roller kiln burning into maximum sintering temperature scope is 1200 DEG C~1220 DEG C, total firing time scope is 90~120 minutes, and when ensureing that 1100 DEG C~1150 DEG C of temperature province is burnt till Between account for the 20% of total firing time, then by edging, polishing, wax, get product.Colored ink is oozed in wherein described ink-jet As colored ink is oozed in Italy U.S. high (METCO), the ink-jet of Guangdong Dowstone Technologies Co., Ltd..
The present invention oozes the preparation method of colored polished brick in porcelain character by a kind of gentle ink-jet as jade has translucency in above-mentioned surface, The polished brick in porcelain character product pattern various colors, the clean mark that prepare are natural, bright in luster, third dimension is strong, from product side Portion can be seen that ink-jet is oozed floral pattern and penetrated into and 2mm reached inside brick body, and surface and internal pattern texture and color are basic Unanimously, beautiful texture is strong, the gentle exquisiteness of finger touch-surface, and product is translucent shape, and translucency is good, with flashlight or light in production Product back side illuminaton, shadow and internal pattern texture, color such as natural penetrating rare jade, agate can be clearly seen in front Unique decorative effect as Nao stones, high-grade elegant, your gas is full, after product surface is corroded with HF, then through Micro-Structure Analysis, production Full lagoriolite (the AlNaSi of product surface analysis2O6) fine crystals, and product flatness is good, intensity is high, abrasion resistance is high, pin-free, molten The defects such as hole.Product indices such as table 4 below after testing.
Table 4:Product quality inspection result (900 × 900mm of specification)
In summary, only presently preferred embodiments of the present invention, not makees any formal limitation to the present invention;It is all The those of ordinary skill of the industry can swimmingly be implemented the present invention as described above;But all it is familiar with this professional technology people Member without departing from the scope of the present invention, a little change for being made using disclosed above technology contents, repaiies Decorations and the equivalent variations developed, are the equivalent embodiment of the present invention;Meanwhile, all substantial technologicals according to the present invention are real to more than Apply any equivalent variations that example is made change, modification with develop, still fall within technical scheme protection domain it It is interior.

Claims (3)

1. colored polished brick in porcelain character is oozed in a kind of gentle ink-jet as jade has translucency in surface, it is characterised in that:
It includes:
Base substrate:Prepared by following weight percent composition:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%~ 0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3% ~4%, all components sum is 100%;Added weight percentage is 0.8%~1.2% auxiliary material;
Wherein:Described auxiliary material includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate;The base substrate 1200 DEG C~ Be translucent shape after 1220 DEG C of temperature lower calcinations;
Billet surface acidulant:Prepared by following parts by weight of component:
20~40 parts of acetic acid, 60~80 parts of water;
The spray amount of described billet surface acidulant is 30~50g/ ㎡;
Penetration-assisting agent:Prepared by following parts by weight component:
60~80 parts of Ludox, 20~40 parts of acetate emulsion;
Described penetration-assisting agent spray amount is 40~60g/ ㎡.
2. a kind of gentle preparation method that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface, it is characterised in that:
It comprises the following steps:
A, base substrate preparation:
The percentage by weight of the component of base substrate is:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%~ 0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3% ~4%, all components sum is 100%;
By the weight percent content of the component of above-mentioned base substrate, the mixing of the potassium feldspar and albite and quartz of corresponding proportion is chosen Sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage be 0.8%~ 1.2% auxiliary material, it into fineness is that 250 mesh sieves tail over as mass percent to add appropriate water in small, broken bits through ball milling 0.5%~0.7% and containing mass percent be 33%~35% moisture slurry, through except iron sieving spray drying be made containing quality Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2It is molded under pressure limit with automatic hydraulic press, then Base substrate is drying to obtain by throwing base, dry kiln;
Additional auxiliary material therein includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate;
Lithium porcelain stone raw material therein is containing P2O5The lithium porcelain stone raw material of composition;
B, billet surface acidulant preparation, are prepared by weight:
20~40 parts of acetic acid and 60~80 parts of water are mixed together to stir and produce billet surface acidulant;
C, penetration-assisting agent preparation, are prepared by weight:
60~80 parts of Ludox and 20~40 parts of acetate emulsion are mixed together to stir and produce penetration-assisting agent;
D, the preparation of product and burn till:
The base substrate that above-mentioned steps A is prepared, first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B and be prepared into The billet surface acidulant arrived, the spray amount of billet surface acidulant is 30~50g/ ㎡, then sprays what above-mentioned steps C was prepared Penetration-assisting agent, the spray amount of penetration-assisting agent is 40~60g/ ㎡, needs the ink-jet of different colours oozing colored ink further according to product design Carry out rational sorting, then carry out inkjet printing and ooze flower, enter back into roller kiln burning into, maximum sintering temperature scope be 1200 DEG C~ 1220 DEG C, total firing time scope is 90~120 minutes, and ensures that 1100 DEG C~1150 DEG C of temperature province firing time is accounted for The 20% of total firing time, then by edging, polishing, waxing, gets product.
3. a kind of gentle preparation side that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface according to claim 2 Method, it is characterised in that:
Assembled watch prepared by the preparation method of colored polished brick in porcelain character is oozed by the described gentle ink-jet as jade has translucency in surface Face color is abundant, clear patterns are natural, bright in luster, third dimension is strong and ink-jet oozes floral pattern penetration depth up to 2mm;Finger is touched Touch gentle as beautiful, product is translucent shape, translucency is good, can be clear in front with flashlight or light in product back side illuminaton Find out shadow and internal pattern, through Micro-Structure Analysis, lagoriolite (AlNaSi has been expired in product surface analysis2O6) fine crystals.
CN201710475109.4A 2017-06-21 2017-06-21 Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method Active CN107266023B (en)

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CN110483024A (en) * 2019-09-06 2019-11-22 清远市简一陶瓷有限公司 A kind of high-flatness ceramic tile blank and preparation method thereof
CN110963792A (en) * 2019-12-19 2020-04-07 广东宏陶陶瓷有限公司 Porcelain polished brick of 80-degree whiteness and color ratio mutton tallow and preparation method thereof

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