CN107266023A - Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface - Google Patents
Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface Download PDFInfo
- Publication number
- CN107266023A CN107266023A CN201710475109.4A CN201710475109A CN107266023A CN 107266023 A CN107266023 A CN 107266023A CN 201710475109 A CN201710475109 A CN 201710475109A CN 107266023 A CN107266023 A CN 107266023A
- Authority
- CN
- China
- Prior art keywords
- ink
- jet
- penetration
- base substrate
- oozed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 37
- 239000011449 brick Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000010977 jade Substances 0.000 title claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000007921 spray Substances 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000010304 firing Methods 0.000 claims abstract description 11
- 239000003086 colorant Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000004575 stone Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 20
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 13
- 229910052744 lithium Inorganic materials 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- 239000013078 crystal Substances 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052593 corundum Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052664 nepheline Inorganic materials 0.000 claims description 5
- 239000010434 nepheline Substances 0.000 claims description 5
- 239000010453 quartz Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 claims description 5
- 238000005211 surface analysis Methods 0.000 claims description 5
- 239000010435 syenite Substances 0.000 claims description 5
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 4
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 4
- 238000005498 polishing Methods 0.000 claims description 4
- 229910052656 albite Inorganic materials 0.000 claims description 3
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000007688 edging Methods 0.000 claims description 3
- 238000007641 inkjet printing Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000002932 luster Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 230000035515 penetration Effects 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 238000004018 waxing Methods 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005457 optimization Methods 0.000 abstract description 8
- 230000000149 penetrating effect Effects 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 5
- 230000008859 change Effects 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 35
- 239000000919 ceramic Substances 0.000 description 6
- 238000005034 decoration Methods 0.000 description 5
- 239000010437 gem Substances 0.000 description 4
- 229910001751 gemstone Inorganic materials 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 241000579895 Chlorostilbon Species 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000010976 emerald Substances 0.000 description 3
- 229910052640 jadeite Inorganic materials 0.000 description 3
- 239000005543 nano-size silicon particle Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052876 emerald Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 229910052604 silicate mineral Inorganic materials 0.000 description 2
- 230000036548 skin texture Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- PQLVXDKIJBQVDF-UHFFFAOYSA-N acetic acid;hydrate Chemical compound O.CC(O)=O PQLVXDKIJBQVDF-UHFFFAOYSA-N 0.000 description 1
- 239000002535 acidifier Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5024—Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
- C04B2235/3203—Lithium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The surface of the present invention is gentle to include base substrate as colored polished brick in porcelain character and preparation method are oozed in ink-jet that jade has translucency, billet surface acidulant and penetration-assisting agent, on the basis of great change is not made to the production technologies of existing porcelain seep curlicue polished bricks, emphasis is constituted to the formula of base substrate, the formula composition of billet surface acidulant, the formula composition of penetration-assisting agent, spray spray amount and the adjustment and optimization of kiln firing process of surface acidulant and penetration-assisting agent, so that the gentle such as jade of colored polished brick in porcelain character product surface is oozed in obtained ink-jet, various colors, it is bright-coloured, ink-jet, which is oozed floral pattern and penetrated into, reaches 2mm inside base substrate, and pattern texture clear and natural, beautiful texture is strong, product is translucent shape, translucency is good, overleaf irradiated with flashlight or light, shadow and interiors of products pattern can be clearly seen in front, unique decorative effect such as rare natural penetrating jade and Agate；The technology possesses stronger universality simultaneously, it is easy in industry promote.
Description
Technical field：
The present invention relates to the preparing technical field of porcelain seep curlicue polished bricks, more particularly, to a kind of surface is gentle as jade has
Colored polished brick in porcelain character and preparation method are oozed in the ink-jet of translucency.
Background technology：
The rare stone material such as jade, Agate is a kind of tcrude ore of bijouterie, and it has quality fine and smooth, soft and moist, logical
Thoroughly, the features such as rich color, after chiseling and carving meticulously, your gas is full.Because their permeabilities are good, have fine-textured skin, soft and moist, these
Raw ore stone material is used as wall by some high-grade places after sanding and polishing, the top grade decoration such as feature wall is interspersed, due to these
The stone material of high value gemstone level has special permeability, under the irradiation of its back side light, and its internal stone material skin texture can be from just
Face reveals out, and more seem splendid, high-grade elegance, and your gas is full, collection dicoration, appreciating and one, by numerous new
High official scholar's pursues, and holds at high price, and conventional ceramic Wall or floor tile is with the continuous innovation of decoration technique, its picture on surface,
Color, the effect of texture can reach the surface effect of the rare stone material such as jade, Agate, but the inside flesh of these stone materials
Reason and the current conventional ceramic Wall or floor tile of permeability are also unable to reach, if can be the inside skin texture and permeability of these rare stone materials
It is replicated on ceramic wall and floor bricks product, makes this increasingly rare, the rare Gem Grade stone material that somethings can only be found by accident, and not through seeking, by common wall
The paving of brick, along with interspersing for light, so that splendid, high-grade grace at home, more dignitary's gas will necessarily be in ceramics dress
Obvious technological innovation is produced in decorations technology, the new development of ceramic decoration technology is led, with considerable economic benefit.
The content of the invention：
It is an object of the invention to overcome disadvantages mentioned above gentle as colored porcelain is oozed in the beautiful ink-jet for having translucency there is provided a kind of surface
Matter polished bricks and preparation method, on the basis of great change is not made to existing porcelain seep curlicue polished bricks production technology, pass through
Being formulated for base substrate is constituted, the formula composition of billet surface acidulant, the formula of penetration-assisting agent constitute, spray billet surface acidulant
Spray amount, the spray amount for spraying penetration-assisting agent, the adjustment and optimization of kiln firing process, so that obtained ink-jet, which is oozed, spends ceramic polished
Brick product surface is gentle as floral pattern clear and natural is oozed in jade, various colors, ink-jet and pattern penetrates into and 2mm is reached inside base substrate, production
Be translucent shape, translucency of product is good, and with flashlight or light in product back side illuminaton, shadow and inside can be clearly seen in front
Pattern, while penetrating into, the color of interiors of products pattern, texture and surface are basically identical, and high-visible, third dimension is strong, with bird with red feathers
Unique decorative effect as the rare penetrating Gem Grade stone material such as emerald stone, Agate, and product surface quality is good, resistant is strong, hard
The defects such as height, strong, the pin-free, fusion hole of wearability are spent, through Micro-Structure Analysis, product surface analysis has been expired as in natural jadeite jade
Sodium aluminum silicate mineral as lagoriolite (AlNaSi2O6) fine crystals.The technology possesses stronger universality simultaneously, easily
Promoted in industry.
In order to solve the above technical problems, the present invention is achieved through the following technical solutions：
Colored polished brick in porcelain character is oozed in the gentle ink-jet as jade has translucency in surface of the present invention, and it includes：
Base substrate：Prepared by following weight percent composition：
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%
~0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition
3%~4%, all components sum is 100%；Added weight percentage is 0.8%~1.2% auxiliary material；
Wherein：Described auxiliary material includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；The base substrate is 1200
DEG C~1220 DEG C of temperature lower calcinations after be translucent shape；
Billet surface acidulant：Prepared by following parts by weight of component：
20~40 parts of acetic acid, 60~80 parts of water；
The spray amount of described billet surface acidulant is 30~50g/ ㎡；
Penetration-assisting agent：Prepared by following parts by weight component：
60~80 parts of Ludox, 20~40 parts of acetate emulsion；
Described penetration-assisting agent spray amount is 40~60g/ ㎡.
The preparation method of colored polished brick in porcelain character is oozed the invention further relates to a kind of gentle ink-jet as jade has translucency in surface, its
Comprise the following steps：
A, base substrate preparation：
The percentage by weight of the component of base substrate is：
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%
~0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition
3%~4%, all components sum is 100%；
By the weight percent content of the component of above-mentioned base substrate, the potassium feldspar and albite and quartz of corresponding proportion are chosen
Mixed sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage are 0.8%
~1.2% auxiliary material, it into fineness is that 250 mesh sieves tail over as mass percent to add appropriate water in small, broken bits through ball milling
0.5%~0.7% and containing mass percent be 33%~35% moisture slurry, through except iron sieving spray drying be made containing quality
Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2It is molded under pressure limit with automatic hydraulic press, then
Base substrate is drying to obtain by throwing base, dry kiln；
Additional auxiliary material therein includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；
Lithium porcelain stone raw material therein is containing P2O5The lithium porcelain stone raw material of composition；
B, billet surface acidulant preparation, are prepared by weight：
20~40 parts of acetic acid and 60~80 parts of water are mixed together to stir and produce billet surface acidulant；
C, penetration-assisting agent preparation, are prepared by weight：
60~80 parts of Ludox and 20~40 parts of acetate emulsion are mixed together to stir and produce penetration-assisting agent；
D, the preparation of product and burn till：
The base substrate that above-mentioned steps A is prepared, first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B systems
Standby obtained billet surface acidulant, the spray amount of billet surface acidulant is 30~50g/ ㎡, then sprays above-mentioned steps C and be prepared into
The penetration-assisting agent arrived, the spray amount of penetration-assisting agent is 40~60g/ ㎡, needs the ink-jet of different colours oozing flower further according to product design
Ink carries out rational sorting, then carries out inkjet printing and oozes flower, enters back into roller kiln burning into maximum sintering temperature scope is 1200
DEG C~1220 DEG C, total firing time scope is 90~120 minutes, and when ensureing that 1100 DEG C~1150 DEG C of temperature province is burnt till
Between account for the 20% of total firing time, then by edging, polishing, wax, get product.
The present invention passes through the described gentle preparation method system that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface
Standby finished surface various colors, clear patterns are natural, bright in luster, third dimension is strong and ink-jet is oozed floral pattern penetration depth and reached
2mm；Finger touches gentle as beautiful, and product is translucent shape, and translucency is good, with flashlight or light in product back side illuminaton,
Shadow and internal pattern can be clearly seen in front, through Micro-Structure Analysis, and lagoriolite (AlNaSi has been expired in product surface analysis2O6)
Fine crystals.
Colored polished brick in porcelain character and preparation method are oozed in the gentle ink-jet as jade has translucency in surface of the present invention：
By the optimization constituted to body recipe, introduced in body recipe containing P2O5Lithium porcelain stone raw material (such as river of composition
The lithium porcelain stone of Xi great Feng porcelain stones company), the LiO in one side lithium porcelain stone2And P2O5It is strong flux, fusing point is low, can be with high temperature
Accelerate the melting of Free quartz, increase the transparency of melt body, so as to ensure the light transmission of product；Another aspect LiO2、P2O5Also
Help to penetrate into the color development that colored ink is oozed in the ink-jet in base substrate, make rich color, gorgeous.LiO is introduced simultaneously2It can also generate
Tiny crystallization, P2O5It is Nucleating Agent, therefore LiO2、P2O5To lagoriolite AlNaSi2O4The generation of fine crystals also acts as rush
Enter effect.
Nepheline syenite feedstock is introduced in body recipe, because the mineral of nepheline syenite are mainly feldspar and rosy clouds
Stone (Na, K) AlSiO4Solid solution, it starts fusing at 1060 DEG C or so, can dissolve quartz at high temperature, therefore after its melting
Viscosity is higher, therefore not only ensure that the light transmission of product, it is ensured that base substrate is unlikely to deform when high temperature is burnt till, and heat is steady
Property and mechanical strength are all high.
Simultaneously body recipe composition optimization also assures that base substrate in high temperature with the nanosilicon in the Ludox of penetration-assisting agent
Reaction, in Surface Creation lagoriolite (AlNaSi2O6) fine crystals, and this crystal is a kind of superfine impalpable structure
Grain, spherical in shape, the particle diameter with very little, particle is present with the aggregation of different caking property, natural in such as jadeite (emerald)
Sodium aluminum silicate mineral；These crystal can not only make light straight saturating and unobstructed, while also because its is spherical in shape, fine and closely woven degree
Height, gentle exquisiteness after polished waxing, the emerald after such as processing, soft and moist, exquisiteness.
The optimization and spray of billet surface acidifying agent prescription composition are acidified the preferred of dosage, it is ensured that the degree of porosity of billet surface
And the aperture of stomata, favourable ink-jet oozes the seepage velocity and depth of colored ink, it is ensured that the color of pattern and the plumpness of texture,
So as to permeate not deep enough because of pattern, later stage polishing process cause to lack flower, pattern texture, the defect such as lack unity and coherence production
It is raw.
Optimization and spray the preferred of penetration-assisting agent amount that penetration-assisting agent formula is constituted, on the one hand ensure that in penetration-assisting agent in Ludox
Nano-silicon can generate lagoriolite (AlNaSi with base substrate in high temperature2O6) fine crystals, because nano-silicon particle diameter is small, distribution is equal
Even, specific surface area is big, and high surface not only ensure that the color development of colored ink is oozed in ink-jet, also easily with the Na in base substrate2O、
Al2O3、SiO2Deng oxide reaction, in Surface Creation lagoriolite fine crystals；The acetate emulsion in penetration-assisting agent can be with simultaneously
Ensure that ink-jet oozes colored ink rapid condensation into fine particle, be deposited to by formed by the effect of billet surface acidulant in stomata,
It will not be spread to other places, so as to ensure the globality of pattern, definition and the depth of infiltration.
The optimization of firing process, is suitably incubated in 1100 DEG C~1150 DEG C temperature provinces, on the one hand ensure that base
The transparency of body melt body in high temperature, it is ensured that the light transmission of product；On the other hand, it is incubated in this region, favorably
In lagoriolite (AlNaSi2O6) fine crystals generation.
The surface of the present invention is gentle as colored polished brick in porcelain character is oozed in the beautiful ink-jet for having translucency and preparation method has the following advantages：
1st, due to optimize base substrate formula composition, billet surface acidulant formula composition, penetration-assisting agent formula composition,
Adjustment and optimization of the spray amount of billet surface acidulant, the spray amount of penetration-assisting agent and firing process etc., so that the production of manufacture
Product surface is gentle as beautiful, and product is translucent shape, and ink-jet oozes floral pattern clean mark, rich color, bright-coloured, and oozes floral pattern and ooze
Saturating depth reaches 2mm, and translucency is good, and with flashlight or light in product back side illuminaton, shadow and product can be seen clearly that in front
Pattern texture, color at internal pattern, and picture on surface and inside 2mm is basically identical, with natural penetrating jadeite jade
Unique decorative effect as the rare Gem Grade stone material such as stone, Agate.Through Micro-Structure Analysis, alumina silicate has been expired in product surface analysis
Sodium (AlNaSi2O6) fine crystals.
2nd, the product surface flatness, the modulus of rupture, rupture strength, wearability, thermal shock resistance, radioactivity reach GB/
A category alignment requests in T4100-2015 annex G, GB6566-2010.
3rd, the product oozes the production technology of colored polished bricks using existing ink-jet, it is easy to accomplish industrialized scale.
Brief description of the drawings：
Fig. 1 is the gentle technological process that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface for preparing the present invention
Figure.
Embodiment：
The present invention is described in further detail with reference to embodiment.
Embodiment 1：
A kind of gentle preparation method that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface, it includes following step
Suddenly：
A, prepare base substrate：
The chemical composition composition such as table 1 below of base substrate：
The chemical composition table (percentage by weight, %) of table 1, base substrate
| Component | SiO2 | Al2O3 | Fe2O3+TiO2 | CaO+MgO | K2O | Na2O | LiO2 | P2O5 | Loss on ignition |
| 1# | 68 | 22 | 0.4 | 0.2 | 4 | 2 | 0.2 | 0.2 | 3 |
| 2# | 69 | 21 | 0.35 | 0.3 | 3 | 2.9 | 0.3 | 0.15 | 3 |
| 3# | 70 | 20 | 0.3 | 0.4 | 2 | 3 | 0.2 | 0.1 | 4 |
| 4# | 68.5 | 20.5 | 0.3 | 0.2 | 3.9 | 2.5 | 0.4 | 0.2 | 3.5 |
| 5# | 68 | 21.3 | 0.4 | 0.3 | 2.4 | 4 | 0.3 | 0.1 | 3.2 |
Prepare base substrate：The potassium feldspar and albite of corresponding proportion and mixing for quartz are chosen by the base substrate chemical composition of table 1
Close sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage be 0.8%~
1.2% auxiliary material, it into fineness is that 250 mesh sieves tail over as mass percent to add appropriate water in small, broken bits through ball milling
0.5%~0.7% and containing mass percent be 33%~35% moisture glaze slip, through except iron sieving spray drying be made containing quality
Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2Pressure limit under be molded with automatic hydraulic press,
Again base substrate is drying to obtain by throwing base, dry kiln；Additional auxiliary material therein include sodium tripolyphosphate, metasilicate pentahydrate sodium and
Sodium carbonate；Lithium porcelain stone raw material therein, which is selected, contains P2O5The lithium porcelain stone of the lithium porcelain stone raw material, such as Jiangxi great Feng porcelain stones company of composition
In, contain 1% or so P2O5；
B, preparation billet surface acidulant：
The formula composition such as table 2 below of billet surface acidulant：
The formula composition table (parts by weight) of table 2, billet surface acidulant
| Component | Acetic acid | Water |
| 1# | 20 | 80 |
| 2# | 30 | 70 |
| 3# | 40 | 60 |
Acetic acid is weighed by the formula composition of the billet surface acidulant of table 2 and water is mixed together to stir and produces billet surface
Acidulant；
C, prepare penetration-assisting agent：
The formula composition such as table 3 below of penetration-assisting agent：
The formula composition table (parts by weight) of table 3, penetration-assisting agent
| Component | Ludox | Acetate emulsion |
| 1# | 80 | 20 |
| 2# | 60 | 40 |
| 3# | 70 | 30 |
Ludox is weighed by the formula composition of the penetration-assisting agent of table 3 and acetate emulsion is mixed together to stir to produce to help and oozed
Agent；
D, the preparation of product and burn till：
The base substrate that above-mentioned steps A is prepared, first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B systems
Standby obtained billet surface acidulant, the spray amount of billet surface acidulant is 30~50g/ ㎡, then sprays above-mentioned steps C and be prepared into
The penetration-assisting agent arrived, the spray amount of penetration-assisting agent is 40~60g/ ㎡, needs the ink-jet of different colours oozing flower further according to product design
Ink carries out rational sorting, then carries out inkjet printing and oozes flower, enters back into roller kiln burning into maximum sintering temperature scope is 1200
DEG C~1220 DEG C, total firing time scope is 90~120 minutes, and when ensureing that 1100 DEG C~1150 DEG C of temperature province is burnt till
Between account for the 20% of total firing time, then by edging, polishing, wax, get product.Colored ink is oozed in wherein described ink-jet
As colored ink is oozed in Italy U.S. high (METCO), the ink-jet of Guangdong Dowstone Technologies Co., Ltd..
The present invention oozes the preparation method of colored polished brick in porcelain character by a kind of gentle ink-jet as jade has translucency in above-mentioned surface,
The polished brick in porcelain character product pattern various colors, the clean mark that prepare are natural, bright in luster, third dimension is strong, from product side
Portion can be seen that ink-jet is oozed floral pattern and penetrated into and 2mm reached inside brick body, and surface and internal pattern texture and color are basic
Unanimously, beautiful texture is strong, the gentle exquisiteness of finger touch-surface, and product is translucent shape, and translucency is good, with flashlight or light in production
Product back side illuminaton, shadow and internal pattern texture, color such as natural penetrating rare jade, agate can be clearly seen in front
Unique decorative effect as Nao stones, high-grade elegant, your gas is full, after product surface is corroded with HF, then through Micro-Structure Analysis, production
Full lagoriolite (the AlNaSi of product surface analysis2O6) fine crystals, and product flatness is good, intensity is high, abrasion resistance is high, pin-free, molten
The defects such as hole.Product indices such as table 4 below after testing.
Table 4：Product quality inspection result (900 × 900mm of specification)
In summary, only presently preferred embodiments of the present invention, not makees any formal limitation to the present invention；It is all
The those of ordinary skill of the industry can swimmingly be implemented the present invention as described above；But all it is familiar with this professional technology people
Member without departing from the scope of the present invention, a little change for being made using disclosed above technology contents, repaiies
Decorations and the equivalent variations developed, are the equivalent embodiment of the present invention；Meanwhile, all substantial technologicals according to the present invention are real to more than
Apply any equivalent variations that example is made change, modification with develop, still fall within technical scheme protection domain it
It is interior.
Claims (3)
1. colored polished brick in porcelain character is oozed in a kind of gentle ink-jet as jade has translucency in surface, it is characterised in that：
It includes：
Base substrate：Prepared by following weight percent composition：
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%~
0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3%
~4%, all components sum is 100%；Added weight percentage is 0.8%~1.2% auxiliary material；
Wherein：Described auxiliary material includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；The base substrate 1200 DEG C~
Be translucent shape after 1220 DEG C of temperature lower calcinations；
Billet surface acidulant：Prepared by following parts by weight of component：
20~40 parts of acetic acid, 60~80 parts of water；
The spray amount of described billet surface acidulant is 30~50g/ ㎡；
Penetration-assisting agent：Prepared by following parts by weight component：
60~80 parts of Ludox, 20~40 parts of acetate emulsion；
Described penetration-assisting agent spray amount is 40~60g/ ㎡.
2. a kind of gentle preparation method that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface, it is characterised in that：
It comprises the following steps：
A, base substrate preparation：
The percentage by weight of the component of base substrate is：
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%~
0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3%
~4%, all components sum is 100%；
By the weight percent content of the component of above-mentioned base substrate, the mixing of the potassium feldspar and albite and quartz of corresponding proportion is chosen
Sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage be 0.8%~
1.2% auxiliary material, it into fineness is that 250 mesh sieves tail over as mass percent to add appropriate water in small, broken bits through ball milling
0.5%~0.7% and containing mass percent be 33%~35% moisture slurry, through except iron sieving spray drying be made containing quality
Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2It is molded under pressure limit with automatic hydraulic press, then
Base substrate is drying to obtain by throwing base, dry kiln；
Additional auxiliary material therein includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；
Lithium porcelain stone raw material therein is containing P2O5The lithium porcelain stone raw material of composition；
B, billet surface acidulant preparation, are prepared by weight：
20~40 parts of acetic acid and 60~80 parts of water are mixed together to stir and produce billet surface acidulant；
C, penetration-assisting agent preparation, are prepared by weight：
60~80 parts of Ludox and 20~40 parts of acetate emulsion are mixed together to stir and produce penetration-assisting agent；
D, the preparation of product and burn till：
The base substrate that above-mentioned steps A is prepared, first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B and be prepared into
The billet surface acidulant arrived, the spray amount of billet surface acidulant is 30~50g/ ㎡, then sprays what above-mentioned steps C was prepared
Penetration-assisting agent, the spray amount of penetration-assisting agent is 40~60g/ ㎡, needs the ink-jet of different colours oozing colored ink further according to product design
Carry out rational sorting, then carry out inkjet printing and ooze flower, enter back into roller kiln burning into, maximum sintering temperature scope be 1200 DEG C~
1220 DEG C, total firing time scope is 90~120 minutes, and ensures that 1100 DEG C~1150 DEG C of temperature province firing time is accounted for
The 20% of total firing time, then by edging, polishing, waxing, gets product.
3. a kind of gentle preparation side that colored polished brick in porcelain character is oozed such as the beautiful ink-jet for having translucency in surface according to claim 2
Method, it is characterised in that：
Assembled watch prepared by the preparation method of colored polished brick in porcelain character is oozed by the described gentle ink-jet as jade has translucency in surface
Face color is abundant, clear patterns are natural, bright in luster, third dimension is strong and ink-jet oozes floral pattern penetration depth up to 2mm；Finger is touched
Touch gentle as beautiful, product is translucent shape, translucency is good, can be clear in front with flashlight or light in product back side illuminaton
Find out shadow and internal pattern, through Micro-Structure Analysis, lagoriolite (AlNaSi has been expired in product surface analysis2O6) fine crystals.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710475109.4A CN107266023B (en) | 2017-06-21 | 2017-06-21 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
| PCT/CN2017/000743 WO2018232547A1 (en) | 2017-06-21 | 2017-12-20 | Inkjet color-penetrated polished porcelain tile with surface being gentle as jade and having light transmittance and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710475109.4A CN107266023B (en) | 2017-06-21 | 2017-06-21 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107266023A true CN107266023A (en) | 2017-10-20 |
| CN107266023B CN107266023B (en) | 2019-10-29 |
Family
ID=60068110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710475109.4A Active CN107266023B (en) | 2017-06-21 | 2017-06-21 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN107266023B (en) |
| WO (1) | WO2018232547A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108503330A (en) * | 2018-04-08 | 2018-09-07 | 清远市简陶瓷有限公司 | Light transmission Dali stone ceramic tile |
| CN108975891A (en) * | 2018-08-27 | 2018-12-11 | 佛山石湾鹰牌陶瓷有限公司 | Ink-jet infiltration spends beautiful matter polished bricks and preparation method thereof |
| CN108975892A (en) * | 2018-08-27 | 2018-12-11 | 佛山石湾鹰牌陶瓷有限公司 | The method for spending beautiful matter polished bricks is seeped in preparation ink-jet and ink-jet infiltration spends beautiful matter polished bricks |
| CN109053171A (en) * | 2018-08-27 | 2018-12-21 | 佛山石湾鹰牌陶瓷有限公司 | Adobe and ink-jet infiltration spend beautiful matter polished bricks |
| WO2018232547A1 (en) * | 2017-06-21 | 2018-12-27 | 广东宏宇新型材料有限公司 | Inkjet color-penetrated polished porcelain tile with surface being gentle as jade and having light transmittance and preparation method therefor |
| CN110483024A (en) * | 2019-09-06 | 2019-11-22 | 清远市简一陶瓷有限公司 | A kind of high-flatness ceramic tile blank and preparation method thereof |
| CN110963792A (en) * | 2019-12-19 | 2020-04-07 | 广东宏陶陶瓷有限公司 | Porcelain polished brick of 80-degree whiteness and color ratio mutton tallow and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030039808A1 (en) * | 1998-12-28 | 2003-02-27 | Hirofumi Ichinose | Recording medium and method of manufacturing the same |
| US20130137816A1 (en) * | 2010-08-31 | 2013-05-30 | E I Du Pont De Nemours And Company | Ink-jet ink comprising cross-linked pigment dispersion and a polymeric binder |
| CN105330342A (en) * | 2015-10-15 | 2016-02-17 | 蒙娜丽莎集团股份有限公司 | One-time sintered super-flat ink-jet penetrating porcelain tiles with three-dimensional decorative effects, and manufacturing method thereof |
| CN105367131A (en) * | 2015-12-07 | 2016-03-02 | 蒙娜丽莎集团股份有限公司 | Ink-jet penetrated polished semitransparent ceramic sheet, and preparation method thereof |
| CN106007662A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Ink jet pattern seeping marble tile |
| CN106007806A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Preparation method of ink jet pattern seeping marble tile |
| CN106280710A (en) * | 2016-08-23 | 2017-01-04 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink jet oozes colored ink permeation-promoter and application process thereof |
| CN106278387A (en) * | 2016-08-15 | 2017-01-04 | 广东宏宇新型材料有限公司 | There is glazed tile of gold decorative effect and preparation method thereof on surface |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104860720B (en) * | 2015-05-07 | 2017-01-04 | 广东宏陶陶瓷有限公司 | Ceramic decoration high temperature scarlet color ink-jet ink and preparation method and applications |
| CN105924134B (en) * | 2016-04-25 | 2018-05-25 | 广东宏宇新型材料有限公司 | There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface |
| CN107266023B (en) * | 2017-06-21 | 2019-10-29 | 广东宏宇新型材料有限公司 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
-
2017
- 2017-06-21 CN CN201710475109.4A patent/CN107266023B/en active Active
- 2017-12-20 WO PCT/CN2017/000743 patent/WO2018232547A1/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030039808A1 (en) * | 1998-12-28 | 2003-02-27 | Hirofumi Ichinose | Recording medium and method of manufacturing the same |
| US20130137816A1 (en) * | 2010-08-31 | 2013-05-30 | E I Du Pont De Nemours And Company | Ink-jet ink comprising cross-linked pigment dispersion and a polymeric binder |
| CN105330342A (en) * | 2015-10-15 | 2016-02-17 | 蒙娜丽莎集团股份有限公司 | One-time sintered super-flat ink-jet penetrating porcelain tiles with three-dimensional decorative effects, and manufacturing method thereof |
| CN105367131A (en) * | 2015-12-07 | 2016-03-02 | 蒙娜丽莎集团股份有限公司 | Ink-jet penetrated polished semitransparent ceramic sheet, and preparation method thereof |
| CN106007662A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Ink jet pattern seeping marble tile |
| CN106007806A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Preparation method of ink jet pattern seeping marble tile |
| CN106278387A (en) * | 2016-08-15 | 2017-01-04 | 广东宏宇新型材料有限公司 | There is glazed tile of gold decorative effect and preparation method thereof on surface |
| CN106280710A (en) * | 2016-08-23 | 2017-01-04 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink jet oozes colored ink permeation-promoter and application process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张翼: "陶瓷渗花墨水的性能及研究状况", 《佛山陶瓷》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018232547A1 (en) * | 2017-06-21 | 2018-12-27 | 广东宏宇新型材料有限公司 | Inkjet color-penetrated polished porcelain tile with surface being gentle as jade and having light transmittance and preparation method therefor |
| CN108503330A (en) * | 2018-04-08 | 2018-09-07 | 清远市简陶瓷有限公司 | Light transmission Dali stone ceramic tile |
| CN108503330B (en) * | 2018-04-08 | 2020-10-27 | 清远市简一陶瓷有限公司 | Light-transmitting marble tile |
| CN108975891A (en) * | 2018-08-27 | 2018-12-11 | 佛山石湾鹰牌陶瓷有限公司 | Ink-jet infiltration spends beautiful matter polished bricks and preparation method thereof |
| CN108975892A (en) * | 2018-08-27 | 2018-12-11 | 佛山石湾鹰牌陶瓷有限公司 | The method for spending beautiful matter polished bricks is seeped in preparation ink-jet and ink-jet infiltration spends beautiful matter polished bricks |
| CN109053171A (en) * | 2018-08-27 | 2018-12-21 | 佛山石湾鹰牌陶瓷有限公司 | Adobe and ink-jet infiltration spend beautiful matter polished bricks |
| WO2020042356A1 (en) * | 2018-08-27 | 2020-03-05 | 佛山石湾鹰牌陶瓷有限公司 | Method for preparing jade-like polished tile having tile-penetrating pattern applied by inkjet printing, and tile prepared thereby |
| CN108975891B (en) * | 2018-08-27 | 2021-11-05 | 佛山石湾鹰牌陶瓷有限公司 | Ink-jet flower-penetrating jade polished brick and preparation method thereof |
| CN110483024A (en) * | 2019-09-06 | 2019-11-22 | 清远市简一陶瓷有限公司 | A kind of high-flatness ceramic tile blank and preparation method thereof |
| CN110483024B (en) * | 2019-09-06 | 2022-06-17 | 清远市简一陶瓷有限公司 | High-flatness ceramic tile blank and preparation method thereof |
| CN110963792A (en) * | 2019-12-19 | 2020-04-07 | 广东宏陶陶瓷有限公司 | Porcelain polished brick of 80-degree whiteness and color ratio mutton tallow and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107266023B (en) | 2019-10-29 |
| WO2018232547A1 (en) | 2018-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107266023B (en) | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method | |
| CN104529553B (en) | The surface of manufacturing with ceramic refuse is as glazed tile and the preparation of broken brill sand flicker starlight | |
| CN104140297B (en) | The glaze of embossment phantom ornamental brick and preparation | |
| CN105948714B (en) | A kind of preparation method of imitating natural marble glazed tile | |
| CN103435369B (en) | Method for manufacturing wear-resistant antiskid dry-particle ceramic tile | |
| CN105272378B (en) | A kind of preparation method and product of the parian thickness glazed brick of the sagging texture of combination | |
| CN106467394B (en) | The fine stoneware tile and preparation method thereof manufactured with solid ceramic regenerant | |
| CN105924134A (en) | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof | |
| CN105000866B (en) | With surface glazed tile having mirror effect of sludge silt manufacture and preparation method thereof | |
| CN101407435B (en) | Method for preparing ceramic underglaze color mud base and ceramic underglaze color mud decoration | |
| CN105924229A (en) | Glaze for thousand-bead multi-color glazed tile and thousand-bead multi-color glazed tile, and preparation methods thereof | |
| CN101659567A (en) | Furnace transmutation decoration glazed brick and production technology | |
| CN105198217B (en) | It is a kind of to be used for throwing vitreous brick production entirely, beneficial to the ground-coat enamel of ceramic ink color development | |
| CN105000916A (en) | Glazed tile manufactured from ceramic wastes and having surface with stone-like luster and preparation method therefor | |
| CN102731169A (en) | Fully glazed ceramic chip and preparation method thereof | |
| CN102653476A (en) | Three-dimensional hierarchical glazed ceramic brick and method for preparing same | |
| CN105293912B (en) | A kind of glaze brick producing process with matte surface | |
| CN104311154B (en) | A kind of underglaze decoration ceramic tile and its manufacturing method | |
| CN105218170B (en) | A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof | |
| KR101021620B1 (en) | Glaze compositon for heat resistant ceramic ware and ceramic ware manufactured thereof | |
| CN102503583A (en) | Preparation method of bright red glaze bone china | |
| CN104891808A (en) | Brown crystal glaze composition | |
| CN108484114A (en) | A kind of glaze Imitation Rock Porcelain Tiles of high additive polished waste material and preparation method thereof | |
| US20080076655A1 (en) | Method of manufacturing stone-like articles | |
| CN103159497A (en) | Jinyongdong stone polished tile and production method for same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |