CN108503330A - Light transmission Dali stone ceramic tile - Google Patents

Light transmission Dali stone ceramic tile Download PDF

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Publication number
CN108503330A
CN108503330A CN201810307750.1A CN201810307750A CN108503330A CN 108503330 A CN108503330 A CN 108503330A CN 201810307750 A CN201810307750 A CN 201810307750A CN 108503330 A CN108503330 A CN 108503330A
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China
Prior art keywords
parts
semi
light transmission
ceramic tile
colorant
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CN201810307750.1A
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CN108503330B (en
Inventor
李炯志
黄海发
蒋小英
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FOSHAN JIANYI CERAMICS Co Ltd
Qingyuan City Letter One Ceramic Co Ltd
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FOSHAN JIANYI CERAMICS Co Ltd
Qingyuan City Letter One Ceramic Co Ltd
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Publication of CN108503330A publication Critical patent/CN108503330A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/144Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of marble or other natural stone
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201Alkali metal oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3436Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3454Calcium silicates, e.g. wollastonite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite

Abstract

The invention discloses light transmission Dali stone ceramic tiles.The light transmission Dali stone ceramic tile includes transparent area, semi-opaque region and opaque area;Transparent area includes following component:20 50 parts of nepheline, 10 30 parts of sodium mountain flour, 14 parts of wollastonite, 4 10 parts of diopside, 10 30 parts of ball clay, 5 20 parts of pyrophillite, 3 15 parts of bentonite;Semi-opaque region includes following component:15 30 parts of nepheline, 5 20 parts of sodium mountain flour, 14 parts of wollastonite, 25 parts of diopside, 10 30 parts of ball clay, 5 20 parts of pyrophillite, 15 parts of bentonite and colorant.Light transmission Dali of the present invention stone ceramic tile has light transmission, semi-transparent and lighttight natural beauty.

Description

Light transmission Dali stone ceramic tile
Technical field
The present invention relates to technical field of tile production, and in particular to light transmission Dali stone ceramic tile.
Background technology
Light transmission Dali stone ceramic tile is the ceramic tile of imitating natural marble light transmission, part natural marble due to ingredient not Together, formation mechenism is different, has natural translucency and impermeability, has unique product characteristic in the design application of house. In the stone material exhibition of Xiamen, there are many stone materials such as, transparent jade, in jewel displaying, by cutting splicing, at stone material back Light makes surface show honorable mottled stereoscopic effect and stone texture and enhances each other's beauty.This entire body light transmission technology is in wall In have fabulous application prospect, there are no similar research and development projects in the stone ceramic tile of Dali in the past.
Also there are many ceramic producers developing light transmission Dali stone ceramic tile in recent years, but they develop to be full wafer ceramic tile be all Light transmission, single light transmission material cannot give expression to that lithotome partial light permeability and part be opaque very well and semi-transparent light transition it is pure Natural beauty.
Invention content
Based on this, the present invention has light transmission, the light transmission of semi-transparent and lighttight natural beauty big it is necessary to provide a kind of Reason stone ceramic tile.
In order to achieve the object of the present invention, the present invention uses following technical scheme:
A kind of light transmission Dali stone ceramic tile comprising transparent area, semi-opaque region and opaque area;
The transparent area includes the component of following parts by weight:20-50 parts of nepheline, 10-30 parts of sodium mountain flour, 1-4 parts of wollastonite, 4-10 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophillite, 3-15 parts of bentonite;
The semi-opaque region includes the component of following parts by weight:15-30 parts of nepheline, 5-20 parts of sodium mountain flour, wollastonite 1-4 Part, 2-5 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophillite, 1-5 parts of bentonite and colorant.
Above-mentioned light transmission Dali stone ceramic tile, by transparent area, semi-opaque region and opaque district's groups at each region corresponds to different Blank, the ceramic tile of firing has light transmission, semi-transparent and lighttight effect, and with beautiful matter light transmission entire body effect, Neng Gougeng The natural beauty of lithotome is embodied well.
In some of embodiments, the colorant is green body colorant, and the colorant is blue colorant, green pigment, coffee One or more of color colorant, black pigment.
In some of embodiments, the colorant includes blue 0-15 parts of colorant, 0-10 parts of green pigment.
In some of embodiments, the colorant includes coffee-like 0-10 parts of colorant.
In some of embodiments, the colorant includes 0-15 parts of yellow colorant, 0-15 parts of black pigment.
In some of embodiments, the quantity of the transparent area, semi-opaque region and opaque area is one, the light transmission Area, semi-opaque region and opaque area are docked successively;The transparent area includes the component of following parts by weight:30 parts of nepheline, sodium mountain flour 20 parts, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, 10 parts of bentonite;The semi-opaque region includes as follows The component of parts by weight:20 parts of nepheline, 15 parts of sodium mountain flour, 3 parts of wollastonite, 3 parts of diopside, 15 parts of ball clay, 15 parts of pyrophillite, swelling 3 parts of soil and blue 6 parts of colorant, 6 parts of green pigment.
In some of embodiments, the quantity of the transparent area is two, including the first transparent area and the second transparent area, institute The quantity for stating semi-opaque region and opaque area is one, and first transparent area docks the semi-opaque region, and described second thoroughly Dock the semi-opaque region and opaque area in light area;First transparent area includes the component of following parts by weight:30 parts of nepheline, sodium 20 parts of mountain flour, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, 10 parts of bentonite;The second transparent area packet Include the component of following parts by weight:20 parts of nepheline, 15 parts of sodium mountain flour, 2 parts of wollastonite, 5 parts of diopside, 20 parts of ball clay, pyrophillite 15 Part, 8 parts of bentonite;The semi-opaque region includes the component of following parts by weight:15 parts of nepheline, 5 parts of sodium mountain flour, 3 parts of wollastonite, thoroughly 5 parts of pyroxene, 10 parts of ball clay, 10 parts of pyrophillite, 3 parts of bentonite and blue 5 parts of colorant, 5 parts of green pigment and blue 7 parts of colorant, 5 parts of green pigment.
In some of embodiments, the semi-opaque region further includes the component of following parts by weight:Glass bead 0.1-0.4 Part.
In some of embodiments, the transparent area further includes the component of following parts by weight:0.05-1 parts of lepidolite.
In some of embodiments, the opaque area further includes the component of following parts by weight:Glisten mica 0.1-0.4 Part.
Description of the drawings
Fig. 1 is the overall structure diagram of light transmission Dali stone ceramic tile described in a preferred embodiment of the present invention;
Fig. 2 is the green body schematic diagram of a layer structure of light transmission Dali stone ceramic tile described in Fig. 1;
Fig. 3 is the green body schematic diagram of a layer structure of light transmission Dali stone ceramic tile described in a preferred embodiment of the present invention;
Fig. 4 is the flow chart of the preparation method of light transmission Dali stone ceramic tile described in Fig. 1;
Fig. 5 is that the grid sheet of the positioning distribution device of the preparation method of light transmission Dali stone ceramic tile described in Fig. 1 coordinates with material frame Structural schematic diagram;
Fig. 6 is the structural representation of the grid sheet of the positioning distribution device of the preparation method of light transmission Dali stone ceramic tile described in Fig. 1 Figure;
Fig. 7 is the structural schematic diagram of the masterplate of the positioning distribution device of the preparation method of light transmission Dali stone ceramic tile described in Fig. 1;
Fig. 8 is the structural schematic diagram of light transmission Dali stone ceramic tile described in another preferred embodiment of the present invention.
Specific implementation mode
To facilitate the understanding of the present invention, below with reference to relevant drawings to invention is more fully described.In attached drawing Give presently preferred embodiments of the present invention.But the present invention can realize in many different forms, however it is not limited to this paper institutes The embodiment of description.Keep the understanding to the disclosure more thorough on the contrary, purpose of providing these embodiments is Comprehensively.
It should be noted that when element is referred to as " being fixed on " another element, it can be directly on another element Or there may also be elements placed in the middle.When an element is considered as " connection " another element, it can be directly connected to To another element or it may be simultaneously present centering elements.
Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein The purpose of the embodiment of body, it is not intended that in the limitation present invention.
Fig. 1 and Fig. 2 are please referred to, the present invention provides a kind of light transmission Dali stone ceramic tile 200, which includes base Body layer 201 and the glazed layer 202 for being overlying on 201 surface of green body layer, green body layer 201 include transparent area 211, semi-opaque region 212 and not Transparent area 213.Transparent area 211 therein includes the component of following parts by weight:20-50 parts of nepheline, 10-30 parts of sodium mountain flour, silicon ash 1-4 parts of stone, 4-10 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophillite, 3-15 parts of bentonite;Semi-opaque region 212 includes such as The component of lower parts by weight:15-30 parts of nepheline, 5-20 parts of sodium mountain flour, 1-4 parts of wollastonite, 2-5 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophillite, 1-5 parts of bentonite and colorant.Semi-opaque region 212 includes blue 5-8 parts of colorant, 5-8 parts of green pigment, indigo plant The amount of color colorant and green pigment can be adjusted according to the degree of light transmission, and the more printing opacity degrees added are lower, but measure Conference influences the brightness of entire ceramic tile, whiteness etc..
Colorant therein is green body colorant, and the colorant includes blue colorant, green pigment, coffee-like colorant, black color One or more of material.
Such as colorant includes blue 0-15 parts of colorant, 0-10 parts of green pigment;Or coffee-like 0-10 parts of colorant;Or yellow color Expect 0-15 parts, 0-15 parts of black pigment.The selection of colorant is affected to the translucent effect of semi-opaque region.Colorant can excessively make half Transparent area translucent effect is poor, and colorant is very few to make semi-opaque region that semi-transparent effect be not achieved.Such as colorant includes blue color Material 0,1,2,3,4,5,6,10,12,15 part, green pigment 0,1,2,3,4,5,6,8,10 parts;Coffee-like colorant 0,1,2,3,4, 5,6,7,8,9,10 parts;Yellow colorant 0,1,2,3,4,5,6,10,12,15 parts, black pigment, 0,1,2,3,4,5,6,10,12, 15 parts.
Above-mentioned light transmission Dali stone ceramic tile 200, thickness 12mm-15mm, the lamp direct projection through 100W-200W, direct projection height 20cm-30cm can have an X-rayed the light of different colours, obtain different effects.
Such as nepheline 15 in transparent area 211,18,20,22,23,25,28,30,35,40,45,50 parts;Sodium mountain flour 10, 11,13,15,16,18,30 parts;Wollastonite 1,2,3,3.5,4 parts;Diopside 4,5,7,8,9,10 parts;Ball clay 10,12,15,16, 18,20,22,25,28,30 parts;Pyrophillite 5,8,10,12,15,18,20 parts;Bentonite 3,5,6,8,10,12,14,15 parts.
Such as semi-opaque region 212 include nepheline 15,18,20,22,25,28,30 parts;Sodium mountain flour 5,8,10,12,15,18, 20 parts;Wollastonite 1,2,3,4 parts;Diopside 2,3,4,5 parts;Ball clay 10,11,12,15,18,20,22,25,28,30 parts;Leaf is cured Stone 5,8,10,12,15,18,20 parts;Bentonite 1,2,3,4,5 parts;Blue colorant 5,6,7,8 parts;Green pigment 5,6,7,8 parts.
Opaque area 213 is the raw material of conventionally used ceramic tile, such as includes the component of following parts by weight:SiO255-75 Part, Al2O310-20 parts, Fe2O30.2-0.8 parts, TiO20-0.15 parts, CaO0-0.3 parts, MgO0-1.5 parts, K2O2-5 parts, Na2It O1.5-4 parts, burns and loses 4-7 parts.Corresponding raw mineral materials is selected according to mentioned component.Can also select other compositions with Light transmission material, the cooperation of semi-transparent material.
Above-mentioned transparent area 211, semi-opaque region 212 and the quantity in opaque area 213 are unlimited, can be one, two or Person is more, and transparent area 211, semi-opaque region 212 and opaque area 213 are accordingly arranged as needed, its unlimited arrangement mode.
The embodiment that will be further illustrated the present invention below by several embodiments.
Embodiment one
Fig. 1 and Fig. 2 are please referred to, light transmission Dali stone ceramic tile 200, including green body layer 201 are a preferred embodiment of the present invention And it is overlying on the glazed layer 202 on 201 surface of green body layer, green body layer 201 is by transparent area 211, semi-opaque region 212 and opaque area 213 Composition, the light transmission Dali stone ceramic tile 200 obtained in this way have light transmission, semi-transparent and opaque when light is irradiated on ceramic tile Effect so that the effect of ceramic tile is more natural, closer to the effect of natural marble.
In the present embodiment, each one of the quantity of transparent area 211, semi-opaque region 212 and opaque area 213, according to transparent area 211 docking semi-opaque regions 212, the mode that opaque area 213 is docked in semi-opaque region 212 arrange.Transparent area therein 211 is by as follows The group of parts by weight is grouped as:30 parts of nepheline, 20 parts of sodium mountain flour, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, 10 parts of bentonite;Semi-opaque region 212 is grouped as by the group of following parts by weight:20 parts of nepheline, 15 parts of sodium mountain flour, 3 parts of wollastonite, thoroughly 3 parts of pyroxene, 15 parts of ball clay, 15 parts of pyrophillite, 3 parts of bentonite and blue 6 parts of colorant, 6 parts of green pigment.In the embodiment, thoroughly Light area 211, semi-opaque region 212 and opaque area 213 form brightness ladder, and when illumination is on ceramic tile, brightness is mottled to be showed, real Existing more natural effect.
Further, transparent area 211, semi-opaque region 212 and/or opaque area 213 are covered in setting on one side for glazed layer 20 There is lines.In the present embodiment, the one side that transparent area 211 is covered in glazed layer 20 with semi-opaque region 212 is equipped with above-mentioned lines.
Above-mentioned light transmission Dali stone ceramic tile, green body layer is by transparent area, semi-opaque region and opaque district's groups at transparent area, half Transparent area and opaque area are accordingly arranged as needed, in this way when light is irradiated on ceramic tile, have light transmission, semi-transparent And lighttight effect so that the effect of ceramic tile is more natural, closer to the effect of natural marble.
In addition, above-mentioned transparent area 211 further includes 0.05-1 parts of lepidolite, for example, 0.05 part of lepidolite, 0.2 part, 0.3 Part, 1 part etc..After lepidolite is added, the crystalline substance of transparent area spends higher thoroughly, keeps the ability that it receives illumination more preferable.But add too many meeting Influence its light transmission.
Above-mentioned semi-opaque region 212 further includes 0.1-0.4 parts of glass bead, for example, 0.1 part of glass bead, 0.2 part, 0.3 Part, 0.4 part etc..After glass bead is added, the heat insulation and preservation effect of ceramic tile can be improved, reduces ceramic tile aging, reduction water absorption rate is low, Improve hydrophobic barrier performance.But test of many times proves, glass bead has added the hardness and extensibility that can influence ceramic tile.
Above-mentioned opaque area 213 further include flash of light 0.1-0.4 part of mica, such as glisten 0.1 part of mica, 0.2 part, 0.3 Part, 0.4 part etc..After flash of light mica is added, the crystalline substance of transparent area spends higher thoroughly, keeps the ability that it receives illumination more preferable.
Fig. 4 is please referred to, the preparation method of the light transmission Dali stone ceramic tile 200 is:
One, it scans to obtain design drawing according to the transparent stone of selection, according to above-mentioned design drawing Design Orientation distribution device 100 And the silk screen group for glaze stamp.
Two, positioning distribution device 100 and light transmission material, semi-transparent material and opaque material are provided.
Fig. 2 to Fig. 4 is please referred to, which includes material frame 10, grid sheet 20 and several masterplates 30, grid Piece 20 is located in material frame 10, and the edge of grid sheet 20 connects material frame 10;Grid sheet 20 at least has first area 21, second area 22 and third region 23, first area 21 is for throwing light transmission material, and for throwing semi-transparent material, third region 23 is used for second area 22 Throw opaque material.Masterplate 30 includes at least the first masterplate 31, the second masterplate 32 and third masterplate 33, and the first masterplate 31, which has, to be corresponded to The first batching hole 311 in first area 21, the second masterplate 32 have the second batching hole 321 corresponding to second area 22, the Three masterplates 33 have the third batching hole 331 corresponding to third region 23;The lines of grid sheet 20 therein and character all in accordance with Design drawing and obtain, the lines and quantity of masterplate 30 are obtained according to the design of grid sheet 20.
It is to be appreciated that the type of 23 corresponding material of above-mentioned first area 21, second area 22 and third region can be with Exchange, such as first area 21 can be used for throwing semi-transparent material and opaque material, second area 22 can be used for throwing light transmission material with it is impermeable Light material, third region 23 can be used for throwing light transmission material and semi-transparent material.Here, feeding intake for each region is not limited, it can basis Design needs to be designed.The shape of first area 21, second area 22 and third region 23 can be flexible and changeable, such as is in not The shape of rule, the shapes such as rectangular.
The shape of grid sheet 20 and region design, can adjust, such as several regions can be docking together as needed, It can be docking together two-by-two, in the present embodiment, first area 21, second area 22 and third region 23 are docking together, I.e. second area 22 and third region 23 are docked in first area 21, and second area 22 docks first area 21 and third region 23; First area 21 and second area 22 are docked in third region 23, and the shape of a ceramic tile is collectively formed in three regions.
It is to be appreciated that the region quantity of above-mentioned grid sheet 20 can be arranged as required to, the opposite joining relation between region It is arranged as required to, this is not restricted.
Three, the first masterplate 31 is covered in material frame 10, the first batching hole 311 corresponds to the first area 21 of grid sheet 20, leads to It crosses the first batching hole 311 and light transmission material is distributed in first area 21, after the completion of laying, remove the first masterplate 31.Further, first Masterplate 31 has the first color, and accordingly, first area 21 is used to throw the light transmission material with the first color.Have on masterplate 30 Color so that operator can better discriminate between the color that each region feeds intake, and prevent material of miscarrying.
Four, the second masterplate 32 is covered in material frame 10, the second batching hole 321 corresponds to the second area 22 of grid sheet 20, leads to It crosses the second batching hole 321 and semi-transparent material is distributed in second area 22, after the completion of laying, remove the second masterplate 32.Further, Two masterplates 32 have the second color, and accordingly, second area 22 is used to throw the light transmission material with the second color.Second color can be with First color is identical, can also be different from the first color.
Five, third masterplate 33 is covered in material frame 10, third batching hole 331 corresponds to the third region 23 of grid sheet 20, leads to It crosses third batching hole 331 and opaque material is distributed in third region 23, after the completion of laying, remove third masterplate 33.Further, Three masterplates 33 have third color, and accordingly, third region 23 is used to throw the light transmission material with third color.Third color can be with First color, the second color are identical, can also be different from the first color, the second color.It is suppressed after completing, obtains base Body.
Six, by the silk screen group, glaze surface treatment is carried out in the upper surface of the green body suppressed, obtains glazed layer;Glaze The pattern of layer is consistent with the pattern of selected design drawing, and ceramic tile can be obtained light transmission Dali stone ceramic tile after firing.Using the system The Dali stone ceramic tile for making method production, inside green body layer with texture, color, the level of the decorative pattern on surface, semi-transparent transition region, thoroughly Light area is corresponded with opaque area, visual effect such as jade and jewel stone material true to nature.
The light transmission Dali stone ceramic tile obtained after firing, thickness 12mm-15mm, the lamp direct projection through 100W-200W, direct projection Height 20cm-30cm can have an X-rayed the light of different colours, obtain different effects.
Further, corresponding throwing can also be respectively set in above-mentioned first area 21, second area 22 and third region 23 The first color, the second color and the third color for expecting color, in order to the preferably corresponding color to feed intake.
When the region of above-mentioned light transmission Dali stone ceramic tile 100 increases, corresponding increase batching hole or masterplate.
Embodiment two
Please refer to Fig. 3, the light transmission Dali stone ceramic tile 200 of the present embodiment, what is different from the first embodiment is that transparent area 211 Quantity is two, including the first transparent area 214 and the second transparent area 215, and the quantity in semi-opaque region 212 and opaque area 213 is equal It it is one, the first transparent area 214 docks semi-opaque region 212, and the second transparent area 215 docks semi-opaque region 212 and opaque area 213;First transparent area 214 is grouped as by the group of following parts by weight:30 parts of nepheline, 20 parts of sodium mountain flour, 3 parts of wollastonite, diopside 7 Part, 20 parts of ball clay, 15 parts of pyrophillite, 10 parts of bentonite;Second transparent area 215 is grouped as by the group of following parts by weight:Nepheline 20 Part, 15 parts of sodium mountain flour, 2 parts of wollastonite, 5 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, 8 parts of bentonite;Semi-opaque region 212 by The group of following parts by weight is grouped as:15 parts of nepheline, 5 parts of sodium mountain flour, 3 parts of wollastonite, 5 parts of diopside, 10 parts of ball clay, pyrophillite 10 Part, 3 parts of bentonite and blue 15 parts of colorant.Light transmission Dali stone ceramic tile 200 described in the embodiment, when illumination is on ceramic tile, The brightness of first transparent area 214 and the second transparent area 215 reduces, and adds the effect of semi-opaque region 212 and opaque area 213, Multiple brightness ladders are formed, when the ceramic tile is applied to wall, there is more unique effect.
Embodiment three
The light transmission Dali stone ceramic tile 200 of the present embodiment, what is different from the first embodiment is that transparent area 211, semi-opaque region 212 And opaque area 213 is docking together, i.e., transparent area 211 docks semi-opaque region 212 and opaque area 213, semi-opaque region 212 Transparent area 211 and opaque area 213 are docked, transparent area 211 and semi-opaque region 212 are docked in opaque area 213.
Transparent area 211 therein is grouped as by the group of following parts by weight:50 parts of nepheline, 30 parts of sodium mountain flour, 4 parts of wollastonite, 4 parts of diopside, 30 parts of ball clay, 20 parts of pyrophillite, 5 parts of bentonite.Colorant is coffee-like 8 parts of colorant.
Semi-opaque region 212 therein is grouped as by the group of following parts by weight:30 parts of nepheline, 20 parts of sodium mountain flour, wollastonite 4 Part, 2 parts of diopside, 30 parts of ball clay, 20 parts of pyrophillite, 5 parts of bentonite and blue 2 parts of colorant, 10 parts of green pigment.
Example IV
The light transmission Dali stone ceramic tile 200 of the present embodiment, what is different from the first embodiment is that transparent area 211 docks opaque area 213 and semi-opaque region 212.
Semi-opaque region 212 therein is grouped as by the group of following parts by weight:15 parts of nepheline, 15 parts of sodium mountain flour, wollastonite 1 Part, 5 parts of diopside, 10 parts of ball clay, 10 parts of pyrophillite, 4 parts of bentonite and 15 parts of yellow colorant.
Embodiment five
The light transmission Dali stone ceramic tile 200 of the present embodiment, what is different from the first embodiment is that transparent area is docked in opaque area 213 211 and semi-opaque region 212.
Transparent area 211 therein is grouped as by the group of following parts by weight:20 parts of nepheline, 10 parts of sodium mountain flour, 1 part of wollastonite, 4 parts of diopside, 10 parts of ball clay, 5 parts of pyrophillite, 3 parts of bentonite.
Embodiment six
The light transmission Dali stone ceramic tile of the present embodiment, what is different from the first embodiment is that transparent area 211 is docked in semi-opaque region 212 And opaque area 213.
In addition, above-mentioned semi-opaque region 212 further includes 0.1-0.4 parts of glass bead, such as 0.1 part of glass bead, 0.2 Part, 0.3 part, 0.4 part etc..After glass bead is added, the heat insulation and preservation effect of ceramic tile can be improved, reduces ceramic tile aging, reduces and inhales Water rate is low, improves hydrophobic barrier performance.But test of many times proves, glass bead has added the hardness that can influence ceramic tile and stretching, extension Property.
Embodiment seven
The light transmission Dali stone ceramic tile of the present embodiment, what is different from the first embodiment is that transparent area 211, semi-opaque region 212 and not What transparent area 213 was covered in glazed layer is equipped with lines on one side.
Embodiment eight
Please refer to Fig. 8, the light transmission Dali stone ceramic tile 200 of the present embodiment, what is different from the first embodiment is that transparent area 211 Quantity is one, and the quantity of semi-opaque region 212 is one, and the quantity in opaque area 213 is two, and an opaque area 213 is right Semi-opaque region 212 is connect, transparent area 211 is docked in another opaque area 213.
In addition, above-mentioned opaque area 213 further includes 0.1-0.4 parts of glass bead, such as 0.1 part of glass bead, 0.2 Part, 0.3 part, 0.4 part etc..After glass bead is added, the heat insulation and preservation effect of ceramic tile can be improved, reduces ceramic tile aging, reduces and inhales Water rate is low, improves hydrophobic barrier performance.But test of many times proves, glass bead has added the hardness that can influence ceramic tile and stretching, extension Property.
In addition, the transparent area of light transmission Dali of the present invention stone ceramic tile, semi-opaque region and opaque area, can also be as It is lower at being grouped as:Transparent area includes the component of following parts by weight:SiO258-68 parts, Al2O314-22 parts, Fe2O30-0.3 parts, TiO20-0.1 parts, CaO5-9 parts, MgO0-2 parts, K2O1-3 parts and Na2It O2-7 parts, burns and loses 3-7 parts;Semi-transparent material is above-mentioned The content of Al2O3 is properly increased in light transmission material component and is added and generates semi-transparent colorant, such as semi-opaque region includes following weight The component of part:SiO250-65 parts, Al2O318-23 parts, Fe2O30.8-1 parts, TiO20-0.1 parts, CaO2-5 parts, MgO0-2 parts, K2O1-2 parts, Na2O2-4 parts and colorant burn and lose 4-7 parts, and the amount of additive color material can be adjusted according to the degree of light transmission, and what is added is more Printing opacity degree is lower, but measuring conference influences the brightness of entire ceramic tile, whiteness, thoroughly sense etc.;Opaque area is the base of routine Body component, such as include the component of following parts by weight:SiO255-73 parts, Al2O310-21 parts, Fe2O30.2-0.8 parts, TiO20- 0.5 part, CaO0-1 parts, MgO0-1.5 parts, K2O2-5 parts, Na2It O3-6 parts, burns and loses 4-7 parts.
But above-mentioned light transmission material, semi-transparent material and opaque material is not limited only to said components, can reach above-mentioned mesh .
Such as:The quantity of transparent area, semi-opaque region and opaque area is one, the transparent area, semi-opaque region and not Transparent area docks successively;Transparent area includes the component of following parts by weight:SiO262.04 part, Al2O319.54 part, Fe2O30.18 part, TiO20.01 part, CaO7.63 parts, MgO1.1 parts, K2O2.98 parts and Na22.99 parts of O burns and loses 5 parts;Semi-opaque region includes as follows The component of parts by weight:SiO262 parts, Al2O322 parts, Fe2O31.0 parts, TiO20.05 part, CaO3 parts, MgO1.5 parts, K2O2 parts, Na2O3 parts and blue 6 parts of colorant, 6 parts of green pigment, burn and lose 5 parts;Opaque area includes the component of following parts by weight: SiO262.03 part, Al2O319.83 part, Fe2O30.94 part, TiO20.08 part, CaO3 parts, MgO0.91 parts, K2O1.53 parts, Na2It O2.34 parts, burns and loses 5 parts.
The colorant of semi-opaque region therein for example can also be:The colorants such as black, coffee color, yellow match, such as coffee 2 parts of coffee color colorant, 3 parts of yellow colorant;2 parts of black pigment.
In another example:The quantity of transparent area is two, including the first transparent area and the second transparent area, the semi-opaque region and not The quantity of transparent area is one, and first transparent area docks the semi-opaque region, the second transparent area docking described half Transparent area and opaque area;First transparent area includes the component of following parts by weight:SiO262.04 part, Al2O319.54 part, Fe2O30.18 part, TiO20.01 part, CaO7.63 parts, MgO1.1 parts, K2O2.98 parts and Na22.99 parts of O burns and loses 5 parts;Second thoroughly Light area includes the component of following parts by weight:SiO262.04 part, Al2O319.54 part, Fe2O30.18 part, TiO20.01 part, CaO6 Part, MgO1.1 parts, K22 parts of O and Na22 parts of O burns and loses 5 parts;Semi-opaque region includes the component of following parts by weight:SiO262 parts, Al2O322 parts, Fe2O31.0 part, TiO20.05 part, CaO3 parts, MgO1.5 parts, K2O2 parts, Na2It is O3 parts and blue 6 parts of colorant, green 6 parts of color colorant burns and loses 5 parts;Opaque area includes the component of following parts by weight:SiO262.03 part, Al2O319.83 part, Fe2O30.94 part, TiO20.08 part, CaO3 parts, MgO0.91 parts, K2O1.53 parts, Na2It O2.34 parts, burns and loses 5 parts.
In addition, above-mentioned transparent area 211 further includes Ng2O1-2 parts, such as Ng2O1 parts, 1.5 parts, 2 parts etc..Ng is added2O Afterwards, the binding force higher between blank reduces bubble, the hole of the ceramic tile surface of formation so that illumination reflecting rear face is finer.
Above-mentioned transparent area 211 further includes Li2O0.01-0.5 parts, such as Li20.01 part, 0.2 part, 0.3 part, 0.5 part of O Deng.Li is added2After O, the crystalline substance of transparent area spends higher thoroughly, keeps the ability that it receives illumination more preferable.
Above-mentioned semi-opaque region 212 further includes Ng2O1-2 parts, such as Ng2O1 parts, 1.5 parts, 2 parts etc..Ng is added2After O, base Binding force higher between material reduces bubble, the hole of the ceramic tile surface of formation so that illumination reflecting rear face is finer.
Above-mentioned semi-opaque region 212 further includes 0.1-0.4 parts of glass bead, for example, 0.1 part of glass bead, 0.2 part, 0.3 Part, 0.4 part etc..After glass bead is added, the heat insulation and preservation effect of ceramic tile can be improved, reduces ceramic tile aging, reduction water absorption rate is low, Improve hydrophobic barrier performance.But test of many times proves, glass bead has added the hardness and extensibility that can influence ceramic tile.
Above-mentioned opaque area 213 further includes Li2O0.01-0.05 parts, such as Li20.01 part of O, 0.2 part, 0.3 part, 0.5 Part etc..Li is added2After O, the crystalline substance in opaque area spends higher thoroughly, keeps the ability that it receives illumination more preferable.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously Cannot the limitation to the scope of the claims of the present invention therefore be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

1. a kind of light transmission Dali stone ceramic tile, which is characterized in that including transparent area, semi-opaque region and opaque area;
The transparent area includes the component of following parts by weight:20-50 parts of nepheline, 10-30 parts of sodium mountain flour, 1-4 parts of wollastonite, saturating brightness 4-10 parts of stone, 10-30 parts of ball clay, 5-20 parts of pyrophillite, 3-15 parts of bentonite;
The semi-opaque region includes the component of following parts by weight:15-30 parts of nepheline, 5-20 parts of sodium mountain flour, 1-4 parts of wollastonite, thoroughly 2-5 parts of pyroxene, 10-30 parts of ball clay, 5-20 parts of pyrophillite, 1-5 parts of bentonite and colorant.
2. light transmission Dali according to claim 1 stone ceramic tile, it is characterised in that:The colorant is green body colorant, the color Material is one or more of blue colorant, green pigment, coffee-like colorant, black pigment.
3. light transmission Dali according to claim 1 or 2 stone ceramic tile, it is characterised in that:The colorant includes blue colorant 0- 15 parts, 0-10 parts of green pigment.
4. light transmission Dali according to claim 1 or 2 stone ceramic tile, it is characterised in that:The colorant includes coffee-like colorant 0-10 parts.
5. light transmission Dali according to claim 1 or 2 stone ceramic tile, it is characterised in that:The colorant includes yellow colorant 0- 15 parts, 0-15 parts of black pigment.
6. light transmission Dali according to claim 1 or 2 stone ceramic tile, it is characterised in that:The transparent area, semi-opaque region and not The quantity of transparent area is one, and the transparent area, semi-opaque region and opaque area are docked successively;The transparent area includes as follows The component of parts by weight:30 parts of nepheline, 20 parts of sodium mountain flour, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, swelling 10 parts of soil;The semi-opaque region includes the component of following parts by weight:20 parts of nepheline, 15 parts of sodium mountain flour, 3 parts of wollastonite, diopside 3 Part, 15 parts of ball clay, 15 parts of pyrophillite, 3 parts of bentonite and blue 6 parts of colorant, 6 parts of green pigment.
7. light transmission Dali according to claim 1 stone ceramic tile, it is characterised in that:The quantity of the transparent area is two, packet Include the first transparent area and the second transparent area, the quantity in the semi-opaque region and opaque area is one, first transparent area The semi-opaque region is docked, second transparent area docks the semi-opaque region and opaque area;First transparent area includes The component of following parts by weight:30 parts of nepheline, 20 parts of sodium mountain flour, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, 10 parts of bentonite;Second transparent area includes the component of following parts by weight:20 parts of nepheline, 15 parts of sodium mountain flour, 2 parts of wollastonite, 5 parts of diopside, 20 parts of ball clay, 15 parts of pyrophillite, 8 parts of bentonite;The semi-opaque region includes the component of following parts by weight:Nepheline 15 parts, 5 parts of sodium mountain flour, 3 parts of wollastonite, 5 parts of diopside, 10 parts of ball clay, 10 parts of pyrophillite, 3 parts of bentonite and blue colorant 5 Part, 5 parts of green pigment and blue 7 parts of colorant, 5 parts of green pigment.
8. light transmission Dali according to claim 1 stone ceramic tile, it is characterised in that:The semi-opaque region further includes following weight The component of part:0.1-0.4 parts of glass bead.
9. light transmission Dali according to claim 1 stone ceramic tile, it is characterised in that:The transparent area further includes following parts by weight Component:0.05-1 parts of lepidolite.
10. light transmission Dali according to claim 1 stone ceramic tile, it is characterised in that:The opaque area further includes following weight Measure the component of part:Glisten 0.1-0.4 parts of mica.
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