CN108503330B - Light-transmitting marble tile - Google Patents
Light-transmitting marble tile Download PDFInfo
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- CN108503330B CN108503330B CN201810307750.1A CN201810307750A CN108503330B CN 108503330 B CN108503330 B CN 108503330B CN 201810307750 A CN201810307750 A CN 201810307750A CN 108503330 B CN108503330 B CN 108503330B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/144—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of marble or other natural stone
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
- C04B2235/3454—Calcium silicates, e.g. wollastonite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a light-transmitting marble tile. The light-transmitting marble tile comprises a light-transmitting area, a semi-light-transmitting area and a light-opaque area; the light-transmitting region comprises the following components: 20-50 parts of nepheline, 10-30 parts of sodalite powder, 1-4 parts of wollastonite, 4-10 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite and 3-15 parts of bentonite; the semi-transparent area comprises the following components: 15-30 parts of nepheline, 5-20 parts of sodalite powder, 1-4 parts of wollastonite, 2-5 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite, 1-5 parts of bentonite and a pigment. The light-transmitting marble tile has the natural beauty of light transmission, semi-light transmission and light impermeability.
Description
Technical Field
The invention relates to the technical field of ceramic tile production, in particular to a light-transmitting marble ceramic tile.
Background
The light-transmitting marble tile is a tile imitating natural marble light-transmitting performance, and part of natural marbles have different forming mechanisms due to different components, natural light-transmitting performance and impermeability, and unique product characteristics in household design and application. On the exhibition of building door stone materials, in the prior exhibition of a plurality of stone materials such as transparent jade, gem and the like, the back of the stone material is polished by cutting and splicing, so that the surface presents a three-dimensional effect of mottled light and the intersection of stone material textures. The whole body light transmission technology has excellent application prospect in the background wall, and similar research and development problems in marble tiles do not exist before.
In recent years, many ceramic manufacturers are developing transparent marble tiles, but the whole tile is transparent, and a single transparent material cannot well express the pure natural beauty of natural stone with partial transparency, partial opacity and semi-transparency transition.
Disclosure of Invention
In view of this, the present invention is necessary to provide a light-transmitting marble tile having a natural beauty of light-transmitting, semi-light-transmitting and non-light-transmitting.
In order to realize the purpose of the invention, the invention adopts the following technical scheme:
a light-transmitting marble tile comprises a light-transmitting area, a semi-light-transmitting area and a light-opaque area;
the light-transmitting area comprises the following components in parts by weight: 20-50 parts of nepheline, 10-30 parts of sodalite powder, 1-4 parts of wollastonite, 4-10 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite and 3-15 parts of bentonite;
the semi-transparent area comprises the following components in parts by weight: 15-30 parts of nepheline, 5-20 parts of sodalite powder, 1-4 parts of wollastonite, 2-5 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite, 1-5 parts of bentonite and a pigment.
The light-transmitting marble tile is composed of the light-transmitting area, the semi-light-transmitting area and the light-tight area, each area corresponds to different blanks, the fired tile has the light-transmitting effect, the semi-light-transmitting effect and the light-tight effect, and the natural beauty of natural stones can be better embodied.
In some embodiments, the colorant is a green colorant, and the colorant is one or more of a blue colorant, a green colorant, a coffee colorant, and a black colorant.
In some embodiments, the colorant comprises 0-15 parts of a blue colorant and 0-10 parts of a green colorant.
In some of these embodiments, the colorant comprises 0-10 parts of a coffee colorant.
In some embodiments, the colorant comprises 0-15 parts yellow colorant and 0-15 parts black colorant.
In some embodiments, the number of the transparent regions, the semi-transparent regions and the opaque regions is one, and the transparent regions, the semi-transparent regions and the opaque regions are sequentially butted; the light-transmitting area comprises the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 10 parts of bentonite; the semi-transparent area comprises the following components in parts by weight: 20 parts of nepheline, 15 parts of sodalite powder, 3 parts of wollastonite, 3 parts of diopside, 15 parts of ball clay, 15 parts of pyrophyllite, 3 parts of bentonite, 6 parts of blue pigment and 6 parts of green pigment.
In some embodiments, the number of the light-transmitting areas is two, and the light-transmitting areas include a first light-transmitting area and a second light-transmitting area, the number of the semi-light-transmitting areas and the number of the non-light-transmitting areas are both one, the first light-transmitting area is abutted against the semi-light-transmitting area, and the second light-transmitting area is abutted against the semi-light-transmitting area and the non-light-transmitting area; the first light-transmitting area comprises the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 10 parts of bentonite; the second light-transmitting area comprises the following components in parts by weight: 20 parts of nepheline, 15 parts of sodalite powder, 2 parts of wollastonite, 5 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 8 parts of bentonite; the semi-transparent area comprises the following components in parts by weight: 15 parts of nepheline, 5 parts of sodalite powder, 3 parts of wollastonite, 5 parts of diopside, 10 parts of ball clay, 10 parts of pyrophyllite, 3 parts of bentonite, 5 parts of blue pigment, 5 parts of green pigment, 7 parts of blue pigment and 5 parts of green pigment.
In some embodiments, the semi-transparent region further comprises the following components in parts by weight: 0.1-0.4 part of vitrified micro bubbles.
In some embodiments, the light-transmitting region further comprises the following components in parts by weight: 0.05-1 part of lepidolite.
In some embodiments, the opaque region further comprises the following components in parts by weight: 0.1 to 0.4 portion of flash mica.
Drawings
Fig. 1 is a schematic view of the overall structure of a light-transmitting marble tile according to a preferred embodiment of the present invention;
fig. 2 is a schematic view of the structure of the green body layer of the light-transmitting marble tile of fig. 1;
fig. 3 is a schematic view of the structure of the green body layer of the light-transmitting marble tile according to a preferred embodiment of the present invention;
fig. 4 is a flow chart of a method for preparing the light-transmitting marble tile of fig. 1;
fig. 5 is a schematic structural view of the matching of the grid pieces and the material frame of the positioning and distributing device of the preparation method of the light-transmitting marble tile shown in fig. 1;
fig. 6 is a schematic view of the structure of the grid pieces of the positioning and distributing device of the preparation method of the light-transmitting marble tile of fig. 1;
fig. 7 is a schematic view of the structure of a stencil of a positioning and distributing device of the method for manufacturing the light-transmitting marble tile of fig. 1;
fig. 8 is a schematic structural view of a light-transmitting marble tile according to another preferred embodiment of the present invention.
Detailed Description
To facilitate an understanding of the invention, the invention will now be described more fully with reference to the accompanying drawings. Preferred embodiments of the present invention are shown in the drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
It will be understood that when an element is referred to as being "secured to" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
Referring to fig. 1 and 2, the present invention provides a light-transmitting marble tile 200, which includes a blank layer 201 and a glaze layer 202 covering the surface of the blank layer 201, wherein the blank layer 201 includes a light-transmitting area 211, a semi-light-transmitting area 212 and a light-proof area 213. The light-transmitting area 211 comprises the following components in parts by weight: 20-50 parts of nepheline, 10-30 parts of sodalite powder, 1-4 parts of wollastonite, 4-10 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite and 3-15 parts of bentonite; the semi-transparent region 212 comprises the following components in parts by weight: 15-30 parts of nepheline, 5-20 parts of sodalite powder, 1-4 parts of wollastonite, 2-5 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite, 1-5 parts of bentonite and a pigment. The semi-transparent region 212 comprises 5-8 parts of blue pigment and 5-8 parts of green pigment, the amounts of the blue pigment and the green pigment can be adjusted according to the degree of light transmission, the degree of light transmission is lower, but the excessive amount can affect the brightness, whiteness and the like of the whole tile.
The colorant is a blank colorant, and the colorant comprises one or more of a blue colorant, a green colorant, a coffee colorant and a black colorant.
For example, the coloring material comprises 0-15 parts of blue coloring material and 0-10 parts of green coloring material; or 0-10 parts of coffee pigment; or 0-15 parts of yellow pigment and 0-15 parts of black pigment. The choice of the pigment has a greater influence on the light transmission effect of the semi-opaque region. Too much pigment can make the translucent region have poor light transmission effect, and too little pigment can make the translucent region not reach the translucent effect. For example, the coloring material includes blue coloring material 0, 1, 2, 3, 4, 5, 6, 10, 12, 15 parts, green coloring material 0, 1, 2, 3, 4, 5, 6, 8, 10 parts; coffee colorant 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10 parts; yellow colorant 0, 1, 2, 3, 4, 5, 6, 10, 12, 15 parts, black colorant 0, 1, 2, 3, 4, 5, 6, 10, 12, 15 parts.
The thickness of the light-transmitting marble tile 200 is 12-15 mm, the light-transmitting marble tile is directly emitted by a lamp of 100-200W, the direct emitting height is 20-30 cm, and light with different colors can be transmitted through the light to obtain different effects.
Such as nepheline 15, 18, 20, 22, 23, 25, 28, 30, 35, 40, 45, 50 parts in the light-transmitting region 211; 10, 11, 13, 15, 16, 18 and 30 parts of sodalite powder; 1, 2, 3, 3.5 and 4 parts of wollastonite; 4, 5, 7, 8, 9 and 10 parts of diopside; ball clay 10, 12, 15, 16, 18, 20, 22, 25, 28 and 30 parts; 5, 8, 10, 12, 15, 18 and 20 parts of pyrophyllite; 3, 5, 6, 8, 10, 12, 14 and 15 parts of bentonite.
For example, semi-opaque region 212 includes nepheline 15, 18, 20, 22, 25, 28, 30 parts; 5, 8, 10, 12, 15, 18 and 20 parts of sodalite powder; 1, 2, 3 and 4 parts of wollastonite; 2, 3, 4 and 5 parts of diopside; ball clay 10, 11, 12, 15, 18, 20, 22, 25, 28 and 30 parts; 5, 8, 10, 12, 15, 18 and 20 parts of pyrophyllite; 1, 2, 3, 4 and 5 parts of bentonite; 5, 6, 7 and 8 parts of blue coloring materials; 5, 6, 7 and 8 parts of green coloring materials.
The opaque region 213 is a material of a commonly used tile, and includes, for example, the following components in parts by weight: SiO 2255-75 parts of Al2O310-20 parts of Fe2O30.2 to 0.8 portion of TiO20-0.15 part, CaO0-0.3 part, MgO0-1.5 parts, K2O2-5 parts, Na21.5-4 parts of O and 4-7 parts of loss on ignition. Selecting corresponding mineral raw materials according to the components. Other components can also be selected to be matched with the light-transmitting material and the light-semi-transmitting material.
The number of the transparent regions 211, the semi-transparent regions 212 and the opaque regions 213 is not limited, and may be one, two or more, and the transparent regions 211, the semi-transparent regions 212 and the opaque regions 213 are arranged correspondingly according to the requirement, without being limited to the arrangement manner.
Embodiments of the present invention will be further illustrated by the following examples.
Example one
Referring to fig. 1 and 2, a transparent marble tile 200 according to a preferred embodiment of the present invention includes a blank layer 201 and a glaze layer 202 covering the surface of the blank layer 201, wherein the blank layer 201 includes a transparent region 211, a semi-transparent region 212 and an opaque region 213, and the transparent marble tile 200 thus obtained has transparent, semi-transparent and opaque effects when light is irradiated onto the tile, so that the tile effect is more natural and closer to the natural marble effect.
In this embodiment, the number of the transparent regions 211, the semi-transparent regions 212 and the opaque regions 213 is respectively one, and the transparent regions 211 are arranged to be opposite to the semi-transparent regions 212, and the semi-transparent regions 212 are opposite to the opaque regions 213. The light-transmitting area 211 comprises the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 10 parts of bentonite; the semi-transparent region 212 consists of the following components in parts by weight: 20 parts of nepheline, 15 parts of sodalite powder, 3 parts of wollastonite, 3 parts of diopside, 15 parts of ball clay, 15 parts of pyrophyllite, 3 parts of bentonite, 6 parts of blue pigment and 6 parts of green pigment. In this embodiment, the transparent region 211, the semi-transparent region 212 and the opaque region 213 form a brightness step, so that when light is irradiated on the tile, brightness is shown in a mottled manner, thereby achieving a more natural effect.
Furthermore, the transparent area 211, the semi-transparent area 212 and/or the opaque area 213 are provided with grains on one side covering the glaze layer 20. In this embodiment, the transparent area 211 and the semi-transparent area 212 are provided with the above-mentioned texture on the surface covering the glaze layer 20.
Foretell printing opacity marble ceramic tile, the body layer comprises printing opacity district, semi-light transmission district and opaque district, and printing opacity district, semi-light transmission district and opaque district carry out corresponding range as required, when light shines on the ceramic tile like this, have printing opacity, semi-transparent and opaque effect for the effect of ceramic tile is more natural, more presses close to the effect of natural marble.
In addition, the light-transmitting region 211 may further include 0.05 to 1 part of lepidolite, for example, 0.05 part, 0.2 part, 0.3 part, 1 part, or the like of lepidolite. After the lithium mica is added, the crystal transmittance of the light-transmitting area is higher, so that the capability of receiving light is better. But adding too much will affect its light transmission properties.
The semi-opaque region 212 further comprises 0.1-0.4 parts of vitrified small balls, such as 0.1 part, 0.2 part, 0.3 part, 0.4 part, etc. After the vitrified micro bubbles are added, the heat insulation effect of the ceramic tile can be improved, the aging of the ceramic tile is reduced, the water absorption rate is reduced, and the hydrophobic seepage-proofing performance is improved. However, multiple tests prove that the hardness and the extensibility of the ceramic tile are influenced by more vitrified micro bubbles.
The opaque region 213 further includes 0.1 to 0.4 parts of mica glitter, for example, 0.1 part, 0.2 part, 0.3 part, 0.4 part, etc. After the flash mica is added, the crystal transmittance of the light transmission area is higher, so that the capability of receiving illumination is better.
Referring to fig. 4, the method for preparing the light-transmitting marble tile 200 includes:
firstly, scanning according to the selected light-transmitting stone to obtain a design drawing, and designing and positioning the distributing device 100 and a silk screen group for printing glaze according to the design drawing.
And secondly, providing a positioning material distribution device 100, a light-transmitting material, a semi-light-transmitting material and a light-proof material.
Referring to fig. 2 to 4, the positioning and distributing device 100 includes a material frame 10, a grid sheet 20 and a plurality of templates 30, wherein the grid sheet 20 is located in the material frame 10, and the edge of the grid sheet 20 is connected to the material frame 10; the grating sheet 20 at least has a first area 21, a second area 22 and a third area 23, wherein the first area 21 is used for feeding the light-transmitting material, the second area 22 is used for feeding the light-transmitting material, and the third area 23 is used for feeding the light-non-transmitting material. The stencil 30 comprises at least a first stencil 31, a second stencil 32 and a third stencil 33, the first stencil 31 having first dispensing openings 311 corresponding to the first area 21, the second stencil 32 having second dispensing openings 321 corresponding to the second area 22, the third stencil 33 having third dispensing openings 331 corresponding to the third area 23; the grains and characters of the grating pieces 20 are obtained according to the design drawing, and the grains and quantity of the template 30 are obtained according to the design of the grating pieces 20.
It is understood that the types of materials corresponding to the first area 21, the second area 22 and the third area 23 can be interchanged, for example, the first area 21 can be used for casting the translucent material and the opaque material, the second area 22 can be used for casting the translucent material and the opaque material, and the third area 23 can be used for casting the translucent material and the translucent material. Here, the material feeding of each area is not limited, and may be designed according to design requirements. The shapes of the first region 21, the second region 22 and the third region 23 can be varied, for example, they are irregular, square, etc.
The shape and the area design of the grating sheet 20 can be adjusted as required, for example, several areas can be butted together, or two areas can be butted together, in this embodiment, the first area 21, the second area 22 and the third area 23 are all butted together, that is, the first area 21 is butted with the second area 22 and the third area 23, and the second area 22 is butted with the first area 21 and the third area 23; the third zone 23 adjoins the first zone 21 and the second zone 22, the three zones together forming the shape of a tile.
It is understood that the number of the regions of the grating sheet 20 can be set according to the requirement, and the abutting relationship between the regions can also be set according to the requirement, which is not limited herein.
Thirdly, covering the first stencil 31 on the material frame 10, arranging the light-transmitting material in the first area 21 through the first feeding holes 311 corresponding to the first area 21 of the grating sheet 20, and removing the first stencil 31 after the arrangement is completed. Further, the first stencil 31 has a first color, and correspondingly, the first area 21 is used for projecting a light-transmitting material having the first color. The stencil 30 is colored so that the operator can better distinguish the colors of the materials fed in each area and prevent the wrong materials from being fed.
Fourthly, covering the second stencil 32 on the material frame 10, wherein the second feeding holes 321 correspond to the second areas 22 of the grating pieces 20, distributing the semi-transparent material in the second areas 22 through the second feeding holes 321, and removing the second stencil 32 after the distributing is finished. Further, the second stencil 32 is of a second color and, correspondingly, the second region 22 is adapted to project a light transmissive material of the second color. The second color may be the same as the first color or may be different from the first color.
Fifthly, covering the third stencil 33 on the material frame 10, wherein the third feeding holes 331 correspond to the third areas 23 of the grating pieces 20, the opaque material is distributed in the third areas 23 through the third feeding holes 331, and after the distribution is completed, the third stencil 33 is removed. Further, the third stencil 33 has a third color, and correspondingly, the third area 23 is used for projecting a light-transmitting material having the third color. The third color may be the same as the first color and the second color, or may be different from the first color and the second color. And pressing after the manufacturing is finished to obtain a blank.
Sixthly, performing glaze treatment on the upper surface of the pressed blank through the wire mesh group to obtain a glaze layer; the pattern of the glaze layer is consistent with the pattern of the selected design drawing, and the light-transmitting marble tile can be obtained after the tile is fired. The marble tile produced by the method has the texture, color and level of the patterns inside and on the surface of the blank layer, the semi-transparent transition area, the light transmission area and the light-tight area which are all in one-to-one correspondence, and the visual effect is vivid like jade and gem stone.
The thickness of the light-transmitting marble tile obtained after firing is 12-15 mm, the light-transmitting marble tile is directly emitted by a lamp with the power of 100-200W, the direct emitting height is 20-30 cm, and lamplight with different colors can be seen through, so that different effects can be obtained.
Furthermore, the first area 21, the second area 22 and the third area 23 may also be respectively provided with a first color, a second color and a third color corresponding to the feeding color, so as to better correspond to the feeding color.
When the area of the light-transmitting marble tile 100 is increased, feeding holes or templates are correspondingly increased.
Example two
Referring to fig. 3, a difference between the transparent marble tile 200 of the present embodiment and the first embodiment is that the number of the transparent regions 211 is two, including a first transparent region 214 and a second transparent region 215, the number of the semi-transparent region 212 and the number of the opaque region 213 are both one, the first transparent region 214 is abutted against the semi-transparent region 212, and the second transparent region 215 is abutted against the semi-transparent region 212 and the opaque region 213; the first light-transmitting region 214 is composed of the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 10 parts of bentonite; the second light-transmitting area 215 is composed of the following components in parts by weight: 20 parts of nepheline, 15 parts of sodalite powder, 2 parts of wollastonite, 5 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 8 parts of bentonite; the semi-transparent region 212 consists of the following components in parts by weight: 15 parts of nepheline, 5 parts of sodalite powder, 3 parts of wollastonite, 5 parts of diopside, 10 parts of ball clay, 10 parts of pyrophyllite, 3 parts of bentonite and 15 parts of blue pigment. The light-transmitting marble tile 200 of this embodiment has a more unique effect when applied to a background wall, because the brightness of the first and second light-transmitting regions 214 and 215 decreases when light is applied to the tile, and the effect of the semi-light-transmitting region 212 and the non-light-transmitting region 213 forms a plurality of brightness steps.
EXAMPLE III
The difference between the transparent marble tile 200 and the first embodiment is that the transparent region 211, the semi-transparent region 212, and the opaque region 213 are all connected together in a butt joint manner, i.e., the transparent region 211 is connected to the semi-transparent region 212 and the opaque region 213, the semi-transparent region 212 is connected to the transparent region 211 and the opaque region 213, and the opaque region 213 is connected to the transparent region 211 and the semi-transparent region 212.
The light-transmitting area 211 comprises the following components in parts by weight: 50 parts of nepheline, 30 parts of sodalite powder, 4 parts of wollastonite, 4 parts of diopside, 30 parts of ball clay, 20 parts of pyrophyllite and 5 parts of bentonite. The colorant is coffee colorant 8 parts.
The semi-transparent area 212 comprises the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 4 parts of wollastonite, 2 parts of diopside, 30 parts of ball clay, 20 parts of pyrophyllite, 5 parts of bentonite, 2 parts of blue pigment and 10 parts of green pigment.
Example four
Unlike the first embodiment, the transparent region 211 of the transparent marble tile 200 of the present embodiment is connected to the opaque region 213 and the semi-transparent region 212.
The semi-transparent area 212 comprises the following components in parts by weight: 15 parts of nepheline, 15 parts of sodalite powder, 1 part of wollastonite, 5 parts of diopside, 10 parts of ball clay, 10 parts of pyrophyllite, 4 parts of bentonite and 15 parts of yellow pigment.
EXAMPLE five
Unlike the first embodiment, the translucent marble tile 200 of the present embodiment is that the opaque region 213 is connected to the translucent region 211 and the semi-translucent region 212.
The light-transmitting area 211 comprises the following components in parts by weight: 20 parts of nepheline, 10 parts of sodalite powder, 1 part of wollastonite, 4 parts of diopside, 10 parts of ball clay, 5 parts of pyrophyllite and 3 parts of bentonite.
EXAMPLE six
Unlike the first embodiment, the translucent region 212 of the translucent marble tile of the present embodiment is connected to the translucent region 211 and the opaque region 213.
In addition, the semi-transparent region 212 further includes 0.1-0.4 parts of vitrified small balls, such as 0.1 part, 0.2 part, 0.3 part, 0.4 part, etc. After the vitrified micro bubbles are added, the heat insulation effect of the ceramic tile can be improved, the aging of the ceramic tile is reduced, the water absorption rate is reduced, and the hydrophobic seepage-proofing performance is improved. However, multiple tests prove that the hardness and the extensibility of the ceramic tile are influenced by more vitrified micro bubbles.
EXAMPLE seven
The difference between the transparent marble tile of this embodiment and the first embodiment is that the transparent area 211, the semi-transparent area 212, and the opaque area 213 are all provided with lines on the surface covering the glazed layer.
Example eight
Referring to fig. 8, a difference between the transparent marble tile 200 of the present embodiment and the first embodiment is that the number of the transparent regions 211 is one, the number of the semi-transparent regions 212 is one, the number of the opaque regions 213 is two, one opaque region 213 is abutted against the semi-transparent region 212, and the other opaque region 213 is abutted against the transparent region 211.
In addition, the opaque region 213 further includes 0.1 to 0.4 parts of vitrified small beads, for example, 0.1 part, 0.2 part, 0.3 part, 0.4 part, etc. After the vitrified micro bubbles are added, the heat insulation effect of the ceramic tile can be improved, the aging of the ceramic tile is reduced, the water absorption rate is reduced, and the hydrophobic seepage-proofing performance is improved. However, multiple tests prove that the hardness and the extensibility of the ceramic tile are influenced by more vitrified micro bubbles.
In addition, the light-transmitting area, the semi-light-transmitting area and the light-proof area of the light-transmitting marble tile can also consist of the following components: the light-transmitting area comprises the following components in parts by weight: SiO 2258 to 68 portions of Al2O314-22 parts of Fe2O30 to 0.3 portion of TiO20-0.1 part, CaO5-9 parts, MgO0-2 parts, K2O1-3 parts and Na2O2-7 parts, loss on ignition 3-7 parts; the semi-transparent material is prepared by properly increasing the content of Al2O3 in the components of the light-transmitting material and adding a pigment for generating semi-transparency, wherein the semi-transparent area comprises the following components in parts by weight: SiO 2250-65 parts of Al2O318-23 parts of Fe2O30.8 to 1 portion of TiO20-0.1 part, CaO2-5 parts, MgO0-2 parts, K2O1-2 parts, Na2O2-4 parts and pigment, wherein the loss of burning is 4-7 parts, the amount of the pigment can be adjusted according to the degree of light transmission, the lower the degree of light transmission, but the excessive amount can affect the brightness, whiteness, transparency and the like of the whole ceramic tile; the opaque region is a conventional green body composition, for example comprising the following components in parts by weight: SiO 2255-73 parts of Al2O310-21 parts of Fe2O30.2 to 0.8 portion of TiO20-0.5 part, CaO0-1 part, MgO0-1.5 parts, K2O2-5 parts, Na2O3-6 parts and loss of ignition 4-7 parts.
However, the above-mentioned light-transmitting material, light-transmitting material and light-proof material are not limited to the above-mentioned components, and the above-mentioned object can be achieved.
For example: the number of the light-transmitting areas, the number of the semi-light-transmitting areas and the number of the light-non-transmitting areas are all one, and the light-transmitting areas, the semi-light-transmitting areas and the light-non-transmitting areas are sequentially butted; the light-transmitting area comprises the following components in parts by weight: SiO 2262.04 parts of Al2O319.54 parts of Fe2O30.18 part of TiO20.01 part, CaO7.63 parts, MgO1.1 parts, K2O2.98 parts and Na2O2.99 parts and loss of ignition 5 parts; the semi-light-transmitting area comprises the following components in parts by weight: SiO 2262 parts of Al2O322 parts of Fe2O31.0 part of TiO20.05 part, CaO3 part, MgO1.5 part, K2O2 parts, Na2O3, 6 parts of blue pigment, 6 parts of green pigment and 5 parts of loss on ignition; the light-tight region comprises the following components in parts by weight: SiO 2262.03 parts of Al2O319.83 parts of Fe2O30.94 part of TiO20.08 part, CaO3 part, MgO0.91 part, K2O1.53 parts, Na2O2.34 parts and loss on ignition 5 parts.
The colorant of the semi-transparent region can be, for example: black, coffee, yellow and other color materials, such as 2 parts of coffee color pigment and 3 parts of yellow pigment; and 2 parts of black pigment.
Another example is: the number of the light-transmitting areas is two, the light-transmitting areas comprise a first light-transmitting area and a second light-transmitting area, the number of the semi-light-transmitting areas and the number of the non-light-transmitting areas are both one, the first light-transmitting areas are in butt joint with the semi-light-transmitting areas, and the second light-transmitting areas are in butt joint with the semi-light-transmitting areas and the non-light-transmitting areas; the first light-transmitting area comprises the following components in parts by weight: SiO 2262.04 parts of Al2O319.54 parts of Fe2O30.18 part of TiO20.01 part, CaO7.63 parts, MgO1.1 parts, K2O2.98 parts and Na2O2.99 parts and loss of ignition 5 parts; the second light-transmitting area comprises the following components in parts by weight: SiO 2262.04 parts of Al2O319.54 parts of Fe2O30.18 part of TiO20.01 part, CaO6 parts, MgO1.1 parts, K2O2 and Na2O2 portion, loss of ignition5 parts of a mixture; the semi-light-transmitting area comprises the following components in parts by weight: SiO 2262 parts of Al2O322 parts of Fe2O31.0 part of TiO20.05 part, CaO3 part, MgO1.5 part, K2O2 parts, Na2O3, 6 parts of blue pigment, 6 parts of green pigment and 5 parts of loss on ignition; the light-tight region comprises the following components in parts by weight: SiO 2262.03 parts of Al2O319.83 parts of Fe2O30.94 part of TiO20.08 part, CaO3 part, MgO0.91 part, K2O1.53 parts, Na2O2.34 parts and loss on ignition 5 parts.
The light-transmitting region 211 further includes Li20.01-0.5 part of O, e.g. Li20.01 part, 0.2 part, 0.3 part, 0.5 part and the like of O. Addition of Li2After O, the crystal transmittance of the light-transmitting area is higher, so that the light-receiving capacity of the light-transmitting area is better.
The semi-opaque region 212 further comprises 0.1-0.4 parts of vitrified small balls, such as 0.1 part, 0.2 part, 0.3 part, 0.4 part, etc. After the vitrified micro bubbles are added, the heat insulation effect of the ceramic tile can be improved, the aging of the ceramic tile is reduced, the water absorption rate is reduced, and the hydrophobic seepage-proofing performance is improved. However, multiple tests prove that the hardness and the extensibility of the ceramic tile are influenced by more vitrified micro bubbles.
The opaque region 213 further includes Li20.01-0.05 part of O, e.g. Li20.01 part, 0.2 part, 0.3 part, 0.5 part and the like of O. Addition of Li2And after O, the crystal transmittance of the opaque region is higher, so that the capability of receiving illumination is better.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. A light-transmitting marble tile is characterized by comprising a light-transmitting area, a semi-light-transmitting area and a light-opaque area;
the light-transmitting area comprises the following components in parts by weight: 20-50 parts of nepheline, 10-30 parts of sodalite powder, 1-4 parts of wollastonite, 4-10 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite and 3-15 parts of bentonite;
the semi-transparent area comprises the following components in parts by weight: 15-30 parts of nepheline, 5-20 parts of sodalite powder, 1-4 parts of wollastonite, 2-5 parts of diopside, 10-30 parts of ball clay, 5-20 parts of pyrophyllite, 1-5 parts of bentonite and a pigment.
2. The light-transmitting marble tile of claim 1, wherein: the pigment is a green pigment, and the pigment is one or more of a blue pigment, a green pigment, a coffee pigment and a black pigment.
3. The light-transmitting marble tile according to claim 1 or 2, wherein: the pigment comprises 0-15 parts of blue pigment and 0-10 parts of green pigment.
4. The light-transmitting marble tile according to claim 1 or 2, wherein: the colorant comprises 0-10 parts of coffee colorant.
5. The light-transmitting marble tile according to claim 1 or 2, wherein: the pigment comprises 0-15 parts of yellow pigment and 0-15 parts of black pigment.
6. The light-transmitting marble tile according to claim 1 or 2, wherein: the number of the light-transmitting areas, the number of the semi-light-transmitting areas and the number of the light-non-transmitting areas are all one, and the light-transmitting areas, the semi-light-transmitting areas and the light-non-transmitting areas are sequentially butted; the light-transmitting area comprises the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 10 parts of bentonite; the semi-transparent area comprises the following components in parts by weight: 20 parts of nepheline, 15 parts of sodalite powder, 3 parts of wollastonite, 3 parts of diopside, 15 parts of ball clay, 15 parts of pyrophyllite, 3 parts of bentonite, 6 parts of blue pigment and 6 parts of green pigment.
7. The light-transmitting marble tile of claim 1, wherein: the number of the light-transmitting areas is two, the light-transmitting areas comprise a first light-transmitting area and a second light-transmitting area, the number of the semi-light-transmitting areas and the number of the non-light-transmitting areas are both one, the first light-transmitting areas are in butt joint with the semi-light-transmitting areas, and the second light-transmitting areas are in butt joint with the semi-light-transmitting areas and the non-light-transmitting areas; the first light-transmitting area comprises the following components in parts by weight: 30 parts of nepheline, 20 parts of sodalite powder, 3 parts of wollastonite, 7 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 10 parts of bentonite; the second light-transmitting area comprises the following components in parts by weight: 20 parts of nepheline, 15 parts of sodalite powder, 2 parts of wollastonite, 5 parts of diopside, 20 parts of ball clay, 15 parts of pyrophyllite and 8 parts of bentonite; the semi-transparent area comprises the following components in parts by weight: 15 parts of nepheline, 5 parts of sodalite powder, 3 parts of wollastonite, 5 parts of diopside, 10 parts of ball clay, 10 parts of pyrophyllite, 3 parts of bentonite and 15 parts of blue pigment.
8. The light-transmitting marble tile of claim 1, wherein: the semi-transparent area also comprises the following components in parts by weight: 0.1-0.4 part of vitrified micro bubbles.
9. The light-transmitting marble tile of claim 1, wherein: the light-transmitting area also comprises the following components in parts by weight: 0.05-1 part of lepidolite.
10. The light-transmitting marble tile of claim 1, wherein: the light-tight region also comprises the following components in parts by weight: 0.1 to 0.4 portion of flash mica.
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| CN116283230B (en) * | 2023-04-04 | 2024-05-28 | 广东简一(集团)陶瓷有限公司 | Locally-transparent marble tile and preparation process thereof |
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