CN102746016A - Production method for reducing bubble rate of glass ceramics composite plate - Google Patents
Production method for reducing bubble rate of glass ceramics composite plate Download PDFInfo
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- CN102746016A CN102746016A CN2012102235873A CN201210223587A CN102746016A CN 102746016 A CN102746016 A CN 102746016A CN 2012102235873 A CN2012102235873 A CN 2012102235873A CN 201210223587 A CN201210223587 A CN 201210223587A CN 102746016 A CN102746016 A CN 102746016A
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- frit
- stationary liquid
- clad plate
- bubble rate
- working method
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Abstract
The invention discloses a production method for reducing a bubble rate of a glass ceramics composite plate. The method comprises the following steps: 1) spreading glaze on adobes; 2) printing in accordance with pre-designed patterns; 3) firing the printing for the first time so that the patterns are fixed on the adobes; 4) sprinkling mixing frits and stationary liquid; 5) firing for the second time; and 6) performing post-processing, wherein the mixing frits is a mixture of high-temperature frits and low-temperature frits, and fusion temperature of frit levelling of the high-temperature frits and the low-temperature frits differs 10 to 150 DEG C; and the stationary liquid is a mixture containing optionally one or two or more of a carbonate solution, a sulfate solution, an acetate solution or a chloride solution which contain alkali metal or alkaline earth metal, and the dissolvability ratio of the metallic compound to the water is 1 : (20 to 800) in the stationary liquid. The method can effectively resolve problems of glass ceramics composite plate defects caused by the bubbles due to sprinkling the mixing frits and the stationary liquid onto the adobes, and can integrally improve production quality and product texture of the glass ceramics composite plate.
Description
Technical field
The present invention relates to ceramic plate manufacturing technology field, relate in particular to a kind of working method that reduces the glass-ceramic clad plate bubble rate.
Background technology
Glass-ceramic clad plate is also claimed compound microlite, and compound microlite is the NEW TYPE OF COMPOSITE sheet material that sytull is compounded in the about 3-5mm of ceramics vitrified brick upper layer, forms through double sintering, and glass-ceramic clad plate thickness is at 13-18mm, glossiness＞95.Glass-ceramic clad plate is the new high-tech product in the present architectural pottery field; It has glittering and translucent, elegant and poised, self-sow and changes unusual imitative bag reason, painted exterior decorative effect; And not contaminated, be easy to clean, inherent good physical and chemical performance; In addition, also have the weather proofing stronger, weathering resistance, thereby receive the favor of high-end building materials market than stone material.
At present, the working method of glass-ceramic clad plate is: sprinkle clear frit in the glaze adobe after carrying out biscuiting, this clear frit is a kind of frit of single prescription, forms transparent glass layer behind the sintering levelling.In this transparent glass layer, always have bubble more or less, after polishing, the brick face can produce either large or small pin hole, and in the middle of perhaps bubble can be present in or frit layer bottom has a strong impact on the attractive in appearance and antifouling property of product.After the follow-up spray stationary liquid and the adjustment of burning till,, do not eliminate the air bubble problem influence with antifouling property attractive in appearance fully to microlite though air bubble problem is had improvement to a certain extent.
This shows how in the frit sintering process, to get rid of bubble, is the present technical issues that need to address in this area.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of working method that reduces the glass-ceramic clad plate bubble rate, reduce the pin hole and the bubble of the product that obtains.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of working method that reduces the glass-ceramic clad plate bubble rate comprises the steps:
1) spills glaze on the adobe upper berth;
2) carry out stamp according to designed patterns in advance;
3) decalcomania is carried out once-firing, be fixed in the adobe;
4) remove mixed frit and stationary liquid then;
5) carry out twice firing again;
6) carry out aftertreatment then;
Wherein, said mixed frit is the mixture of high temperature frit and low temperature frit, and the frit levelling fusion temperature of high temperature frit and low temperature frit differs 10 ℃～150 ℃; Said stationary liquid is any kind or the two or more mixture in carbonate solution, sulfate liquor, acetate solution or the chloride soln that contains basic metal or earth alkali metal, and in the stationary liquid, metallic compound is 1 with the solubility ratio of water: (20～800).
Preferably, the frit levelling fusion temperature of said high temperature frit and low temperature frit differs 20 ℃～130 ℃.
Preferably, the mass ratio of said high temperature frit and low temperature frit is 1: 1～10: 1.
Preferably, the mass ratio of said high temperature frit and low temperature frit is 2: 1～8: 1.
Preferably, the mass ratio of said high temperature frit and low temperature frit is 3: 1～7: 1.
Preferably, in the stationary liquid, metallic compound is 1 with the solubility ratio of water: (30～600).
Preferably, in the stationary liquid, metallic compound is 1 with the solubility ratio of water: (100～400).
Preferably, said stationary liquid is the mixture of carbonate solution, sulfate liquor, acetate solution, chloride soln.
Preferably, said stationary liquid is the mixture of carbonate solution, sulfate liquor, acetate solution.
Preferably, said stationary liquid is the mixture of carbonate solution, acetate solution.
Compared with prior art; The working method of reduction glass-ceramic clad plate bubble rate of the present invention, owing in adobe, sprinkle mixed frit and stationary liquid, mixed frit comprises high temperature frit and low temperature frit; In sintering process; Because the levelling fusion temperature of high temperature frit and low temperature frit is different, has played the effect in filler particles gap mutually, thereby has greatly reduced bubble rate; Effectively solve the microlite defective that causes because of air bubble problem, the whole quality of microlite production and the texture of product of improving; Simultaneously; Owing to spread stationary liquid simultaneously, this fixedly fluid power in frit sintering, levelling process, produces promote row's bubble or or the compacting row effect of steeping, make after burning till, polishing; The glass-ceramic clad plate surface free of pinholes that obtains; And the visual no bubble of frit layer, product is more attractive in appearance, and antifouling property improves greatly.
Embodiment
In order to make those skilled in the art understand technical scheme of the present invention better, the present invention is described in further detail below by specific embodiment.
The working method of reduction glass-ceramic clad plate bubble rate of the present invention comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, once-firing
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit in the adobe after burning till, the mixed frit here mainly is meant the transparent glass frit;
5, twice firing
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit is high temperature frit and low temperature frit, can adopt two or more frit to mix.The raw material type of high temperature frit and low temperature frit is approaching, and just the refractory raw material proportion is different, causes frit levelling fusion temperature different.As far as frit levelling fusion temperature, the high temperature frit is higher than the mixture of high temperature frit and low temperature frit, and low temperature frit is lower than the mixture of high temperature frit and low temperature frit.Comprise standard industrial chemicals (also can be converted to oxide compound representes) such as quartz, lime carbonate, soda ash, zinc oxide, aluminum oxide, boric acid, barium carbonate in the frit admixtion prescription; Proportioning through the adjustment different material just can be regulated frit levelling fusion temperature, makes it to become high temperature frit or low temperature frit.Oxide compound comprises in the frit admixtion prescription: SiO
2, Al
2O
3, CaO, MgO, Na
2O, K
2O, Li
2O, B
2O
3, ZnO etc., wherein, SiO
2, Al
2O
3Be the high-temperature flame-proof component, promptly these two kinds of materials relative content in prescription is high more, and the frit glass melting temperature is high more, and it is high more that the finished product frit burns till the levelling fusion temperature, is the high temperature frit.CaO, MgO, Na
2O, K
2O, Li
2O etc. are the low temperature component of fluxing, and its relative content is high more, and the frit glass melting temperature is low more, and it is low more that the finished product frit burns till the levelling fusion temperature, i.e. low temperature frit.Traditional testing program all is to design around single frit prescription, single sintering curve, adopts mixed frit test difficulty big, and the control difficulty is also big, but greatly reduces finished product microlite microcrystalline coating bubble rate.
Wherein, stationary liquid is any one or the two or more mixture in carbonate solution, sulfate liquor, acetate solution or the chloride soln that contains basic metal or earth alkali metal, and metallic compound is 1 with the solubility ratio of water in the stationary liquid: (20～800).
When stationary liquid was mixture, the ratio of each metallic compound can be any ratio.
Stationary liquid among the present invention, the fusing point of its MOX should be far above the levelling temperature of frit itself.
The present invention is through selecting suitable metallic compound as the stationary liquid composition; And through suitable stationary liquid solubility is set; Make in frit sintering, levelling process, to produce and promote row's bubble or the perhaps effect of compacting row bubble; If stationary liquid solubility overrich can have a strong impact on the frit performance, obtain opposite result; If too rare, then do not have due effect.
Time burn till among the present invention, the temperature of twice firing, equipment used etc. can select technology of the prior art for use, repeat no more here.
Embodiment one
The working method of the reduction glass-ceramic clad plate bubble rate in the present embodiment comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, burn till
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit in the adobe after burning till, the frit here mainly is meant the transparent glass frit;
5, burn till
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit comprises high temperature frit and low temperature frit, high temperature frit and low temperature frit mass ratio be 1: 1.
Wherein, the high temperature frit is processed by following materials in weight portion:: SiO
2: 68 parts, Al
2O
3: 12 parts, CaO:6 part, Na
2O, K
2O, Li
26 parts of O sums, B
2O
3: 3 parts, 5 parts of other acceptable materials;
Wherein, low temperature frit is processed by following materials in weight portion: SiO
2: 58 parts, Al
2O
3: 9 parts, CaO:3 part, Na
2O, K
2O, Li
210 parts of O sums, B
2O
3: 5 parts, 15 parts of other acceptable materials;
Wherein, stationary liquid is a sodium carbonate solution, and in the stationary liquid, yellow soda ash is 1: 20 with the solubility ratio of water.
In the present embodiment, stationary liquid is a sodium carbonate solution, in actual implementation process, also can adopt calcium carbonate soln or magnesiumcarbonate solution or solution of potassium carbonate.
Embodiment two
The working method of the reduction glass-ceramic clad plate bubble rate in the present embodiment comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, burn till
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit in the adobe after burning till, the mixed frit here mainly is meant the transparent glass frit;
5, burn till
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit is the mixture of high temperature frit and low temperature frit, and the weight ratio of high temperature frit and low temperature frit is 1: 2.
Wherein, the high temperature frit is processed by following materials in weight portion: SiO
2: 65 parts, Al
2O
3: 18 parts, CaO:3 part, Na
2O, K
2O, Li
24 parts of O sums, ZnO:2 part, B
2O
3: 5 parts, 3 parts of other acceptable materials.
Wherein, low temperature frit is processed by following materials in weight portion: SiO
2: 62 parts, Al
2O
3: 2 parts, CaO:5 part, MgO:6 part, Na
2O, K
2O, Li
27 parts of O sums, B
2O
3: 10 parts, other 8 parts.
Wherein, stationary liquid is an Adlerika, and in the stationary liquid, sal epsom is 1: 100 with the solubility ratio of water.
In the present embodiment, fixedly the liquid level Adlerika in actual implementation process, also can adopt calcium sulphate soln or metabisulfite solution or potassium sulfate solution.
Embodiment three
The working method of the reduction glass-ceramic clad plate bubble rate in the present embodiment comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, burn till
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit in the adobe after burning till, the frit here mainly is meant the transparent glass frit;
5, burn till
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit is the mixture of high temperature frit and low temperature frit, and the weight ratio of high temperature frit and low temperature frit is 2: 1.
Wherein, the high temperature frit is processed by following materials in weight portion: SiO
2: 59 parts, Al
2O
3: 30 parts, CaO:1 part, Na
2O, K
2O, Li
23 parts of O sums, ZnO:2 part, B
2O
3: 3 parts, 2 parts of other acceptable materials.
Wherein, low temperature frit is processed by following materials in weight portion: SiO
2: 55 parts, Al
2O
3: 3 parts, CaO:6 part, MgO:15 part, Na
2O, K
2O, Li
29 parts of O sums, B
2O
3: 8 parts, other 4 parts.
Wherein, stationary liquid is a sodium acetate soln, and in the stationary liquid, sodium-acetate is 1: 300 with the solubility ratio of water.
In the present embodiment, stationary liquid is a sodium acetate soln, in actual implementation process, also can adopt calcium acetate solution or magnesium acetate solution or liquor kalii acetici; Perhaps also can adopt chloride soln, concrete as: magnesium chloride solution or sodium chloride solution or Klorvess Liquid or calcium chloride solution.
Embodiment four
The working method of the reduction glass-ceramic clad plate bubble rate in the present embodiment comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, burn till
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit and stationary liquid in the adobe after burning till, the frit here mainly is meant the transparent glass frit;
5, burn till
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit is the mixture of high temperature frit and low temperature frit, and the weight ratio of high temperature frit and low temperature frit is 3: 2.
Wherein, the high temperature frit is processed by following materials in weight portion: SiO
2: 60 parts, Al
2O
3: 10 parts, CaO:8 part, Na
2O, K
2O, Li
29 parts of O sums, ZnO:3 part, B
2O
3: 4 parts, 6 parts of other acceptable materials.
Wherein, low temperature frit is processed by following materials in weight portion: SiO
2: 52 parts, Al
2O
3: 2 parts, CaO:12 part, MgO:18 part, Na
2O, K
2O, Li
26 parts of O sums, B
2O
3: 6 parts, other 4 parts.
Wherein, stationary liquid is the mixing solutions of lime carbonate and magnesium acetate, and in the stationary liquid, these two kinds of metallic compounds of lime carbonate and magnesium acetate are 1: 600 with the solubility ratio of water.Wherein, the weight ratio of lime carbonate and magnesium acetate is 1: 3.
Embodiment five
The working method of the reduction glass-ceramic clad plate bubble rate in the present embodiment comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, burn till
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit in the adobe after burning till, the mixed frit here mainly is meant the transparent glass frit;
5, burn till
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit is the mixture of high temperature frit and low temperature frit, and the weight ratio of high temperature frit and low temperature frit is 4: 5.
Wherein, the high temperature frit is processed by following materials in weight portion: SiO
2: 70 parts, Al
2O
3: 16 parts, CaO:3 part, Na
2O, K
2O, Li
23 parts of O sums, ZnO:3 part, B
2O
3: 4 parts, 1 part of other acceptable material.
Wherein, low temperature frit is processed by following materials in weight portion: SiO
2: 49 parts, Al
2O
3: 5 parts, CaO:16 part, MgO:13 part, Na
2O, K
2O, Li
27 parts of O sums, B
2O
3: 4 parts, other 6 parts.
Wherein, stationary liquid is the mixing solutions of magnesiumcarbonate, sodium-acetate, calcium sulfate, and in the stationary liquid, magnesiumcarbonate, sodium-acetate, these three kinds of metallic compounds of calcium sulfate are 1: 450 with the solubility ratio of water.Wherein, the weight ratio of magnesiumcarbonate, sodium-acetate, calcium sulfate is 3: 2: 5.
Embodiment six
The working method of the reduction glass-ceramic clad plate bubble rate in the present embodiment comprises the steps:
1, glazing
In adobe, glaze is spilt in the shop;
2, stamp
After the glazing is exactly stamp, prints according to pre-designed decalcomania to get final product;
3, burn till
Stamp need burn till decalcomania afterwards, burns till to be fixed in the adobe;
4, sprinkle mixed frit and stationary liquid
Spill mixed frit in the adobe after burning till, the mixed frit here mainly is meant the transparent glass frit;
5, burn till
Burning till of this step is with the fusing of transparent glass frit, is uniformly distributed in the adobe, carries out twice firing.
6, polishing, polishing, side cut
This step is a post-processing step;
Wherein, mixed frit is the mixture of high temperature frit and low temperature frit, and the weight ratio of high temperature frit and low temperature frit is 6: 5.
Wherein, the high temperature frit is processed by following materials in weight portion: SiO
2: 70 parts, Al
2O
3: 12 parts, CaO:7 part, Na
2O, K
2O, Li
25 parts of O sums, ZnO:3 part, B
2O
3: 2 parts, 1 part of other acceptable material.
Wherein, low temperature frit is processed by following materials in weight portion: SiO
2: 53 parts, Al
2O
3: 7 parts, CaO:14 part, MgO:19 part, Na
2O, K
2O, Li
23 parts of O sums, B
2O
3: 3 parts, other 1 part.
Wherein, stationary liquid is the mixing solutions of magnesiumcarbonate, Potassium ethanoate, calcium sulfate, magnesium chloride, and in the stationary liquid, these four kinds of metallic compounds are 1: 800 with the solubility ratio of water.The mass ratio of magnesiumcarbonate, Potassium ethanoate, calcium sulfate, magnesium chloride is 1: 3: 4: 5.
Glass-ceramic clad plate to the working method by embodiment one～embodiment six obtains is observed, and simultaneously certain commercially available glass-ceramic clad plate is carried out the observation and the detection of same project, and the result is following:
| Sequence number | The surface | Frit layer | Antifouling property |
| Embodiment one | Visual free of pinholes | Visual no bubble | Pyatyi |
| Embodiment two | Visual free of pinholes | Visual no bubble | Pyatyi |
| Embodiment three | Visual free of pinholes | Visual no bubble | Pyatyi |
| Embodiment four | Visual free of pinholes | Visual no bubble | Pyatyi |
| Embodiment five | Visual free of pinholes | Visual no bubble | Pyatyi |
| Embodiment six | Visual free of pinholes | Visual no bubble | Pyatyi |
| Reference examples | Visual have a small amount of pin hole | Visual have a small amount of bubble | Three grades |
More than the present invention has been carried out detailed introduction, use concrete example in the literary composition principle of the present invention and embodiment set forth, the explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.
Claims (10)
1. a working method that reduces the glass-ceramic clad plate bubble rate is characterized in that, comprises the steps:
1) spills glaze on the adobe upper berth;
2) carry out stamp according to designed patterns in advance;
3) decalcomania is carried out once-firing, be fixed in the adobe;
4) remove mixed frit and stationary liquid then;
5) carry out twice firing again;
6) carry out aftertreatment then;
Wherein, said mixed frit is the mixture of high temperature frit and low temperature frit, and the frit levelling fusion temperature of high temperature frit and low temperature frit differs 10 ℃～150 ℃; Said stationary liquid is any one or the two or more mixture in carbonate solution, sulfate liquor, acetate solution or the chloride soln that contains basic metal or earth alkali metal, and in the stationary liquid, metallic compound is 1 with the solubility ratio of water: (20～800).
2. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, the frit levelling fusion temperature of said high temperature frit and low temperature frit differs 20 ℃～130 ℃.
3. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, the mass ratio of said high temperature frit and low temperature frit is 1: 1～10: 1.
4. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, the mass ratio of said high temperature frit and low temperature frit is 2: 1～8: 1.
5. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, the mass ratio of said high temperature frit and low temperature frit is 3: 1～7: 1.
6. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, in the stationary liquid, metallic compound is 1 with the solubility ratio of water: (30～600).
7. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, in the stationary liquid, metallic compound is 1 with the solubility ratio of water: (100～400).
8. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, said stationary liquid is the mixture of carbonate solution, sulfate liquor, acetate solution, chloride soln.
9. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, said stationary liquid is the mixture of carbonate solution, sulfate liquor, acetate solution.
10. the working method of reduction glass-ceramic clad plate bubble rate as claimed in claim 1 is characterized in that, said stationary liquid is the mixture of carbonate solution, acetate solution.
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| CN2012102235873A CN102746016A (en) | 2012-06-29 | 2012-06-29 | Production method for reducing bubble rate of glass ceramics composite plate |
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| CN109133894A (en) * | 2018-10-31 | 2019-01-04 | 广东博德精工建材有限公司 | A kind of hard jade brick green body and preparation method thereof |
| CN111333328A (en) * | 2020-05-21 | 2020-06-26 | 佛山市东鹏陶瓷发展有限公司 | High-wear-resistance glaze material with polished glaze and preparation method thereof |
| CN113415995A (en) * | 2021-07-14 | 2021-09-21 | 佛山东鹏洁具股份有限公司 | FFC ceramic, antibacterial easy-to-clean glaze thereof, preparation method and application |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109133894A (en) * | 2018-10-31 | 2019-01-04 | 广东博德精工建材有限公司 | A kind of hard jade brick green body and preparation method thereof |
| CN109133894B (en) * | 2018-10-31 | 2021-08-03 | 广东博德精工建材有限公司 | Hard jade brick blank and manufacturing method thereof |
| CN111333328A (en) * | 2020-05-21 | 2020-06-26 | 佛山市东鹏陶瓷发展有限公司 | High-wear-resistance glaze material with polished glaze and preparation method thereof |
| CN111333328B (en) * | 2020-05-21 | 2020-09-29 | 佛山市东鹏陶瓷发展有限公司 | High-wear-resistance glaze material with polished glaze and preparation method thereof |
| CN113415995A (en) * | 2021-07-14 | 2021-09-21 | 佛山东鹏洁具股份有限公司 | FFC ceramic, antibacterial easy-to-clean glaze thereof, preparation method and application |
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Application publication date: 20121024 |