CN103435369B - Method for manufacturing wear-resistant antiskid dry-particle ceramic tile - Google Patents

Method for manufacturing wear-resistant antiskid dry-particle ceramic tile Download PDF

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Publication number
CN103435369B
CN103435369B CN201310349396.6A CN201310349396A CN103435369B CN 103435369 B CN103435369 B CN 103435369B CN 201310349396 A CN201310349396 A CN 201310349396A CN 103435369 B CN103435369 B CN 103435369B
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dry
wear
particle
dry granular
resistant
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CN201310349396.6A
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Chinese (zh)
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CN103435369A (en
Inventor
黄建平
王永强
陈志川
肖惠银
王彦君
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东莞市唯美陶瓷工业园有限公司
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Abstract

The invention relates to a method for manufacturing a wear-resistant antiskid dry-particle ceramic tile, which comprises the following steps: (1) forming a ceramic tile plane matrix and carrying out pattern decoration; (2) preparing dry particles with wear-resistant and antiskid properties; (3) mixing the wear-resistant antiskid dry particles, flashing dry particles and transparent dry particles according to a certain proportion for distribution; (4) applying the mixed dry particles to the surface of a decorative glazed body and spraying a temperature-resistant fixing agent; (5) conveying the obtained product to a roller kiln for firing and preparing the finished product of the ceramic tile through subsequent processes. According to the method for manufacturing the wear-resistant antiskid dry particle ceramic tile, the dry particles with good wear resistance are mixed with the transparent dry particles and the flashing dry particles, a dry powder distribution mode is adopted and the wear-resistant antiskid dry particles are bulged due to different melting performance of various dry particles in the firing process, so that the problems of wear resistance of the surface and thickness of a wear-resistant layer are solved; by distributing the transparent dry particles, a decorative pattern has a stereoscopic decorating effect under the covering of a glass layer, so that unification of wear-resistant and antiskid properties and decoration of the ceramic tile is achieved.

Description

The manufacture method of wear-resistant antiskid dry-particle ceramic tile
Technical field
The present invention relates to the manufacture method of the wear-resistant antiskid dry-particle ceramic tile of a kind of dry granular decoration.
Background technology
The surface abrasion resistance anti-skid of ceramic tile more and more causes the concern of society and human consumer, and the research of its wear-resisting antiskid has become one of major subjects of ceramic industry scientific and technical innovation.
CN201110359646.5 discloses one " anti-skidding screen printing glaze and manufacture method and application " thereof, and the anti-skidding screen printing glaze of this invention, is before entering kiln, increase by one silk screen printing at non-gloss firing face brick, then fires, to improve wear-resisting antiskid performance.Though its technique is simple, weak point is, the finite thickness that silk screen printing produces, and is difficult to stand long wearing and tearing; In addition, particularly when anti-skidding glaze layer thickness increases, the transparency of glaze layer reduces, and will affect the decorative effect of pattern.
CN200620155231.0 discloses " a kind of Antiskid ceramic polished brick ", the surface of this adobe body basic unit is provided with the anti-slip material surface layer be made up of anti-slip material, the contact surface of adobe body basic unit and surface layer is rough degree of depth anti-skid structure, have employed the multi-layer compound structure of multiple processing mode, the weak point of this technology is, its non-skid finish needs the post-production of finished bricks to realize.
Summary of the invention
The object of this invention is to provide a kind of research of being filled a prescription by wear resistance, prepare a kind of dry granular with better wear resistance, mix with transparent dry granular, the dry granular that glistens, by the form of Dry powder material distribution, and at sintering procedure because the melting behaviour of various dry granular is different, make wear-resistant antiskid dry-particle protruding, solve surface abrasion resistance and wearing layer thickness problem; By the cloth of transparent dry granular, make decorative pattern under the covering of glass coating, there is three-dimensional decorative effect, realize the wear-resisting antiskid of ceramic tile and the manufacture method of ornamental unified wear-resistant antiskid dry-particle ceramic tile.
Technical solution of the present invention is the manufacture method of described wear-resistant antiskid dry-particle ceramic tile, and its special character is, comprises following operation:
(1) forming ceramic brick planar substrates, carries out pattern decorative;
(2) preparation has the dry granular of wear-resisting antiskid performance;
(3) by proportioning mixing wear-resistant antiskid dry-particle, flash of light dry granular, transparent dry granular, for cloth;
(4) mixing dry granular cloth is imposed on the surface of decoration glazed body, spray heatproof fixing agent;
(5) be delivered to roller kiln to burn till, through following process, make ceramic tile finished product.
As preferably: (2) described operation comprises following operation further:
(2.1) to add water preparing burden wet-milling into ball mill by the formula of wear-resistant antiskid dry-particle, slip spraying dry being made powder particle, between particle diameter 0.12mm ~ 0.40mm;
(2.2) be contained in saggar by powder particle, send in kiln and calcine, firing temperature is 900 DEG C ~ 1100 DEG C, and the cycle is 120 minutes;
(2.3) sieved by ripe powder particle, preparing particle diameter is that particle between 0.13mm ~ 0.35mm is for subsequent use.
As preferably: described operation wear-resisting antiskid performance dry granular (2), composed as follows by weight percentage:
Nano-corundum 0% ~ 8% silicate flux raw material 70% ~ 88%
Clay-type substance 10% ~ 22% polishing slag 0% ~ 10%
As preferably: described operation mixing dry granular (3), it is composed as follows by weight percentage:
Wear-resistant antiskid dry-particle 10% ~ 25% transparent dry granular 70% ~ 88% flash of light dry granular 2% ~ 5%.
As preferably: described operation transparent dry granular (3), by weight percentage, said composition is made up of following component:
Wherein, the melt temperature of described transparent dry granular is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm.
As preferably: described operation flash of light dry granular (3), by weight percentage, said composition is made up of following component:
Sheet mica 65% glistens clipped wire 35%
Wherein, the melt temperature of described flash of light dry granular is 1100 DEG C ~ 1180 DEG C, and median size is 0.08mm ~ 0.18mm, for making the flashing ornaments effect of product surface.
As preferably: (4) described operation comprises further: the mixing dry granular prepared is adopted dry granular distributor, dry granular is evenly distributed in the surface of adobe patterned layer, and heatproof fixing agent is sprayed make it fixing in the surface of dry granule layer, cloth doses adjusts according to the rotating speed of distributor and the gait of march of adobe.
As preferably: described operation heatproof fixing agent (4), by weight percentage, said composition is made up of following component:
Carboxymethyl cellulose 2% water-based stamp-pad ink 10% polyvinyl alcohol 1%
Ball clay 3% glue 84%
As preferably: the firing temperature of described operation (5) roller kiln is 1160 DEG C ~ 1230 DEG C, firing period 60 ~ 80 minutes; The control of temperature should ensure to combine together at sintering process dry granular and adobe, and wear-resistant antiskid dry-particle has relief.
As preferably: (5) described operation comprises further carries out edging to going out kiln-made product, makes the wear-resisting antiskid ceramic tile that surface has protruding particle; Also can carry out semipolish to its surface, protruding particle be glittered, has more ornamental.
Compared with prior art, advantage of the present invention
(1) formula, the proportioning of wear-resistant antiskid dry-particle, refer to nano-corundum and the higher raw material such as kaolin, ball clay of alumina content, the introducing of these raw materials adds dry granule layer and burns till the mullite content being at high temperature, thus improve surface hardness and the wear resisting property of goods, simultaneously due to the relief of wear-resisting dry granular, improve the surface anti-skidding performance of goods.
(2) this preparation method is by the higher preparation of raw material of multiple alumina content, prepare mud, the operation such as spraying dry, powder burn till, realize the preparation of wear-resistant antiskid dry-particle, being a little of this technology: it has evaded high-temperature fusion, the technique of getting and preparing dry granular of quenching, need to introduce a large amount of flux raw material, the increase of glass ingredient and cause the reduction of wear resistance.
(3) the present invention is also by the mixing of wear-resistant antiskid dry-particle, flash of light dry granular, transparent dry granular, and being prepared into can for the mixing dry granular of cloth, and the combination of this dry granular has taken into account the decorative effect of wear-resisting antiskid, transparent dry granular and flash of light dry granular.
(4) fine particle clay introduced by heatproof fixing agent of the present invention in formula, for the simple fixing agent be made up of organic compound, can make the low temperature of cloth dry granular after entering roller kiln and middle thermophase fixed effect better, avoid organic volatilization period and the dry granular caused is loose, the introducing of clay compensate for the fixed effect of fixing agent in this stage, makes dry granular meet the needs of function and decorative effect.
(5) the firing temperature 1160 DEG C ~ 1250 DEG C of roller kiln of the present invention, firing period 60 ~ 80 minutes, be by the control to calcining system, realization has surface abrasion resistance particle projection, has transparent glass layer to cover, and has the wear-resisting antiskid ceramic tile goods of flash effect.
The surface of this wear-resisting antiskid ceramic tile product and lithotome similar, have protruding particle, have the claimed flare pellet of similar mica etc., more approach the true stone effect of lithotome, its surface anti-skidding, wear-resisting, have higher ornamental.Quality product meets national standard, and radioactivity is low, and meet the requirement of category-A decorating and renovating material, use occasion is unrestricted.
(7) wear-resisting antiskid ceramic tile product of the present invention can also pass through following process, carries out semipolish to the surface of these goods, obtains a kind of wear-resistant ceramic brick with starbright, and its wear resistance is given prominence to, and decorative effect is better.
(8) present invention employs ceramics factory's waste materials such as polishing slag, have larger meaning to the energy-saving and emission-reduction of Production of Ceramics.
Accompanying drawing explanation
Fig. 1 is the technological process of production schematic diagram of wear-resistant antiskid dry-particle ceramic tile of the present invention.
Fig. 2 to Fig. 4 is that dry granular skid-resistance ceramic tile product of the present invention is exempted to throw and half to be thrown, structural representation after polishing.
Embodiment
The present invention is further detailed in conjunction with the accompanying drawings below:
[embodiment 1]
Refer to shown in accompanying drawing 1, in the present embodiment, the manufacture method of described wear-resistant antiskid dry-particle ceramic tile, comprises following operation:
(1) forming ceramic brick planar substrates, carries out pattern decorative;
(2) preparation has the dry granular of wear-resisting antiskid performance;
(2.1) to add water preparing burden wet-milling into ball mill by the formula of wear-resistant antiskid dry-particle, slip spraying dry being made powder particle, between particle diameter 0.12mm ~ 0.40mm;
(2.2) be contained in saggar by powder particle, send in kiln and calcine, firing temperature is 900 DEG C ~ 1100 DEG C, and the cycle is 120 minutes;
(2.3) sieved by ripe powder particle, preparing particle diameter is that particle between 0.13mm ~ 0.35mm is for subsequent use;
(3) by proportioning mixing wear-resistant antiskid dry-particle, flash of light dry granular, transparent dry granular, for cloth;
(3.1) select transparent dry granular, flash of light dry granular by the meltbility of product decoration and dry granular, the coefficient of expansion, and store classifiedly for subsequent use;
(3.2) by the formula of mixing dry granular, wear-resisting dry granular, transparent dry granular and flash of light dry granular are mixed;
(4) mixing dry granular cloth is imposed on the surface of decoration glazed body, spray heatproof fixing agent;
(4.1) to spraying fixing agent, for having good combination with cloth dry granule layer by the surface of the ceramic adobe of decoration;
(4.2) mixing dry granular is imposed on the surface of decorative blank by the uniform cloth of distributor, according to the cloth total amount of the different choice 0.10 ㎏/㎡ ~ 0.30 ㎏/㎡ of product performance and following process mode;
(4.3) heatproof fixing agent is sprayed dry granule layer surface, dry granule layer is fixed, and prevent dry granular displacement in conveying and the pre-heating stage after entering roller kiln and fly away;
(5) be delivered to roller kiln to burn till, through following process, make ceramic tile finished product.
(5.1) firing temperature of described wear-resistant ceramic brick is 1160 DEG C ~ 1230 DEG C, firing period 60 ~ 80 minutes; The control of temperature is that dry granular and adobe are fully merged, wear-resistant antiskid dry-particle slight convex, to ensure its wear-resisting, non-skid property.
(5.2) carry out edging process and make to going out kiln-made product the wear-resisting antiskid ceramic tile that surface has protruding particle;
(5.3) carry out edging to going out kiln-made product and partly throw process, making surface and there is protruding particle effect and the wear-resistant ceramic brick of some point flash of light;
(5.4) carrying out edging and polished finish to going out kiln-made product, making smooth surface, but include the wear-resistant ceramic brick of abrasion resistant particles.
(6) be delivered to roller kiln described in burn till, through following process, make ceramic tile finished product;
Wherein, the proportioning of the mixing dry granular of described wear-resistant antiskid dry-particle ceramic tile consists of:
Transparent dry granular 83% glistens dry granular 5% wear-resistant antiskid dry-particle 12%.
Described operation wear-resisting antiskid performance dry granular (2), it is composed as follows by weight percentage:
Nano-corundum 8% ball clay 12%
The cubic albite 32% of ultrawhite kaolin 6%
Ultrawhite potassium sodium stone flour 32% polishing slag 10%
Described operation transparent dry granular (3), meets adjustment dry granule layer and the coefficient of expansion of base and the needs of melt temperature; Its melt temperature is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm; By weight percentage, said composition is made up of following component:
BaO???3.5～4.5%??CaO??10～12%????Al 2O 3??18.5～20.5%
Na 2O??2.5～3.5%??K 2O??3.5～4.5%??SiO 2???50～55%
ZnO???2.5～3%????MgO??0.5～2%????B 2O 3???0.5～1.5%
Described operation flash of light dry granular (3), by weight percentage, said composition is made up of following component:
Sheet mica 65% glistens clipped wire 35%
The melt temperature of described flash of light dry granular is 1100 DEG C ~ 1180 DEG C, and median size is 0.08mm ~ 0.18mm, for making the flashing ornaments effect of product surface.
Described operation heatproof fixing agent (4), by weight percentage, said composition is made up of following component:
Carboxymethyl cellulose 2% water-based stamp-pad ink 10%
Polyvinyl alcohol 1% ball clay 3%
Glue 84%.
[embodiment 2]
Shown in accompanying drawings 1, in the present embodiment, the manufacture method of described wear-resistant antiskid dry-particle ceramic tile, comprises following operation:
(1) forming ceramic brick planar substrates, carries out pattern decorative;
(2) preparation has the dry granular of wear-resisting antiskid performance;
(2.1) to add water preparing burden wet-milling into ball mill by the formula of wear-resistant antiskid dry-particle, slip spraying dry being made powder particle, between particle diameter 0.12mm ~ 0.40mm;
(2.2) be contained in saggar by powder particle, send in kiln and calcine, firing temperature is 900 DEG C ~ 1100 DEG C, and the cycle is 120 minutes;
(2.3) being sieved by powder particle as getting particle diameter is that particle between 0.13mm ~ 0.35mm is for subsequent use
(3) by proportioning mixing wear-resistant antiskid dry-particle, flash of light dry granular, transparent dry granular, for cloth;
(3.1) dry granular is selected to store classifiedly for subsequent use by product requirement;
(3.2) powder is crossed screen sizing, the dry granular material of obtained 0.13mm ~ 0.35mm part particle diameter;
(3.3) by recipe requirements, various dry granular is mixed, for the preparation of the mixing dry granular of cloth;
(4) mixing dry granular cloth is imposed on the surface of decoration glazed body, spray heatproof fixing agent;
(4.1) to spraying fixing agent, for being combined preferably with cloth dry granular by the surface of the ceramic adobe of decoration;
(4.2) mixing dry granular is imposed on the surface of decorative blank by the uniform cloth of distributor, according to the cloth total amount of the different choice 0.10 ㎏/㎡ ~ 0.30 ㎏/㎡ of product performance and following process mode;
(4.3) heatproof fixing agent is sprayed dry granule layer surface, dry granule layer is fixed, and prevent dry granular displacement in conveying and the pre-heating stage after entering roller kiln and fly away;
(5) be delivered to roller kiln to burn till, through following process, make ceramic tile finished product;
(5.1) firing temperature of described wear-resistant ceramic brick is 1160 DEG C ~ 1230 DEG C, firing period 60 ~ 80 minutes; The control of temperature is that dry granular and adobe are fully merged, and wear-resistant antiskid dry-particle has slight convex effect, to ensure its wear-resisting, non-skid property;
(5.2) the soft polishing of profiling is carried out to going out kiln-made product bossing surface, polishing machine adopts the various combinations such as diamond, silicon carbide, Elastic abrasive body to process, obtain surperficial starbright, glossiness is that the wear-resisting antiskid half of 18 ~ 40 degree throws ceramic tile product, its wear-resisting antiskid didirtresistance is taken into account, and decorative effect is closer to natural sandstone effect.
Wherein, the proportioning of the mixing dry granular of described wear-resistant antiskid dry-particle ceramic tile consists of:
Transparent dry granular 77% glistens dry granular 5% wear-resistant antiskid dry-particle 18%.
Described operation wear-resisting antiskid performance dry granular (2), it is composed as follows by weight percentage:
Polishing slag 10% nano-corundum 8%
Four directions albite 32% ultrawhite kaolin 6%
Ball clay 12% ultrawhite potassium sodium stone flour 32%
Described operation transparent dry granular (3), meets adjustment dry granule layer and the coefficient of expansion of base and the needs of melt temperature; Its melt temperature is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm; By weight percentage, said composition is made up of following component:
BaO???3.5～4.5%??CaO??10～12%????Al 2O 3??18.5～20.5%
Na 2O??2.5～3.5%??K 2O??3.5～4.5%??SiO 2???50～55%
ZnO???2.5～3%????MgO??0.5～2%????B 2O 3???0.5～1.5%
Wherein, the melt temperature of described transparent dry granular is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm;
Described operation flash of light dry granular (3), by weight percentage, said composition is made up of following component:
Sheet mica 65% glistens clipped wire 35%
Wherein, the melt temperature of described flash of light dry granular is 1100 DEG C ~ 1180 DEG C, and median size is 0.08mm ~ 0.18mm, for making the flashing ornaments effect of product surface
Described operation heatproof fixing agent (4), by weight percentage, said composition is made up of following component:
Carboxymethyl cellulose 2% water-based stamp-pad ink 10% polyvinyl alcohol 1%
Ball clay 4% glue 83%.
[embodiment 3]
Shown in accompanying drawings 1, in the present embodiment, refer to shown in accompanying drawing 1, in the present embodiment, the manufacture method of described wear-resistant antiskid dry-particle ceramic tile, comprises following operation:
(1) forming ceramic brick planar substrates, carries out pattern decorative;
(2) preparation has the dry granular of wear-resisting antiskid performance;
(2.1) to add water preparing burden wet-milling into ball mill by the formula of wear-resistant antiskid dry-particle, slip spraying dry being made powder particle, between particle diameter 0.12mm ~ 0.40mm;
(2.2) be contained in saggar by powder particle, send in kiln and calcine, firing temperature is 900 DEG C ~ 1100 DEG C, and the cycle is 120 minutes;
(2.3) being sieved by powder particle as getting particle diameter is that particle between 0.13mm ~ 0.35mm is for subsequent use
(3) by proportioning mixing wear-resistant antiskid dry-particle, flash of light dry granular, transparent dry granular, for cloth;
(3.1) dry granular is selected to store classifiedly for subsequent use by product requirement;
(3.1.1) to add water preparing burden ball milling into ball mill by formula, through deironing, sieve after slip spraying dry is made powder particle, between particle diameter 0.12mm ~ 0.40mm;
(3.1.2) powder is contained in biscuiting in shuttle kiln in saggar, firing temperature is 900 DEG C ~ 1100 DEG C;
(3.1.3) stage treatment of being sieved by powder obtains the dry granular material that thickness is 0.13mm ~ 0.35mm;
(3.2) by recipe requirements, dry granular is mixed;
(4) mixing dry granular cloth is imposed on the surface of decoration glazed body, spray heatproof fixing agent;
(4.1) to spraying fixing agent, for being combined preferably with cloth dry granular by the surface of the ceramic adobe of decoration;
(4.2) mixing dry granular is imposed on the surface of decorative blank by the uniform cloth of distributor, according to the cloth total amount of the different choice 0.50 ㎏/㎡ ~ 0.90 ㎏/㎡ of product performance and following process mode;
(4.3) heatproof fixing agent is sprayed dry granule layer surface, dry granule layer is fixed, and prevent dry granular displacement in conveying and the pre-heating stage after entering roller kiln and fly away,
(5) be delivered to roller kiln to burn till, through following process, make ceramic tile finished product.
(5.1) firing temperature of described wear-resistant ceramic brick is 1160 DEG C ~ 1230 DEG C, firing period 60 ~ 80 minutes; The control of temperature is that dry granular and adobe are fully merged, and ensures its antifouling, wear resisting property;
(5.2) carry out mirror polish to going out kiln-made product bossing surface, polishing machine adopts the various combinations such as diamond, silicon carbide, Elastic abrasive body to process, and glossiness is the wear-resisting polishing ceramic tile goods of 85 ~ 95 degree.Wherein, the proportioning of the mixing dry granular of described wear-resistant antiskid dry-particle ceramic tile consists of:
Transparent dry granular 88% wear-resistant antiskid dry-particle 12%.
Described operation wear-resisting antiskid performance dry granular (2), it is composed as follows by weight percentage:
Polishing slag 10% nano-corundum 8%
Four directions albite 32% ultrawhite kaolin 6%
Ball clay 12% ultrawhite potassium sodium stone flour 32%
Described operation transparent dry granular (3), meets adjustment dry granule layer and the coefficient of expansion of base and the needs of melt temperature; Its melt temperature is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm; By weight percentage, said composition is made up of following component:
BaO???3.5%～4.5%??CaO??10%～12%????Al 2O 3??18.5%～20.5%
Na 2O??2.5%～3.5%??K 2O??3.5%～4.5%??SiO 2???50%～55%
ZnO???2.5%～3%????MgO??0.5%～2%????B 2O 3???0.5%～1.5%
Wherein, the melt temperature of described transparent dry granular is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm;
Described operation flash of light dry granular (3), by weight percentage, said composition is made up of following component:
Sheet mica 65% glistens clipped wire 35%
Wherein, the melt temperature of described flash of light dry granular is 1100 DEG C ~ 1180 DEG C, and median size is 0.08mm ~ 0.18mm, for making the flashing ornaments effect of product surface.
Described operation heatproof fixing agent (4), by weight percentage, said composition is made up of following component:
Carboxymethyl cellulose 2% water-based stamp-pad ink 10%
Polyvinyl alcohol 1% ball clay 3%
Glue 84%.
The foregoing is only preferred embodiment of the present invention, all equalizations done according to the claims in the present invention scope change and modify, and all should belong to the covering scope of the claims in the present invention.

Claims (3)

1. a manufacture method for wear-resistant antiskid dry-particle ceramic tile, is characterized in that, comprises operation:
(1) forming ceramic brick planar substrates, carries out pattern decorative;
(2) preparation has the dry granular of wear-resisting antiskid performance;
(2.1) to add water preparing burden wet-milling into ball mill by the formula of wear-resistant antiskid dry-particle, slip spraying dry being made powder particle, between particle diameter 0.12mm ~ 0.40mm;
(2.2) be contained in saggar by powder particle, send in kiln and calcine, firing temperature is 900 DEG C ~ 1100 DEG C, and the cycle is 120 minutes;
(2.3) sieved by ripe powder particle, preparing particle diameter is that particle between 0.13mm ~ 0.35mm is for subsequent use;
Described operation wear-resisting antiskid performance dry granular (2), it is composed as follows by weight percentage:
Nano-corundum 8% silicate flux raw material 70% ~ 88%
Clay-type substance 10% ~ 22% polishing slag 10%;
(3) by proportioning mixing wear-resistant antiskid dry-particle, flash of light dry granular, transparent dry granular, for cloth;
Described operation transparent dry granular (3), by weight percentage, said composition is made up of following component:
BaO????3.5%～4.5%??????????CaO??10%～12%
Al 2O 3?18.5%～20.5%????????Na 2O?2.5%～3.5%
K 2O????3.5%～4.5%??????????SiO 2?50%～55%
ZnO????2.5%～3%???????????????MgO???0.5%～2%
B 2O 3??????0.5%～1.5%
Wherein, the melt temperature of described transparent dry granular is 1100 DEG C ~ 1200 DEG C, and median size is 0.1mm ~ 0.25mm;
(4) mixing dry granular cloth is imposed on the surface of decoration glazed body, spray heatproof fixing agent;
Described operation mixing dry granular (4), by weight percentage, said composition is made up of following component:
Wear-resistant antiskid dry-particle 10% ~ 25% transparent dry granular 70% ~ 88% flash of light dry granular 2% ~ 5%;
(4) described operation comprises further: the mixing dry granular prepared is adopted dry granular distributor, dry granular is evenly distributed in the surface of adobe patterned layer, and heatproof fixing agent is sprayed make it fixing in the surface of dry granule layer, cloth doses adjusts according to the rotating speed of distributor and the gait of march of adobe;
(5) be delivered to roller kiln to burn till, through following process, make ceramic tile finished product;
The firing temperature of described operation (5) roller kiln is 1160 DEG C ~ 1230 DEG C, firing period 60 ~ 80 minutes; The control of temperature should ensure to combine together at sintering process dry granular and adobe, and wear-resistant antiskid dry-particle has relief.
2. the manufacture method of wear-resistant antiskid dry-particle ceramic tile according to claim 1, it is characterized in that: described operation flash of light dry granular (3), by weight percentage, said composition is made up of following component:
Sheet mica 65% glistens clipped wire 35%
Wherein, the melt temperature of described flash of light dry granular is 1100 DEG C ~ 1180 DEG C, and median size is 0.08 mm ~ 0.18mm, for making the flashing ornaments effect of product surface.
3. the manufacture method of wear-resistant antiskid dry-particle ceramic tile according to claim 1, it is characterized in that: described operation heatproof fixing agent (4), by weight percentage, said composition is made up of following component:
Carboxymethyl cellulose 2% water-based stamp-pad ink 10%
Polyvinyl alcohol 1% ball clay 3%
Glue 84%.
CN201310349396.6A 2013-08-12 2013-08-12 Method for manufacturing wear-resistant antiskid dry-particle ceramic tile CN103435369B (en)

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CN105565908B (en) * 2015-12-23 2018-07-31 蒙娜丽莎集团股份有限公司 A kind of compound roll marks dry granular solid porcelain brick and its production technology
CN106045475A (en) * 2016-05-30 2016-10-26 泉州阳光创艺陶瓷股份有限公司 Method for preparing pearl porcelain sand from blank waste and pearl porcelain sand creative ceramic
CN106699146B (en) * 2016-12-28 2020-06-30 佛山市三水新明珠建陶工业有限公司 Semi-polished ceramic glazed tile with fluorescence effect and manufacturing method thereof
CN106830686A (en) * 2017-01-03 2017-06-13 佛山石湾华鹏陶瓷有限公司 It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method
CN107417304A (en) * 2017-08-18 2017-12-01 佛山市东鹏陶瓷有限公司 A kind of preparation technology of the strong dry granular brick of brick face third dimension
CN107651862B (en) * 2017-09-26 2020-04-17 东莞泰升玻璃有限公司 Anti-skid glass processing technology
CN108275880A (en) * 2018-01-23 2018-07-13 合肥利裕泰玻璃制品有限公司 A kind of wear-resisting antiskid glass and preparation method thereof
CN108587320A (en) * 2018-05-11 2018-09-28 广西欧神诺陶瓷有限公司 A kind of function glue applied to inkjet printing, ornamental porcelain brick and preparation method thereof
CN109231955A (en) * 2018-08-10 2019-01-18 瑞高（浙江）环保新材料科技有限公司 The wear-resisting ceramic plate of a kind of nanometer of dry granular and preparation process
CN109081686A (en) * 2018-08-22 2018-12-25 刘志成 A kind of imitation stone mosaic and its synthetic method
CN109053226B (en) * 2018-08-27 2021-03-12 河源市东源鹰牌陶瓷有限公司 Method for preparing matte dry particle glazed tile
CN109227901A (en) * 2018-10-10 2019-01-18 东莞市唯美陶瓷工业园有限公司 Can simultaneously a variety of dry-particle ceramic tiles of charity, preparation method and its control method
CN109516836A (en) * 2018-11-27 2019-03-26 广西欧神诺陶瓷有限公司 A kind of preparation method of skid-proof ceramic tile
CN109665871A (en) * 2018-12-27 2019-04-23 佛山欧神诺陶瓷有限公司 It is a kind of to improve the process for throwing brilliant ceramic brick surface wear-resisting property
CN109834809B (en) * 2019-03-01 2020-08-04 江西和美陶瓷有限公司 Dry particle decorative ceramic tile with strong stereoscopic impression and manufacturing method thereof
CN112499971A (en) * 2021-02-08 2021-03-16 佛山欧神诺陶瓷有限公司 Crystal flash dry particle, crystal flash ceramic tile and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101157575A (en) * 2007-09-21 2008-04-09 广东欧文莱陶瓷有限公司 Decoration layer grail vulcanized ceramic face glazing brick and preparation method thereof
CN201809293U (en) * 2010-10-13 2011-04-27 广东道氏标准制釉股份有限公司 Ceramic glazed brick with glitter effect
CN102503435A (en) * 2011-09-22 2012-06-20 佛山市科捷制釉有限公司 Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles

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