CN110304903A - A kind of preparation method of state porcelain porcelain tool living - Google Patents
A kind of preparation method of state porcelain porcelain tool living Download PDFInfo
- Publication number
- CN110304903A CN110304903A CN201910557395.8A CN201910557395A CN110304903A CN 110304903 A CN110304903 A CN 110304903A CN 201910557395 A CN201910557395 A CN 201910557395A CN 110304903 A CN110304903 A CN 110304903A
- Authority
- CN
- China
- Prior art keywords
- parts
- porcelain
- powder
- piezoelectricity
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/0072—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention provides a kind of preparation method of state porcelain porcelain tool living, the described method includes: being prepared to piezoelectricity magnetization material, heating mixing is carried out to piezoelectricity magnetization material, smashed piezoelectricity magnetization feed powder body and base-material is taken to be sent into ball mill and mix by certain number, Ball-milling Time is 15~17 hours, it pulverizes, the partial size that powder is made is 60~80 mesh；Slurry is made in the good powder of ball milling, the water content of slurry is adjusted to 50~60%；It takes the porcelain made in advance to have carcass, coats one layer of slurry made in advance in the surfaces externally and internally of carcass, dry, the time 2~3 hours；Stove is sent into fire.The porcelain tool of the production method of offer of the invention, production not only enhances the activation effect of porcelain tool, but also improves the quality of porcelain tool.
Description
Technical field
The invention belongs to porcelain to have preparation field, in particular to a kind of preparation method of state porcelain porcelain tool living.
Background technique
China is the native place of porcelain, and porcelain is the important creation of ancient times working people；The invention of porcelain is China
Nationality contributes the greatness of world civilization；Original porcelain tool is a kind of material being burnt into kaolin, and done implements are thinner than pottery
Cause and it is hard；Generally as container, the deposit and packaging of substance are carried out；As people's cultural life and the continuous of material life mention
Height, people are no longer content with the packaging functions of porcelain tool；Appearance is exquisite, has become the mesh that people constantly chase now using health
Mark.
Your porcelain is first of five big porcelain, your traditional porcelain mainly uses quartz, black feldspar, melilite, high territory (wind scoop
Soil, half way up the mountain soil), clay (black wool soil, Tang Goutu), calcite, dolomite, plant ash etc. adds and forms；Mainly pass through when adding a
Including Raw material processing first: pug, glaze are processed into traditional handicraft, by picking up the works such as choosing, rinsing, broken, grinding, aging
Sequence；Secondly it forms: with hand throwing, engraving, kneading model, opening up base molding；It is finally burnt into: first through 800 DEG C or so biscuitings, using glaze method
Glazing is required according to combinations color and lustre, 1 time or 2 glazings, with reduction burn at.Although in CN102503365A patent application
Preparing joined iron ore in outer glaze, but its due to the amount of addition iron ore it is smaller, weight percent only has 2~3%, especially
It is the tourmaline powder that nano-scale particle is not added in this patent, nano-scaled electric stone has good piezoelectric effect, and science is
Verified this kind of material can significantly change water clusters clustering architecture, pH value, and anion release strength is significantly larger than other mines
Stone.In CN101700167A patent application, although referring to your china bowl has the function of fresh-keeping, energy in the material of the porcelain
The composition for enough forming preservation is to joined green agate, has piezoelectricity magnetic material due to lacking in the technical solution of this application
The substance of matter, and its lack effective combined use of a variety of magnetisable materials, this application is more without using iron ore and silica, therefore
This application does not have magnetizing function, does not have health-care effect yet.Therefore the preparation method and charger sheet one of above-mentioned porcelain tool, preparation
Porcelain has without good effect.
Summary of the invention
In view of the above-mentioned problems, a kind of preparation method of state porcelain porcelain tool living of the present invention, which comprises
Piezoelectricity magnetization material is prepared, comprising:
Iron ore calcining is then ground into ferriferrous oxide nano powder；
Tourmaline, diatomite are ground into powder；
Heating mixing is carried out to piezoelectricity magnetization material, comprising:
Piezoelectricity magnetization material is mixed according to a certain percentage, abrasive lapping is magnetized to mixed piezoelectricity using ball mill；
With 1~5 DEG C of speed of temperature control, 450~600 DEG C of temperature control consoles are at the uniform velocity warming up to, are kept for constant temperature 7~9 hours；
With 0.5~3 DEG C of speed of temperature control, 800~950 DEG C are at the uniform velocity warming up to, is kept for constant temperature 24~30 hours；
Mixed material will be heated to take out, 60~80 mesh are crushed using ball-type grinder；
Smashed piezoelectricity magnetization feed powder body and base-material is taken to be sent into ball mill and mix by certain number, milling time is
It 15~17 hours, pulverizes, the partial size that powder is made is 60~80 mesh；
Slurry is made in ground powder, the water content of slurry is adjusted to 50~60%；
It takes the porcelain made in advance to have carcass, coats one layer of slurry made in advance in the surfaces externally and internally of carcass, dry, the time
2~3 hours；
Stove is sent into fire.
Further, the temperature of the iron ore calcining is 1250 DEG C~1350 DEG C, and calcination time is 7~10 hours；Institute
State be ground into nano-powder be 90~110 mesh are ground into using ball-type grinder, then with nano-level grinder be ground into Dn50≤
100nm。
Further, the tourmaline is ground into the nano-powder of Dn50≤100nm.
Further, the diatomite is ground into the powder of 800~1000 mesh.
Further, the mixed proportion of the piezoelectricity magnetization material is ferroso-ferric oxide: tourmaline: diatomite=(0.25
~1): 1:(0.15~1).
Further, the base-material includes silica, Mayan stone, quartz, melilite, black wool soil, wind scoop soil and calcite
In any one or more.
Further, the component for the parts by weight that the piezoelectricity magnetization material and the base-material are added includes ferroso-ferric oxide
25~100 parts, 100 parts of tourmaline, 15~100 parts of diatomite, 30~60 parts of silica, 66 parts of quartz, 120 parts of melilite, Ma
45~85 parts of refined stone, 25~45 parts of black wool soil, 30~65 parts of wind scoop soil and 30~65 parts of calcite.
Further, the piezoelectricity magnetization is expected and the component of the parts by weight of base-material addition includes, 55 parts of ferroso-ferric oxide,
100 parts of tourmaline, 45 parts of diatomite, 45 parts of silica, 66 parts of quartz, 120 parts of melilite, 60 parts of Mayan stone, black wool soil 35 parts,
60 parts and 40 parts of calcite of wind scoop soil.
Further, the firing program is:
Fire door is opened after igniting, is gradually warmed up, and furnace temperature is made to rise to 600 DEG C from room temperature in 5 hours；
Fire door is closed, furnace temperature is made to be gradually heated to 1260 DEG C, the firing time 8~9 hours；
Furnace temperature is controlled after the completion of firing, and is kept the temperature 36 hours, is come out of the stove.
The porcelain tool of production method provided by the invention, production not only enhances the activation effect of porcelain tool, but also improves porcelain
The quality of tool.Other features and advantages of the present invention will be illustrated in the following description, also, partly becomes from specification
It obtains it is clear that understand through the implementation of the invention.The objectives and other advantages of the invention can be by specification, right
Pointed structure is achieved and obtained in claim.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical solution in the embodiment of the present invention is clearly and completely illustrated, it is clear that described embodiment is the present invention one
Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making
Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of creative work.
The present invention provides a kind of preparation method of state porcelain porcelain tool living, which comprises
Step 1: piezoelectricity magnetization material is prepared, comprising:
Iron ore calcining is then ground into nano-powder；
Tourmaline, diatomite are ground into powder；
Specifically, taking ready iron ore, it is sent into inertia calcining in calcining furnace, calcined iron ore is in dark brown,
Calcination temperature therein is 1250 DEG C~1350 DEG C, and calcination time is 7~10 hours, is taken out after calcining, and ball-type grinder crushes
100 mesh or so, then it is ground into nano-level grinder the powder of Dn50≤100nm.Tourmaline is taken, is crushed using ball-type grinder
100 mesh or so, then it is ground into nano-level grinder the powder of Dn50≤100nm.Diatomite is taken, is allowed to reach in the way of grinding
To 800~1000 mesh.
Step 2: heating mixing is carried out to piezoelectricity magnetization material, comprising:
Piezoelectricity magnetization material is mixed according to a certain percentage, abrasive lapping is magnetized to mixed piezoelectricity using ball mill；
With 1~5 DEG C of speed of temperature control, 450~600 DEG C of temperature control consoles are at the uniform velocity warming up to, are kept for constant temperature 7~9 hours；
With 0.5~3 DEG C of speed of temperature control, 800~950 DEG C are at the uniform velocity warming up to, is kept for constant temperature 24~30 hours；
Mixed material will be heated to take out, 60~80 mesh are crushed using ball-type grinder.
Specifically, ferriferrous oxide nano powder and tourmaline nano-powder and 800~1000 mesh diatomite powders are pressed
According to (0.25~1): 1:(0.15~1) mixing, carry out functional material self assembly preparation: firstly, ball mill grinding 6~24 hours,
There is good magnetic and electric conductivity using ferroso-ferric oxide, in nanometer piezo-electric material and ferroso-ferric oxide powder ground and mixed
In the process, the self-service dress of nanometer piezo-electric material under the conditions of realization is magnetic.Secondly, with 1~5 DEG C of speed inert atmosphere roasting of temperature control
It burns, is warming up to 450~600 DEG C of temperature control consoles, kept for constant temperature 7~9 hours, this temperature control atmosphere diatomite starts phase transformation reaction, together
When by nano ferriferrous oxide magnetism and electric conductivity, adjust automatically piezo-electric material crystalline electrode auto arrangement, at the same benefit
The short circuit of piezo-electric material crystalline electrode is prevented with diatomite phase transformation reaction；Finally, 800 are uniformly heating to again with 0.5~3 DEG C~
950 DEG C, 24~30 hours self-assembled materials of constant temperature is kept to start solid phase reaction, generates numerous extremely small reaction member,
And piezoelectric effect is utilized, activate this part mixing material；60~80 mesh are crushed using ball-type grinder after taking-up.
Step 3: it takes smashed piezoelectricity magnetization feed powder body and base-material to be sent into ball mill and mix by certain number, grinds
Time consuming 15~17 hours, pulverizes, and the partial size that powder is made is 60~80 mesh；
Specifically, the base-material includes in silica, Mayan stone, quartz, melilite, black wool soil, wind scoop soil and calcite
Any one or more；The component for the parts by weight that the piezoelectricity magnetization feed powder body and the base-material are added includes four oxidations
25~100 parts of three-iron, 100 parts of tourmaline, 15~100 parts of diatomite, 30~60 parts of silica, 66 parts of quartz, melilite 120
Part, 45~85 parts of Mayan stone, 25~45 parts of black wool soil, 30~65 parts of wind scoop soil and 30~65 parts of calcite.Preferably, the pressure
The component for the parts by weight that electrically magnetization feed powder body and the base-material are added includes 55 parts of ferroso-ferric oxide, 100 parts of tourmaline, silicon
45 parts of diatomaceous earth, 45 parts of silica, 66 parts of quartz, 120 parts of melilite, 60 parts of Mayan stone, 35 parts of black wool soil, 60 parts of wind scoop soil and side
40 parts of stone of solution.
Step 4: being made slurry for ground powder, and the water content of slurry is adjusted to 50~60%.
Step 5: the porcelain made in advance tool carcass (carcass is fired using clay, feldspar and quartz) is taken, in tire
The surfaces externally and internally of body coats one layer of slurry made in advance, dries, and the time 2~3 hours.
Step 6: it is sent into stove and fires.
Specifically, firing program is: opening fire door after igniting, be gradually warmed up, rise to furnace temperature from room temperature in 5 hours
600 DEG C, realize hydrofuge process；Fire door is closed, furnace temperature is made to be gradually heated to 1260 DEG C, the firing time 8~9 hours；It fires and completes
After control furnace temperature, keep the temperature 36 hours, come out of the stove, finished product.
Due to four oxidation three-bodies, tourmaline powder different meshes in the present invention, there may be differences for the performance of the product of production
Not.When the present invention proves ferroso-ferric oxide by test, the mesh number of tourmaline powder reaches 20000 mesh, i.e. Dn50≤100nm
When, performance is best；This experiment carries out the evaluation of effect using the method for negative ion concentration detection.
Illustratively, the number of ferroso-ferric oxide, tourmaline powder and diatomite is respectively 50 parts, 100 parts, 30 parts
When, it sets diatomite and is tested as 800 mesh, shown in specific performance such as following table (1):
The ferroso-ferric oxide and tourmaline powder test result of table (1) different meshes
Ferroso-ferric oxide powder is different from the mesh number of tourmaline powder it can be seen from table (1), the anion that detected
Concentration is different, and can be seen that material mesh number is different, and performance difference is larger, thus by table (1) it can be concluded that with mesh number increasing
The concentration of negative oxygen ion is added also to increase, in 20000 mesh, negative ion concentration reaches 19800 when i.e. Dn50≤100nm, by
In the 10000/cm of negative ion concentration that the scope of the present invention is functional material generation3More than and its, reaching 10,000/cm3And
There is good effect when more than it；Therefore in the present invention ferroso-ferric oxide and tourmaline powder nano particle Dn50≤
100nm hereinafter, its negative ion concentration just can guarantee it is enough both effectiveness.
Since the number of three kinds of ferroso-ferric oxide, tourmaline and diatomite raw materials is different in the present invention, the product of preparation
Performance may be different, and the present invention proves 25~100 parts of ferroso-ferric oxide, 100 parts of tourmaline, diatomite 15~100 by test
When part, performance is more excellent.
Illustratively, pass through the ferriferrous oxide nano powder of different numbers, tourmaline nano-powder and diatomite in powder
Body is mixed, and the detection of negative ion concentration is then carried out, shown in result such as following table (2):
The piezoelectricity magnetization material test result of table (2) difference number
By table (2) it can be seen that constantly increasing by four oxidations three in the inside of the tourmaline nano-powder of certain number
When iron nano-powder and diatomite powder, the negative ion concentration of detection gradually increases, it can be deduced that ferriferrous oxide nano
Powder number number, diatomite powder number number directly affect the performance of porcelain tool, while in ferriferrous oxide nano powder
When the number of body, tourmaline nano-powder and diatomite powder is respectively 55 parts, 100 parts, 45 parts, negative ion concentration reaches most
Greatly；When continuing to add ferroso-ferric oxide and diatomite, negative ion concentration starts to reduce, in ferriferrous oxide nano powder and silicon
Diatomaceous earth is respectively added to 105 parts, and negative ion concentration is less than 10,000/cm3；Since proportion technique protection scope of the present invention is function material
Expect the 10000/cm of negative ion concentration generated3More than and its, reaching 10,000/cm3And its there is good effect when above；
Therefore it can be concluded that 25~100 parts of ferroso-ferric oxide, 15~100 parts of diatomite whens can protect when tourmaline powder is 100 parts
Demonstrate,prove 10,000/cm of negative ion concentration3More than and its；Obtain ferroso-ferric oxide: tourmaline: diatomite=(0.25~1): 1:
When (0.15~1), it is best that manufactured porcelain has effect.It should be noted that Dn50 expression is 50% grain diameter maximum gauge, together
When table (2) unit be part.
Illustratively, the production of porcelain tool is carried out by the ingredient of different numbers；It specifically includes:
Case column situation one: the parts by weight of material: 100 parts of iron ore, 100 parts of tourmaline, 100 parts of diatomite, silica are added
30 parts, 66 parts of quartz, 120 parts of melilite, 45 parts of Mayan stone, 25 parts of black wool soil, 30 parts, 30 parts of calcite of wind scoop soil.
Case column situation two: the parts by weight of material: 50 parts of iron ore, 100 parts of tourmaline, 30 parts of diatomite, silica 45 are added
Part, 35 parts of 66 parts of quartz, 120 parts of melilite, 60 parts of Mayan stone, black wool soil, 60 parts and 36 parts of calcite of wind scoop soil.
Case column situation three: the parts by weight of material: 25 parts of iron ore, 100 parts of tourmaline, 15 parts of diatomite, silica 60 are added
Part, 45 parts of 66 parts of quartz, 120 parts of melilite, 85 parts of Mayan stone, black wool soil, 65 parts and 65 parts of calcite of wind scoop soil.
Case column situation four: the parts by weight of material: 60 parts of silica, 66 parts of quartz, 120 parts of melilite, Mayan stone 85 are added
Part, 45 parts of black wool soil, 65 parts and 65 parts of calcite of wind scoop soil.
Ingredient in four kinds of situations is different, and preparation method is identical (for case situation four not following steps one and step
Rapid two operation), prepare ingredient by said ratio, carries out preparation manipulation, wherein the preparation method comprises the following steps:
Step 1: preprepared iron ore will be taken, it is sent into calcining furnace and calcines, calcined iron ore is in dark brown
Color, calcination temperature therein are 1250 DEG C~1350 DEG C, and calcination time is 7~10 hours, are taken out after calcining, ball-type grinder powder
Broken 100 mesh or so, then the powder for being ground into Dn50≤100nm with nano-level grinder are spare；
Step 2: by ferriferrous oxide nano powder, tourmaline powder and diatomite (800~1000 mesh) according to (0.25
~1): 1:(0.15~1) ratio mixes, and carries out functional material self assembly preparation: (1) ball mill grinding 6 hours, utilizes four oxidations
Three-iron has good magnetic and electric conductivity, real during nanometer piezo-electric material and ferroso-ferric oxide powder ground and mixed
The self-service dress of nanometer piezo-electric material under the conditions of existing magnetism.(2) with 1 DEG C of speed inert atmosphere roasting of temperature control, 550 DEG C of temperature are warming up to
Platform is controlled, is kept for constant temperature 9 hours, this temperature control atmosphere diatomite starts phase transformation reaction, while by the magnetic of nano ferriferrous oxide
Property and electric conductivity, adjust automatically piezo-electric material crystalline electrode auto arrangement, at the same using diatomite phase transformation reaction prevent piezoelectricity
Property material crystals electric pole short circuit；(3) 850 DEG C are being uniformly heating to 1 DEG C, 24 hours self-assembled materials of constant temperature is kept to start solid phase
Reaction generates numerous extremely small reaction member, and utilizes piezoelectric effect, activates this part mixing material, and secondary grinds
Wearing into 60~80 mesh has pyroelectric effect and magnetic effect powder, spare；
Step 3: taking the above-mentioned powder handled well in advance in proportion, it is sent into ball mill, proportionally takes preprepared
Silica, Mayan stone, quartz, melilite, black wool soil, wind scoop soil and calcite, are sent into ball mill, mix, and Ball-milling Time 15~
It 17 hours, pulverizes, the partial size that powder is made is 60~80 mesh, spare；
Step 4: slurry is made in the good powder of ball milling, the water content of slurry is adjusted to 50~60%, it is spare；
Step 5: the porcelain made in advance tool carcass (carcass is fired using clay, feldspar and quartz) is taken, in tire
The surfaces externally and internally of body coats one layer of slurry made in advance, dries, and the time 2~3 hours；
It is fired Step 6: being sent into stove, firing program is: opening fire door after igniting, is gradually warmed up, makes furnace in 5 hours
Temperature rises to 600 DEG C from room temperature, realizes hydrofuge process；Fire door is closed, so that furnace temperature is gradually heated to 1260 DEG C, the firing time 8~9 is small
When；Furnace temperature is controlled after the completion of firing, and is kept the temperature 36 hours, is come out of the stove, finished product.
Test one: to porcelain obtained in case situation one, two, three, four tool test, illustratively, packaging white wine into
Row test.Odorous principle evaluation and test is carried out to the white spirit original wine of selection (alcohol concentration >=45 °) first, to the result of evaluation and test into
Row record.It is then contained in four porcelain tools made of aforementioned four situation and places 2 into same white wine (alcohol concentration >=45 °)
It, carries out odorous principle evaluation and test, it is both effectiveness to verify its.Esters majority is the volatilization with aromatic odor in Luzhou-flavor liquo
The main constituents of property compound and Luzhou-flavor liquo fragrance taste.The monomer flavor component of esters, to contain in its structural formula
The number of carbon atom number, shows smell of different strengths and weaknesses, the fragrance containing 1~2 carbon is weak, and the duration is short；Containing 3~5
Carbon has fat smelly, and content should not be excessive in wine；The fragrance of 6~12 carbon is dense, and the duration is longer.It is main in Luzhou-flavor liquo
Wanting esters is ethyl hexanoate, ethyl lactate, ethyl acetate, and wherein key component is using gas-chromatography comparison as shown in following table (3):
Porcelain under table (3) different situations has testing result
It can clearly find out from upper table (3), the main of Luzhou-flavor liquo changed dramatically using the porcelain tool of the technology of the present invention
Fragrance component, wherein the enamel of case situation one, case situation two and case situation three can reach offer odorous principle
16% or more concentration.Especially Luzhou-flavor ingredient, that is, hexyl hexanoate of long-term effect can increase to 1.8% or more from the 0 of former wine,
Confirm the validity of function porcelain tool of the invention.
Test two: the test for having progress packaging water to porcelain made of case situation three illustratively utilizes above-mentioned case feelings
The ingredient of shape three state porcelain porcelain tool living made of aforesaid operations, is contained into underground water, marked as A；It is contained using general porcelain tool into phase
Same underground water, marked as B；Stand 20min；Then use O17NMR half-peak breadth mark；Identify result are as follows: B porcelain has interior O17NMR
Half-peak breadth test is 76.8Hz, and A porcelain has interior O17NMR half-peak breadth becomes 63.2Hz, it can is concluded that and utilizes the present invention
Manufactured porcelain tool, has preferable far infrared fuel factor to hydrone and improves water molecule cluster size effect.
It should be noted that the test method educational circles of water molecule cluster size uses O17NMR half-peak breadth mark, generally originally
The O of water17NMR half-peak breadth >=80Hz, raw water of the present invention use underground water.
You need to add is that tourmaline is a kind of characterized by boracic, the silicate mine of the cyclic structure of chemical composition complexity
Object, main chemical compositions SiO2、FeO+Fe2O3、B2O3、Al2O3、Na2O、MgO、Li2O、MnO2Deng；The characteristics of tourmaline mineral
It is that in the case where temperature, pressure change, the potential difference of tourmaline crystal can be caused with piezoelectricity and pyroelectricity, makes surrounding
Air ionize, that is hit is electronically attached to neighbouring water and oxygen molecule and it is made to be converted into negative aeroion；Electrically
Stone is a kind of good environment functional material, for the coating material of indoor coating and furniture, electric appliance etc., can produce anion,
It purifies the air of a room；In addition, because of its pyroelectricity, with the variation of temperature, crystallizable mineral body both ends can produce voltage, polarity from
Son can be such that human body generates in the electromagnetic radiation that equilbrium position vibrates and dipole moment variation is caused to generate far infrared band, infra-red radiation
Fuel factor.In addition research discovery produces crude tourmaline using Xinjiang and prepares tourmaline micro mist as raw material, using X-ray diffractometer, sweeps
Retouch Electronic Speculum, high resolution electron microscopy,17The heat of the O nuclear magnetic resonance research phase structure of tourmaline micro mist, micro-structure feature and tourmaline
Releasing electrically influences water clusters clustering architecture, and is inquired into the mechanism that it is acted on.The result shows that prepared tourmaline
The crystallinity of micro mist is intact, and the crystallite of the pyroelectric material tourmaline with OWP one-way polar structure is in the environment of temperature fluctuation
It can be considered electric dipole；Tourmaline powder is to water17The half-peak breadth of O nuclear magnetic resoance spectrum has apparent influence, Hz=145.41Hz
Hz=81.11Hz is dropped to, shows that tourmaline micro mist has apparent effect to the improvement of water clusters clustering architecture, and find tourmaline
Class material only have nano-scale be ion when effect just it is significant.
The present invention provides a kind of method, and simple, easily operated porcelain has preparation method, and the porcelain tool of preparation has certain guarantor
Health-care function, and quality is high.
The present invention provides a kind of preparation method of state porcelain porcelain tool living, although having carried out in detail to the present invention with reference to the foregoing embodiments
Thin explanation, those skilled in the art should understand that: it still can be to technical side documented by foregoing embodiments
Case is modified or equivalent replacement of some of the technical features；And these are modified or replaceed, and do not make corresponding skill
The essence of art scheme departs from the spirit and scope of the technical scheme of various embodiments of the present invention.
Claims (9)
1. a kind of preparation method of state porcelain porcelain tool living, which is characterized in that the described method includes:
Piezoelectricity magnetization material is prepared, comprising:
Iron ore calcining is then ground into ferriferrous oxide nano powder；
Tourmaline, diatomite are ground into powder；
Heating mixing is carried out to piezoelectricity magnetization material, comprising:
Piezoelectricity magnetization material is mixed according to a certain percentage, abrasive lapping is magnetized to mixed piezoelectricity using ball mill；
With 1~5 DEG C of speed of temperature control, 450~600 DEG C of temperature control consoles are at the uniform velocity warming up to, are kept for constant temperature 7~9 hours；
With 0.5~3 DEG C of speed of temperature control, 800~950 DEG C are at the uniform velocity warming up to, is kept for constant temperature 24~30 hours；
Mixed material will be heated to take out, 60~80 mesh are crushed using ball-type grinder；
It taking smashed piezoelectricity magnetization feed powder body and base-material to be sent into ball mill by certain number to mix, milling time is 15~
It 17 hours, pulverizes, the partial size that powder is made is 60~80 mesh；
Slurry is made in ground powder, the water content of slurry is adjusted to 50~60%；
It takes the porcelain made in advance to have carcass, coats one layer of slurry made in advance in the surfaces externally and internally of carcass, dry, the time 2~3
Hour；
Stove is sent into fire.
2. the preparation method for state porcelain porcelain tool of living according to claim 1, which is characterized in that the temperature of iron ore calcining is
1250 DEG C~1350 DEG C, calcination time is 7~10 hours；The nano-powder that is ground into is to be ground into 90 using ball-type grinder
~110 mesh, then Dn50≤100nm is ground into nano-level grinder.
3. the preparation method of state porcelain porcelain tool living according to claim 1 or claim 2, which is characterized in that the tourmaline is ground into
The nano-powder of Dn50≤100nm.
4. the preparation method of state porcelain porcelain tool living according to claim 1 or claim 2, which is characterized in that the diatomite is ground into 800
The powder of~1000 mesh.
5. the preparation method of state porcelain porcelain tool living according to claim 1 or claim 2, which is characterized in that the piezoelectricity magnetization material
Mixed proportion is ferroso-ferric oxide: tourmaline: diatomite=(0.25~1): 1:(0.15~1).
6. the preparation method for state porcelain porcelain tool of living according to claim 5, which is characterized in that the base-material includes silica, Mayan
Stone, quartz, melilite, black wool soil, wind scoop soil and calcite in any one or more.
7. the preparation method for state porcelain porcelain tool of living according to claim 6, which is characterized in that piezoelectricity magnetization material and described
The component for the parts by weight that base-material is added includes 25~100 parts of ferroso-ferric oxide, 100 parts of tourmaline, 15~100 parts of diatomite, silicon
30~60 parts of stone, 66 parts of quartz, 120 parts of melilite, 45~85 parts of Mayan stone, 25~45 parts of black wool soil, wind scoop soil 30~65
Part and 30~65 parts of calcite.
8. the preparation method for state porcelain porcelain tool of living according to claim 7, which is characterized in that the piezoelectricity magnetization material and base-material
The component of the parts by weight of addition includes 55 parts of ferroso-ferric oxide, 100 parts of tourmaline, 45 parts of diatomite, 45 parts of silica, quartz
66 parts, 120 parts of melilite, 60 parts of Mayan stone, 35 parts of black wool soil, 60 parts and 40 parts of calcite of wind scoop soil.
9. the preparation method of state porcelain porcelain tool living according to claim 1 or claim 2, which is characterized in that the firing program is:
Fire door is opened after igniting, is gradually warmed up, and furnace temperature is made to rise to 600 DEG C from room temperature in 5 hours；
Fire door is closed, furnace temperature is made to be gradually heated to 1260 DEG C, the firing time 8~9 hours；
Furnace temperature is controlled after the completion of firing, and is kept the temperature 36 hours, is come out of the stove.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910557395.8A CN110304903B (en) | 2019-06-25 | 2019-06-25 | Preparation method of active porcelain |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910557395.8A CN110304903B (en) | 2019-06-25 | 2019-06-25 | Preparation method of active porcelain |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110304903A true CN110304903A (en) | 2019-10-08 |
| CN110304903B CN110304903B (en) | 2022-05-27 |
Family
ID=68077329
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910557395.8A Active CN110304903B (en) | 2019-06-25 | 2019-06-25 | Preparation method of active porcelain |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110304903B (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108292A (en) * | 2007-08-24 | 2008-01-23 | 傅斌 | Wine biological activity filtering pistil |
| CN101148353A (en) * | 2007-08-21 | 2008-03-26 | 常州众博复合材料有限公司 | Powder material capable of producing anion and preparation method thereof |
| CN102690102A (en) * | 2012-05-03 | 2012-09-26 | 上海长洲盛锦文化传播有限公司 | Ceramic product having alcoholic drink alcoholization function and preparation method thereof |
| CN102775188A (en) * | 2011-05-13 | 2012-11-14 | 王强 | Far infrared ceramic material |
| CN104129996A (en) * | 2014-08-06 | 2014-11-05 | 淄博百康经贸有限公司 | Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof |
| CN104556978A (en) * | 2014-12-24 | 2015-04-29 | 唐山立雄峰汇材料科技有限公司 | Functional ceramic wine set |
| CN105174903A (en) * | 2015-07-27 | 2015-12-23 | 陈广平 | Resonant biological energy ceramic and preparation method therefor |
| CN105565902A (en) * | 2015-12-24 | 2016-05-11 | 河南廷怀汝瓷科技有限公司 | Active-state ceramic earthenware |
| CN105565789A (en) * | 2015-12-24 | 2016-05-11 | 河南廷怀汝瓷科技有限公司 | Active magnetizing glaze ceramic |
| CN105601260A (en) * | 2015-12-24 | 2016-05-25 | 淄博永辰环境影响评价有限公司 | Water purification ceramic |
| CN105645938A (en) * | 2014-11-10 | 2016-06-08 | 厦门美巨信息科技有限公司 | Far-infrared negative-ion ceramic and preparation method thereof |
-
2019
- 2019-06-25 CN CN201910557395.8A patent/CN110304903B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101148353A (en) * | 2007-08-21 | 2008-03-26 | 常州众博复合材料有限公司 | Powder material capable of producing anion and preparation method thereof |
| CN101108292A (en) * | 2007-08-24 | 2008-01-23 | 傅斌 | Wine biological activity filtering pistil |
| CN102775188A (en) * | 2011-05-13 | 2012-11-14 | 王强 | Far infrared ceramic material |
| CN102690102A (en) * | 2012-05-03 | 2012-09-26 | 上海长洲盛锦文化传播有限公司 | Ceramic product having alcoholic drink alcoholization function and preparation method thereof |
| CN104129996A (en) * | 2014-08-06 | 2014-11-05 | 淄博百康经贸有限公司 | Anion easy-cleaning functional ceramic additive and preparation method thereof, ceramic prepared by using additive and preparation method thereof |
| CN105645938A (en) * | 2014-11-10 | 2016-06-08 | 厦门美巨信息科技有限公司 | Far-infrared negative-ion ceramic and preparation method thereof |
| CN104556978A (en) * | 2014-12-24 | 2015-04-29 | 唐山立雄峰汇材料科技有限公司 | Functional ceramic wine set |
| CN105174903A (en) * | 2015-07-27 | 2015-12-23 | 陈广平 | Resonant biological energy ceramic and preparation method therefor |
| CN105565902A (en) * | 2015-12-24 | 2016-05-11 | 河南廷怀汝瓷科技有限公司 | Active-state ceramic earthenware |
| CN105565789A (en) * | 2015-12-24 | 2016-05-11 | 河南廷怀汝瓷科技有限公司 | Active magnetizing glaze ceramic |
| CN105601260A (en) * | 2015-12-24 | 2016-05-25 | 淄博永辰环境影响评价有限公司 | Water purification ceramic |
Non-Patent Citations (4)
| Title |
|---|
| 冯丽萍 等: "《薄膜技术与应用》", 29 February 2016, 西北工业大学出版社 * |
| 张晓晖: "《新型环境净化功能材料 电气石及其与ZnO复合粉体的性能研究》", 31 December 2015, 中国地质大学出版社 * |
| 录华: "《精细化工概论》", 30 November 1999, 化学工业出版社 * |
| 高如琴 等: "电气石/硅藻土基内墙砖釉层热处理温度对其结构与性能的影响", 《硅酸盐学报》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110304903B (en) | 2022-05-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104030661B (en) | Volcanic rock ceramic implement articles for use and preparation method thereof | |
| CN102503574B (en) | Manufacture craft for pale yellowish green colored glaze of Ru porcelain | |
| KR101971940B1 (en) | Manufacturing method for emitter having far-infrared radiation thermal effect and an anion generating function and the emitter made therefrom | |
| CN106336116A (en) | Ceramic glaze, preparation method and method for making ceramic by utilization of ceramic glaze | |
| KR20180045437A (en) | Celadon glaze composition and manufacturing method of the same | |
| CN110423004A (en) | A kind of activity magnetization vitreous enamel | |
| CN109574623A (en) | A kind of production method of multi-functional pottery ball | |
| CN102992735A (en) | Preparation method of carbon-containing black pottery | |
| CN110304903A (en) | A kind of preparation method of state porcelain porcelain tool living | |
| CN104829211B (en) | Preparation method for anion ceramsite | |
| CN106517358B (en) | Infrared pigment of a kind of manganese systems inverse spinel phase high emissivity and preparation method thereof | |
| CN110407558A (en) | A kind of state porcelain porcelain tool living | |
| CN103962575A (en) | Method for preparing ultra-fine tungsten powder through rare-earth yttrium-doped ammonium paratungstate | |
| CN110357575A (en) | A kind of formula and its preparation process of heat-resisting high-transmittance day jade porcelain | |
| CN107987558A (en) | A kind of flowers shape LaFexEu1-xO3/TiO2The preparation method of compound superfine red ceramic paint | |
| CN105905949A (en) | Preparation method of magnetic Fe3O4/Fe2O3 composite nanorod | |
| CN104891988B (en) | A kind of Bi0.5Na0.4Li0.1MxTi1‑xO3Lead-free anti-ferroelectric high energy storage density ceramics and preparation method thereof | |
| KR100983845B1 (en) | Clearing ceramic ball and method for preparing the same | |
| CN108048109A (en) | It is a kind of for multi-functional passivator of paddy fields in south china heavy metal-polluted soil Cd and preparation method thereof | |
| JP3466969B2 (en) | Manufacturing method of far infrared radiation ceramics | |
| KR20210004743A (en) | Functional white clay ceramic ball made from porous powder and its manufacturing method. | |
| CN102535169A (en) | Far-infrared polyurethane synthetic leather resin | |
| CN103755386A (en) | Ceramic silicon iron red pigment mainly prepared from laterite | |
| KR20200113813A (en) | Manufacturing process of functional tongue type balls | |
| TW201944907A (en) | Heat conversion energy ceramic coffee baking machine capable of preventing charring and carbonization during baking to ensure health and flavor that the beverage should have |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |