CN105645938A - Far-infrared negative-ion ceramic and preparation method thereof - Google Patents
Far-infrared negative-ion ceramic and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a far-infrared negative-ion ceramic. The ceramic comprises the following components by weight: 0.1 to 0.18 part of magnesium oxide, 0.2 to 0.29 part of calcium oxide, 1.80 to 2.78 parts of potassium oxide, 22 to 25 parts of aluminium oxide, 71 to 72.4 parts of silicon dioxide, 0.23 to 0.28 part of sodium oxide, 0.1 to 0.13 part of ferric oxide, 1 to 3 parts of tourmaline and 1 to 3 parts of germanium oxide. The invention also provides a manufacturing method for the far-infrared negative-ion ceramic by using the above-mentioned components; and the far-infrared negative-ion ceramic has the advantages of mildness, beautiful appearance, and comprehensive functions of emitting far infrared wave and releasing negative ions.
Description
Technical field
The present invention relates to a kind of pottery, particularly relate to the making method of a kind of far-infrared negative-ion pottery and goods thereof.
Background technology
Far infrared rays is the hertzian wave with strong heat effect, is easily absorbed by object and is converted in object energy. Far infrared rays, due to its resonance effect and temperature control effect, can produce resonance with water molecules, make water molecule activation, and then activate other macromole. Based on this principle, wear or use the product that can disperse far infrared rays that human body physical and mental health is had important effect in daily life. Often emittance is lower for single natural material that can be emitting far-infrared, and is difficult to be applied.
The health-care effect of negative ion has been widely studied and has verified, negative ion has the effect of stronger Adsorption and decomposition, capable of purifying air; The effect that human body also has blood purification, cell bring back to life, can strengthen resistance of human body. HUMAN HEALTH is had important effect by the negative ion concentration improving human body and periphery subenvironment.
The healthcare product of current function ceramics on the market is more, but all can only realize single performance that is emitting far-infrared or anion releasing, multiple efficacies cannot be realized, and the emissive power of far infrared rays or negative ion are very weak, it is difficult to reach health care in fact and physiotherapy simultaneously. In addition, it is serious that traditional manufacture craft causes starting material to run off, it is difficult to makes the performance that product keeps stable, lasting.
Therefore, research and development can the material of simultaneously efficient transmission far infrared rays and anion releasing, and develop and can be used for keeping healthy and the far-infrared negative-ion product of physiotherapy has important meaning.
Summary of the invention
It is an object of the invention to provide a kind of far-infrared negative-ion pottery, this pottery can involve negative ion by transmitting far red light stable lastingly simultaneously, can be used for manufacturing far-infrared negative-ion ceramic.
Another object of the present invention is to provide the making method of a kind of far-infrared negative-ion ceramic, far-infrared negative-ion ceramic making is become daily living article, has attractive in appearance and practical effect concurrently.
For reaching above-mentioned purpose, the solution of the present invention is: a kind of far-infrared negative-ion pottery comprises the component of following weight part:
Magnesium oxide 0.1 0.18 weight part calcium oxide 0.2 0.29 weight part potassium oxide 1.80 2.78 weight part aluminium sesquioxide 22 25 parts by weight of silica 71 72.4 weight sodium oxide 0.23 0.28 weight part ferric oxide 0.1 0.13 parts by weight of tourmaline 13 weight part germanium oxide 13 weight part.
Described far-infrared negative-ion pottery 4-18 micron far infrared transmissivity is 0.9-0.94, and the concentration of anion releasing is 1700-2000inos/cc.
Preferably, far-infrared negative-ion pottery is made up of by its weight percent following component: magnesium oxide 0.1 0.18%, calcium oxide 0.2 0.29%, potassium oxide 1.80 2.78%, aluminium sesquioxide 22 25%, silicon-dioxide 71 72.4%, sodium oxide 0.23 0.28%, ferric oxide 0.1 0.13%, tourmalinite 1 3%, germanium oxide 1 3%.
Preferably, far-infrared negative-ion pottery is made up of by its weight percent following component: magnesium oxide 0.14%, calcium oxide 0.23%, potassium oxide 2.05%, aluminium sesquioxide 22.08%, silicon-dioxide 71.15%, sodium oxide 0.24%, ferric oxide 0.11%, tourmalinite 2%, germanium oxide 2%.
The making method of a kind of far-infrared negative-ion ceramic comprises the following steps:
(1) according to the composition weight proportioning of above-mentioned far-infrared negative-ion pottery, grind after getting starting material mixing, sieve, obtained far-infrared negative-ion ceramic powder;
(2) far-infrared negative-ion ceramic powder mixes with the ratio of paraffin by weight 100:10-20, stirs more than 30min in the temperature higher than 70 DEG C, and insulation 3-10h, forms blank;
(3) blank injects mould by the mode of extruding, peels off mould molding after cooling, forms base substrate;
(4) base substrate shave burr repair after in outer surface alumina powder, calcine despumation through more than 800 DEG C;
(5) base substrate after calcining is by high pressure air gun spray dust removing;
(6) base substrate after dedusting is modulated through mineral color dyeing, glazing, in more than 1300 DEG C sintering, obtained can the far-infrared negative-ion ceramic of simultaneously emitting far-infrared and anion releasing.
Preferably, the middle degree particle diameter of described far-infrared negative-ion ceramic powder is 1um-5um.
Preferably, in step (2), the temperature range stirring and being incubated is 100-150 DEG C.
Preferably, in step (4), the purity of described alumina powder is 99-99.9%, and middle degree particle diameter is 10-30nm.
Preferably, in step (4), the time of described calcining is 2.5-4h.
Preferably, in step (6), described mineral color contains at least one of manganese, cobalt, iron, selenium, magnesium, praseodymium.
Preferably, in step (6), the time of described sintering is 6-10h.
The invention has the beneficial effects as follows:
1, far-infrared negative-ion pottery has comprehensive function that is emitting far-infrared and anion releasing, far infrared bio-electromagnetic wave human body is useful to surrounding space transmitting that can be eternal lastingly, and 4-18 micron far infrared transmissivity can reach 0.92; Ionizing air anion releasing, the negative ion concentration of periphery microenvironment can up to 1700-2000inos/cc simultaneously. Relative to the pottery of simple function, its two kinds of function synergic effects, effect is more obvious, applies more extensive. The obtained ornaments worn can accelerate human body amount of blood supply, purification blood, improves human tissue cell's circulation, it is to increase the immunological competence of body, regulates the mental status, thus play the effect of health care. Obtained articles for daily use can eliminate harmful organic molecule, and activation moisture, purifies water and air.
2, to prepare the method for far-infrared negative-ion ceramic simple and convenient in the present invention, and starting material loss is low, product density height, purity height, gentle attractive in appearance, uniform color, emitting far-infrared effect with anion releasing of maintenance ceramic that can be stable lastingly, over-all properties is good.
The present invention is described in further detail by following examples; But the making method of a kind of far-infrared negative-ion of the present invention pottery and goods thereof is not limited to embodiment.
Embodiment
The far-infrared negative-ion pottery of the present invention comprises the component of following weight part: magnesium oxide 0.1 0.18 weight part, calcium oxide 0.2 0.29 weight part, potassium oxide 1.80 2.78 weight part, aluminium sesquioxide 22 25 weight part, silicon-dioxide 71 72.4 weight part, sodium oxide 0.23 0.28 weight part, ferric oxide 0.1 0.13 weight part, tourmalinite 13 weight part and germanium oxide 13 weight part.
Preferred as one, far-infrared negative-ion pottery can be made up of by its weight percent following component: magnesium oxide 0.1 0.18%, calcium oxide 0.2 0.29%, potassium oxide 1.80 2.78%, aluminium sesquioxide 22 25%, silicon-dioxide 71 72.4%, sodium oxide 0.23 0.28%, ferric oxide 0.1 0.13%, tourmalinite 1 3%, germanium oxide 1 3%.
Preferred as one, far-infrared negative-ion pottery can be made up of by its weight percent following component: magnesium oxide 0.14%, calcium oxide 0.23%, potassium oxide 2.05%, aluminium sesquioxide 22.08%, silicon-dioxide 71.15%, sodium oxide 0.24%, ferric oxide 0.11%, tourmalinite 2%, germanium oxide 2%. Far-infrared negative-ion pottery can have higher spectral emittance, the far infrared light wave of transmitting 4-18 micron that can be lasting, eternal at normal temperatures, and emittance can reach 0.9-0.94; The function simultaneously having anion releasing concurrently, the negative ion concentration of periphery microenvironment can up to 1700-2000inos/cc.
By the far-infrared negative-ion of said ratio pottery, in its component, the valence band of element Ge can capture the outer valence electron of other components, thus increases the concentration in electronics, hole, it is to increase ir radiation. In addition, cause lattice distortion when germanium and magnesium, calcium etc. form sosoloid, reduce the symmetry of particle vibration, thus improve the activity of lattice vibration, also improve far infrared transmissivity. The structural formula of tourmalinite is (Na, Ca) (Mg, Fe)3B3Al6Si6(O, OH, F), has pyroelectricity and piezoelectricity, and its voltage official post air occurs ionization to produce negative ion, and its electrostatic field also can make water molecules generation electrolysis form bioactive molecule, thus activated water, purified water source.
The far-infrared ceramic made by said ratio component, launches and the function of negative ion release with far infrared, and is suitable for making various ceramic. The making method of far-infrared negative-ion ceramic is according to said components proportioning, get the base mateiral of each component, such as feldspar, kaolin, quartz etc. obtain pure component starting material through techniques such as calcining, deironing, refinements, carry out after mixing grinding, sieving, obtained uniform far-infrared negative-ion ceramic powder, the middle degree particle size range of powder between 1um-5um, such as, can be preferably 3um.
Being mixed with the ratio of paraffin by weight 100:10-20 by far-infrared negative-ion ceramic powder, stir more than 30min in the temperature higher than 70 DEG C, insulation 3-10h, forms blank. Temperature is preferably between 100-150 DEG C, and paraffin mixes with far-infrared negative-ion ceramic powder after fully melting, and is formed with the blank of plasticity-, and blank injects mould by the mode of extruding, to be cooled peels off mould molding to room temperature, formation base substrate. Base substrate shave burr repair after in outer surface alumina powder. The purity of alumina powder reaches 99-99.9%; middle degree particle diameter is between 100nm-300nm; it it is nano level high purity powdered form; the outside surface being wrapped in base substrate can form a protective layer and sealing coat in preparation process; reduce base substrate and extraneous contact; when base substrate (such as the ceramic bead) of the little size of large-scale making, the mutual impact between base substrate can be reduced, prevent base substrate from boning.Concrete, in actual fabrication process, ceramic bead can be rolled in nano aluminium oxide powder. The base substrate being enclosed with nano aluminium oxide is placed in the temperature lower calcination of more than 800 DEG C with despumation, and calcination time is 2.5-4h. At this temperature, paraffin decomposition gasification, nano aluminium oxide enters in the space of base substrate. Base substrate after calcining by high pressure air gun spray dust removing to remove the impurity of attachment further, then through dyeing, the glazing of mineral color modulation, in more than 1300 DEG C sintering, obtained far-infrared negative-ion ceramic, mineral color contains at least one of manganese, cobalt, iron, selenium, magnesium, praseodymium, and sintering time is 6-10h. In sintering process, potassium oxide and sodium oxide fusing form the glass matrix of pottery, it is to increase glaze paint glossiness and transparency, bonding crystal phase, fills the alternate space of crystal, it is to increase the density of pottery. The nano aluminium oxide of trace improves sintering activity, improves the thermostability of far-infrared negative-ion pottery simultaneously. Sintering temperature can be preferably 1300-1500 DEG C.
The present invention is fine and close by the far-infrared ceramic article construction that proportioning is obtained, gentle attractive in appearance, color enriches, and has the function of and anion releasing emitting far-infrared to surrounding space eternal lastingly, it is possible to make multiple daily necessities, have a wide range of applications. The bangle of far-infrared negative-ion ceramic preparation is carried with, subcutaneous deep skin temperature can be made to increase, expansion capillary blood vessel, stimulate circulation, the tissue metabolism of strengthening blood and cell, effectively promote human metabolism, the self-regeneration function of reinforcement inner tissue organ, regulate the unbalance of body thus reach prevention and the object of conditioning. The ceramic cup of far-infrared negative-ion ceramic preparation, can eliminate the impuritys such as the residual chlorine in water, purify water; Simultaneously due to itself and the resonant interaction of water molecules, can reducing the association of water molecules, thus activate moisture, increase dissolved oxygen amount, makes to be contained in wine wherein or tea mouthfeel more glycol. In addition, far-infrared negative-ion ceramic also can improve the negative ion concentration of surrounding microenvironment, the hazardous organic molecules such as catalytic decomposition formaldehyde, promotes the sedimentation of air suspension thing, purification air.
Above-described embodiment is only used for illustrating further a kind of far-infrared negative-ion pottery of the present invention; but the present invention is not limited to embodiment; every any simple modification, equivalent variations and modification above embodiment done according to the technical spirit of the present invention, all falls in the protection domain of technical solution of the present invention.
Claims (10)
1. a far-infrared negative-ion pottery, it is characterised in that comprise the component of following weight part:
Magnesium oxide 0.1 0.18 weight part calcium oxide 0.2 0.29 weight part potassium oxide 1.80 2.78 weight part aluminium sesquioxide 22 25 parts by weight of silica 71 72.4 weight part sodium oxide 0.23 0.28 weight part ferric oxide 0.1 0.13 parts by weight of tourmaline 13 weight part germanium oxide 13 weight part
Described far-infrared negative-ion pottery 4-18 micron far infrared transmissivity is 0.9-0.94, and the concentration of anion releasing is 1700-2000inos/cc.
2. far-infrared negative-ion according to claim 1 pottery, it is characterised in that be made up of by its weight percent following component:
Magnesium oxide 0.1 0.18%, calcium oxide 0.2 0.29%, potassium oxide 1.80 2.78%, aluminium sesquioxide 22 25%, silicon-dioxide 71 72.4%, sodium oxide 0.23 0.28%, ferric oxide 0.1 0.13%, tourmalinite 1 3%, germanium oxide 1 3%.
3. far-infrared negative-ion according to claim 2 pottery, it is characterised in that be made up of by its weight percent following component:
Magnesium oxide 0.14%, calcium oxide 0.23%, potassium oxide 2.05%, aluminium sesquioxide 22.08%, silicon-dioxide 71.15%, sodium oxide 0.24%, ferric oxide 0.11%, tourmalinite 2%, germanium oxide 2%.
4. the making method of a far-infrared negative-ion ceramic, it is characterised in that comprise the following steps:
(1) composition weight proportioning according to the arbitrary item of claim 1-3, get starting material mix after grinding, sieve, obtained far-infrared negative-ion ceramic powder;
(2) far-infrared negative-ion ceramic powder mixes with the ratio of paraffin by weight 100:10-20, stirs more than 30min in the temperature higher than 70 DEG C, and insulation 3-10h, forms blank;
(3) blank injects mould by the mode of extruding, peels off mould molding after cooling, forms base substrate;
(4) base substrate shave burr repair after in outer surface aluminium sesquioxide powder, calcine despumation through more than 800 DEG C;
(5) base substrate after calcining is by high pressure air gun spray dust removing;
(6) base substrate after dedusting is modulated through mineral color dyeing, glazing, in more than 1300 DEG C sintering, obtained can the far-infrared negative-ion ceramic of simultaneously emitting far-infrared and anion releasing.
5. making method according to claim 4, it is characterised in that: the middle degree particle diameter of described far-infrared negative-ion ceramic powder is 1um-5um.
6. making method according to claim 4, it is characterised in that: in step (2), the temperature range stirring and being incubated is 100-150 DEG C.
7. making method according to claim 4, it is characterised in that: in step (4), the purity of described alumina powder is 99-99.9%, and middle degree particle diameter is 10nm-30nm.
8. making method according to claim 4, it is characterised in that: in step (4), the time of described calcining is 2.5-4h.
9. making method according to claim 4, it is characterised in that: in step (6), described mineral color contains at least one of manganese, cobalt, iron, selenium, magnesium, praseodymium.
10. making method according to claim 4, it is characterised in that: in step (6), the time of described sintering is 6-10h.
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