CN107188532A - A kind of nano ceramics filtering material suitable for water process - Google Patents

A kind of nano ceramics filtering material suitable for water process Download PDF

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Publication number
CN107188532A
CN107188532A CN201710414926.9A CN201710414926A CN107188532A CN 107188532 A CN107188532 A CN 107188532A CN 201710414926 A CN201710414926 A CN 201710414926A CN 107188532 A CN107188532 A CN 107188532A
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water
nano
filtering material
nano ceramics
oxide
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王晓华
王玲玉
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Anhui Blue Crown Polytron Technologies Inc
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Anhui Blue Crown Polytron Technologies Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/14Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means with multiple outlet openings; with strainers in or outside the outlet opening
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Abstract

The invention discloses a kind of nano ceramics filtering material suitable for water process, it is made up of by weight percentage following components:Cerium oxide 5%~6%, zinc oxide 10%~12%, titanium oxide 16%~18%, germanium oxide 8%~10%, borax 16%~18%, rare earth element 0.5%~1%, remaining is ceramics.Its preparation method is that existing ceramics are modified using nano-powder and several mineral materials purification, it is separately added into cerium oxide, zinc oxide, titanium oxide, germanium oxide, borax, rare earth lanthanum element and tourmaline powder, using nanometer technology, the combination between crystal grain, crystal boundary and powder is set all to reach nanometer level, through being sintered at high temperature into negative oxygen ion nano-ceramic particle and negative oxygen ion nano ceramics plate.The nano-ceramic particle and nano ceramics plate being made of nano ceramics filtering material of the present invention are handled water, can form far infrared water, alkalescent water, negative oxygen ion water and small molecule ecologic active water.

Description

A kind of nano ceramics filtering material suitable for water process
Technical field
The present invention relates to a kind of nano ceramics filtering material suitable for water process, it is weak that the filtering material can produce far infrared Alkaline negative oxygen ion small molecule ecologic active water.
Background technology
First, can change water quality in the market gondola water faucet common at present has following several:
1st, removal of impurity gondola water faucet
Shower nozzle is easy to block after having used long due to water quality and quality, this kind of deimpurity general Logical gondola water faucet species is various, and outward appearance, function are varied, but can only remove some large particulate matters in water removal, and the change to water quality does not have There is any effect.
2nd, except the gondola water faucet of chlorine residue
National standard regulation running water chlorinty is greater than equal to 0.05 mg/litre, not upper limit requirement.Municipal administration is certainly A certain amount of chlorine residue must be kept in water, to ensure the microbiological indicator safety of drinking water, that is, prevents running water from dispatching from the factory After may cause " secondary pollution ".But when chlorine and organic acid reaction, many carcinogenic byproducts, such as three halogen first will be produced Alkane etc..More than a certain amount of chlorine, itself can also produce many harm to human body, and with niff, be commonly called as " bleaching powder Taste ".So outlet terminal effectively removes chlorine residue in water, injury of the chlorine to human body can be farthest reduced.
(1) with the washing bath containing chlorine residue, having four one-tenth in the total amount of chlorine in bathroom is sucked by respiratory tract, three one-tenth be by Skin absorbs, and is that, usually by drinking 6 to 8 times into chlorine in human body, the lighter produces itch, the carcinogenic probability increase of severe one 30%.
(2) when giving child bathing, chlorine can make hair produce dry and astringent fracture bifurcated, can also make skin bleachingization, and skin layer takes off Fall and produce allergy.When chlorine and organic matter such as sweat interact, agene in surrounding air is easily caused, easily Damage eyes and throat.Chlorine is sucked after lung by respiratory tract, can be damaged breathing cell, is easily caused asthma and pulmonary emphysema.
(3) it is long-term to drink the water containing chlorine residue and cause heart disease, coronary atherosclerosis, anaemia, carcinoma of urinary bladder, liver cancer, The symptom of the carcinoma of the rectum, hypertension and allergy.
In the market terminal water purification except chlorine residue mode it is very different, typically using charcoal absorption, KDF technologies or Asia Calcium sulfate water purification, removes the harmful substance in water in the way of adsorbing or chemically react.
1) charcoal absorption purification (physical cleaning), activated carbon internal pore structure is flourishing, specific surface area is big, adsorption capacity By force.Exactly these micropores enable activated carbon to adsorb various toxic and harmful gas and impurity, are purified water so as to clean water source.
2) KDF (chemical cleaning method) is a kind of copper of high-purity, zinc alloy granules, is a kind of new filter medium.Its is net Water principle is to utilize redox reaction, and KDF media carry out electron exchange with pollutant, and many polluters are become harmless object Matter, major function is the water-soluble heavy metal such as dechlorination and the such as lead, mercury, the cadmium that go in water removal.
During the water delivery pipe corrosion that ferrous materials are made, iron is aoxidized to form FeO colloids, and FeO is contacted with KDF, can also be sent out Raw redox reaction.
3) calcium sulfite (chemical cleaning method) is also advanced dechlorination water-purifying material at present.Calcium sulfite energy moment removes chemical combination Property chlorine residue, free residual chlorine, hypochlorous acid, hypochlorite ion, chlorine etc..
The shortcoming of prior art
1st, activated carbon water purification
(1) the super amount organic matter of charcoal absorption, these organic matters can turn into the nutrition of the microorganisms such as bacterium, bacterium Meeting amount reproduction hyperplasia in the micropore of activated carbon, and total plate count in water outlet may be caused exceeded.
(2) activated carbon in water purifier is nitrite nitrogen mineralized nitrogen in water, often gone out under microorganism catalysis effect Nitrite in existing water purifier discharge water is higher than intaking, and nitrite is not to lead carcinogen in itself, but it and amine in water The inferior ammonium nitrate of qualitative response generation is strong carcinogen.
2nd, KDF water purification
KDF and chlorine reaction generation zinc ion (Zn2+), may result in zinc in water exceeded.The reaction needs that KDF works Time, in fact any chemical reaction is required for the time, but time length has difference, and what KDF rose is redox reaction, it Reaction effect is relevant with several factors, for example water temperature, the turbidity of raw water, acid-base value of water etc., so low hydraulic pressure using effect Obvious, because water and KDF reaction time are long, normal hydraulic pressure KDF does not reach preferable clean-up effect.The current materials of KDF The price of material is also somewhat expensive, thus in certain price market purchasing power also have it is limited.
3rd, calcium sulfite water purification
Calcium sulfite is strong base-weak acid salt, is slightly soluble in water, shows alkalescence, pH value can be raised, during increasing amount water, it may appear that sulfuric acid Compound precipitation phenomenon.
4th, purification function is single, is easily blocked at terminal water outlet, and common gondola water faucet does not use one section comprehensively due to water purification ability Easily blocked at time terminal water outlet.
5th, existing gondola water faucet is it cannot be guaranteed that multifunctional purifying and with certain ageing at present, during one section of charcoal absorption Between after will lose original adsorption capacity, there is no good adsorption cleaning ability;By the purification that chemically reacts, cause in water Content of mineral substances changes.
Can change water quality above-mentioned nothing but this is several for existing gondola water faucet in the market, i.e., remaining in deimpurity, water removal Chlorine, heavy metal in water removal, and really be able to reach running water perfection purification, by being beneficial to the flower of human body after terminal water outlet Spill and not yet exist.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of nano ceramics filtering material suitable for water process.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is, a kind of nano ceramics suitable for water process Filtering material, is made up of by weight percentage following components:
Cerium oxide 5%~6%, zinc oxide 10%~12%, titanium oxide 16%~18%, germanium oxide 8%~10%, borax 16%~18%, rare earth lanthanum element 0.5%~1%, remaining is ceramics.
Nano ceramics filtering material is prepared by following methods:
The parts by weight ceramic particles such as general add cerium oxide at 2397 DEG C~2406 DEG C, and 1975 DEG C~1990 DEG C add oxidation Zinc, 1830 DEG C~1879 DEG C addition titanium oxide, 1086 DEG C~1115 DEG C addition germanium oxides, 880 DEG C of addition boraxs, through Rare Earth Lanthanum member Element catalysis, adds tourmaline powder, makes product formation nano-powder, and add water stirring shaping, it is sintered at high temperature into a diameter of 2~ Nano-ceramic particle or nano ceramics plate that 10mm and shapes and sizes differ.
Preferably, rare earth element is selected from lanthanum element
Water purification gondola water faucet with multiple water treatment function, including shower nozzle, the handle with hollow cavity and with hollow interior The upper end connection of the filter cylinder of chamber, shower nozzle and handle;The lower end connection of filter cylinder and handle;
The hollow cavity of handle and filter cylinder is filled with the nano ceramics being made of above-mentioned nano ceramics filtering material Particle.
Preferably, shower nozzle is provided with water outlet plate, water outlet plate uses the nano ceramics that above-mentioned nano ceramics filtering material is made Plate.
It is further preferred that, the thickness of water outlet plate is 6~10mm.
Preferably, the water inlet of handle and the water inlet of filter cylinder are respectively provided with filter screen;Filter screen is passed through using stainless steel filament Close weave is processed, and effective aperture reaches micron level.
Preferably, the lower end of filter cylinder and handle is connected by flexible pipe.
Negative oxygen ion nano ceramics is made using negative oxygen ion nano ceramics technology in the present invention:Specifically use nano-powder And several mineral materials purification existing ceramics are modified, be separately added into cerium oxide, zinc oxide, titanium oxide, germanium oxide, borax, Rare earth lanthanum element and tourmaline powder, using nanometer technology, make the combination between crystal grain, crystal boundary and powder all reach nanometer level, Through being sintered at high temperature into negative oxygen ion nano-ceramic particle and negative oxygen ion nano ceramics plate, the ceramic wafer is by nano-ceramic powder A diameter of 50~100mm is made, thickness is 6~10mm, and pore size is that 0.8~3.6nm can break up macromolecular mass water to be small Molecular water.The product intensity, toughness and superplasticity are increased substantially, and add its service life.Nano-ceramic particle hydraulic pressure, Under the impact of current, rotation, collision, friction, releasing negative oxygen ion, and launch wavelength 9~20um far infrared waves, its Normal Luminous Intensity Radiance more than 90%, negative oxygen ion burst size 1KG/s*m3
Above-mentioned filtering material can be applied in terms of water process, be such as applied to gondola water faucet and the fire hose is first-class.
The beneficial effects of the invention are as follows:
The nano-ceramic particle and nano ceramics plate being made of nano ceramics filtering material of the present invention are handled water, Far infrared water, alkalescent water, negative oxygen ion water and small molecule ecologic active water can be formed.
Brief description of the drawings
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
Fig. 1 is the water purification gondola water faucet structure schematic diagram of nano ceramics filtering material embodiment of the present invention.
Fig. 2 is the water purification shower handle structural representation of nano ceramics filtering material embodiment of the present invention.
Fig. 3 is the water purification gondola water faucet water outlet terminal assembly structural representation of nano ceramics filtering material embodiment of the present invention.
Fig. 4 is the gondola water faucet and water heater connection diagram of nano ceramics filtering material embodiment of the present invention.
In figure, 1- shower nozzles, 2- handles, 3- filter cylinders, 4- nano ceramics plates, 5- nano-ceramic particles, 6- flexible pipes.
Embodiment
Embodiment 1
A kind of nano ceramics filtering material, is made up of by weight percentage following components:
Cerium oxide 5%~6%, zinc oxide 10%~12%, titanium oxide 16%~18%, germanium oxide 8%~10%, borax 16%~18%, rare earth lanthanum element 0.5%~1%, remaining is ceramics;
The nano ceramics filtering material, is prepared by following methods:
The parts by weight ceramic particles such as general add cerium oxide at 2397 DEG C~2406 DEG C, and 1975 DEG C~1990 DEG C add oxidation Zinc, 1830 DEG C~1879 DEG C addition titanium oxide, 1086 DEG C~1115 DEG C addition germanium oxides, 880 DEG C of addition boraxs, through Rare Earth Lanthanum member Element catalysis, adds tourmaline powder, makes product formation nano-powder, and add water stirring shaping, it is sintered at high temperature into a diameter of 2~ Nano-ceramic particle or nano ceramics plate that 10mm and shapes and sizes differ.
Embodiment 2
The present embodiment is a kind of water purification gondola water faucet
Fig. 1 is a kind of water purification gondola water faucet, is made up of shower nozzle 1, handle 2 and filter cylinder 3.Shower nozzle 2 is connected with the upper end of handle 2, filter Cylinder 3 is connected with the lower end of handle.
Handle 2 and filter cylinder 3 are respectively provided with hollow cavity.
The hollow cavity of handle 2 is filled with nano-ceramic particle as filter core.
The hollow cavity of filter cylinder 3 is filled with same nano-ceramic particle as filter core.
In addition, being respectively provided with filter screen in the water inlet of handle and the water inlet of filter cylinder, filter screen is using stainless steel filament through tension Close braiding is processed, and effective aperture reaches micron level.
As shown in figure 3, the water outlet plate of shower nozzle is made up of nano ceramics plate, the nano ceramics plate used is also to be made pottery by nanometer Porcelain filtering material high temperature sintering is made.The thickness of water outlet plate is 7.5mm.
Above-mentioned water outlet plate is provided in below showerhead plate, and does not have any drilling above water outlet plate.Due to receiving There is certain gap after rice ceramic filter material high temperature sintering, by powerful hydraulic pressure so that current are from water outlet plate when using Gap in pass through and from the aperture on showerhead plate spray.
Filter cylinder 3 is connected with the lower end of handle 2 by flexible pipe.
As shown in figure 4, when installing, handle is connected with filter cylinder with flexible pipe, then filter cylinder is mounted in the delivery port of water heater, i.e., It can complete to install.
In use, opening water heater, the hot water that water heater is produced enters from the water inlet of filter cylinder, and respectively by filter cylinder The first filtering material and handle cavity in the second filtering material, finally again from the shower nozzle water outlet being made of nano ceramic material Sprayed in the aperture of plate, for shower or bathing.
By such filter cylinder, handle and shower nozzle three-stage filtration, the water sprayed from shower nozzle forms far infrared water, alkalescent Water, negative oxygen ion water and small molecule ecologic active water.
The gondola water faucet employs the operation principle of three-level catalysis:
(1) twice are catalyzed:It is made up of the nano-ceramic particle in filter cylinder and handle cavity, these nano-ceramic particles are in water Under pressure, the impact of current, rotation, collision, friction, releasing negative oxygen ion implement sterilization, purification, form far infrared alkalescent and bear Oxonium ion small molecule ecologic active water.
(2) it is catalyzed together:It is made up of the nano ceramics plate of shower nozzle, is located at the nano ceramics plate at shower nozzle and makees in hydraulic pressure Under, macromolecular is further broken into micromolecular water and sprayed.
The present embodiment can form far infrared water, alkalescent water, negative oxygen ion water, small molecule ecologic active water when in use, Numerical value is as shown in table 1 after testing:
Table 1
Item detection Gondola water faucet water detected value City tap-water national standard
Chloride content (mg/L) 0~0.06 0.3~250
PH value (alkalescent) 7.5~8.5 6.5~8.5
Soluble solid (mg/L) 194 <=1000
Anion synthetic detergent (mg/L) Nothing 0.3
Negative oxygen ion content (individual/cm3) 1800 600
The quantity (individual) of hydrone in micel 1~3 12
Basic test method and result
(1) chlorine residue is tested:It is separately added into remaining equivalent chlorine test agent in the water sample of three equivalent, observation color change can be with It was found that, chlorine residue is not contained in pure water, tap water contents of residual chlorine is higher, in the running water of purification gondola water faucet purification, chlorine residue is almost It is removed, color is close with pure water.
(2) active water is tested:Equivalent amount of active water test agent, ecosystem active water are separately added into the water sample of three equivalent It is presented red, yellow is presented in non-protogenous state water;Color change is observed it can be found that pure water is non-protogenous state water, running water is in Taken on a red color in existing faint red, the running water of purification gondola water faucet purification as ecosystem active water.
(3) calcium ions and magnesium ions are tested:Equivalent calcium ions and magnesium ions test agent is separately added into the water sample of three equivalent, experiment water is in Existing red, illustrates containing calcium ions and magnesium ions, and calcium ions and magnesium ions are not contained in blueness explanation;Observation color change can be found that three water samples In all contain calcium ions and magnesium ions.Illustrate that water purification gondola water faucet does not influence content micro- in water.
Use effect
(1) far infrared water
After percutaneous absorption far infrared, resonance is produced with hydrone in skin, strengthens its intermolecular adhesion, makes skin Inertia water (i.e. four hydrogen molecules and an oxygen molecule combination) in skin becomes separate aqueous (i.e. two hydrogen atoms and an oxygen Atom combination), improve body oxygen content, cell thus can rejuvenate.Separate aqueous can freely come in and go out between cell, then Through resonance, heat energy is converted into, the temperature microlitre of subcutaneous deep is made, the waste that metabolism is produced is excreted.
(2) alkalescent water
In also known as week-base water, natural weakly alkaline water, often containing a variety of nutrition such as potassium, calcium, sodium, magnesium, metasilicic acid Material, alkalescent water, which is used for a long time, in skin can improve Skin Cell environment, can improve acidic constitution, accelerate cell new old generation Thank.
(3) negative oxygen ion water
The electronics that negative oxygen ion water is produced by the friction of current, loses electronics and is referred to as oxidation, macromolecule is received in chemistry Rice ceramic particle is under hydraulic pressure, the impact of current, and hydrone is cut into many subsets by rotation, collision, friction, so that Obtained negatively charged active water, the molecules align of negative oxygen ion water is neat, cohesive force is strong, intermolecular absorption affinity is small, contains High efficiency energy, closest to human body cell water.Can active cell, raising cell life vigor, supplement repair cell film potential, enhancing Hematopoiesis function, purifies blood, removes blood rubbish, reduces blood viscosity, stimulates circulation, and activates brain cell, and skin care maintenance promotees Enter acidic constitution weak base, improve intracellular loops born of the same parents.
(4) ecologic active water
Light water is after the multiple filtrations such as sand filtration, carbon filtration, membrane filtration, then passes through the raw ion exchange of electricity with nanometer technology Device, acidic materials harmful in water are separated, and retain original mineral ion in water, with weak base Property, the water of subset feature.
(5) micromolecular water
Natural water passes through after good magnetization treatment, and water is cut into the ionized water rich in subset, micromolecular water With strong penetration, strong dissolving power, strong extension, alkalescent, human body cell is penetrated into, nutrition is supplied to cell, and handle Bacterium and toxin in cell are taken out of extracellular, are accelerated the circulation of skin fine vascular, are enhanced metabolism, show toxin expelling Ability.
Embodiment 3
The present embodiment is tap.
The water inlet end of the tap is provided with filling nano-ceramic particle or nano ceramics plate in cavity, cavity.
In use, from the water inlet of tap rear end, by filling the filtering of nano-ceramic particle or nano ceramics plate in cavity, The water outlet of tap forms far infrared water, alkalescent water, negative oxygen ion water and small molecule ecologic active water.
The embodiments of the present invention described above are not intended to limit the scope of the present invention.It is any in the present invention Spirit and principle within the modifications, equivalent substitutions and improvements made etc., should be included in the claim protection model of the present invention Within enclosing.

Claims (9)

1. a kind of nano ceramics filtering material suitable for water process, is made up of by weight percentage following components:
Cerium oxide 5%~6%, zinc oxide 10%~12%, titanium oxide 16%~18%, germanium oxide 8%~10%, borax 16% ~18%, rare earth element 0.5%~1%, remaining is ceramics.
2. nano ceramics filtering material as claimed in claim 1, it is characterised in that prepared by following methods:
The parts by weight ceramic particles such as general add cerium oxide at 2397 DEG C~2406 DEG C, and 1975 DEG C~1990 DEG C add zinc oxide, 1830 DEG C~1879 DEG C addition titanium oxide, 1086 DEG C~1115 DEG C addition germanium oxides, 880 DEG C of addition boraxs, through rare earth lanthanum element Catalysis, adds tourmaline powder, makes product formation nano-powder, and add water stirring shaping, is sintered at high temperature into a diameter of 2~10mm And the nano-ceramic particle or nano ceramics plate that shapes and sizes differ.
3. the water purification gondola water faucet with multiple water treatment function, including shower nozzle and the handle with hollow cavity, the shower nozzle and hand The upper end connection of handle;It is characterized in that:Also include the filter cylinder with hollow cavity;The lower end connection of the filter cylinder and handle;
The hollow cavity of the handle and filter cylinder is filled with using the nano ceramics filtering material described in claim 1 or 2 The nano-ceramic particle being made.
4. water purification gondola water faucet according to claim 3, it is characterised in that:The shower nozzle is provided with water outlet plate, and the water outlet plate is adopted The nano ceramics plate being made of the nano ceramics filtering material described in claim 1 or 2.
5. water purification gondola water faucet according to claim 3, it is characterised in that:The thickness of the water outlet plate is 6~10mm.
6. water purification gondola water faucet according to claim 3, it is characterised in that:The water inlet of the handle and the water inlet of filter cylinder are equal Filter screen is set;The filter screen is processed using stainless steel filament by close weave, and effective aperture reaches micron level.
7. the water purification gondola water faucet according to claim 3-6 any one, it is characterised in that:The lower end of the filter cylinder and handle leads to Cross flexible pipe connection.
8. the tap with multiple water treatment function, it is characterised in that the inner chamber of the tap is filled with will using right The nano-ceramic particle for asking the nano ceramics filtering material described in 1 to be made.
9. application of the nano ceramics filtering material as claimed in claim 1 in terms of water process.
CN201710414926.9A 2017-06-05 2017-06-05 A kind of nano ceramics filtering material suitable for water process Pending CN107188532A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046506A (en) * 2018-01-24 2018-05-18 珠海韵动热工技术有限公司 A kind of new photon energy negative ion ceramic ceramic shell water purifier

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CN101148353A (en) * 2007-08-21 2008-03-26 常州众博复合材料有限公司 Powder material capable of producing anion and preparation method thereof
CN105149121A (en) * 2015-08-07 2015-12-16 刘振 Novel multifunctional filter for sprinkler and top shower
CN105645938A (en) * 2014-11-10 2016-06-08 厦门美巨信息科技有限公司 Far-infrared negative-ion ceramic and preparation method thereof
CN205667751U (en) * 2016-05-20 2016-11-02 泉州市晋源消防水暖有限公司 A kind of water purification tap
CN206007120U (en) * 2016-06-18 2017-03-15 福建南安市九尊王洁具有限公司 A kind of domestic gondola water faucet

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Publication number Priority date Publication date Assignee Title
CN101148353A (en) * 2007-08-21 2008-03-26 常州众博复合材料有限公司 Powder material capable of producing anion and preparation method thereof
CN105645938A (en) * 2014-11-10 2016-06-08 厦门美巨信息科技有限公司 Far-infrared negative-ion ceramic and preparation method thereof
CN105149121A (en) * 2015-08-07 2015-12-16 刘振 Novel multifunctional filter for sprinkler and top shower
CN205667751U (en) * 2016-05-20 2016-11-02 泉州市晋源消防水暖有限公司 A kind of water purification tap
CN206007120U (en) * 2016-06-18 2017-03-15 福建南安市九尊王洁具有限公司 A kind of domestic gondola water faucet

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046506A (en) * 2018-01-24 2018-05-18 珠海韵动热工技术有限公司 A kind of new photon energy negative ion ceramic ceramic shell water purifier

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Application publication date: 20170922