CN103922810A - Bright red glaze for ceramic and method for producing ceramic products from bright red glaze - Google Patents
Bright red glaze for ceramic and method for producing ceramic products from bright red glaze Download PDFInfo
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- CN103922810A CN103922810A CN201410143644.6A CN201410143644A CN103922810A CN 103922810 A CN103922810 A CN 103922810A CN 201410143644 A CN201410143644 A CN 201410143644A CN 103922810 A CN103922810 A CN 103922810A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052742 iron Inorganic materials 0.000 claims abstract description 22
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 12
- 239000002893 slag Substances 0.000 claims abstract description 10
- 239000004575 stone Substances 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 6
- 239000010433 feldspar Substances 0.000 claims abstract description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims abstract description 4
- 210000003298 dental enamel Anatomy 0.000 claims description 51
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 27
- 238000001354 calcination Methods 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000002360 preparation method Methods 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- 238000000498 ball milling Methods 0.000 claims description 10
- 241000272814 Anser sp. Species 0.000 claims description 7
- 241001494479 Pecora Species 0.000 claims description 7
- AQCDIIAORKRFCD-UHFFFAOYSA-N cadmium selenide Chemical compound [Cd]=[Se] AQCDIIAORKRFCD-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000006148 magnetic separator Substances 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000004021 humic acid Substances 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- -1 zirconium silicates Chemical class 0.000 claims description 5
- 229910052593 corundum Inorganic materials 0.000 abstract description 3
- GNRZYLVLEDQAKH-UHFFFAOYSA-N 5,7-dihydroxy-2-methyl-6,8-bis(3-methylbut-2-enyl)chromen-4-one Chemical compound O1C(C)=CC(=O)C2=C(O)C(CC=C(C)C)=C(O)C(CC=C(C)C)=C21 GNRZYLVLEDQAKH-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052656 albite Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 abstract 1
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 abstract 1
- 229940093474 manganese carbonate Drugs 0.000 abstract 1
- 235000006748 manganese carbonate Nutrition 0.000 abstract 1
- 239000011656 manganese carbonate Substances 0.000 abstract 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 abstract 1
- 238000000227 grinding Methods 0.000 description 7
- 229910052573 porcelain Inorganic materials 0.000 description 6
- 238000010304 firing Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000001062 red colorant Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910006501 ZrSiO Inorganic materials 0.000 description 1
- LFZDEAVRTJKYAF-UHFFFAOYSA-L barium(2+) 2-[(2-hydroxynaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical group [Ba+2].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21.C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 LFZDEAVRTJKYAF-UHFFFAOYSA-L 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention relates to a bright red glaze for ceramic and a method for producing ceramic products from the bright red glaze. The base glaze comprises feldspar, Eyangshan Stone, wattenschlick, pulverin, calcite, calcined barium carbonate, manganese oxide powder, industrial iron ore slag, calcined iron red and manganese carbonate; the cover glaze comprises albite, calcite, kaolin, zirconium silicate, calcined barium carbonate and coated cadmium selenide red; the Eyangshan Stone comprises the following components: 92.83% of SiO2, 1.90% of Al2O3, 0.81% of Fe2O3, 1.19% of CaO, 1.70% of MgO, 1.29% of K2O and Na2O and 0.41% of ignition loss (IL). The uniform black spots come out regularly in red glaze prepared by the invention and the bright red glaze is noble and elegant.
Description
Technical field
The invention belongs to ceramic glaze production technical field, be specifically related to a kind of scarlet glaze material for ceramics and make ceramic product method.
Background technology
Red porcelain except its gloss color all good, more because being difficult to burn till, it becomes treasure in porcelain, as equal red porcelain, hold a memorial ceremony for red porcelain, Lang Hong porcelain etc., its color form and aspect and purplish red or red-brown are close, China and foreign countries' ceramist all attempts to burn out the large red porcelain that people dream of in recent years.Along with the breakthrough of technology on beramic color, packed cadmium selenium red colorant [Cd (Se
xs
1-x)-ZrSiO
4] increase again much brilliance for ceramic high temperature color glaze.
Summary of the invention
The object of this invention is to provide a kind of scarlet glaze material for ceramics and make the method for ceramic product.
Scarlet glaze material for ceramics provided by the invention, comprises ground-coat enamel and cover-coat enamel, consists of by weight:
Ground-coat enamel: 12 ~ 18 parts of feldspars, 25 ~ 35 parts, goose sheep mountain stone, 25 ~ 35 parts of wattenshlicks, 12 ~ 18 parts, plant ash, 10 ~ 12 parts, calcite, 5 ~ 8 parts of barium carbonates of calcining, 4 ~ 6 parts of manganese powders of oxidation, 10 ~ 15 parts, industrial iron ore slag, 1 ~ 3 part of iron oxide red of calcining, 1 ~ 3 part of manganous carbonate;
Cover-coat enamel: 60 ~ 100 parts of albites, 8 ~ 12 parts, calcite, 8 ~ 12 parts of kaolin, 3 ~ 5 parts of zirconium silicates, 4 ~ 6 parts of barium carbonates of calcining, packed cadmium selenium red 10 ~ 15 parts;
Described goose sheep mountain stone composition is: SiO
292.83%, Al
2o
31.90%, Fe
2o
30.81%, CaO 1.19%, MgO 1.70%, K
2o+Na
2o 1.29%, burning decrement IL 0.41%.
Described wattenshlick composition is preferably: SiO
251.74%, Al
2o
316.34%, Fe
2o
36.98%, CaO 6.23%, MgO 1.43%, K
2o+Na
2o 3.91%, burning decrement IL 9.18%.
Described calcining iron oxide red is that iron oxide red makes after 1250 DEG C of calcination.
The preparation method of above-mentioned scarlet glaze material for ceramics, comprising:
(1) preparation of ground-coat enamel, by raw material: ballstone: water=1:1.5 ~ 2:0.5 ~ 0.8 ball milling, fineness is that 250 mesh sieves tail over and are less than 0.5%;
(2) preparation of cover-coat enamel, by raw material: ballstone: water=1:1.5 ~ 2:0.5 ~ 0.8 ball milling, fineness is that 250 mesh sieves tail over and are less than 1%.
As improvement, in the preparation of step (2) cover-coat enamel, also carry out magnetic separator and inhale iron.
The scarlet glaze material for ceramics of above-mentioned preparation is made to the method for ceramic product; comprise: the glazing on ceramic body by ground-coat enamel and cover-coat enamel; adopt oxydizing flame to fire the ceramic body of first-class glaze; be raised to 300 DEG C by 95 ~ 105 DEG C of intensifications per hour; then be raised to 700 DEG C by 145 ~ 155 DEG C of intensifications per hour; finally be raised to 1250 DEG C by 190 ~ 210 DEG C of intensifications per hour, the cooling down of then ceasing fire.
As improvement, first ground-coat enamel is diluted to 50 ~ 70 degree Beaume with the Sodium salts humic acids aqueous solution, then to be diluted to clear water be 40 ~ 45 degree Beaume; Water glass for cover-coat enamel (aqueous solution of water glass) is diluted to 62 ~ 65 degree Beaume, then to be diluted to clear water be 45 ~ 50 degree Beaume, then glazing.
Preferably adopt glaze method glazing, ground-coat enamel gauge control is at 0.9 ~ 1.1mm left and right, cover-coat enamel gauge control 1.5-1.8mm.Preferably burn till with shuttle kiln or roller kiln.
Ground-coat enamel of the present invention is black touched with red without cobalt black color glaze, cover-coat enamel is that packed cadmium selenium red colorant is the red glaze of making toner, the improvement of composition and firing process by ground-coat enamel and cover-coat enamel, adjust the coefficient of expansion of base and glaze, making glaze produce liquid phase separation is made, regularly in the red glaze of making separate out even stain, just as the solar flare of separating out under the sun, elegant.
Embodiment
The present invention goose sheep used mountain stone is taken from Bei Eyang mountain, suburbs, Changsha, does not need exploitation, and its composition is: SiO
292.83%, Al
2o
31.90%, Fe
2o
30.81%, CaO 1.19%, MgO 1.70%, K
2o/Na
2o 1.29%, burning decrement IL 0.41%; Dongting Lake wattenshlick used is taken from Dongting Lake lake region, and its composition is: SiO
251.74%, Al
2o
316.34%, Fe
2o
36.98%, CaO 6.23%, MgO 1.43%, K
2o/Na
2o 3.91%, burning decrement IL 9.18%; It is more than institute of ceramic research inspection center of Hunan Province result of laboratory test.
The present invention's calcining barium carbonate used is barium oxide; Calcining iron oxide red is that iron oxide red (ferric oxide) makes after 1250 DEG C of calcination; In specific embodiment, iron ore slag derives from the iron ore slag waste that chemical plant, Zhuzhou produces; In embodiment, emerging 2845 bright red (AP2845) in Red pigment used Taiwan ten thousand, are a kind of packed cadmium selenium red colorants, purchased from South Sea Wan Xing mineral dye company limited.Following raw material by weight.
Embodiment 1
Prepare in the steps below scarlet glaze material for ceramics of the present invention, and be made into ceramic product:
By primary industry iron ore slag and calcining iron oxide red, respectively ball milling 60 hours is for subsequent use in advance, and 250 mesh sieves tail over and are less than 0.01%, can better reach so the final fineness requirement of ground-coat enamel.
(1) preparation of ground-coat enamel: by 15 parts of feldspars, 30 parts, Changsha E Yangshan stone, 30 parts of Dongting Lake wattenshlicks, 15 parts, plant ash, 11 parts, calcite, 6 parts of barium carbonates of calcining, 5 parts of manganese powders of oxidation, 12 parts, the industrial iron ore slag that ball milling is crossed in advance, 2 parts of calcining iron oxide reds, 2 parts of the manganous carbonates that ball milling is crossed in advance; By expecting: ball: water=1:1.5:0.6 mixes, wet ball grinding 18 hours, glaze slip is crossed 250 mesh sieves, tails over and is less than 0.5%.
(2) preparation of cover-coat enamel: 80 parts of albites, 10 parts, calcite, 10 parts of kaolin, 4 parts of zirconium silicates, 5 parts of barium carbonates of calcining, Taiwan ten thousand emerging 2845 bright red 12 parts; By expecting: ball: water=1:1.5:0.6 mixes, wet ball grinding 16 hours, glaze slip is crossed 250 mesh sieves, tails over and is less than 1%, and magnetic separator is inhaled iron twice.Cover-coat enamel can not be sneaked into irony in fine grinding process, in order to avoid affect color development effect, after going out ball mill and sieving, magnetic separator is inhaled iron.Mill lining can use corundum, rubber mass, and mill body can be used corundum ball, Dalian ballstone etc.
(3) glazing: with 50% Sodium salts humic acids aqueous solution dilution ground-coat enamel to 60 degree Beaume, then to be diluted to clear water be that 43 degree Beaume are for subsequent use; Cover-coat enamel is diluted to 50 degree Beaume with water glass, then to be diluted to clear water be 48 degree Beaume.Then adopt glaze method to ceramic body glazing, ground-coat enamel gauge control is in 1mm left and right, about cover-coat enamel gauge control 1.5-1.8mm.
(4) fire: sintering curve: 100-300 DEG C heats up slowly, 100 DEG C of liters per hour; 300-700 DEG C, 150 DEG C of intensifications per hour; 700-1250 DEG C, 200 DEG C of intensifications per hour.Employing oxydizing flame burns till, 1250 DEG C of left and right of terminal firing temperature, the cooling down of then ceasing fire.Available shuttle kiln or roller kiln burn till, and can improve the raising of kiln room temp, temperature be uniformly distributed the use of adding accurate temperature measurement instrument with the control of kiln internal ambience, make to fire more stable, fire quality and greatly improve.
Embodiment 2
Be prepared scarlet glaze material for ceramics of the present invention by the method for embodiment 1 and step, and be made into ceramic product.
(1) preparation of ground-coat enamel: by 18 parts of feldspars, 25 parts, goose sheep mountain stone, 35 parts of wattenshlicks, 18 parts, plant ash, 12 parts, calcite, 8 parts of barium carbonates of calcining, 6 parts of manganese powders of oxidation, 15 parts, industrial iron ore slag, 3 parts of iron oxide reds of calcining, 3 parts of manganous carbonates; By expecting: ball: water=1:1.5:0.5 mixes, wet ball grinding 20 hours, glaze slip is crossed 250 mesh sieves, tails over and is less than 0.5%.
(2) preparation of cover-coat enamel: 60 parts of albites, 12 parts, calcite, 12 parts of kaolin, 5 parts of zirconium silicates, 6 parts of barium carbonates of calcining, packed cadmium selenium red 15 parts; By expecting: ball: water=1:1.5:0.5 mixes, wet ball grinding 15 hours, glaze slip is crossed 250 mesh sieves, tails over and is less than 1%, and magnetic separator is inhaled iron twice.
(3) glazing: with 50% Sodium salts humic acids aqueous solution dilution ground-coat enamel to 50 degree Beaume, then to be diluted to clear water be that 40 degree Beaume are for subsequent use; Cover-coat enamel is diluted to 62 degree Beaume with water glass, then to be diluted to clear water be 45 degree Beaume.Then adopt glaze method to ceramic body glazing, ground-coat enamel gauge control is in 0.9 ~ 1.1mm left and right, about cover-coat enamel gauge control 1.5-1.8mm.
(4) fire: sintering curve: 100-300 DEG C heats up slowly, 95 DEG C of liters per hour; 300-700 DEG C, 114 DEG C of intensifications per hour; 700-1250 DEG C, 190 DEG C of intensifications per hour.Adopt roller kiln, oxydizing flame to burn till, 1250 DEG C of left and right of terminal firing temperature, the cooling down of then ceasing fire.
Embodiment 3
Be prepared scarlet glaze material for ceramics of the present invention by the method for embodiment 1 and step, and be made into ceramic product.
(1) preparation of ground-coat enamel: by 12 parts of feldspars, 35 parts, goose sheep mountain stone, 25 parts of wattenshlicks, 12 parts, plant ash, 10 parts, calcite, 5 parts of barium carbonates of calcining, 4 parts of manganese powders of oxidation, 10 parts, industrial iron ore slag, 1 part of iron oxide red of calcining, 1 part of manganous carbonate; By expecting: ball: water=1:2:0.8 mixes, wet ball grinding 16 hours, glaze slip is crossed 250 mesh sieves, tails over and is less than 0.5%.
(2) preparation of cover-coat enamel: 100 parts of albites, 8 parts, calcite, 8 parts of kaolin, 3 parts of zirconium silicates, 4 parts of barium carbonates of calcining, packed cadmium selenium red 10 parts; By expecting: ball: water=1:2:0.8 mixes, wet ball grinding 16 hours, glaze slip is crossed 250 mesh sieves, tails over and is less than 1%, and magnetic separator is inhaled iron twice.
(3) glazing: with 50% Sodium salts humic acids aqueous solution dilution ground-coat enamel to 70 degree Beaume, then to be diluted to clear water be that 45 degree Beaume are for subsequent use; Cover-coat enamel is diluted to 65 degree Beaume with water glass, then to be diluted to clear water be 50 degree Beaume.Then adopt glaze method to ceramic body glazing, ground-coat enamel gauge control is in 0.9 ~ 1.1mm left and right, about cover-coat enamel gauge control 1.5-1.8mm.
(4) fire: sintering curve: 100-300 DEG C heats up slowly, 105 DEG C of liters per hour; 300-700 DEG C, 155 DEG C of intensifications per hour; 700-1250 DEG C, 210 DEG C of intensifications per hour.Adopt shuttle kiln, oxydizing flame to burn till, 1250 DEG C of left and right of terminal firing temperature, the cooling down of then ceasing fire.
Claims (10)
1. a scarlet glaze material for ceramics, comprises ground-coat enamel and cover-coat enamel, consists of by weight:
Ground-coat enamel: 12 ~ 18 parts of feldspars, 25 ~ 35 parts, goose sheep mountain stone, 25 ~ 35 parts of wattenshlicks, 12 ~ 18 parts, plant ash, 10 ~ 12 parts, calcite, 5 ~ 8 parts of barium carbonates of calcining, 4 ~ 6 parts of manganese powders of oxidation, 10 ~ 15 parts, industrial iron ore slag, 1 ~ 3 part of iron oxide red of calcining, 1 ~ 3 part of manganous carbonate;
Cover-coat enamel: 60 ~ 100 parts of albites, 8 ~ 12 parts, calcite, 8 ~ 12 parts of kaolin, 3 ~ 5 parts of zirconium silicates, 4 ~ 6 parts of barium carbonates of calcining, packed cadmium selenium red 10 ~ 15 parts;
Described goose sheep mountain stone composition is: SiO
292.83%, Al
2o
31.90%, Fe
2o
30.81%, CaO 1.19%, MgO 1.70%, K
2o+Na
2o 1.29%, burning decrement IL 0.41%.
2. scarlet glaze material for ceramics according to claim 1, is characterized in that described wattenshlick composition is: SiO
251.74%, Al
2o
316.34%, Fe
2o
36.98%, CaO 6.23%, MgO 1.43%, K
2o+Na
2o 3.91%, burning decrement IL 9.18%.
3. scarlet glaze material for ceramics according to claim 1 and 2, is characterized in that described calcining iron oxide red is that iron oxide red makes after 1250 DEG C of calcination.
4. a preparation method for scarlet glaze material for ceramics claimed in claim 1, comprising:
(1) preparation of ground-coat enamel, by raw material: ballstone: water=1:1.5 ~ 2:0.5 ~ 0.8 ball milling, fineness is that 250 mesh sieves tail over and are less than 0.5%;
(2) preparation of cover-coat enamel, by raw material: ballstone: water=1:1.5 ~ 2:0.5 ~ 0.8 ball milling, fineness is that 250 mesh sieves tail over and are less than 1.0%.
5. the preparation method of scarlet glaze material for ceramics according to claim 4, is characterized in that in the preparation of step (2) cover-coat enamel, also carrying out magnetic separator inhales iron.
6. according to the preparation method of the scarlet glaze material for ceramics described in claim 4 or 5, it is characterized in that first industrial iron ore slag and calcining iron oxide red ball milling being distinguished to ball milling in advance before ground-coat enamel ball milling, 250 mesh sieves tail over and are less than 0.01%.
7. the scarlet glaze material for ceramics by one of claim 4-6 preparation is made the method for ceramic product; comprise: the glazing on ceramic body by ground-coat enamel and cover-coat enamel; adopt oxydizing flame to fire the ceramic body of first-class glaze; be raised to 300 DEG C by 95 ~ 105 DEG C of intensifications per hour; then be raised to 700 DEG C by 145 ~ 155 DEG C of intensifications per hour; finally be raised to 1250 DEG C by 190 ~ 210 DEG C of intensifications per hour, the cooling down of then ceasing fire.
8. the method for making ceramic product according to claim 7, is characterized in that first the ground-coat enamel Sodium salts humic acids aqueous solution being diluted to 50 ~ 70 degree Beaume, then to be diluted to clear water be 40 ~ 45 degree Beaume; Cover-coat enamel is diluted to 62 ~ 65 degree Beaume with water glass, then to be diluted to clear water be 45 ~ 50 degree Beaume, then glazing.
9. according to the method for making ceramic product described in claim 7 or 8, it is characterized in that adopting glaze method glazing, ground-coat enamel gauge control is at 0.9 ~ 1.1mm left and right, cover-coat enamel gauge control 1.5-1.8mm.
10. according to the method for making ceramic product described in claim 7 or 8, it is characterized in that burning till with shuttle kiln or roller kiln.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410143644.6A CN103922810B (en) | 2014-04-11 | 2014-04-11 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410143644.6A CN103922810B (en) | 2014-04-11 | 2014-04-11 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103922810A true CN103922810A (en) | 2014-07-16 |
| CN103922810B CN103922810B (en) | 2015-05-20 |
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|---|---|---|---|
| CN201410143644.6A Expired - Fee Related CN103922810B (en) | 2014-04-11 | 2014-04-11 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
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| CN106186689A (en) * | 2016-06-27 | 2016-12-07 | 丽水学院 | A kind of for preparing the frit of Longquan celadon, Longquan celadon fritted glaze and the preparation method of this fritted glaze |
| CN107352798A (en) * | 2017-09-01 | 2017-11-17 | 王向群 | A kind of iron oxide red fancy glaze and preparation method thereof |
| CN107445482A (en) * | 2017-08-07 | 2017-12-08 | 昆明理工大学 | A kind of glaze using discarded object and the ceramic preparation using the glaze |
| CN108840566A (en) * | 2018-08-17 | 2018-11-20 | 湖南德兴瓷业有限公司 | Red glaze of low temperature and preparation method thereof |
| CN108975702A (en) * | 2018-09-17 | 2018-12-11 | 泉州市陶瓷科学技术研究所 | Utilize the rust red glaze porcelain and its preparation process of the preparation of magnet mine tailings |
| CN113860923A (en) * | 2021-09-26 | 2021-12-31 | 蒙娜丽莎集团股份有限公司 | Bright red rock glaze and preparation method thereof |
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| JP2005350327A (en) * | 2004-06-14 | 2005-12-22 | Inax Corp | Decorated ceramic body, its production method, and glaze preparation |
| CN103224413A (en) * | 2013-04-06 | 2013-07-31 | 湖南益嘉瓷业有限公司 | Producing method of violet gold glaze |
| CN103553715A (en) * | 2013-10-08 | 2014-02-05 | 东莞市高诚陶瓷制品有限公司 | Oxidation reaction glaze material |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106186689A (en) * | 2016-06-27 | 2016-12-07 | 丽水学院 | A kind of for preparing the frit of Longquan celadon, Longquan celadon fritted glaze and the preparation method of this fritted glaze |
| CN106186689B (en) * | 2016-06-27 | 2018-11-20 | 丽水学院 | A kind of preparation method of the frit for being used to prepare Longquan celadon, Longquan celadon fritted glaze and the fritted glaze |
| CN107445482A (en) * | 2017-08-07 | 2017-12-08 | 昆明理工大学 | A kind of glaze using discarded object and the ceramic preparation using the glaze |
| CN107445482B (en) * | 2017-08-07 | 2021-01-19 | 昆明理工大学 | Glaze prepared from waste and ceramic preparation method using glaze |
| CN107352798A (en) * | 2017-09-01 | 2017-11-17 | 王向群 | A kind of iron oxide red fancy glaze and preparation method thereof |
| CN108840566A (en) * | 2018-08-17 | 2018-11-20 | 湖南德兴瓷业有限公司 | Red glaze of low temperature and preparation method thereof |
| CN108840566B (en) * | 2018-08-17 | 2021-06-22 | 湖南德兴瓷业有限公司 | Low-temperature red glaze and preparation method thereof |
| CN108975702A (en) * | 2018-09-17 | 2018-12-11 | 泉州市陶瓷科学技术研究所 | Utilize the rust red glaze porcelain and its preparation process of the preparation of magnet mine tailings |
| CN113860923A (en) * | 2021-09-26 | 2021-12-31 | 蒙娜丽莎集团股份有限公司 | Bright red rock glaze and preparation method thereof |
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| CN103922810B (en) | 2015-05-20 |
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