CN108840566B - Low-temperature red glaze and preparation method thereof - Google Patents
Low-temperature red glaze and preparation method thereof Download PDFInfo
- Publication number
- CN108840566B CN108840566B CN201810938050.2A CN201810938050A CN108840566B CN 108840566 B CN108840566 B CN 108840566B CN 201810938050 A CN201810938050 A CN 201810938050A CN 108840566 B CN108840566 B CN 108840566B
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- glaze
- oxide
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- temperature red
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- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000292 calcium oxide Substances 0.000 claims abstract description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012535 impurity Substances 0.000 claims abstract description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 4
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 4
- 239000011669 selenium Substances 0.000 claims abstract description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000003631 expected effect Effects 0.000 description 1
- -1 ferrous metal oxides Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a low-temperature red glaze and a preparation method thereof, wherein a glaze used for the low-temperature red glaze comprises the following components in percentage by mass: 65% of silicon dioxide, 20% of aluminum oxide, 0.05% of ferric oxide, 2.8% of potassium oxide, 2.3% of sodium oxide, 0.14% of magnesium oxide, 0.3% of calcium oxide, 6% of selenium, 0.01% of titanium oxide and the balance of inevitable impurities, wherein the total content is 100%. The invention can greatly reduce the expansion coefficient of the glaze, thereby matching the expansion coefficients of the glaze and the blank and preventing the phenomenon of glaze stripping.
Description
Technical Field
The invention relates to a low-temperature red glaze and a preparation method thereof.
Background
At present, ceramic colored glaze is mainly some non-ferrous metal oxides, salts or double salts, and many colored glazes can be decomposed and discolored due to high-temperature calcination and can only be colored at low temperature, so the ceramic colored glaze is called as low-temperature colored glaze. However, the firing temperature of the low-temperature red glaze is 750-950 ℃, and the ceramic body must be fired at high temperature first and then decorated with the low-temperature red glaze at the temperature, but at the same time, a new problem occurs, namely the glaze is stripped during the firing process of the ceramic, so that the defects are caused.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the low-temperature red glaze which can greatly reduce the expansion coefficient of the glaze, so that the expansion coefficients of the glaze and a blank are matched, and the phenomenon of glaze stripping is prevented.
In order to solve the technical problems, the technical scheme of the invention is as follows: the low-temperature red glaze comprises the following components in percentage by mass: 65% of silicon dioxide, 20% of aluminum oxide, 0.05% of ferric oxide, 2.8% of potassium oxide, 2.3% of sodium oxide, 0.14% of magnesium oxide, 0.3% of calcium oxide, 6% of selenium, 0.01% of titanium oxide and the balance of inevitable impurities, wherein the total content is 100%.
The invention also provides a preparation method of the low-temperature red glaze, which comprises the following steps:
s1: preparing materials according to the components and the parts by mass of the components of the glaze:
s2: according to the material: ball: the mass ratio of water is 1: 1.75: 1.5, performing wet ball milling for 19-21 hours;
s3: after sieving and deironing the ball-milled glaze, adjusting the glaze into glaze slip with the concentration of 45-60 baume degrees;
s4: after the blank body with smooth surface is immersed in the glaze slip, the finished product is sintered under the oxidizing atmosphere of 750-950 ℃.
After the technical scheme is adopted, the low-molecular-weight alkaline oxide is added to replace the high-molecular-weight oxidation flux according to the ratio of the number of the same molecules, so that the content of the silicon dioxide is correspondingly increased actually, the expansion coefficient of the glaze can be greatly reduced due to the increase of the content of the silicon dioxide, the expansion coefficients of the glaze and the blank are matched, and the phenomenon of glaze stripping is prevented.
Detailed Description
In order that the present invention may be more clearly understood, the following detailed description of the present invention is given with reference to specific examples.
The low-temperature red glaze comprises the following components in percentage by mass: 65% of silicon dioxide, 20% of aluminum oxide, 0.05% of ferric oxide, 2.8% of potassium oxide, 2.3% of sodium oxide, 0.14% of magnesium oxide, 0.3% of calcium oxide, 6% of selenium, 0.01% of titanium oxide and the balance of inevitable impurities, wherein the total content is 100%.
The preparation method of the low-temperature red glaze comprises the following steps:
s1: preparing materials according to the components and the parts by mass of the components of the glaze:
s2: according to the material: ball: the mass ratio of water is 1: 1.75: 1.5, performing wet ball milling for 19-21 hours;
s3: after sieving and deironing the ball-milled glaze, adjusting the glaze into glaze slip with the concentration of 45-60 baume degrees;
s4: after the blank body with smooth surface is immersed in the glaze slip, the finished product is sintered under the oxidizing atmosphere of 750-950 ℃.
The observation shows that the glaze surface of the low-temperature red glaze prepared by the embodiment has no glaze stripping phenomenon, and the expected effect is achieved.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are only exemplary embodiments of the present invention, and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (1)
1. The preparation method of the low-temperature red glaze is characterized in that the glaze used for the low-temperature red glaze comprises the following components in percentage by mass: 65% of silicon dioxide, 20% of aluminum oxide, 0.05% of ferric oxide, 2.8% of potassium oxide, 2.3% of sodium oxide, 0.14% of magnesium oxide, 0.3% of calcium oxide, 6% of selenium, 0.01% of titanium oxide and the balance of inevitable impurities, wherein the total content is 100%; the method comprises the following steps:
s1: preparing materials according to the components and the parts by mass of the components of the glaze:
s2: according to the material: ball: the mass ratio of water is 1: 1.75: 1.5, performing wet ball milling for 19-21 hours;
s3: after sieving and deironing the ball-milled glaze, adjusting the glaze into glaze slip with the concentration of 45-60 baume degrees;
s4: after the blank body with smooth surface is immersed in the glaze slip, the finished product is sintered under the oxidizing atmosphere of 750-950 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810938050.2A CN108840566B (en) | 2018-08-17 | 2018-08-17 | Low-temperature red glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810938050.2A CN108840566B (en) | 2018-08-17 | 2018-08-17 | Low-temperature red glaze and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108840566A CN108840566A (en) | 2018-11-20 |
| CN108840566B true CN108840566B (en) | 2021-06-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810938050.2A Active CN108840566B (en) | 2018-08-17 | 2018-08-17 | Low-temperature red glaze and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN108840566B (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1144200A (en) * | 1995-08-29 | 1997-03-05 | 天津市玻璃器皿厂 | Enriched selenium red glass colouring agent and its use |
| CN1962557A (en) * | 2006-12-06 | 2007-05-16 | 江苏高淳陶瓷股份有限公司 | Ceramic scarlet-variable glaze and its application method |
| CN101054478A (en) * | 2006-04-11 | 2007-10-17 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Lead-free low-cadmium stripping quantity selenium-cadmium dye, preparing method and using method thereof |
| CN102515862A (en) * | 2011-12-14 | 2012-06-27 | 广东松发陶瓷股份有限公司 | Bright red glaze for decoration |
| CN103922810A (en) * | 2014-04-11 | 2014-07-16 | 望城县铜官窑创伟陶艺坊 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
| CN106348599A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Vermilion glaze and preparation method thereof |
| CN106430970A (en) * | 2015-08-07 | 2017-02-22 | 费罗公司 | Nickel-free and chromium-free forehearth colors for glass tanks |
| CN106542812A (en) * | 2016-09-26 | 2017-03-29 | 广东协进陶瓷有限公司 | A kind of magic glazed tile and its production method |
| CN206069715U (en) * | 2016-09-26 | 2017-04-05 | 广东协进陶瓷有限公司 | A kind of production line of magic glazed tile |
| CN107651834A (en) * | 2017-10-30 | 2018-02-02 | 江苏拜富科技有限公司 | Low temperature coloured glass red stain and preparation method thereof and application method |
-
2018
- 2018-08-17 CN CN201810938050.2A patent/CN108840566B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1144200A (en) * | 1995-08-29 | 1997-03-05 | 天津市玻璃器皿厂 | Enriched selenium red glass colouring agent and its use |
| CN101054478A (en) * | 2006-04-11 | 2007-10-17 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Lead-free low-cadmium stripping quantity selenium-cadmium dye, preparing method and using method thereof |
| CN1962557A (en) * | 2006-12-06 | 2007-05-16 | 江苏高淳陶瓷股份有限公司 | Ceramic scarlet-variable glaze and its application method |
| CN102515862A (en) * | 2011-12-14 | 2012-06-27 | 广东松发陶瓷股份有限公司 | Bright red glaze for decoration |
| CN103922810A (en) * | 2014-04-11 | 2014-07-16 | 望城县铜官窑创伟陶艺坊 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
| CN106430970A (en) * | 2015-08-07 | 2017-02-22 | 费罗公司 | Nickel-free and chromium-free forehearth colors for glass tanks |
| CN106348599A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Vermilion glaze and preparation method thereof |
| CN106542812A (en) * | 2016-09-26 | 2017-03-29 | 广东协进陶瓷有限公司 | A kind of magic glazed tile and its production method |
| CN206069715U (en) * | 2016-09-26 | 2017-04-05 | 广东协进陶瓷有限公司 | A kind of production line of magic glazed tile |
| CN107651834A (en) * | 2017-10-30 | 2018-02-02 | 江苏拜富科技有限公司 | Low temperature coloured glass red stain and preparation method thereof and application method |
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| Publication number | Publication date |
|---|---|
| CN108840566A (en) | 2018-11-20 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Low temperature red glaze and its preparation method Granted publication date: 20210622 Pledgee: Zhuzhou Branch of China Everbright Bank Co.,Ltd. Pledgor: HUNAN DEXING CERAMICS Co.,Ltd. Registration number: Y2024980014569 |
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