CN108840566A - Red glaze of low temperature and preparation method thereof - Google Patents
Red glaze of low temperature and preparation method thereof Download PDFInfo
- Publication number
- CN108840566A CN108840566A CN201810938050.2A CN201810938050A CN108840566A CN 108840566 A CN108840566 A CN 108840566A CN 201810938050 A CN201810938050 A CN 201810938050A CN 108840566 A CN108840566 A CN 108840566A
- Authority
- CN
- China
- Prior art keywords
- glaze
- low temperature
- oxide
- component
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims abstract description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 4
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 4
- 239000011669 selenium Substances 0.000 claims abstract description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000292 calcium oxide Substances 0.000 claims abstract description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 description 4
- 238000010304 firing Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses red glaze of a kind of low temperature and preparation method thereof, the component and each component mass percent that glaze used in the red glaze of low temperature contains are as follows：Silica 65%, aluminum oxide 20%, di-iron trioxide 0.05%, potassium oxide 2.8%, sodium oxide molybdena 2.3%, magnesia 0.14%, calcium oxide 0.3%, selenium 6%, titanium oxide 0.01%, remaining is inevitable impurity, amounts to 100%.The present invention can substantially reduce the coefficient of expansion of glaze, thus the phenomenon that making the coefficient of expansion of glaze and base match, prevent stripping glaze.
Description
Technical field
The present invention relates to red glaze of a kind of low temperature and preparation method thereof.
Background technique
Currently, ceramic colour glaze is mainly some nonferrous metal oxides, salt or double salt, there are many color glaze because of high-temperature calcination meeting
Decompose eclipsed, and can only quality at low temperature, therefore be referred to as low temperature color glaze, at present the decorated technique of ceramic utensil
Afterwards, glaze paint is bright and color is scarlet, only the red yellow glaze of low temperature.However the red glaze firing temperature of low temperature is at 750-950 DEG C, herein
At a temperature of allow ceramic body must first grand feu, then carry out the decoration of the red glaze of low temperature, but will appear new problem again at the same time
I.e. ceramics shell glaze during firing, cause defect.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of red glaze of low temperature is provided, it can be with
The coefficient of expansion of glaze is substantially reduced, thus the phenomenon that making the coefficient of expansion of glaze and base match, prevent stripping glaze.
In order to solve the above technical problems, the technical scheme is that：A kind of red glaze of low temperature, glaze used in it contain
Some components and each component mass percent are as follows：Silica 65%, aluminum oxide 20%, di-iron trioxide 0.05%,
Potassium oxide 2.8%, sodium oxide molybdena 2.3%, magnesia 0.14%, calcium oxide 0.3%, selenium 6%, titanium oxide 0.01%, remaining is not
Evitable impurity amounts to 100%.
The present invention also provides a kind of preparation method of the red glaze of low temperature, the step of method contains, is as follows：
S1：It stocks up according to each component and each component mass parts of glaze：
S2：By material：Ball：Mass ratio=1 of water：1.75：1.5, wet ball grinding 19~21 hours；
S3：After glaze after ball milling is sieved and removes iron, then it is tuned into the glaze slip of 45~60 Baume degrees of concentration；
S4：After the green body for taking appearance bright and clean immerses the glaze slip, then it is fired under 750 DEG C -950 DEG C of oxidizing atmosphere
Product.
After above-mentioned technical proposal, the basic anhydride of low molecular weight are added in the present invention, by with the ratio between molecular number
Replace high molecular weight to aoxidize flux, actually also correspondingly improve the content of silica in this way, the content of silica improves
The coefficient of expansion of glaze can be substantially reduced, thus the phenomenon that making the coefficient of expansion of glaze and base match, prevent stripping glaze.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into
One step detailed description.
A kind of red glaze of low temperature, the component and each component mass percent that glaze used in it contains are as follows：Silica
65%, aluminum oxide 20%, di-iron trioxide 0.05%, potassium oxide 2.8%, sodium oxide molybdena 2.3%, magnesia 0.14%, oxygen
Change calcium 0.3%, selenium 6%, titanium oxide 0.01%, remaining is inevitable impurity, amounts to 100%.
The step of preparation method of the red glaze of the low temperature, method contains, is as follows：
S1：It stocks up according to each component and each component mass parts of glaze：
S2：By material：Ball：Mass ratio=1 of water：1.75：1.5, wet ball grinding 19~21 hours；
S3：After glaze after ball milling is sieved and removes iron, then it is tuned into the glaze slip of 45~60 Baume degrees of concentration；
S4：After the green body for taking appearance bright and clean immerses the glaze slip, then it is fired under 750 DEG C -950 DEG C of oxidizing atmosphere
Product.
The red glaze of the low temperature that the present embodiment is prepared passes through it has been observed that the phenomenon that shelling glaze does not occur in its glaze paint, reaches
Desired effect.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects
It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in guarantor of the invention
Within the scope of shield.
Claims (2)
1. a kind of red glaze of low temperature, it is characterised in that：The component and each component mass percent that glaze used in it contains are as follows：
Silica 65%, aluminum oxide 20%, di-iron trioxide 0.05%, potassium oxide 2.8%, sodium oxide molybdena 2.3%, magnesia
0.14%, calcium oxide 0.3%, selenium 6%, titanium oxide 0.01%, remaining is inevitable impurity, amounts to 100%.
2. a kind of preparation method of the red glaze of low temperature as described in claim 1, it is characterised in that the step of method contains is as follows：
S1：It stocks up according to each component and each component mass parts of glaze：
S2：By material：Ball：Mass ratio=1 of water：1.75：1.5, wet ball grinding 19~21 hours；
S3：After glaze after ball milling is sieved and removes iron, then it is tuned into the glaze slip of 45~60 Baume degrees of concentration；
S4：After the green body for taking appearance bright and clean immerses the glaze slip, finished product then is fired under 750 DEG C -950 DEG C of oxidizing atmosphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810938050.2A CN108840566B (en) | 2018-08-17 | 2018-08-17 | Low-temperature red glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810938050.2A CN108840566B (en) | 2018-08-17 | 2018-08-17 | Low-temperature red glaze and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108840566A true CN108840566A (en) | 2018-11-20 |
| CN108840566B CN108840566B (en) | 2021-06-22 |
Family
ID=64188556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810938050.2A Active CN108840566B (en) | 2018-08-17 | 2018-08-17 | Low-temperature red glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108840566B (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1144200A (en) * | 1995-08-29 | 1997-03-05 | 天津市玻璃器皿厂 | Enriched selenium red glass colouring agent and its use |
| CN1962557A (en) * | 2006-12-06 | 2007-05-16 | 江苏高淳陶瓷股份有限公司 | Ceramic scarlet-variable glaze and its application method |
| CN101054478A (en) * | 2006-04-11 | 2007-10-17 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Lead-free low-cadmium stripping quantity selenium-cadmium dye, preparing method and using method thereof |
| CN102515862A (en) * | 2011-12-14 | 2012-06-27 | 广东松发陶瓷股份有限公司 | Bright red glaze for decoration |
| CN103922810A (en) * | 2014-04-11 | 2014-07-16 | 望城县铜官窑创伟陶艺坊 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
| CN106348599A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Vermilion glaze and preparation method thereof |
| CN106430970A (en) * | 2015-08-07 | 2017-02-22 | 费罗公司 | Nickel-free and chromium-free forehearth colors for glass tanks |
| CN106542812A (en) * | 2016-09-26 | 2017-03-29 | 广东协进陶瓷有限公司 | A kind of magic glazed tile and its production method |
| CN206069715U (en) * | 2016-09-26 | 2017-04-05 | 广东协进陶瓷有限公司 | A kind of production line of magic glazed tile |
| CN107651834A (en) * | 2017-10-30 | 2018-02-02 | 江苏拜富科技有限公司 | Low temperature coloured glass red stain and preparation method thereof and application method |
-
2018
- 2018-08-17 CN CN201810938050.2A patent/CN108840566B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1144200A (en) * | 1995-08-29 | 1997-03-05 | 天津市玻璃器皿厂 | Enriched selenium red glass colouring agent and its use |
| CN101054478A (en) * | 2006-04-11 | 2007-10-17 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Lead-free low-cadmium stripping quantity selenium-cadmium dye, preparing method and using method thereof |
| CN1962557A (en) * | 2006-12-06 | 2007-05-16 | 江苏高淳陶瓷股份有限公司 | Ceramic scarlet-variable glaze and its application method |
| CN102515862A (en) * | 2011-12-14 | 2012-06-27 | 广东松发陶瓷股份有限公司 | Bright red glaze for decoration |
| CN103922810A (en) * | 2014-04-11 | 2014-07-16 | 望城县铜官窑创伟陶艺坊 | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze |
| CN106430970A (en) * | 2015-08-07 | 2017-02-22 | 费罗公司 | Nickel-free and chromium-free forehearth colors for glass tanks |
| CN106348599A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Vermilion glaze and preparation method thereof |
| CN106542812A (en) * | 2016-09-26 | 2017-03-29 | 广东协进陶瓷有限公司 | A kind of magic glazed tile and its production method |
| CN206069715U (en) * | 2016-09-26 | 2017-04-05 | 广东协进陶瓷有限公司 | A kind of production line of magic glazed tile |
| CN107651834A (en) * | 2017-10-30 | 2018-02-02 | 江苏拜富科技有限公司 | Low temperature coloured glass red stain and preparation method thereof and application method |
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|---|
| 丁建中: "《钧窑艺术》", 31 December 2011, 知识产权出版社 * |
| 西北轻工业学院编: "《陶瓷工艺学》", 31 July 1980, 中国轻工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108840566B (en) | 2021-06-22 |
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Denomination of invention: Low temperature red glaze and its preparation method Granted publication date: 20210622 Pledgee: Zhuzhou Branch of China Everbright Bank Co.,Ltd. Pledgor: HUNAN DEXING CERAMICS Co.,Ltd. Registration number: Y2024980014569 |