CN105859266B - Transmutation is from raw glaze Shandong celadon and pug and method - Google Patents
Transmutation is from raw glaze Shandong celadon and pug and method Download PDFInfo
- Publication number
- CN105859266B CN105859266B CN201610200944.2A CN201610200944A CN105859266B CN 105859266 B CN105859266 B CN 105859266B CN 201610200944 A CN201610200944 A CN 201610200944A CN 105859266 B CN105859266 B CN 105859266B
- Authority
- CN
- China
- Prior art keywords
- celadon
- shandong
- glaze
- raw
- pug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Glass Compositions (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
From raw glaze Shandong celadon and pug and method, unpainted clay idol is burnt into from raw glaze Shandong celadon by the atmosphere system for using redox alternately to change in ceramic kiln, described with cyan glaze layer but also to have cyan porcelain body with cyan glaze layer, or not only from raw glaze Shandong celadon for transmutation.The present invention can guarantee that ceramic unpainted clay idol is effectively precipitated glaze layer and is enriched in surface and is burnt into Shandong celadon finished product by transmutation in once-firing, be conducive to improve Shandong celadon production efficiency, yield rate and energy conservation and environmental protection, carbon emission amount is especially reduced, is the great-leap-forward progress of Production of Ceramics.
Description
Technical field
The present invention relates to celadon manufacturing technology, especially a kind of transmutation is from raw glaze Shandong celadon and pug and method.The kiln
Become the atmosphere system for referring to that the firing atmosphere in ceramic kiln is alternately changed using redox；The Shandong celadon begins at the Song Dynasty
A porcelain kind；The glaze layer for referring to porcelain body surface from raw glaze is that unpainted clay idol is spontaneous in sintering process in kiln to be precipitated out of carcass
And/or carcass is burnt into skin effect and is formed, that is to say, that has been omitted completely enamel frit makeing, this two big process of glazing and related step
Suddenly；The pug refers to the composition of raw materials for making ceramic unpainted clay idol, usually includes the mixture of multi mineral.Implement the present invention,
It can guarantee that ceramic unpainted clay idol is effectively precipitated glaze layer and is enriched in surface and is burnt into Shandong celadon finished product by transmutation in once-firing,
Be conducive to improve Shandong celadon production efficiency, yield rate and energy conservation and environmental protection, especially reduction carbon emission amount, be the leap of Production of Ceramics
Formula progress.
Background technique
Celadon is with porcelain exquisiteness, and color is pure, the lucid and lively smoothness of lines, and moulding is dignified simple and natural and is world-famous for.Shandong celadon is
One kind of celadon.Shandong celadon starts from the Song Dynasty, and Shandong celadon glaze is changed in kiln, the unique individual character of every porcelain, Shandong celadon
Firing temperature be usually above other celadons, every kiln finished product is few, especially bottle class skill product, and moulding is unique, and type is complicated, becomes
Treasure in few, even more seldom.After being decorated by the carved porcelain artistic technique, the works carved, picture clear layer, stereoscopic effect
It is prominent.Shandong celadon is generally burnt under reducing atmosphere, and the product porcelain burnt is fine and smooth, and glaze is is green and luxuriant, glittering and translucent, lucid and lively
Simple and elegant, artistic effect is obvious.Traditional Production of Ceramics generallys use the twice firing mode including biscuiting and glaze firing, i.e. unpainted clay idol enters
The porcelain body of current kiln discharge is carried out surface glazing and (previously prepared glaze is covered on porcelain body by kiln kiln discharge again after biscuiting
Surface), then enter kiln again and is fired by glaze.Ceramic production technology generally comprises raw material and selectes, ingredient, crushes, and sieving removes iron,
Filters pressing, pugging form pug, form, dry, biscuiting, glazing, and glaze firing i.e. firing is ceramic product, and wherein raw material is selected refers mainly to
Mineral selection, pugging some are divided into a pugging and secondary pugging, aging process are arranged between a pugging and secondary pugging,
It crushes to use and adds water for ball milling.The equipment that Production of Ceramics is related to generally comprises blender, ball mill, vibration screening machine, magnetic magnetic separator de-ironing,
Mud plunger pump and filter press, pug mill, molding equipment, furnace etc..Since last century eight, the nineties, in ceramic green
Produce and research practice in, what unpainted clay idol occurred in sintering process release glaze from glazing or certainly or just obtains from analysis glaze or from raw glaze phenomenon
Pay attention to, capillary force etc. be precipitated from the liquid phase of formula, mechanism, addition activator into solid-phase construction and has carried out various discussions,
But spontaneous glaze ceramics once-firing technology is still in practicalization so far.The present inventor has been devoted to spontaneous for many years
The productivity of glaze ceramic product is researched and developed, and is completed achievement of the present invention, is realized transmutation from the practical of raw glaze Shandong celadon production technology
Change.
Summary of the invention
The present invention is in view of the deficiencies in the prior art or insufficient, provide a kind of transmutation from raw glaze Shandong celadon and pug and
Method.The transmutation refers to the atmosphere system that the firing atmosphere in ceramic kiln is alternately changed using redox；The Shandong is green
Porcelain begins at the porcelain kind of Song Dynasty；The glaze layer for referring to porcelain body surface from raw glaze is that unpainted clay idol is spontaneous in sintering process in kiln
Be precipitated out of carcass and/or carcass firing skin effect and formed, that is to say, that be omitted completely enamel frit makeing, this is two big for glazing
Process and correlation step；The pug refers to the composition of raw materials for making ceramic unpainted clay idol, usually includes the mixture of multi mineral.
Implement the present invention, can guarantee that ceramic unpainted clay idol is effectively precipitated glaze layer and is enriched in surface and is burnt by transmutation in once-firing
Shandong celadon finished product is conducive to improve Shandong celadon production efficiency, yield rate and energy conservation and environmental protection, especially reduction carbon emission amount, is pottery
The great-leap-forward progress of porcelain production.
Technical scheme is as follows:
Transmutation is from raw glaze Shandong celadon, which is characterized in that including porcelain body and from raw glaze glaze layer, the transmutation is from raw glaze Shandong celadon
Including following chemical component and weight content: it be 8~18%, CaO is that 6~14%, MgO is that SiO2, which is 68~78%, Al2O3,
It is 0.2~1%, Fe2O3 is 0.1~0.3% that 1.3~3.8%, K2O, which are 1.1~2.6%, Na2O, and calcination loss object is 0.05
~0.25%；The pug that the transmutation is made from raw glaze Shandong celadon includes following component and weight content: quartz is 38~50%,
Kaolin is 18~36%, and calcite is 10~21%, and bentonite is 8~12%, and talcum is 6~12%, aluminum oxide 2
~8%.
One kind is from raw glaze Shandong celadon, which is characterized in that described to include from raw glaze Shandong celadon including porcelain body and from raw glaze glaze layer
Following chemical component and weight content: SiO2 be 68~78%, Al2O3 be 8~18%, CaO be 6~14%, MgO be 1.3~
It is 0.2~1%, Fe2O3 is 0.1~0.3% that 3.8%, K2O, which are 1.1~2.6%, Na2O, calcination loss object is 0.05~
0.25%；The pug dry body from raw glaze Shandong celadon includes following chemical component and weight content: SiO2 is 66~76%,
Al2O3 be 7~16%, CaO be 5.5~12%, MgO be 1.29~3.7%, K2O be 1~2.5%, Na2O be 0.25~
0.95%, Fe2O3 are 0.1~0.3%, and calcination loss object is 5~10%.
One kind is from raw glaze Shandong celadon pug, which is characterized in that the dry body of the pug includes following chemical component and weight
Content: SiO2 be 66~76%, Al2O3 be 7~16%, CaO be 5.5~12%, MgO be 1.29~3.7%, K2O be 1~
2.5%, Na2O are that 0.25~0.95%, Fe2O3 is 0.1~0.3%, and calcination loss object is 5~10%；The pug is made
Raw material includes following component and weight content: quartz is 38~50%, and kaolin is 18~36%, and calcite is 10~21%,
Bentonite is 8~12%, and talcum is 6~12%, and aluminum oxide is 2~8%.
The dry body of the pug further includes following chemical component and weight content: TiO2 is 0.0~0.6%；It is made described
The raw material of pug includes following component and weight content: titanium dioxide is 0.1~2%；The dry body of the pug further includes changing as follows
Study point and weight content: ZrO2 is 0.0~1.2%；The raw material that the pug is made includes following component and weight content: silicon
Sour zirconium is 0.1~6%.
From raw glaze Shandong celadon, the Quinary system refers to that the chemical component from raw glaze Shandong celadon belongs to for a kind of Quinary system
" K2O-MgO-CaO-Al2O3-SiO2 " Quinary system, which is characterized in that described from raw glaze Shandong including porcelain body and from raw glaze glaze layer
Celadon includes following chemical component and weight content: it be 8~18%, CaO is 6~14%, MgO that SiO2, which is 68~78%, Al2O3,
It is 1.1~2.6%, Na2O for 1.3~3.8%, K2O be 0.2~1%, Fe2O3 is 0.1~0.3%, calcination loss object is
0.05~0.25%.
The Quinary system from raw glaze Shandong celadon further include following chemical component and weight content: TiO2 be 0.0~
0.6% and/or ZrO2 is 0.0~1.2%.
One kind is from raw glaze Shandong celadon pug, which is characterized in that the dry body of the pug includes following chemical component and weight
Content: SiO2 be 66~76%, Al2O3 be 7~16%, CaO be 5.5~12%, MgO be 1.29~3.7%, K2O be 1~
2.5%, Na2O are that 0.25~0.95%, Fe2O3 is 0.1~0.3%, and calcination loss object is 5~10%.
The dry body of the pug further includes following chemical component and weight content: TiO2 is 0.0~0.6% and/or ZrO2
It is 0.0~1.2%.
Transmutation is from raw glaze Shandong celadon process for calcining, which comprises the following steps: using oxidation in ceramic kiln
Unpainted clay idol is burnt into from raw glaze Shandong celadon by the atmosphere system of reduction alternately variation, described to have cyan glaze layer from raw glaze Shandong celadon, or
Person had not only had cyan glaze layer but also had had cyan porcelain body.
The atmosphere system is the following steps are included: when fire box temperature rises to T1 value, and firing atmosphere is by before in kiln
Oxidizing atmosphere changes into reducing atmosphere, and reducing atmosphere to fire box temperature is kept to rise to T2 value；Since the T2 value, burnt in kiln
Oxidizing atmosphere is changed by reducing atmosphere at atmosphere, and the oxidizing atmosphere to fire box temperature is kept to rise to T3 value；When from T3 value
Heat preservation is played 40 minutes~80 minutes up to transmutation from raw glaze Shandong celadon；T1 to T2 section internal furnace heating rate be 60 DEG C/
Hour~40 DEG C/h, described T1=1170 DEG C ± 10 DEG C, described T2=1200 DEG C ± 10 DEG C；The furnace in the section of T2 to T3
Thorax heating rate is 10 DEG C/h~6 DEG C/h, described T3=1240 DEG C ± 25 DEG C.
Technical effect of the invention is as follows: transmutation of the present invention is from raw glaze Shandong blueness from raw glaze Shandong celadon and pug and method
Great-leap-forward progress of the porcelain technical field in terms of functionization.The present invention innovatively defines transmutation from raw glaze Shandong celadon, the kiln
Become from raw glaze Shandong celadon with the color and permeability and thermal stability outstanding as sapphire.In pug raw material of the invention
It does not need to prepare activator component.Pug of the present invention spontaneously forms the glaze layer on porcelain body surface in kiln in sintering process, reduce
Several processes avoid the possible lead cadmium pollution of prefabricated glaze, while improving the binding force between glaze layer and porcelain body.
Transmutation of the invention uses Quinary system, including oxidation dipotassium, magnesia, calcium oxide, three oxygen from raw glaze Shandong celadon
Change two aluminium, silica, i.e. " K2O-MgO-CaO-Al2O3-SiO2 " Quinary system.It is the temperature i.e. burning in burner hearth in furnace
Firing ring is used at temperature measurement, also known as ceramic firing ring, ceramic firing ring is a kind of ceramic temperature indicator of high precision,
It can record product thermal process experienced in sintering procedure faithfully.Heating rate is usually by fast in furnace in the present invention
To slow.Dry body is formed by the way of spontaneously drying, saves the energy, reduces carbon emission amount.Production pug in the present invention includes
Raw material is selected, ingredient, crushes, and is sieved, mixing, and impurity elimination removes iron, filters pressing, pugging.Except iron uses magnetic magnetic separator de-ironing, magnetic field strength is
1.5 ten thousand~30,000 Gausses.Except iron removes iron using multistage, such as three-level passes sequentially through three magnetic separator de-ironings, also cries three times except iron.Its
Middle pugging is divided into a pugging and secondary pugging, and aging process is arranged between a pugging and secondary pugging.It wherein crushes and adopts
With ball mill, sieving uses vibration screening machine, and mixing uses blender, and filters pressing uses filter press, and pugging uses pug mill.Loading of kiln
Coal gas can be used in once-firing or natural gas is fuel.The gas alternately changed in loading of kiln once-firing using redox
Atmosphere system, oxidation or reducing atmosphere are by fuel when adjusting burning with air than realizing.Firing temperature of the invention can be
1200 DEG C -1265 DEG C or 1200 DEG C -1270 DEG C, -80 minutes 40 minutes are kept the temperature, for example, 1230 DEG C keep the temperature 50 minutes.Firing
Period can be 8~14 hours or 9~11 hours or 10 hours or so.Firing temperature measurement uses firing ring, also known as ceramic
Firing ring, ceramic firing ring are a kind of ceramic temperature indicators of high precision, it can record product institute in sintering procedure faithfully
The thermal process of experience.Firing temperature measurement can also use thermocouple, and thermoscope also can be used.Thermoscope (fusible cone) is
A kind of high-precision ceramic firing temperature indicator.Thermoscope (fusible cone) may determine when fire completely,
Or kiln whether provide enough heats guarantee in the curing or kiln of ceramics with the presence or absence of the difference of temperature or
It is whether problematic in sintering procedure.
Specific embodiment
Below with reference to examples illustrate the present invention.
Spontaneous glaze ceramics single firing process process includes that raw material is selected, and ingredient crushes, and is sieved, and mixing, impurity elimination removes iron,
Filters pressing, pugging, molding, loading of kiln once-firing, kiln discharge, quality inspection, finished product packing.Wherein except iron uses magnetic magnetic separator de-ironing, magnetic field strength
For 1.5 ten thousand~30,000 Gausses.Except iron can remove iron using multistage, such as three-level removes iron, is conducive to continuous production.Wherein pugging point
For a pugging and secondary pugging, aging process is set between a pugging and secondary pugging.It wherein crushes and uses ball mill,
Sieving uses vibration screening machine, and mixing uses blender, and filters pressing uses filter press, and pugging uses pug mill.It is once burnt in loading of kiln
At the middle atmosphere system alternately changed using redox, oxidation or reducing atmosphere are by adjusting fuel and air ratio when burning
It realizes.Coal gas can be used in loading of kiln once-firing or natural gas is fuel.
Transmutation is from raw glaze Shandong celadon, which is characterized in that including porcelain body and from raw glaze glaze layer, the transmutation is from raw glaze Shandong celadon
Including following chemical component and weight content: it be 8~18%, CaO is that 6~14%, MgO is that SiO2, which is 68~78%, Al2O3,
It is 0.2~1%, Fe2O3 is 0.1~0.3% that 1.3~3.8%, K2O, which are 1.1~2.6%, Na2O, and calcination loss object is 0.05
~0.25%；The pug that the transmutation is made from raw glaze Shandong celadon includes following component and weight content: quartz is 38~50%,
Kaolin is 18~36%, and calcite is 10~21%, and bentonite is 8~12%, and talcum is 6~12%, aluminum oxide 2
~8%.
One kind is from raw glaze Shandong celadon, which is characterized in that described to include from raw glaze Shandong celadon including porcelain body and from raw glaze glaze layer
Following chemical component and weight content: SiO2 be 68~78%, Al2O3 be 8~18%, CaO be 6~14%, MgO be 1.3~
It is 0.2~1%, Fe2O3 is 0.1~0.3% that 3.8%, K2O, which are 1.1~2.6%, Na2O, calcination loss object is 0.05~
0.25%；The pug dry body from raw glaze Shandong celadon includes following chemical component and weight content: SiO2 is 66~76%,
Al2O3 be 7~16%, CaO be 5.5~12%, MgO be 1.29~3.7%, K2O be 1~2.5%, Na2O be 0.25~
0.95%, Fe2O3 are 0.1~0.3%, and calcination loss object is 5~10%.
One kind is from raw glaze Shandong celadon pug, which is characterized in that the dry body of the pug includes following chemical component and weight
Content: SiO2 be 66~76%, Al2O3 be 7~16%, CaO be 5.5~12%, MgO be 1.29~3.7%, K2O be 1~
2.5%, Na2O are that 0.25~0.95%, Fe2O3 is 0.1~0.3%, and calcination loss object is 5~10%；The pug is made
Raw material includes following component and weight content: quartz is 38~50%, and kaolin is 18~36%, and calcite is 10~21%,
Bentonite is 8~12%, and talcum is 6~12%, and aluminum oxide is 2~8%.The dry body of the pug further includes following chemistry
Ingredient and weight content: TiO2 is 0.0~0.6%；The raw material that the pug is made includes following component and weight content: titanium white
Powder is 0.1~2%；The dry body of the pug further includes following chemical component and weight content: ZrO2 is 0.0~1.2%；It is made
The raw material of the pug includes following component and weight content: zirconium silicate is 0.1~6%.
From raw glaze Shandong celadon, the Quinary system refers to that the chemical component from raw glaze Shandong celadon belongs to for a kind of Quinary system
" K2O-MgO-CaO-Al2O3-SiO2 " Quinary system, which is characterized in that described from raw glaze Shandong including porcelain body and from raw glaze glaze layer
Celadon includes following chemical component and weight content: it be 8~18%, CaO is 6~14%, MgO that SiO2, which is 68~78%, Al2O3,
It is 1.1~2.6%, Na2O for 1.3~3.8%, K2O be 0.2~1%, Fe2O3 is 0.1~0.3%, calcination loss object is
0.05~0.25%.The Quinary system from raw glaze Shandong celadon further include following chemical component and weight content: TiO2 be 0.0~
0.6% and/or ZrO2 is 0.0~1.2%.
One kind is from raw glaze Shandong celadon pug, which is characterized in that the dry body of the pug includes following chemical component and weight
Content: SiO2 be 66~76%, Al2O3 be 7~16%, CaO be 5.5~12%, MgO be 1.29~3.7%, K2O be 1~
2.5%, Na2O are that 0.25~0.95%, Fe2O3 is 0.1~0.3%, and calcination loss object is 5~10%.The dry body of the pug
Further include following chemical component and weight content: TiO2 is that 0.0~0.6% and/or ZrO2 is 0.0~1.2%.
Transmutation is from raw glaze Shandong celadon process for calcining, which comprises the following steps: using oxidation in ceramic kiln
Unpainted clay idol is burnt into from raw glaze Shandong celadon by the atmosphere system of reduction alternately variation, described to have cyan glaze layer from raw glaze Shandong celadon, or
Person had not only had cyan glaze layer but also had had cyan porcelain body.The atmosphere system is the following steps are included: when fire box temperature rises to T1 value
When, firing atmosphere changes into reducing atmosphere by oxidizing atmosphere before in kiln, and reducing atmosphere to fire box temperature is kept to rise to
T2 value；Since the T2 value, firing atmosphere changes into oxidizing atmosphere by reducing atmosphere in kiln, and keeps the oxidizing atmosphere to burner hearth
Temperature rises to T3 value；40 minutes~80 minutes are kept the temperature from T3 value up to transmutation from raw glaze Shandong celadon；In the area of T1 to T2
Between internal furnace heating rate be 60 DEG C/h~40 DEG C/h, described T1=1170 DEG C ± 10 DEG C, described T2=1200 DEG C ±
10℃；It is 10 DEG C/h~6 DEG C/h, described T3=1240 DEG C ± 25 DEG C in the section internal furnace heating rate of T2 to T3.
Firing temperature in the present invention is further controlled at 1200 DEG C~1245 DEG C.Maximum temperature is no more than 1245 DEG C,
Under the premise of guaranteeing ceramic product quality, energy consumption is effectively reduced.It is arranged relative to firing temperature at 1250 DEG C -1430 DEG C
Range or 1270 DEG C of -1310 DEG C of ranges or 1260 DEG C of -1310 DEG C of ranges, the present invention can save 10% or more the energy, this is right
For the Production of Ceramics industry of highly energy-consuming, it is energy efficiency, especially reduces the marked improvement of carbon emission amount.
It is hereby stated that described above facilitate those skilled in the art understand that the invention, but not limit the present invention
The protection scope of creation.Any equivalent replacement described above, modification are improved without disengaging the invention substantive content
And/or delete numerous conform to the principle of simplicity and the implementation that carries out, each fall within the protection scope of the invention.
Claims (9)
1. transmutation is from raw glaze Shandong celadon, which is characterized in that including porcelain body and from raw glaze glaze layer, the transmutation is from raw glaze Lu Qingcibao
Include following chemical component and weight content: SiO2For 68~78%, Al2O3For 8~18%, CaO be 6~14%, MgO be 1.3~
3.8%, K2O is 1.1~2.6%, Na2O is 0.2~1%, Fe2O3Be 0.1~0.3%, calcination loss object be 0.05~
0.25%；The pug that the transmutation is made from raw glaze Shandong celadon includes following component and weight content: quartz is 38~50%, high
Ridge soil be 18~36%, calcite be 10~21%, bentonite be 8~12%, talcum be 6~12%, aluminum oxide be 2~
8%；
The transmutation, which refers to, is burnt into unpainted clay idol from raw glaze Shandong using the atmosphere system that redox alternately changes in ceramic kiln
Celadon, it is described that not only there is cyan glaze layer from raw glaze Shandong celadon but also there is cyan porcelain body.
2. a kind of from raw glaze Shandong celadon, which is characterized in that described both to have had from raw glaze Shandong celadon including porcelain body and from raw glaze glaze layer
Cyan glaze layer has a cyan porcelain body again, it is described from raw glaze Shandong celadon include following chemical component and weight content: SiO2For 68~
78%, Al2O3It is 6~14%, MgO for 8~18%, CaO is 1.3~3.8%, K2O is 1.1~2.6%, Na2O be 0.2~
1%, Fe2O3It is 0.1~0.3%, calcination loss object is 0.05~0.25%；The pug dry body from raw glaze Shandong celadon includes
Following chemical component and weight content: SiO2For 66~76%, Al2O3It is 5.5~12%, MgO 1.29 for 7~16%, CaO
~3.7%, K2O is 1~2.5%, Na2O is 0.25~0.95%, Fe2O3Be 0.1~0.3%, calcination loss object be 5~
10%.
3. a kind of from raw glaze Shandong celadon pug, described that not only there is cyan glaze layer from raw glaze Shandong celadon but also there is cyan porcelain body, spy
Sign is that the dry body of the pug includes following chemical component and weight content: SiO2For 66~76%, Al2O3It is 7~16%,
CaO is that 5.5~12%, MgO is 1.29~3.7%, K2O is 1~2.5%, Na2O is 0.25~0.95%, Fe2O3For 0.1~
0.3%, calcination loss object is 5~10%；The raw material that the pug is made includes following component and weight content: quartz for 38~
50%, kaolin is 18~36%, and calcite is 10~21%, and bentonite is 8~12%, and talcum is 6~12%, three oxidations two
Aluminium is 2~8%.
4. according to claim 3 from raw glaze Shandong celadon pug, which is characterized in that the dry body of the pug further includes as follows
Chemical component and weight content: TiO2It is 0.0~0.6%；The raw material that the pug is made includes following component and weight content:
Titanium dioxide is 0.1~2%；The dry body of the pug further includes following chemical component and weight content: ZrO2It is 0.0~1.2%；
The raw material that the pug is made includes following component and weight content: zirconium silicate is 0.1~6%.
5. a kind of Quinary system is from raw glaze Shandong celadon, described not only to have had cyan glaze layer from raw glaze Shandong celadon but also had cyan porcelain body,
The Quinary system refers to that the chemical component from raw glaze Shandong celadon belongs to " K2O-MgO-CaO-Al2O3-SiO2" Quinary system,
Be characterized in that, including porcelain body and from raw glaze glaze layer, it is described from raw glaze Shandong celadon include following chemical component and weight content: SiO2
For 68~78%, Al2O3It is 6~14%, MgO for 8~18%, CaO is 1.3~3.8%, K2O is 1.1~2.6%, Na2O is
0.2~1%, Fe2O3It is 0.1~0.3%, calcination loss object is 0.05~0.25%.
6. Quinary system according to claim 5 is from raw glaze Shandong celadon, which is characterized in that the Quinary system is from raw glaze Shandong
Celadon further includes following chemical component and weight content: TiO2For 0.0~0.6% and/or ZrO2It is 0.0~1.2%.
7. a kind of from raw glaze Shandong celadon pug, which is characterized in that described that not only there is cyan glaze layer from raw glaze Shandong celadon but also there is blueness
Color porcelain body, the dry body of the pug include following chemical component and weight content: SiO2For 66~76%, Al2O3It is 7~16%,
CaO is that 5.5~12%, MgO is 1.29~3.7%, K2O is 1~2.5%, Na2O is 0.25~0.95%, Fe2O3For 0.1~
0.3%, calcination loss object is 5~10%.
8. according to claim 7 from raw glaze Shandong celadon pug, which is characterized in that the dry body of the pug further includes as follows
Chemical component and weight content: TiO2For 0.0~0.6% and/or ZrO2It is 0.0~1.2%.
9. transmutation is from raw glaze Shandong celadon process for calcining, which comprises the following steps: in ceramic kiln also using oxidation
Unpainted clay idol is burnt into from raw glaze Shandong celadon by the atmosphere system that original alternately changes, described not only to have had cyan glaze layer from raw glaze Shandong celadon but also had
There is cyan porcelain body；
The atmosphere system is the following steps are included: when fire box temperature rises to T1 value, and firing atmosphere is by oxidation before in kiln
Atmosphere changes into reducing atmosphere, and reducing atmosphere to fire box temperature is kept to rise to T2 value；Since the T2 value, gas is burnt into kiln
Atmosphere changes into oxidizing atmosphere by reducing atmosphere, and the oxidizing atmosphere to fire box temperature is kept to rise to T3 value；From T3 value Shi Qibao
Temperature 40 minutes~80 minutes up to transmutation from raw glaze Shandong celadon；It is 60 DEG C/h in the section internal furnace heating rate of T1 to T2
~40 DEG C/h, described T1=1170 DEG C ± 10 DEG C, described T2=1200 DEG C ± 10 DEG C；In the section internal furnace liter of T2 to T3
Warm speed is 10 DEG C/h~6 DEG C/h, described T3=1240 DEG C ± 25 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610200944.2A CN105859266B (en) | 2016-03-31 | 2016-03-31 | Transmutation is from raw glaze Shandong celadon and pug and method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610200944.2A CN105859266B (en) | 2016-03-31 | 2016-03-31 | Transmutation is from raw glaze Shandong celadon and pug and method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105859266A CN105859266A (en) | 2016-08-17 |
| CN105859266B true CN105859266B (en) | 2019-05-24 |
Family
ID=56627087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610200944.2A Active CN105859266B (en) | 2016-03-31 | 2016-03-31 | Transmutation is from raw glaze Shandong celadon and pug and method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105859266B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108046600A (en) * | 2017-12-21 | 2018-05-18 | 洛阳名力科技开发有限公司 | A kind of ceramic artistic glaze |
| CN108423990A (en) * | 2018-04-18 | 2018-08-21 | 福建省东丰阁文化发展有限公司 | A kind of pseudo-classic formula of blueness glaze small cup glaze water and preparation method |
| CN109534802B (en) * | 2018-12-24 | 2021-08-24 | 温克仁 | Far infrared autogenous glaze porcelain with high utilization of desert materials and preparation process thereof |
| CN114105623A (en) * | 2021-08-03 | 2022-03-01 | 湖南仙凤瓷业有限公司 | High-strength jade porcelain pug and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253124A (en) * | 1998-10-29 | 2000-05-17 | 淄博通博高档骨质瓷有限责任公司 | Green porcelain glaze and process for preparing products of green porcelain glaze |
| CN101885601A (en) * | 2010-06-20 | 2010-11-17 | 景德镇陶瓷学院 | Method for manufacturing medium-temperature Longquan powder celadon |
| CN103435336A (en) * | 2013-08-15 | 2013-12-11 | 何晓洪 | Self-forming glaze white jade porcelain pug and manufacturing method of porcelain pug product |
| CN103553718A (en) * | 2013-10-29 | 2014-02-05 | 山东鲁青瓷文化艺术有限公司 | Double-fambe glaze melting technology of ceramic |
| CN104529416A (en) * | 2014-11-29 | 2015-04-22 | 卢烨 | Pale green porcelain |
-
2016
- 2016-03-31 CN CN201610200944.2A patent/CN105859266B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1253124A (en) * | 1998-10-29 | 2000-05-17 | 淄博通博高档骨质瓷有限责任公司 | Green porcelain glaze and process for preparing products of green porcelain glaze |
| CN101885601A (en) * | 2010-06-20 | 2010-11-17 | 景德镇陶瓷学院 | Method for manufacturing medium-temperature Longquan powder celadon |
| CN103435336A (en) * | 2013-08-15 | 2013-12-11 | 何晓洪 | Self-forming glaze white jade porcelain pug and manufacturing method of porcelain pug product |
| CN103553718A (en) * | 2013-10-29 | 2014-02-05 | 山东鲁青瓷文化艺术有限公司 | Double-fambe glaze melting technology of ceramic |
| CN104529416A (en) * | 2014-11-29 | 2015-04-22 | 卢烨 | Pale green porcelain |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105859266A (en) | 2016-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110790506A (en) | Granular double-layer reaction glaze and preparation method thereof | |
| CN105859266B (en) | Transmutation is from raw glaze Shandong celadon and pug and method | |
| CN105776861B (en) | A kind of bright red nanometer glaze slip of sanitary ceramics and its preparation method and application | |
| CN107216127B (en) | Dehua pearl white porcelain and its preparation process | |
| CN103641447B (en) | A kind of preparation method of engineering ceramics acid-fast alkali-proof container | |
| CN105819844A (en) | Mutton-fat jade like spontaneous glaze ceramic, pug and once-firing production process | |
| CN105669161A (en) | Method of reductive firing of ceramic at medium temperature (1190-1260 DEG C) | |
| CN103224415B (en) | One-time sintered cobalt blue frit dry particles and preparation method thereof | |
| CN103922810B (en) | Bright red glaze for ceramic and method for producing ceramic products from bright red glaze | |
| CN106565204A (en) | High-performance red-slurry ceramic product and preparation method thereof | |
| CN110452020A (en) | It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings | |
| CN110217991A (en) | A kind of high strength china glaze and preparation method thereof | |
| CN111574189A (en) | Manufacturing process of iron oxide red kiln transformation glazed porcelain | |
| CN113402265A (en) | White-bottom black-flower enamel and preparation method thereof | |
| CN107572822A (en) | A kind of pottery plum green glaze and preparation method thereof | |
| CN105294057A (en) | Preparation process for ultrathin ceramic brick | |
| CN109053137A (en) | Laterite underglaze colour bone china and preparation method thereof | |
| CN112374762A (en) | Moon white glaze for jun porcelain and preparation method thereof | |
| CN106277792B (en) | A kind of emerald blueness glaze and its method for cooking | |
| CN104291785B (en) | Beautiful pottery of a kind of high-grade porcelain kind crystal magnesium and preparation method thereof | |
| CN107619268B (en) | Porcelain formula and production process | |
| CN109592991A (en) | A kind of pearl-frosted glaze ceramics and its manufacture craft of waste old ceramics preparation | |
| CN108569888A (en) | A kind of Buddha jumping over the wall container formulations and manufacture craft | |
| CN113185123A (en) | Preparation process of high-strength azure glazed porcelain | |
| CN104418336B (en) | Synthetic wollastonite, protein porcelain containing the same and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xie Jingyu Inventor after: Chen Jinhai Inventor before: Xie Jingyu |
|
| COR | Change of bibliographic data | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |