CN109592991A - A kind of pearl-frosted glaze ceramics and its manufacture craft of waste old ceramics preparation - Google Patents
A kind of pearl-frosted glaze ceramics and its manufacture craft of waste old ceramics preparation Download PDFInfo
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Abstract
The present invention relates to ceramic fabrication technique fields, are specifically related to the pearl-frosted glaze and its manufacture craft of a kind of waste old ceramics preparation.The pearl-frosted glaze ceramics of waste old ceramics preparation, it further include pearl-frosted glaze including ceramic body, the pearl-frosted glaze of waste old ceramics preparation provided by the invention, the raw materials such as waste old ceramics and low temperature titanium glaze frit are introduced as glaze, it realizes a glazing, once form by a firing, the process difficulties for solving the multiple glazing of traditional frosted glaze, repeatedly firing.After ceramic sintering molding, the frosted texture of protrusion is formed, glaze glossiness is high, and artistic effect is unique.The pearl-frosted glaze is easy fired glaze ceramics, and using low temperature fast firing technique, the low temperature titanium glaze frit introduced in glaze makes the glossiness of glaze high, has pearlescent gloss.This kind of pearl-frosted glaze ceramics provide a kind of frontier of waste old ceramics application, with positive meaning and have positive economic benefit to the development of promotion ceramic product.
Description
Technical field
The present invention relates to ceramic fabrication technique fields, are specifically related to a kind of pearl-frosted glaze ceramics of waste old ceramics preparation
And its manufacture craft.
Background technique
With the fast development of social economy and ceramic industry, ceramic yield increases substantially.Traditional ceramics it is main
Raw material is non-renewable natural mineral raw, and the natural minerals such as clay, feldspar, quartz that China's china industry consumes every year are total
Amount has reached 1.3 hundred million tons or more, and more year by year.While yield surges, the yield of shraff is also more next
It is more.Because can all generate waste material, including base from overall processes such as feedstock processing, mixing, ball milling to body preparation, forming, dryings
Body waste material, useless glaze, semi-finished product waste material, firing waste material, waste gypsum, useless saggar and useless refractory slab etc..According to incomplete statistics, the whole nation
The annual output of shraff is estimated at 10,000,000 tons or so.It is how to handle and headache that a large amount of shraff, which not only allows enterprise,
Also it allows government for it is destroyed caused by environment and puzzles one's brains, how it to be turned waste into wealth, becoming entire industry realization can
The task of top priority of sustainable development.
Have some reasonable technologies using shraff now, as application No. is disclosed in CN201710946573.7
" ceramic and preparation method thereof made of waste old ceramics material "；For another example application No. is disclosed in CN201410233377.1
It all employs waste old ceramics in " ceramic and preparation method thereof made of waste old ceramics " to be introduced into green body, as green body original
Material is utilized.It is existing, it is also rarely reported using the technology of waste old ceramics enamel frit makeing, so if can be prepared using waste old ceramics
Glaze with effect unique provides a kind of completely new application field to the utilization of waste old ceramics.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides the pearl-frosted glaze and its system of a kind of preparation of waste old ceramics
Make technique.
To achieve the above object, The technical solution adopted by the invention is as follows: a kind of pearl-frosted glaze of waste old ceramics preparation
Ceramics, including ceramic body further include pearl-frosted glaze, and the parts by weight of raw materials of the pearl-frosted glaze is as follows: waste old ceramics
10-30 parts, 20-30 parts of low temperature titanium glaze frit, 15-20 parts of white clouds soil, 15-20 parts of potassium feldspar, 5-10 parts of kaolin, stone
10-20 parts of English, 1-5 parts of stalactite, 0-5 parts of colorant, 1-5 parts of zircon, 1-2 parts of tricalcium phosphate.
Further, the chemical composition mass percent of low temperature titanium glaze frit is as follows: R2O2-4%, CaO1-3%,
ZnO1-3%, PbO2-4%, Al2O310-15%, B2O3 15-20%, SiO2 45-50%, ZrO2 8-12%,
TiO21-5%.
Further, the chemical composition mass percent of low temperature titanium glaze frit is as follows: R2O3%, CaO2%, ZnO2%,
PbO3%, Al2O312%, B2O3 18%, SiO2 48%, ZrO29%, TiO2 3%.
Further, the parts by weight of raw materials of pearl-frosted glaze is as follows: 13 parts of waste old ceramics, 22 parts of low temperature titanium glaze frit, white
16 parts of cloud soil, 17 parts of potassium feldspar, 6 parts of kaolin, quartzy 18 parts, 4 parts of stalactite, 3 parts of zircon, 1 part of tricalcium phosphate.
Further, the parts by weight of raw materials of pearl-frosted glaze is as follows: 21 parts of waste old ceramics, 20 parts of low temperature titanium glaze frit, white
16 parts of cloud soil, 15 parts of potassium feldspar, 7 parts of kaolin, quartzy 12 parts, 2 parts of stalactite, 4 parts of colorant, 2 parts of zircon, tricalcium phosphate
1 part.
Further, colorant is one or more of metal oxide, colorant.
A kind of manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation, makes the treasure of above-mentioned waste old ceramics preparation
Bead mill sand glaze, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, enamel frit makeing, when preparing pearl-frosted glaze, by the parts by weight of raw materials of pearl-frosted glaze by low temperature titanium glaze frit, white
Cloud soil, potassium feldspar, kaolin, quartz, stalactite, colorant, zircon, tricalcium phosphate are added in wet bulb grinding machine, wherein material:
Ball: the ratio of water is 2:1:1-2, and milling time is 4-5 hours, after having ground, will by the parts by weight of raw materials of pearl-frosted glaze
Waste old ceramics raw material is added in slurry, continues stirring 4-5 hours；
Step 3, glazing applies pearl-frosted glaze on ceramic body surface, glaze slip thickness is more than or equal to after body drying
0.8mm；
Step 4, it is burnt into, glaze green body will be contained after waiting body drying and be put into kiln, formed by a firing, firing temperature is
950-1010 DEG C, obtain pearl-frosted glaze.
Further, before step 2 enamel frit makeing, waste old ceramics are crushed, cross 50-100 mesh, calcines, obtains through 300-400 DEG C
Obtain waste old ceramics raw material.
Further, when step 3 glazing, first stirring glaze slip mixes waste old ceramics raw material and slurry, using glaze pouring
In billet surface glazing.
Further, the firing control in step 4 is as follows: ceramic body being put into tunnel oven, preheating section: through 20-30
Minute rises to 300 DEG C by room temperature；Warming-up section: kiln continues to heat up, and is warming up to 800 DEG C ± 10 DEG C by 2-3 hours；Keep the temperature rank
Section, kiln are warming up to firing temperature in 1-2 hours, keep the temperature 30-50 minutes after reaching firing temperature；Temperature descending section: kiln warp
It spends 1-2 hours and is cooled to 200-300 DEG C.
The pearl-frosted glaze of waste old ceramics preparation provided by the invention, provides a kind of completely new ceramic decoration method, solution
It has determined the multiple glazing of traditional frosted glaze, the process difficulties repeatedly fired, has introduced the raw materials such as waste old ceramics and low temperature titanium glaze frit and make
It for glaze, realizes a glazing, once form by a firing, this kind of pearl-frosted glaze is attached to using glaze package waste old ceramics formation
The particle texture on ceramic body surface after ceramic sintering molding, forms the frosted texture of protrusion, and glaze glossiness is high, art effect
Fruit is unique.The pearl-frosted glaze is easy fired glaze ceramics, and using low temperature fast firing technique, pearl-frosted glaze is in involvement state
When waste old ceramics belong to solid states, waste old ceramics are wrapped in glaze by pearl-frosted glaze, formation be attached to ceramic blank body surface
The particle in face, the low temperature titanium glaze frit introduced in glaze make the glossiness of glaze high, have pearlescent gloss.This kind of pearl
Frosted glaze ceramics provide a kind of frontier of waste old ceramics application, to pushing the development of ceramic product to have a positive meaning
And there is positive economic benefit.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
A kind of pearl-frosted glaze ceramics of waste old ceramics preparation, including ceramic body, further include pearl-frosted glaze, the treasure
The parts by weight of raw materials of bead mill sand glaze is as follows: 10-30 parts of waste old ceramics, 20-30 parts of low temperature titanium glaze frit, white clouds soil 15-20
Part, 15-20 parts of potassium feldspar, 5-10 parts of kaolin, 10-20 parts of quartz, 1-5 parts of stalactite, 0-5 parts of colorant, zircon
1-5 parts, 1-2 parts of tricalcium phosphate；Wherein colorant is one or more of metal oxide, colorant；
The chemical composition mass percent of low temperature titanium glaze frit is as follows: R2O2-4%, CaO1-3%, ZnO1-3%,
PbO2-4%, Al2O310-15%, B2O3 15-20%, SiO2 45-50%, ZrO2 8-12%, TiO2 1-5%.
A kind of manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation, makes the treasure of above-mentioned waste old ceramics preparation
Bead mill sand glaze, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, waste old ceramics are crushed by enamel frit makeing, cross 50-100 mesh, are calcined through 300-400 DEG C, and waste old ceramics are obtained
Raw material, when preparing pearl-frosted glaze, by the parts by weight of raw materials of pearl-frosted glaze by low temperature titanium glaze frit, white clouds soil, potassium feldspar, height
Ridge soil, quartz, stalactite, colorant, zircon, tricalcium phosphate are added in wet bulb grinding machine, wherein material: ball: the ratio of water is 2:
1:1-2, milling time are 4-5 hours, and after having ground, waste old ceramics raw material is added by the parts by weight of raw materials of pearl-frosted glaze
In slurry, continue stirring 4-5 hours；
Step 3, glazing applies pearl-frosted glaze on ceramic body surface, glaze slip thickness is more than or equal to after body drying
0.8mm, first stirring glaze slip mixes waste old ceramics raw material and slurry, using glaze pouring in billet surface glazing；
Step 4, it is burnt into, glaze green body will be contained after waiting body drying and be put into kiln, formed by a firing, firing temperature is
950-1010 DEG C, pearl-frosted glaze is obtained, firing control is as follows: ceramic body being put into tunnel oven, preheating section: through 20-
300 DEG C are risen to by room temperature within 30 minutes；Warming-up section: kiln continues to heat up, and is warming up to 800 DEG C ± 10 DEG C by 2-3 hours；Heat preservation
Stage, kiln are warming up to firing temperature in 1-2 hours, keep the temperature 30-50 minutes after reaching firing temperature；Temperature descending section: kiln
200-300 DEG C was cooled to by 1-2 hours.
Specific embodiment one:
A kind of pearl-frosted glaze ceramics of waste old ceramics preparation, including ceramic body, further include pearl-frosted glaze, the treasure
The parts by weight of raw materials of bead mill sand glaze is as follows:
13 parts of waste old ceramics, 22 parts of low temperature titanium glaze frit, 16 parts of white clouds soil, 17 parts of potassium feldspar, 6 parts of kaolin, quartz 18
Part, 4 parts of stalactite, 3 parts of zircon, 1 part of tricalcium phosphate；Wherein the chemical composition mass percent of low temperature titanium glaze frit is as follows:
R2O3%, CaO2%, ZnO2%, PbO3%, Al2O312%, B2O3 18%, SiO2 48%, ZrO29%, TiO2 3%.
The pearl-frosted glaze of above-mentioned waste old ceramics preparation, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, waste old ceramics are crushed by enamel frit makeing, cross 60 meshes, waste old ceramics raw material are obtained through 400 DEG C of calcinings, after calcining
Ceramic powders whiteness increase, when preparing pearl-frosted glaze, by pearl-frosted glaze parts by weight of raw materials by low temperature titanium glaze frit,
White clouds soil, potassium feldspar, kaolin, quartz, stalactite, colorant, zircon, tricalcium phosphate are added in wet bulb grinding machine, wherein material:
Ball: the ratio of water is 2:1:1, and milling time is 4 hours, after having ground, by the parts by weight of raw materials of pearl-frosted glaze by waste and old pottery
Porcelain raw material is added in slurry, continues stirring 5 hours；
Step 3, glazing applies pearl-frosted glaze on ceramic body surface, glaze slip thickness is more than or equal to after body drying
1.8mm, first stirring glaze slip mixes waste old ceramics raw material and slurry, using glaze pouring in billet surface glazing；
Step 4, it is burnt into, glaze green body will be contained after waiting body drying and be put into kiln, formed by a firing, firing temperature 1008
DEG C, pearl-frosted glaze is obtained, firing control is as follows: ceramic body being put into tunnel oven, preheating section: through 20-30 minutes by normal
Temperature rise is to 300 DEG C；Warming-up section: kiln continues to heat up, and is warming up to 800 DEG C ± 10 DEG C by 2-3 hours；Holding stage, kiln exist
It is warming up to firing temperature in 1-2 hours, keeps the temperature 30-50 minutes after reaching firing temperature；Temperature descending section: kiln passes through 1-2 hours
It is cooled to 200-300 DEG C.
This kind of pearl-frosted glaze forms the particle texture for being attached to ceramic body surface using glaze package waste old ceramics, precious
Pearl particle is larger, the transparent color of glaze, and after ceramic sintering molding, granular sensation is obvious, and glaze glossiness is high, and artistic effect is unique.
Specific embodiment two:
A kind of pearl-frosted glaze ceramics of waste old ceramics preparation, including ceramic body, further include pearl-frosted glaze, the treasure
The parts by weight of raw materials of bead mill sand glaze is as follows:
21 parts of waste old ceramics, 20 parts of low temperature titanium glaze frit, 16 parts of white clouds soil, 15 parts of potassium feldspar, 7 parts of kaolin, quartz 12
Part, 2 parts of stalactite, 4 parts of copper oxide, 2 parts of zircon, 1 part of tricalcium phosphate；The wherein chemical composition quality hundred of low temperature titanium glaze frit
Divide ratio as follows: R2O3%, CaO2%, ZnO2%, PbO3%, Al2O312%, B2O3 18%, SiO2 48%, ZrO29%, TiO2
3%.
A kind of manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation, makes the treasure of above-mentioned waste old ceramics preparation
Bead mill sand glaze, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, waste old ceramics are crushed by enamel frit makeing, cross 80 meshes, are calcined through 300 DEG C, and waste old ceramics raw material, preparation are obtained
When pearl-frosted glaze, by the parts by weight of raw materials of pearl-frosted glaze by low temperature titanium glaze frit, white clouds soil, potassium feldspar, kaolin, stone
English, stalactite, colorant, zircon, tricalcium phosphate are added in wet bulb grinding machine, wherein material: ball: the ratio of water is 2:1:1, grinding
Time is 4 hours, after having ground, and waste old ceramics raw material is added in slurry by the parts by weight of raw materials of pearl-frosted glaze, continues to stir
It mixes 4-5 hours；
Step 3, glazing applies pearl-frosted glaze on ceramic body surface, glaze slip thickness is more than or equal to after body drying
1.0mm, first stirring glaze slip mixes waste old ceramics raw material and slurry, using glaze pouring in billet surface glazing；
Step 4, it is burnt into, glaze green body will be contained after waiting body drying and be put into kiln, formed by a firing, firing temperature 980
DEG C, pearl-frosted glaze is obtained, firing control is as follows: ceramic body being put into tunnel oven, preheating section: through 30 minutes by room temperature liter
To 300 DEG C；Warming-up section: kiln continues to heat up, and is warming up to 805 DEG C by 3 hours；Holding stage, kiln are warming up in 1 hour
Firing temperature keeps the temperature 40 minutes after reaching firing temperature；Temperature descending section: kiln was cooled to 300 DEG C by 2 hours.
This kind of pearl-frosted glaze forms the particle texture for being attached to ceramic body surface using glaze package waste old ceramics, precious
Pearl particle is smaller, and glaze is in pale red, after ceramic sintering molding, forms pico- protrusion, glaze glossiness is high, and artistic effect is only
It is special.
The pearl-frosted glaze of waste old ceramics preparation provided by the invention, provides a kind of completely new ceramic decoration method, solution
It has determined the multiple glazing of traditional frosted glaze, the process difficulties repeatedly fired, has introduced the raw materials such as waste old ceramics and low temperature titanium glaze frit and make
It for glaze, realizes a glazing, once form by a firing, this kind of pearl-frosted glaze is attached to using glaze package waste old ceramics formation
The particle texture on ceramic body surface after ceramic sintering molding, forms the frosted texture of protrusion, and glaze glossiness is high, art effect
Fruit is unique.The pearl-frosted glaze is easy fired glaze ceramics, and using low temperature fast firing technique, pearl-frosted glaze is in involvement state
When waste old ceramics belong to solid states, waste old ceramics are wrapped in glaze by pearl-frosted glaze, formation be attached to ceramic blank body surface
The particle in face, the low temperature titanium glaze frit introduced in glaze make the glossiness of glaze high, have pearlescent gloss.This kind of pearl
Frosted glaze ceramics provide a kind of frontier of waste old ceramics application, to pushing the development of ceramic product to have a positive meaning
And there is positive economic benefit.
It above are only the specific embodiment of the present invention, but the design concept of the present invention is not limited to this, all benefits
It is made a non-material change to the present invention, should all be belonged to behavior that violates the scope of protection of the present invention with this design.
Claims (10)
1. a kind of pearl-frosted glaze ceramics of waste old ceramics preparation, including ceramic body, it is characterised in that: further include pearl-frosted
The parts by weight of raw materials of glaze, the pearl-frosted glaze is as follows: 10-30 parts of waste old ceramics, 20-30 parts of low temperature titanium glaze frit, white clouds soil
15-20 parts, 15-20 parts of potassium feldspar, 5-10 parts of kaolin, 10-20 parts of quartz, 1-5 parts of stalactite, 0-5 parts of colorant, zircon
1-5 parts, 1-2 parts of tricalcium phosphate.
2. the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 1, it is characterised in that: the low temperature titanium glaze
The chemical composition mass percent of frit is as follows: R2O 2-4%, CaO 1-3%, ZnO 1-3%, PbO 2-4%, Al2O3 10-
15%, B2O315-20%, SiO245-50%, ZrO28-12%, TiO21-5%.
3. the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 2, it is characterised in that: the low temperature titanium glaze
The chemical composition mass percent of frit is as follows: R2O 3%, CaO 2%, ZnO 2%, PbO 3%, Al2O312%, B2O3
18%, SiO248%, ZrO29%, TiO23%.
4. the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 1 or 3, it is characterised in that: the pearl
The parts by weight of raw materials of frosted glaze is as follows: 13 parts of waste old ceramics, 22 parts of low temperature titanium glaze frit, 16 parts of white clouds soil, 17 parts of potassium feldspar, height
6 parts of ridge soil, quartzy 18 parts, 4 parts of stalactite, 3 parts of zircon, 1 part of tricalcium phosphate.
5. the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 1 or 3, it is characterised in that: the pearl
The parts by weight of raw materials of frosted glaze is as follows: 21 parts of waste old ceramics, 20 parts of low temperature titanium glaze frit, 16 parts of white clouds soil, 15 parts of potassium feldspar, height
7 parts of ridge soil, quartzy 12 parts, 2 parts of stalactite, 4 parts of colorant, 2 parts of zircon, 1 part of tricalcium phosphate.
6. the pearl-frosted glaze ceramics of waste old ceramics according to claim 1 preparation, it is characterised in that: the colorant is
One or more of metal oxide, colorant.
7. a kind of manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation, production require to give up described in 1-6 any one
The standby pearl-frosted glaze of old ceramic system, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, enamel frit makeing, when preparing pearl-frosted glaze, by the parts by weight of raw materials of pearl-frosted glaze by low temperature titanium glaze frit, white clouds
Soil, potassium feldspar, kaolin, quartz, stalactite, colorant, zircon, tricalcium phosphate are added in wet bulb grinding machine, wherein material: ball:
The ratio of water is 2:1:1-2, and milling time is 4-5 hours, after having ground, by the parts by weight of raw materials of pearl-frosted glaze by waste and old pottery
Porcelain raw material is added in slurry, continues stirring 4-5 hours；
Step 3, glazing applies pearl-frosted glaze on ceramic body surface, glaze slip thickness is more than or equal to 0.8mm after body drying；
Step 4, it is burnt into, glaze green body will be contained after waiting body drying and be put into kiln, formed by a firing, firing temperature 950-1010
DEG C, obtain pearl-frosted glaze.
8. the manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 7, it is characterised in that: institute
Before stating step 2 enamel frit makeing, waste old ceramics are crushed, cross 50-100 mesh, are calcined through 300-400 DEG C, waste old ceramics raw material is obtained.
9. the manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 7, it is characterised in that: institute
When stating step 3 glazing, first stirring glaze slip mixes waste old ceramics raw material and slurry, using glaze pouring in billet surface glazing.
10. the manufacture craft of the pearl-frosted glaze ceramics of waste old ceramics preparation according to claim 7, it is characterised in that:
Firing control in step 4 is as follows: ceramic body is put into tunnel oven,
Preheating section: 300 DEG C were risen to by room temperature through 20-30 minutes；
Warming-up section: kiln continues to heat up, and is warming up to 800 DEG C ± 10 DEG C by 2-3 hours；
Holding stage, kiln are warming up to firing temperature in 1-2 hours, keep the temperature 30-50 minutes after reaching firing temperature；
Temperature descending section: kiln was cooled to 200-300 DEG C by 1-2 hours.
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