CN110040959A - A kind of blue and white porcelain and its manufacture craft with wood kiln effect modelled after an antique - Google Patents
A kind of blue and white porcelain and its manufacture craft with wood kiln effect modelled after an antique Download PDFInfo
- Publication number
- CN110040959A CN110040959A CN201910298697.8A CN201910298697A CN110040959A CN 110040959 A CN110040959 A CN 110040959A CN 201910298697 A CN201910298697 A CN 201910298697A CN 110040959 A CN110040959 A CN 110040959A
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- blue
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0009—Pigments for ceramics
Abstract
The present invention relates to ceramic fabrication technique fields, are specifically related to a kind of blue and white porcelain and its manufacture craft with wood kiln effect modelled after an antique.Blue and white porcelain with wood kiln effect modelled after an antique, including ceramic body further include the blue and white color material being sequentially arranged on ceramic body and clear frit modelled after an antique.Blue and white porcelain provided by the invention with wood kiln effect modelled after an antique, introduce distinct configuration clear frit modelled after an antique and blue and white color material, closest by the effect for matching the blue and white porcelain surface that fired blue and white porcelain and traditional wood kiln are fired with blue and white porcelain method for cooking provided by the invention, artistic effect is unique；The present invention provides a kind of completely new blue and white porcelain method for cooking, after firing by using gas kiln, reuse the secondary firing of electrical kiln, when being fired using electrical kiln, pine branch has been put into kiln, oil-containing gases are formed when the firing of pine branch and are covered in ceramic surface, are made ceramic surface that there is glossy gloss, are furthermore reduced the brightness of oil modelled after an antique, keep the color of glaze modelled after an antique slightly partially green, effect of the color closer to wood kiln.
Description
Technical field
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of blue and white porcelain with wood kiln effect modelled after an antique and
Its manufacture craft.
Background technique
Blue and white is one of mainstream kind of Chinese porcelain, belongs to underglaze colour porcelain.It is former that blue and white porcelain, which is with the cobalt ore containing cobalt oxide,
Material, describes decorative pattern, then cover layer of transparent glaze, through high temperature reduction flame once-firing on ceramic body.In indigo plant after the firing of cobalt material
Color has the characteristics that bright-coloured strong coloring force, color development, firing rate height, in colour-stable.
It is green as social economy is to the substantial increase of ceramic demand and the fast development of ceramic sintering process industry
The firing of flower porcelain is fired from traditional wood kiln fires by coal pit furnace, until the transformation of present gas kiln burning process.Although using
The blue and white porcelain that gas kiln is fired is able to achieve energy conservation and environmental protection, fires the features such as effect stability, high yield rate, but along with firing process
Change, there are very big difference, such as wood kiln in the blue and white porcelain surface that the blue and white porcelain surface effect and wood kiln fired using gas kiln are fired
Blue and white ceramic glaze surface color development is sedate, glossy degree is high, be that gas kiln institute is inaccessiable.Therefore, so if modern burning can be used
Tool processed burns out the blue and white porcelain that effect is fired closest to traditional wood kiln, has positive meaning to the heritage and development of blue and white porcelain.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of blue and white porcelain with wood kiln effect modelled after an antique and its
Manufacture craft.
To achieve the above object, The technical solution adopted by the invention is as follows: a kind of blue and white pottery with wood kiln effect modelled after an antique
Porcelain, including ceramic body, it is characterised in that: further include the blue and white color material being sequentially arranged on ceramic body and clear frit modelled after an antique, institute
The parts by weight of raw materials for stating clear frit modelled after an antique is as follows: 30-40 parts quartzy, 15-20 parts of aluminium hydroxide, 15-20 parts of potassium feldspar, stone
10-15 parts of lime stone, 10-15 parts of calcination of talc, 5-10 parts of kaolin, 1-5 parts of zirconium silicate.
Further, the raw material components of clear frit modelled after an antique are as follows: quartzy 32 parts, 16 parts of aluminium hydroxide, 18 parts of potassium feldspar, stone
13 parts of lime stone, 12 parts of calcination of talc, 6 parts of kaolin, 3 parts of zirconium silicate.
Further, the raw material components of blue and white color material are as follows: 30-40 parts of aluminium oxide, quartz 20-30 parts, cobalt oxide
10-15 parts, 5-10 parts of zinc oxide, 5-10 parts of feldspar, 5-10 parts of sodium metavanadate, 5-10 parts of sodium fluoride.
Further, the raw material components of blue and white color material are as follows: 34 parts of aluminium oxide, quartzy 23 parts, 12 parts of cobalt oxide, zinc oxide
8 parts, 8 parts of feldspar, 7 parts of sodium metavanadate, 8 parts of sodium fluoride.
A kind of manufacture craft of the blue and white porcelain with wood kiln effect modelled after an antique makes above-mentioned with wood kiln effect modelled after an antique
Blue and white porcelain, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, enamel frit makeing prepares clear frit modelled after an antique, by the parts by weight of raw materials of clear frit modelled after an antique by quartz, aluminium hydroxide, potassium
Feldspar, lime stone, calcination of talc, kaolin, zirconium silicate, which are added in wet bulb grinding machine, is made clear frit modelled after an antique；
Step 3, glazing draws blue and white pattern using blue and white color material on ceramic body, after waiting blue and white material dry, is making pottery
Porcelain billet surface applies clear frit modelled after an antique, and glaze slip thickness is more than or equal to 0.2-0.5mm；
Step 4, it fires for the first time, ceramic body is put into this progress first time firing of gas kiln, firing temperature is
1290-1300 DEG C；
Step 5, it fires for second, the ceramics after gas kiln is fired are transferred in electrical kiln when being cooled to 200-300 DEG C, are heated up
To 1210-1220 DEG C, pine branch is added into electrical kiln, continues to fire 5-8 hours, obtains the blue and white pottery with wood kiln effect modelled after an antique
Porcelain.
Further, middle material in wet bulb grinding machine in step 2: ball: the ratio of water is 2:1:1-2, and milling time is that 4-5 is small
When.
Further, 3-5 investment pine branch is divided in step 5.
Further, pine branch dosage described in step 5 is that every cubic metre of kiln launches 600-800g.
Further, one layer of turpentine oil is smeared outside pine branch.
Further, the firing control of electrical kiln is as follows in step 5: be rapidly heated: electrical kiln is warming up to 8-10 DEG C/min
600-650 DEG C；Heat up at a slow speed: furnace temperature is warming up to 1000-1010 DEG C with 5-8 DEG C/min, then is warming up to 1-2 DEG C/min
1210-1220 DEG C, it is every that pine branch put by kiln hole when constant temperature 3-5 is small when temperature reaches 1210-1220 DEG C, when constant temperature
Every pine branch of 30-50 minutes investments；Blowing out is cooling: blowing out, Temperature fall is cooling, kiln discharge.
Blue and white porcelain provided by the invention with wood kiln effect modelled after an antique, introduces clear frit modelled after an antique and the blueness of distinct configuration
Festoon material, the blueness fired by matching fired blue and white porcelain and traditional wood kiln with blue and white porcelain method for cooking provided by the invention
The effect on flower porcelain surface is closest, and artistic effect is unique；The present invention provides a kind of completely new blue and white porcelain method for cooking, by making
After being fired with gas kiln, the secondary firing of electrical kiln is reused, when firing using electrical kiln, pine branch, the firing of pine branch have been put into kiln
When formed oil-containing gases be covered in ceramic surface, make ceramic surface have glossy gloss, furthermore reduce the brightness of oil modelled after an antique,
Keep the color of glaze modelled after an antique slightly partially green, effect of the color closer to wood kiln.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
A kind of blue and white porcelain with wood kiln effect modelled after an antique, including ceramic body, it is characterised in that: further include being sequentially arranged in
Blue and white color material and clear frit modelled after an antique on ceramic body, the parts by weight of raw materials of the clear frit modelled after an antique are as follows: 30-40 parts quartzy,
15-20 parts of aluminium hydroxide, 15-20 parts of potassium feldspar, 10-15 parts of lime stone, 10-15 parts of calcination of talc, kaolin 5-10
Part, 1-5 parts of zirconium silicate；
The raw material components of the blue and white color material are as follows: 30-40 parts of aluminium oxide, 20-30 parts of quartz, cobalt oxide 10-15
Part, 5-10 parts of zinc oxide, 5-10 parts of feldspar, 5-10 parts of sodium metavanadate, 5-10 parts of sodium fluoride.
Above by the clear frit modelled after an antique of the selection preparation of the component of raw material, after the firing of gas kiln, surface gloss is low,
When again passing by electrical kiln firing, the grease in electric kiln is adsorbed on clear frit modelled after an antique, forms glossy effect；Blue and white color material
Firing temperature is 1080-1100 degrees Celsius, and blue and white color material color development is completed when firing in gas kiln, is guaranteed in being transferred to electrical kiln again
When secondary firing, the color development of blue and white material is stablized.
A kind of manufacture craft of the blue and white porcelain with wood kiln effect modelled after an antique makes above-mentioned with wood kiln effect modelled after an antique
Blue and white porcelain, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, enamel frit makeing prepares clear frit modelled after an antique, by the parts by weight of raw materials of clear frit modelled after an antique by quartz, aluminium hydroxide, potassium
Feldspar, lime stone, calcination of talc, kaolin, zirconium silicate, which are added in wet bulb grinding machine, is made clear frit modelled after an antique, in wet bulb grinding machine in
Material: ball: the ratio of water is 2:1:1-2, and milling time is 4-5 hours；
Step 3, glazing draws blue and white pattern using blue and white color material on ceramic body, after waiting blue and white material dry, is making pottery
Porcelain billet surface applies clear frit modelled after an antique, and glaze slip thickness is more than or equal to 0.2-0.5mm；
Step 4, it fires for the first time, ceramic body is put into this progress first time firing of gas kiln, firing temperature is
1290-1300 DEG C；
Step 5, it fires for second, the ceramics after gas kiln is fired are transferred in electrical kiln when being cooled to 200-300 DEG C, are heated up
To 1210-1220 DEG C, pine branch is added into electrical kiln, continues to fire 5-8 hours, obtains the blue and white pottery with wood kiln effect modelled after an antique
The firing control of porcelain, electrical kiln is as follows:
Be rapidly heated: electrical kiln is warming up to 600-650 DEG C with 8-10 DEG C/min；
Heat up at a slow speed: furnace temperature is warming up to 1000-1010 DEG C with 5-8 DEG C/min, then is warming up to 1-2 DEG C/min
1210-1220 DEG C, it is every that pine branch put by kiln hole when constant temperature 3-5 is small when temperature reaches 1210-1220 DEG C, when constant temperature
Every pine branch of 30-50 minutes investments, divide 3-5 investment pine branch, pine branch dosage is that every cubic metre of kiln launches 600-
800g, pine branch smear one layer of turpentine oil outside；
Blowing out is cooling: blowing out, Temperature fall is cooling, kiln discharge.
Specific embodiment one:
A kind of blue and white porcelain with wood kiln effect modelled after an antique, including ceramic body, further include being sequentially arranged on ceramic body
Blue and white color material and clear frit modelled after an antique, the parts by weight of raw materials of the clear frit modelled after an antique it is as follows: quartz 32 parts, 16 parts of aluminium hydroxide,
18 parts of potassium feldspar, 13 parts of lime stone, 12 parts of calcination of talc, 6 parts of kaolin, 3 parts of zirconium silicate；The raw material components of the blue and white color material
It is as follows: 34 parts of aluminium oxide, quartzy 23 parts, 12 parts of cobalt oxide, 8 parts of zinc oxide, 8 parts of feldspar, 7 parts of sodium metavanadate, 8 parts of sodium fluoride.
A kind of manufacture craft of the blue and white porcelain with wood kiln effect modelled after an antique makes above-mentioned with wood kiln effect modelled after an antique
Blue and white porcelain, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, enamel frit makeing prepares clear frit modelled after an antique, by the parts by weight of raw materials of clear frit modelled after an antique by quartz, aluminium hydroxide, potassium
Feldspar, lime stone, calcination of talc, kaolin, zirconium silicate, which are added in wet bulb grinding machine, is made clear frit modelled after an antique, in wet bulb grinding machine in
Material: ball: the ratio of water is 2:1:1, and milling time is 5 hours；
Step 3, glazing obtains blue and white color material after mixing blue and white color material according to raw material components, made pottery using blue and white color material
Blue and white pattern is drawn on porcelain billet body, after waiting blue and white material dry, applies clear frit modelled after an antique on ceramic body surface, glaze slip thickness is greater than
Equal to 0.4mm；
Step 4, it fires for the first time, ceramic body is put into this progress first time firing of gas kiln, firing temperature is
1298℃；
Step 5, it fires for second, the ceramics after gas kiln is fired are transferred in electrical kiln when being cooled to 275 DEG C, are warming up to 1218
DEG C, pine branch is added into electrical kiln, continues to fire 7 hours, obtains the blue and white porcelain with wood kiln effect modelled after an antique, the firing control of electrical kiln
It makes as follows:
Be rapidly heated: electrical kiln is warming up to 630 DEG C with 8 DEG C/min；
Heat up at a slow speed: furnace temperature is warming up to 1050 DEG C with 6 DEG C/min, then is warming up to 1220 DEG C with 2 DEG C/min, when temperature reaches
Constant temperature 4 hours at 1220 DEG C put into pine branch every pine branch of 45 minutes investments by kiln hole when constant temperature, and point 5 investments are loose
Branch, pine branch dosage are that every cubic metre of kiln launches 600g, smear one layer of turpentine oil outside pine branch；
Blowing out is cooling: blowing out, Temperature fall is cooling, kiln discharge.
Blue and white porcelain provided by the invention with wood kiln effect modelled after an antique introduces the imitative of distinct configuration
Ancient clear frit and blue and white color material, by matching fired blue and white porcelain and tradition with blue and white porcelain method for cooking provided by the invention
The effect on the blue and white porcelain surface that wood kiln is fired is closest, and artistic effect is unique；The present invention provides a kind of completely new blue and white porcelains to burn
Method processed after being fired by using gas kiln, is reused the secondary firing of electrical kiln, when being fired using electrical kiln, pine has been put into kiln
Branch forms oil-containing gases when the firing of pine branch and is covered in ceramic surface, so that ceramic surface is had glossy gloss, furthermore reduce
The brightness of oil modelled after an antique keeps the color of glaze modelled after an antique slightly partially green, effect of the color closer to wood kiln.
It above are only the specific embodiment of the present invention, but the design concept of the present invention is not limited to this, all benefits
It is made a non-material change to the present invention, should all be belonged to behavior that violates the scope of protection of the present invention with this design.
Claims (10)
1. a kind of blue and white porcelain with wood kiln effect modelled after an antique, including ceramic body, it is characterised in that: further include being sequentially arranged in pottery
Blue and white color material and clear frit modelled after an antique on porcelain billet body, the parts by weight of raw materials of the clear frit modelled after an antique are as follows: 30-40 parts quartzy, hydrogen
15-20 parts of aluminium oxide, 15-20 parts of potassium feldspar, 10-15 parts of lime stone, 10-15 parts of calcination of talc, 5-10 parts of kaolin,
1-5 parts of zirconium silicate.
2. the blue and white porcelain according to claim 1 with wood kiln effect modelled after an antique, it is characterised in that: the clear frit modelled after an antique
Raw material components it is as follows: quartzy 32 parts, 16 parts of aluminium hydroxide, 18 parts of potassium feldspar, 13 parts of lime stone, 12 parts of calcination of talc, kaolinite
6 parts, 3 parts of zirconium silicate of soil.
3. the blue and white porcelain according to claim 1 or 2 with wood kiln effect modelled after an antique, it is characterised in that: the blue and white coloured silk
The raw material components of material are as follows: 30-40 parts of aluminium oxide, 20-30 parts of quartz, 10-15 parts of cobalt oxide, 5-10 parts of zinc oxide, length
5-10 parts of stone, 5-10 parts of sodium metavanadate, 5-10 parts of sodium fluoride.
4. the blue and white porcelain according to claim 3 with wood kiln effect modelled after an antique, it is characterised in that: the blue and white color material
Raw material components are as follows: 34 parts of aluminium oxide, quartzy 23 parts, 12 parts of cobalt oxide, 8 parts of zinc oxide, 8 parts of feldspar, 7 parts of sodium metavanadate, fluorine
Change 8 parts of sodium.
5. a kind of manufacture craft of the blue and white porcelain with wood kiln effect modelled after an antique, production requires to have described in 1-4 any one
The blue and white porcelain of wood kiln effect modelled after an antique, the specific steps are as follows:
Step 1, base prepares ceramic body, and the ceramic body repaired biscuit made is formed；
Step 2, enamel frit makeing prepares clear frit modelled after an antique, by clear frit modelled after an antique parts by weight of raw materials by quartz, aluminium hydroxide, potassium feldspar,
Lime stone, calcination of talc, kaolin, zirconium silicate, which are added in wet bulb grinding machine, is made clear frit modelled after an antique；
Step 3, glazing draws blue and white pattern using blue and white color material on ceramic body, after waiting blue and white material dry, in ceramic blank
Clear frit modelled after an antique is applied in body surface face, and glaze slip thickness is more than or equal to 0.2-0.5mm；
Step 4, it fires for the first time, ceramic body is put into this progress first time firing of gas kiln, firing temperature 1290-
1300℃；
Step 5, it fires for second, the ceramics after gas kiln is fired are transferred in electrical kiln when being cooled to 200-300 DEG C, are warming up to
1210-1220 DEG C, pine branch is added into electrical kiln, continues to fire 5-8 hours, obtains the blue and white pottery with wood kiln effect modelled after an antique
Porcelain.
6. the manufacture craft of the blue and white porcelain according to claim 5 with wood kiln effect modelled after an antique, it is characterised in that: described
Middle material in wet bulb grinding machine in step 2: ball: the ratio of water is 2:1:1-2, and milling time is 4-5 hours.
7. the manufacture craft of the blue and white porcelain according to claim 5 with wood kiln effect modelled after an antique, it is characterised in that: described
Divide 3-5 investment pine branch in step 5.
8. the manufacture craft of the blue and white porcelain according to claim 5 or 7 with wood kiln effect modelled after an antique, it is characterised in that:
Pine branch dosage described in the step 5 is that every cubic metre of kiln launches 600-800g.
9. the manufacture craft of the blue and white porcelain according to claim 5 or 7 with wood kiln effect modelled after an antique, it is characterised in that:
One layer of turpentine oil is smeared outside the pine branch.
10. the manufacture craft of the blue and white porcelain according to claim 7 with wood kiln effect modelled after an antique, which is characterized in that step
The firing control of electrical kiln is as follows in rapid 5:
Be rapidly heated: electrical kiln is warming up to 600-650 DEG C with 8-10 DEG C/min；
Heat up at a slow speed: furnace temperature is warming up to 1000-1010 DEG C with 5-8 DEG C/min, then is warming up to 1210- with 1-2 DEG C/min
1220 DEG C, when constant temperature 3-5 is small when temperature reaches 1210-1220 DEG C, pine branch is put into every 30- by kiln hole when constant temperature
Pine branch of 50 minutes investments；
Blowing out is cooling: blowing out, Temperature fall is cooling, kiln discharge.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910298697.8A CN110040959A (en) | 2019-04-15 | 2019-04-15 | A kind of blue and white porcelain and its manufacture craft with wood kiln effect modelled after an antique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910298697.8A CN110040959A (en) | 2019-04-15 | 2019-04-15 | A kind of blue and white porcelain and its manufacture craft with wood kiln effect modelled after an antique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110040959A true CN110040959A (en) | 2019-07-23 |
Family
ID=67277067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910298697.8A Withdrawn CN110040959A (en) | 2019-04-15 | 2019-04-15 | A kind of blue and white porcelain and its manufacture craft with wood kiln effect modelled after an antique |
Country Status (1)
| Country | Link |
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| CN (1) | CN110040959A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113292359A (en) * | 2021-06-18 | 2021-08-24 | 景德镇陶瓷大学 | Antique blue and white material, preparation method thereof and antique blue and white porcelain comprising antique blue and white material |
| CN114835476A (en) * | 2022-03-15 | 2022-08-02 | 福建省德化县豪发陶瓷有限公司 | High-strength blue-and-white five-color glazed porcelain and preparation method thereof |
-
2019
- 2019-04-15 CN CN201910298697.8A patent/CN110040959A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113292359A (en) * | 2021-06-18 | 2021-08-24 | 景德镇陶瓷大学 | Antique blue and white material, preparation method thereof and antique blue and white porcelain comprising antique blue and white material |
| CN114835476A (en) * | 2022-03-15 | 2022-08-02 | 福建省德化县豪发陶瓷有限公司 | High-strength blue-and-white five-color glazed porcelain and preparation method thereof |
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Application publication date: 20190723 |